Product Number 840 SAFETY DATA SHEET
Issuing Date No data available Revision Date 03-11-2015 Revision Number 2 The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources. UL makes no representations or warranties regarding the completeness or accuracy of the information in this SDS and disclaims all liability in connection with the use of this information or the substance described in this SDS. The layout, appearance and format of this SDS is © 2014 UL LLC. All rights reserved.
Product identifier
Product Name Acetone
Other means of identification
Synonyms None
Recommended use of the chemical and restrictions on use Recommended Use
Uses advised against
Multi-purpose solvent
No information available
Details of the supplier of the safety data sheet
Supplier Name Sunnyside Corporation
Supplier Address 225 Carpenter Avenue
Wheeling
IL
60090
US
Supplier Phone Number
Supplier Email
Emergency telephone number
Phone:8003238611
Fax:8475419043
[email protected]
Chem Trec 8004249300
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Serious eye damage/eye irritation Category 2
Specific target organ toxicity (single exposure) Category 3 Flammable liquids Category 2
GHS Label elements, including precautionary statements
2. HAZARDS IDENTIFICATION
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
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Precautionary Statements - Prevention
Avoid breathing dust/fume/gas/mist/vapors/spray
Use only outdoors or in a well-ventilated area
Keep away from heat/sparks/open flames/hot surfaces. - No smoking Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ ventilating/ lighting/ equipment Use only non-sparking tools
Take precautionary measures against static discharge
Wear protective gloves/protective clothing/eye protection/face protection Keep cool
Precautionary Statements - Response
Skin
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell Fire
In case of fire: Use CO2, dry chemical, or foam for extinction Precautionary Statements - Storage
Store in a well-ventilated place. Keep container tightly closed Store locked up
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC)
Not applicable
Unknown Toxicity
0% of the mixture consists of ingredient(s) of unknown toxicity EmergencyOverview
Signal word Danger
Hazard Statements
Causes serious eye irritation
May cause drowsiness or dizziness
Highly flammable liquid and vapor
Appearance Clear Physical State Liquid Odor Pungent
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Otherinformation
May be harmful if inhaled
PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION Interactions with Other Chemicals
Use of alcoholic beverages may enhance toxic effects.
.
Chemical Name CAS No Weight-% Trade Secret
Acetone 67-64-1 60 - 100 *
*The exact percentage (concentration) of composition has been withheld as a trade secret First aid measures
General Advice Show this safety data sheet to the doctor in attendance.
Eye Contact If symptoms persist, call a physician. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Keep eye wide open while rinsing. Do not rub affected area.
Skin Contact In the case of skin irritation or allergic reactions see a physician. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes.
Inhalation Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, (trained personnel should) give oxygen.
Ingestion Do NOT induce vomiting. Rinse mouth immediately and drink plenty of water.
Never give anything by mouth to an unconscious person. Call a physician.
Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination.
Most important symptoms and effects, both acute and delayed Most Important Symptoms and
Effects
Burning sensation. Drowsiness. Dizziness.
Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically.
4. FIRST AID MEASURES
3. COMPOSITION/INFORMATION ON INGREDIENTS
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Suitable Extinguishing Media
Dry chemical. Carbon dioxide (CO2). Water spray. Alcohol resistant foam.
Unsuitable Extinguishing Media
CAUTION: All these products have a very low flash point. Use of water spray when fighting fire may be inefficient.
Specific Hazards Arising from the Chemical
Vapors can form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard.
Uniform Fire Code Flammable Liquid: I-B
Irritant: Liquid
Hazardous Combustion Products
Carbon oxides.
Explosion Data
Sensitivity to Mechanical Impact No.
Sensitivity to Static Discharge Yes.
Protective equipment and precautions for firefighters
Move containers from fire area if you can do it without risk.
Personal precautions, protective equipment and emergency procedures Personal Precautions ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Stop leak if you can do it without risk.
OtherInformation Water spray may reduce vapor; but may not prevent ignition in closed spaces.
Environmental Precautions
Environmental Precautions Prevent entry into waterways, sewers, basements or confined areas.
Methods and material for containment and cleaning up
Methods for Containment A vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.
Methods for cleaning up Use clean non-sparking tools to collect absorbed material. Soak up with inert absorbent material. Dike far ahead of liquid spill for later disposal.
6. ACCIDENTAL RELEASE MEASURES
5. FIRE-FIGHTING MEASURES
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Precautions for safe handling
Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product. Use personal protection equipment. Avoid breathing vapors or mists. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use grounding and bonding connection when transferring this material to prevent static discharge, fire or explosion. Use with local exhaust ventilation. Use spark-proof tools and explosion-proof equipment. Keep in an area equipped with sprinklers. Use according to package label instructions.
Conditions for safe storage, including any incompatibilities Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Keep in properly labeled containers. Do not store near combustible materials.
Keep in an area equipped with sprinklers.
Incompatible Products None known based on information supplied.
Control parameters
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Acetone
67-64-1
STEL = 750 ppm
TWA: 500 ppm
TWA: 1000 ppm
TWA: 2400 mg/m3
(vacated) TWA: 1800 mg/m3
(vacated) TWA: 750 ppm
(vacated) STEL: 1000 ppm
(vacated) STEL: 2400 mg/m3
IDLH: 2500 ppm 10% LEL
TWA: 250 ppm
TWA: 590 mg/m3
ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits NIOSH IDLH Immediately Dangerous to Life or Health Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992) See section 15 for national exposure control parameters Appropriate engineering controls
Engineering Measures Showers
Eyewash stations
Ventilation systems
Individual protection measures, such as personal protective equipment Eye/Face Protection Tight sealing safety goggles.
Skin and Body Protection Long sleeved clothing. Chemical resistant apron. Impervious gloves. Antistatic boots.
Respiratory Protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
7. HANDLING AND STORAGE
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Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection. Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is recommended.
Wash hands before breaks and immediately after handling the product.
Physical and Chemical Properties
Physical State
Appearance
Liquid
Clear Odor Pungent
Color Colorless Odor Threshold No information available Property Values Remarks/ Method
pH N/A None known
Melting / freezing point
Boiling point / boiling range
Flash Point
Evaporation Rate
No data available
56 °C / 133 °F
-18 C / 0 F
No data available
None known
None known
None known
None known
Flammability (solid, gas)
Flammability Limit in Air
N/A None known
Upper flammability limit No data available
Lower flammability limit
Vapor pressure
Vapor density
Specific Gravity
Water Solubility
2.5% @ 77 °F
213 mmHg @ 75 °F
No data available No
data available
Soluble in water No
None known
None known
None known
None known
Solubility in other solvents data available None known
Partition coefficient: n-octanol/waterNo data available None known Autoignition temperature 869 °F None known
Decompositiontemperature No data available None known
Kinematic viscosity No data available None known
Dynamic viscosity No data available None known
Explosive properties No data available
Oxidizing Properties No data available
OtherInformation
Softening Point
VOC Content (%)
Particle Size
Particle Size Distribution
No data available
Exempt
No data available
9. PHYSICAL AND CHEMICAL PROPERTIES
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Reactivity
No data available.
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
HazardousPolymerization
Hazardous polymerization does not occur.
Conditions to avoid
Heat, flames and sparks.
Incompatible materials
Caustics, amines, alkanolamines, ammonia, strong oxidizing agents and chlorinated compounds.
Hazardous Decomposition Products
Carbon oxides.
Information on likely routes of exposure
Product Information .
Inhalation Specific test data for the substance or mixture is not available. May cause drownsiness and dizziness based on components. May cause irritation of respiratory tract.
Eye Contact Specific test data for the substance or mixture is not available. Expected to be an irritant based on components. May cause redness, itching, and pain. May cause temporary eye irritation.
Skin Contact Specific test data for the substance or mixture is not available. May cause irritation.
Prolonged contact may cause redness and irritation.
Ingestion Specific test data for the substance or mixture is not available. Ingestion may cause irritation to mucous membranes. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.
ComponentInformation
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
Acetone
67-64-1
- - = 50100 mg/m3 ( Rat ) 8 h
Information on toxicological effects
Symptoms May cause redness and tearing of the eyes.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
11. TOXICOLOGICAL INFORMATION
10. STABILITY AND REACTIVITY
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Sensitization No information available.
Mutagenic Effects No information available.
Carcinogenicity Contains no ingredient listed as a carcinogen.
Reproductive Toxicity No information available.
STOT - single exposure No information available.
STOT - repeated exposure No information available.
Chronic Toxicity No known effect based on information supplied.
Target Organ Effects Eyes. Central Nervous System (CNS). Respiratory system. Skin.
Aspiration Hazard No information available.
Numerical measures of toxicity Product Information
The following values are calculated based on chapter 3.1 of the GHS document ATEmix(inhalation-dust/mist)
100.20 mg/l
Ecotoxicity
The environmental impact of this product has not been fully investigated.
Persistence and Degradability
No information available.
Bioaccumulation
No information available
Chemical Name Log Pow
Acetone
67-64-1
-0.24
Other adverse effects
No information available.
12. ECOLOGICAL INFORMATION
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Waste treatment methods
Disposal methods This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261).
ContaminatedPackaging Dispose of contents/containers in accordance with local regulations.
US EPA Waste Number D001 U002
Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes Acetone
67-64-1
U002
California Hazardous Waste Codes 212
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical Name California Hazardous Waste
Acetone
67-64-1
Ignitable
DOT
UN-No.
Proper Shipping Name
Hazard Class
Packing Group
Description
UN1090
ACETONE
3 II
UN1090, ACETONE, 3, II
TDG
UN-No. UN1090
Proper Shipping Name ACETONE
Hazard Class 3
Packing Group II
Description UN1090, ACETONE, 3, II
MEX
UN-No. UN1090
Proper Shipping Name ACETONE
Hazard Class 3
Packing Group II
Description UN1090 ACETONE, 3, II
ICAO
UN-No. UN1090
Proper Shipping Name ACETONE
Hazard Class 3
Packing Group II
Description UN1090, ACETONE, 3, II
IATA
UN-No. UN1090
Proper Shipping Name ACETONE
Hazard Class 3
14. TRANSPORT INFORMATION
13. DISPOSAL CONSIDERATIONS
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Packing Group II
Description UN1090, ACETONE, 3, II
IMDG/IMO
UN-No. UN1090
Proper Shipping Name ACETONE
Hazard Class 3
Packing Group II
EmS No. F-E, S-D
Description UN1090, ACETONE, 3, II, FP -18C
RID
UN-No. UN1090
Proper Shipping Name ACETONE
Hazard Class 3
Packing Group II
Classification code F1
Description UN1090 ACETONE, 3, II
ADR
UN-No. UN1090
Proper Shipping Name ACETONE
Hazard Class 3
Packing Group II
Classification code F1
Description UN1090 ACETONE, 3, II
ADN
UN-No. UN1090
Proper Shipping Name ACETONE
Hazard Class 3
Packing Group II
Classification code F1
Description UN1090 ACETONE, 3, II
Hazard Labels 3
Limited Quantity 1 L
Ventilation VE01
International Inventories
TSCA Complies
DSL All components are listed either on the DSL or NDSL.
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories
Acute Health Hazard Yes
Chronic Health Hazard No
Fire Hazard Yes
Sudden release of pressure hazard No
Reactive Hazard No
15. REGULATORY INFORMATION
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CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs
RQ
Acetone
67-64-1
5000 lb RQ= 2270 kg final RQ
RQ= 5000 lb final RQ
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
.
Chemical Name New Jersey Massachusetts Pennsylvania Rhode Island Illinois Acetone
67-64-1
X X X X
International Regulations
Mexico
National occupational exposure limits
Component Carcinogen Status Exposure Limits
Acetone
67-64-1 ( 60 - 100 )
Mexico: TWA= 1000 ppm
Mexico: TWA= 2400 mg/m3
Mexico: STEL= 1260 ppm
Mexico: STEL= 3000 mg/m3
Mexico - Occupational Exposure Limits - Carcinogens
Canada
WHMIS Hazard Class
B2 - Flammable liquid
D2B - Toxic materials
NFPA Health Hazards 2 Flammability 3 Instability 0 Physical and Chemical Hazards -
HMIS Health Hazards 2 Flammability 3 Physical Hazard 0 Personal Protection X
16. OTHER INFORMATION
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Prepared By Product Stewardship
23 British American Blvd.
Latham, NY 12110
1-800-572-6501
Revision Date 15-Sep-2014
Revision Note No information available
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of Safety Data Sheet
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SAFETY DATA SHEET
GHS product identifier
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
545 EPOXY PRIMER White Base
Relevant identified uses of the substance or mixture and uses advised against Identified uses
Uses advised against
Professional use
Industrial use
Consumer use
Product use : Two component coating for exterior use.
Supplier's details
Akzo Nobel Coatings Ltd.
4-110 Woodbine Downs Blvd.
Etobicoke ON M9W 5S6
Canada
International Paint (International) 1-713-682-1711
CHEMTREC (USA) +1 (800) 424-9300 (24Hr)
CHEMTREC (International) +1 (703) 527-3887
Domestic Poison Control Center Customer Service +1 (800) 854-6813 Akzo Nobel Coatings
International Paint LLC
6001 Antoine Drive
Houston, Texas 77091
International Paint 1-800-589-1267
International Paint (International) 1-713-682-1711
Akzo Nobel Performance Coatings, S.A. de C.V.
Anillo Periférico #205 Km16.64
Hacienda San José
García, Nuevo Leon, Mexico.
CP 66000
RFC: ANA9510267C4
SDS code : OD8001
Section 2. Hazards identification
FLAMMABLE LIQUIDS - Category 2
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 1A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3
Classification of the
substance or mixture
:
GHS label elements
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Date of issue/Date of revision : Date of previous issue : Version : 2 1/22
4/1/2026
12/4/2023
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Section 2. Hazards identification
Signal word : Danger
Hazard statements : Highly flammable liquid and vapor.
May cause an allergic skin reaction.
Causes serious eye damage.
May cause drowsiness or dizziness.
May cause cancer.
Hazard pictograms :
Precautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use only outdoors or in a well-ventilated area. Avoid breathing vapor. Contaminated work clothing must not be allowed out of the workplace.
Response : IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Wash contaminated clothing before reuse. IF ON SKIN:
Wash with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor.
Storage : Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national or international regulations.
Hazards not otherwise
classified
: None known.
Section 3. Composition/information on ingredients
Substance/mixture : Mixture
Ingredient name % CAS number
Talc , not containing asbestiform fibres ≥10 - ≤25 14807-96-6 titanium dioxide ≥10 - ≤25 13463-67-7
Fatty acids, C18-unsatd., dimers, oligomeric reaction products with tall-oil fatty acids and triethylenetetramine
≥10 - ≤25 68082-29-1
calcium carbonate ≥10 - ≤25 471-34-1
Isopropyl alcohol ≤10 67-63-0
butanone ≤10 78-93-3
trizinc bis(orthophosphate) ≤10 7779-90-0
butan-1-ol ≤5 71-36-3
n-butyl acetate ≤5 123-86-4
Date of issue/Date of revision : Date of previous issue : Version : 2 2/22
4/1/2026
12/4/2023
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Section 3. Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Any concentration shown as a range is to protect confidentiality or is due to batch variation. 1-methoxy-2-propanol ≤5 107-98-2
xylene ≤2 1330-20-7
3,6-diazaoctanethylenediamin <1 112-24-3
ethylbenzene <1 100-41-4
Crystalline Silica, respirable part in whole product, <10µm ≤0.3 14808-60-7 Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician.
Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses if easy to do. Continue to rinse for at least 10 minutes.
Chemical burns must be treated promptly by a physician.
Get medical attention immediately. Call a poison center or physician. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness.
Skin contact : May cause an allergic skin reaction.
Eye contact : Causes serious eye damage.
Potential acute health effects
Date of issue/Date of revision : Date of previous issue : Version : 2 3/22
4/1/2026
12/4/2023
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Section 4. First aid measures
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Ingestion : Can cause central nervous system (CNS) depression.
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Adverse symptoms may include the following:
stomach pains
Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
:
:
:
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
phosphorus oxides
metal oxide/oxides
Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion.
Use dry chemical, CO₂, water spray (fog) or foam.
Extinguishing media
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Date of issue/Date of revision : Date of previous issue : Version : 2 4/22
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Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
:
: No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
Section 7. Handling and storage
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous.
Do not reuse container.
:
Precautions for safe handling
Date of issue/Date of revision : Date of previous issue : Version : 2 5/22
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Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Ensure spraying away from persons. Avoid inhalation of vapor, spray or mist. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. :
:
Talc , not containing asbestiform fibres None.
titanium dioxide OSHA PEL 1989 (United States, 3/1989).
TWA: 10 mg/m³ 8 hours. Form: Total dust
OSHA PEL (United States, 5/2018).
TWA: 15 mg/m³ 8 hours. Form: Total dust
ACGIH TLV (United States, 1/2023).
TWA: 2.5 mg/m³ 8 hours. Form: respirable
fraction, finescale particles
Fatty acids, C18-unsatd., dimers, oligomeric reaction products with talloil fatty acids and triethylenetetramineNone. calcium carbonate None.
Isopropyl alcohol ACGIH TLV (United States, 1/2023). Notes:
Refers to Appendix A -- Carcinogens.
ACGIH 2003 Adoption
STEL: 400 ppm 15 minutes.
TWA: 200 ppm 8 hours.
NIOSH REL (United States, 10/2020).
STEL: 1225 mg/m³ 15 minutes.
STEL: 500 ppm 15 minutes.
TWA: 980 mg/m³ 10 hours.
TWA: 400 ppm 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 980 mg/m³ 8 hours.
TWA: 400 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989).
STEL: 1225 mg/m³ 15 minutes.
STEL: 500 ppm 15 minutes.
TWA: 980 mg/m³ 8 hours.
TWA: 400 ppm 8 hours.
butanone ACGIH TLV (United States, 1/2023). Notes:
Substances for which there is a Biological
Exposure Index or Indices
STEL: 885 mg/m³ 15 minutes.
STEL: 300 ppm 15 minutes.
