Revision Date: 10/1/2008 Revision Date: 10/1/2008 10/1/2008 Document Control Number: Document Control Number:
SWP 5-17
TETRA TECH, INC. TETRA TECH, INC.
BIOHAZA BIOHAZARD SAFETY BIOHAZARD SAFETYRD SAFETY RD SAFETY
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet.
Revision Date Revision Date Document Authorizer Document Authorizer Revision Details Revision Details 10/1/2008 Chris McClain Update from 1998 format
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ITEM 11.1. ATTACHMENT 3
Revision Date: 10/1/2008 Revision Date: 10/1/200810/1/2008 10/1/2008 Document Control Number: Document Control Number:
5-19
TETRA TECH, INC. TETRA TECH, INC. A TECH, INC.
SAFE LIFTING and CARRYING PRACTICES AFE LIFTING and CARRYING PRACTICES AFE LIFTING and CARRYING PRACTICES
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet.
To prevent injuries and adverse health effects, the following general safe work practices (SWP) are to be followed when lifting and carrying while in an office or field environment. These SWPs establish a pattern of general precautions and measures for reducing risks associated with back injury and trauma associated with improper lifting and carrying of heavy objects. This list is not inclusive and may be amended as necessary.
· First, inspect the area where the load will be lifted, transported, and then deposited. Remove any obstacles that could present a tripping or other hazard. · Perform a "test lift" by slightly pushing or moving the object to gauge your ability to safely lift/move/deposit the item without injuring yourself. IF YOU ARE NOT CONFIDENT THAT YOU
CAN MOVE THE OBJECT WITHOUT INJYURING YOURSELF - THEN EITHER GET A MECHANICAL LIFTING AID OR GET HELP. DO NOT ATTEMPT TO MOVE THE OBJECT YOURSELF. · Get as close to the object as you can, and bend at the knees (not at the back). · Assure that can get a firm grasp on the object.
· Keeping the load as close to you body as possible, lift with your legs, and avoid turning or twisting while lifting, carrying, or depositing the load. · Carry the object in a manner that it does not obstruct your vision and so that you can maintain a clear line of sight of your path of travel and the area where you will set it down. · Set the object down using the same techniques as you did in lifting it (don't turn or twist, keep it close to your body, use your legs - not your back).
Disclaimer: This safe work practice (SWP) is the property of Tetra Tech, Inc. (Tetra Tech). Any reuse of the SWP without DisclaimerDisclaimer Tetra Tech’s permission is at the sole risk of the user. The user will hold harmless Tetra Tech for any damages that result from unauthorized reuse of this SWP. Authorized users are responsible for obtaining proper training and qualification from their employer before performing operations described in this SWP. ~
ITEM 11.1. ATTACHMENT 3
Revision Date: 10/1/2008 Revision Date: 10/1/200810/1/2008 10/1/2008 Document Control Number: Document Control Number:
5-19
TETRA TECH, INC. TETRA TECH, INC. A TECH, INC.
SAFE LIFTING and CARRYING PRACTICES AFE LIFTING and CARRYING PRACTICES AFE LIFTING and CARRYING PRACTICES
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet.
Revision Date Revision Date Document Authorizer Document Authorizer Revision Details Revision Details 10/1/2008 Chris McClain Update from 1998 format
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ITEM 11.1. ATTACHMENT 3
Revision Date: 10/1/2008
Document Control Number:
SWP 5-26
TETRA TECH, INC.
PREVENTION of SUN EXPOSURE
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet.
By far, the most common cause of skin cancer is overexposure to the sun. Ninety percent of all skin cancers occur on parts of the body that not usually covered by clothing. People who sunburn easily, and those with fair skin and red or blond hair are more prone to develop skin cancer. The amount of time spent in the sun also affects a person's risk of skin cancer.
Premature aging of the skin also occurs with prolonged sun exposure. Tetra Tech encourages personnel to avoid prolonged exposure to the sun, and recommends the following:
• Sunburn can occur during any time of the year. To avoid sunburn, wear hats with wide brims.
• Use sunscreen with a Sun Protective Factor (SPF) rating of 15 or higher. • To prevent skin cancer:
o Cover up with a wide brimmed hat and a bandanna for your neck. Wear longsleeved shirts and pants which the sun cannot penetrate. o Use sunscreens to help prevent skin cancer as well as premature aging of your skin. Use a Sun Protective Factor (SPF) rating of 15 or higher. o Apply sunscreen at least an hour before going into the sun and again after swimming or perspiring a lot.
o Do not use indoor sun lamps, tanning salons/parlors, or tanning pills. • You can still get burned on a cloudy day. Try to stay out of the direct sun at midday, because sun rays are their strongest between 10 a.m. and 3 p.m. Beware of high altitudes - where there is less atmosphere to filter out the ultraviolet rays. Skiers should remember that snow reflects the sun's rays, too.
• Know your skin. Whatever your skin type, do a monthly self-examination of your skin to note any moles, blemishes or birthmarks. Check them once a month and if you notice any changes in size, shape or color, or if a sore does not heal, see your physician without delay.
Disclaimer: This safe work practice (SWP) is the property of Tetra Tech, Inc. (Tetra Tech). Any reuse of the SWP without Tetra Tech’s permission is at the sole risk of the user. The user will hold harmless Tetra Tech for any damages that result from unauthorized reuse of this SWP. Authorized users are responsible for obtaining proper training and qualification from their employer before performing operations described in this SWP.
Document Authorizer
Revision Date
Name Approval Date
Revision Details
Chris McClain 10/1/2008
Rick Lemmon
NEW
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ITEM 11.1. ATTACHMENT 3
Revision Date: 10/1/2008
Document Control Number:
SWP 5-26
TETRA TECH, INC.
PREVENTION of SUN EXPOSURE
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet. ~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
UNDERGROUND UTILITIES
Revision Date: 10/01/2011
Document Control Number:
SWP 5-35
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet.
1.0 PURPOSE
This program provides requirements for identification, location, and avoidance of underground utilities, appurtenances, and structures during intrusive activities. The program also addresses actions to be taken in response to encountering or contacting underground utilities.
2.0 SCOPE
These requirements are applicable to all Tetra Tech operations. The procedures address the requirements and recommendations for identifying and locating, working around, and encountering or contacting underground utilities.
3.0 MAINTENANCE
The Vice President, Corporate Health and Safety or designee is responsible for updating this procedure. Approval authority rests with Tetra Tech’s Senior Vice President, Corporate Administration. Suggestions for revision shall be submitted to Corporate Administration department.
4.0 DEFINITIONS
4.1 Aggressive Methods
The use of mechanized equipment such as excavators, backhoes, drill rigs, directional drilling, road saws, etc. Non-Aggressive methods involve the use of manual or non-mechanized methods such as hand-digging with shovels and air/hydro/vacuum methods.
4.2 Buffer Zone
As defined in this procedure, the area around a utility where only non-aggressive excavation methods may be utilized, unless specific conditions are met.
The definition cited above, and the excavation requirements and restrictions associated with it, will vary depending on the particular state regulations. Tetra Tech requires the imposition of a four-foot ~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
UNDERGROUND UTILITIES
Revision Date: 10/01/2011
Document Control Number:
SWP 5-35
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet.
Buffer Zone on all sides of the utility as measured from the outside edges of the utility, both horizontally and vertically. Since most jurisdictions recognize Buffer Zones which vary somewhere in the range of 18 to 36 inches, this distance must be verified by consulting the applicable state regulations before excavating so that adjustments to surface markings can be made to achieve the required four-foot buffer zone.
Referred to as the “Tolerance Zone”, “Safety Zone”, or “Approximate Location of Underground Utilities” in some jurisdictions.
Information relative to excavation within the buffer zone is contained in Section 5.2.2.4.
4.3 Competent Person
A Competent Person has the ability to recognize hazards associated with underground utilities and the authority to stop or direct operations to ensure the safety of personnel and conformance with this procedure. The Competent Person has an understanding of this procedure, and the “One-Call” system requirements for the jurisdiction where excavation is occurring. The Competent Person must be capable of notifying One-Call agencies and maintaining and tracking One-Call Locate Numbers. Additionally, they must have knowledge of methods and work practices for utility identification, avoidance, and protection.
4.4 De-Energize
As applicable to a utility, to physically eliminate and/or prevent the presence, transmission, flow, or release of energy or materials which may cause harm to personnel or property.
4.5 Excavation
An operation for the purpose of movement or removal of earth, rock, or the materials in the ground, including but not limited to; digging, blasting, auguring, backfilling, test boring, drilling, pile driving, directional drilling, grading, plowing-in, hammering, pulling-in, jacking-in, trenching, tunneling, structural demolition, milling, scraping, tree and root removal (grubbing), fence or sign post installation. Tetra Tech requires that the designated One-Call agency for the applicable jurisdiction be contacted any time an intrusive activity is planned.
4.6 Jurisdiction
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ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
UNDERGROUND UTILITIES
Revision Date: 10/01/2011
Document Control Number:
SWP 5-35
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet.
The authority having legal jurisdiction relative to regulations and requirements for notification of excavation activities and associated identification and marking. In the United States, the states have jurisdiction, and most consider the regulations applicable when excavation is to be performed in any location, including any public or private way, any company right-of-way or easement, or any public or privately owned land or way.
4.7 Locate
To indicate the existence of a utility by establishing a mark through the use of flags, pins, stakes, paint, or some other customary manner, that approximately determines the location of a line or facility.
4.8 Locate Request
A communication between an entity performing intrusive activities and a utility marking agency (One-Call, etc.).
4.9 Observer
The person assigned to visually monitor and, as needed, signal the operator during mechanized intrusive activity when the activity is occurring within four feet of the outside edge of the buffer zone. This person remains in close communication with the equipment operator(s) and will stop the activity if needed.
4.10 One-Call Agency
An entity that administers a system through which a person can notify owners/operators of underground lines or utilities of the intent to perform intrusive activities in proposed public areas.
4.11 Positive Response
Communication with the entity performing intrusive activities, prior to the activity, to ensure that all contacted (typically via the One-Call agency) owner/operators have located and marked the underground utilities.
4.12 Potholing
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ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
UNDERGROUND UTILITIES
Revision Date: 10/01/2011
Document Control Number:
SWP 5-35
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet.
The practice of exposing an underground facility by safe, non-aggressive excavation methods in order to ascertain the precise horizontal and vertical position and orientation of underground lines or utilities.
4.13 Underground Utility
An underground or submerged conductor, pipe, or structure used in providing electric or communications service (including but not limited to, traffic control loops and similar underground or submerged devices), or an underground or submerged pipe used in carrying, providing, or gathering gas, oil or oil product, sewage, storm drainage, water or other liquid service (including, but not limited to, irrigation systems), and appurtenances thereto. As used in this procedure, utility includes all underground appurtenances and structures.
The following are examples of the types of underground utilities that may be present in a given location:
Natural gas pipelines
High voltage electric cables
Water pipelines
Fiber optic telecommunications lines
Steam pipelines
Gasoline, oil, or other fuels
Sewer pipelines
Hazardous Materials
Underground Storage Tanks (USTs)
Abandoned underground structures containing hazardous materials, hazardous wastes, and radioactive materials
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ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
UNDERGROUND UTILITIES
Revision Date: 10/01/2011
Document Control Number:
SWP 5-35
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet.
Note: Electrical and pressurized mechanical underground utilities that are not energized shall be considered as applicable to the requirements of this procedure until they are disconnected and removed or protected by a lockout/tagout system approved by Tetra Tech (see Section 5.2.2.6)
4.14 Underground Utility Owner
Any person, utility, municipality, authority, political subdivision or other person or entity who owns, operates, or controls the operation of an underground line/facility.
4.15 White Lining
The practice whereby the entity which intends to perform intrusive activities pre-marks the site with an outline of the area where intrusive activities will occur. This involves the use of white paint, flags, stakes, or a combination thereof to mark the extent of where work is to be performed. The marking may vary depending on what intrusive activities are to be conducted. For example, for general excavation, an area outline of the excavation shall be marked, while for drilling, the individual boreholes shall be marked. Studies have shown that pre-marking is a practice that does prevent utility contact incidents.
5.0 DISCUSSION
5.1 Responsibilities
5.1.1 Competent Person
The Competent Person shall be responsible for:
Obtaining a copy of, and understanding the applicable regulations for the state of jurisdiction where the excavation activities are to be performed. Contacting the appropriate One-Call agency or private locating service, as applicable. Recording One-Call locate numbers.
If necessary, renewing One-Call locate numbers before expiration. Ensuring that white-lining of the area to be excavated is performed. ~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
UNDERGROUND UTILITIES
Revision Date: 10/01/2011
Document Control Number:
SWP 5-35
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet. Ensuring that a “positive response” has been received from every utility owner/operator identified by the One-Call agency and that they have located their underground utilities and have appropriately marked any potential conflicts with the areas of planned intrusive activities.
Completion of the Ground Disturbance Permit (Excavation/Utility Locates) or equivalent. Reviewing applicable AHAs or other client specific requirements with all project members before work begins.
Conducting training on communication protocols to be used by the excavation observer and equipment operator.
Ensuring Implementation of appropriate work practices during intrusive activities (including maintaining the prescribed buffer zone for use of aggressive methods). Conducting daily inspections of the excavation area to make sure that all markings are intact.
Maintaining required records.
Providing the Project Manager or Site Supervisor with all required documentation on a daily basis.
5.1.2 Observer
Whenever intrusive operations with mechanized equipment are being conducted within four feet of the outside edge of the buffer zone, horizontally and vertically, an observer must be assigned to monitor the activities. The observer is responsible for:
Observing the operation to ensure that the operator stops operations if utilities are observed.
Reviewing hand signals and other forms of communication with the operator. Properly signaling the operator.
~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
UNDERGROUND UTILITIES
Revision Date: 10/01/2011
Document Control Number:
SWP 5-35
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet. Stopping the operation immediately if the observer’s attention must be diverted even momentarily.
Stopping the operation immediately if a hand signal or other directive is not followed.
Operations will not resume until the observer and operator mutually agree that the reason(s) for not complying with the directive(s) are/is identified and fully corrected. Maintaining required records, such as logbook entries, or other, as requested by line management.
5.1.3 Line Management
The Project Manager (PM) shall be responsible for:
Ensuring compliance with this procedure.
Providing the necessary resources for compliance with this procedure. Designating Competent Personnel in consultation with the Site Safety Coordinator prior to the start of work.
5.1.4 Site Safety Coordinator
The Site Safety Coordinator (SSC) shall be responsible for:
Providing oversight on the implementation of the requirements contained in this procedure. Consulting with the PM and Competent Person on underground utility issues.
5.2 Procedure
The following sections provide the requirements and recommendations of this procedure, which are intended to prevent injury to personnel, damage to infrastructure, and associated indirect effects associated with encountering or contacting underground utilities during the execution of intrusive work. Underground utilities present multiple potential hazards that must be recognized before and during work which occurs near them, therefore, this procedure is divided into sections addressing underground utility identification and location, working around or near underground utilities, and actions to be taken in the event that underground utilities are encountered or ~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
UNDERGROUND UTILITIES
Revision Date: 10/01/2011
Document Control Number:
SWP 5-35
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet. contacted. Hazards that may be presented by underground utilities include explosion and fire, electrocution, toxic exposures, pathogens, and drowning.
5.2.1 Identifying and Locating Underground Utilities
The possibility of the existence of underground utilities must be evaluated as early as possible in the planning phase for any project which involves intrusive activities. The Project Safety Checklist or equivalent should be used for documentation of the identification of this potential hazard and the procedures to be followed to address them. The following sections describe various methods for identifying and locating utilities on a site. Plans should be verified during the readiness review.
The Ground Disturbance Permit (Excavations/Utility Locate) or equivalent must be completed before any activities meeting the definition of excavation are conducted. This document is intended to be used as a guide during the process of locating and marking utilities in the area and in the overall process of underground utilities management during the course of the project.
All underground utilities on a site involving excavation, must be located and identified before intrusive activities commence, by one or more of the following entities:
The Utility Owner
A Private or Public Utility Locating Service
An Approved Tetra Tech Competent Person
These options are described in greater detail in the following Sub-Sections:
5.2.1.1 Pre-Planning and the Site Specific Health and Safety Plan The Site-Specific Health and Safety Plan developed for the project must:
Identify the location and types of underground utilities that are believed to be present on the site.
Reference this procedure and describe how it will be implemented on the project. Contain an Activity Hazard Analysis in which the hazards associated with underground utilities are identified, as well as the measures used to control them. ~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
UNDERGROUND UTILITIES
Revision Date: 10/01/2011
Document Control Number:
SWP 5-35
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet. Contain, as an appendix, a copy of the applicable regulations from the state of jurisdiction where excavation activities are to be performed. These can usually be obtained via the Internet.
Contain clear and concise procedures to be followed in the event that contact with underground utilities occurs.
Address underground utilities and potential associated scenarios in the emergency response section.
5.2.1.2 “One-Call” Locating and Marking Services
Every state has utility marking service programs having various names such as “One-Call”, “DigSafe”, “Call-Before-You-Dig”, “Dig-Safely”, and many others. These services will identify the types and locations of any utility that may exist in an area to be excavated, as long as the property is in the public domain.
The appropriate One-Call service for the jurisdiction where the project is located must be contacted prior to beginning excavation work. The One-Call agency should be given as detailed a description of the property as possible; address, cross street, utility pole numbers, physical description, etc.
Notification to the One-Call service shall allow sufficient lead time for the agency to mark the utilities before excavation begins. The lead times vary, but range from two to ten days, depending on the state of jurisdiction.
A complete listing of One-Call agencies and telephone numbers for all states is available in the “Call-Before-You-Dig Call Center Directory”, which can be accessed online.
Once notified, the One-Call agency will provide the contractor with a unique “locate number” or “reference number”. This reference number must be kept in the project files by the Competent Person or designee. Additionally, the reference numbers have expiration dates, which may vary depending on the particular One-Call agency. The valid period of the locate number and required renew notification date shall be requested from the One-Call agency.
On a project with multiple contractors, each contractor must request a separate locate number.
Under no circumstances will any other contractor or entity be allowed to work under our locate number. Subcontractors to Tetra Tech may excavate under the locate number secured by Tetra ~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
UNDERGROUND UTILITIES
Revision Date: 10/01/2011
Document Control Number:
SWP 5-35
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet.
Tech, provided that they are excavating within the area which was previously white-lined by Tetra Tech and subsequently marked. However, the One-Call agency must be contacted and notified of this arrangement so that the subcontractor can be recorded as working under the existing locate number. If a Tetra Tech subcontractor will be excavating in an area not white-lined by Tetra Tech, then the Tetra Tech subcontractor must request a new locate.
The area where work is to be performed shall be white-lined by Tetra Tech personnel before the locating service goes to the site.
It is good practice to arrange a pre-excavation meeting at the project site with the personnel performing the utility location and marking. This meeting will facilitate communications, coordinate the marking with actual excavation, and assure identification of high-priority utilities.
The One-Call agency should provide the identities of the utility owners that will be notified of the locate request. This information shall be recorded on the Ground Disturbance Permit maintained in the project files. The contact person and phone number for each utility owner shall also be recorded.
The utility owners should provide a “positive response” relative to the locate request, which can consist of two types of action by the utility owner. The facility owner or operator is required to 1) mark it’s underground utilities with stakes, paint, or flags, or 2) notify the excavator that the utility owner/operator has no underground utilities in the area of the excavation.
The positive responses shall be recorded on the Ground Disturbance Permit and cross-checked with the list of utility owners that the One-Call agency stated that they would notify. If it is discovered that a utility owner has not provided a positive response, then the One-Call agency must be notified.
Excavation shall not be conducted until positive responses have been received from all utility owners identified by the One-Call agency as having underground utilities on the property.
Before beginning excavation, the excavator must verify that the location marked was correct, and the distinct, color-coded markings of all utility owners are present.
Examine the site to check for any visible signs of underground utilities that have not been located and marked such as pedestals, risers, meters, warning signs, manholes, pull boxes, valve boxes, ~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
UNDERGROUND UTILITIES
Revision Date: 10/01/2011
Document Control Number:
SWP 5-35
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet. patched asphalt or concrete pavement, areas of subsidence, fresh sod or grass, lack of grass or vegetation, and new trench lines.
The markings placed by the utility owners must be documented by Tetra Tech using a still, digital, or video camera. The photo-documentation shall be maintained with the project files indefinitely.
The markings placed by the utility owners or marking services shall follow the American Public Works Association Uniform Color Code as described in ANSI Standard Z 535.1. This code appears below.
American Public Works Association Uniform Color Code
Red - Electric Power Lines, Cables, Conduit
Orange - Communications, Telephone, Cable TV
Yellow - Gas, Oil, Steam, Petroleum or Gaseous Materials Green - Sewers and Drains
Blue - Potable Water Systems
Purple - Reclaimed Water, Irrigation, Slurry Lines
Pink - Temporary Survey Markings
White - Proposed Excavation
5.2.1.3 Private Utility Locating and Marking Services
As discussed, One-Call agencies arrange for the identification and marking of underground utilities only on public property, up to the point of contact with private property. In the event that excavation activities are to be conducted on non-public properties, the presence, location, depth, and orientation of all underground utilities within the white-lined area shall be ascertained through records review, including any site plot plans, utility layout plans, and as-built drawings available from the property owner, as well as through interviews with knowledgeable personnel associated with the property. Additionally, the information gathered from these sources shall be verified by physical detection methods (non-aggressive), performance of a geophysical survey, or by procuring ~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
UNDERGROUND UTILITIES
Revision Date: 10/01/2011
Document Control Number:
SWP 5-35
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet. the services of a private utility locating and marking service. If any detection methods are to be self-performed, the requirements of 5.2.1.4 must be followed.
The above requirements are also intended to address the potential presence of unknown or undocumented underground utilities, therefore, the area to be excavated must also be evaluated by the PM to determine if the potential for unknown or undocumented underground utilities exist.
If the determination is made that the presence of these unknown or undocumented underground utilities is unlikely, then a variance should be requested to eliminate the requirement to identify them.
Variance to this requirement above must be approved by the PM and SSC.
5.2.1.4 Self-Performance of Utility Locating and Marking The techniques and instruments used to locate and characterize underground utilities can be extremely complicated and difficult to use effectively. Additionally, interpretation of the data generated by this instrumentation can be difficult. The utility marking services described in 5.2.1.1 and 5.2.1.2 are staffed by well-trained, experienced professionals who perform locating activities on a regular basis. For these reasons, it is most desirable that these professional services are used for utility location and marking on projects.
In some instances, such as long-term projects where excavation is a primary task, and the presence of underground utilities is extensive, it may be prudent to self-perform locating and marking activities.
If locating and marking is to be self-performed, all personnel using instrumentation will be trained on the use of the equipment that will be used, and the interpretation of the data.
There are a variety of locating methods which may be utilized for self-performance of utility locating as categorized below:
Magnetic field-based locators or path tracers
Buried electronic marker systems (EMS)
Ground penetration radar-based buried –structure detectors Acoustics-based plastic pipe locators
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ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
UNDERGROUND UTILITIES
Revision Date: 10/01/2011
Document Control Number:
SWP 5-35
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet. Active probes or beacons for non-metallic pipes
Magnetic polyethylene pipe
Before self-performing any underground utility locating on a project, approval must be obtained from the Operating Unit Health and Safety Manager.
5.2.2 Working Near or Around Underground Utilities
After the site has been properly evaluated for the presence of underground utilities, intrusive activities may begin. Since there is no perfect way of eliminating the hazards presented by underground utilities, an effort must be made to perform the tasks following the direction and guidance as described by the following best practices that should be implemented during the execution of the project.
5.2.2.1 Work Site Review
Before beginning intrusive activities, a meeting shall be held between all members of the project team. This shall consist of a review of the marked utility locations with the equipment operators, observers, laborers, etc.
5.2.2.2 Preservation of Marks
During excavation, efforts must be made to preserve the markings placed by the utility owners until they are no longer required. If any markings are obliterated, the One-Call agency must be contacted for re-marking. No intrusive activities are to take place if markings are not visible.
5.2.2.3 Excavation Observer
Whenever intrusive operations are being conducted within four feet of the edge of the buffer zone, an observer must be assigned to monitor the activities. The observer will be designated each day, and a review of hand signals and other forms of communication between the observer and operator will be conducted. The directives of the observer will be followed precisely and immediately by those operating equipment.
5.2.2.4 Excavation Within The Buffer Zone
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ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
UNDERGROUND UTILITIES
Revision Date: 10/01/2011
Document Control Number:
SWP 5-35
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet.
Performing intrusive activities within the buffer zone requires careful adherence to proper guidelines and procedures to minimize the risk of contact with underground utilities.
The purpose of the buffer zone is to designate and define an area where careful, prudent, and reasonable excavation practices are to be used to prevent contact with underground utilities.
However, there may be occasions where it is necessary to perform aggressive excavation methods in this designated area.
The boundaries of the buffer zone as defined in Section 4.2 will be observed at all times during intrusive activities. Aggressive excavation methods (excavators, backhoes, drill rigs) must be restricted to areas outside of the 4-foot buffer zone unless a special exemption to this requirement is obtained.
Consider whether the objective of the project can be completed without performing intrusive activities in the buffer zone at all. This will greatly reduce the risks presented by performing work in close proximity to underground utilities. If after consideration, the determination is made that intrusive activities in the buffer zone are necessary, then a formal exemption request shall be made to the PESM according to the guidelines below.
A request to utilize aggressive excavation methods in the buffer zone may be made if:
There is no other appropriate and reasonable alternative to using aggressive methods in the buffer zone; and
The utility has been de-energized (and purged if necessary), verified as de-energized, and locked-out (per Section 5.2.2.6); or
the depth and orientation of the utility has been adequately and visually determined through the use of non-aggressive methods such as air/hydro/vacuum excavation, potholing, probing, hand-digging, or a combination thereof; and for utilities containing electrical energy, the depth of the existing water table is below the location of the utility; and
application for the exemption has been submitted to the SSC; and the exemption has been granted and approved in writing by the SSC. ~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
UNDERGROUND UTILITIES
Revision Date: 10/01/2011
Document Control Number:
SWP 5-35
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet.
The following conditions will apply to this request:
Aggressive methods may be used in the buffer zone only to the extent allowed by the applicable state or other jurisdictional regulations.
Appropriate physical protection measures for exposed utilities as described in Section
5.2.2.5 shall be implemented to eliminate the potential for equipment contact with utilities. The extent of the project excavation area to be covered by the exemption request must be specified.
When evaluating the use of aggressive excavation methods in the buffer zone, the SSC will consider the type of utility involved and the associated risk potential.
Based on this evaluation, the SSC may impose further conditions and requirements, which will be detailed in the HASP.
Even if the above exemption conditions are met, the SSC has authority to deny the request, the reasons for which will be provided.
Unless exempted according to the above provisions of this procedure, only non-aggressive methods may be used within the buffer zone. Non-aggressive, or non-mechanized equipment is used in order to prevent mechanical contact with underground utilities which could result in damage to the utility and create the potential for personal injury and property damage. Following are examples of non-aggressive excavation methods:
Hand-digging
Non-conductive hand tools must be used when digging within the buffer zone surrounding underground electrical utilities.
If conductive hand tools must be used near electrical lines, then the SSC shall be consulted to determine additional requirements relative to safe electrical practices, procedures, and equipment.
Hydro-excavation (water pressure).