TWA: 590 mg/m³ 8 hours.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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Section 8. Exposure controls/personal protection
TWA: 200 ppm 8 hours.
NIOSH REL (United States, 10/2020).
STEL: 885 mg/m³ 15 minutes.
STEL: 300 ppm 15 minutes.
TWA: 590 mg/m³ 10 hours.
TWA: 200 ppm 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 590 mg/m³ 8 hours.
TWA: 200 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989).
STEL: 885 mg/m³ 15 minutes.
STEL: 300 ppm 15 minutes.
TWA: 590 mg/m³ 8 hours.
TWA: 200 ppm 8 hours.
trizinc bis(orthophosphate) None.
butan-1-ol ACGIH TLV (United States, 1/2023). Notes:
2002 Adoption.
TWA: 20 ppm 8 hours.
NIOSH REL (United States, 10/2020).
Absorbed through skin
CEIL: 150 mg/m³
CEIL: 50 ppm
OSHA PEL (United States, 5/2018).
TWA: 300 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989).
Absorbed through skin
CEIL: 150 mg/m³
CEIL: 50 ppm
n-butyl acetate NIOSH REL (United States, 10/2020).
STEL: 950 mg/m³ 15 minutes.
STEL: 200 ppm 15 minutes.
TWA: 710 mg/m³ 10 hours.
TWA: 150 ppm 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 710 mg/m³ 8 hours.
TWA: 150 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989).
STEL: 950 mg/m³ 15 minutes.
STEL: 200 ppm 15 minutes.
TWA: 710 mg/m³ 8 hours.
TWA: 150 ppm 8 hours.
ACGIH TLV (United States, 1/2023). [Butyl
acetates]
STEL: 150 ppm 15 minutes.
TWA: 50 ppm 8 hours.
1-methoxy-2-propanol ACGIH TLV (United States, 1/2023).
STEL: 369 mg/m³ 15 minutes.
STEL: 100 ppm 15 minutes.
TWA: 184 mg/m³ 8 hours.
TWA: 50 ppm 8 hours.
NIOSH REL (United States, 10/2020).
STEL: 540 mg/m³ 15 minutes.
STEL: 150 ppm 15 minutes.
TWA: 360 mg/m³ 10 hours.
TWA: 100 ppm 10 hours.
Date of issue/Date of revision : Date of previous issue : Version : 2 7/22
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Section 8. Exposure controls/personal protection
OSHA PEL 1989 (United States, 3/1989).
STEL: 540 mg/m³ 15 minutes.
STEL: 150 ppm 15 minutes.
TWA: 360 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
xylene OSHA PEL (United States, 5/2018).
[Xylenes]
TWA: 435 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989).
[Xylenes (o-, m-, p-isomers)]
STEL: 655 mg/m³ 15 minutes.
STEL: 150 ppm 15 minutes.
TWA: 435 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
ACGIH TLV (United States, 1/2023). [pxylene and mixtures containing p-xylene] Ototoxicant.
TWA: 20 ppm 8 hours.
3,6-diazaoctanethylenediamin OARS WEEL (United States, 4/2022).
Absorbed through skin
TWA: 1 ppm 8 hours.
ethylbenzene ACGIH TLV (United States, 1/2023).
Ototoxicant. Notes: Substances for which
there is a Biological Exposure Index or
Indices 2002 Adoption.
TWA: 20 ppm 8 hours.
NIOSH REL (United States, 10/2020).
STEL: 545 mg/m³ 15 minutes.
STEL: 125 ppm 15 minutes.
TWA: 435 mg/m³ 10 hours.
TWA: 100 ppm 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 435 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989).
STEL: 545 mg/m³ 15 minutes.
STEL: 125 ppm 15 minutes.
TWA: 435 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
Crystalline Silica, respirable part in whole product, <10µm OSHA PEL Z3 (United States, 6/2016).
TWA: 250 mppcf / (%SiO₂+5) 8 hours. Form:
Respirable
TWA: 10 mg/m³ / (%SiO₂+2) 8 hours. Form:
Respirable
OSHA PEL (United States, 5/2018). [Silica,
crystalline]
TWA: 50 µg/m³ 8 hours. Form: Respirable
dust
OSHA PEL 1989 (United States, 3/1989).
Notes: as quartz
TWA: 0.1 mg/m³, (as quartz) 8 hours. Form:
Respirable dust
ACGIH TLV (United States, 1/2023). [Silica,
crystalline] Notes: Respirable fraction; see
Date of issue/Date of revision : Date of previous issue : Version : 2 8/22
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Section 8. Exposure controls/personal protection
Appendix C, paragraph C.
TWA: 0.025 mg/m³ 8 hours. Form:
Respirable fraction
NIOSH REL (United States, 10/2020).
[SILICA, CRYSTALLINE] Notes: See
Appendix A - NIOSH Potential
Occupational Carcinogen
TWA: 0.05 mg/m³ 10 hours. Form: respirable
dust
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/ or face shield. If inhalation hazards exist, a full-face respirator may be required instead.
Eye/face protection
:
:
Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear antistatic protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Date of issue/Date of revision : Date of previous issue : Version : 2 9/22
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Section 8. Exposure controls/personal protection
Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Wear a respirator conforming to EN140 with type A/P2 filter or better.
Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/ or hazardous fumes. Wet sanding/flatting should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used.
Respiratory protection :
Section 9. Physical and chemical properties and safety
characteristics
Melting point/freezing point
Vapor pressure
Relative vapor density
Solubility(ies)
Not available.
Odor Solvent.
pH
Color White.
Auto-ignition temperature
Not applicable.
Not applicable. [DIN EN 1262]
Odor threshold Not available.
Partition coefficient: noctanol/water
:
:
:
:
:
:
:
:
:
Appearance
Flammability : Not available.
The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.
Media Result
cold water Not soluble [OECD (TG 105)]
Not available.
:
Ingredient name
Vapor Pressure at 20˚C Vapor pressure at 50˚C
mm Hg kPa Method mm Hg kPa Method
butanone 78.7564 10.5
Isopropyl alcohol 33.00268 4.4
n-butyl acetate 11.25096 1.5 DIN EN 13016-2
Flash point : Closed cup: 7°C (44.6°F) [Pensky-Martens] Boiling point or initial
boiling point and boiling
range
: 79°C (174.2°F)
Lower and upper explosion
limit
: Greatest known range: Lower: 1.48% Upper: 13.74% (1-methoxy-2-propanol) Density : 1.523 g/cm³ [DIN EN ISO 2811-1]
Physical state : Liquid.
Date of issue/Date of revision : Date of previous issue : Version : 2 10/22
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Section 9. Physical and chemical properties and safety
characteristics
Viscosity Kinematic (room temperature): 144 mm2/s (144 cSt) [DIN EN ISO 3219] Kinematic (40°C (104°F)): 220 mm2/s (220 cSt) [DIN EN ISO 3219] :
Decomposition temperature : Not available.
Particle characteristics
Median particle size : Not applicable.
Percentage of particles
with aerodynamic diameter
≤ 10 μm
: 0
Ingredient name °C °F Method
1-methoxy-2-propanol 270 518
butan-1-ol 355 671 EU A.15
Fatty acids, C18-unsatd., dimers, oligomeric reaction
products with tall-oil fatty acids and
triethylenetetramine
401 753.8
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
Chemical stability The product is stable.
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Information on toxicological effects
calcium carbonate LD50 Oral Rat 6450 mg/kg -
Isopropyl alcohol LC50 Inhalation Gas. Rat 16000 ppm 8 hours LD50 Dermal Rabbit 12800 mg/kg - LD50 Intraperitoneal Guinea pig 2560 mg/kg - LD50 Intraperitoneal Mouse 4477 mg/kg - LD50 Intraperitoneal Rabbit 667 mg/kg - LD50 Intraperitoneal Rat 2735 mg/kg - LD50 Intravenous Mouse 1509 mg/kg - LD50 Intravenous Rabbit 1184 mg/kg - LD50 Intravenous Rat 1088 mg/kg - LD50 Oral Mouse 3600 mg/kg - Product/ingredient name Result Species Dose Exposure
Date of issue/Date of revision : Date of previous issue : Version : 2 11/22
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Section 11. Toxicological information
Irritation/Corrosion
LD50 Oral Mouse 3600 mg/kg - LD50 Oral Rabbit 6410 mg/kg - LD50 Oral Rat 5045 mg/kg - LD50 Oral Rat 5000 mg/kg - butanone LC50 Inhalation Vapor Mouse 32 g/m³ 4 hours LC50 Inhalation Vapor Rat 23500 mg/m³ 8 hours
LD50 Dermal Rabbit 6480 mg/kg - LD50 Intraperitoneal Guinea pig 2 g/kg - LD50 Intraperitoneal Mouse 616 mg/kg - LD50 Intraperitoneal Rat 607 mg/kg - LD50 Oral Mouse 3000 mg/kg - LD50 Oral Rat 2737 mg/kg - trizinc bis(orthophosphate) LD50 Intraperitoneal Mouse 552 mg/kg - LD50 Intraperitoneal Rat 551 mg/kg - butan-1-ol LC50 Inhalation Vapor Rat 24000 mg/m³ 4 hours LD50 Dermal Rabbit 3400 mg/kg - LD50 Oral Rat 790 mg/kg - n-butyl acetate LD50 Oral Rat 10768 mg/kg - 1-methoxy-2-propanol LC50 Inhalation Gas. Rat 10000 ppm 5 hours LD50 Dermal Rabbit 13 g/kg - LD50 Intraperitoneal Rat 3720 mg/kg - LD50 Intravenous Mouse 5300 mg/kg - LD50 Intravenous Rabbit 1200 mg/kg - LD50 Intravenous Rat 4200 mg/kg - LD50 Oral Mouse 11700 mg/kg - LD50 Oral Rabbit 5700 mg/kg - LD50 Oral Rat 6600 mg/kg - LD50 Subcutaneous Rabbit 5 g/kg - LD50 Subcutaneous Rat 7800 mg/kg - xylene LD50 Oral Rat 4300 mg/kg - LD50 Subcutaneous Rat 1700 mg/kg - 3,6-diazaoctanethylenediamin LD50 Intraperitoneal Mouse 468 mg/kg - LD50 Intravenous Mouse 350 mg/kg - LD50 Oral Mouse 38.5 mg/kg - LD50 Oral Rabbit 5500 mg/kg - LD50 Oral Rat 2500 mg/kg - ethylbenzene LC50 Inhalation Gas. Rabbit 4000 ppm 4 hours LC50 Inhalation Vapor Mouse 35500 mg/m³ 2 hours
LC50 Inhalation Vapor Rat 55000 mg/m³ 2 hours
LD50 Dermal Rabbit >5000 mg/kg - LD50 Dermal Rabbit 17800 uL/kg - LD50 Intraperitoneal Mouse 2624 uL/kg - LD50 Oral Rat 3500 mg/kg - LD50 Oral Rat 3500 mg/kg - calcium carbonate Eyes - Severe irritant Rabbit - 24 hours 750 ug
- Skin - Moderate irritant Rabbit - 24 hours 500
mg
-
Isopropyl alcohol Eyes - Moderate irritant Rabbit - 10 mg - Eyes - Moderate irritant Rabbit - 24 hours 100 mg
- Eyes - Severe irritant Rabbit - 100 mg - Skin - Mild irritant Rabbit - 500 mg - butanone Skin - Mild irritant Rabbit - 24 hours 14 - Product/ingredient name Result Species Score Exposure Observation Date of issue/Date of revision : Date of previous issue : Version : 2 12/22
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Section 11. Toxicological information
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Reproductive toxicity
Not available.
Sensitization
Not available.
Classification
Talc , not containing
asbestiform fibres
- 3 -
titanium dioxide - 2B -
Isopropyl alcohol - 3 - xylene - 3 - ethylbenzene - 2B - Crystalline Silica, respirable part in whole product, <10µm
- 1 Known to be a human carcinogen.
Product/ingredient name OSHA IARC NTP
mg
Skin - Mild irritant Rabbit - 24 hours 402
mg
- Skin - Moderate irritant Rabbit - 24 hours 500
mg
- butan-1-ol Eyes - Severe irritant Rabbit - 0.005 Ml - Eyes - Severe irritant Rabbit - 1.62 mg - Eyes - Severe irritant Rabbit - 24 hours 2 mg
- Skin - Moderate irritant Rabbit - 24 hours 20
mg
- n-butyl acetate Eyes - Moderate irritant Rabbit - 100 mg - Skin - Moderate irritant Rabbit - 24 hours 500 mg
- 1-methoxy-2-propanol Eyes - Mild irritant Rabbit - 24 hours 500 mg
- Skin - Mild irritant Rabbit - 500 mg - xylene Eyes - Mild irritant Rabbit - 87 mg - Eyes - Severe irritant Rabbit - 24 hours 5 mg
- Skin - Mild irritant Rat - 8 hours 60 Ul - Skin - Moderate irritant Rabbit - 100 % - Skin - Moderate irritant Rabbit - 24 hours 500 mg
- 3,6-diazaoctanethylenediamin Eyes - Moderate irritant Rabbit - 24 hours 20 mg
- Eyes - Severe irritant Rabbit - 49 mg - Skin - Severe irritant Rabbit - 490 mg - Skin - Severe irritant Rabbit - 24 hours 5 mg
- ethylbenzene Eyes - Severe irritant Rabbit - 500 mg - Skin - Mild irritant Rabbit - 24 hours 15 mg
-
Date of issue/Date of revision : Date of previous issue : Version : 2 13/22
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Section 11. Toxicological information
Not available.
Information on the likely
routes of exposure
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness.
Ingestion : Can cause central nervous system (CNS) depression.
Skin contact : May cause an allergic skin reaction.
Eye contact : Causes serious eye damage.
Symptoms related to the physical, chemical and toxicological characteristics Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Adverse symptoms may include the following:
stomach pains
Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
:
:
:
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Aspiration hazard
Name Result
xylene ASPIRATION HAZARD - Category 1
ethylbenzene ASPIRATION HAZARD - Category 1
: Not available.
Potential acute health effects
Isopropyl alcohol Category 3 - Narcotic effects
butanone Category 3 - Narcotic effects
butan-1-ol Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
n-butyl acetate Category 3 - Narcotic effects
1-methoxy-2-propanol Category 3 - Narcotic effects
xylene Category 3 - Respiratory tract
irritation
Name Category Route of
exposure
Target organs
Name Category
ethylbenzene Category 2 - hearing organs
Crystalline Silica, respirable part in whole product, <10µm Category 1 inhalation lungs Route of
exposure
Target organs
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Section 11. Toxicological information
Not available.
Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.
General :
Carcinogenicity : May cause cancer. Risk of cancer depends on duration and level of exposure.
Mutagenicity : No known significant effects or critical hazards.
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure Potential immediate
effects
: Not available.
Short term exposure
Potential delayed effects : Not available.
Potential immediate
effects
: Not available.
Long term exposure
Potential delayed effects : Not available.
Reproductive toxicity : No known significant effects or critical hazards.
Numerical measures of toxicity
Acute toxicity estimates
Product/ingredient name
Product as-supplied 10274.9 68135 N/A 681.4 N/A
butan-1-ol 500 N/A N/A N/A N/A
xylene N/A 1100 N/A 11 N/A
3,6-diazaoctanethylenediamin N/A 1100 N/A N/A N/A
ethylbenzene N/A N/A N/A 11 N/A
Oral (mg/
kg)
Dermal
(mg/kg)
Inhalation
(gases)
(ppm)
Inhalation
(vapors)
(mg/l)
Inhalation
(dusts and
mists) (mg/
l)
Section 12. Ecological information
Toxicity
titanium dioxide Acute LC50 15.9 mg/l Fresh water Crustaceans - Ceriodaphnia dubia - Neonate
48 hours
Acute LC50 >1000 mg/l Fresh water Fish - Pimephales promelas 96 hours calcium carbonate Acute LC50 >56000 ppm Fresh water Fish - Gambusia affinis - Adult 96 hours Chronic NOEC 61 mg/g Fresh water Fish - Oncorhynchus mykiss - Juvenile (Fledgling, Hatchling,
Weanling)
28 days
Chronic NOEC 61 mg/g Fresh water Fish - Oncorhynchus mykiss - Juvenile (Fledgling, Hatchling,
Weanling)
35 days
Chronic NOEC 61 mg/g Fresh water Fish - Oncorhynchus mykiss - Juvenile (Fledgling, Hatchling,
Weanling)
35 days
Chronic NOEC 61 mg/g Fresh water Fish - Oncorhynchus mykiss - 42 days Product/ingredient name Result Species Exposure
Date of issue/Date of revision : Date of previous issue : Version : 2 15/22
4/1/2026
12/4/2023
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Section 12. Ecological information
Juvenile (Fledgling, Hatchling,
Weanling)
Chronic NOEC 61 mg/g Fresh water Fish - Oncorhynchus mykiss - Juvenile (Fledgling, Hatchling,
Weanling)
42 days
Isopropyl alcohol Acute EC50 10100 mg/l Fresh water Daphnia - Daphnia magna 48 hours Acute EC50 7550 mg/l Fresh water Daphnia - Daphnia magna - Neonate
48 hours
Acute EC50 9550 mg/l Fresh water Fish - Pimephales promelas 96 hours Acute LC50 1400000 µg/l Marine water Crustaceans - Crangon crangon 48 hours Acute LC50 10400000 µg/l Fresh water Fish - Pimephales promelas 96 hours Acute LC50 6550000 µg/l Fresh water Fish - Pimephales promelas 96 hours Acute LC50 9640000 µg/l Fresh water Fish - Pimephales promelas 96 hours Acute LC50 4200 mg/l Fresh water Fish - Rasbora heteromorpha 96 hours butanone Acute EC50 >500 mg/l Fresh water Algae - Pseudokirchneriella subcapitata
96 hours
Acute EC50 >500000 µg/l Marine water Algae - Skeletonema costatum 96 hours Acute EC50 5091000 µg/l Fresh water Daphnia - Daphnia magna - Larvae
48 hours
Acute LC50 5600 ppm Fresh water Fish - Gambusia affinis - Adult 96 hours Acute LC50 3220000 µg/l Fresh water Fish - Pimephales promelas 96 hours trizinc bis(orthophosphate) Acute LC50 90 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours butan-1-ol Acute EC50 1983 mg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 2300000 µg/l Marine water Fish - Alburnus alburnus 96 hours Acute LC50 1910000 µg/l Fresh water Fish - Pimephales promelas - Juvenile (Fledgling, Hatchling,
Weanling)
96 hours
Acute LC50 1940000 µg/l Fresh water Fish - Pimephales promelas - Juvenile (Fledgling, Hatchling,
Weanling)
96 hours
Acute LC50 1730000 µg/l Fresh water Fish - Pimephales promelas 96 hours n-butyl acetate Acute LC50 32 mg/l Marine water Crustaceans - Artemia salina 48 hours Acute LC50 62000 µg/l Fresh water Fish - Danio rerio 96 hours xylene Acute EC50 90 mg/l Fresh water Crustaceans - Cypris subglobosa 48 hours Acute LC50 8.5 ppm Marine water Crustaceans - Palaemonetes pugio - Adult
48 hours
Acute LC50 8500 µg/l Marine water Crustaceans - Palaemonetes pugio
48 hours
Acute LC50 16940 µg/l Fresh water Fish - Carassius auratus 96 hours Acute LC50 15700 µg/l Fresh water Fish - Lepomis macrochirus - Juvenile (Fledgling, Hatchling,
Weanling)
96 hours
Acute LC50 20870 µg/l Fresh water Fish - Lepomis macrochirus 96 hours Acute LC50 19000 µg/l Fresh water Fish - Lepomis macrochirus 96 hours Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hours 3,6-diazaoctanethylenediamin Acute EC50 3700 µg/l Fresh water Algae - Pseudokirchneriella subcapitata
96 hours
Acute LC50 33900 µg/l Fresh water Daphnia - Daphnia magna 48 hours ethylbenzene Acute EC50 4600 µg/l Fresh water Algae - Pseudokirchneriella subcapitata
72 hours
Acute EC50 5400 µg/l Fresh water Algae - Pseudokirchneriella subcapitata
72 hours
Acute EC50 3600 µg/l Fresh water Algae - Pseudokirchneriella subcapitata
96 hours
Acute EC50 4900 µg/l Marine water Algae - Skeletonema costatum 72 hours Acute EC50 7700 µg/l Marine water Algae - Skeletonema costatum 96 hours Acute EC50 6.53 mg/l Marine water Crustaceans - Artemia sp. - Nauplii
48 hours
Date of issue/Date of revision : Date of previous issue : Version : 2 16/22
4/1/2026
12/4/2023
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Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects : No known significant effects or critical hazards.