Air excavation (air pressure).
~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
UNDERGROUND UTILITIES
Revision Date: 10/01/2011
Document Control Number:
SWP 5-35
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet. Vacuum extraction (soil excavation/removal).
Air excavation/vacuum extraction combination.
Aggressive methods may be used for the removal of pavement over a utility, if allowed by the state regulations.
5.2.2.5 Protection of Underground Utilities
It is very important that consideration be given to the protection of underground utilities when performing adjacent intrusive activities. This is necessary not only to prevent physical damage and associated indirect effects, but also to prevent the potential for injury to employees and the public.
When using aggressive excavation methods within the buffer zone around exposed underground utilities, physical protection may be appropriate. Basically, this involves creation of a physical barrier between the mechanized operation and the utility. The following are some possible types of physical protective measures:
Heavy timbers, similar to swamp mats.
Sheets of plywood.
Blasting mats.
Once exposed, underground utilities no longer have the support provided by surrounding soil and may need to be physically supported to prevent shifting, bending, separation, or collapse, which could result in damage to the utility, and possibly personnel. Following are suggested support methods:
Timber shoring underneath the utility.
Timbers or girders over the top of the excavation fitted with hangers that support the utility. Design by a PE for complicated or large applications. Utilities must also be protected from objects that may fall into the excavation such as rocks and equipment. This can be accomplished by following these guidelines:
~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
UNDERGROUND UTILITIES
Revision Date: 10/01/2011
Document Control Number:
SWP 5-35
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet. Cast spoils as far away from the excavation as possible. Excavated and loose materials shall be kept two feet from the edge of excavations, as required by OSHA. Relocate large rocks, cobbles, and boulders away from the excavation and sloped spoils piles.
When vehicles and machinery are operating adjacent to excavations, warning systems such as soil berms, stop logs or barricades shall be utilized to prevent vehicles from entering the excavation or trench.
Scaling or barricades shall be used to prevent rock and soils from falling into the excavation.
Barriers shall be provided to prevent personnel from inadvertently falling into an excavation.
5.2.2.6 De-Energizing Utilities
Utilities can carry many types of potential energy, including electricity, flowing liquids, liquids under pressure, gasses under pressure, etc. A release, such as may happen if a utility conveyance is compromised, could result in personal injury, property damage, and other indirect effects. If the white lines of the proposed excavation area overlaps or extends into the buffer zone of a known underground utility, then if at all possible, that utility shall be de-energized to physically prevent the transmission, flow, or release of energy. Conversely, if the buffer zone of the known utility lies outside of the white-lined, proposed excavation area, then de-energization is not required.
The owner of the utility shall be contacted to determine the feasibility and methodology of deenergizing the utility. Plenty of lead-time should be provided for this since it may take utility companies weeks to de-energize some utilities.
Depending on the utility and the material being conveyed, isolation points which may be suitable for de-energizing include but are not limited to the following:
Electrical circuit breakers
Slide gate
~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
UNDERGROUND UTILITIES
Revision Date: 10/01/2011
Document Control Number:
SWP 5-35
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet. Disconnect switches
Piping flanges
Other similar devices
When utilities are de-energized, it must be verified by demonstration. This can be accomplished by testing equipment, switching on a machine or lighting, opening a valve, etc. For any currentcarrying electrical equipment, such as cables, electrical panels, etc., successful de-energization must be certified through the use of appropriate electrical testing equipment.
Whenever a utility is de-energized, a means of ensuring that the energy isolation device and equipment cannot be operated until the device is removed must be provided. Typically, this is achieved by utilizing a lockout device, accompanied by a written tag that physically controls the configuration of the energy isolation point. Lockout devices include but are not limited to the following:
Locks
Chains
Valve covers
Circuit breaker hasps
Blind flanges
Slip blinds, and
Multiple lock hasps
When de-energizing and locking out of utilities is practiced, the provisions of DCN 2-16 Control of Hazardous Energy Lockout/Tagout, shall be followed, as applicable.
In the event that a utility is de-energized, but there is no means of adequately providing a physical locking-out of the utility, then a spotter must be posted at the point of isolation to ensure that the utility is not re-energized. The spotter must be supplied with a communication device such as a site radio.
~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
UNDERGROUND UTILITIES
Revision Date: 10/01/2011
Document Control Number:
SWP 5-35
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet.
5.2.2.7 Damage Discovery
During excavation, utility damage may be discovered which is pre-existing or otherwise not related to a known contact. Disclosure to the utility owner is very important because the possibility of utility failure or endangerment of the surrounding population increases when damage has occurred. The utility may not immediately fail as a result of damage, but the utility owner or operator must be afforded the opportunity to inspect the utility and make a damage assessment and effect repairs if necessary. The following guidance applies:
Observe and photograph the utility from a safe distance and determine in there is damage.
Damage would be all breaks, leaks, nicks, dents, gouges, grooves, or other damages to utility lines, conduits, coatings, or cathodic protection systems. The One-Call agency or private location service must be contacted immediately.
5.2.3 Encountering or Contacting Underground Utilities
In the event that encountering or contacting an underground utility occurs, it is imperative that the appropriate actions are taken to minimize damage to the utility, prevent personal injury, and minimize indirect effects.
5.2.3.1 Encountering Underground Utilities
It is possible that underground utilities will be encountered in locations that have previously been “cleared” of having underground utilities by the locating service, or are found outside of the area which has been marked as having underground utilities. In either case, if this occurs, the following applies:
Intrusive activities must be curtailed
The One-Call agency or private location service must be contacted immediately The PM and PESM must be notified
No further intrusive activities may be conducted until:
The One-Call agency/private location service and/or the subject utility owner visit the site; ~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
UNDERGROUND UTILITIES
Revision Date: 10/01/2011
Document Control Number:
SWP 5-35
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet. Identification of the utility owner and the type of material/energy being conveyed by the utility has been made; and
The orientation and depth of the subject utility has been determined and suitably marked. A Tetra Tech Incident Report and Investigation form must be completed per DCN 2-2 Incident Reporting and Investigation Program. The report should be accompanied by photographs clearly showing the marking(s), and the actual location, with a distance gauge to document how far off the mark the utility was encountered.
5.2.3.2 Contacting Underground Utilities
If excavation or other equipment being used for intrusive activities makes contact with an underground utility, the following guidelines apply:
Intrusive activities must be stopped immediately.
Observe the utility from a safe distance and determine if there is damage. Damage would be all breaks, leaks, nicks, dents, gouges, grooves, scratched coatings, cathodic protection compromise, material leakage, obvious electrical energy. Move all personnel to the evacuation meeting point as described in the SSHP.
EXCEPTION: If an electrical line has been contacted and it is your belief that equipment (such as an excavator) is electrically energized, do not approach the equipment. Order the operator to remain in the equipment until emergency personnel can de-energize the source (unless the equipment is on fire, at which time the operator should jump off of the vehicle and shuffle along the ground to a safe area). Shuffling is required because current flows outward through the soil in a ripple pattern called a power gradient, creating a pattern of high and low potential, Shuffling decreases the chance that these gradients could be bridged, causing current to flow through the body, resulting in electrocution.
Secure the area to prevent the public from entering.
Contact emergency responders as specified in the SSHP. The One-Call agency or if known, the utility owner must be contacted immediately. ~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
UNDERGROUND UTILITIES
Revision Date: 10/01/2011
Document Control Number:
SWP 5-35
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet. The PM and SSC must be notified.
No further intrusive activities may be conducted until:
The utility owner inspects the scene and after repairs, verifies that all danger has passed. The orientation and depth of the subject utility has been determined and suitably marked. Permission from the emergency responders to resume work has been given.
A Tetra Tech Incident Report and Investigation form must be completed per DCN 2-2. The report should be accompanied by photographs clearly showing the marking(s), and the actual location, with a distance gauge to document how far off the mark the utility was encountered.
State and Local regulations must be reviewed to determine if reporting to any additional agencies is required.
5.3 Training
Competent Persons shall have adequate experience and/or training to carry out the requirements of this procedure.
6.0 SOURCES OF INFORMATION
6.1 Organizations
Common Ground Alliance
Center for Subsurface Strategic Action (CSSA)
DigSafely
National Utility Contractors Association (NUCA)
National Utility Locating Contractors Association (NULCA) Underground Focus Magazine
~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
UNDERGROUND UTILITIES
Revision Date: 10/01/2011
Document Control Number:
SWP 5-35
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet. NUCA State Listing of One-Call centers
Utility Safety Magazine
6.2 Vendors and Commercial Sites
RadioDetection, Inc. (Detection Instruments)
Heath Consultants (Detection Instruments)
Ben Meadows Company (Detection Instruments)
So-Deep, Inc. (Complete Utilities Services)
Concept Engineering Group, Inc. (Air Excavation Equipment) Rycom Instruments, Inc. (Detection Instruments)
Schonstedt Instrument Company (Detection Instruments) Forestry Suppliers, Inc. (Fiberglass Probe – “Fiberglass Tile Probe”, Part #77543, Approx. $20.00, Telephone 800-647-5368)
7.0 REFERENCES
Common Ground Study of One-Call Systems and Damage Prevention Best Practices, August, 1999, Sponsored by US DOT.
~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
UNDERGROUND UTILITIES
Revision Date: 10/01/2011
Document Control Number:
SWP 5-35
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet.
Revision Date
Document Authorizer
Name Revision Details
10/01/2011
Chris McClain
Update
~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
SPILL PREVENTION AND CLEANUP
Revision Date: 01/31/2013
Document Control
Number:
SWP 5-47
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet.
1.0 PURPOSE
Tt employees involved in remediation of spills or hazardous waste releases may be required to handle containers of hazardous waste. Services performed at hazardous and non-hazardous waste sites may also necessitate handling materials such as gasoline and oil for equipment operation, and chemicals for preservation of samples brought onto a site. Tt facilities may also maintain chemicals on-site in the construction materials engineering (CME) and analytical laboratories. These scenarios present the primary potential for spills or container leaks.
This safe work practice (SWP) addresses general guidance for spill prevention and cleanup.
Specific guidance for spill response can also be found in site-specific health and safety plans developed for hazardous waste sites, work plans for non-hazardous waste sites, the chemical hygiene plan, and the facility emergency response plan. Spill and discharge control practices should follow specific procedures to ensure the safety of responders and bystanders and to limit environmental impacts.
2.0 SPILL PREVENTION
The best spill response approach is to prevent spills from occurring. In order to achieve this, the following practices should be employed at Tt facilities and client job sites. Make sure that all containers are appropriately labeled and that material safety data sheets (MSDS) are available. Before handling operating and analysis materials or hazardous waste, appropriate precautions should be in place to prevent spills and exposure to individuals.
Store chemicals in appropriate locations. Make sure that incompatible chemicals are not stored in the same area. Refer to Appendix A for a general listing of incompatible chemicals.
When transporting chemicals, ensure that the containers are properly closed, secured, and labeled. Do not carry more than one container at one time. If this is required, place containers within totes.
Only keep the necessary quantity of each chemical on hand. For ease of use, keep chemicals in working containers that are appropriately sized for handling. ~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
SPILL PREVENTION AND CLEANUP
Revision Date: 01/31/2013
Document Control
Number:
SWP 5-47
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet. Ensure that chemicals that are no longer needed and expended chemical containers are disposed of according to regulations pertaining to the specific material.
3.0 GENERAL SPILL RESPONSE PROTOCOLS
In the event that a spill does occur, the following general steps should be followed:
The first concern should be for human health and safety. Tend to injuries immediately, evacuate the area if necessary, and alert appropriate response personnel.
If the material is flammable or combustible, an attempt should be made to remove all sources of heat or ignition. However, this does NOT mean unplugging machinery; doing so may cause sparks.
Consult the MSDS before spill cleanup activities to determine the proper PPE and cleanup equipment to be utilized.
If the material is still spilling or leaking, attempt to stop additional spillage and contain the area to prevent spread of the contamination. Cleanup should be conducted according to the proper techniques described in the MSDS, site-specific health and safety plan, and/or emergency response plan. Cleanup should only be attempted by properly trained personnel wearing appropriate PPE.
All waste should be disposed of according to applicable regulations. IF THE SPILL IS TOO LARGE – CALL IN APPROPRIATE RESPONSE PERSONNEL. DO NOT ATTEMPT TO MANAGE THE SPILL YOURSELF.
~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
SPILL PREVENTION AND CLEANUP
Revision Date: 01/31/2013
Document Control
Number:
SWP 5-47
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet.
4.0 DETAILED SPILL RESPONSE PROTOCOLS
This section provides more detailed steps to follow in the event of a spill or leak.
4.1 Immediate Actions
In the event of a spill, employees should immediately:
Check for injured personnel.
Clear the affected area.
Contain the spill and isolate it, if it is safe to do so. Contact the facility manager, project manager (PM) or site safety coordinator (SSC).
Immediate action should be taken to control and contain any spill following the general guidelines below:
Unnecessary personnel should be kept away from the spill or discharge. The hazardous area should be isolated.
If the spill or discharge creates a hazardous situation or results in injury or an environmental release, the emergency procedures of the HASP should be implemented. Emergency response telephone numbers, designated contacts, and special reporting procedures are presented in the HASP. Personnel should stay on the upwind side of the spill or discharge. Entry into a confined space or low area where liquids or vapors may accumulate should be avoided.
~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
SPILL PREVENTION AND CLEANUP
Revision Date: 01/31/2013
Document Control
Number:
SWP 5-47
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet. Sources of ignition should be eliminated if the spill or discharge involves combustible materials.
Drains, manholes, waterways, sewers, and the like should be identified and covered or protected.
The spill should be controlled or absorbed using appropriate media or devices. When the spill or discharge is fully contained and under control, spill or discharge material should be collected.
Following cleanup, the spill area should be evaluated by collecting soil samples and screening the area with air monitoring instruments.
4.2 Decontamination of Personnel
If an individual is contaminated while handling or transporting hazardous materials, emergency response personnel must be notified and a spill team activated. The individual must also be decontaminated and receive medical attention. If decontamination procedures would cause further injury, decontamination should not be performed. Instead, use a blanket or other material to contain the contamination during transport, and inform emergency response personnel that the victim has not been decontaminated.
4.3 Risk Assessment
The risk assessment is based upon the hazards posed by the chemicals, the quantity of materials involved, and the location of the spill. A spill response leader should be designated if the spill warrants activation of a spill team (i.e., when a person is injured or contaminated, or a spill is beyond the control of the individual or site personnel). He/she is responsible for all aspects of the response until relieved by a qualified replacement. The spill response leader should determine the level of risk by answering the following questions:
~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
SPILL PREVENTION AND CLEANUP
Revision Date: 01/31/2013
Document Control
Number:
SWP 5-47
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet.
4.3.1 What chemical is involved?
This may be determined by interviewing the person(s) who reported the spill and reviewing associated MSDS. Use knowledge of the work area and visual inspection to make a preliminary identification. This will be verified by direct inspection by the entry team.
4.3.2 How much has spilled?
Information gained when answering the question above should determine the quantity involved.
For a continuing leak, attempt to estimate the leak rate. If the quantity cannot be determined, you must assume release of the complete contents of the container.
4.3.3 Where is the incident located?
Take into account the relative area as well as the physical location. For example, determine where the spill is located relative to drains, water bodies, and other potential receptors.
4.4 Development of Spill Cleanup Plan
The spill response leader should develop a spill cleanup plan that includes the following elements:
Ensure that safety is the number one priority and that all safety issues are addressed prior to beginning spill cleanup.
Ensure that communication links between the spill response leader, members of the spill response team and emergency response personnel are in place. Determine if the risk level associated with the spill allows for internal personnel to conduct the cleanup or if emergency response personnel should be summoned. Determine the number of workers needed to safely and effectively perform the cleanup.
~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
SPILL PREVENTION AND CLEANUP
Revision Date: 01/31/2013
Document Control
Number:
SWP 5-47
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet. Identify spill response materials and ensure that materials are adequate for the anticipated spills.
Assign cleanup duties and responsibilities to the spill response team members. Inform the appropriate facility manager, project manager, and client contacts. Determine the required PPE to be worn by entry and backup spill team members and ensure that it is worn during the activities. Use the site health and safety plan contingency section or the facility emergency response plan to assist in this activity. Typical protective equipment may be Level C or D. In the event that the spill warrants a higher level of protection, Tt personnel should summon emergency response personnel.
If the spill or discharge material is solid and nonreactive, the material should be scooped up and placed in a suitable and compatible container until the disposal method has been determined.
If liquid is discharged, the following general procedures apply:
- The point of discharge should be immediately identified and measures taken to eliminate further discharges by uprighting or patching containers, transferring contents, or other appropriate methods.
- Any discharged liquids or sludge should be removed or retrieved. - Discharged materials should be cleaned up with absorbent materials or devices.
- Spent absorbent material should be placed into storage or disposal containers. Determine proper equipment and spill control media to be used based on the chemical of concern. Typical equipment needed to accomplish spill cleanup may include:
~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
SPILL PREVENTION AND CLEANUP
Revision Date: 01/31/2013
Document Control
Number:
SWP 5-47
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet. Seal/plug material
Absorption socks and booms
Broom
Shovel
Open head 55-gallon drum with liner
85-gallon salvage drum
Control the area so that unnecessary personnel do not enter and situations that may escalate the hazards in the area are eliminated. Ideally, the exclusion zone should be physically barricaded off. At a minimum, barricade tape can be placed. An exclusion zone, contamination reduction zone, and a support zone may be needed. Only authorized personnel will be allowed in these areas. Wind direction, plant and surrounding populations, and the properties of the spilled material must be considered in establishing the initial controlled zone. Exclusion zones should be barricaded (or at least taped off with barricade tape) to prevent general public access. The zone can be expanded or contracted as more information is gathered about the spill.
Determine if the situation requires monitoring of explosive atmosphere, oxygen deficiency, or toxic levels of chemicals. This will also help determine the level of PPE required and conditions that would require the area to be evacuated and emergency response personnel summoned.
4.5 Implementation Spill Cleanup Plan
After the spill response leader has developed a plan to containerize and remove all material contaminated by the spill, the assigned members of the spill team will complete the following steps.
~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
SPILL PREVENTION AND CLEANUP
Revision Date: 01/31/2013
Document Control
Number:
SWP 5-47
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet.
4.5.1 Cleanup, containerize, and decontaminate the area Attempt to control the source of the leak if the full contents of a drum or container have not spilled. Perhaps the simplest procedure is to position the drum or container so that the leak is above the liquid level. Alternatively, a drum patch or plug can be applied to the leak. The leaking chemical may also be controlled using absorbent spill berms positioned around the drum or container. Contain free-flowing liquids by diking or absorbing.
Place all spill residues and cleanup equipment in an appropriate container. If solvent is used to decontaminate equipment, floors, or walkways, appropriate fire protection should be used.
Decontaminate and salvage as much equipment as possible. Use only a final water wash where it is safe and appropriate to do so.
4.5.2 Analyze the affected area for proper decontamination safety Use monitoring and detection equipment, if needed.
Check equipment for problems.
Examine walkways, floors, and stairs for obstructions or hazards (i.e. slip/fall exposure from liquid residue).
Use any resources needed (safety, industrial hygiene, environmental, etc.) to ensure that the area has been decontaminated and is safe to re-enter.
4.5.3 Secure all response equipment
Restock spill supplies.
~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
SPILL PREVENTION AND CLEANUP
Revision Date: 01/31/2013
Document Control
Number:
SWP 5-47
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet. Repair damaged equipment.
4.5.4 Release site resumption of operations
Notify operating personnel.
Document spill or release in on-site or facility log.
As soon as the area is safe for reoccupancy, the spill response leader, in conjunction with the site or facility manager, must initiate actions to allow the facility to resume normal operations. Use established procedures to announce an “All Clear.” Properly mark spill residue containers for hazardous waste management. Clean and prepare all emergency response materials for immediate use storage. Complete all spill response reports as required.
5.0 FINAL TERMINATION OF THE INCIDENT
The project manager (PM) and site safety coordinator (SSC) should conduct a formal review and debriefing of the responders at the conclusion of the project. Corrective actions may need to be implemented if a cause for the spill was determined and can be prevented from happening again.
Final termination of the incident will be complete when the appropriate personnel review all reports and any corrective actions are completed.
6.0 REPORTING
In some instances, a release may require reporting to government agencies. If a reportable quantity is released (this quantity is stated on the Material Safety Data Sheet) or human health or the environment is threatened, appropriate national, state, and local administering agency personnel should be notified. The timeframe for notification may vary from agency to agency. ~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
SPILL PREVENTION AND CLEANUP
Revision Date: 01/31/2013
Document Control
Number:
SWP 5-47
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet.
Notification may be required immediately or within 24 hours, depending on the type, location, and amount of released material. The appropriate agency to report spills to should be determined during HASP development.
All spills and chemical releases must be reported and investigated in accordance with Tt Program 2.1 Incident Reporting and Investigation. Details must be documented on the Forms IR and IR–B and entered into the Tetra Tech TOTAL system for appropriate incident review and tracking.
INCOMPATIBLE CHEMICALS
When certain hazardous chemicals are stored or mixed together, violent reactions may occur because the chemicals are incompatible (i.e., unsuitable for mixing). Classes of incompatible chemicals should be segregated according to hazard class during storage. Use the following general guidelines for hazard class storage.
Flammable/combustible liquids and organic acids
Flammable solids
Mineral acids
Caustics
Oxidizers
Perchloric acid
Compressed gases
Separate hazardous chemicals in storage as follows:
Oxidizing acids are segregated from organic acids, and flammable and combustible materials.
~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
SPILL PREVENTION AND CLEANUP
Revision Date: 01/31/2013
Document Control
Number:
SWP 5-47
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet. Acids are separated from inorganic bases.
Acids are separated from active metals such as sodium, potassium, and magnesium.
Acids are separated from chemicals that could generate toxic gases upon contact, such as iron sulfide and sodium cyanide.
Water-reactive chemicals such as calcium oxide are stored in a cool, dry place away from any potential water source.
Oxidizers are physically segregated from flammable and combustible chemicals or materials.
Oxidizers are physically segregated from reducing agents such as zinc, alkaline metals, and formic acid.
Large bottles of corrosives are stored on a low shelf or in specially designed (i.e., UL listed) cabinets. Single-glass bottles of acids and corrosives can also be placed within buckets or other means for both safe handling and as a means of secondary containment in the event of breakage.
Carefully read the label before storing any chemical substance. Use the materials safety data sheets (MSDS) to find special storage information and information on incompatibilities. If you have questions regarding proper storage of chemicals or if a container is not clearly labeled, contact a qualified individual for additional information.
Before mixing, storing, or transporting any chemicals, refer to the following partial list of incompatible chemicals, the chemicals’ MSDS, or other reliable reference for further information or to verify compatibility.
List of Incompatible Chemicals
Chemical Incompatible Chemical(s)
Acetic Acid Aldehyde, bases, carbonates, hydroxides, metals, oxidizers, peroxides, ~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
SPILL PREVENTION AND CLEANUP
Revision Date: 01/31/2013
Document Control
Number:
SWP 5-47
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet.
Chemical Incompatible Chemical(s)
phosphates, xylene
Acetylene Halogens (chlorine, fluorine, etc.), mercury, potassium, oxidizers, silver Acetone Acids, amines, oxidizers, plastics
Alkali and alkaline earth
metals
Acids, chromium, ethylene, halogens, hydrogen, mercury, nitrogen, oxidizers, plastics, sodium chloride, sulfur
Ammonia Acids, aldehydes, amides, halogens, heavy metals, oxidizers, plastics, sulfur
Ammonium nitrate Acids, alkalis, chloride salts, combustible materials, metals, organic materials, phosphorous, reducing agents, urea
Aniline Acids, aluminum, dibenzoyl peroxide, oxidizers, plastics Azides Acids, heavy metals, oxidizers
Bromine
Acetaldehyde, alcohols, alkalis, amines, combustible materials, ethylene, fluorine, hydrogen, ketones (acetone, carbonyls, etc.), metals, sulfur
Calcium oxide Acids, ethanol, fluorine, organic materials Carbon (activated) Alkali metals, calcium hypochlorite, halogens, oxidizers Carbon tetrachloride Benzoyl peroxide, ethylene, fluorine, metals, oxygen, plastics, silanes Chlorates Powdered metals, sulfur, finely divided organic or combustible materials Chromic acid Acetone, alcohols, alkalis, ammonia, bases Chromium trioxide Benzene, combustible materials, hydrocarbons, metals, organic materials, phosphorous, plastics
Chlorine
Alcohols, ammonia, benzene, combustible materials, flammable compounds (hydrazine), hydrocarbons (acetylene, ethylene, etc.), hydrogen peroxide, iodine, metals, nitrogen, oxygen, sodium hydroxide Chlorine dioxide Hydrogen, mercury, organic materials, phosphorous, potassium hydroxide, sulfur
Copper Calcium, hydrocarbons, oxidizers
Hydroperoxide Reducing agents
Cyanides Acids, alkaloids, aluminum, iodine, oxidizers, strong bases Flammable liquids Ammonium nitrate, chromic acid, hydrogen peroxide, nitric acid, sodium peroxide, halogens
Fluorine Alcohols, aldehydes, ammonia, combustible materials, halocarbons, halogens, hydrocarbons, ketones, metals, organic acids
Hydrocarbons (e.g. butane,
propane benzene,
turpentine, etc.)
Acids, bases, oxidizers, plastics
Hydrofluoric acid Metals, organic materials, plastics, silica (glass), (anhydrous) sodium Hydrogen peroxide Acetylaldehyde, acetic acid, acetone, alcohol’s carboxylic acid, ~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
SPILL PREVENTION AND CLEANUP
Revision Date: 01/31/2013
Document Control
Number:
SWP 5-47
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet.
Chemical Incompatible Chemical(s)
combustible materials, metals, nitric acid, organic compounds, phosphorous, sulfuric acid, sodium, aniline
Hydrogen sulfide Acetylaldehyde, metals, oxidizers, sodium Hypochlorites Acids, activated carbon
Iodine Acetylaldehyde, acetylene, ammonia, metals, sodium Mercury Acetylene, aluminum, amines, ammonia, calcium, fulminic acid, lithium, oxidizers, sodium
Nitrates Acids, nitrites, metals, sulfur, sulfuric acid Nitric acid
Acetic acid, acetonitrile, alcohol’s, amines, (concentrated) ammonia, aniline, bases, benzene, cumene, formic acid, ketones, metals, organic materials, plastics, sodium, toluene
Oxalic acid Oxidizers, silver, sodium chlorite
Oxygen
Acetaldehyde, secondary alcohol’s, alkalis and alkalines, ammonia, carbon monoxide, combustible materials, ethers, flammable materials, hydrocarbons, metals, phosphorous, polymers
Perchloric acid
Acetic acid, alcohols, aniline, combustible materials, dehydrating agents, ethylbenzene, hydriotic acid, hydrochloric acid, iodides, ketones, organic material, oxidizers, pyridine
Peroxides, organic Acids (organic or mineral)
Phosphorous (white) Oxygen (pure and in air), alkalis
Potassium Acetylene, acids, alcohols, halogens, hydrazine, mercury, oxidizers, selenium, sulfur
Potassium chlorate Acids, ammonia, combustible materials, fluorine, hydrocarbons, metals, organic materials, sugars
Potassium perchlorate (also
see chlorates)
Alcohols, combustible materials, fluorine, hydrazine, metals, organic matter, reducing agents, sulfuric acid
Potassium permanganate Benzaldehyde, ethylene glycol, glycerol, sulfuric acid Silver acetylene, ammonia, oxidizers, ozonides, peroxyformic acid Sodium Acids, hydrazine, metals, oxidizers, water
Sodium nitrate Acetic anhydride, acids, metals, organic matter, peroxyformic acid, reducing agents
Sodium peroxide Acetic acid, benzene, hydrogen sulfide metals, oxidizers, peroxyformic acid, phosphorous, reducers, sugars, water
Sulfides Acids
Sulfuric acid Potassium chlorates, potassium perchlorate, potassium permanganate ~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
SPILL PREVENTION AND CLEANUP
Revision Date: 01/31/2013
Document Control
Number:
SWP 5-47
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet.