Product/ingredient name
Isopropyl alcohol 0.05 - Low
butanone 0.3 - Low
trizinc bis(orthophosphate) - 60960 High
butan-1-ol 1 - Low
n-butyl acetate 2.3 - Low
1-methoxy-2-propanol <1 - Low
xylene 3.12 8.1 to 25.9 Low
3,6-diazaoctanethylenediamin -1.66 to -1.4 - Low
ethylbenzene 3.6 - Low
Persistence and degradability
Soil/Water partition
coefficient
: Not available.
Mobility in soil
Not available.
Acute EC50 13.3 mg/l Marine water Crustaceans - Artemia sp. - Nauplii
48 hours
Acute EC50 2.97 mg/l Fresh water Daphnia - Daphnia magna - Neonate
48 hours
Acute EC50 2.93 mg/l Fresh water Daphnia - Daphnia magna - Neonate
48 hours
Acute LC50 8.78 mg/l Marine water Crustaceans - Artemia sp. - Nauplii
48 hours
Acute LC50 13.3 mg/l Marine water Crustaceans - Artemia sp. - Nauplii
48 hours
Acute LC50 40000 µg/l Marine water Crustaceans - Cancer magister - Zoea
48 hours
Acute LC50 18.4 mg/l Fresh water Daphnia - Daphnia magna - Neonate
48 hours
Acute LC50 13.9 mg/l Fresh water Daphnia - Daphnia magna - Neonate
48 hours
Acute LC50 75000 µg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 5100 µg/l Marine water Fish - Menidia menidia 96 hours Acute LC50 4.3 ul/L Marine water Fish - Morone saxatilis - Juvenile (Fledgling, Hatchling, Weanling)
96 hours
Acute LC50 4200 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours Acute LC50 9090 µg/l Fresh water Fish - Pimephales promelas 96 hours Acute LC50 9100 µg/l Fresh water Fish - Pimephales promelas 96 hours Date of issue/Date of revision : Date of previous issue : Version : 2 17/22
4/1/2026
12/4/2023
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Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Disposal methods :
RCRA Toxic hazardous waste "U" List
butanone 78-93-3 Listed U159
butan-1-ol 71-36-3 Listed U031
Reaction mass of ethylbenzene and xylene - Listed U239
Ingredient CAS # Status Reference
number
Section 14. Transport information
The information provided in section 14 is based on a bulk package shipment via ground transport in North America. All shippers are responsible for ensuring the proper transportation classification and package/container requirements are followed for the relevant mode of transport.
Reportable quantity 7073.9 lbs / 3211.6 kg [557.06 gal / 2108.7 L]. Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements.
Additional information
DOT Classification :
The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.
IMDG : Emergency schedules F-E, _S-E_
PAINT
3 II
UN1263
PAINT
3 II
PAINT
UN1263
3 II
UN1263
DOT Classification IMDG IATA
No. Yes. The environmentally
hazardous substance mark is
not required.
UN number
UN proper shipping
name
Transport hazard
class(es)
Packing group
Environmental
hazards
IATA : The environmentally hazardous substance mark may appear if required by other transportation regulations.
Marine Pollutant(s):
trizinc bis(orthophosphate)
Date of issue/Date of revision : Date of previous issue : Version : 2 18/22
4/1/2026
12/4/2023
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Section 14. Transport information
Special precautions for user
Transport in bulk according
to IMO instruments
Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
: Not available.
:
Section 15. Regulatory information
U.S. Federal regulations :
United States inventory (TSCA 8b): All components are active or exempted.
SARA 311/312
Classification : FLAMMABLE LIQUIDS - Category 2
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 1A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3
Composition/information on ingredients
Name % Classification
titanium dioxide ≥10 - ≤25 CARCINOGENICITY - Category 2 Fatty acids, C18-unsatd., dimers,
oligomeric reaction products
with tall-oil fatty acids and
triethylenetetramine
≥10 - ≤25 SERIOUS EYE DAMAGE - Category 1
Isopropyl alcohol ≤10 FLAMMABLE LIQUIDS - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
SARA 302/304
Composition/information on ingredients
No products were found.
SARA 304 RQ : Not applicable.
TSCA 5(e) substance consent order: No products found.
TSCA 5(a)2 final significant new use rules: No products found.
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
Clean Water Act (CWA) 307: trizinc bis(orthophosphate); ethylbenzene; toluene Clean Water Act (CWA) 311: n-butyl acetate; Reaction mass of ethylbenzene and xylene
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
: Listed
Clean Air Act Section 602
Class I Substances
: Not listed
Clean Air Act Section 602
Class II Substances
: Not listed
DEA List I Chemicals
(Precursor Chemicals)
: Not listed
DEA List II Chemicals
(Essential Chemicals)
: Not listed
Date of issue/Date of revision : Date of previous issue : Version : 2 19/22
4/1/2026
12/4/2023
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Section 15. Regulatory information
The following components are listed: TALC; TITANIUM DIOXIDE; ISOPROPYL ALCOHOL; METHYL ETHYL KETONE; N-BUTYL ALCOHOL; BUTYL ACETATE; PROPYLENE GLYCOL METHYL ETHER; XYLENE
Massachusetts :
State regulations
SARA 313
Product name CAS number %
trizinc bis(orthophosphate) 7779-90-0 ≤10
butan-1-ol 71-36-3 ≤5
xylene 1330-20-7 ≤2
ethylbenzene 100-41-4 <1
Form R - Reporting
requirements
Supplier notification trizinc bis(orthophosphate) 7779-90-0 ≤10 butan-1-ol 71-36-3 ≤5
xylene 1330-20-7 ≤2
ethylbenzene 100-41-4 <1
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed. butanone ≤10 FLAMMABLE LIQUIDS - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
butan-1-ol ≤5 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (oral) - Category 4
SKIN IRRITATION - Category 2
SERIOUS EYE DAMAGE - Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
n-butyl acetate ≤5 FLAMMABLE LIQUIDS - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
1-methoxy-2-propanol ≤5 FLAMMABLE LIQUIDS - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
xylene ≤2 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (dermal) - Category 4
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
ASPIRATION HAZARD - Category 1
3,6-diazaoctanethylenediamin <1 ACUTE TOXICITY (dermal) - Category 4 SKIN CORROSION - Category 1B
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1
ethylbenzene <1 FLAMMABLE LIQUIDS - Category 2
ACUTE TOXICITY (inhalation) - Category 4
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
Crystalline Silica, respirable part
in whole product, <10µm
≤0.3 CARCINOGENICITY - Category 1A
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 1
Date of issue/Date of revision : Date of previous issue : Version : 2 20/22
4/1/2026
12/4/2023
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Section 15. Regulatory information
California Prop. 65
New York : The following components are listed: Methyl ethyl ketone; Butyl alcohol; Butyl acetate; Xylene mixed
New Jersey : The following components are listed: TALC (NOT CONTAINING ASBESTOS FIBERS); TITANIUM DIOXIDE; ISOPROPYL ALCOHOL; METHYL ETHYL KETONE; ZINC compounds; n-BUTYL ALCOHOL; n-BUTYL ACETATE; PROPYLENE GLYCOL MONOMETHYL ETHER; XYLENES; SILICA, QUARTZ
Pennsylvania : The following components are listed: TALC; TITANIUM OXIDE; 2-PROPANOL; 2-BUTANONE; ZINC COMPOUNDS; 1-BUTANOL; ACETIC ACID, BUTYL ESTER; 2-PROPANOL, 1-METHOXY-; BENZENE, DIMETHYLAustralia : Not determined.
Canada : All components are listed or exempted.
China : Not determined.
Japan : Japan inventory (CSCL): Not determined.
Japan inventory (ISHL): Not determined.
Republic of Korea : Not determined.
New Zealand : Not determined.
Philippines : Not determined.
Taiwan : Not determined.
Turkey : Not determined.
United States : All components are active or exempted.
Thailand : Not determined.
Viet Nam : Not determined.
Eurasian Economic Union : Russian Federation inventory: Not determined.
Inventory list
WARNING: This product can expose you to chemicals including Titanium dioxide, Ethylbenzene and Silica, crystalline, which are known to the State of California to cause cancer, and Toluene, which is known to the State of California to cause birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov. titanium dioxide - - ethylbenzene Yes. - Crystalline Silica, respirable part in whole product, <10µm - - toluene - Yes.
Ingredient name No significant risk
level
Maximum
acceptable dosage
level
Section 16. Other information
History
Procedure used to derive the classification
Classification Justification
FLAMMABLE LIQUIDS - Category 2 On basis of test data
SERIOUS EYE DAMAGE - Category 1 Calculation method
SKIN SENSITIZATION - Category 1 Calculation method
CARCINOGENICITY - Category 1A Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3
Calculation method
Date of printing : 4/2/2026
Date of issue/Date of revision : Date of previous issue : Version : 2 21/22
4/1/2026
12/4/2023
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Section 16. Other information
Notice to reader
Indicates information that has changed from previously issued version.
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available
SGG = Segregation Group
UN = United Nations
Unique ID : 1710D167A4331FD18BB060330D29076D
Version : 2
Date of issue/ Date of
revision
Date of previous issue
:
:
4/1/2026
12/4/2023
IMPORTANT NOTE: the information contained in this data sheet (as may be amended from time to time) is not intended to be exhaustive and is presented in good faith and believed to be correct as of the date on which it is prepared. It is the userˈs responsibility to verify that this data sheet is current prior to using the product to which it relates.
Persons using the information must make their own determinations as to the suitability of the relevant product for their purposes prior to use. Where those purposes are other than as specifically recommended in this safety data sheet, then the user uses the product at their own risk.
MANUFACTURER’S DISCLAIMER: the conditions, methods and factors affecting the handling, storage, application, use and disposal of the product are not under the control and knowledge of the manufacturer. Therefore the manufacturer does not assume responsibility for any adverse events which may occur in the handling, storage, application, use, misuse or disposal of the product and, so far as permitted by applicable law, the manufacturer expressly disclaims liability for any and all loss, damages and/or expenses arising out of or in any way connected to the storage, handling, use or disposal of the product. Safe handling, storage, use and disposal are the responsibility of the users. Users must comply with all applicable health and safety laws.
Unless we have agreed to the contrary, all products are supplied by us subject to our standard terms and conditions of business, which include limitations of liability. Please make sure to refer to these and / or the relevant agreement which you have with AkzoNobel (or its affiliate, as the case may be). © AkzoNobel
Date of issue/Date of revision : Date of previous issue : Version : 2 22/22
4/1/2026
12/4/2023
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SAFETY DATA SHEET
GHS product identifier
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
545 EPOXY PRIMER Gray Base
Relevant identified uses of the substance or mixture and uses advised against Identified uses
Uses advised against
Professional use
Industrial use
Consumer use
Product use : Two component coating for exterior use.
Supplier's details
Akzo Nobel Coatings Ltd.
4-110 Woodbine Downs Blvd.
Etobicoke ON M9W 5S6
Canada
International Paint (International) 1-713-682-1711
CHEMTREC (USA) +1 (800) 424-9300 (24Hr)
CHEMTREC (International) +1 (703) 527-3887
Domestic Poison Control Center Customer Service +1 (800) 854-6813 Akzo Nobel Coatings
International Paint LLC
6001 Antoine Drive
Houston, Texas 77091
International Paint 1-800-589-1267
International Paint (International) 1-713-682-1711
Akzo Nobel Performance Coatings, S.A. de C.V.
Anillo Periférico #205 Km16.64
Hacienda San José
García, Nuevo Leon, Mexico.
CP 66000
RFC: ANA9510267C4
SDS code : OD1001
Section 2. Hazards identification
FLAMMABLE LIQUIDS - Category 2
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 1A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3
Classification of the
substance or mixture
:
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Date of issue/Date of revision : Date of previous issue : 1/289/17/2026 No previous validation
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 240
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Section 2. Hazards identification
Signal word : Danger
Hazard statements : Highly flammable liquid and vapor.
May cause an allergic skin reaction.
Causes serious eye damage.
May cause drowsiness or dizziness.
May cause cancer.
Hazard pictograms :
Precautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use only outdoors or in a well-ventilated area. Avoid breathing vapor. Contaminated work clothing must not be allowed out of the workplace.
Response : IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. If skin irritation or rash occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor.
Storage : Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national or international regulations.
GHS label elements
Hazards not otherwise
classified
: None known.
Hazards identified when
used
: No known significant effects or critical hazards.
This product contains TiO2 which has been classified as a GHS Carcinogen Category 2 based on its IARC 2B classification. For many products, TiO2 is utilized as a raw material in a liquid coating formulation. In this case, the TiO2 particles are bound in a matrix with no meaningful potential for human exposure to unbound particles of TiO2 when the product is applied with a brush or roller. Sanding the coating surface or mist from spray applications may be harmful depending on the duration and level of exposure and require the use of appropriate personal protective equipment and/or engineering controls (see Section 8).
Section 3. Composition/information on ingredients
Ingredient name % Identifiers
Substance/mixture : Mixture
Talc , not containing asbestiform fibres ≥10 - ≤30 14807-96-6 titanium dioxide ≥7 - ≤13 13463-67-7
Fatty acids, C18-unsatd., dimers, oligomeric reaction products with tall-oil fatty acids and triethylenetetramine
≥7 - ≤13 68082-29-1
calcium carbonate ≥7 - ≤13 471-34-1
Isopropyl alcohol ≥5 - ≤10 67-63-0
Date of issue/Date of revision : Date of previous issue : 2/289/17/2026 No previous validation
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 241
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Section 3. Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Any concentration shown as a range is to protect confidentiality or is due to batch variation. trizinc bis(orthophosphate) ≥3 - ≤7 7779-90-0
butanone ≥3 - ≤7 78-93-3
butan-1-ol ≥1 - ≤5 71-36-3
1-methoxy-2-propanol ≥1 - ≤5 107-98-2
n-butyl acetate ≥1 - ≤5 123-86-4
xylene ≥0.5 - ≤1.5 1330-20-7
3,6-diazaoctanethylenediamin ≥0.1 - ≤1 112-24-3
carbon black, respirable powder ≥0.1 - ≤1 1333-86-4
ethylbenzene ≥0.1 - ≤1 100-41-4
Crystalline Silica, respirable part in whole product, <10µm ≥0.1 - ≤1 14808-60-7 2,3-epoxypropyl neodecanoate ≤0.1 26761-45-5
Get medical attention. If necessary, call a poison center or physician. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses if easy to do. Chemical burns must be treated promptly by a physician.
Get medical attention if adverse health effects persist or are severe. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention if irritation occurs.
Get medical attention. If necessary, call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Date of issue/Date of revision : Date of previous issue : 3/289/17/2026 No previous validation
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 242
545 EPOXY PRIMER Gray Base
Section 4. First aid measures
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness.
Ingestion : Can cause central nervous system (CNS) depression.
Skin contact : May cause an allergic skin reaction.
Eye contact : Causes serious eye damage.
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Adverse symptoms may include the following:
stomach pains
Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
:
:
:
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
phosphorus oxides
metal oxide/oxides
Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion.
Use dry chemical, CO₂, water spray (fog) or foam.
Extinguishing media
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Date of issue/Date of revision : Date of previous issue : 4/289/17/2026 No previous validation
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 243
545 EPOXY PRIMER Gray Base
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Dispose of via a licensed waste disposal contractor.
Contaminated absorbent material may pose the same hazard as the spilled product.
Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations.
:
: No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Absorb with an inert material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
Section 7. Handling and storage
Advice on general
occupational hygiene
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Date of issue/Date of revision : Date of previous issue : 5/289/17/2026 No previous validation
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 244
545 EPOXY PRIMER Gray Base
Section 7. Handling and storage
Conditions for safe storage,
including any
incompatibilities
Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. :
Talc , not containing asbestiform fibres ACGIH TLV (United States, 1/2025) A4.
TWA 8 hours: 2 mg/m³. Form: Respirable
fraction.
NIOSH REL (United States, 10/2020)
TWA 10 hours: 2 mg/m³. Form: Respirable
fraction.
OSHA PEL 1989 (United States, 3/1989)
TWA 8 hours: 2 mg/m³. Form: Respirable
dust.
titanium dioxide ACGIH TLV (United States, 1/2025) A3.
TWA 8 hours: 2.5 mg/m³. Form: respirable
fraction, finescale particles.
NIOSH REL (United States, 10/2020) NIA.
OSHA PEL 1989 (United States, 3/1989)
TWA 8 hours: 10 mg/m³. Form: Total dust.
Fatty acids, C18-unsatd., dimers, oligomeric reaction products with talloil fatty acids and triethylenetetramineNone. calcium carbonate NIOSH REL (United States, 10/2020)
[calcium carbonate]
TWA 10 hours: 10 mg/m³. Form: Total.
TWA 10 hours: 5 mg/m³. Form: Respirable
fraction.
Isopropyl alcohol ACGIH TLV (United States, 1/2025) A4.
TWA 8 hours: 200 ppm.
STEL 15 minutes: 400 ppm.
NIOSH REL (United States, 10/2020)
TWA 10 hours: 400 ppm.
TWA 10 hours: 980 mg/m³.
STEL 15 minutes: 500 ppm.
STEL 15 minutes: 1225 mg/m³.
OSHA PEL 1989 (United States, 3/1989)
TWA 8 hours: 400 ppm.
TWA 8 hours: 980 mg/m³.
STEL 15 minutes: 500 ppm.
STEL 15 minutes: 1225 mg/m³.
trizinc bis(orthophosphate) None.
butanone ACGIH TLV (United States, 1/2025)
Absorbed through skin.
TWA 8 hours: 75 ppm.
STEL 15 minutes: 150 ppm.
NIOSH REL (United States, 10/2020)
TWA 10 hours: 200 ppm.
TWA 10 hours: 590 mg/m³.
STEL 15 minutes: 300 ppm.
STEL 15 minutes: 885 mg/m³.
OSHA PEL 1989 (United States, 3/1989)
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
Date of issue/Date of revision : Date of previous issue : 6/289/17/2026 No previous validation
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 245
545 EPOXY PRIMER Gray Base
Section 8. Exposure controls/personal protection
TWA 8 hours: 200 ppm.
TWA 8 hours: 590 mg/m³.
STEL 15 minutes: 300 ppm.
STEL 15 minutes: 885 mg/m³.
butan-1-ol ACGIH TLV (United States, 1/2025)
TWA 8 hours: 20 ppm.
NIOSH REL (United States, 10/2020)
Absorbed through skin.
CEIL: 50 ppm.
CEIL: 150 mg/m³.
OSHA PEL 1989 (United States, 3/1989)
Absorbed through skin.
CEIL: 50 ppm.
CEIL: 150 mg/m³.
1-methoxy-2-propanol ACGIH TLV (United States, 1/2025) A4.
TWA 8 hours: 50 ppm.
TWA 8 hours: 184 mg/m³.
STEL 15 minutes: 100 ppm.
STEL 15 minutes: 369 mg/m³.
NIOSH REL (United States, 10/2020)
TWA 10 hours: 100 ppm.
TWA 10 hours: 360 mg/m³.
STEL 15 minutes: 150 ppm.
STEL 15 minutes: 540 mg/m³.
OSHA PEL 1989 (United States, 3/1989)
TWA 8 hours: 100 ppm.
TWA 8 hours: 360 mg/m³.
STEL 15 minutes: 150 ppm.
STEL 15 minutes: 540 mg/m³.
n-butyl acetate ACGIH TLV (United States, 1/2025) [Butyl acetates]
STEL 15 minutes: 150 ppm.
TWA 8 hours: 50 ppm.
NIOSH REL (United States, 10/2020)
TWA 10 hours: 150 ppm.
TWA 10 hours: 710 mg/m³.
STEL 15 minutes: 200 ppm.
STEL 15 minutes: 950 mg/m³.
OSHA PEL 1989 (United States, 3/1989)
TWA 8 hours: 150 ppm.
TWA 8 hours: 710 mg/m³.
STEL 15 minutes: 200 ppm.
STEL 15 minutes: 950 mg/m³.
xylene ACGIH TLV (United States, 1/2025) [pxylene and mixtures containing p-xylene] A4. Ototoxicant.
TWA 8 hours: 20 ppm.
OSHA PEL 1989 (United States, 3/1989)
[Xylenes (o-, m-, p-isomers)]
TWA 8 hours: 100 ppm.
TWA 8 hours: 435 mg/m³.
STEL 15 minutes: 150 ppm.
STEL 15 minutes: 655 mg/m³.
3,6-diazaoctanethylenediamin None.
carbon black, respirable powder ACGIH TLV (United States, 1/2025) A3.
TWA 8 hours: 3 mg/m³. Form: Inhalable
fraction.
NIOSH REL (United States, 10/2020) NIA.
TWA 10 hours: 3.5 mg/m³.
Date of issue/Date of revision : Date of previous issue : 7/289/17/2026 No previous validation
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 246
545 EPOXY PRIMER Gray Base
Section 8. Exposure controls/personal protection
TWA 10 hours: 0.1 mg/m³ (as cyclohexaneextractable fraction).
OSHA PEL 1989 (United States, 3/1989)
TWA 8 hours: 3.5 mg/m³.
ethylbenzene ACGIH TLV (United States, 1/2025) A3.
Ototoxicant.
TWA 8 hours: 20 ppm.
NIOSH REL (United States, 10/2020)
TWA 10 hours: 100 ppm.
TWA 10 hours: 435 mg/m³.
STEL 15 minutes: 125 ppm.
STEL 15 minutes: 545 mg/m³.
OSHA PEL 1989 (United States, 3/1989)
TWA 8 hours: 100 ppm.
TWA 8 hours: 435 mg/m³.
STEL 15 minutes: 125 ppm.
STEL 15 minutes: 545 mg/m³.
Crystalline Silica, respirable part in whole product, <10µm ACGIH TLV (United States, 1/2025) [Silica, crystalline] A2.
TWA 8 hours: 0.025 mg/m³. Form:
Respirable fraction.
NIOSH REL (United States, 10/2020)
[SILICA, CRYSTALLINE] NIA.
TWA 10 hours: 0.05 mg/m³. Form: respirable
dust.
OSHA PEL 1989 (United States, 3/1989)
TWA 8 hours: 0.1 mg/m³ (as quartz). Form:
Respirable dust.
2,3-epoxypropyl neodecanoate None.
Environmental exposure
controls
: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Biological exposure indices
Isopropyl alcohol ACGIH BEI (United States, 1/2025)
BEI: 40 mg/l, acetone [in urine]. Sampling
time: end of shift at end of workweek.
butanone ACGIH BEI (United States, 1/2025)
BEI: 2 mg/l, methyl ethyl ketone [in urine].
Sampling time: end of shift.
xylene ACGIH BEI (United States, 1/2025) [xylenes
(technical or commercial grades)]
BEI: 0.3 g/g creatinine, methylhippuric acids
[in urine]. Sampling time: end of shift.
ethylbenzene ACGIH BEI (United States, 1/2025)
BEI: 150 mg/g creatinine, sum of mandelic
acid and phenylglyoxylic acid [in urine].
Sampling time: end of shift.
Ingredient name Exposure indices
Date of issue/Date of revision : Date of previous issue : 8/289/17/2026 No previous validation
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545 EPOXY PRIMER Gray Base
Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet sanding/flatting should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Wear a respirator conforming to EN140 with type A/P2 filter or better.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/ or face shield. If inhalation hazards exist, a full-face respirator may be required instead.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear antistatic protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.
:
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Section 9. Physical and chemical properties
Melting point/freezing point Not available.
Odor Solvent.
pH
Color Gray.
Evaporation rate Not available.
Not applicable. [DIN EN 1262]
Odor threshold Not available.
:
:
:
:
:
:
Appearance
Flammability : Not available.
The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.
Physical state : Liquid.
Flash point : Closed cup: -7°C (19.4°F) [Pensky-Martens] Boiling point or initial
boiling point and boiling
range
: 79°C (174.2°F)
Date of issue/Date of revision : Date of previous issue : 9/289/17/2026 No previous validation
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 248
545 EPOXY PRIMER Gray Base
Section 9. Physical and chemical properties
Relative vapor density
Solubility(ies)
Not available.
Not applicable.
Viscosity Kinematic (room temperature): 462 mm2/s (462 cSt) [DIN EN ISO 3219] Kinematic (40°C (104°F)): 700 mm2/s (700 cSt) [DIN EN ISO 3219] Partition coefficient: noctanol/water
:
:
:
:
Decomposition temperature : Not available.
Particle characteristics
Median particle size : Not applicable.
Media Result
cold water Not soluble [OECD (TG 105)]
cold water Not soluble [OECD (TG 105)]
Aerodynamic particle size
distribution
:
≤ 10 μm 0
Aerodynamic diameter Percentage of particles
Lower and upper explosion
limit
: Greatest known range: Lower: 1.48% Upper: 13.74% (1-methoxy-2-propanol) Vapor pressure : There are no data available on the mixture itself.
Auto-ignition temperature : There are no data available on the mixture itself.
Density : 1.516 g/cm³ [DIN EN ISO 2811-1]
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
Chemical stability The product is stable.
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Information on toxicological effects
There are no data available on the mixture itself.
The mixture has been assessed following the weight of evidence and calculation methods of the Occupational Safety and Health Administration (OSHA) Hazard Communication Standard (HCS) (29 CFR 1910.1200) and is classified for toxicological properties accordingly. See Sections 2 and 3 for details.
Date of issue/Date of revision : Date of previous issue : 10/289/17/2026 No previous validation
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 249
545 EPOXY PRIMER Gray Base
Section 11. Toxicological information
calcium carbonate Rat - Oral - LD50 6450 mg/kg -
Isopropyl alcohol Rat - Oral - LD50 5045 mg/kg Toxic effects:
Behavioral - Altered
sleep time (including
change in righting
reflex) Behavioral -
Somnolence (general
depressed activity)
Rat - Intraperitoneal - LD50 2735 mg/kg - Rat - Intravenous - LD50 1088 mg/kg - Mouse - Oral - LD50 3600 mg/kg Toxic effects:
Behavioral - Altered
sleep time (including
change in righting
reflex) Behavioral -
Somnolence (general
depressed activity)
Mouse - Intraperitoneal - LD50 4477 mg/kg - Rabbit - Oral - LD50 6410 mg/kg - Rabbit - Dermal - LD50 12800 mg/kg - Rabbit - Intraperitoneal - LD50 667 mg/kg - Rabbit - Intravenous - LD50 1184 mg/kg - Guinea pig - Intraperitoneal - LD50
2560 mg/kg - Mouse - Oral - LD50 3600 mg/kg Toxic effects:
Behavioral - General
anesthetic
Rat - Oral - LD50 5000 mg/kg Toxic effects:
Behavioral - General
anesthetic
Mouse - Intravenous - LD50 1509 mg/kg - Rat - Inhalation - LC50 Gas. 16000 ppm [8 hours] - trizinc bis(orthophosphate) Mouse - Intraperitoneal - LD50 552 mg/kg Toxic effects: Lung, Thorax, or
Respiration - Other
changes
Rat - Intraperitoneal - LD50 551 mg/kg - butanone Rabbit - Dermal - LD50 6480 mg/kg - Mouse - Oral - LD50 3000 mg/kg - Rat - Oral - LD50 2737 mg/kg - Rat - Intraperitoneal - LD50 607 mg/kg - Product/ingredient name Result Dose Effects
Date of issue/Date of revision : Date of previous issue : 11/289/17/2026 No previous validation
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 250
545 EPOXY PRIMER Gray Base
Section 11. Toxicological information
Mouse - Intraperitoneal - LD50 616 mg/kg - Guinea pig - Intraperitoneal - LD50
2 g/kg - Rat - Inhalation - LC50 Vapor 23500 mg/m³ [8 hours] - Mouse - Inhalation - LC50 Vapor 32 g/m³ [4 hours] - butan-1-ol Rat - Oral - LD50 790 mg/kg Toxic effects: Liver - Fatty liver
degeneration Kidney,
Ureter, and Bladder -
Other changes Blood -
Other changes
Rabbit - Dermal - LD50 3400 mg/kg - Rat - Inhalation - LC50 Vapor 24000 mg/m³ [4 hours] - 1-methoxy-2-propanol Rat - Intraperitoneal - LD50 3720 mg/kg - Rat - Subcutaneous - LD50 7800 mg/kg Toxic effects:
Behavioral -
Convulsions or effect
on seizure threshold
Behavioral - Ataxia
Lung, Thorax, or
Respiration - Dyspnea
Rat - Intravenous - LD50 4200 mg/kg Toxic effects:
Behavioral -
Convulsions or effect
on seizure threshold
Behavioral - Ataxia
Lung, Thorax, or
Respiration - Dyspnea
Mouse - Oral - LD50 11700 mg/kg Toxic effects:
Behavioral -
Convulsions or effect
on seizure threshold
Behavioral - Ataxia
Lung, Thorax, or
Respiration - Dyspnea
Mouse - Intravenous - LD50 5300 mg/kg Toxic effects:
Behavioral -
Convulsions or effect
on seizure threshold
Behavioral - Ataxia
Lung, Thorax, or
Respiration - Dyspnea
Rabbit - Oral - LD50 5700 mg/kg - Rabbit - Dermal - LD50 13 g/kg - Rabbit - Subcutaneous - LD50 5 g/kg - Rabbit - Intravenous - LD50 1200 mg/kg - Rat - Oral - LD50 6600 mg/kg Toxic effects: Brain and Coverings - Other
Date of issue/Date of revision : Date of previous issue : 12/289/17/2026 No previous validation
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 251
545 EPOXY PRIMER Gray Base
Section 11. Toxicological information
degenerative changes
Behavioral - General
anesthetic Lung,
Thorax, or
Respiration - Dyspnea
Rat - Inhalation - LC50 Gas. 10000 ppm [5 hours] - n-butyl acetate Rat - Oral - LD50 10768 mg/kg Toxic effects:
Behavioral -
Somnolence (general
depressed activity)
Lung, Thorax, or
Respiration - Other
changes Liver - Other
changes
xylene Rat - Oral - LD50 4300 mg/kg Toxic effects: Liver - Other changes Kidney,
Ureter, and Bladder -
Other changes
Rat - Subcutaneous - LD50 1700 mg/kg - 3,6-diazaoctanethylenediamin Rat - Oral - LD50 2500 mg/kg - Mouse - Intraperitoneal - LD50 468 mg/kg - Mouse - Intravenous - LD50 350 mg/kg - Rabbit - Oral - LD50 5500 mg/kg - Mouse - Oral - LD50 38.5 mg/kg - carbon black, respirable powder Rat - Oral - LD50 >15400 mg/kg Toxic effects:
Behavioral -
Somnolence (general
depressed activity)
ethylbenzene Rat - Oral - LD50 3500 mg/kg Toxic effects: Liver - Other changes Kidney,
Ureter, and Bladder -
Other changes
Mouse - Intraperitoneal - LD50 2624 ul/kg - Rabbit - Dermal - LD50 17800 ul/kg - Rat - Oral - LD50 3500 mg/kg - Rabbit - Dermal - LD50 >5000 mg/kg - Rat - Inhalation - LC50 Vapor 55000 mg/m³ [2 hours] - Mouse - Inhalation - LC50 Vapor 35500 mg/m³ [2 hours] - Rabbit - Inhalation - LC50 Gas. 4000 ppm [4 hours] - 2,3-epoxypropyl neodecanoate Rat - Oral - LD50 >10 g/kg Toxic effects:
Behavioral - Ataxia
Gross Metabolite
Changes - Weight
loss or decreased
weight gain
Date of issue/Date of revision : Date of previous issue : 13/289/17/2026 No previous validation
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 252
545 EPOXY PRIMER Gray Base
Section 11. Toxicological information
Conclusion/Summary [Product] : Not available.
Skin corrosion/irritation
calcium carbonate Rabbit - Skin - Moderate irritant
Duration of treatment/exposure: 24 hours
Amount/concentration applied: 500 mg
Isopropyl alcohol Rabbit - Skin - Mild irritant
Amount/concentration applied: 500 mg
butanone Rabbit - Skin - Mild irritant
Duration of treatment/exposure: 24 hours
Amount/concentration applied: 14 mg
Rabbit - Skin - Mild irritant
Duration of treatment/exposure: 24 hours
Amount/concentration applied: 402 mg
Rabbit - Skin - Moderate irritant
Duration of treatment/exposure: 24 hours
Amount/concentration applied: 500 mg
butan-1-ol Rabbit - Skin - Moderate irritant
Duration of treatment/exposure: 24 hours
Amount/concentration applied: 20 mg
1-methoxy-2-propanol Rabbit - Skin - Mild irritant
Amount/concentration applied: 500 mg
n-butyl acetate Rabbit - Skin - Moderate irritant
Duration of treatment/exposure: 24 hours
Amount/concentration applied: 500 mg
xylene Rat - Skin - Mild irritant
Duration of treatment/exposure: 8 hours
Amount/concentration applied: 60 Ul
Rabbit - Skin - Moderate irritant
Duration of treatment/exposure: 24 hours
Amount/concentration applied: 500 mg
Rabbit - Skin - Moderate irritant
Amount/concentration applied: 100 %
3,6-diazaoctanethylenediamin Rabbit - Skin - Severe irritant Duration of treatment/exposure: 24 hours
Amount/concentration applied: 5 mg
Rabbit - Skin - Severe irritant
Amount/concentration applied: 490 mg
ethylbenzene Rabbit - Skin - Mild irritant
Duration of treatment/exposure: 24 hours
Amount/concentration applied: 15 mg
2,3-epoxypropyl neodecanoate Rabbit - Skin - Moderate irritant Amount/concentration applied: 0.5 Ml
Product/ingredient name Result
Conclusion/Summary [Product] : Not available.