Revision Date
Document Authorizer
Revision Details
Name
01/31/2013 Chris McClain New
~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
HAND TOOLS
Revision Date: 01/31/2013
Document Control Number:
SWP-5-51
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet.
1.0 INTRODUCTION
Hand tools are used routinely in many Tetra Tech Operations. In order to prevent accidents associated with their use, our employees must be aware of the dangers associated with the different types of tools and the safety precautions necessary to prevent accidents. The following safe work practices must be followed when using hand tools.
2.0 GENERAL SAFETY RULES
All tools, regardless of ownership, shall be of an approved type and maintained in good and safe condition. Tools not meeting the requirements detailed in this safe work practice are prohibited. Tools are subject to inspection at any time. The supervisor has the authority and responsibility to condemn unserviceable tools, regardless of ownership.
Defective tools shall be tagged to prevent their use and shall be removed from the job site. Employees shall always use the proper tool for the job performed. Hammers with metal handles, screwdrivers, knives with metal continuing through the handle and metallic measuring tapes shall not be used on or near energized electrical circuits or equipment. Tools shall not be thrown from place to place or from person to person; tools that must be raised or lowered from one elevation to another shall be placed in tool buckets or firmly attached to hand lines.
Tools shall never be placed unsecured on elevated places. Employees using hand and power tools and exposed to the hazard of falling, flying, abrasive, and splashing objects, or exposed to harmful dust, fumes, mists vapors, or gases shall be provided with the designated PPE necessary to project them from the hazard. The designated PPE should be determined on a case by case basis.
3.0 HAND TOOLS
All impact tools such as chisels, punches, drift pins, etc., that become mushroomed or cracked shall be dressed, repaired, or replaced before further use. Chisels, drills, punches, ground rods, and pipes shall be held with suitable holders or tongs (not with the hands) while being struck by another employee. Shims shall not be used to make a wrench fit.
Wrenches with sprung or damaged jaws shall not be used. Pipe shall not be used to extend a wrench handle for added leverage unless the wrench was designed for such use.
Tools shall be used only for the purposes for which they have been approved. Tools with sharp edges shall be stored and handled so that they will not cause injury or damage.
They shall not be carried in pockets.
~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
HAND TOOLS
Revision Date: 01/31/2013
Document Control Number:
SWP-5-51
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet. Wooden handles that are loose, cracked, or splintered shall be replaced. The handle shall not be taped or lashed with wire.
All cutting tools such as saws, wood chisels, drawknives, or axes shall be kept in suitable guards or in special compartments.
Tools shall not be left lying around where they may cause a person to trip or stumble. When working on or above open grating, a canvas or other suitable covering shall be used to cover the grating to prevent tools or parts from dropping to a lower level where others are present or the danger area shall be barricaded or guarded.
The insulation on hand tools shall not be depended upon to protect users from shock.
4.0 PORTABLE ELECTRIC TOOLS
The non-current carrying metal parts of portable electric tools such as drills, saws, and grinders shall be effectively grounded when connected to a power source unless the tool is an approved double-insulated type and the tool is connected to the power supply by means of an isolating transformer or other isolated power supply, such as a 24-volt DC system. All powered tools shall be examined prior to use to ensure general serviceability and the presence of all applicable safety devices. The electric cord and electric components shall be given an especially thorough examination.
Powered tools shall be used only within their capability and shall be operated in accordance with the instructions of the manufacturer.
All tools shall be kept in good repair and shall be disconnected from the power source while repairs are being made.
Electrical tools shall not be used where there is a hazard of flammable vapors, gases, or dusts. All power tools and cord sets shall be protected by ground fault circuit interrupters (GFCI). When using any power source, ensure that GFCI is functional. Otherwise, external GFCI must be used.
5.0 PNEUMATIC TOOLS
Compressed air and compressed air tools shall be used with caution. Pneumatic tools shall never be pointed at another person. Pneumatic power tools shall be secured to the hose or whip by some positive means to prevent the tool from becoming accidentally disconnected.
Safety clips or retainers shall be securely installed and maintained on pneumatic impact (percussion) tools to prevent attachments from being accidentally expelled. Compressed air shall not be used for cleaning purposes except when reduced to less than 30 psi and then only with effective chip guarding and personal protective equipment. ~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
HAND TOOLS
Revision Date: 01/31/2013
Document Control Number:
SWP-5-51
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet. Compressed air shall not be used to blow dust or dirt from clothing. The manufacturer’s safe operating pressure for hoses, pipes, valves, filters, and other fittings shall not be exceeded.
The use of hoses for hoisting or lowering tools shall not be permitted. All hoses exceeding ½ inch inside diameter shall have a safety device at the source of supply or branch fine to reduce pressure in case of hose failure or disengagement of a connection. Before making adjustments or changing air tools, unless equipped with quick change connectors, the air shall be shut off at the air supply valve ahead of the hose. The hose shall be bled at the tool before breaking the connection.
Eye, foot and hearing protection devices shall be worn during pneumatic tool use. Pneumatic tools shall be operated only by competent persons who have been trained in their use. A pneumatic tool used where it may contact exposed live electrical parts shall have a nonconductive hose and an accumulator to collect moisture. Employees shall not use any part of their bodies to locate or attempt to stop an air leak.
6.0 POWDER ACTUATED TOOLS
A powder actuated tool must always be treated the same as a loaded firearm. ALWAYS ASSUME THE TOOL IS LOADED. These tools come in both low and high velocity models, and both should have built-in safeguards; however, extreme caution must be used when working with this tool. Powder actuated tools can be used only by employees who have been trained in their operation. The user must have a current operator’s card.
The following checklist, which may not be complete for all scenarios, is required at a minimum before each use of a powder actuated tool. (Project Managers are responsible for identifying other site specific requirements.)
Check the safety for proper operation and make sure the bore is clear. Select the proper cartridge for the job to be done; never use a higher charge than is necessary. Make sure that the drive part of the tool will not penetrate the mounting surface and fly out the other side. The work area must be backed up by a plank or beam. Do not use this tool on hard steel, cast iron, rock, or other extremely hard materials. Make sure no one else is in the immediate area; concrete chips, metal spalls or rebounding studs could injure bystanders. Insure protective shield is in place to confine flying fragments or particles when the tool is fired.
Make sure the tool is at the correct angle to the work surface, and maintain pressure against the surface.
Always wear proper eye and hearing protection.
~
ITEM 11.1. ATTACHMENT 3
TETRA TECH, INC.
HAND TOOLS
Revision Date: 01/31/2013
Document Control Number:
SWP-5-51
The online version of this document supersedes all other versions. Paper copies of this document are uncontrolled. The controlled version of this document can be found on the Tetra Tech Intranet. Do not use in an explosive or flammable atmosphere.
Never point the tool at anyone.
Do not load until ready for use and never leave a loaded tool unattended. If the tool develops a defect during use, it should be tagged and removed from service until it is properly repaired.
7.0 GUARDS
Hazardous moving parts - belts, gears, shafts, pulleys or other reciprocating, rotating or moving parts of equipment must be guarded if such parts are exposed. Guards must be provided as necessary to protect the operator and others from point of operation hazards, in-running nip point hazards, rotating parts, flying chips, and sparks etc. All guards shall meet the requirements set forth by ANSI.
SAFETY GUARDS SHALL NEVER BE REMOVED OR TAMPERED WITH
Revision Date
Document Authorizer
Revision Details
Name
1/31/2013 Chris McClain Update
~
ITEM 11.1. ATTACHMENT 3
HEALTH AND SAFETY PLAN
Vacant Site (future Civic Center), 117-9040001
APPENDIX C
SAFETY DATA SHEETS AND CHEMICAL INVENTORY
111: I TETRA TECH
ITEM 11.1. ATTACHMENT 3
Chemical Inventory Listing:
Liquinox
Alconox
Hydrochloric acid (Preservative)
Isobutylene calibration gas
Fire extinguisher
Diesel Fuel
Gasoline
Automotive grease
Chemical Oxidant (RemOX-S ISCO Reagent)
ITEM 11.1. ATTACHMENT 3
Safety Data Sheet
Effective date: 11 May 2020 Revision : 11 May 2020
Trade Name: Liquinox®
F7303 | SDS12E.0 | Created by Alconox Inc. | (914) 948-4040 | www.alconox.com
1.1 GHS Product identifier
Trade Name: Liquinox®
Product number: 1201, 1201-1, 1205, 1215, 1230, 1232, 1232-1, 1255
1.2 Application of the substance / the mixture: Cleaning material/Detergent
1.2.1 Recommended dilution ratio: 1 - 2% in water
1.3 Details of the supplier of the Safety Data Sheet
Manufacturer:
Alconox Inc.
30 Glenn St
White Plains, NY 10603
(914) 948-4040
Supplier:
Emergency telephone number:
ChemTel Inc
North America: 1-888-255-3924
International: +1 813-248-0573
2.1 Classification of the substance or mixture:
In compliance with EC regulation No. 1272, 29CFR1910/1200 and GHS requirements.
Hazard-determining components of labeling:
Alcohol ethoxylate
Sodium alkylbenzene sulfonate
Sodium xylenesulphonate
Lauramine oxide
2.2 Label elements:
Eye damage, category 1.
Skin irritation, category 2.
Product at recommended dilution:
Eye irritation, category 2B
Hazard pictograms:
Signal word: Danger
Hazard statements:
H315 Causes skin irritation.
H318 Causes serious eye damage.
Precautionary statements:
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection. 1 Identification of the substance/mixture and of the supplier 2 Hazards identification
ITEM 11.1. ATTACHMENT 3
Safety Data Sheet
Effective date: 11 May 2020 Revision : 11 May 2020
Trade Name: Liquinox®
F7303 | SDS12E.0 | Created by Alconox Inc. | (914) 948-4040 | www.alconox.com P302+P352 If on skin: Wash with soap and water.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P501 Dispose of contents and container as instructed in Section 13.
Hazardous Elements at Use Dilution:
Hazard pictograms:
Signal word: Warning
Hazard statements:
H320 Causes eye irritation
Precautionary statements:
P302+P352 If on skin: Wash with soap and water.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.
P501 Dispose of contents and container as instructed in Section 13 Additional information: None.
Hazard description
Hazards Not Otherwise Classified (HNOC): May cause surfaces to become slippery. Use caution in areas of foot traffic if on floors.
Information concerning particular hazards for humans and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version.
Classification system:
The classification is according to EC regulation No. 1272, 29CFR1910/1200 and GHS, and extended by company and literature data. The classification is in accordance with the latest editions of international substances lists and is supplemented by information from technical literature and by information provided by the company.
3.1 Chemical characterization: None
3.2 Description: None
3.3 Hazardous components (percentages by weight)
Identification Chemical Name Classification Wt. %
CAS number:
68081-81-2 or
68411-30-3
Sodium Alkylbenzene Sulfonate Acute Tox. 4; H303
Skin Irrit. 2 ; H315
Eye Dam. 1; H318
10-25
CAS number:
1300-72-7
Sodium Xylenesulphonate Eye Irrit. 2;H319 2.5-10
CAS number:
84133-50-6
Alcohol Ethoxylate Skin Irrit. 2 ; H315
Eye Dam. 1; H318
2.5-10
CAS number:
1643-20-5
Lauramine oxide Skin Irrit. 2 ; H315
Eye Dam. 1; H318
1-2
3 Composition/information on ingredients
ITEM 11.1. ATTACHMENT 3
Safety Data Sheet
Effective date: 11 May 2020 Revision : 11 May 2020
Trade Name: Liquinox®
F7303 | SDS12E.0 | Created by Alconox Inc. | (914) 948-4040 | www.alconox.com At use dilution:
CAS number:
68081-81-2 or
68411-30-3
Sodium Alkylbenzene Sulfonate Eye Irr. 2B; H319 0.1-0.25
3.4 Additional Information: None.
4.1 Description of first aid measures
General information: None.
After inhalation:
Maintain an unobstructed airway.
Loosen clothing as necessary and position individual in a comfortable position.
After skin contact:
Wash affected area with soap and water.
Seek medical attention if symptoms develop or persist.
After eye contact:
Rinse/flush exposed eye(s) gently using water for 15-20 minutes.
Remove contact lens(es) if able to do so during rinsing.
Seek medical attention if irritation persists or if concerned.
After swallowing:
Rinse mouth thoroughly.
Seek medical attention if irritation, discomfort, or vomiting persists.
4.2 Most important symptoms and effects, both acute and delayed None
4.3 Indication of any immediate medical attention and special treatment needed:
No additional information.
First aid measure at recommended dilution:
General information: None.
After inhalation:
Maintain an unobstructed airway.
Loosen clothing as necessary and position individual in a comfortable position.
After skin contact:
Wash affected area with soap and water.
After eye contact:
Rinse/flush exposed eye(s) gently using water for 15-20 minutes.
Remove contact lens(es) if able to do so during rinsing.
After swallowing:
Rinse mouth thoroughly. Seek medical attention if irritation, discomfort, or vomiting develops.
4 First aidmeasures
I I I I
ITEM 11.1. ATTACHMENT 3
Safety Data Sheet
Effective date: 11 May 2020 Revision : 11 May 2020
Trade Name: Liquinox®
F7303 | SDS12E.0 | Created by Alconox Inc. | (914) 948-4040 | www.alconox.com
5.1 Extinguishing media
Suitable extinguishing agents:
Use appropriate fire suppression agents for adjacent combustible materials or sources of ignition.
For safety reasons unsuitable extinguishing agents: None
5.2 Special hazards arising from the substance or mixture:
Thermal decomposition can lead to release of irritating gases and vapors.
5.3 Advice for firefighters
Protective equipment:
Wear protective eye wear, gloves and clothing.
Refer to Section 8.
5.4 Additional information:
Avoid inhaling gases, fumes, dust, mist, vapor and aerosols.
Avoid contact with skin, eyes and clothing.
6.1 Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation.
Ensure air handling systems are operational.
6.2 Environmental precautions:
Should not be released into the environment.
Prevent from reaching drains, sewer or waterway.
6.3 Methods and material for containment and cleaning up:
Wear protectiveeyewear, glovesand clothing.
6.4 Reference to other sections: None
7.1 Precautions for safe handling:
Avoidbreathing mistor vapor.
Do not eat, drink, smoke or use personal products when handling chemical substances.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool,well-ventilatedarea.
7.3 Specific end use(s):
No additional information.
8.1 Control parameters :
25322-68-3, Poly(ethylene oxide), AIHA TWA 10 mg/m3 (<0.15% present in concentrate) 5 Firefighting measures
6 Accidental release measures
7 Handling andstorage
8 Exposure controls/personal protection
•
ITEM 11.1. ATTACHMENT 3
Safety Data Sheet
Effective date: 11 May 2020 Revision : 11 May 2020
Trade Name: Liquinox®
F7303 | SDS12E.0 | Created by Alconox Inc. | (914) 948-4040 | www.alconox.com
8.2 Exposure controls
Appropriate engineering controls:
Emergency eye wash fountains and safety showers should be available in the immediate vicinity of use or handling.
Respiratory protection:
Not needed under normal conditions.
Protection of skin:
Select glove material impermeable and resistant to the substance.
Eye protection:
Safety goggles or glasses, or appropriate eye protection.
General hygienic measures:
Wash hands before breaks and at the end ofwork.
Avoid contact with skin, eyes and clothing.
Exposure Control and Personal Protective Equipment at recommended dilution:
Under normal use and operational conditions, no special personal protective equipment or engineering controls will be necessary. Handle with care.
Appearance
(physical state,
color):
Pale yellow liquid Explosion limit lower:
Explosion limit
upper:
Not determined or not
available.
Not determined or not
available.
Odor:
Not determined or not
available. Vapor pressure at 20°C:
Not determined or not
available.
Odor threshold:
Not determined or not
available. Vapor density:
Not determined or not
available.
pH-value: 8.5 (as is) Relative density:
Not determined or not
available.
Melting/Freezing point:
Not determined or not
available. Solubilities:
Not determined or not
available.
Boiling
point/Boiling range:
Not determined or not
available.
Partition coefficient (noctanol/water):
Not determined or not
available.
Flash point (closed
cup):
Not determined or not
available.
Auto/Self-ignition
temperature:
Not determined or not
available.
Evaporation rate:
Not determined or not
available.
Decomposition
temperature:
Not determined or not
available.
Flammability (solid,
gaseous):
Not flammable Viscosity:
a. Kinematic: Not
determined or not available.
b. Dynamic: Not determined
or not available.
Density at 20°C: 1.08 g/mL
9 Physical and chemical properties
ITEM 11.1. ATTACHMENT 3
Safety Data Sheet
Effective date: 11 May 2020 Revision : 11 May 2020
Trade Name: Liquinox®
F7303 | SDS12E.0 | Created by Alconox Inc. | (914) 948-4040 | www.alconox.com
10.1 Reactivity: Not determined or not available.
10.2 Chemical stability: Not determined or not available.
10.3 Possibility hazardous reactions: Not determined or not available.
10.4 Conditions to avoid: Not determined or not available.
10.5 Incompatible materials: Not determined or not available.
10.6 Hazardous decomposition products: Not determined or not available.
11.1 Information on toxicological effects:
Acute Toxicity:
Oral:
: LD50 >5000 mg per kg (Rat, Oral) - product.
Chronic Toxicity: No additional information.
Skin corrosion/irritation (raw materials):
Alcohol Ethoxylate: May cause mild to moderate skin irritation.
Sodium Alkylbenzene Sulfonate: Causes skin irritation.
Lauramine oxide: Causes skin irritation.
Serious eyedamage/irritation (raw materials):
Sodium Alkylbenzene Sulfonate: Causes serious eye damage.
Alcohol Ethoxylate: Causes moderate to severe eye irritation and conjunctivitis.
Sodium xylenesulphonate: irritating to eyes.
Lauramine oxide: Causes serious eye damage.
Product information at recommended dilution:
Eye irritation may occur upon direct contact with eyes. No specific hazards for skin contact, inhalation, or chronic exposure are expected within normal use parameters.
Respiratory or skin sensitization: No additional information.
Carcinogenicity: Noadditional information.
IARC (International Agency for Research on Cancer): None of the ingredients are listed.
NTP (National Toxicology Program): None of the ingredients are listed.
Germ cell mutagenicity: No additional information.
Reproductive toxicity: No additional information.
STOT-single and repeated exposure: No additional information.
Additional toxicological information: No additional information. 10 Stability and reactivity
11 Toxicological information
ITEM 11.1. ATTACHMENT 3
Safety Data Sheet
Effective date: 11 May 2020 Revision : 11 May 2020
Trade Name: Liquinox®
F7303 | SDS12E.0 | Created by Alconox Inc. | (914) 948-4040 | www.alconox.com
12.1 Toxicity:
Sodium Alkylbenzene Sulfonate: Fish, LC50 1.67 mg/l, 96 hours.
Sodium Alkylbenzene Sulfonate: Aquatic invertebrates, EC50 Daphnia 2.9 mg/l, 48 hours. Sodium Alkylbenzene Sulfonate: Aquatic Plants, EC50 Algae 29 mg/l, 96 hours.
Lauramine oxide: Fish, LC50 24.3 mg/l, 96h [Killifish (Cyprinodontidae)] Lauramine oxide: Aquatic invertebrates, (LC50): 3.6 mg/l 96 hours [Daphnia (Daphnia)].
Lauramine oxide: Aquatic plants, EC50 Algae 0.31 mg/l 72 hours [Algae] Alcohol Ethoxylate: Aquatic invertebrates, (LC50): 4.01 mg/l 48 hours [Daphnia (daphnia)].
12.2 Persistence and degradability: No additional information.
12.3 Bioaccumulative potential: No additional information.
12.4 Mobility in soil: No additional information.
General notes: No additional information.
12.5 Results of PBT and vPvB assessment:
PBT: No additional information.
vPvB: No additional information.
12.6 Other adverse effects: No additionalinformation.
13.1 Waste treatment methods (consult local, regional and national authorities for proper disposal) Relevant Information:
It is the responsibility of the waste generator to properly characterize all waste materials according to applicable regulatory entities. (US 40CFR262.11).
14.1 UN Number:
ADR, ADN, DOT, IMDG, IATA
None
14.2 UN Proper shipping name:
ADR, ADN, DOT, IMDG, IATA
None
14.3 Transport hazard classes:
ADR, ADN, DOT, IMDG, IATA
Class:
Label:
LTD.QTY:
None
None
None
US DOT
Limited Quantity Exception: None
12 Ecological information
13 Disposal considerations
14 Transport information
ITEM 11.1. ATTACHMENT 3
Safety Data Sheet
Effective date: 11 May 2020 Revision : 11 May 2020
Trade Name: Liquinox®
F7303 | SDS12E.0 | Created by Alconox Inc. | (914) 948-4040 | www.alconox.com Bulk:
RQ (if applicable): None
Proper shipping Name:
None Hazard Class: None
Packing Group: None
Marine Pollutant (if applicable): No
additional information.
Comments: None
Non Bulk:
RQ (if applicable): None
Proper shipping Name:
None Hazard Class: None
Packing Group: None
Marine Pollutant (if applicable): No
additional information.
Comments: None
14.4 Packing group:
ADR, ADN, DOT, IMDG, IATA
None
14.5 Environmental hazards: None
14.6 Special precautions foruser: None
Danger code (Kemler): None
EMS number: None
Segregation groups: None
14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable.
14.8 Transport/Additional information:
Transport category: None
Tunnel restriction code: None
UN "Model Regulation": None
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture.
North American
SARA
Section 313 (specific toxic chemical listings): None of the ingredients arelisted.
Section 302 (extremely hazardous substances): None of the ingredients arelisted.
CERCLA (Comprehensive Environmental Response, Clean up and Liability Act) Reportable Spill Quantity: None of the ingredients are listed.
TSCA (Toxic Substances Control Act):
Inventory: All ingredients are listed as active.
Rules and Orders: Not applicable.
Proposition 65 (California):
Chemicals known to cause cancer: None of the ingredients are listed.
Chemicals known to cause reproductive toxicity for females: None of the ingredients are listed.
Chemicals known to cause reproductive toxicity for males: None of the ingredients are listed.
Chemicals known to cause developmental toxicity: None of the ingredients are listed. 15Regulatoryinformation
Canadian
Canadian Domestic Substances List (DSL):
All ingredients are listed.
ITEM 11.1. ATTACHMENT 3
Safety Data Sheet
Effective date: 11 May 2020 Revision : 11 May 2020
Trade Name: Liquinox®
F7303 | SDS12E.0 | Created by Alconox Inc. | (914) 948-4040 | www.alconox.com Asia Pacific
EU
Abbreviations and Acronyms: None
Summary of Phrases
Hazard statements:
H315 Causes skin irritation.
H318 Causes serious eye damage.
Precautionary statements:
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 If on skin: Wash with soap and water.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P501 Dispose of contents and container as instructed in Section
13. Manufacturer Statement:
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
NFPA: 1-0-0
HMIS: 1-0-0
At recommended dilution:
NFPA: 1-0-0
HMIS: 1-0-0
Australia
Australian Inventory of Chemical Substances (AICS): All ingredients are listed.
China
Inventory of Existing Chemical Substances in China (IECSC): All ingredients are listed.
Japan
Inventory of Existing and New Chemical Substances (ENCS): All ingredients are listed.
Korea
Existing Chemicals List (ECL): All ingredients are listed.
New Zealand
New Zealand Inventory of Chemicals (NZOIC): All ingredients are listed.
Philippines
Philippine Inventory of Chemicals and Chemical Substances (PICCS): All ingredients are listed.
Taiwan
Taiwan Chemical Substance Inventory (TSCI): All ingredients are listed. 16 Other information
REACH Article 57 (SVHC): None of the ingredients are listed.
Germany MAK: Not classified.
ITEM 11.1. ATTACHMENT 3
MATERIAL SAFETY DATA SHEET - CALIBRATION CHECK GAS
1 ___________________________________________________________________________ PRODUCT NAME: ISOBUTYLENE (1 PPM – 0.9%) IN AIR
MSDS NO: 248 Version:3 Date: August, 2010
___________________________________________________________________________
1. Chemical Product and Company Identification
Gasco Affiliates, LLC
320 Scarlett Blvd.
Oldsmar, FL 34677
TELEPHONE NUMBER: (800) 910-0051 24-HOUR EMERGENCY NUMBER: 1-800-424-9300 FAX NUMBER: (866) 755-8920
E-MAIL: [email protected]
PRODUCT NAME: ISOBUTYLENE (1 PPM – 0.9%) IN AIR
CHEMICAL NAME: Isobutylene in air
COMMON NAMES/ SYNONYMS: None
TDG (Canada) CLASSIFICATION: 2.2
WHIMIS CLASSIFICATION: A
___________________________________________________________________________
2. COMPOSITION/ INFORMATION ON INGREDIENTS
INGREDIENT %VOLUME PEL-OSHA TLV-ACGIH LD50 or LC50
Route/Species
Isobutylene 0.0001-0.9 N/A N/A N/A
FORMULA: C4H8
Air 99.0 to N/A N/A N/A
FORMULA: Mixture 99.9999
___________________________________________________________________________
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Release of this product may produce oxygen-deficient atmospheres (especially in confined spaces or other poorly ventilated environments); individuals in such atmospheres may be asphyxiated. Isobutylene may cause drowsiness and other central nervous system effects in high concentrations; however, due to the low concentration of this gas mixture, this is unlikely to occur.
ROUTE OF ENTRY:
Skin Contact Skin Absorption Eye Contact Inhalation Ingestion No No No Yes No
HEALTH EFFECTS:
Exposure Limits Irritant Sensitization Reproductive Hazard Mutagen Yes No No No No
Carcinogenicity: --NTP: No IARC: No OSHA: No
EYE EFFECTS:
N/A.
SKIN EFFECTS:
N/A.
GASCO:.-
ITEM 11.1. ATTACHMENT 3
MATERIAL SAFETY DATA SHEET - CALIBRATION CHECK GAS
2 PRODUCT NAME: ISOBUTYLENE (1 PPM – 0.9%) IN AIR
INGESTION EFFECTS:
Ingestion unlikely. Gas at room temperature.
INHALATION EFFECTS:
Due to the small size of this cylinder, no unusual health effects from over-exposure are anticipated under normal routine use.