Serious eye damage/eye irritation
calcium carbonate Rabbit - Eyes - Severe irritant
Duration of treatment/exposure: 24 hours
Amount/concentration applied: 750 ug
Isopropyl alcohol Rabbit - Eyes - Moderate irritant
Duration of treatment/exposure: 24 hours
Amount/concentration applied: 100 mg
Rabbit - Eyes - Moderate irritant
Amount/concentration applied: 10 mg
Rabbit - Eyes - Severe irritant
Product/ingredient name Result
Date of issue/Date of revision : Date of previous issue : 14/289/17/2026 No previous validation
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 253
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Section 11. Toxicological information
Classification
Conclusion/Summary [Product] Not available.
Amount/concentration applied: 100 mg
butan-1-ol Rabbit - Eyes - Severe irritant
Duration of treatment/exposure: 24 hours
Amount/concentration applied: 2 mg
Rabbit - Eyes - Severe irritant
Amount/concentration applied: 0.005 Ml
Rabbit - Eyes - Severe irritant
Amount/concentration applied: 1.62 mg
1-methoxy-2-propanol Rabbit - Eyes - Mild irritant
Duration of treatment/exposure: 24 hours
Amount/concentration applied: 500 mg
n-butyl acetate Rabbit - Eyes - Moderate irritant
Amount/concentration applied: 100 mg
xylene Rabbit - Eyes - Mild irritant
Amount/concentration applied: 87 mg
Rabbit - Eyes - Severe irritant
Duration of treatment/exposure: 24 hours
Amount/concentration applied: 5 mg
3,6-diazaoctanethylenediamin Rabbit - Eyes - Moderate irritant Duration of treatment/exposure: 24 hours
Amount/concentration applied: 20 mg
Rabbit - Eyes - Severe irritant
Amount/concentration applied: 49 mg
ethylbenzene Rabbit - Eyes - Severe irritant
Amount/concentration applied: 500 mg
:
Conclusion/Summary [Product] : Not available.
Respiratory corrosion/irritation
Not available.
Respiratory or skin sensitization
Not available.
Skin
: Not available.
Respiratory
: Not available.
Conclusion/Summary [Product]
Conclusion/Summary [Product]
Germ cell mutagenicity
Not available.
Conclusion/Summary [Product] : Not available.
Carcinogenicity
Not available.
Conclusion/Summary [Product] : Not available.
Date of issue/Date of revision : Date of previous issue : 15/289/17/2026 No previous validation
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 254
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Section 11. Toxicological information
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness.
Ingestion : Can cause central nervous system (CNS) depression.
Skin contact : May cause an allergic skin reaction.
Eye contact : Causes serious eye damage.
Potential acute health effects
Talc , not containing
asbestiform fibres
- 3 -
titanium dioxide - 2B -
Isopropyl alcohol - 3 - xylene - 3 - carbon black, respirable powder
- 2B - ethylbenzene - 2B - Crystalline Silica, respirable part in whole product, <10µm
- 1 Known to be a human carcinogen.
Product/ingredient name OSHA IARC NTP
Reproductive toxicity
: Not available.
Not available.
Conclusion/Summary [Product]
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Isopropyl alcohol SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3
butanone SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3
butan-1-ol SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
1-methoxy-2-propanol SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3
n-butyl acetate SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3
xylene SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3
Product/ingredient name Result
Product/ingredient name Result
ethylbenzene SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) (hearing organs) - Category 2
Crystalline Silica, respirable part in whole
product, <10µm
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) (lungs) (inhalation) - Category 1
Aspiration hazard
Product/ingredient name Result
xylene ASPIRATION HAZARD - Category 1
ethylbenzene ASPIRATION HAZARD - Category 1
Information on the likely routes of exposure
Not available.
Date of issue/Date of revision : Date of previous issue : 16/289/17/2026 No previous validation
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 255
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Section 11. Toxicological information
Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.
General :
Carcinogenicity : May cause cancer. Risk of cancer depends on duration and level of exposure.
Mutagenicity : No known significant effects or critical hazards.
Reproductive toxicity : No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Adverse symptoms may include the following:
stomach pains
Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
:
:
:
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity
Acute toxicity estimates
Potential immediate
effects
: Not available.
Short term exposure
Potential delayed effects : Not available.
Potential immediate
effects
: Not available.
Long term exposure
Potential delayed effects : Not available.
Product/ingredient name
Product data 10539.8 70351.2 N/A 703.5 N/A
butan-1-ol 500 N/A N/A N/A N/A
xylene N/A 1100 N/A 11 N/A
3,6-diazaoctanethylenediamin 500 1100 N/A N/A N/A
ethylbenzene N/A N/A N/A 11 N/A
Oral (mg/
kg)
Dermal
(mg/kg)
Inhalation
(gases)
(ppm)
Inhalation
(vapors)
(mg/l)
Inhalation
(dusts
and mists)
(mg/l)
Not available.
Potential chronic health effects
Conclusion/Summary [Product] : Not available.
Date of issue/Date of revision : Date of previous issue : 17/289/17/2026 No previous validation
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 256
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Section 12. Ecological information
Toxicity
titanium dioxide Acute - LC50 - Fresh water Crustaceans - Water flea -
Ceriodaphnia
dubia - Neonate
15.9 mg/l [48
hours]
Effect:
Mortality
Acute - LC50 - Fresh water Fish - Fathead
minnow -
Pimephales
promelas
>1000 mg/l [96
hours]
Effect:
Mortality
calcium carbonate Chronic - NOEC - Fresh
water
Fish - Rainbow
trout,donaldson
trout -
Oncorhynchus
mykiss - Juvenile
(Fledgling,
Hatchling,
Weanling)
61 mg/g [28
days]
Effect:
Biochemistry
Chronic - NOEC - Fresh
water
Fish - Rainbow
trout,donaldson
trout -
Oncorhynchus
mykiss - Juvenile
(Fledgling,
Hatchling,
Weanling)
61 mg/g [42
days]
Effect:
Biochemistry
Chronic - NOEC - Fresh
water
Fish - Rainbow
trout,donaldson
trout -
Oncorhynchus
mykiss - Juvenile
(Fledgling,
Hatchling,
Weanling)
61 mg/g [35
days]
Effect:
Biochemistry
Chronic - NOEC - Fresh
water
Fish - Rainbow
trout,donaldson
trout -
Oncorhynchus
mykiss - Juvenile
(Fledgling,
Hatchling,
Weanling)
61 mg/g [42
days]
Effect:
Enzymes
Chronic - NOEC - Fresh
water
Fish - Rainbow
trout,donaldson
trout -
Oncorhynchus
mykiss - Juvenile
(Fledgling,
Hatchling,
Weanling)
61 mg/g [35
days]
Effect:
Accumulation
There are no data available on the mixture itself.
The mixture has been assessed following the weight of evidence and calculation methods of the Occupational Safety and Health Administration (OSHA) Hazard Communication Standard (HCS) (29 CFR 1910.1200) and is classified for ecotoxicological properties accordingly. See Sections 2 and 3 for details.
Product/ingredient name Result Species Dose Effects
Date of issue/Date of revision : Date of previous issue : 18/289/17/2026 No previous validation
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 257
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Section 12. Ecological information
Acute - LC50 - Fresh water Fish - Western
mosquitofish -
Gambusia affinis - Adult
>56000 ppm
[96 hours]
Effect:
Mortality
Isopropyl alcohol Acute - LC50 - Marine water Crustaceans - Common shrimp,
sand shrimp -
Crangon crangon
1400000 µg/l
[48 hours]
Effect:
Mortality
Acute - LC50 - Fresh water Fish - Fathead
minnow -
Pimephales
promelas
10400000 µg/l
[96 hours]
Effect:
Mortality
Acute - LC50 - Fresh water Fish - Fathead
minnow -
Pimephales
promelas
6550000 µg/l
[96 hours]
Effect:
Mortality
Acute - LC50 - Fresh water Fish - Fathead
minnow -
Pimephales
promelas
9640000 µg/l
[96 hours]
Effect:
Mortality
Acute - LC50 - Fresh water Fish -
Harlequinfish,
red rasbora -
Rasbora
heteromorpha
4200 mg/l [96
hours]
Effect:
Mortality
Acute - EC50 - Fresh water Daphnia - Water
flea - Daphnia
magna
10100 mg/l [48
hours]
Effect:
Intoxication
Acute - EC50 - Fresh water Fish - Fathead
minnow -
Pimephales
promelas
9550 mg/l [96
hours]
Effect:
Behavior
Acute - EC50 - Fresh water Daphnia - Water
flea - Daphnia
magna - Neonate
7550 mg/l [48
hours]
Effect:
Intoxication
trizinc bis(orthophosphate) Acute - LC50 - Fresh water Fish - Rainbow trout,donaldson
trout -
Oncorhynchus
mykiss
90 µg/l [96
hours]
Effect:
Mortality
butanone Acute - EC50 - Fresh water Daphnia - Water
flea - Daphnia
magna - Larvae
5091000 µg/l
[48 hours]
Effect:
Intoxication
Acute - LC50 - Fresh water Fish - Fathead
minnow -
Pimephales
promelas
3220000 µg/l
[96 hours]
Effect:
Mortality
Acute - EC50 - Marine water Algae - Diatom -
Skeletonema
costatum
>500000 µg/l
[96 hours]
Effect:
Population
Date of issue/Date of revision : Date of previous issue : 19/289/17/2026 No previous validation
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 258
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Section 12. Ecological information
Acute - EC50 - Fresh water Algae - Green
algae -
Pseudokirchneriella
subcapitata
>500 mg/l [96
hours]
Effect:
Population
Acute - LC50 - Fresh water Fish - Western
mosquitofish -
Gambusia affinis - Adult
5600 ppm [96
hours]
Effect:
Mortality
butan-1-ol Acute - LC50 - Fresh water Fish - Fathead
minnow -
Pimephales
promelas - Juvenile
(Fledgling,
Hatchling,
Weanling)
1910000 µg/l
[96 hours]
Effect:
Mortality
Acute - LC50 - Fresh water Fish - Fathead
minnow -
Pimephales
promelas - Juvenile
(Fledgling,
Hatchling,
Weanling)
1940000 µg/l
[96 hours]
Effect:
Mortality
Acute - LC50 - Marine water Fish - Bleak -
Alburnus alburnus
2300000 µg/l
[96 hours]
Effect:
Mortality
Acute - LC50 - Fresh water Fish - Fathead
minnow -
Pimephales
promelas
1730000 µg/l
[96 hours]
Effect:
Mortality
Acute - EC50 - Fresh water Daphnia - Water
flea - Daphnia
magna
1983 mg/l [48
hours]
Effect:
Intoxication
n-butyl acetate Acute - LC50 - Fresh water Fish - Zebra danio - Danio
rerio
62000 µg/l [96
hours]
Effect:
Mortality
Acute - LC50 - Marine water Crustaceans -
Brine shrimp -
Artemia salina
32 mg/l [48
hours]
Effect:
Mortality
xylene Acute - LC50 - Marine water Crustaceans -
Daggerblade
grass shrimp -
Palaemonetes
pugio
8500 µg/l [48
hours]
Effect:
Mortality
Acute - LC50 - Fresh water Fish - Fathead
minnow -
Pimephales
promelas
13400 µg/l [96
hours]
Effect:
Mortality
Acute - LC50 - Fresh water Fish - Goldfish -
Carassius
auratus
16940 µg/l [96
hours]
Effect:
Mortality
Date of issue/Date of revision : Date of previous issue : 20/289/17/2026 No previous validation
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 259
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Section 12. Ecological information
Acute - LC50 - Fresh water Fish - Bluegill -
Lepomis
macrochirus - Juvenile
(Fledgling,
Hatchling,
Weanling)
15700 µg/l [96
hours]
Effect:
Mortality
Acute - LC50 - Fresh water Fish - Bluegill -
Lepomis
macrochirus
20870 µg/l [96
hours]
Effect:
Mortality
Acute - LC50 - Fresh water Fish - Bluegill -
Lepomis
macrochirus
19000 µg/l [96
hours]
Effect:
Mortality
Acute - LC50 - Marine water Crustaceans -
Daggerblade
grass shrimp -
Palaemonetes
pugio - Adult
8.5 ppm [48
hours]
Effect:
Mortality
Acute - EC50 - Fresh water Crustaceans -
Ostracod -
Cypris
subglobosa
90 mg/l [48
hours]
Effect:
Intoxication
3,6-diazaoctanethylenediamin Acute - EC50 - Fresh water Algae - Green algae -
Pseudokirchneriella
subcapitata
3700 µg/l [96
hours]
Effect:
Population
Acute - LC50 - Fresh water Daphnia - Water
flea - Daphnia
magna
33900 µg/l [48
hours]
Effect:
Intoxication
carbon black, respirable powder Acute - EC50 - Fresh water Daphnia - Water flea - Daphnia
magna - Neonate
37.563 mg/l [48
hours]
Effect:
Intoxication
Acute - LC50 - Fresh water Daphnia - Water
flea - Daphnia
magna - Neonate
61.547 mg/l [48
hours]
Effect:
Mortality
ethylbenzene Acute - LC50 - Fresh water Daphnia - Water flea - Daphnia
magna
75000 µg/l [48
hours]
Effect:
Mortality
Acute - LC50 - Marine water Crustaceans -
Dungeness or
edible crab -
Cancer magister - Zoea
40000 µg/l [48
hours]
Effect:
Mortality
Acute - LC50 - Fresh water Fish - Fathead
minnow -
Pimephales
promelas
9090 µg/l [96
hours]
Effect:
Mortality
Acute - LC50 - Marine water Fish - Striped
bass - Morone
saxatilis - Juvenile
4.3 µl/l [96
hours]
Effect:
Mortality
Date of issue/Date of revision : Date of previous issue : 21/289/17/2026 No previous validation
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 260
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Section 12. Ecological information
(Fledgling,
Hatchling,
Weanling)
Acute - EC50 - Fresh water Algae - Green
algae -
Pseudokirchneriella
subcapitata
4600 µg/l [72
hours]
Effect: Growth
Acute - LC50 - Fresh water Fish - Rainbow
trout,donaldson
trout -
Oncorhynchus
mykiss
4200 µg/l [96
hours]
Effect:
Mortality
Acute - LC50 - Marine water Fish - Atlantic
silverside -
Menidia menidia
5100 µg/l [96
hours]
Effect:
Mortality
Acute - EC50 - Marine water Algae - Diatom -
Skeletonema
costatum
4900 µg/l [72
hours]
Effect:
Population
Acute - EC50 - Marine water Algae - Diatom -
Skeletonema
costatum
7700 µg/l [96
hours]
Effect:
Population
Acute - EC50 - Fresh water Algae - Green
algae -
Pseudokirchneriella
subcapitata
5400 µg/l [72
hours]
Effect:
Population
Acute - EC50 - Fresh water Algae - Green
algae -
Pseudokirchneriella
subcapitata
3600 µg/l [96
hours]
Effect:
Population
Acute - EC50 - Marine water Crustaceans -
Brine shrimp -
Artemia sp. - Nauplii
6.53 mg/l [48
hours]
Effect:
Intoxication
Acute - LC50 - Marine water Crustaceans -
Brine shrimp -
Artemia sp. - Nauplii
8.78 mg/l [48
hours]
Effect:
Mortality
Acute - LC50 - Marine water Crustaceans -
Brine shrimp -
Artemia sp. - Nauplii
13.3 mg/l [48
hours]
Effect:
Mortality
Acute - EC50 - Fresh water Daphnia - Water
flea - Daphnia
magna - Neonate
2.97 mg/l [48
hours]
Effect:
Intoxication
Acute - EC50 - Fresh water Daphnia - Water
flea - Daphnia
magna - Neonate
2.93 mg/l [48
hours]
Effect:
Intoxication
Acute - LC50 - Fresh water Daphnia - Water
flea - Daphnia
magna - Neonate
18.4 mg/l [48
hours]
Effect:
Mortality
Date of issue/Date of revision : Date of previous issue : 22/289/17/2026 No previous validation
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 261
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Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects
No known significant effects or critical hazards.
Product/ingredient name
Isopropyl alcohol 0.05 - Low
trizinc bis(orthophosphate) - 60960 High
butanone 0.3 - Low
butan-1-ol 1 - Low
1-methoxy-2-propanol <1 - Low
n-butyl acetate 2.3 - Low
xylene 3.12 8.1 to 25.9 Low
3,6-diazaoctanethylenediamin -1.66 to -1.4 - Low
ethylbenzene 3.6 - Low
2,3-epoxypropyl
neodecanoate
4.4 - High
Persistence and degradability
Soil/Water partition
coefficient
: Not available.
Mobility in soil
Acute - LC50 - Fresh water Daphnia - Water
flea - Daphnia
magna - Neonate
13.9 mg/l [48
hours]
Effect:
Mortality
Acute - LC50 - Fresh water Fish - Fathead
minnow -
Pimephales
promelas
9100 µg/l [96
hours]
Effect:
Mortality
Acute - EC50 - Marine water Crustaceans -
Brine shrimp -
Artemia sp. - Nauplii
13.3 mg/l [48
hours]
Effect:
Intoxication
Conclusion/Summary [Product] : Not available.
Not available.
Conclusion/Summary [Product] : Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Disposal methods :
RCRA Toxic hazardous waste "U" List
Date of issue/Date of revision : Date of previous issue : 23/289/17/2026 No previous validation
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 262
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Section 13. Disposal considerations
butanone 78-93-3 Listed U159
butan-1-ol 71-36-3 Listed U031
xylene 1330-20-7 Listed U239
Ingredient CAS # Status Reference
number
Section 14. Transport information
Special precautions for user
Transport in bulk according
to IMO instruments
Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
: Not available.