NFPA HAZARD CODES HMIS HAZARD CODES RATING SYSTEM
Health: 1 Health: 1 0= No Hazard
Flammability: 0 Flammability: 0 1= Slight Hazard
Reactivity: 0 Reactivity: 0 2= Moderate Hazard
3= Serious Hazard
4= Severe Hazard
___________________________________________________________________________
4. FIRST AID MEASURES
EYES:
N/A
SKIN:
N/A
INGESTION:
Not required
INHALATION:
PROMPT MEDICAL ATTENTION IS MANDATORY IN ALL CASED OF OVEREXPOSURE. RESCUE PERSONNEL SHOULD BE EQUIPPED THE SELF-CONTAINED BREATHING APPARATUS. Victims should be assisted to an uncontaminated area and inhale fresh air. Quick removal from the contaminated area is most important. If breathing has stopped administer artificial resuscitation and supplemental oxygen. Further treatment should be symptomatic and supportive. ___________________________________________________________________________
5. FIRE-FIGHTING MEASURES
These containers hold gas under pressure, with no liquid phase. If involved in a major fire, they should be sprayed with water to avoid pressure increases, otherwise pressures will rise and ultimately they may distort or burst to release the contents. The gases will not add significantly to the fire, but containers or fragments may be projected considerable distances - thereby hampering fire fighting efforts.
___________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
In terms of weight, these containers hold very little contents, such that any accidental release by puncturing etc. will be of no practical concern.
___________________________________________________________________________
7. HANDLING AND STORAGE
Suck back of water into the container must be prevented. Do not allow backfeed into the container. Use only properly specified equipment which is suitable for this product, its supply pressure and temperature. Use only in well-ventilated areas. Do not heat cylinder by any means to increase rate of product from the cylinder. Do not allow the temperature where cylinders are stored to exceed 130oF (54oC).
___________________________________________________________________________
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Use adequate ventilation for extended use of gas.
GASCO:.-
ITEM 11.1. ATTACHMENT 3
MATERIAL SAFETY DATA SHEET - CALIBRATION CHECK GAS
3 PRODUCT NAME: ISOBUTYLENE (1 PPM – 0.9%) IN AIR
___________________________________________________________________________
9. PHYSICAL AND CHEMICAL PROPERTIES
PARAMETER: VALUE:
Physical state : Gas
Evaporation point : N/A
pH : N/A
Odor and appearance : Colorless, odorless gas
___________________________________________________________________________
10. STABILITY AND REACTIVITY
Stable under normal conditions. Expected shelf life 48 months. ___________________________________________________________________________
11. TOXICOLOGICAL INFORMATION
No toxicological damage caused by this product.
___________________________________________________________________________
12. ECOLOGICAL INFORMATION
No ecological damage caused by this product.
___________________________________________________________________________
13. DISPOSAL INFORMATION
Do not discharge into any place where its accumulation could be dangerous. Used containers are acceptable for disposal in the normal waste stream as long as the cylinder is empty and valve removed or cylinder wall is punctured; but GASCO encourages the consumer to return cylinders.
___________________________________________________________________________
14. TRANSPORT INFORMATION
United States DOT Canada TDG
PROPER SHIPPING NAME: Compressed Gas N.O.S. Compressed Gas N.O.S. (Isobutylene in Air) (Isobutylene in Air)
HAZARD CLASS: 2.2 2.2
IDENTIFICATION NUMBER: UN1956 UN1956
SHIPPING LABEL: NONFLAMMABLE GAS NONFLAMMABLE GAS
___________________________________________________________________________
15. REGULATORY INFORMATION
Isobutylene is listed under the accident prevention provisions of section 112(r) of the Clean Air Act (CAA) with a threshold quantity (TQ) of 10,000 pounds.
___________________________________________________________________________
16. OTHER INFORMATION
This MSDS has been prepared in accordance with the Chemicals (Hazard Information and Packaging for Supply (Amendment) Regulation 1996. The information is based on the best knowledge of GASCO, and its advisors and is given in good faith, but we cannot guarantee its accuracy, reliability or completeness and therefore disclaim any liability for loss or damage arising out of use of this data. Since conditions of use are outside the control of the Company and its advisors we disclaim any liability for loss or damage when the product is used for other purposes than it is intended.
MSDS/S010/248/ August, 2010
GASCO:.-
ITEM 11.1. ATTACHMENT 3
ABC
MATERIAL SAFETY DATA SHEET
Section 1. Chemical product and company identification
Product Name: ABC Dry Chemical Fire Extinguishant
Synonym: Multi-purpose Dry Chemical (CH550, F15, F18)
Manufacturer: AMEREX CORPORATION
Internet Address: www.amerex-fire.com
Address: 7595 Gadsden Highway
P.O. Box 81
Trussville, AL 35173-0081
Telephone: (205) 655-3271
Emergency Contacts: Chemtrec 1(800) 424-9300 or
(703) 527–3887
Revised: February, 2012
Section 2. Hazard identification and emergency overview Emergency overview: Light yellow, fine solid powder, odorless.
Adverse health effects and symptoms: Irritating to the respiratory system, eyes and skin. Symptoms may include coughing, shortness of breath, and irritation of the lungs, eyes, and skin. Ingestion, although unlikely, may cause cramps, nausea and diarrhea.
Exposure guidelines:
Ingredients OSHA PEL**** ACGIH TLV DFG MAK *
Mono-ammonium phosphate PNOC**
Total dust, 15 mg/m3
Respirable fraction, 5 mg/m3
PNOC
Total dust, 10 mg/m3
Respirable fraction, 3 mg/m3
PNOC
Total dust, 4 mg/m3
Respirable fraction,
1.5 mg/m3
Ammonium sulphate PNOC
Total dust, 15 mg/m3
Respirable fraction, 5 mg/m3
PNOC
Total dust, 10 mg/m3
Respirable fraction, 3 mg/m3
PNOC
Total dust, 4 mg/m3
Respirable fraction,
1.5 mg/m3
Mica 6 mg/m33 mg/m3 NR
Fullers Earth PNOC
Total dust, 15 mg/m3
Respirable fraction, 5 mg/m3
PNOC
Total dust, 10 mg/m3
Respirable fraction, 3 mg/m3
PNOC
Total dust, 4 mg/m3
Respirable fraction,
1.5 mg/m3
ITEM 11.1. ATTACHMENT 3
ABC
Silicone oil NR*** NR NR
Calcium carbonate PNOC
Total dust, 15 mg/m3
Respirable fraction, 5 mg/m3
PNOC
Total dust, 10 mg/m3
Respirable fraction, 3 mg/m3
-------
Amorphous silica 143 mg/m3 80 mg/m3
or % SiO2
10 mg/m34 mg/m3
Yellow 14 pigment NR NR NR
*German regulatory limits **PNOC = Particulates not otherwise classified (ACGIH) also known as Particulates not otherwise regulated (OSHA) *** NR = Not Regulated. All values are 8 hour time weighted average concentrations. **** Total dust PEL for Washington state= 10mg/ m3 for PNOC Hazard symbols: WHMIS (Canadian workplace hazardous materials identification system
D2B Product may irritate eyes, skin, or mucous membranes Section 3. Composition/information on ingredients
Name/Compound Weight % CAS #
Mono-ammonium phosphate and
Ammonium sulphate
>94 7722-76-1
7783-20-2
Fullers Earth
magnesium aluminum silicate-
<3 8031-18-3
Mica
potassium aluminum silicate
1-2 12001-26-2
Silicone oil
methyl hydrogen polysiloxane
<1 63148-57-2
Calcium carbonate <1 1317-65-3
Amorphous silica
precipitated synthetic zeolite
<1 112926-00-8
Yellow 14 pigment – di-azo dye <1 5468-75-7
Section 4. First Aid Measures
Eye Exposure: Irrigate eyes with water and repeat until pain free. Seek medical attention if irritation develops or if vision changes occur.
ITEM 11.1. ATTACHMENT 3
ABC
Skin Exposure: In case of contact, wash with plenty of soap and water. Seek medical attention if irritation develops.
Inhalation: If respiratory irritation or distress occurs remove victim to fresh air. Seek medical attention if irritation persists.
Ingestion: If victim is conscious and alert, give 2-3 glasses of water to drink and do not induce vomiting. Seek immediate medical attention. Do not leave victim unattended.
To prevent aspiration of swallowed product, lay victim on side with head lower than waist. If vomiting occurs and the victim is conscious, give water to further dilute the chemical.
Medical conditions possibly aggravated by exposure: Inhalation of product may aggravate existing chronic respiratory problems such as asthma, emphysema, or bronchitis. Skin contact may aggravate existing skin disease. Chronic overexposure may cause pneumoconiosis (―dusty lung‖ disease).
Section 5. Fire fighting measures
Extinguishing media: non combustible and non flammable – product is an extinguishing agent.
Unusual fire/explosion hazards: in a fire this material may decompose, releasing oxides of sulfur and carbon (see Section 10).
Insensitive to mechanical impact or static discharge.
HMIS Hazard Ranking:
health = 1, flammability = 0, reactivity = 0, personal protective equipment: ½ mask APR w/HEPA cartridges (see Section 8).
Section 6. Accidental release measures
Clean up released material using vacuum or wet sweep and shovel to minimize generation of dust. Wear appropriate respiratory protection. Bag and drum for disposal. If product is used and/or contaminated, use PPE and containment appropriate to the nature of the mixture. Prevent material from entering waterways.
ITEM 11.1. ATTACHMENT 3
ABC
Section 7. Handling and storage
Avoid skin, eye, or respiratory exposure. Use appropriate PPE when handling or maintaining equipment, and wash thoroughly after handling (see Section 8). Keep product in original container or extinguisher. Contents may be under pressure – inspect for extinguisher rust periodically to insure container integrity. Do not mix with other extinguishing agents.
Section 8. Exposure controls/ personal protection
During the application of this product against fires, exhaust gases and the products of incomplete combustion (PICs) are the principal respiratory hazards. In the manufacture of extinguishers, automated systems and point source ventilation controls sufficiently minimize respiratory exposure. Employers and employees must use their collective judgment in determining occupational settings where the use of a dust mask or air purifying respirator is prudent. The need for respiratory protection is not likely for short-term use in well ventilated areas.
Respiratory protection: use N95 dust mask or air-purifying respirator (APR) with high efficiency particulate air (HEPA) filters.
Eye protection: wear chemical goggles.
Skin protection: use nitrile, latex, or similar gloves and coveralls. Good personal hygiene practices essential, such as avoiding food, tobacco products, or other hand-tomouth contact when handling. Wash thoroughly after handling.
Section 9. Physical and chemical properties
Appearance: yellow powder, finely divided odorless solid.
Specific gravity: ~ .88 in aerated condition
Solubility: product is coated-not immediately soluble in water Non –flammable
Flash point: none
Vapor pressure: < 1 mm Hg
pH: approximately 4-5
Boiling point: not applicable
No explosive or oxidizing properties
ITEM 11.1. ATTACHMENT 3
ABC
Section 10. Stability and reactivity
Stability: stable
Incompatibles: strong alkalis (bases), magnesium, strong oxidizers such as calcium hypochlorite (pool chlorine) and isocyanuric acids.
Decomposition products: heat of fire may release carbon monoxide, carbon dioxide, and sulfur dioxide. Oxides of phosphorous and ammonia reported.
Possibility of hazardous reactions: Slight. See incompatibilities above.
Section 11. Toxicological information
Acute toxicity: Mono ammonium phosphate LD50 (rat): > 1000mg/kg body weight Ammonium sulfate LD50 (rat): 2840 mg/kg body weight
Target organs in man: respiratory system, eyes, skin. This product is an irritant to epithelial tissue, and may aggravate dermatitis. No information was found indicating the product causes sensitization.
Chronic toxicity: Pneumoconiosis, or ―dusty lung‖ disease, may result from chronic exposure to any dust.
Reproductive
toxicity: This product’s ingredients are not known to have reproductive or teratogenic effects.
Section 12. Ecological information
Ecotoxicity: negative effects unknown. Provides nutrient nitrogen and phosphorus to plant life.
Persistence/
Degradability: degrades rapidly in humid/wet environment.
Bioaccummulation: extent unknown.
Mobility in soil: slow evaporation rate; water soluble, may leach to groundwater.
ITEM 11.1. ATTACHMENT 3
ABC
Section 13. Disposal considerations
This product is not a RCRA characteristically hazardous or listed hazardous waste.
Dispose of according to state or local laws, which may be more restrictive than federal laws or regulations. Used product may be altered or contaminated, creating different disposal considerations.
Section 14. Transportation information
This product is not a hazardous material under U.S. Department of Transportation (DOT) 49 CFR 172, and is not regulated by the DOT or Transport Canada ―Transportation of Dangerous Goods‖ regulations.
When shipped in a stored pressure type fire extinguisher, and pressurized with a nonflammable, non-toxic inert expellant gas, the fire extinguisher is considered a hazardous material by the US Department of Transportation and Transport Canada.
The proper shipping name shall be FIRE EXTINGUISHER and the UN designation is UN 1044. The DOT hazard class/ division is 2.2. Non-Flammable Gas. Packing Group –N/A.
Section 15. Regulatory information
International Inventory Status:
All ingredients are on the following inventories
Country(ies) Agency Status
United States of America TSCA Yes
Canada DSL Yes
Europe EINECS/ELINCS Yes
Australia AICS Yes
Japan MITI Yes
South Korea KECL Yes
ITEM 11.1. ATTACHMENT 3
ABC
European Risk and Safety phrases:
EU Classification: Harmful.
R Phrases: 22 Harmful if swallowed.
36/37/38 Irritating to eyes, respiratory system, and skin.
S Phrases: 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
36 Wear suitable protective clothing.
Components:
Mono ammonium phosphate:
EU Classification: Harmful.
R Phrases: 22 Harmful if swallowed.
36/37/38 Irritating to eyes, respiratory system, and skin.
S Phrases: 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
36 Wear suitable protective clothing.
Ammonium sulfate:
EU Classification: Irritant
R Phrases: 22 Harmful if swallowed.
36/37/38 Irritating to eyes, respiratory system, and skin.
S Phrases: 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
36 Wear suitable protective clothing.
U.S. federal regulatory information:
None of the chemicals in this product are under SARA reporting requirements or have SARA threshold planning quantities (TPQs) or CERCLA reportable quantities (RQs), or are regulated under TSCA 8(d).
State regulatory information:
Chemicals in this product are covered under specific State regulations, as denoted below:
Alaska - Designated Toxic and Hazardous Substances: None California – Permissible Exposure Limits for Chemical Contaminants: None Florida – Substance List: Mica Dust, Ammonium Sulfate
Illinois – Toxic Substance List: None
Kansas – Section 302/303 List: None
---
ITEM 11.1. ATTACHMENT 3
ABC
Massachusetts – Substance List: Mica Dust, Ammonium Sulfate Minnesota – List of Hazardous Substances: None
Missouri – Employer Information/Toxic Substance List: None New Jersey – Right to Know Hazardous Substance List: None North Dakota – List of Hazardous Chemicals, Reportable Quantities: None Pennsylvania – Hazardous Substance List: None
Rhode Island – Hazardous Substance List: Mica Dust, Ammonium Sulfate Texas – Hazardous Substance List: No
West Virginia – Hazardous Substance List: None
Wisconsin – Toxic and Hazardous Substances: None
California Proposition 65: No component is listed on the California Proposition 65 list. _____________________________________________________________________ Section 16
Section 17. Other information
This MSDS conforms to requirements under U.S., U.K., Canadian, Australian, and EU regulations or standards, and conforms to the proposed 2003 ANSI Z400.1 format.
The information herein is given in good faith but no warranty, expressed or implied, is made. Updated by Lindsay R. Hill, CIH.
When shipped in a stored pressure type fire extinguisher, and pressurized with a non-flammable, non-toxic inert expellant gas, the fire extinguisher is considered a hazardous material by the US Department of Transportation and Transport Canada. The proper shipping name shall be FIRE EXTINGUISHER and the UN designation is UN 1044. The DOT hazard class/ division is 2.2 NonFlammable Gas. Packing Group—N/A ITEM 11.1. ATTACHMENT 3
Hydrochloric Acid HX0607 Page: 1/1
Material Safety Data Sheet
Hydrochloric Acid
Section 1. Product and Company Identification
Product name : Hydrochloric Acid
Product code : HX0607
Synonym : Muriatic Acid
Material uses : Other non-specified industry: Analytical reagent.
Manufacturer : EMD Chemicals Inc.
P.O. Box 70
480 Democrat Road
Gibbstown, NJ 08027
856-423-6300 Technical Service
Monday - Friday: 8:00 - 5:00 PM
Validation date : 4/5/2006.
Print date :
In case of emergency : 800-424-9300 CHEMTREC (USA)
613-996-6666 CANUTEC (Canada)
24 Hours/Day: 7 Days/Week
Section 2. Hazards Identification
Physical state : Liquid. (Colorless.)
Odor : Pungent.
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Emergency overview : DANGER!
POISON!
MAY BE FATAL IF INHALED OR SWALLOWED.
CAUSES SEVERE EYE AND SKIN BURNS.
CAUSES SEVERE RESPIRATORY TRACT IRRITATION.
CAUSES DAMAGE TO THE FOLLOWING ORGANS: LUNGS, RESPIRATORY TRACT, SKIN, EYE, LENS OR CORNEA.
Do not ingest. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist.
Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling.
Routes of entry : Dermal contact. Eye contact. Inhalation. Ingestion.
Potential acute health effects
Eyes : Severely corrosive to the eyes.
Skin : Severely corrosive to the skin.
Inhalation : Very toxic by inhalation. Severely irritating to the respiratory system.
Ingestion : Very toxic if swallowed. May cause burns to mouth, throat and stomach.
Potential chronic health
effects
:
Carcinogenic effects : No known significant effects or critical hazards.
Mutagenic effects : No known significant effects or critical hazards.
Teratogenicity /
Reproductive toxicity
: No known significant effects or critical hazards.
Medical conditions
aggravated by overexposure
: Repeated skin exposure can produce local skin destruction or dermatitis. Repeated or prolonged exposure to the substance can produce lung damage. Repeated or prolonged contact with spray or mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to the substance can produce target organs damage.
See toxicological information (section 11)
Section 3. Composition/Information on Ingredients
United States
Name CAS number % by Weight
I I
11EMD
I
ITEM 11.1. ATTACHMENT 3
Hydrochloric Acid
The 100% indicates this product is a concentrated acid. Assay (HCl) value is approximately 36-38%.
7647-01-0 100
Section 4. First Aid Measures
Eye contact : Get medical attention immediately. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Chemical burns must be treated promptly by a physician.
Skin contact : Get medical attention immediately. Flush contaminated skin with plenty of water.
Continue to rinse for at least 10 minutes. Remove contaminated clothing and shoes.
Wash contaminated clothing thoroughly with water before removing or wear gloves.
Chemical burns must be treated promptly by a physician. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Inhalation : Get medical attention immediately. Move exposed person to fresh air. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Ingestion : Get medical attention immediately. Wash out mouth with water. Remove dentures if any. Move exposed person to fresh air. Keep person warm and at rest. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous.
Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs.
Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing or wear gloves.
Section 5. Fire Fighting Measures
Flammability of the product : No specific hazard.
Extinguishing media
Suitable : Use an extinguishing agent suitable for the surrounding fire.
Not suitable : None known.
Special exposure hazards : Not available.
Special protective
equipment for fire-fighters
: Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special remarks on fire
hazards
: Flammable hydrogen gas may be produced on prolonged contact with metals such as aluminum, tin, lead and zinc.
Section 6. Accidental Release Measures
Personal precautions : Immediately contact emergency personnel. Keep unnecessary personnel away.
Use suitable protective equipment.
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Methods for cleaning up : If emergency personnel are unavailable, contain spilled material. For small spills, add absorbent (soil may be used in the absence of other suitable materials), scoop up material and place in a sealable, liquid-proof container for disposal. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Place spilled material in an appropriate container for disposal.
Section 7. Handling and Storage
Handling : Do not ingest. Do not get in eyes or on skin or clothing. Keep container closed. Use ITEM 11.1. ATTACHMENT 3
only with adequate ventilation. Do not breathe vapor or mist. Wash thoroughly after handling.
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.
Section 8. Exposure Controls/Personal Protection
Product name Exposure limits
United States
Hydrochloric Acid ACGIH TLV (United States, 2003).
CEIL: 2 ppm
NIOSH REL (United States, 12/2001).
CEIL: 7 mg/m3
Form: All forms
CEIL: 5 ppm Form: All forms
OSHA PEL (United States, 8/1997).
CEIL: 7 mg/m3
Form: All forms
CEIL: 5 ppm Form: All forms
OSHA PEL 1989 (United States, 3/1989).
CEIL: 7 mg/m3
Form: All forms
CEIL: 5 ppm Form: All forms
ACGIH TLV (United States, 1/2005). Notes: Refers to Appendix A -- Carcinogens. ACGIH 2003 Adoption
CEIL: 2 ppm Form: All forms
Consult local authorities for acceptable exposure limits.
Engineering measures : Use only with adequate ventilation. If user operations generate dust, fumes, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Personal protection
Eyes : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts.
Recommended: face shield , splash goggles
Skin : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Body: Recommended: chemical-resistant protective suit
Respiratory : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Hands : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Recommended: PVC
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Section 9. Physical and Chemical Properties
Physical state : Liquid. (Colorless.)
Color : Colorless.
Odor : Pungent.
Molecular weight : 36.46 g/mole
Molecular formula : Cl-H
Boiling/condensation point : 110°C (230°F)
Melting/freezing point : -74°C (-101.2°F)
Critical temperature : 51.5°C (124.7°F)
Relative density : 1.2 (Water = 1)
Vapor pressure : 21.3 kPa (160 mm Hg) (at 20°C)
Vapor density : >1 (Air = 1)
Evaporation rate : >1
Solubility : Soluble in water
ITEM 11.1. ATTACHMENT 3
Section 10. Stability and Reactivity
Stability and reactivity : The product is stable.
Incompatibility with various
substances
: Reactive or incompatible with the following materials: metals and alkalis.
Hazardous decomposition
products
: These products are halogenated compounds, hydrogen chloride.
Hazardous polymerization : Will not occur.
Conditions of reactivity : Flammable hydrogen gas may be produced on prolonged contact with metals such as aluminum, tin, lead and zinc.
Explosive in the presence of the following materials or conditions: metals.
Section 11. Toxicological Information
Toxicity data
United States
Product/ingredient name Test Result Route Species
Hydrochloric Acid LD50
LC50
900 mg/kg
1108 ppm (1
hour/hours)
Oral
Inhalation
Rabbit
Mouse
Chronic effects on humans : CARCINOGENIC EFFECTS: A4 (Not classifiable for humans or animals.) by ACGIH, 3 (Not classifiable for humans.) by IARC.
Causes damage to the following organs: lungs, upper respiratory tract, skin, eye, lens or cornea.
Other toxic effects on
humans
: Extremely hazardous in case of skin contact (corrosive), of eye contact (corrosive), of ingestion, of inhalation (lung irritant).
Hazardous in case of inhalation (lung corrosive).
Specific effects
Carcinogenic effects : No known significant effects or critical hazards.
Mutagenic effects : No known significant effects or critical hazards.
Teratogenicity /
Reproductive toxicity
: No known significant effects or critical hazards.
Sensitization
Ingestion : May cause burns to mouth, throat and stomach.
Inhalation : Severely irritating to the respiratory system.
Eyes : Severely corrosive to the eyes.
Skin : Severely corrosive to the skin.
Section 12. Ecological Information
Environmental precautions : No known significant effects or critical hazards.
Products of degradation : These products are halogenated compounds.
Toxicity of the products of
biodegradation
: The products of degradation are as toxic as the product itself.
Section 13. Disposal Considerations
Waste disposal : The generation of waste should be avoided or minimized wherever possible. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.
Disposal should be in accordance with applicable regional, national and local laws and regulations. Local regulations may be more stringent than regional or national requirements.
The information presented below only applies to the material as supplied. The identification based on characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees.
ITEM 11.1. ATTACHMENT 3
Section 14. Transport Information
information
Regulatory UN number
name
Proper shipping Class PG* Label
information
Additional
DOT Classification UN1789
A
HYDROCHLORIC
CID
8 II
5000 lbs. (2268 kg)
Reportable quantity
PG* : Packing group
Section 15. Regulatory Information
United States
HCS Classification :
Target organ effects
Corrosive material
Highly toxic material
U.S. Federal regulations : TSCA 8(b) inventory: Listed
SARA 302/304/311/312 extremely hazardous substances: Hydrochloric Acid SARA 302/304 emergency planning and notification: Hydrochloric Acid Hydrochloric Acid : Sudden release of pr
SARA 311/312 MSDS distribution - chemical inventory - hazard identification:
SARA 302/304/311/312 hazardous chemicals: Hydrochloric Acid essure, Immediate (acute) health hazard,
Clean Air Act (CAA) 112 accidental releas
Clean Water Act (CWA) 311: Hydrochloric Acid
Clean Water Act (CWA) 307: No products were found.
Delayed (chronic) health hazard
e prevention: Hydrochloric Acid
Clean Air Act (CAA) 112 regulated flammable substances: No products were found.
Clean Air Act (CAA) 112 regulated toxic substances: Hydrochloric Acid SARA 313
Product name CAS number Concentration
Form R - Reporting requirements :
Hydrochloric Acid 7647-01-0 100
Supplier notification :
Hydrochloric Acid 7647-01-0 100
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.
State regulations : Pennsylvania RTK: Hydrochloric Acid : (environmental hazard, generic New Jersey: Hydrochloric Acid
Massachusetts RTK: Hydrochloric Acid
environmental hazard)
Canada
WHMIS (Canada) : Class D-1A: Material causing immediate and serious toxic effects (Very toxic).
Class E: Corrosive material
CEPA DSL/CEPA NDSL : CEPA DSL: Hydrochloric Acid
EU regulations
information required by the CPR.
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all the Hazard
ymbol/symbols s
:
Risk phrases :
R37- Irritating to respiratory system.
R34- Causes burns.
Safety phrases :
S26- In case of contact with eyes, rins
S1/2- Keep locked up and out of the reach of children.
e immediately with plenty of water and seek
S45- In case of accident or if you feel
medical advice.
unwell, seek medical advice immediately
(show the label where possible).
International regulations
International lists : Australia (NICNAS): Hydrochloric Acid China: Hydrochloric Acid
,I
ITEM 11.1. ATTACHMENT 3
Germany water class: Hydrochloric Acid
Japan (METI): Hydrochloric Acid
Korea (TCCL): Hydrochloric Acid
Philippines (RA6969): Hydrochloric Acid
Section 16. Other Information
Label requirements : DANGER!
POISON!
MAY BE FATAL IF INHALED OR SWALLOWED.
CAUSES SEVERE EYE AND SKIN BURNS.
CAUSES SEVERE RESPIRATORY TRACT IRRITATION.
CAUSES DAMAGE TO THE FOLLOWING ORGANS: LUNGS, RESPIRATORY TRACT, SKIN, EYE, LENS OR CORNEA.
National Fire
Protection
Association (U.S.A.)
:
Health
0 Flammability
3 0 Instability
Special
Other special considerations : Section 3 lists this product as 100% which indicates that it is a concentrated acid.
Notice to reader
The statements contained herein are based upon technical data that EMD Chemicals Inc. believes to be reliable, are offered for information purposes only and as a guide to the appropriate precautionary and emergency handling of the material by a properly trained person having the necessary technical skills. Users should consider these data only as a supplement to other information gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use, storage and disposal of these materials and the safety and health of employees and customers and the protection of the environment. EMD CHEMICALS INC. MAKES NO REPRESENTATION OR WARRANTY OF ANY
KIND, EXPRESS OR IMPLIED, INCLUDING MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE, WITH RESPECT TO THE INFORMATION HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS.
Lab Chemicals | Biosciences | Life Science Solutions | Corporate | Privacy | Sitem EMD Chemicals is Merck KGaA, Darmstadt, Germany, in the US and Canada.
ITEM 11.1. ATTACHMENT 3
MATERIAL SAFETY DATA SHEET
1. Product and Company Identification
Material name UNLEADED GASOLINE
Version # 03
Issue date 07-28-2011
Revision date 11-13-2012
Supersedes date 09-28-2012
MSDS Number 002
Product use Motor fuels.
Synonym(s) Regular/Premium/Midgrade - Unleaded Gasoline, RFG - Reformulated Unleaded Gasoline, Conventional Unleaded Gasoline, Oxygenated Unleaded Gasoline, Non-Oxygenated Unleaded Gasoline, CARB (California Air Resource Board) Unleaded Gasoline, RBOB - Reformulated Blendstock for Oxygenate Blending, CBOB - Conventional Blendstock for Oxygenate Blending, Petrol, Motor Fuel.
See section 16 for complete information.
Manufacturer/Supplier Valero Marketing & Supply Company and Affiliates P.O. Box 696000
San Antonio, TX 78269-6000
General Assistance 210-345-4593
Emergency 24 Hour Emergency 866-565-5220
1-800-424-9300 (CHEMTREC USA)
2. Hazards Identification
Physical state Liquid.
Appearance Light straw to red clear liquid with characteristic strong odor of gasoline.
Emergency overview DANGER!
Extremely flammable liquid and vapor - vapor may cause flash fire. Will be easily ignited by heat, spark or flames. Heat may cause the containers to explode.
Harmful if inhaled, absorbed through skin, or swallowed. Aspiration may cause lung damage.
Irritating to eyes, respiratory system and skin. In high concentrations, vapors and spray mists are narcotic and may cause headache, fatigue, dizziness and nausea. Contains benzene. Cancer hazard - can cause cancer. Mutagen. May cause heritable genetic damage. May cause adverse reproductive effects - such as birth defects, miscarriages, or infertility. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Static accumulating flammable materials can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite material and vapor may cause flash fire (or explosion).
OSHA regulatory status This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication).
Potential health effects
Routes of exposure Inhalation. Ingestion. Skin contact. Eye contact.
Eyes Contact may irritate or burn eyes. Eye contact may result in corneal injury.
Skin Harmful if absorbed through skin. Irritating to skin. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.
Inhalation Harmful if inhaled. Irritating to respiratory system. In high concentrations, vapors and spray mists are narcotic and may cause headache, fatigue, dizziness and nausea. May cause breathing disorders and lung damage. May cause cancer by inhalation. Prolonged inhalation may be harmful.
Ingestion Harmful if swallowed. Ingestion may result in vomiting; aspiration (breathing) of vomitus into lungs must be avoided as even small quantities may result in aspiration pneumonitis. Irritating to mouth, throat, and stomach.
Target organs Blood. Eyes. Liver. Respiratory system. Skin. Kidneys. Central nervous system.
CPH MSDS NA
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¥-
VALERO
ITEM 11.1. ATTACHMENT 3
Chronic effects Cancer hazard. Contains material which may have reproductive toxicity, teratogenetic or mutagenic effects. Liver injury may occur. Kidney injury may occur. May cause central nervous system disorder (e.g., narcosis involving a loss of coordination, weakness, fatigue, mental confusion and blurred vision) and/or damage. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.
Signs and symptoms Irritation of nose and throat. Irritation of eyes and mucous membranes. Skin irritation.
Unconsciousness. Corneal damage. Narcosis. Cyanosis (blue tissue condition, nails, lips, and/or skin). Decrease in motor functions. Behavioral changes. Edema. Liver enlargement. Jaundice.
Conjunctivitis. Proteinuria. Defatting of the skin. Rash.
Potential environmental effects Toxic to aquatic organisms. Harmful to aquatic life with long lasting effects.
Components CAS # Percent
3. Composition / Information on Ingredients
Gasoline 86290-81-5 0-100
Toluene 108-88-3 0-30
Hexane (Other Isomers) 96-14-0 5-25
Xylene (o, m, p isomers) 1330-20-7 0-25
Octane (All isomers) 111-65-9 0-18.5
Ethanol 64-17-5 0-10
1,2,4, Trimethylbenzene 95-63-6 0-6
n-Heptane 142-82-5 1-5
Pentane 109-66-0 1-5
Cumene 98-82-8 0-5
Ethylbenzene 100-41-4 0-5
Benzene 71-43-2 0-4.9
n-Hexane 110-54-3 0-3
Cyclohexane 110-82-7 0-3
4. First Aid Measures
First aid procedures
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention.
Skin contact Remove contaminated clothing and shoes. Wash off immediately with soap and plenty of water.
Get medical attention if irritation develops or persists. Wash clothing separately before reuse.
Destroy or thoroughly clean contaminated shoes. If high pressure injection under the skin occurs, always seek medical attention.
Inhalation Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration.
Get medical attention.
Ingestion Rinse mouth thoroughly. Do not induce vomiting without advice from poison control center. Do not give mouth-to-mouth resuscitation. If vomiting occurs, keep head low so that stomach content does not get into the lungs. Get medical attention immediately.
Notes to physician In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation.
Symptoms may be delayed.
General advice If exposed or concerned: get medical attention/advice. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before re-use.
5. Fire Fighting Measures
Flammable properties Flammable by OSHA criteria. Containers may explode when heated.
Extinguishing media
Suitable extinguishing
media
Water spray. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing
media
Do not use a solid water stream as it may scatter and spread fire.
CPH MSDS NA
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ITEM 11.1. ATTACHMENT 3
Protection of firefighters
Specific hazards arising
from the chemical
Vapor may cause flash fire. Vapors can flow along surfaces to distant ignition source and flash back. Sensitive to static discharge.
Protective equipment and
precautions for firefighters
Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, protective clothing and face mask.
Fire fighting
equipment/instructions
Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, protective clothing and face mask. Withdraw immediately in case of rising sound from venting safety devices or any discoloration of tanks due to fire. Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Move containers from fire area if you can do it without risk. In the event of fire, cool tanks with water spray. Cool containers exposed to flames with water until well after the fire is out. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. Vapors may form explosive air mixtures even at room temperature. Prevent buildup of vapors or gases to explosive concentrations. Some of these materials, if spilled, may evaporate leaving a flammable residue. Water runoff can cause environmental damage. Use compatible foam to minimize vapor generation as needed.
Specific methods In the event of fire and/or explosion do not breathe fumes. Use water spray to cool unopened containers.
Hazardous combustion
products
Carbon monoxide. Carbon Dioxide. Sulfur oxides. Nitrogen oxides (NOx). Hydrocarbons.
6. Accidental Release Measures
Personal precautions Keep unnecessary personnel away. Local authorities should be advised if significant spills cannot be contained. Keep upwind. Keep out of low areas. Ventilate closed spaces before entering. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.
See Section 8 of the MSDS for Personal Protective Equipment.
Environmental precautions Gasoline may contain oxygenated blend products (Ethanol, etc.) that are soluble in water and therefore precautions should be taken to protect surface and groundwater sources from contamination. If facility or operation has an "oil or hazardous substance contingency plan", activate its procedures. Stay upwind and away from spill. Wear appropriate protective equipment including respiratory protection as conditions warrant. Do not enter or stay in area unless monitoring indicates that it is safe to do so. Isolate hazard area and restrict entry to emergency crew. Extremely flammable. Review Firefighting Measures, Section 5, before proceeding with clean up. Keep all sources of ignition (flames, smoking, flares, etc.) and hot surfaces away from release. Contain spill in smallest possible area. Recover as much product as possible (e.g. by vacuuming). Stop leak if it can be done without risk. Use water spray to disperse vapors. Use compatible foam to minimize vapor generation as needed. Spilled material may be absorbed by an appropriate absorbent, and then handled in accordance with environmental regulations.
Prevent spilled material from entering sewers, storm drains, other unauthorized treatment or drainage systems and natural waterways. Contact fire authorities and appropriate federal, state and local agencies. If spill of any amount is made into or upon navigable waters, the contiguous zone, or adjoining shorelines, contact the National Response Center at 1-800-424-8802. For highway or railways spills, contact Chemtrec at 1-800-424-9300.
Methods for containment Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leak if you can do so without risk. This material is a water pollutant and should be prevented from contaminating soil or from entering sewage and drainage systems and bodies of water. Dike the spilled material, where this is possible. Prevent entry into waterways, sewers, basements or confined areas.
Methods for cleaning up Use non-sparking tools and explosion-proof equipment.
Small Spills: Absorb spill with vermiculite or other inert material, then place in a container for chemical waste. Clean surface thoroughly to remove residual contamination. This material and its container must be disposed of as hazardous waste.
Large Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Prevent product from entering drains. Do not allow material to contaminate ground water system. Should not be released into the environment.
Other information Clean up in accordance with all applicable regulations.
CPH MSDS NA
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ITEM 11.1. ATTACHMENT 3
7. Handling and Storage
Handling Eliminate sources of ignition. Avoid spark promoters. Ground/bond container and equipment.
These alone may be insufficient to remove static electricity.
Wear personal protective equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Do not taste or swallow. Avoid prolonged exposure. Use only with adequate ventilation. Wash thoroughly after handling. The product is extremely flammable, and explosive vapor/air mixtures may be formed even at normal room temperatures.
DO NOT handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. When using, do not eat, drink or smoke. Avoid release to the environment.
Storage Flammable liquid storage. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. The pressure in sealed containers can increase under the influence of heat. Keep container tightly closed in a cool, well-ventilated place. Keep away from food, drink and animal feedingstuffs. Keep out of the reach of children.
8. Exposure Controls / Personal Protection
Occupational exposure limits
US. ACGIH Threshold Limit Values
Components Type Value
1,2,4, Trimethylb enzen e TWA 25 ppm
(CAS 95-63-6)
Benzene (CAS 71-43-2) STEL 2.5 ppm
TWA 0.5 ppm
Cumene (CAS 98-82-8) TWA 50 ppm
Cyclohexan e (CAS TWA 100 ppm
110-82-7)
Ethanol (CAS 64-17-5) STEL 1000 ppm
Ethylbenze ne (CAS TWA 20 ppm
100-41-4)
Gasoline (CAS 86290-81-5) STEL 500 ppm
TWA 300 ppm
Hexane (Other Isomers) STEL 1000 ppm
(CAS 96-14-0)
TWA 500 ppm
n-Heptane (CAS 142-82-5) STEL 500 ppm
TWA 400 ppm
n-Hexane (CAS 110-54-3) TWA 50 ppm
Octane (All isomers) (CAS TWA 300 ppm
111-65-9)
Pentane (CAS 109-66-0) TWA 600 ppm
Toluene (CAS 108-88-3) TWA 20 ppm
Xylene (o, m, p isomers) STEL 150 ppm
(CAS 1330-20-7)
TWA 100 ppm
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Components Type Value
Benzene (CAS 71-43-2) STEL 5 ppm
TWA 1 ppm
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value
Cumene (CAS 98-82-8) PEL 245 mg/m3
50 ppm
Cyclohexan e (CAS PEL 1050 mg/m3
110-82-7)
300 ppm
Ethanol (CAS 64-17-5) PEL 1900 mg/m3
CPH MSDS NA
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ITEM 11.1. ATTACHMENT 3
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value
1000 ppm
Ethylbenze ne (CAS PEL 435 mg/m3
100-41-4)
100 ppm
n-Heptane (CAS 142-82-5) PEL 2000 mg/m3
500 ppm
n-Hexane (CAS 110-54-3) PEL 1800 mg/m3
500 ppm
Octane (All isomers) (CAS PEL 2350 mg/m3
111-65-9)
500 ppm
Pentane (CAS 109-66-0) PEL 2950 mg/m3
1000 ppm
Xylene (o, m, p isomers) PEL 435 mg/m3
(CAS 1330-20-7)
100 ppm
US. OSHA Table Z-2 (29 CFR 1910.1000)
Components Type Value
Benzene (CAS 71-43-2) Ceiling 25 ppm
TWA 10 ppm
Toluene (CAS 108-88-3) Ceiling 300 ppm
TWA 200 ppm
Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2) Components Type Value
1,2,4, Trimethylb enzen e TWA 123 mg/m3
(CAS 95-63-6)
25 ppm
Benzene (CAS 71-43-2) STEL 8 mg/m3
2.5 ppm
TWA 1.6 mg/m3
0.5 ppm
Cumene (CAS 98-82-8) TWA 246 mg/m3
50 ppm
Cyclohexan e (CAS TWA 344 mg/m3
110-82-7)
100 ppm
Ethanol (CAS 64-17-5) TWA 1880 mg/m3
1000 ppm
Ethylbenze ne (CAS STEL 543 mg/m3
100-41-4)
125 ppm
TWA 434 mg/m3
100 ppm
Gasoline (CAS 86290-81-5) STEL 500 ppm
TWA 300 ppm
Hexane (Other Isomers) STEL 3500 mg/m3
(CAS 96-14-0)
1000 ppm
TWA 1760 mg/m3
500 ppm
n-Heptane (CAS 142-82-5) STEL 2050 mg/m3
500 ppm
TWA 1640 mg/m3
400 ppm
n-Hexane (CAS 110-54-3) TWA 176 mg/m3
50 ppm
CPH MSDS NA
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ITEM 11.1. ATTACHMENT 3
Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2) Components Type Value
Octane (All isomers) (CAS TWA 1400 mg/m3
111-65-9)
300 ppm
Pentane (CAS 109-66-0) TWA 1770 mg/m3
600 ppm
Toluene (CAS 108-88-3) TWA 188 mg/m3
50 ppm
Xylene (o, m, p isomers) STEL 651 mg/m3
(CAS 1330-20-7)
150 ppm
TWA 434 mg/m3
100 ppm
Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended)
Components Type Value
1,2,4, Trimethylb enzen e TWA 25 ppm
(CAS 95-63-6)
Benzene (CAS 71-43-2) STEL 2.5 ppm
TWA 0.5 ppm
Cumene (CAS 98-82-8) STEL 75 ppm
TWA 25 ppm
Cyclohexan e (CAS TWA 100 ppm
110-82-7)
Ethanol (CAS 64-17-5) STEL 1000 ppm
Ethylbenze ne (CAS TWA 20 ppm
100-41-4)
Gasoline (CAS 86290-81-5) STEL 500 ppm
TWA 300 ppm
Hexane (Other Isomers) TWA 200 ppm
(CAS 96-14-0)
n-Heptane (CAS 142-82-5) STEL 500 ppm
TWA 400 ppm
n-Hexane (CAS 110-54-3) TWA 20 ppm
Octane (All isomers) (CAS TWA 300 ppm
111-65-9)
Pentane (CAS 109-66-0) TWA 600 ppm
Toluene (CAS 108-88-3) TWA 20 ppm
Xylene (o, m, p isomers) STEL 150 ppm
(CAS 1330-20-7)
TWA 100 ppm
Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) Components Type Value
1,2,4, Trimethylb enzen e TWA 25 ppm
(CAS 95-63-6)
Benzene (CAS 71-43-2) STEL 2.5 ppm
TWA 0.5 ppm
Cumene (CAS 98-82-8) TWA 50 ppm
Cyclohexan e (CAS TWA 100 ppm
110-82-7)
Ethanol (CAS 64-17-5) STEL 1000 ppm
Ethylbenze ne (CAS STEL 125 ppm
100-41-4)
TWA 100 ppm
Gasoline (CAS 86290-81-5) STEL 500 ppm
TWA 300 ppm
Hexane (Other Isomers) STEL 1000 ppm
(CAS 96-14-0)
TWA 500 ppm
CPH MSDS NA
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ITEM 11.1. ATTACHMENT 3
Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) Components Type Value
n-Heptane (CAS 142-82-5) STEL 500 ppm
TWA 400 ppm
n-Hexane (CAS 110-54-3) TWA 50 ppm
Octane (All isomers) (CAS TWA 300 ppm
111-65-9)
Pentane (CAS 109-66-0) STEL 2210 mg/m3
750 ppm
TWA 1770 mg/m3
600 ppm
Toluene (CAS 108-88-3) TWA 20 ppm
Xylene (o, m, p isomers) STEL 150 ppm
(CAS 1330-20-7)
TWA 100 ppm
Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) Components Type Value
1,2,4, Trimethylb enzen e TWA 123 mg/m3
(CAS 95-63-6)
25 ppm
Benzene (CAS 71-43-2) STEL 15.5 mg/m3
5 ppm
TWA 3 mg/m3
1 ppm
Cumene (CAS 98-82-8) TWA 246 mg/m3
50 ppm
Cyclohexan e (CAS TWA 1030 mg/m3
110-82-7)
300 ppm
Ethanol (CAS 64-17-5) TWA 1880 mg/m3
1000 ppm
Ethylbenze ne (CAS STEL 543 mg/m3
100-41-4)
125 ppm
TWA 434 mg/m3
100 ppm
Hexane (Other Isomers) STEL 3500 mg/m3
(CAS 96-14-0)
1000 ppm
TWA 1760 mg/m3
500 ppm
n-Heptane (CAS 142-82-5) STEL 2050 mg/m3
500 ppm
TWA 1640 mg/m3
400 ppm
n-Hexane (CAS 110-54-3) TWA 176 mg/m3
50 ppm
Octane (All isomers) (CAS STEL 1750 mg/m3
111-65-9)
375 ppm
TWA 1400 mg/m3
300 ppm
Pentane (CAS 109-66-0) TWA 350 mg/m3
120 ppm
Toluene (CAS 108-88-3) TWA 188 mg/m3
50 ppm
Xylene (o, m, p isomers) STEL 651 mg/m3
(CAS 1330-20-7)
150 ppm
TWA 434 mg/m3
CPH MSDS NA
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ITEM 11.1. ATTACHMENT 3
Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) Components Type Value
100 ppm
Mexico. Occupational Exposure Limit Values
Components Type Value
1,2,4, Trimethylb enzen e STEL 170 mg/m3
(CAS 95-63-6)
35 ppm
TWA 125 mg/m3
25 ppm
Benzene (CAS 71-43-2) STEL 16 mg/m3
5 ppm
TWA 3.2 mg/m3
1 ppm
Cumene (CAS 98-82-8) STEL 365 mg/m3
75 ppm
TWA 245 mg/m3
50 ppm
Cyclohexan e (CAS STEL 1300 mg/m3
110-82-7)
375 ppm
TWA 1050 mg/m3
300 ppm
Ethanol (CAS 64-17-5) TWA 1900 mg/m3
1000 ppm
Ethylbenze ne (CAS STEL 545 mg/m3
100-41-4)
125 ppm
TWA 435 mg/m3
100 ppm
Hexane (Other Isomers) STEL 3500 mg/m3
(CAS 96-14-0)
1000 ppm
TWA 1760 mg/m3
500 ppm
n-Heptane (CAS 142-82-5) STEL 2000 mg/m3
500 ppm
TWA 1600 mg/m3
400 ppm
n-Hexane (CAS 110-54-3) TWA 176 mg/m3
50 ppm
Octane (All isomers) (CAS STEL 1800 mg/m3
111-65-9)
375 ppm
TWA 1450 mg/m3
300 ppm
Pentane (CAS 109-66-0) STEL 2250 mg/m3
760 ppm
TWA 1800 mg/m3
600 ppm
Toluene (CAS 108-88-3) TWA 188 mg/m3
50 ppm
Xylene (o, m, p isomers) STEL 655 mg/m3
(CAS 1330-20-7)
150 ppm
TWA 435 mg/m3
100 ppm
CPH MSDS NA
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ITEM 11.1. ATTACHMENT 3
Engineering controls Provide adequate general and local exhaust ventilation. Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Use explosion-proof equipment.
Personal protective equipment
Eye / face protection Wear safety glasses. If splash potential exists, wear full face shield or chemical goggles.
Skin protection Wear chemical-resistant, impervious gloves. Full body suit and boots are recommended when handling large volumes or in emergency situations. Flame retardant protective clothing is recommended.
Respiratory protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. If workplace exposure limits for product or components are exceeded, NIOSH approved equipment should be worn. Proper respirator selection should be determined by adequately trained personnel, based on the contaminants, the degree of potential exposure and published respiratory protection factors. This equipment should be available for nonroutine and emergency use.
General hygiene
considerations
Consult supervisor for special handling instructions. Avoid contact with eyes. Avoid contact with skin. Keep away from food and drink. Wash hands before breaks and immediately after handling the product. Provide eyewash station and safety shower. Handle in accordance with good industrial hygiene and safety practice.
9. Physical & Chemical Properties
Appearance Light straw to red clear liquid with characteristic strong odor of gasoline.
Physical state Liquid.
Form Liquid.
Color Light straw to red clear.
Odor Characteristic Gasoline Odor (Strong).
Odor threshold Not available.
pH Not available.
Vapor pressure 60.8 - 101.3 kPa (20°C)
Vapor density 3 - 4 (Air=1)
Boiling point 80.1 - 440.1 °F (26.7 - 226.7 °C)
Melting point/Freezing point 44 °F (6.67 °C) May start to solidify at this temperature. This is based on data for the following ingredient: Cyclohexane. Weighted average: -91.9 deg C (-133.4 deg F) Solubility (water) Very slightly soluble.
Specific gravity 0.66 - 0.75 (Water=1) (60°F)
Flash point -40 °F (-40 °C) (closed cup)
Flammability limits in air,
upper, % by volume
7.1 %
Flammability limits in air,
lower, % by volume
1.3 %
Auto-ignition temperature > 500 °F (> 260 °C)
VOC 100 %
Evaporation rate 10 - 11 BuAc
Other data
Flash point class Flammable IA
10. Chemical Stability & Reactivity Information
Chemical stability Stable under normal temperature conditions and recommended use.
Conditions to avoid Heat, flames and sparks. Ignition sources. Contact with incompatible materials. Do not pressurize, cut, weld, braze, solder, drill, grind or expose empty containers to heat, flame, sparks, static electricity, or other sources of ignition; they may explode and cause injury or death.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition
products
Carbon oxides. Sulfur oxides. Nitrogen oxides (NOx). Hydrocarbons.
Possibility of hazardous
reactions
Hazardous polymerization does not occur.
CPH MSDS NA
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ITEM 11.1. ATTACHMENT 3
11. Toxicological Information
Test Results
Toxicological data
Components Species
1,2,4, Trimethylbenzene (CAS 95-63-6)
LD50 Rabbit
Dermal
Acute
> 3160 mg/kg
LC50 Rat
Inhalation
> 2000 mg/l, 48 Hours
LD50 Rat
Oral
6 g/kg
Benzene (CAS 71-43-2)
LD50 Rat
Oral
Acute
3306 mg/kg
Cumene (CAS 98-82-8)
LC50 Mouse
Inhalation
Acute
2000 mg/l, 7 Hours
Rat 8000 mg/l, 4 Hours
LD50 Rat
Oral
1400 mg/kg
2.91 g/kg
Cyclohexane (CAS 110-82-7)
LD50 Rat
Oral
Acute
12705 mg/kg
Ethanol (CAS 64-17-5)
LC50 Rat
Inhalation
Acute
30000 mg/m3
LD50 Rat
Oral
11.5 g/kg
Ethylbenzene (CAS 100-41-4)
LD50 Rabbit
Dermal
Acute
> 5000 mg/kg
LD50 Rat
Oral
5.46 g/kg
n-Heptane (CAS 142-82-5)
LC50 Rat
Inhalation
Acute
103 mg/l, 4 Hours
Octane (All isomers) (CAS 111-65-9)
LC50 Rat
Inhalation
Acute
118 mg/l, 4 Hours
Pentane (CAS 109-66-0)
LC50 Rat
Inhalation
Acute
364 mg/l, 4 Hours
CPH MSDS NA
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ITEM 11.1. ATTACHMENT 3
Components Species Test Results
Toluene (CAS 108-88-3)
LD50 Rabbit
Dermal
Acute
14.1 ml/kg
LC50 Rat
Inhalation
49000 mg/m³, 4 Hours
LD50 Rat
Oral
636 mg/kg
Xylene (o, m, p isomers) (CAS 1330-20-7)
LD50 Rat
Oral
Acute
4300 mg/kg
Sensitization This substance may have a potential for sensitization which may provoke an allergic reaction among sensitive individuals.
Acute effects Harmful if inhaled, absorbed through skin, or swallowed. Harmful: may cause lung damage if swallowed. Irritating to eyes, respiratory system and skin. In high concentrations, vapors and spray mists are narcotic and may cause headache, fatigue, dizziness and nausea.
Local effects
US. ACGIH Threshold Limit Values
Benzene (CAS 71-43-2) Can be absorbed through the skin. n-Hexane (CAS 110-54-3) Can be absorbed through the skin.
Chronic effects Repeated exposure of laboratory animals to high concentrations of gasoline vapors has caused kidney damage and cancer in rats and cancer in mice. Gasoline was evaluated for genetic activity in assays using microbial cells, cultured mammalian cells and rat bone marrow cells. The results were all negative so gasoline was considered nonmutagenic under these conditions.
Overexposure to this product or its components has been suggested as a cause of liver abnormalities in laboratory animals and humans. Lifetime studies by the American Petroleum Institute have shown that kidney damage and kidney cancer can occur in male rats after prolonged inhalation exposures at elevated concentrations of total gasoline. Kidneys of mice and female rats were unaffected. The U.S. EPA Risk Assessment Forum has concluded that the male rat kidney tumor results are not relevant for humans. Total gasoline exposure also produced liver tumors in female mice only. The implication of these data for humans has not been determined.
Subchronic effects Subchronic inhalation of benzene by rats produced decreased white blood cell counts, decreased bone marrow cell activity, increased red blood cell activity and cataracts. Blood disorders may occur after prolonged inhalation, prolonged skin contact and/or ingestion. Liver and kidney damage may occur after prolonged and repeated exposure.
Carcinogenicity
ACGIH Carcinogens
Benzene (CAS 71-43-2) A1 Confirmed human carcinogen.
Ethanol (CAS 64-17-5) A3 Confirmed animal carcinogen with unknown relevance to humans.
Ethylbenzene (CAS 100-41-4) A3 Confirmed animal carcinogen with unknown relevance to humans.
Gasoline (CAS 86290-81-5) A3 Confirmed animal carcinogen with unknown relevance to humans.
Toluene (CAS 108-88-3) A4 Not classifiable as a human carcinogen.
Xylene (o, m, p isomers) (CAS 1330-20-7) A4 Not classifiable as a human carcinogen.
IARC Monographs. Overall Evaluation of Carcinogenicity
Benzene (CAS 71-43-2) 1 Carcinogenic to humans.
Cumene (CAS 98-82-8) 2B Possibly carcinogenic to humans.
Ethylbenzene (CAS 100-41-4) 2B Possibly carcinogenic to humans.
Gasoline (CAS 86290-81-5) 2B Possibly carcinogenic to humans.
Toluene (CAS 108-88-3) 3 Not classifiable as to carcinogenicity to humans.
Xylene (o, m, p isomers) (CAS 1330-20-7) 3 Not classifiable as to carcinogenicity to humans.
US NTP Report on Carcinogens: Known carcinogen
Benzene (CAS 71-43-2) Known To Be Human Carcinogen.
CPH MSDS NA
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ITEM 11.1. ATTACHMENT 3
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Benzene (CAS 71-43-2) Cancer hazard.