:
The information provided in section 14 is based on a bulk package shipment via ground transport in North America. All shippers are responsible for ensuring the proper transportation classification and package/container requirements are followed for the relevant mode of transport.
Reportable quantity 7229 lbs / 3282 kg [571.9 gal / 2164.9 L]. Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements.
Additional information
DOT Classification :
The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.
IMDG : Emergency schedules F-E, _S-E_
PAINT
3 II
UN1263
PAINT
3 II
PAINT
UN1263
3 II
UN1263
DOT Classification IMDG IATA
No. Yes. The environmentally
hazardous substance mark is
not required.
UN number
UN proper shipping
name
Transport hazard
class(es)
Packing group
Environmental
hazards
IATA : The environmentally hazardous substance mark may appear if required by other transportation regulations.
Marine Pollutant(s):
trizinc bis(orthophosphate)
Section 15. Regulatory information
U.S. Federal regulations
TSCA 8(a) PAIR: 2-methoxy-1-methylethyl acetate
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
TSCA 5(a)2 - Proposed significant new use rules
No products found
TSCA 5(e) substance consent order: No products found.
TSCA 5(a)2 - Final significant new use rules
No products found
Date of issue/Date of revision : Date of previous issue : 24/289/17/2026 No previous validation
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 263
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Section 15. Regulatory information
Clean Water Act (CWA) 307: trizinc bis(orthophosphate); ethylbenzene; zinc oxide; toluene Clean Water Act (CWA) 311: n-butyl acetate; xylene; ethylbenzene; toluene Clean Air Act Section 602
Class I Substances
: Not listed
Clean Air Act Section 602
Class II Substances
: Not listed
DEA List I Chemicals
(Precursor Chemicals)
: Not listed
DEA List II Chemicals
(Essential Chemicals)
: Not listed
SARA 302/304
SARA 304 RQ : Not applicable.
No products were found.
Composition/information on ingredients
SARA 311/312
Classification : FLAMMABLE LIQUIDS - Category 2
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 1A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3
titanium dioxide ≥7 - ≤13 CARCINOGENICITY - Category 2
Fatty acids, C18-unsatd., dimers,
oligomeric reaction products
with tall-oil fatty acids and
triethylenetetramine
≥7 - ≤13 SERIOUS EYE DAMAGE - Category 1
Isopropyl alcohol ≥5 - ≤10 FLAMMABLE LIQUIDS - Category 2 EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
butanone ≥3 - ≤7 FLAMMABLE LIQUIDS - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
butan-1-ol ≥1 - ≤5 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (oral) - Category 4
SKIN IRRITATION - Category 2
SERIOUS EYE DAMAGE - Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
1-methoxy-2-propanol ≥1 - ≤5 FLAMMABLE LIQUIDS - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
n-butyl acetate ≥1 - ≤5 FLAMMABLE LIQUIDS - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
xylene ≥0.5 - ≤1.5 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (dermal) - Category 4
Name % Classification
Composition/information on ingredients
Not applicable.
TSCA 12(b) - Chemical export notification
United States inventory (TSCA 8b): All components are active or exempted.
Date of issue/Date of revision : Date of previous issue : 25/289/17/2026 No previous validation
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Section 15. Regulatory information
The following components are listed: TALC; TITANIUM DIOXIDE; ISOPROPYL ALCOHOL; METHYL ETHYL KETONE; N-BUTYL ALCOHOL; PROPYLENE GLYCOL METHYL ETHER; BUTYL ACETATE; XYLENE
Massachusetts :
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed. trizinc bis(orthophosphate) 7779-90-0 ≥3 - ≤7
butan-1-ol 71-36-3 ≥1 - ≤5
xylene 1330-20-7 ≥0.5 - ≤1.5
ethylbenzene 100-41-4 ≥0.1 - ≤1
trizinc bis(orthophosphate) 7779-90-0 ≥3 - ≤7
butan-1-ol 71-36-3 ≥1 - ≤5
xylene 1330-20-7 ≥0.5 - ≤1.5
ethylbenzene 100-41-4 ≥0.1 - ≤1
Form R - Reporting
requirements
Supplier notification
California Prop. 65
New York : The following components are listed: Methyl ethyl ketone; Butyl alcohol; Butyl acetate; Xylene mixed
New Jersey : The following components are listed: TALC (NOT CONTAINING ASBESTOS FIBERS); TITANIUM DIOXIDE; ISOPROPYL ALCOHOL; ZINC compounds; METHYL ETHYL KETONE; n-BUTYL ALCOHOL; PROPYLENE GLYCOL MONOMETHYL ETHER; nBUTYL ACETATE; XYLENES; CARBON BLACK; ETHYL BENZENE; SILICA, QUARTZ Pennsylvania : The following components are listed: TALC; TITANIUM OXIDE; 2-PROPANOL; ZINC COMPOUNDS; 2-BUTANONE; 1-BUTANOL; 2-PROPANOL, 1-METHOXY-; ACETIC ACID, BUTYL ESTER; BENZENE, DIMETHYLState regulations
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
ASPIRATION HAZARD - Category 1
3,6-diazaoctanethylenediamin ≥0.1 - ≤1 ACUTE TOXICITY (oral) - Category 4 ACUTE TOXICITY (dermal) - Category 4
SKIN CORROSION - Category 1B
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1
carbon black, respirable powder ≥0.1 - ≤1 CARCINOGENICITY - Category 2 ethylbenzene ≥0.1 - ≤1 FLAMMABLE LIQUIDS - Category 2
ACUTE TOXICITY (inhalation) - Category 4
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
Crystalline Silica, respirable part
in whole product, <10µm
≥0.1 - ≤1 CARCINOGENICITY - Category 1A
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 1
2,3-epoxypropyl neodecanoate ≤0.1 SKIN SENSITIZATION - Category 1A GERM CELL MUTAGENICITY - Category 2
TOXIC TO REPRODUCTION - Category 2
WARNING: This product can expose you to chemicals including Titanium dioxide, which is known to the State of California to cause cancer, and Toluene, which is known to the State of California to cause birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov.
Date of issue/Date of revision : Date of previous issue : 26/289/17/2026 No previous validation
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Section 15. Regulatory information
titanium dioxide - - carbon black, respirable powder - - ethylbenzene Yes. - Crystalline Silica, respirable part in whole product, <10µm - - toluene - Yes.
Ingredient name No significant risk
level
Maximum
acceptable dosage
level
Inventory list
United States : All components are active or exempted.
Canada : All components are listed or exempted.
Section 16. Other information
History
Procedure used to derive the classification
Classification Justification
FLAMMABLE LIQUIDS - Category 2 On basis of test data
SERIOUS EYE DAMAGE - Category 1 Calculation method
SKIN SENSITIZATION - Category 1 Calculation method
CARCINOGENICITY - Category 1A Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3
Calculation method
Date of printing
Date of issue/ Date of
revision
Date of previous issue
:
:
:
9/17/2026
9/17/2026
No previous validation
0 3
3 National Fire Protection Association (U.S.A.)
Health
Special hazards
Instability
Flammability
Notice to reader
Indicates information that has changed from previously issued version.
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available
SGG = Segregation Group
UN = United Nations
Unique ID : 595075622C3C1FD1ACD2773C8299B882
IMPORTANT NOTE: the information contained in this data sheet (as may be amended from time to time) is not intended to be exhaustive and is presented in good faith and believed to be correct as of the date on which it is prepared. It is the userˈs responsibility to verify that this data sheet is current prior to using the product to which it relates.
Persons using the information must make their own determinations as to the suitability of the relevant product for their purposes prior to use. Where those purposes are other than as specifically recommended in this safety data sheet, then the user uses the product at their own risk.
Date of issue/Date of revision : Date of previous issue : 27/289/17/2026 No previous validation
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 266
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Section 16. Other information
MANUFACTURER’S DISCLAIMER: the conditions, methods and factors affecting the handling, storage, application, use and disposal of the product are not under the control and knowledge of the manufacturer. Therefore the manufacturer does not assume responsibility for any adverse events which may occur in the handling, storage, application, use, misuse or disposal of the product and, so far as permitted by applicable law, the manufacturer expressly disclaims liability for any and all loss, damages and/or expenses arising out of or in any way connected to the storage, handling, use or disposal of the product. Safe handling, storage, use and disposal are the responsibility of the users. Users must comply with all applicable health and safety laws.
Unless we have agreed to the contrary, all products are supplied by us subject to our standard terms and conditions of business, which include limitations of liability. Please make sure to refer to these and / or the relevant agreement which you have with AkzoNobel (or its affiliate, as the case may be). © AkzoNobel
Date of issue/Date of revision : Date of previous issue : 28/289/17/2026 No previous validation
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SAFETY DATA SHEET
GHS product identifier
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
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Relevant identified uses of the substance or mixture and uses advised against Identified uses
Uses advised against
Professional use
Industrial use
All other uses
Product use : Two component coating for exterior use.
Supplier's details
Akzo Nobel Coatings Ltd.
110 Woodbine Downs Blvd.
Unit #4 Etobicoke, Ontario
Canada M9W 5S6
International Paint (International) 1-713-682-1711
CHEMTREC (USA) +1 (800) 424-9300 (24Hr)
CHEMTREC (International) +1 (703) 527-3887
Domestic Poison Control Center Customer Service +1 (800) 854-6813 Akzo Nobel Coatings
International Paint LLC
6001 Antoine Drive
Houston, Texas 77091
International Paint 1-800-589-1267
International Paint (International) 1-713-682-1711
Cía. Mexicana de Pinturas International, S.A. de
C.V.
Carretera Anillo Periférico, No Ext 205,
No Interior A, Colonia HDA S JOSE, Garcia
Garcia, CP 66000, Nuevo Leon.
RFC: ANA9510267C4
SDS code : OD3001
Section 2. Hazards identification
FLAMMABLE LIQUIDS - Category 2
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION - Category 1B
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 ASPIRATION HAZARD - Category 1
Classification of the
substance or mixture
:
GHS label elements
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Date of issue/Date of revision : Date of previous issue : Version : 2 1/17
1/14/2025
12/19/2022
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 268
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Section 2. Hazards identification
Signal word : Danger
Hazard statements : Highly flammable liquid and vapor.
May be fatal if swallowed and enters airways.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
May cause drowsiness or dizziness.
Suspected of causing cancer.
May damage fertility or the unborn child.
May cause damage to organs through prolonged or repeated exposure. (hearing organs) Hazard pictograms :
Precautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Wash hands thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace.
Response : IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or doctor. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Wash contaminated clothing before reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention.
Storage : Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national or international regulations.
Hazards not otherwise
classified
: None known.
Section 3. Composition/information on ingredients
Substance/mixture : Mixture
Ingredient name % CAS number
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Phenol, 4,4'-(1-methylethylidene)bis-, polymer with 2,2'-[(1-methylethylidene) bis(4,1-phenyleneoxymethylene)]bis[oxirane]
≥25 - ≤50 25036-25-3
2-methoxy-1-methylethyl acetate ≥25 - ≤50 108-65-6
butanone ≥10 - ≤25 78-93-3
xylene ≤10 1330-20-7
ethylbenzene ≤3 100-41-4
Urea, polymer with formaldehyde, butylated ≤3 68002-19-7 2-methoxypropyl acetate ≤0.3 70657-70-4
Date of issue/Date of revision : Date of previous issue : Version : 2 2/17
1/14/2025
12/19/2022
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 269
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Section 3. Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses if easy to do. Continue to rinse for at least 10 minutes. Get medical attention.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness.
Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways.
Ingestion :
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Eye contact : Causes serious eye irritation.
Over-exposure signs/symptoms
Inhalation Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
Date of issue/Date of revision : Date of previous issue : Version : 2 3/17
1/14/2025
12/19/2022
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Section 4. First aid measures
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Skin contact
Ingestion Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO₂, water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures : No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
For non-emergency
personnel
Date of issue/Date of revision : Date of previous issue : Version : 2 4/17
1/14/2025
12/19/2022
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Section 6. Accidental release measures
Environmental precautions
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. :
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist.
Do not swallow. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. :
Precautions for safe handling
Date of issue/Date of revision : Date of previous issue : Version : 2 5/17
1/14/2025
12/19/2022
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Phenol, 4,4'-(1-methylethylidene)bis-, polymer with 2,2'-[ (1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bis[oxirane] None.
2-methoxy-1-methylethyl acetate OARS WEEL (United States, 7/2018).
TWA: 50 ppm 8 hours.
butanone ACGIH TLV (United States, 1/2023). Notes:
Substances for which there is a Biological
Exposure Index or Indices
STEL: 885 mg/m³ 15 minutes.
STEL: 300 ppm 15 minutes.
TWA: 590 mg/m³ 8 hours.
TWA: 200 ppm 8 hours.
NIOSH REL (United States, 10/2020).
STEL: 885 mg/m³ 15 minutes.
STEL: 300 ppm 15 minutes.
TWA: 590 mg/m³ 10 hours.
TWA: 200 ppm 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 590 mg/m³ 8 hours.
TWA: 200 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989).
STEL: 885 mg/m³ 15 minutes.
STEL: 300 ppm 15 minutes.
TWA: 590 mg/m³ 8 hours.
TWA: 200 ppm 8 hours.
xylene OSHA PEL (United States, 5/2018).
[Xylenes]
TWA: 435 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989).
[Xylenes (o-, m-, p-isomers)]
STEL: 655 mg/m³ 15 minutes.
STEL: 150 ppm 15 minutes.
TWA: 435 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
ACGIH TLV (United States, 1/2023). [pxylene and mixtures containing p-xylene] Ototoxicant.
TWA: 20 ppm 8 hours.
ethylbenzene ACGIH TLV (United States, 1/2023).
Ototoxicant. Notes: Substances for which
there is a Biological Exposure Index or
Indices 2002 Adoption.
TWA: 20 ppm 8 hours.
NIOSH REL (United States, 10/2020).
STEL: 545 mg/m³ 15 minutes.
STEL: 125 ppm 15 minutes.
TWA: 435 mg/m³ 10 hours.
TWA: 100 ppm 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 435 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989).
STEL: 545 mg/m³ 15 minutes.
STEL: 125 ppm 15 minutes.
TWA: 435 mg/m³ 8 hours.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
Date of issue/Date of revision : Date of previous issue : Version : 2 6/17
1/14/2025
12/19/2022
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Section 8. Exposure controls/personal protection
TWA: 100 ppm 8 hours.
Urea, polymer with formaldehyde, butylated None.
2-methoxypropyl acetate None.
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Wear a respirator conforming to EN140 with type A/P2 filter or better.
Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/ or hazardous fumes. Wet sanding/flatting should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear antistatic protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Date of issue/Date of revision : Date of previous issue : Version : 2 7/17
1/14/2025
12/19/2022
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Section 9. Physical and chemical properties and safety
characteristics
Physical state
Melting point/freezing point
Vapor pressure
Relative vapor density
Solubility(ies)
Liquid.
Not available.
Odor Solvent.
pH
Color Colorless.
Auto-ignition temperature
Not applicable.
Not applicable. [DIN EN 1262]
Viscosity Kinematic (room temperature): 1 mm2/s (1 cSt) [DIN EN ISO 3219] Kinematic (40°C (104°F)): 1 mm2/s (1 cSt) [DIN EN ISO 3219] Odor threshold Not available.
Partition coefficient: noctanol/water
:
:
:
:
:
:
:
:
:
:
:
Appearance
Flammability : Not available.
Decomposition temperature : Not available.
Particle characteristics
Median particle size : Not applicable.
The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.
Media Result
cold water Not soluble [OECD (TG 105)]
Percentage of particles
with aerodynamic diameter
≤ 10 μm
: 0
Not available.
:
Ingredient name
Vapor Pressure at 20˚C Vapor pressure at 50˚C
mm Hg kPa Method mm Hg kPa Method
butanone 78.7564 10.5
ethylbenzene 9.30076 1.2
xylene 6.7 0.89
Ingredient name °C °F Method
2-methoxy-1-methylethyl acetate 333 631.4
butanone 404 759.2
xylene 432 809.6
Flash point : Closed cup: -7°C (19.4°F) [Pensky-Martens] Boiling point, initial boiling
point, and boiling range
: 79°C (174.2°F)
Lower and upper explosion
limit
: Greatest known range: Lower: 1.8% Upper: 11.5% (butanone) Density : 0.975 g/cm³ [DIN EN ISO 2811-1]
Date of issue/Date of revision : Date of previous issue : Version : 2 8/17
1/14/2025
12/19/2022
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 275
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Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
Chemical stability The product is stable.
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Irritation/Corrosion
Information on toxicological effects
butanone LC50 Inhalation Vapor Mouse 32 g/m³ 4 hours
LC50 Inhalation Vapor Rat 23500 mg/m³ 8 hours
LD50 Dermal Rabbit 6480 mg/kg - LD50 Intraperitoneal Guinea pig 2 g/kg - LD50 Intraperitoneal Mouse 616 mg/kg - LD50 Intraperitoneal Rat 607 mg/kg - LD50 Oral Mouse 3000 mg/kg - LD50 Oral Rat 2737 mg/kg - xylene LD50 Oral Rat 4300 mg/kg - LD50 Subcutaneous Rat 1700 mg/kg - ethylbenzene LC50 Inhalation Gas. Rabbit 4000 ppm 4 hours LC50 Inhalation Vapor Mouse 35500 mg/m³ 2 hours
LC50 Inhalation Vapor Rat 55000 mg/m³ 2 hours
LD50 Dermal Rabbit >5000 mg/kg - LD50 Dermal Rabbit 17800 uL/kg - LD50 Intraperitoneal Mouse 2624 uL/kg - LD50 Oral Rat 3500 mg/kg - LD50 Oral Rat 3500 mg/kg - Product/ingredient name Result Species Dose Exposure
butanone Skin - Mild irritant Rabbit - 24 hours 14
mg
- Skin - Mild irritant Rabbit - 24 hours 402
mg
- Skin - Moderate irritant Rabbit - 24 hours 500
mg
- xylene Eyes - Mild irritant Rabbit - 87 mg - Eyes - Severe irritant Rabbit - 24 hours 5 mg
- Skin - Mild irritant Rat - 8 hours 60 Ul - Skin - Moderate irritant Rabbit - 100 % - Skin - Moderate irritant Rabbit - 24 hours 500 mg
- ethylbenzene Eyes - Severe irritant Rabbit - 500 mg - Skin - Mild irritant Rabbit - 24 hours 15 - Product/ingredient name Result Species Score Exposure Observation Date of issue/Date of revision : Date of previous issue : Version : 2 9/17
1/14/2025
12/19/2022
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 276
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Section 11. Toxicological information
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Sensitization
Not available.