Epidemiology Contains benzene. Human epidemiology studies indicate that prolonged and/or repeated overexposure to benzene may cause damage to the blood-producing system and serious blood disorders, including leukemia. Animal tests suggest that prolonged and/or repeated overexposure to benzene may damage the embryo/fetus. The relevance of these animal studies to humans has not been fully established. Studies have shown a risk of spontaneous abortions in women exposed to high concentrations of organic solvents during pregnancy.
Mutagenicity In in-vitro experiments, neither benzene, toluene nor xylene changed the number of sister-chromatid exchanges (SCEs) or the number of chromosomal aberrations in human lymphocytes. However, toluene and xylene caused a significant cell growth inhibition which was not observed with benzene in the same concentrations. In in-vivo experiments, toluene changed the number of sister-chromatid exchanges (SCEs) in human lymphocytes. Toluene may cause heritable genetic damage.
Neurological effects Chronic exposure to high concentrations of various hydrocarbon blends may lead to polyneuropathy (peripheral nerve damage), characterized by progressive weakness and numbness in the extremities, loss of deep tendon reflexes and reduction of motor nerve conduction velocity. Numerous cases of polyneuritis have been reported following prolonged exposures to a petroleum fraction containing various isomers of heptane as major ingredients.
May cause central nervous system disorder (e.g., narcosis involving a loss of coordination, weakness, fatigue) and/or damage.
Reproductive effects Benzene, xylene and toluene have demonstrated animal effects of reproductive toxicity. Animal studies of benzene have shown testicular effects, alterations in reproductive cycles, chromosomal aberrations and embryo/fetotoxicity. Ethanol has demonstrated human effects of reproductive toxicity. May damage fertility or the unborn child. Can cause adverse reproductive effects - such as birth defects, miscarriages, or infertility. Avoid exposure to women during early pregnancy.
Avoid contact during pregnancy/while nursing.
Teratogenicity Abusive inhalation of toluene ("glue sniffing") has been reported to be associated with birth defects in the offspring of abusers. Rats exposed to benzene and xylene vapor during pregnancy showed embryo/fetotoxic effects. Ethanol has demonstrated human effects of teratogenicity.
Further information Symptoms may be delayed.
12. Ecological Information
Ecotoxicological data
Components Species Test Results
1,2,4, Trimethylbenzene (CAS 95-63-6)
Aquatic
Fish LC50 Fathead minnow (Pimephales promelas) 7.19 - 8.28 mg/l, 96 hours Benzene (CAS 71-43-2)
Aquatic
Crustacea EC50 Water flea (Daphnia magna) 8.76 - 15.6 mg/l, 48 hours Fish LC50 Rainbow trout,donaldson trout 5.3 mg/l, 96 hours (Oncorhynchus mykiss)
Cumene (CAS 98-82-8)
Aquatic
Crustacea EC50 Brine shrimp (Artemia sp.) 3.55 - 11.29 mg/l, 48 hours Fish LC50 Rainbow trout,donaldson trout 2.7 mg/l, 96 hours (Oncorhynchus mykiss)
Cyclohexane (CAS 110-82-7)
Aquatic
Fish LC50 Fathead minnow (Pimephales promelas) 3.961 - 5.181 mg/l, 96 hours Ethanol (CAS 64-17-5)
Aquatic
Algae EC50 Freshwater algae 275 mg/l, 72 Hours
Marine water algae 1970 mg/l
Fish LC50 Fathead minnow (Pimephales promelas) > 100 mg/l, 96 hours Freshwater fish 11200 mg/l, 96 Hours
CPH MSDS NA
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ITEM 11.1. ATTACHMENT 3
Components Species Test Results
Invertebrate EC50 Freshwater invertebrate 5012 mg/l, 48 Hours Marine water invertebrate 857 mg/l, 48 Hours
Ethylbenzene (CAS 100-41-4)
Aquatic
Crustacea EC50 Water flea (Daphnia magna) 1 - 4 mg/l, 48 hours Fish LC50 Rainbow trout,donaldson trout 4 mg/l, 96 hours (Oncorhynchus mykiss)
n-Hexane (CAS 110-54-3)
Aquatic
Fish LC50 Fathead minnow (Pimephales promelas) 2.101 - 2.981 mg/l, 96 hours Toluene (CAS 108-88-3)
Aquatic
Crustacea EC50 Water flea (Daphnia magna) 5.46 - 9.83 mg/l, 48 hours Fish LC50 Coho salmon,silver salmon 5.5 mg/l, 96 hours
(Oncorhynchus kisutch)
Xylene (o, m, p isomers) (CAS 1330-20-7)
Aquatic
Fish LC50 Rainbow trout,donaldson trout 8 mg/l, 96 Hours (Oncorhynchus mykiss)
Ecotoxicity Contains a substance which causes risk of hazardous effects to the environment.
Environmental effects The product contains a substance which is toxic to aquatic organisms and which may cause long-term adverse effects in the aquatic environment.
Aquatic toxicity Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
Persistence and degradability Not available.
Bioaccumulation /
Accumulation
Not available.
Partition coefficient
Ethanol -0.31
Benzene 2.13
Toluene 2.73
Ethylbenzene 3.15
Xylene (o, m, p isomers) 3.2
Pentane 3.39
Cyclohexane 3.44
Hexane (Other Isomers) 3.6
Cumene 3.66
n-Hexane 3.9
n-Heptane 4.66
Octane (All isomers) 5.18
13. Disposal Considerations
Waste codes D001: Waste Flammable material with a flash point <140 °F D018: Waste Benzene
Disposal instructions Dispose in accordance with all applicable regulations. Dispose of this material and its container to hazardous or special waste collection point. Incinerate the material under controlled conditions in an approved incinerator. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container.
14. Transport Information
DOT
UN number UN1203
Basic shipping requirements:
Proper shipping name Gasoline
CPH MSDS NA
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ITEM 11.1. ATTACHMENT 3
Hazard class 3
Packing group II
Special provisions 139, B33, B101, T8
Additional information:
Packaging exceptions 150
Packaging non bulk 202
Packaging bulk 242
IATA
UN number UN1203
UN proper shipping name Gasoline
Transport hazard class(es) 3
Packing group II
ERG code 3H
IMDG
UN number UN1203
UN proper shipping name Gasoline
Transport hazard class(es) 3
Packing group II
EmS F-E, S-E
TDG
Proper shipping name GASOLINE; MOTOR SPIRIT; or PETROL, MARINE POLLUTANT Hazard class 3
UN number UN1203
Packing group II
Marine pollutant Yes
Special provisions 17
15. Regulatory Information
US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Benzene (CAS 71-43-2)
Cumene (CAS 98-82-8)
Ethylbenzene (CAS 100-41-4)
n-Hexane (CAS 110-54-3)
Toluene (CAS 108-88-3)
Xylene (o, m, p isomers) (CAS 1330-20-7)
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: De minimis concentration 1,2,4, Trimethylbenzene (CAS 95-63-6) 1.0 %
Benzene (CAS 71-43-2) 0.1 %
Cumene (CAS 98-82-8) 1.0 %
Cyclohexane (CAS 110-82-7) 1.0 %
Ethylbenzene (CAS 100-41-4) 0.1 %
n-Hexane (CAS 110-54-3) 1.0 %
Toluene (CAS 108-88-3) 1.0 %
Xylene (o, m, p isomers) (CAS 1330-20-7) 1.0 %
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance 1,2,4, Trimethylbenzene (CAS 95-63-6) Listed.
Benzene (CAS 71-43-2) Listed.
Cumene (CAS 98-82-8) Listed.
Cyclohexane (CAS 110-82-7) Listed.
Ethylbenzene (CAS 100-41-4) Listed.
n-Hexane (CAS 110-54-3) Listed.
Toluene (CAS 108-88-3) Listed.
Xylene (o, m, p isomers) (CAS 1330-20-7) Listed.
CPH MSDS NA
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ITEM 11.1. ATTACHMENT 3
CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4) Gasoline: 100
Toluene: 1000
Hexane (Other Isomers): 100
Xylene (o, m, p isomers): 100
Octane (All isomers): 100
Pentane: 100
Cumene: 5000
Ethylbenzene: 1000
Benzene: 10
n-Hexane: 5000
Cyclohexane: 1000
Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes
Delayed Hazard - Yes
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
Section 302 extremely
hazardous substance (40
CFR 355, Appendix A)
No
Section 311/312 (40 CFR
370)
No
Drug Enforcement
Administration (DEA) (21 CFR
1308.11-15)
Not controlled
Canadian regulations This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
WHMIS status Controlled
WHMIS classification B2 - Flammable Liquids
D1A - Immediate/Serious-VERY TOXIC
D2A - Other Toxic Effects-VERY TOXIC
D2B - Other Toxic Effects-TOXIC
WHMIS labeling
Inventory status
Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) No European Inventory of Existing Commercial Chemical
Substances (EINECS)
Europe Yes
Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) Yes Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippine Inventory of Chemicals and Chemical Substances (PICCS)
Philippines Yes
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory No State regulations WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm.
US - California Hazardous Substances (Director's): Listed substance 1,2,4, Trimethylbenzene (CAS 95-63-6) Listed.
Benzene (CAS 71-43-2) Listed.
CPH MSDS NA
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ITEM 11.1. ATTACHMENT 3
Cumene (CAS 98-82-8) Listed.
Cyclohexane (CAS 110-82-7) Listed.
Ethanol (CAS 64-17-5) Listed.
Ethylbenzene (CAS 100-41-4) Listed.
Hexane (Other Isomers) (CAS 96-14-0) Listed.
n-Heptane (CAS 142-82-5) Listed.
n-Hexane (CAS 110-54-3) Listed.
Octane (All isomers) (CAS 111-65-9) Listed.
Pentane (CAS 109-66-0) Listed.
Toluene (CAS 108-88-3) Listed.
Xylene (o, m, p isomers) (CAS 1330-20-7) Listed.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance Benzene (CAS 71-43-2) Listed.
Cumene (CAS 98-82-8) Listed.
Ethylbenzene (CAS 100-41-4) Listed.
Toluene (CAS 108-88-3) Listed.
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance Benzene (CAS 71-43-2) Listed: February 27, 1987 Carcinogenic.
Cumene (CAS 98-82-8) Listed: April 6, 2010 Carcinogenic.
Ethylbenzene (CAS 100-41-4) Listed: June 11, 2004 Carcinogenic.
US - California Proposition 65 - CRT: Listed date/Developmental toxin Benzene (CAS 71-43-2) Listed: December 26, 1997 Developmental toxin.
Toluene (CAS 108-88-3) Listed: January 1, 1991 Developmental toxin.
US - California Proposition 65 - CRT: Listed date/Female reproductive toxin Toluene (CAS 108-88-3) Listed: August 7, 2009 Female reproductive toxin.
US - California Proposition 65 - CRT: Listed date/Male reproductive toxin Benzene (CAS 71-43-2) Listed: December 26, 1997 Male reproductive toxin.
US - New Jersey RTK - Substances: Listed substance
1,2,4, Trimethylbenzene (CAS 95-63-6) Listed.
Benzene (CAS 71-43-2) Listed.
Cumene (CAS 98-82-8) Listed.
Cyclohexane (CAS 110-82-7) Listed.
Ethanol (CAS 64-17-5) Listed.
Ethylbenzene (CAS 100-41-4) Listed.
n-Heptane (CAS 142-82-5) Listed.
n-Hexane (CAS 110-54-3) Listed.
Octane (All isomers) (CAS 111-65-9) Listed.
Pentane (CAS 109-66-0) Listed.
Toluene (CAS 108-88-3) Listed.
Xylene (o, m, p isomers) (CAS 1330-20-7) Listed.
US - Pennsylvania RTK - Hazardous Substances: Special hazard Benzene (CAS 71-43-2) Special hazard.
US. Massachusetts RTK - Substance List
1,2,4, Trimethylbenzene (CAS 95-63-6) Listed.
Benzene (CAS 71-43-2) Listed.
Cumene (CAS 98-82-8) Listed.
Cyclohexane (CAS 110-82-7) Listed.
Ethanol (CAS 64-17-5) Listed.
Ethylbenzene (CAS 100-41-4) Listed.
Hexane (Other Isomers) (CAS 96-14-0) Listed.
n-Heptane (CAS 142-82-5) Listed.
n-Hexane (CAS 110-54-3) Listed.
Octane (All isomers) (CAS 111-65-9) Listed.
Pentane (CAS 109-66-0) Listed.
Toluene (CAS 108-88-3) Listed.
Xylene (o, m, p isomers) (CAS 1330-20-7) Listed.
US. New Jersey Worker and Community Right-to-Know Act
1,2,4, Trimethylbenzene (CAS 95-63-6) 500 LBS
Benzene (CAS 71-43-2) 500 LBS
Cumene (CAS 98-82-8) 500 LBS
Cyclohexane (CAS 110-82-7) 500 LBS
Ethylbenzene (CAS 100-41-4) 500 LBS
n-Hexane (CAS 110-54-3) 500 LBS
CPH MSDS NA
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ITEM 11.1. ATTACHMENT 3
Pentane (CAS 109-66-0) 500 LBS
Toluene (CAS 108-88-3) 500 LBS
Xylene (o, m, p isomers) (CAS 1330-20-7) 500 LBS
US. Pennsylvania RTK - Hazardous Substances
1,2,4, Trimethylbenzene (CAS 95-63-6) Listed.
Benzene (CAS 71-43-2) Listed.
Cumene (CAS 98-82-8) Listed.
Cyclohexane (CAS 110-82-7) Listed.
Ethanol (CAS 64-17-5) Listed.
Ethylbenzene (CAS 100-41-4) Listed.
Gasoline (CAS 86290-81-5) Listed.
Hexane (Other Isomers) (CAS 96-14-0) Listed.
n-Heptane (CAS 142-82-5) Listed.
n-Hexane (CAS 110-54-3) Listed.
Octane (All isomers) (CAS 111-65-9) Listed.
Pentane (CAS 109-66-0) Listed.
Toluene (CAS 108-88-3) Listed.
Xylene (o, m, p isomers) (CAS 1330-20-7) Listed.
16. Other Information
Further information HMIS® is a registered trade and service mark of the NPCA.
Other information Note: This Material Safety Data Sheet applies to the listed products and synonym descriptions for Hazard Communication purposes only. Technical Specifications vary greatly depending on the products and are not reflected in this document. Consult specification sheets for technical information.
HMIS® ratings Health: 2*
Flammability: 3
Physical hazard: 0
NFPA ratings Health: 1
Flammability: 3
Instability: 0
Disclaimer This Material Safety Data Sheet (MSDS) was prepared in accordance with 29 CFR 1910.1200 by Valero Marketing & Supply Co., ("VALERO"). VALERO does not assume any liability arising out of product use by others. The information, recommendations, and suggestions presented in this MSDS are based upon test results and data believed to be reliable. The end user of the product has the responsibility for evaluating the adequacy of the data under the conditions of use, determining the safety, toxicity and suitability of the product under these conditions, and obtaining additional or clarifying information where uncertainty exists. No guarantee expressed or implied is made as to the effects of such use , the results to be obtained, or the safety and toxicity of the product in any specific application. Furthermore, the information herein is not represented as absolutely complete, since it is not practicable to provide all the scientific and study information in the format of this document, plus additional information may be necessary under exceptional conditions of use, or because of applicable laws or government regulations.
CPH MSDS NA
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ITEM 11.1. ATTACHMENT 3
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ITEM 11.1. ATTACHMENT 3
2 Nbufsjbm tbgfuz ebub tiffu - TLG Bvupnpujwf xiffm cfbsjoh hsfbtf Ifbmui xbsojoht; Joibmbujpo. Ifbujoh dbo hfofsbuf wbqpst uibu nbz dbvtf sftqjsbupsz jssjubujpo, obvtfb boe ifbebdift. Joibmbujpo ib{bse bu sppn ufnqfsbuvsf jt vomjlfmz evf up uif mpx wpmbujmjuz pg uijt qspevdu. Tljo dpoubdu. Sfqfbufe ps qspmpohfe dpoubdu dbo sftvmu jo eszjoh pg uif tljo. Fzf dpoubdu. Jssjubujoh. Johftujpo. Dbo dbvtf tupnbdi bdif boe wpnjujoh. Nbjo ib{bse, jg johftufe, jt btqjsbujpo joup uif mvoht boe tvctfrvfou qofvnpojujt.
Puifs jogpsnbujpo; Spvuf pg fousz; Joibmbujpo. Tljo boe/ps fzf dpoubdu. Johftujpo.
Nfejdbm tznqupnt; Nfejdbm dpoejujpot bhhsbwbufe cz fyqptvsf; Opu efufsnjofe
4. Gjstu bje nfbtvsft
Joibmbujpo; Wbqps joibmbujpo voefs bncjfou dpoejujpot jt opsnbmmz opu b qspcmfn. Jg pwfsdpnf cz wbqps pg ipu qspevdu, jnnfejbufmz sfnpwf gspn tpvsdf pg fyqptvsf. Npwf uif fyqptfe ^S`a]\ b] T`SaV OW` Ob ]\QS) @]` P`SObVW\U RWTlQcZbWSa ]fgUS\ [Og PS \SQSaaO`g) ASb nfejdbm buufoujpo jg boz ejtdpngpsu dpoujovft.
?gSa5 IW\aS bVS SgS eWbV eObS` W[[SRWObSZg) =]\bW\cS b] `W\aS T]` Ob ZSOab ,0 [W\cbSa) Dpoubdu qiztjdjbo jg ejtdpngpsu dpoujovft.
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Gmbnnbcjmjuz mjnju - mpxfs(%); O/E
Gmbnnbcjmjuz mjnju - vqqfs(%); O/E
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J^SQWOZ l`S lUVbW\U ^`]QSRc`Sa5 LaS eObS` b] YSS^ l`S Sf^]aSR Q]\bOW\S`a Q]]Z O\R RWa^S`aS dO^]`a) NObS` a^`Og [Og PS caSR b] mcaV a^WZZa OeOg T`][ Sf^]ac`Sa O\R RWZcbS a^WZZa b] \]\(mO[[OPZS [Wfbc`Sa) ;d]WR eObS` W\ ab`OWUVb V]aS ab`SO[6 eWZZ aQObbS` O\R a^`SOR l`S) DSS^ `c\(]TT eObS` ]cb ]T aSeS`a boe xbufs tpvsdft. Ejlf gps xbufs dpouspm.
L\cacOZ l`S $ Sf^Z]aW]\ VOhO`Ra5 H`Saac`S eWZZ W\Q`SOaS W\ ]dS` VSObSR' QZ]aSR Q]\bOW\S`a) Ib{bsepvt dpncvtujpo qspevdut; Bdsje tnplf/gvnft. Pyjeft pg; Dbscpo. Tvmgvs.
H`]bSQbWdS [SOac`Sa W\ QOaS ]T l`S5 JSZT(Q]\bOW\SR P`SObVW\U S_cW^[S\b O\R QVS[WQOZ `SaWabO\b QZ]bVW\U sfdpnnfoefe.
5KF
ITEM 11.1. ATTACHMENT 3
Nbufsjbm tbgfuz ebub tiffu - TLG Bvupnpujwf xiffm cfbsjoh hsfbtf 3
6. Bddjefoubm sfmfbtf nfbtvsft
Qfstpobm qsfdbvujpot; Njojnj{f tljo dpoubdu.
Qsfdbvujpot up qspufdu uif
fowjsponfou; Lffq qspevdu pvu pg tfxfst boe xbufsdpvstft cz ejljoh ps jnqpvoejoh. Bewjtf bvuipsjujft jg qspevdu ibt foufsfe ps nbz foufs tfxfst, xbufsdpvstft ps fyufotjwf mboe bsfbt. Bttvsf dpogpsnjuz xjui bqqmjdbcmf hpwfsonfou sfhvmbujpot.
Tqjmm dmfbo-vq qspdfevsft; Lffq bmm tpvsdft pg jhojujpo boe ipu nfubm tvsgbdft bxbz gspn tqjmm. Bwpje dpoubdu xjui fzft ps tljo. Qmbdf mfbljoh dpoubjofst jo xfmm wfoujmbufe bsfb. Jg l`S ^]bS\bWOZ SfWaba' PZO\YSb a^WZZ eWbV T]O[ ]` caS eObS` a^`Og b] RWa^S`aS wbqpst. Dpoubjo tqjmm up njojnj{f dpoubnjobufe bsfb boe gbdjmjubuf tbmwbhf ps RWa^]aOZ) K] QZSO\ c^ a^WZZ' mcaV O`SO a^O`W\UZg eWbV eObS` ]` caS OPa]`PO\b nbufsjbm. Bwpje ejtdibshf up obuvsbm xbufs xbzt.
7. Iboemjoh boe tupsbhf
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8. Fyqptvsf dpouspmt, qfstpobm qspufdujpo
Dpnqpofou TUE UXB TUFM UXB TUFM
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ITEM 11.1. ATTACHMENT 3
4 2 FYJ WNFQXFKJ Y^ IFYFXMJ J Y 80+&ZYTR TYN[J \ MJ J QGJ FWNSLLWJ FXJ 5WTYJ HYN[J J VZNUR J SY
*SLNSJ J WNSLHTSYWTQX : XJ J SLNSJ J WNSLHTSYWTQXYTWJ IZHJ FNWHTSYFR NSFYNTSYTUJ WR NXXNGQJ J ]UTXZWJ QJ [J Q MS\bWZObW]\5 F] a^SQWlQ dS\bWZObW]\ `S_cW`S[S\ba \]bSR' Pcb T]`QSR dS\bWZObW]\ [Og abWZZ PS WJ VZNWJ INKFNWHTSYFR NSFYNTSJ ]HJ J IXFHHJ UYFGQJ QJ [J Q ISa^W`Ob]`a5 F] a^SQWlQ `SQ][[S\RObW]\ [ORS' Pcb `Sa^W`Ob]`g ^`]bSQbW]\ [Og ab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- F_FWITZXIJ HTR UTXNYNTSUWTIZHYX 4]NIJ XTK ( FWGTS8ZQKZW 5KF
ITEM 11.1. ATTACHMENT 3
Nbufsjbm tbgfuz ebub tiffu - TLG Bvupnpujwf xiffm cfbsjoh hsfbtf 5
11. Upyjdpmphjdbm jogpsnbujpo
Upyjdpmphjdbm jogpsnbujpo; Op fyqfsjnfoubm upyjdpmphjdbm ebub po uif qsfqbsbujpo bt tvdi jt bwbjmbcmf.
12. Fdpmphjdbm jogpsnbujpo
Fdpmphjdbm jogpsnbujpo; Uifsf jt op fdpmphjdbm ebub po uif qspevdu jutfmg.
13. Ejtqptbm dpotjefsbujpot
Ejtqptbm nfuipet; Tqjmmfe nbufsjbm, vovtfe dpoufout boe fnquz dpoubjofst nvtu cf ejtqptfe pg jo bddpsebodf xjui mpdbm, tubuf boe gfefsbm sfhvmbujpot.
14. Usbotqpsu jogpsnbujpo
EPU ib{bse dmbtt; Opu sfhvmbufe.
CRS\bWlQObW]\ \])5 F*;
V.T. EPU ib{bse mbcfm; Op EPU mbcfm sfrvjsfnfou opufe
Tfb usbotqpsu opuft; Opu sfhvmbufe.
Bjs usbotqpsu opuft; Opu sfhvmbufe.
15. Sfhvmbupsz jogpsnbujpo
VT Gfefsbm sfhvmbujpot;
=][^]\S\b J;I; .+- =?I=E; J;I; .,.
Ejtujmmbuft, qfuspmfvn, tfwfsfmz izespusfbufe ifbwz obqiuifojd O/B O/B O/B >WabWZZObSa' ^Sb`]ZSc[' a]ZdS\b(RSeOfSR VSOdg ^O`OTl\WQ F*; F*; F*; Qfuspmfvn ejtujmmbuft
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ITEM 11.1. ATTACHMENT 3
6 Nbufsjbm tbgfuz ebub tiffu - TLG Bvupnpujwf xiffm cfbsjoh hsfbtf Xpslqmbdf ib{bsepvt nbufsjbmt jogpsnbujpo tztufn - XIJNJT; Jowfoupsjft
Dpnqpofou DBO VT FV BVT KBQ LPS DIO QIMQ
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Ejtujmmbuft, qfuspmfvn, tpmwfou-efxbyfe ETM Zft OBW OBW OBW OBW OBW OBW BSOdg ^O`OTl\WQ ^Sb`]ZSc[ RWabWZZObSa
Sftjevbm pjmt, qfuspmfvn, ETM Zft FJOFDT Zft Op Zft OBW Zft a]ZdS\b(`Sl\SR
16. Puifs jogpsnbujpo
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TLG sftfswft uif sjhiu up bmufs boz qbsu pg uijt qvcmjdbujpo xjuipvu qsjps opujdf.
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xxx.wtn.tlg.dpn
5KF
ITEM 11.1. ATTACHMENT 3
Fuels, diesel
DMA LS, Marine Distillate Fuels, Ultra Low Sulfur No. 2 Diesel Fuel
SAFETY DATA SHEET
Product name
Other means of
identification
Section 1. Identification
SDS #
Product use Fuel for marine engines.
Code SMF2115
Supplier BP Products North America Inc.
150 West Warrenville Road
Naperville, Illinois 60563-8460
USA
EMERGENCY HEALTH
INFORMATION:
1 (800) 447-8735
Outside the US: +1 703-527-3887 (CHEMTREC)
EMERGENCY SPILL
INFORMATION:
1 (800) 424-9300 CHEMTREC (USA)
OTHER PRODUCT
INFORMATION
1 (866) 4 BP - MSDS
(866-427-6737 Toll Free - North America)
email: [email protected]
SMF2115
Relevant identified uses of the substance or mixture and uses advised against Section 2. Hazards identification
FLAMMABLE LIQUIDS - Category 4
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 ASPIRATION HAZARD - Category 1
Classification of the
substance or mixture
Signal word Danger
Hazard statements Combustible liquid.
Harmful if inhaled.
Causes skin irritation.
Suspected of causing cancer.
May be fatal if swallowed and enters airways.
May cause damage to organs through prolonged or repeated exposure.
Hazard pictograms
Precautionary statements
GHS label elements
OSHA/HCS status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Date of issue 10/07/2014.
Fuels, diesel Page: 1/15
ENGLISH
(ENGLISH)
Product name Product code
Version 1 Format US Language
SMF2115
(US)
,..
,..
ITEM 11.1. ATTACHMENT 3
Section 2. Hazards identification
Prevention Obtain special instructions before use.
Wear protective gloves and eye protection.
Do not breathe vapor.
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Use explosion-proof electrical/ventilating/lighting/material-handling equipment.
Avoid release to the environment.
Response IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
Do NOT induce vomiting.
IF ON SKIN: Wash with plenty of soap and water.
Take off contaminated clothing and wash it before reuse.
Storage Keep cool.
Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations.
Hazards not otherwise
classified
This material may contain significant quantities of polycyclic aromatic hydrocarbons (PAHs), some of which have been shown by experimental studies to induce skin cancer.
Note: High Pressure Applications
Injections through the skin resulting from contact with the product at high pressure constitute a major medical emergency.
See 'Notes to physician' under First-Aid Measures, Section 4 of this Safety Data Sheet.
Section 3. Composition/information on ingredients
There are no ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Substance/mixture
Occupational exposure limits, if available, are listed in Section 8.
Mixture
May also contain small quantities of proprietary performance additives.
Fuels, diesel, No 2 68476-34-6 > 99
Contains:
naphthalene 91-20-3 1 - 3
Ingredient name CAS number %
Do not induce vomiting. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately.
Aspiration hazard if swallowed. Can enter lungs and cause damage. Get medical attention immediately.
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
Eyelids should be held away from the eyeball to ensure thorough rinsing. Check for and remove any contact lenses. Get medical attention.
If inhaled, remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Get medical attention.
Section 4. First aid measures
Eye contact
Inhalation
Ingestion
Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Description of necessary first aid measures
See Section 11 for more detailed information on health effects and symptoms.
Most important symptoms/effects, acute and delayed
Skin contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention.
Date of issue 10/07/2014.
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ENGLISH
(ENGLISH)
Product name Product code
Version 1 Format US Language
SMF2115
(US)
ITEM 11.1. ATTACHMENT 3
Section 4. First aid measures
Notes to physician Treatment should in general be symptomatic and directed to relieving any effects.
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal intubation. Monitor for cardiac dysrhythmias.
Note: High Pressure Applications
Injections through the skin resulting from contact with the product at high pressure constitute a major medical emergency. Injuries may not appear serious at first but within a few hours tissue becomes swollen, discolored and extremely painful with extensive subcutaneous necrosis.
Surgical exploration should be undertaken without delay. Thorough and extensive debridement of the wound and underlying tissue is necessary to minimize tissue loss and prevent or limit permanent damage. Note that high pressure may force the product considerable distances along tissue planes.
Specific treatments No specific treatment.
Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. This material is toxic to aquatic organisms.
Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.
Hazardous combustion
products
Specific hazards arising
from the chemical
Combustion products may include the following:
carbon oxides (CO, CO2) (carbon monoxide, carbon dioxide) other hazardous substances.
Combustible liquid. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard.
Fire-fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full turnout gear.
Special protective
equipment for fire-fighters
In case of fire, use foam, dry chemical or carbon dioxide extinguisher or spray.
Extinguishing media
Do not use water jet.
Suitable extinguishing
media
Unsuitable extinguishing
media
Special protective actions
for fire-fighters
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures Immediately contact emergency personnel. No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Put on appropriate personal protective equipment.
Floors may be slippery; use care to avoid falling. Eliminate all ignition sources.
For non-emergency
personnel
For emergency responders Entry into a confined space or poorly ventilated area contaminated with vapor, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work. Wear self-contained breathing apparatus. Wear a suitable chemical protective suit. Chemical resistant boots. See also the information in "For nonemergency personnel".
Date of issue 10/07/2014.
Fuels, diesel Page: 3/15
ENGLISH
(ENGLISH)
Product name Product code
Version 1 Format US Language
SMF2115
(US)
ITEM 11.1. ATTACHMENT 3
Section 6. Accidental release measures
Environmental precautions
Eliminate all ignition sources. Stop leak if without risk. Move containers from spill area.
Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Dike spill area and do not allow product to reach sewage system and surface or ground water. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Use spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pose the same hazard as the spilled product. The method and equipment used must be in conformance with appropriate regulations and industry practice on explosive atmospheres. Dispose of via a licensed waste disposal contractor.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities.
Large spill
Eliminate all ignition sources. Stop leak if without risk. Move containers from spill area.
Absorb with an inert material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. The method and equipment used must be in conformance with appropriate regulations and industry practice on explosive atmospheres.
Small spill
Methods and materials for containment and cleaning up
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Wash thoroughly after handling. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Store and use only in equipment/ containers designed for use with this product. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.
Light hydrocarbon vapors can build up in the headspace of tanks. These can cause flammability/explosion hazards even at temperatures below the normal flash point (note:
flash point must not be regarded as a reliable indicator of the potential flammability of vapor in tank headspaces). Tank headspaces should always be regarded as potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging and sampling from storage tanks. Do not enter storage tanks. If entry to vessels is necessary, follow permit to work procedures. Entry to any tanks or other confined space requires a full risk assessment and appropriate control measures to be put in place in conformance with appropriate regulations and industry practice on confined space entry. When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static discharge. Ensure Protective measures Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Avoid contact of spilled material and runoff with soil and surface waterways. Empty containers retain product residue and can be hazardous.
Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Do not reuse container. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Do not breathe vapor or mist. Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not swallow. Aspiration hazard if swallowed. Can enter lungs and cause damage. Never siphon by mouth.
Precautions for safe handling
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ITEM 11.1. ATTACHMENT 3
Section 7. Handling and storage
equipment used is properly earthed or bonded to the tank structure. Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks).
Explosive air/vapor mixtures may form at ambient temperature. If product comes into contact with hot surfaces, or leaks occur from pressurized fuel pipes, the vapor or mists generated will create a flammability or explosion hazard. Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be allowed to accumulate. Dispose of safely immediately after use.
Fuels, diesel, No 2 ACGIH TLV (United States). Absorbed through skin.
TWA: 100 mg/m³, (measured as total
hydrocarbons) 8 hours. Issued/Revised:
1/2007 Form: Inhalable fraction and vapor
naphthalene ACGIH TLV (United States). Absorbed
through skin.
TWA: 52 mg/m³ 8 hours. Issued/Revised:
5/1996
TWA: 10 ppm 8 hours. Issued/Revised:
5/1996
OSHA PEL (United States).
TWA: 50 mg/m³ 8 hours. Issued/Revised:
6/1993
TWA: 10 ppm 8 hours. Issued/Revised:
6/1993
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Eye/face protection Chemical splash goggles.
Environmental exposure
controls
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
All activities involving chemicals should be assessed for their risks to health, to ensure exposures are adequately controlled. Personal protective equipment should only be considered after other forms of control measures (e.g. engineering controls) have been suitably evaluated. Personal protective equipment should conform to appropriate standards, be suitable for use, be kept in good condition and properly maintained.
Your supplier of personal protective equipment should be consulted for advice on selection and appropriate standards. For further information contact your national organisation for standards.
Provide exhaust ventilation or other engineering controls to keep the relevant airborne concentrations below their respective occupational exposure limits.
The final choice of protective equipment will depend upon a risk assessment. It is important to ensure that all items of personal protective equipment are compatible.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures
Control parameters
Individual protection measures
Occupational exposure limits
Skin protection
While specific OELs for certain components may be shown in this section, other components may be present in any mist, vapor or dust produced. Therefore, the specific OELs may not be applicable to the product as a whole and are provided for guidance only.
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ITEM 11.1. ATTACHMENT 3
Section 8. Exposure controls/personal protection
Hand protection
Use only with adequate ventilation. Do not breathe vapor or mist. If ventilation is inadequate, use a NIOSH certified respirator with an organic vapor cartridge and P95 particulate filter. If operating conditions cause high vapor concentrations or the TLV is exceeded, use supplied-air respirator.
CAUTION: The protection provided by air-purifying respirators is limited. Use a positive pressure air-supplied respirator if there is any potential for an uncontrolled release, if exposure levels are not known, or if concentrations exceed the protection limits of airpurifying respirator.
Use with adequate ventilation.
In case of insufficient ventilation, wear suitable respiratory equipment.
If there is a requirement for the use of a respiratory protective device, but the use of breathing apparatus (independent of ambient atmosphere) is not required, then a suitable filtering device must be worn.
The filter class must be suitable for the maximum contaminant concentration (gas/vapor/ aerosol/particulates) that may arise when handling the product.
The correct choice of respiratory protection depends upon the chemicals being handled, the conditions of work and use, and the condition of the respiratory equipment. Safety procedures should be developed for each intended application. Respiratory protection equipment should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions.
Wear chemical resistant gloves. Recommended: Nitrile gloves.
Do not re-use gloves. Protective gloves must give suitable protection against mechanical risks (i.e. abrasion, blade cut and puncture). Protective gloves will deteriorate over time due to physical and chemical damage. Inspect and replace gloves on a regular basis. The frequency of replacement will depend upon the circumstances of use.
Respiratory protection
Body protection Use of protective clothing is good industrial practice. Cotton or polyester/cotton overalls will only provide protection against light superficial contamination that will not soak through to the skin. Overalls should be laundered on a regular basis. When the risk of skin exposure is high (e.g. when cleaning up spillages or if there is a risk of splashing) then chemical resistant aprons and/or impervious chemical suits and boots will be required. Wear suitable protective clothing. Footwear highly resistant to chemicals.
When there is a risk of ignition from static electricity, wear anti-static protective clothing.
For greatest effectiveness against static electricity, overalls, boots and gloves should all be anti-static. When there is a risk of ignition wear inherently fire resistant protective clothes and gloves. Work clothing / overalls should be laundered on a regular basis.
Laundering of contaminated work clothing should only be done by professional cleaners who have been told about the hazards of the contamination. Always keep contaminated work clothing away from uncontaminated work clothing and uncontaminated personal clothes. When the risk of skin exposure is high (from experience this could apply to the following tasks: cleaning work, maintenance and service, filling and transfer, taking samples and cleaning up spillages) then a chemical protective suit and boots will be required. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Consult your supervisor or Standard Operating Procedure (S.O.P) for special handling instructions.
Section 9. Physical and chemical properties
Physical state Liquid.
Odor Kerosene
pH
Color Yellow. [Light]
Not available.
Odor threshold Not available.
Appearance
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ITEM 11.1. ATTACHMENT 3
Section 9. Physical and chemical properties
Melting point
Vapor pressure
Vapor density
Not available.
Not available.
<0.266 kPa (<2 mm Hg) at 20°C
Evaporation rate Not available.
Auto-ignition temperature
Flash point
257°C (494.6°F)
Closed cup: >60°C (>140°F)
Not available.
Viscosity Dynamic: 0.003 Pa·s (3 cP) at 37.778°C
Kinematic: 2 to 11 mm2/s (2 to 11 cSt) at 40°C
Partition coefficient: noctanol/water
Boiling point 162.78°C (325°F)
Flammability (solid, gas)
Lower and upper explosive
(flammable) limits
Lower: 0.7%
Upper: 5%
Decomposition temperature Not available.
Density
Solubility
860 kg/m³ (0.86 g/cm³)
negligible <0.1%
Not applicable. Based on - Physical state
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
Chemical stability The product is stable.
Incompatible materials
Possibility of hazardous
reactions
Under normal conditions of storage and use, hazardous reactions will not occur.
Under normal conditions of storage and use, hazardous polymerization will not occur.
Reactivity No specific test data available for this product. Refer to Conditions to avoid and Incompatible materials for additional information.
Keep away from heat, sparks and flame. Avoid all possible sources of ignition (spark or flame).
Reactive or incompatible with the following materials: oxidizing materials, acids and alkalis.
halogenated compounds.
Section 11. Toxicological information
Information on toxicological effects
Acute toxicity
Fuels, diesel, No 2 LC50 Inhalation
Dusts and mists
Rat 4.1 mg/l 4 hours Based on Diesel
fuel
LD50 Dermal Rabbit >4300 mg/kg - Based on No. 2
Heating Oil.
LD50 Dermal Rabbit >4300 mg/kg - Based on Diesel
fuel
LD50 Oral Rat 17900 mg/kg - Based on No. 2
Heating Oil.
LD50 Oral Rat 7600 mg/kg - Based on Diesel
Product/ingredient
name
Test Species Result Exposure Remarks
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ITEM 11.1. ATTACHMENT 3
Section 11. Toxicological information
naphthalene - 2B Reasonably anticipated to be a human carcinogen.
Product/ingredient name OSHA IARC NTP
Classification
fuel
Conclusion/Summary Not available.
Carcinogenicity
Fuels, diesel, No 2 Mouse Dermal Positive -
Dermal -
Unspecified
2 years - Based on
Heating Oil.
Product/ingredient
name
Species Exposure Test Result
Conclusion/Summary Suspected of causing cancer.
Mutagenicity
Fuels, diesel, No 2 OECD 471 Experiment: In vitro Positive Based on Diesel fuel Subject: Nonmammalian species
Equivalent to OECD
476
Experiment: In vitro Negative Based on Heating
Oil.
Subject:
Mammalian-Animal
Cell: Germ
not guideline Experiment: In vivo Negative Based on Heating Oil.
Subject: Unspecified
Cell: Somatic
Product/ingredient name Test Experiment Result
Conclusion/Summary Not classified. Based on available data, the classification criteria are not met.
Irritation/Corrosion
Fuels, diesel, No 2 Rabbit Skin -
Irritation
- - - - Based on No.
2 Heating Oil.
Rabbit Skin -
Irritation
- - - - Based on
Diesel fuel
Rabbit Eyes - Nonirritating to
the eyes.
- - - - Based on No.
2 Heating Oil.
Rabbit Eyes - Nonirritating to
the eyes.
- - - - Based on
Diesel fuel
Product/ingredient
name
Result Score Exposure Observation
Sensitizer
Fuels, diesel, No 2 skin Guinea pig Not sensitizing Based on No. 2 Heating Oil.
skin Guinea pig Not sensitizing Based on Diesel
fuel
Product/ingredient name Route of
exposure
Species Result
Species Remarks
Remarks
Route Remarks
Remarks
Conc.
Reproductive toxicity
IARC :
2B - Possible carcinogen to human.
NTP :
Possible - Reasonably anticipated to be human carcinogens.
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ITEM 11.1. ATTACHMENT 3
Section 11. Toxicological information
Information on the likely
routes of exposure
Irritating to mouth, throat and stomach. Aspiration hazard if swallowed -- harmful or fatal if liquid is aspirated into lungs.
Ingestion
Skin contact Causes skin irritation.
Eye contact No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics Skin contact
Ingestion Adverse symptoms may include the following:
nausea or vomiting
Adverse symptoms may include the following:
irritation
redness
Eye contact Adverse symptoms may include the following:
pain or irritation
watering
redness
Delayed and immediate effects and also chronic effects from short and long term exposure Specific target organ toxicity (repeated exposure)
Name Category
Fuels, diesel, No 2 Category 2 Not determined Not determined Aspiration hazard
Name Result
Fuels, diesel, No 2 ASPIRATION HAZARD - Category 1
Route of
exposure
Target organs
Routes of entry anticipated: Oral, Dermal, Inhalation.
Potential acute health effects
Potential immediate
effects
Vapor, mists or fumes may contain polycyclic aromatic hydrocarbons some of which are known to produce skin cancer. May be harmful by inhalation if exposure to vapor, mists or fumes resulting from thermal decomposition products occurs. Vapor, mist or fume may irritate the nose, mouth and respiratory tract. Vapor, mist or fume may cause eye irritation. Exposure to vapor, mist or fume may cause stinging, redness and watering of the eyes.
Short term exposure
Potential delayed effects As with all such products containing potentially harmful levels of PCAs, prolonged or repeated skin contact may eventually result in dermatitis or more serious irreversible skin disorders including cancer.
Product/ingredient name Maternal
toxicity
Fertility Development
toxin
Species Result Exposure
Fuels, diesel, No 2 - - Negative Rat Dermal 20 days
- - Negative Rat Dermal 10 days
- - Negative Rat Dermal 10 days
Conclusion/Summary Development: Not classified. Based on available data, the classification criteria are not met.
Fertility: Not classified. Based on available data, the classification criteria are not met.
Effects on or via lactation: Not classified. Based on available data, the classification criteria are not met.
Inhalation Harmful if inhaled.
Inhalation Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
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ITEM 11.1. ATTACHMENT 3
Section 11. Toxicological information
May cause damage to organs through prolonged or repeated exposure. Vapor, mists or fumes may contain polycyclic aromatic hydrocarbons some of which are known to produce skin cancer.
General
Carcinogenicity Suspected of causing cancer. Risk of cancer depends on duration and level of exposure.
Mutagenicity No known significant effects or critical hazards.
Teratogenicity No known significant effects or critical hazards.
Developmental effects No known significant effects or critical hazards.
Fertility effects No known significant effects or critical hazards.
Potential chronic health effects
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Potential immediate
effects
Not available.
Long term exposure
Potential delayed effects Not available.
Aspiration of this product into the lungs can cause chemical pneumonia and can be fatal.
Aspiration into the lungs can occur while vomiting after ingestion of this product. Do not siphon by mouth.
Other information
Additional information Middle distillate: From skin-painting studies of petroleum distillates of similar composition and distillate range, it has been shown that these types of materials often possess weak carcinogenic activity in laboratory animals. In these tests, the material is painted on the shaved backs of mice twice a week for their lifetime. The material is not washed off between applications. Therefore, there may be a potential risk of skin cancer from prolonged or repeated skin contact with this product in the absence of good personal hygiene. This particular product has not been tested for carcinogenic activity, but we have chosen to be cautious in light of the findings with other distillate streams.
Occasional skin contact with this product is not expected to have serious effects, but good personal hygiene should be practiced and repeated skin contact avoided. This product can also be expected to produce skin irritation upon prolonged or repeated skin contact. Personal hygiene measures taken to prevent skin irritation are expected to be adequate to prevent risk of skin cancer.
Diesel exhaust particulates have been classified by the National Toxicological Program (NTP) to be a reasonably anticipated human carcinogen. Exposure should be minimized to reduce potential risk.
Naphthalene has been reported to cause developmental toxicity in mice after oral exposure to relatively high dose levels, but developmental toxicity was not observed in NTP (National Toxicology Program) sponsored studies in rats and rabbits. Ingestion or inhalation of naphthalene can result in hemolysis and other blood abnormalities, and individuals (and infants) deficient in glucose-6-phosphate dehydrogenase may be especially susceptible to these effects. Inhalation of naphthalene may cause headache and nausea. Airborne exposure can result in eye irritation. Naphthalene exposure has been associated with cataracts in animals and humans.
Section 12. Ecological information
Toxicity
Product/ingredient nameSpecies Test/Result Exposure Effects Remarks Date of issue 10/07/2014.
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ITEM 11.1. ATTACHMENT 3
Section 12. Ecological information
Persistence and degradability
Not available.
Fuels, diesel, No 2 Micro-organism EL50 >1000 mg/l
Nominal Fresh
water
40 hours growth inhibition Based on
Vacuum gas oil /
Hydrocracked
gas oil / Distillate
Fuel
Micro-organism NOELR 3.217 mg/
l Nominal Fresh
water
40 hours growth inhibition Based on
Vacuum gas oil /
Hydrocracked
gas oil / Distillate
Fuel
Algae Acute EL50 22
mg/l Nominal
Fresh water
72 hours (growth rate) Based on Diesel
fuel
Daphnia Acute EL50 210
mg/l Nominal
Fresh water
48 hours Mobility Based on Diesel
fuel
Daphnia Acute EL50 68
mg/l Nominal
Fresh water
48 hours Mobility Based on Diesel
fuel
Algae Acute ErL50 78
mg/l Nominal
Fresh water
72 hours (growth rate) Based on Diesel
fuel
Fish Acute LL50 65
mg/l Nominal
Fresh water
96 hours Mortality Based on Diesel
fuel
Fish Acute LL50 21
mg/l Nominal
Fresh water
96 hours Mortality Based on Diesel
fuel
Algae Acute NOELR 10
mg/l Nominal
Fresh water
72 hours (growth rate) Based on Diesel
fuel
Algae Acute NOELR 1
mg/l Nominal
Fresh water
72 hours (growth rate) Based on Diesel
fuel
Daphnia Acute NOELR 46
mg/l Nominal
Fresh water
48 hours Mobility Based on Diesel
fuel
Fish Chronic NOEL 0.
083 mg/l Nominal
Fresh water
14 days Mortality Based on
Vacuum gas oil /
Hydrocracked
gas oil / Distillate
Fuel
Daphnia Chronic NOELR
0.2 mg/l Nominal
Fresh water
21 days Immobilization Based on
Vacuum gas oil /
Hydrocracked
gas oil / Distillate
Fuel
Conclusion/Summary Not available.
Product/ingredient name Test Result Remarks
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ITEM 11.1. ATTACHMENT 3
Section 12. Ecological information
Mobility Spillages may penetrate the soil causing ground water contamination. This material may accumulate in sediments.
Bioaccumulative potential
Other adverse effects No known significant effects or critical hazards.
Conclusion/Summary Not available.
Soil/water partition
coefficient (KOC)
Not available.
Mobility in soil
This product is not expected to bioaccumulate through food chains in the environment.
Other ecological information Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be impaired.
Fuels, diesel, No 2 OECD 301 F 60 % - Readily - 28 days Based on Diesel fuel OECD 301 F 57.5 % - Not readily - 28 days Based on Diesel fuel Equivalent to
EPA OTS 796.
3100
35 % - Not readily - 28 days Based on Gas Oils (petroleum), solvent refined
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.
Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Disposal methods
United States - RCRA Toxic hazardous waste "U" List
Naphthalene 91-20-3 Listed U165
Ingredient CAS # Status Reference
number
Section 14. Transport information
DIESEL FUEL
MARINE
POLLUTANT
DIESEL FUEL
NA 1993 UN1202 UN1202
DOT
Classification
IMDG IATA
UN number
UN proper
shipping name
TDG
Classification
UN 1202
DIESEL FUEL DIESEL FUEL
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ITEM 11.1. ATTACHMENT 3
Section 14. Transport information
Combustible
liquid.
III
3 III
3 III
Non-bulk
packages (less
than or equal
to 119 gal) of
combustible
liquids are not
regulated as
hazardous
materials in
package sizes
less than the
product
reportable
quantity.
Reportable
quantity
3333.3 lbs /
1513.3 kg [464.
86 gal / 1759.7
L]
Package sizes
shipped in
quantities less
than the
product
reportable
quantity are not
subject to the
RQ (reportable
quantity)
transportation
requirements.
The marine
pollutant mark
is not required
when
transported in
sizes of ≤5 L or
≤5 kg.
Emergency
schedules
(EmS)
F-E, S-E
The
environmentally
hazardous
substance
mark may
appear if
required by
other
transportation
regulations.
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL
73/78 and the IBC Code
No. Yes. No.
Not available.
MARPOL Annex 1 rules apply for bulk shipments by
sea.
Category: gas oils, including ship's bunkers
Proper shipping name
3 III
No.
-
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i>
-
ITEM 11.1. ATTACHMENT 3
Section 15. Regulatory information
U.S. Federal regulations
Massachusetts The following components are listed: NAPHTHALENE SARA 313
Product name CAS number Concentration
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed. naphthalene 91-20-3 1 - 3
naphthalene 91-20-3 1 - 3
Form R - Reporting
requirements
Supplier notification
New Jersey The following components are listed: NAPHTHALENE; MOTH FLAKES Pennsylvania The following components are listed: NAPHTHALENE State regulations
SARA 302/304
No products were found.
Composition/information on ingredients
SARA 311/312
Classification Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
Other regulations
United States inventory All components are listed or exempted. (TSCA 8b)
At least one component is not listed.
All components are listed or exempted.
Not determined.
All components are listed or exempted.
At least one component is not listed.
China inventory (IECSC)
Japan inventory (ENCS)
Korea inventory (KECI)
Philippines inventory
(PICCS)
Australia inventory (AICS)
California Prop. 65 WARNING: This product contains a chemical known to the State of California to cause cancer.
naphthalene; ethylbenzene; cumene
WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm.
toluene
WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm.
Benzene
Prop 65 chemicals will result under certain conditions from the use of this material. For example, burning fuels produces combustion products including diesel exhaust, a Prop 65 carcinogen, and carbon monoxide, a Prop 65 reproductive toxin.
Canada inventory All components are listed or exempted.
REACH Status For the REACH status of this product please consult your company contact, as identified in Section 1.
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ITEM 11.1. ATTACHMENT 3
Section 16. Other information
History
Date of issue/Date of
revision
Notice to reader
Date of previous issue
Indicates information that has changed from previously issued version.
Key to abbreviations ACGIH = American Conference of Industrial Hygienists ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
CAS Number = Chemical Abstracts Service Registry Number GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) OEL = Occupational Exposure Limit
SDS = Safety Data Sheet
STEL = Short term exposure limit
TWA = Time weighted average
UN = United Nations
UN Number = United Nations Number, a four digit number assigned by the United Nations Committee of Experts on the Transport of Dangerous Goods. 10/07/2014.
10/03/2014.
Hazardous Material Information System (U.S.A.)
2 2
0 0
2 2
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.
All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the accuracy or completeness of the data and information in this data sheet.
The data and advice given apply when the product is sold for the stated application or applications. You should not use the product other than for the stated application or applications without seeking advice from BP Group.
It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. The BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material.
Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions that should be taken. You can contact the BP Group to ensure that this document is the most current available. Alteration of this document is strictly prohibited.
Personal protection X
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ITEM 11.1. ATTACHMENT 3
SAFETY DATA SHEET
1. Identification
Product identifier RemOx® S ISCO Reagent
Other means of identification Not available.
Recommended use Remediation of soils and groundwater.
Recommended restrictions Use in accordance with supplier's recommendations.
Manufacturer / Importer / Supplier / Distributor information Manufacturer/Supplier CARUS CORPORATION
Address 315 Fifth Street,
Peru, IL 61354, USA
Telephone 815 223-1500 - All other non-emergency inquiries about the product should be directed to the company
E-mail [email protected]
Website www.caruscorporation.com
Contact person Dr. Chithambarathanu Pillai
Emergency Telephone For Hazardous Materials [or Dangerous Goods] Incidents ONLY (spill, leak, fire, exposure or accident), call CHEMTREC at CHEMTREC®, USA: 001 (800) 424-9300
CHEMTREC®, Mexico (Toll-Free - must be dialed from within country):
01-800-681-9531
CHEMTREC®, Other countries: 001 (703) 527-3887
2. Hazard(s) identification
Physical hazards Oxidizing solids Category 2
Health hazards Acute toxicity, oral Category 4
Skin corrosion/irritation Category 1B
Specific target organ toxicity, single exposure Category 1 (Respiratory System) Category 1 (Respiratory System, central
nervous system)
Specific target organ toxicity, repeated
exposure
OSHA defined hazards Not classified.
Label elements
Signal word Danger
Hazard statement May intensify fire; oxidizer. Harmful if swallowed. Causes severe skin burns and eye damage.
Causes damage to organs (Respiratory System). Causes damage to organs (Respiratory System, central nervous system) through prolonged or repeated exposure.
Precautionary statement
Prevention Keep away from heat. Take any precaution to avoid mixing with combustibles/ Keep/Store away from clothing//combustible materials. Wash thoroughly after handling. Do not breathe dust. Wear protective gloves/protective clothing/eye protection/face protection. Do not eat, drink or smoke when using this product.
Response In case of fire: Use water for extinction. If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor.
Storage Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise Not classified.
classified (HNOC)
Hazardous to the aquatic environment, Category 1
long-term hazard
Environmental hazards
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ITEM 11.1. ATTACHMENT 3
3. Composition/information on ingredients
Substances
Potassium permanganate 7722-64-7 > 97.5
Common name and CAS number
synonyms
Chemical name %
Composition comments All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
4. First-aid measures
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. For breathing difficulties, oxygen may be necessary. Get medical attention immediately.
Skin contact Take off immediately all contaminated clothing. Immediately flush skin with plenty of water. Get medical attention immediately. Wash contaminated clothing before reuse.
Contact with skin may leave a brown stain of insoluble manganese dioxide. This can be easily removed by washing with a mixture of equal volume of household vinegar and 3% hydrogen peroxide, followed by washing with soap and water.
Eye contact Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyelids wide apart. Continue rinsing. Get medical attention immediately.