Information on the likely
routes of exposure
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness.
Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways.
Ingestion :
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Eye contact : Causes serious eye irritation.
Symptoms related to the physical, chemical and toxicological characteristics Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Aspiration hazard
Name Result
xylene ASPIRATION HAZARD - Category 1
ethylbenzene ASPIRATION HAZARD - Category 1
: Not available.
Potential acute health effects
Classification
xylene - 3 - ethylbenzene - 2B -
Product/ingredient name OSHA IARC NTP
mg
2-methoxy-1-methylethyl acetate Category 3 - Narcotic effects butanone Category 3 - Narcotic effects
xylene Category 3 - Respiratory tract
irritation
2-methoxypropyl acetate Category 3 - Respiratory tract
irritation
Name Category Route of
exposure
Target organs
Name Category
ethylbenzene Category 2 - hearing organs
Route of
exposure
Target organs
Date of issue/Date of revision : Date of previous issue : Version : 2 10/17
1/14/2025
12/19/2022
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 277
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Section 11. Toxicological information
Not available.
May cause damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.
General :
Suspected of causing cancer. Risk of cancer depends on duration and level of exposure.
Carcinogenicity :
Mutagenicity : No known significant effects or critical hazards.
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure Potential immediate
effects
: Not available.
Short term exposure
Potential delayed effects : Not available.
Potential immediate
effects
: Not available.
Long term exposure
Potential delayed effects : Not available.
Reproductive toxicity : May damage fertility or the unborn child.
Numerical measures of toxicity
Acute toxicity estimates
Product/ingredient name
Product as-supplied N/A 11529.3 N/A 93.4 N/A
xylene N/A 1100 N/A 11 N/A
ethylbenzene N/A N/A N/A 11 N/A
Oral (mg/
kg)
Dermal
(mg/kg)
Inhalation
(gases)
(ppm)
Inhalation
(vapors)
(mg/l)
Inhalation
(dusts and
mists) (mg/
l)
Date of issue/Date of revision : Date of previous issue : Version : 2 11/17
1/14/2025
12/19/2022
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 278
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Section 11. Toxicological information
Section 12. Ecological information
Toxicity
Persistence and degradability
butanone Acute EC50 >500 mg/l Fresh water Algae - Pseudokirchneriella subcapitata
96 hours
Acute EC50 >500000 µg/l Marine water Algae - Skeletonema costatum 96 hours Acute EC50 5091000 µg/l Fresh water Daphnia - Daphnia magna - Larvae
48 hours
Acute LC50 5600 ppm Fresh water Fish - Gambusia affinis - Adult 96 hours Acute LC50 3220000 µg/l Fresh water Fish - Pimephales promelas 96 hours xylene Acute EC50 90 mg/l Fresh water Crustaceans - Cypris subglobosa 48 hours Acute LC50 8.5 ppm Marine water Crustaceans - Palaemonetes pugio - Adult
48 hours
Acute LC50 8500 µg/l Marine water Crustaceans - Palaemonetes pugio
48 hours
Acute LC50 16940 µg/l Fresh water Fish - Carassius auratus 96 hours Acute LC50 15700 µg/l Fresh water Fish - Lepomis macrochirus - Juvenile (Fledgling, Hatchling,
Weanling)
96 hours
Acute LC50 20870 µg/l Fresh water Fish - Lepomis macrochirus 96 hours Acute LC50 19000 µg/l Fresh water Fish - Lepomis macrochirus 96 hours Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hours ethylbenzene Acute EC50 4600 µg/l Fresh water Algae - Pseudokirchneriella subcapitata
72 hours
Acute EC50 5400 µg/l Fresh water Algae - Pseudokirchneriella subcapitata
72 hours
Acute EC50 3600 µg/l Fresh water Algae - Pseudokirchneriella subcapitata
96 hours
Acute EC50 4900 µg/l Marine water Algae - Skeletonema costatum 72 hours Acute EC50 7700 µg/l Marine water Algae - Skeletonema costatum 96 hours Acute EC50 6.53 mg/l Marine water Crustaceans - Artemia sp. - Nauplii
48 hours
Acute EC50 13.3 mg/l Marine water Crustaceans - Artemia sp. - Nauplii
48 hours
Acute EC50 2.97 mg/l Fresh water Daphnia - Daphnia magna - Neonate
48 hours
Acute EC50 2.93 mg/l Fresh water Daphnia - Daphnia magna - Neonate
48 hours
Acute LC50 8.78 mg/l Marine water Crustaceans - Artemia sp. - Nauplii
48 hours
Acute LC50 13.3 mg/l Marine water Crustaceans - Artemia sp. - Nauplii
48 hours
Acute LC50 40000 µg/l Marine water Crustaceans - Cancer magister - Zoea
48 hours
Acute LC50 18.4 mg/l Fresh water Daphnia - Daphnia magna - Neonate
48 hours
Acute LC50 13.9 mg/l Fresh water Daphnia - Daphnia magna - Neonate
48 hours
Acute LC50 75000 µg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 5100 µg/l Marine water Fish - Menidia menidia 96 hours Acute LC50 4.3 ul/L Marine water Fish - Morone saxatilis - Juvenile (Fledgling, Hatchling, Weanling)
96 hours
Acute LC50 4200 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours Acute LC50 9090 µg/l Fresh water Fish - Pimephales promelas 96 hours Acute LC50 9100 µg/l Fresh water Fish - Pimephales promelas 96 hours Product/ingredient name Result Species Exposure
Date of issue/Date of revision : Date of previous issue : Version : 2 12/17
1/14/2025
12/19/2022
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 279
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Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects : No known significant effects or critical hazards.
Product/ingredient name
2-methoxy-1-methylethyl
acetate
1.2 - low
butanone 0.3 - low
xylene 3.12 8.1 to 25.9 low
ethylbenzene 3.6 - low
Soil/water partition
coefficient (KOC)
: Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Disposal methods :
United States - RCRA Toxic hazardous waste "U" List
butanone 78-93-3 Listed U159
xylene 1330-20-7 Listed U239
Ingredient CAS # Status Reference
number
Section 14. Transport information
The information provided in section 14 is based on a bulk package shipment via ground transport in North America. All shippers are responsible for ensuring the proper transportation classification and package/container requirements are followed for the relevant mode of transport.
PAINT
3 II
UN1263
PAINT
3 II
PAINT
UN1263
3 II
UN1263
DOT Classification IMDG IATA
UN number
UN proper shipping
name
Transport hazard
class(es)
Packing group
Date of issue/Date of revision : Date of previous issue : Version : 2 13/17
1/14/2025
12/19/2022
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 280
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Section 14. Transport information
Special precautions for user
Transport in bulk according
to IMO instruments
Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
: Not available.
:
Reportable quantity 1048.1 lbs / 475.85 kg [128.93 gal / 488.05 L]. Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements.
Additional information
DOT Classification :
IMDG : Emergency schedules F-E, _S-E_
Environmental No. No.
hazards
No.
Section 15. Regulatory information
U.S. Federal regulations :
United States inventory (TSCA 8b): All components are active or exempted.
SARA 311/312
Classification : FLAMMABLE LIQUIDS - Category 2
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION - Category 1B
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 ASPIRATION HAZARD - Category 1
SARA 302/304
Composition/information on ingredients
(lbs) (gallons)
SARA 302 TPQ SARA 304 RQ
Name % EHS (lbs) (gallons)
Formaldehyde, solution <0.1 Yes. 500 55.5 100 11.1
SARA 304 RQ : 485625.5 lbs / 220474 kg [59736.5 gal / 226127.1 L] TSCA 5(e) substance consent order: No products found.
TSCA 5(a)2 final significant new use rules: No products found.
TSCA 8(a) PAIR: 2-methoxy-1-methylethyl acetate
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
Clean Water Act (CWA) 307: ethylbenzene; toluene
Clean Water Act (CWA) 311: xylene; ethylbenzene; toluene; Formaldehyde, solution Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
: Listed
Clean Air Act Section 602
Class I Substances
: Not listed
Clean Air Act Section 602
Class II Substances
: Not listed
DEA List I Chemicals
(Precursor Chemicals)
: Not listed
DEA List II Chemicals
(Essential Chemicals)
: Not listed
Date of issue/Date of revision : Date of previous issue : Version : 2 14/17
1/14/2025
12/19/2022
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 281
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Section 15. Regulatory information
The following components are listed: METHYL ETHYL KETONE; XYLENE; ETHYL
BENZENE
Massachusetts :
California Prop. 65
New York : The following components are listed: Methyl ethyl ketone; Xylene mixed; Ethylbenzene New Jersey : The following components are listed: METHYL ETHYL KETONE; XYLENES; ETHYL
BENZENE
Pennsylvania : The following components are listed: 2-BUTANONE; BENZENE, DIMETHYL-; BENZENE, ETHYLState regulations
WARNING: Cancer and Reproductive Harm - www.P65Warnings.ca.gov.
Ingredient name No significant risk Maximum Type of toxicity SARA 313
Product name CAS number %
xylene 1330-20-7 ≤10
ethylbenzene 100-41-4 ≤3 Form R - Reporting
requirements
Supplier notification xylene 1330-20-7 ≤10
ethylbenzene 100-41-4 ≤3
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
Composition/information on ingredients
Name % Classification
Phenol, 4,4'-(1-methylethylidene)
bis-, polymer with 2,2'-[
(1-methylethylidene)bis
(4,1-phenyleneoxymethylene)]bis
[oxirane]
≥25 - ≤50 SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
2-methoxy-1-methylethyl acetate ≥25 - ≤50 FLAMMABLE LIQUIDS - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
butanone ≥10 - ≤25 FLAMMABLE LIQUIDS - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
xylene ≤10 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (dermal) - Category 4
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
ASPIRATION HAZARD - Category 1
ethylbenzene ≤3 FLAMMABLE LIQUIDS - Category 2
ACUTE TOXICITY (inhalation) - Category 4
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
2-methoxypropyl acetate ≤0.3 FLAMMABLE LIQUIDS - Category 3 EYE IRRITATION - Category 2B
TOXIC TO REPRODUCTION - Category 1B
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
Date of issue/Date of revision : Date of previous issue : Version : 2 15/17
1/14/2025
12/19/2022
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 282
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Section 15. Regulatory information
ethylbenzene Yes. - Cancer
toluene - Yes. Developmental
Formaldehyde, solution Yes. - Cancer
level acceptable dosage
level
Australia : All components are listed or exempted.
Canada : All components are listed or exempted.
China : All components are listed or exempted.
Japan : Japan inventory (CSCL): Not determined.
Japan inventory (ISHL): Not determined.
Republic of Korea : All components are listed or exempted.
New Zealand : All components are listed or exempted.
Philippines : All components are listed or exempted.
Taiwan : All components are listed or exempted.
Turkey : Not determined.
United States : All components are active or exempted.
Thailand : Not determined.
Viet Nam : All components are listed or exempted.
Eurasian Economic Union : Russian Federation inventory: Not determined.
Inventory list
Section 16. Other information
History
Key to abbreviations :
Procedure used to derive the classification
Classification Justification
FLAMMABLE LIQUIDS - Category 2 On basis of test data
SKIN IRRITATION - Category 2 Calculation method
EYE IRRITATION - Category 2A Calculation method
SKIN SENSITIZATION - Category 1 Calculation method
CARCINOGENICITY - Category 2 Calculation method
TOXIC TO REPRODUCTION - Category 1B Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method ASPIRATION HAZARD - Category 1 Calculation method
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available
SGG = Segregation Group
UN = United Nations
Unique ID : C9158E3CECB71EEFB4CF482214C9E692
Version : 2
Date of printing 1/14/2025
Date of issue/ Date of
revision
Date of previous issue
:
:
:
1/14/2025
12/19/2022
Date of issue/Date of revision : Date of previous issue : Version : 2 16/17
1/14/2025
12/19/2022
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 283
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Section 16. Other information
Notice to reader
Indicates information that has changed from previously issued version.
IMPORTANT NOTE: the information contained in this data sheet (as may be amended from time to time) is not intended to be exhaustive and is presented in good faith and believed to be correct as of the date on which it is prepared. It is the userˈs responsibility to verify that this data sheet is current prior to using the product to which it relates.
Persons using the information must make their own determinations as to the suitability of the relevant product for their purposes prior to use. Where those purposes are other than as specifically recommended in this safety data sheet, then the user uses the product at their own risk.
MANUFACTURER’S DISCLAIMER: the conditions, methods and factors affecting the handling, storage, application, use and disposal of the product are not under the control and knowledge of the manufacturer. Therefore the manufacturer does not assume responsibility for any adverse events which may occur in the handling, storage, application, use, misuse or disposal of the product and, so far as permitted by applicable law, the manufacturer expressly disclaims liability for any and all loss, damages and/or expenses arising out of or in any way connected to the storage, handling, use or disposal of the product. Safe handling, storage, use and disposal are the responsibility of the users. Users must comply with all applicable health and safety laws.
Unless we have agreed to the contrary, all products are supplied by us subject to our standard terms and conditions of business, which include limitations of liability. Please make sure to refer to these and / or the relevant agreement which you have with AkzoNobel (or its affiliate, as the case may be). © AkzoNobel
Date of issue/Date of revision : Date of previous issue : Version : 2 17/17
1/14/2025
12/19/2022
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 284
Awlfair LW White Base
SAFETY DATA SHEET
GHS product identifier
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
Awlfair LW White Base
Relevant identified uses of the substance or mixture and uses advised against Identified uses
Uses advised against
Professional use
Industrial use
Consumer use
Product use : Two component coating for interior and exterior use.
Supplier's details
Akzo Nobel Coatings Ltd.
4-110 Woodbine Downs Blvd.
Etobicoke ON M9W 5S6
Canada
International Paint (International) 1-713-682-1711
CHEMTREC (USA) +1 (800) 424-9300 (24Hr)
CHEMTREC (International) +1 (703) 527-3887
Domestic Poison Control Center Customer Service +1 (800) 854-6813 Akzo Nobel Coatings
International Paint LLC
6001 Antoine Drive
Houston, Texas 77091
International Paint 1-800-589-1267
International Paint (International) 1-713-682-1711
Akzo Nobel Performance Coatings, S.A. de C.V.
Anillo Periférico #205 Km16.64
Hacienda San José
García, Nuevo Leon, Mexico.
CP 66000
RFC: ANA9510267C4
SDS code : OD8200
Section 2. Hazards identification
SKIN IRRITATION - Category 2
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION - Category 1B
Classification of the
substance or mixture
:
GHS label elements
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Date of issue/Date of revision : Date of previous issue : Version : 3 1/15
7/25/2025
5/3/2024
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 285
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Section 2. Hazards identification
Signal word : Danger
Hazard statements : Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye damage.
Suspected of causing cancer.
May damage fertility or the unborn child.
Hazard pictograms :
Precautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Avoid breathing dust. Wash hands thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Response : IF exposed or concerned: Get medical advice or attention. Take off contaminated clothing and wash it before reuse. Wash contaminated clothing before reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor.
Storage : Store locked up.
Disposal : Dispose of contents and container in accordance with all local, regional, national or international regulations.
Hazards not otherwise
classified
: None known.
Section 3. Composition/information on ingredients
Substance/mixture : Mixture
Ingredient name % CAS number
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Any concentration shown as a range is to protect confidentiality or is due to batch variation. reaction product: bisphenol-A-(epichlorhydrin); epoxy resin ≥50 - ≤75 25068-38-6 Talc , not containing asbestiform fibres ≥10 - ≤25 14807-96-6 1,4-bis(2,3 epoxypropoxy)butane ≥10 - ≤20 2425-79-8
Reaction mass of 2,2'-[methylenebis(4,1-phenyleneoxymethylene)]dioxirane and [2-({2-[4-(oxiran-2-ylmethoxy)benzyl]phenoxy}methyl)oxirane and [2,2'- [methylenebis(2,1-phenyleneoxymethylene)]dioxirane
≤10 -
glass, oxide, chemicals ≤5 65997-17-3
titanium dioxide ≤3 13463-67-7
Date of issue/Date of revision : Date of previous issue : Version : 3 2/15
7/25/2025
5/3/2024
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 286
Awlfair LW White Base
Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician.
Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses if easy to do. Continue to rinse for at least 10 minutes.
Chemical burns must be treated promptly by a physician.
Get medical attention immediately. Call a poison center or physician. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Eye contact : Causes serious eye damage.
Over-exposure signs/symptoms
Skin contact
Inhalation Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Potential acute health effects
Date of issue/Date of revision : Date of previous issue : Version : 3 3/15
7/25/2025
5/3/2024
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 287
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Section 4. First aid measures
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Ingestion Adverse symptoms may include the following:
stomach pains
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
halogenated compounds
metal oxide/oxides
No specific fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures : No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Provide adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
For non-emergency
personnel
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
Date of issue/Date of revision : Date of previous issue : Version : 3 4/15
7/25/2025
5/3/2024
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 288
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Section 6. Accidental release measures
Environmental precautions
Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Avoid dust generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. Dispose of via a licensed waste disposal contractor. Note:
see Section 1 for emergency contact information and Section 13 for waste disposal. : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Large spill :
Move containers from spill area. Avoid dust generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. Place spilled material in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not ingest. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. :
Precautions for safe handling
reaction product: bisphenol-A-(epichlorhydrin); epoxy resin None.