Ingestion Immediately rinse mouth and drink plenty of water. Never give anything by mouth to a victim who is unconscious or is having convulsions. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Get medical attention immediately.
Most important
symptoms/effects, acute and
delayed
Contact with this material will cause burns to the skin, eyes and mucous membranes. Permanent eye damage including blindness could result.
Indication of immediate
medical attention and special
treatment needed
Provide general supportive measures and treat symptomatically. In case of shortness of breath, give oxygen. Decomposition products are alkaline. Brown stain is insoluble manganese dioxide.
General information In the case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.
5. Fire-fighting measures
Suitable extinguishing media Flood with water from a distance, water spray or fog.
Unsuitable extinguishing
media
The following extinguishing media are ineffective: Dry chemical. Foam. Carbon dioxide (CO2).
Halogenated materials.
Specific hazards arising from
the chemical
May intensify fire; oxidizer. May ignite combustibles (wood, paper, oil, clothing, etc.). Contact with incompatible materials or heat (135 ºC / 275 ºF) could result in violent exothermic chemical reaction. Oxidizing agent, may cause spontaneous ignition of combustible materials. By heating and fire, corrosive vapors/gases may be formed.
Special protective equipment
and precautions for firefighters
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Selection of respiratory protection for firefighting: follow the general fire precautions indicated in the workplace.
Fire-fighting
equipment/instructions
Move container from fire area if it can be done without risk. Cool containers exposed to flames with water until well after the fire is out. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Dike fire control water for later disposal. Water runoff can cause environmental damage.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Keep unnecessary personnel away. Keep upwind. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Avoid inhalation of vapors and contact with skin and eyes. Wear protective clothing as described in Section 8 of this safety data sheet. Local authorities should be advised if significant spillages cannot be contained.
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Methods and materials for
containment and cleaning up
Keep combustibles (wood, paper, oil, etc.) away from spilled material. Should not be released into the environment. This product is miscible in water. Stop leak if possible without any risk. Dike the spilled material, where this is possible. Clean up spills immediately by sweeping or shoveling up the material. Do not return spilled material to the original container; transfer to a clean metal or plastic drum. To clean up potassium permanganate solutions, follow either of the following two options:
Option # 1: Dilute to approximately 6% with water, and then reduce with sodium thiosulfate, a bisulfite or ferrous salt solution. The bisulfite or ferrous salt may require some dilute sulfuric acid (10% w/w) to promote reduction. Neutralize with sodium carbonate to neutral pH, if acid was used.
Decant or filter and deposit sludge in approved landfill. Where permitted, the sludge may be drained into sewer with large quantities of water.
Option # 2: Absorb with inert media like diatomaceous earth or inert floor dry, collect into a drum and dispose of properly. Do not use saw dust or other incompatible media. Disposal of all materials shall be in full and strict compliance with all federal, state, and local regulations pertaining to permanganates.
To clean contaminated floors, flush with abundant quantities of water into sewer, if permitted by federal, state, and local regulations. If not, collect water and treat as described above.
Never return spills in original containers for re-use. For waste disposal, see Section 13 of the MSDS.
Environmental precautions Do not allow to enter drains, sewers or watercourses. Contact local authorities in case of spillage to drain/aquatic environment.
7. Handling and storage
Precautions for safe handling Take any precaution to avoid mixing with combustibles. Keep away from clothing and other combustible materials. Do not get this material in your eyes, on your skin, or on your clothing. Do not breathe dust or mist or vapor of the solution. If clothing becomes contaminated, remove and wash off immediately. When using, do not eat, drink or smoke. Good personal hygiene is necessary. Wash hands and contaminated areas with water and soap before leaving the work site.
Avoid release to the environment.
Conditions for safe storage,
including any incompatibilities
Store locked up. Keep container tightly closed and in a well-ventilated place. Store in a cool, dry place. Store away from incompatible materials (See Section 10). Follow applicable local/national/international recommendations on storage of oxidizers. Store in accordance with NFPA 430 requirements for Class II oxidizers.
Before using, read Material Safety Data Sheet (MSDS) for this product.
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value
Potassium permangana te Ceiling 5 mg/m3
(CAS 7722-64-7)
US. ACGIH Threshold Limit Values
Components Type Value
Potassium permangana te TWA 0.2 mg/m3
(CAS 7722-64-7)
US NIOSH Pocket Guide to Chemical Hazards: Recommended exposure limit (REL) Components Type Value Form
Potassium permangana te TWA 1 mg/m3 Fume.
(CAS 7722-64-7)
US NIOSH Pocket Guide to Chemical Hazards: Short Term Exposure Limit (STEL) Components Type Value Form
Potassium permangana te STEL 3 mg/m3 Fume.
(CAS 7722-64-7)
Biological limit values No biological exposure limits noted for the ingredient(s).
Exposure guidelines Follow standard monitoring procedures.
Appropriate engineering
controls
Provide adequate general and local exhaust ventilation. An eye wash and safety shower must be available in the immediate work area.
Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Wear face shield if there is risk of splashes.
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Skin protection
Hand protection Use protective gloves made of: Rubber or plastic. Suitable gloves can be recommended by the glove supplier.
Other Wear chemical-resistant, impervious gloves.
Respiratory protection In case of inadequate ventilation or risk of inhalation of dust, use suitable respiratory equipment with particle filter. In the United States of America, if respirators are used, a program should be instituted to assure compliance with OSHA 29 CFR 1910.134.
Measurement Element: Manganese (Mn)
10 mg/m3
Any particulate respirator equipped with an N95, R95, or P95 filter (including N95, R95, and P95 filtering facepieces) except quarter-mask respirators. The following filters may also be used: N99, R99, P99, N100, R100 or P100.
Any supplied-air respirator.
25 mg/m3
Any supplied-air respirator operated in a continuous-flow mode.
Any powered, air-purifying respirator with a high-efficiency particulate filter. 50 mg/m3
Any air-purifying, full-face piece respirator equipped with an N100, R100, or P100 filter.
Any supplied-air respirator with a tight-fitting face piece that is operated in a continuous-flow mode.
Any powered, air-purifying respirator with a tight-fitting face piece and a high-efficiency particulate filter.
Any self-contained breathing apparatus with a full face piece.
Any supplied-air respirator with a full face piece.
500 mg/m3
Any supplied-air respirator operated in a pressure-demand or other positive-pressure mode.
Emergency or planned entry into unknown concentrations or IDLH conditions - Any self-contained breathing apparatus that has a full face piece and is operated in a pressure-demand or other positive-pressure mode.
Escape
Any air-purifying, full-face piece respirator equipped with an N100, R100, or P100 filter.
Any appropriate escape-type, self-contained breathing apparatus.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene
considerations
When using, do not eat, drink or smoke. Keep from contact with clothing and other combustible materials. Remove and wash contaminated clothing promptly. Wash hands before breaks and immediately after handling the product. Handle in accordance with good industrial hygiene and safety practice.
9. Physical and chemical properties
Appearance Dark purple solid with metallic luster.
Physical state Solid.
Form Solid.
Color Dark purple.
Odor Odorless.
Odor threshold Not available.
pH Not applicable.
Melting point/freezing point Starts to decompose with evolution of oxygen (O2) at temperatures above 150 °C. Once initiated, the decomposition is exothermic and self sustaining.
Initial boiling point and boiling
range
Not applicable.
Flash point Not applicable.
Evaporation rate Not applicable.
Flammability (solid, gas) Non flammable.
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
Not applicable.
Flammability limit - upper
(%)
Not applicable.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
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Vapor pressure Not applicable.
Vapor density Not applicable.
Relative density 2.7 (20 °C) ( Water = 1)
Solubility(ies) 6 % (20 °C)
20 % (65 °C)
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not applicable.
Other information
Explosive properties Not explosive. Can explode in contact with sulfuric acid, peroxides and metal powders.
Molecular weight 158.03
Oxidizing properties Strong oxidizing agent.
10. Stability and reactivity
Reactivity The product is non-reactive under normal conditions of use, storage and transport.
Chemical stability Stable at normal conditions.
Possibility of hazardous
reactions
Contact with combustible material may cause fire. Can explode in contact with sulfuric acid, peroxides and metal powders. Starts to decompose with evolution of oxygen (O2) at temperatures above 150 °C. Once initiated, the decomposition is exothermic and self sustaining.
Conditions to avoid Contact with incompatible materials or heat (135 °C / 275 °F) could result in violent exothermic chemical reaction.
Incompatible materials Acids. Peroxides. Reducing agents. Combustible material. Metal powders. Contact with hydrochloric acid liberates chlorine gas.
Hazardous decomposition
products
By heating and fire, corrosive vapors/gases may be formed.
11. Toxicological information
Information on likely routes of exposure
Ingestion Harmful if swallowed.
Inhalation May cause irritation to the respiratory system.
Skin contact Causes severe skin burns.
Eye contact Causes serious eye damage.
Symptoms related to the
physical, chemical and
toxicological characteristics
Contact with this material will cause burns to the skin, eyes and mucous membranes. Permanent eye damage including blindness could result.
Information on toxicological effects
Acute toxicity Harmful if swallowed.
Components Species Test Results
Potassium permanganate (CAS 7722-64-7)
LD50 Rat
Oral
Acute
780 mg/kg, 14 days, (Male)
525 mg/kg, 14 days, (Female)
Skin corrosion/irritation Causes severe skin burns.
Serious eye damage/eye
irritation
Causes serious eye damage.
Respiratory sensitization Not classified.
Skin sensitization Not classified.
Germ cell mutagenicity Not classified.
Carcinogenicity Not classified.
Reproductive toxicity Not classified.
Specific target organ toxicity -
single exposure
Causes damage to organs (respiratory system).
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Specific target organ toxicity -
repeated exposure
Causes damage to organs (respiratory system, central nervous system) through prolonged or repeated exposure.
Aspiration hazard Not classified.
Chronic effects May cause damage to respiratory system. Prolonged exposure, usually over many years, to manganese oxide fume/dust can lead to chronic manganese poisoning, chiefly affecting the central nervous system.
Further information No other specific acute or chronic health impact noted.
12. Ecological information
Ecotoxicity Very toxic to aquatic life with long lasting effects.
Components Species Test Results
Potassium permanganate (CAS 7722-64-7)
Aquatic
Fish LC50 Bluegill (Lepomis macrochirus) 2.7 mg/l, 96 hours, static
2.3 mg/l, 96 hours, flow through
2.3 mg/l, 96 hours
1.8 - 5.6 mg/l
Carp (Cyprinus carpio) 3.16 - 3.77 mg/l, 96 hours
2.97 - 3.11 mg/l, 96 hours
Goldfish (Carassius auratus) 3.3 - 3.93 mg/l, 96 hours, static Milkfish, salmon-herring (Chanos > 1.4 mg/l, 96 hours
chanos)
Rainbow trout (Oncorhynchus mykiss) 1.8 mg/l, 96 hours
1.08 - 1.38 mg/l, 96 hours
0.77 - 1.27 mg/l, 96 hours
Rainbow trout,donaldson trout 0.275 - 0.339 mg/l, 96 hours (Oncorhynchus mykiss)
Persistence and degradability Expected to be readily converted by oxidizable materials to insoluble manganese oxide.
Bioaccumulative potential Potential to bioaccumulate is low.
Mobility in soil Not available.
Mobility in general The product is water soluble and may spread in water systems.
Other adverse effects None known.
13. Disposal considerations
Disposal instructions Dispose of contents/container in accordance with local/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code D001: Ignitable waste
The Waste code should be assigned in discussion between the user, the producer and the waste disposal company.
Waste from residues / unused
products
Do not allow this material to drain into sewers/water supplies. Dispose in accordance with all applicable regulations.
Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is emptied. Rinse container at least three times to an absence of pink color before disposing. Empty containers should be taken to an approved waste handling site for recycling or disposal.
14. Transport information
DOT
UN number UN1490
UN proper shipping name Potassium permanganate
Transport hazard class(es) 5.1
Subsidiary class(es) -
Packing group II
Special precautions for user Read safety instructions, MSDS and emergency procedures before handling.
Labels required 5.1
Special provisions IB8, IP2, IP4, T3, TP33
Packaging exceptions 152
Packaging non bulk 212
Packaging bulk 240
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IATA
UN number UN1490
UN proper shipping name Potassium permanganate
Transport hazard class(es) 5.1
Subsidiary class(es) -
Packaging group II
Environmental hazards Yes
Labels required 5.1
ERG Code 5L
Special precautions for user Read safety instructions, MSDS and emergency procedures before handling.
IMDG
UN number UN1490
UN proper shipping name POTASSIUM PERMANGANATE
Transport hazard class(es) 5.1
Subsidiary class(es) -
Packaging group II
Marine pollutant Yes
Environmental hazards
Labels required 5.1
EmS F-H, S-Q
Special precautions for user Read safety instructions, MSDS and emergency procedures before handling.
Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
This substance/mixture is not intended to be transported in bulk.
15. Regulatory information
US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
CERCLA/SARA Hazardous Substances - Not applicable.
Drug Enforcement Administration (DEA) (21 CFR 1310.02 (b) 8: List II chemical.
Department of Homeland Security (DHS) Chemical Facility Anti-Terrorism Standards (6 CFR 27, Appendix A): Listed.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes
Delayed Hazard - Yes
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely
hazardous substance
No
SARA 311/312 Hazardous
chemical
Yes
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Potassium permanganate (CAS 7722-64-7)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated.
Clean Water Act (CWA)
Section 112(r) (40 CFR
68.130)
Hazardous substance
Safe Drinking Water Act
(SDWA)
Not regulated.
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Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number
Potassium permanganate (CAS 7722-64-7) 6579
Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Potassium permanganate (CAS 7722-64-7) 15 % wt
DEA Exempt Chemical Mixtures Code Number
Potassium permanganate (CAS 7722-64-7) 6579
Food and Drug
Administration (FDA)
Not regulated.
US state regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm.
California OSH Hazardous Substance List: Listed.
US. Massachusetts RTK - Substance List
Potassium permanganate (CAS 7722-64-7)
US. New Jersey Worker and Community Right-to-Know Act
Potassium permanganate (CAS 7722-64-7) 500 lbs
US. Pennsylvania RTK - Hazardous Substances
Potassium permanganate (CAS 7722-64-7)
US. Rhode Island RTK
Not regulated.
US. California Proposition 65
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance Not listed.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes European Inventory of Existing Commercial Chemical
Substances (EINECS)
Europe Yes
Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) Yes Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippine Inventory of Chemicals and Chemical Substances (PICCS)
Philippines Yes
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s).
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
16. Other information, including date of preparation or last revision Issue date 04-03-2013
Revision date -
Version # 01
Further information Not available.
List of abbreviations LD50: Lethal Dose, 50%.
LC50: Lethal Concentration, 50%.
References HSDB® - Hazardous Substances Data Bank
Registry of Toxic Effects of Chemical Substances (RTECS) ACGIH
EPA: AQUIRE database
NLM: Hazardous Substances Data Base
US. IARC Monographs on Occupational Exposures to Chemical Agents IARC Monographs. Overall Evaluation of Carcinogenicity
National Toxicology Program (NTP) Report on Carcinogens ACGIH Documentation of the Threshold Limit Values and Biological Exposure Indices RemOx® S ISCO Reagent SDS US
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Disclaimer This safety data sheet was prepared in accordance with the Safety Data Sheet for Chemical Products (JIS Z 7250:2005). The information contained herein is accurate to the best of our knowledge. However, data, safety standards and government regulations are subject to change and, therefore, holders and users should satisfy themselves that they are aware of all current data and regulations relevant to their particular use of product. CARUS CORPORATION DISCLAIMS
ALL LIABILITY FOR RELIANCE ON THE COMPLETENESS OR ACCURACY OR THE INFORMATION INCLUDED HEREIN. CARUS CORPORATION MAKES NO WARRANTY, EITHER
EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY WARRANTIES OF
MERCHANTIABILITY OR FITNESS FOR PARTICULAR USE OR PURPOSE OF THE PRODUCT DESCRIBED HEREIN. All conditions relating to storage, handling, and use of the product are beyond the control of Carus Corporation, and shall be the sole responsibility of the holder or user of the product.
(Carus and design) is a registered service mark of Carus Corporation. RemOx® is a registered trademark of Carus Corporation. Copyright 1998.
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HEALTH AND SAFETY PLAN
Vacant Site (future Civic Center), 117-9040001
APPENDIX D
HEAT ILLNESS PRVENTION PLAN
111: I TETRA TECH
ITEM 11.1. ATTACHMENT 3
1 PROCEDURES
FOR HEAT ILLNESS
PREVENTION
Employer Name: Tetra Tech
Work Site: 10153 Folsom Blvd., Rancho Cordova, CA
The following designated person or persons (Program Administrator Safety Coordinator / Supervisor/Foreman/Field Supervisor/Crew Leader) have the authority and responsibility for implementing the provisions of this program at this worksite.
Responsibility
Program Manager
Project Manager/SSC
Field Supervisor
Field Staff
Corporate Health & Safety
(HSR)
Name/Title
Tetra Tech Personnel:
Betty Li
Keith Hoofard
Zack Laforet
Garrett Kuhl
Robert Rolon, CIH
Telephone No.
(916) 853-1800 (office)
(916) 709-4732 (cell)
(603) 801-1624 (cell)
(650) 804-8412 (cell)
(407) 448-9553
California Employers with any outdoor places of employment must comply with the Heat Illness Prevention Standard T8 CCR 3395. These procedures have been created to assist the employer in crafting their heat illness prevention procedures, and to reduce the risk of work related heat illnesses among their employees.
These procedures are not intended to supersede or replace the application of any other Title 8 regulation, particularly T8 3203 Injury and Illness Prevention Program (IIPP). Title 8 CCR 3203 requires an employer to establish, implement, and maintain an effective IIPP. The measures listed here may be integrated into the Employer’s Injury and Illness Prevention Program.
The employer must also be aware that other standards apply to Heat Illness Prevention such as the requirement to provide for drinking water, first aid and emergency response.
ITEM 11.1. ATTACHMENT 3
2 Please note: These procedures provide the minimal steps applicable to most outdoor work settings and are essential to reducing the incidence of heat related illnesses. In working environments with a higher risk for heat illness (e.g., during a heat wave, or other severe working or environmental conditions), Tetra Tech will exercise greater caution and additional protective measures beyond what is listed in this document, as needed to protect their employees.
For additional information on preventing Heat Related Illness, please visit the DOSH website at:
http://www.dir.ca.gov/DOSH/DOSH/HeatIllnessInfo.html
ITEM 11.1. ATTACHMENT 3
3 HEAT ILLNESS PREVENTION ELEMENTS
The elements reflected within this Heat Illness Prevention guide are those contained in Title 8 of the California Code of Regulations, Section 3395 (T8 CCR 3395) and consist of the following:
Provision of Water
Access to Shade
Procedures for Handling
a Heat Wave
Weather Monitoring and
Acclimatization
Written Procedures
Training
> PROVISION OF WATER
Water is a key preventive measure to minimize the risk of heat related illnesses. 3395 (c) Employees shall have access to potable drinking water meeting the requirements of Sections 1524, 3363, and 3457, as applicable. Where the supply of water is not plumbed or otherwise continuously supplied, water shall be provided in sufficient quantity at the beginning of the work shift to provide one quart per employee per hour for drinking for the entire shift. Employers may begin the shift with smaller quantities of water if they have effective procedures for replenishment during the shift as needed to allow employees to drink one quart or more per hour. The frequent drinking of water, as described in (e), shall be encouraged.
To ensure access to sufficient quantities of potable drinking water, the following steps will be taken:
Tetra Tech employee will bring at least 2 quarts per employee at the start of the shift. Each subcontractor’s employer will also bring same quantities of water for their employees. Supervisor/designated person will monitor water containers every 30 minutes, and employees are encouraged to report to supervisor/designated person low levels or dirty water. Water containers will be located as close as practicable to the areas where employees are working (given the working conditions and layout of the worksite), to encourage the frequent drinking of water. If field terrain prevents the water from being placed as close as possible to the workers, bottled water or personal water containers will be made available, so that workers can have drinking water readily accessible.
When drinking water levels within a container drop below 50%, the water shall be replenished immediately; or water levels should not fall below the point that will allow for adequate water during the time necessary to effect replenishment.
Disposable/single use drinking cups or bottles will be provided to employees, or provisions will be made to issue employees their own cups or bottles each day.
ITEM 11.1. ATTACHMENT 3
4 Water will be fresh, pure, and suitably cool and provided to employees free of charge. During hot weather, the water must be cooler than the ambient temperature but not so cool as to cause discomfort.
When employees are working across large areas, water will be placed in multiple locations. All water containers will be kept in sanitary condition. Water from non-approved or non-tested water sources (e.g., untested wells) is not acceptable. If hoses or connections are used, they must be governmentally approved for potable drinking water systems, as shown on the manufactures label.
To encourage frequent drinking of potable water, the following steps will be taken:
Supervisor will provide frequent reminders to employees to drink frequently, and more water breaks will be provided.
Every morning there will be short tailgate meetings to remind workers about the importance of frequent consumption of water throughout the shift.
When the temperature equals or exceeds 95 degrees Fahrenheit or during a heat wave, preshift meetings will be held before start of work to encourage employees to drink plenty of water, and remind employees of their right to take a cool-down rest when necessary will be conducted. Additionally, the number of water breaks will be increased. Supervisors/foreman will lead by example and workers will be reminded throughout the work shift to drink water. Noise making devices, such as air horns, may be used to remind employee’s to take their water break.
> ACCESS TO SHADE
Access to rest and shade or other cooling measures are important preventive steps to minimize the risk of heat related illnesses.
3395 (d) Access to shade
(1) Shade shall be present when the temperature exceeds 80 degrees Fahrenheit. When the outdoor temperature in the work area exceeds 80 degrees Fahrenheit, the employer shall have and maintain one or more areas with shade at all times while employees are present that are either open to the air or provided with ventilation or cooling. The amount of shade present shall be at least enough to accommodate the number of employees on recovery or rest periods, so that they can sit in a normal posture fully in the shade without having to be in physical contact with each other. The shade shall be located as close as practicable to the areas where employees are working. Subject to the same specifications, the amount of shade present during meal periods shall be at least enough to accommodate the number of employees on the meal period who remain onsite.
(2) Shade shall be available when the temperature does not exceed 80 degrees Fahrenheit. When the outdoor temperature in the work area does not exceed 80 degrees Fahrenheit employers shall either provide shade as per subsection (d)(1) or provide timely access to shade upon an employee's request.
(3) Employees shall be allowed and encouraged to take a preventative cool-down rest in the shade when they feel the need to do so to protect themselves from overheating. Such access to shade shall be permitted at all times. An individual employee who takes a preventative cool-down rest:
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5 (A) shall be monitored and asked if he or she is experiencing symptoms of heat illness; (B) shall be encouraged to remain in the shade; and (C) shall not be ordered back to work until any signs or symptoms of heat illness have abated, but in no event less than 5 minutes in addition to the time needed to access the shade.
(4) If an employee exhibits signs or reports symptoms of heat illness while taking a preventative cool-down rest or during a preventative cool-down rest period, the employer shall provide appropriate first aid or emergency response according to subsection (f) of this section To ensure access to shade at all time and to a preventative recovery period, the following steps will be taken:
Shade structures will be opened and placed as close as practical to the workers, when the temperature equals or exceeds 80 degrees Fahrenheit. When the temperature is below 80 degrees Fahrenheit, access to shade will be provided promptly, when requested by an employee.
Note: The interior of a vehicle may not be used to provide shade unless the vehicle is airconditioned and the air conditioner is on. Enough shade structures will be available at the site, to accommodate all of the employees who are on such a break at any point in time. During meal periods there will be enough shade for all of the employees who choose to remain in the general area of work or in areas designated for recovery and rest periods. (Employers may rotate employees in and out of meal periods, as with recovery and rest periods.)
Daily, workers will be informed of the location of the shade structures and will be encouraged to take a five minute cool-down rest in the shade. An employee who takes a preventative cool-down rest break will be monitored and asked if he/she is experiencing symptoms of heat illness and in no case will the employee be ordered back to work until signs or symptoms of heat illness have abated. (see also the section on Emergency Response for additional information)
Shade structures will be relocated to follow along with the crew and they will be placed as close as practical to the employees, so that access to shade is provided at all times. All employees on a recovery, rest break or meal period will have full access to shade so they can sit in a normal posture without having to be in physical contact with each other. In situations where it is not safe or feasible to provide access to shade (e.g., during high winds), a note will be made of these unsafe or unfeasible conditions, and of the steps that will be taken to provide shade upon request.
Procedures for Monitoring the Weather
The Tetra Tech field supervisor will check the weather in advance to determine whether high temperatures or a heat wave is expected. The field supervisor will check readily available internet National Weather Service website (www.nws.noaa.gov/). A thermometer will be used at the jobsite to monitor for sudden increases in temperature, and to ensure that once the temperature exceeds 80 degrees F, shade structures will be opened and made available to the workers. In addition, when the temperature equals or exceeds 95 degrees F, additional preventive measures such as the High Heat Procedures will be implemented.
> PROCEDURES FOR HANDLING A HEAT WAVE:
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6 For purposes of this section only, “heat wave” means any day in which the predicted high temperature for the day will be at least 80 degrees Fahrenheit and at least ten degrees Fahrenheit higher than the average high daily temperature in the preceding five days. During a heat wave or heat spike, the work day will be cut short or rescheduled (example conducted at night or during cooler hours).
During a heat wave or heat spike, and before starting work, tailgate meetings will be held, to review the company heat illness prevention procedures, the weather forecast and emergency response. In addition, if schedule modifications are not possible, workers will be provided with an increased number of water and rest breaks and will be observed closely for signs and symptoms of heat illness.
Tetra Tech will ensure effective employee observation/monitoring by implementing one or more of the following to be on the lookout for signs and symptoms of heat illness and to ensure that emergency procedures are initiated when someone displays possible signs or symptoms of heat illness:
o Supervisor or designee observation of 20 or fewer employees, or o Mandatory buddy system, or
o Regular communication with sole employee such as by radio or cellular phone, or o Some other means of observation.
> HIGH HEAT PROCEDURES:
High Heat Procedures are additional preventive measures that this company will use when the temperature equals or exceeds 95 degrees Fahrenheit.
Effective communication by voice, direct observation (applicable for work crews of 20 or fewer), mandatory buddy system, or electronic means will be maintained, so that employees at the worksite can contact a supervisor when necessary. If the supervisor is unable to be near the workers (to observe them or communicate with them), then an electronic device, such as a cell phone or text messaging device, may be used for this purpose if reception in the area is reliable.
Frequent communication will be maintained with employees working by themselves or in smaller groups (keep tabs on them via phone or two-way radio), to be on the lookout for possible symptoms of heat illness. The employee(s) will be contacted regularly and as frequently as possible throughout the day, since an employee in distress may not be able to summon help on his or her own.
Effective communication and direct observation for alertness and/or signs and symptoms of heat illness will be conducted frequently. When the supervisor is not available, a designated alternate responsible person must be assigned, to look for signs and symptoms of heat illness. If a supervisor, designated observer, or any employee reports any signs or symptoms of heat illness in any employee, the supervisor or designated person will take immediate action commensurate with the severity of the illness (see Emergency Response Procedures). Employees will be reminded constantly throughout the work shift to drink plenty of water and take preventative cool-down rest break when needed.
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