Talc , not containing asbestiform fibres OSHA PEL 1989 (United States, 3/1989).
TWA: 2 mg/m³ 8 hours. Form: Respirable
dust
NIOSH REL (United States, 10/2020).
TWA: 2 mg/m³ 10 hours. Form: Respirable
fraction
ACGIH TLV (United States, 1/2023).
TWA: 2 mg/m³ 8 hours. Form: Respirable
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
Date of issue/Date of revision : Date of previous issue : Version : 3 5/15
7/25/2025
5/3/2024
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Section 8. Exposure controls/personal protection
fraction
1,4-bis(2,3 epoxypropoxy)butane None.
Reaction mass of 2,2'-[methylenebis(4,1-phenyleneoxymethylene)] dioxirane and [2-({2-[4-(oxiran-2-ylmethoxy)benzyl]phenoxy}methyl) oxirane and [2,2'-[methylenebis(2,1-phenyleneoxymethylene)]dioxirane None.
glass, oxide, chemicals NIOSH REL (United States, 10/2020). [FIBROUS GLASS DUST]
TWA: 3 f/cc 10 hours. Form: Fibers of spec
length
TWA: 5 mg/m³ 10 hours. Form: Total
NIOSH REL (United States, 10/2020).
[MINERAL WOOL FIBER]
TWA: 3 f/cc 10 hours. Form: Fibers of spec
length
ACGIH TLV (United States, 1/2023).
[Continuous filament glass fibers]
TWA: 5 mg/m³ 8 hours. Form: Inhalable
fraction
TWA: 1 f/cc 8 hours. Form: Respirable fibers:
length greater than 5 uM; aspect ratio equal to
or greater than 3:1 as determined by the
membrane filter method at 400-450X
magnification (4-mm objective) phase contrast
illumination.
titanium dioxide OSHA PEL 1989 (United States, 3/1989).
TWA: 10 mg/m³ 8 hours. Form: Total dust
OSHA PEL (United States, 5/2018).
TWA: 15 mg/m³ 8 hours. Form: Total dust
ACGIH TLV (United States, 1/2023).
TWA: 2.5 mg/m³ 8 hours. Form: respirable
fraction, finescale particles
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/ or face shield. If inhalation hazards exist, a full-face respirator may be required instead.
Eye/face protection :
Environmental exposure
controls
: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
: If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Date of issue/Date of revision : Date of previous issue : Version : 3 6/15
7/25/2025
5/3/2024
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 290
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Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Wear a respirator conforming to EN140 with type A/P2 filter or better.
Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/ or hazardous fumes. Wet sanding/flatting should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Respiratory protection :
:
Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
:
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Section 9. Physical and chemical properties and safety
characteristics
Melting point/freezing point
Vapor pressure
Relative vapor density
Solubility(ies)
Not available.
Odor Characteristic.
pH
Color White.
Auto-ignition temperature
Not applicable.
Not available. [DIN EN 1262]
Odor threshold Not available.
Partition coefficient: noctanol/water
:
:
:
:
:
:
:
:
:
Appearance
Flammability : Not available.
Decomposition temperature : Not available.
The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.
Media Result
cold water Not soluble [OECD (TG 105)]
Not applicable.
: Not available.
Not applicable.
Flash point : Closed cup: 101°C (213.8°F) [Pensky-Martens] Boiling point or initial
boiling point and boiling
range
: 266°C (510.8°F)
Density : 1.123 g/cm³ [DIN EN ISO 2811-1]
Physical state : Solid.
Date of issue/Date of revision : Date of previous issue : Version : 3 7/15
7/25/2025
5/3/2024
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 291
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Section 9. Physical and chemical properties and safety
characteristics
Viscosity Kinematic (room temperature): 89045 mm2/s (89045 cSt) [DIN EN ISO 3219] Kinematic (40°C (104°F)): 99998 mm2/s (99998 cSt) [DIN EN ISO 3219] :
Particle characteristics
Median particle size : Not available.
Percentage of particles
with aerodynamic diameter
≤ 10 μm
: 0
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
Chemical stability The product is stable.
No specific data.
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Irritation/Corrosion
Information on toxicological effects
1,4-bis(2,3 epoxypropoxy)
butane
LD50 Dermal Rabbit 1130 mg/kg - LD50 Oral Mouse 1100 µg/kg - LD50 Oral Rat 1134 mg/kg - Product/ingredient name Result Species Dose Exposure
reaction product: bisphenol-A-
(epichlorhydrin); epoxy resin
Eyes - Mild irritant Rabbit - 100 mg - Skin - Moderate irritant Rabbit - 24 hours 500 Ul - Skin - Severe irritant Rabbit - 24 hours 2
mg
- 1,4-bis(2,3 epoxypropoxy)
butane
Eyes - Moderate irritant Rabbit - 100 mg - Skin - Moderate irritant Rabbit - 24 hours 10 mg
- Reaction mass of 2,2'-
[methylenebis
(4,1-phenyleneoxymethylene)]
dioxirane and [2-({2-[4-
(oxiran-2-ylmethoxy)benzyl]
Skin - Mild irritant Rabbit - 24 hours 500
Ul -
Product/ingredient name Result Species Score Exposure Observation Date of issue/Date of revision : Date of previous issue : Version : 3 8/15
7/25/2025
5/3/2024
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 292
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Section 11. Toxicological information
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Sensitization
Not available.
Information on the likely
routes of exposure
Inhalation : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Eye contact : Causes serious eye damage.
Symptoms related to the physical, chemical and toxicological characteristics Inhalation Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Not available.
Aspiration hazard
: Not available.
Potential acute health effects
Classification
Talc , not containing
asbestiform fibres
- 3 - glass, oxide, chemicals - 3 -
titanium dioxide - 2B -
Product/ingredient name OSHA IARC NTP
phenoxy}methyl)oxirane and
[2,2'-[methylenebis
(2,1-phenyleneoxymethylene)]
dioxirane
Not available.
Date of issue/Date of revision : Date of previous issue : Version : 3 9/15
7/25/2025
5/3/2024
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 293
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Section 11. Toxicological information
Not available.
Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.
General :
Suspected of causing cancer. Risk of cancer depends on duration and level of exposure.
Carcinogenicity :
Mutagenicity : No known significant effects or critical hazards.
Skin contact
Ingestion Adverse symptoms may include the following:
stomach pains
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure Potential immediate
effects
: Not available.
Short term exposure
Potential delayed effects : Not available.
Potential immediate
effects
: Not available.
Long term exposure
Potential delayed effects : Not available.
Reproductive toxicity : May damage fertility or the unborn child.
Numerical measures of toxicity
Acute toxicity estimates
Product/ingredient name
Product as-supplied 4432.6 9751.8 N/A 97.5 N/A
1,4-bis(2,3 epoxypropoxy)butane 500 1100 N/A 11 N/A
Oral (mg/
kg)
Dermal
(mg/kg)
Inhalation
(gases)
(ppm)
Inhalation
(vapors)
(mg/l)
Inhalation
(dusts and
mists) (mg/
l)
Date of issue/Date of revision : Date of previous issue : Version : 3 10/15
7/25/2025
5/3/2024
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 294
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Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects : No known significant effects or critical hazards.
Product/ingredient name
reaction product: bisphenol-A-
(epichlorhydrin); epoxy resin
2.64 to 3.78 31 Low
1,4-bis(2,3 epoxypropoxy)
butane
-0.269 - Low
Reaction mass of 2,2'-
[methylenebis
(4,1-phenyleneoxymethylene)]
dioxirane and [2-({2-[4-
(oxiran-2-ylmethoxy)benzyl]
phenoxy}methyl)oxirane and
[2,2'-[methylenebis
(2,1-phenyleneoxymethylene)]
dioxirane
2.7 - Low
Toxicity
Persistence and degradability
Soil/Water partition
coefficient
: Not available.
Mobility in soil
Not available.
titanium dioxide Acute LC50 15.9 mg/l Fresh water Crustaceans - Ceriodaphnia dubia - Neonate
48 hours
Acute LC50 >1000 mg/l Fresh water Fish - Pimephales promelas 96 hours Product/ingredient name Result Species Exposure
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Disposal methods :
Date of issue/Date of revision : Date of previous issue : Version : 3 11/15
7/25/2025
5/3/2024
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 295
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Section 14. Transport information
Special precautions for user Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
:
The information provided in section 14 is based on a bulk package shipment via ground transport in North America. All shippers are responsible for ensuring the proper transportation classification and package/container requirements are followed for the relevant mode of transport.
Additional information
This product is not regulated as a dangerous good when transported in sizes of ≤5 L or ≤5 kg, provided the packagings meet the general provisions of 4.1.1.1, 4.1.1.2 and
4.1.1.4 to 4.1.1.8.
IMDG : Emergency schedules F-A, S-F
ENVIRONMENTALLY
HAZARDOUS SUBSTANCE,
SOLID, N.O.S. (reaction
product: bisphenol-A-
(epichlorhydrin); epoxy resin,
Reaction mass of 2,2'-
[methylenebis
(4,1-phenyleneoxymethylene)]
dioxirane and [2-({2-[4-(oxiran2-ylmethoxy)benzyl]
phenoxy}methyl)oxirane and
[2,2'-[methylenebis
(2,1-phenyleneoxymethylene)]
dioxirane)
9 III
UN3077
-
-
-
ENVIRONMENTALLY
HAZARDOUS SUBSTANCE,
SOLID, N.O.S. (reaction
product: bisphenol-A-
(epichlorhydrin); epoxy resin,
Reaction mass of 2,2'-
[methylenebis
(4,1-phenyleneoxymethylene)]
dioxirane and [2-({2-[4-(oxiran2-ylmethoxy)benzyl]
phenoxy}methyl)oxirane and
[2,2'-[methylenebis
(2,1-phenyleneoxymethylene)]
dioxirane)
UN3077
9 III
Not regulated.
DOT Classification IMDG IATA
No. Yes.
UN number
UN proper shipping
name
Transport hazard
class(es)
Packing group
Environmental
hazards
IATA : This product is not regulated as a dangerous good when transported in sizes of ≤5 L or ≤5 kg, provided the packagings meet the general provisions of 5.0.2.4.1, 5.0.2.6.1.1 and
5.0.2.8. Marine Pollutant(s):
reaction product: bisphenol-A-
(epichlorhydrin); epoxy resin,
Reaction mass of 2,2'-
[methylenebis
(4,1-phenyleneoxymethylene)]
dioxirane and [2-({2-[4-(oxiran2-ylmethoxy)benzyl]
phenoxy}methyl)oxirane and
[2,2'-[methylenebis
(2,1-phenyleneoxymethylene)]
dioxirane
Date of issue/Date of revision : Date of previous issue : Version : 3 12/15
7/25/2025
5/3/2024
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 296
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Section 14. Transport information
Transport in bulk according
to IMO instruments
: Not available.
Section 15. Regulatory information
U.S. Federal regulations :
United States inventory (TSCA 8b): All components are active or exempted.
SARA 311/312
Classification : SKIN IRRITATION - Category 2
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION - Category 1B
Composition/information on ingredients
Name % Classification
reaction product: bisphenol-A-
(epichlorhydrin); epoxy resin
≥50 - ≤75 SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
1,4-bis(2,3 epoxypropoxy)butane ≥10 - ≤20 ACUTE TOXICITY (oral) - Category 4 ACUTE TOXICITY (dermal) - Category 4
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1
TOXIC TO REPRODUCTION - Category 1B
Reaction mass of 2,2'-
[methylenebis
(4,1-phenyleneoxymethylene)]
dioxirane and [2-({2-[4-(oxiran2-ylmethoxy)benzyl]
phenoxy}methyl)oxirane and
[2,2'-[methylenebis
≤10 SKIN IRRITATION - Category 2
SKIN SENSITIZATION - Category 1
SARA 302/304
Composition/information on ingredients
No products were found.
SARA 304 RQ : Not applicable.
TSCA 5(e) substance consent order: No products found.
TSCA 5(a)2 final significant new use rules: No products found.
TSCA 8(a) PAIR: Siloxanes and Silicones, di-Me, reaction products with silica TSCA 8(a) CDR Exempt/Partial exemption: Not determined
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
: Listed
Clean Air Act Section 602
Class I Substances
: Not listed
Clean Air Act Section 602
Class II Substances
: Not listed
DEA List I Chemicals
(Precursor Chemicals)
: Not listed
DEA List II Chemicals
(Essential Chemicals)
: Not listed
Date of issue/Date of revision : Date of previous issue : Version : 3 13/15
7/25/2025
5/3/2024
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 297
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Section 15. Regulatory information
Massachusetts : The following components are listed: TALC; FIBROUS GLASS; TITANIUM DIOXIDE California Prop. 65
New York : None of the components are listed.
New Jersey : The following components are listed: TALC (NOT CONTAINING ASBESTOS FIBERS);
TITANIUM DIOXIDE
Pennsylvania : The following components are listed: TALC; TITANIUM OXIDE State regulations
(2,1-phenyleneoxymethylene)]
dioxirane
titanium dioxide ≤3 CARCINOGENICITY - Category 2
Australia : Not determined.
Canada : All components are listed or exempted.
China : All components are listed or exempted.
Japan : Japan inventory (CSCL): Not determined.
Japan inventory (ISHL): Not determined.
Republic of Korea : Not determined.
New Zealand : All components are listed or exempted.
Philippines : All components are listed or exempted.
Taiwan : All components are listed or exempted.
Turkey : Not determined.
United States : All components are active or exempted.
Thailand : All components are listed or exempted.
Viet Nam : All components are listed or exempted.
Eurasian Economic Union : Russian Federation inventory: All components are listed or exempted.
Inventory list
WARNING: This product can expose you to Titanium dioxide, which is known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov. titanium dioxide - -
Ingredient name No significant risk
level
Maximum
acceptable dosage
level
Section 16. Other information
History
Procedure used to derive the classification
Classification Justification
SKIN IRRITATION - Category 2 Calculation method
SERIOUS EYE DAMAGE - Category 1 Calculation method
SKIN SENSITIZATION - Category 1 Calculation method
CARCINOGENICITY - Category 2 Calculation method
TOXIC TO REPRODUCTION - Category 1B Calculation method
Date of printing 8/12/2026
Date of issue/ Date of
revision
Date of previous issue
:
:
:
7/25/2025
5/3/2024
Date of issue/Date of revision : Date of previous issue : Version : 3 14/15
7/25/2025
5/3/2024
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 298
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Section 16. Other information
Notice to reader
Indicates information that has changed from previously issued version.
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available
SGG = Segregation Group
UN = United Nations
Unique ID : DA7DF488320C1EEF82AB15B1430D88CF
Version : 3
IMPORTANT NOTE: the information contained in this data sheet (as may be amended from time to time) is not intended to be exhaustive and is presented in good faith and believed to be correct as of the date on which it is prepared. It is the userˈs responsibility to verify that this data sheet is current prior to using the product to which it relates.
Persons using the information must make their own determinations as to the suitability of the relevant product for their purposes prior to use. Where those purposes are other than as specifically recommended in this safety data sheet, then the user uses the product at their own risk.
MANUFACTURER’S DISCLAIMER: the conditions, methods and factors affecting the handling, storage, application, use and disposal of the product are not under the control and knowledge of the manufacturer. Therefore the manufacturer does not assume responsibility for any adverse events which may occur in the handling, storage, application, use, misuse or disposal of the product and, so far as permitted by applicable law, the manufacturer expressly disclaims liability for any and all loss, damages and/or expenses arising out of or in any way connected to the storage, handling, use or disposal of the product. Safe handling, storage, use and disposal are the responsibility of the users. Users must comply with all applicable health and safety laws.
Unless we have agreed to the contrary, all products are supplied by us subject to our standard terms and conditions of business, which include limitations of liability. Please make sure to refer to these and / or the relevant agreement which you have with AkzoNobel (or its affiliate, as the case may be). © AkzoNobel
Date of issue/Date of revision : Date of previous issue : Version : 3 15/15
7/25/2025
5/3/2024
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 299
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SAFETY DATA SHEET
GHS product identifier
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
Awlfair LW Standard Red Converter
Relevant identified uses of the substance or mixture and uses advised against Identified uses
Uses advised against
Professional use
Industrial use
All other uses
Product use : Two component coating for interior and exterior use.
Supplier's details
Akzo Nobel Coatings Ltd.
4-110 Woodbine Downs Blvd.
Etobicoke ON M9W 5S6
Canada
International Paint (International) 1-713-682-1711
CHEMTREC (USA) +1 (800) 424-9300 (24Hr)
CHEMTREC (International) +1 (703) 527-3887
Domestic Poison Control Center Customer Service +1 (800) 854-6813 Akzo Nobel Coatings
International Paint LLC
6001 Antoine Drive
Houston, Texas 77091
International Paint 1-800-589-1267
International Paint (International) 1-713-682-1711
Akzo Nobel Performance Coatings, S.A. de C.V.
Anillo Periférico #205 Km16.64
Hacienda San José
García, Nuevo Leon, Mexico.
CP 66000
RFC: ANA9510267C4
SDS code : OD7200
Section 2. Hazards identification
ACUTE TOXICITY (oral) - Category 4
SKIN CORROSION - Category 1C
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Classification of the
substance or mixture
:
GHS label elements
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Date of issue/Date of revision : Date of previous issue : Version : 2 1/14
7/25/2025
12/19/2022
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 300
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Section 2. Hazards identification
Signal word : Danger
Hazard statements : Harmful if swallowed.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
May cause damage to organs through prolonged or repeated exposure.
Hazard pictograms :
Precautionary statements
Prevention : Wear protective gloves, protective clothing and eye or face protection. Do not breathe dust. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace.
Response : IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Immediately call a POISON CENTER or doctor. IF SWALLOWED: Immediately call a POISON CENTER or doctor. Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
Immediately call a POISON CENTER or doctor. Wash contaminated clothing before reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or doctor.
Storage : Store locked up.
Disposal : Dispose of contents and container in accordance with all local, regional, national or international regulations.
Hazards not otherwise
classified
: None known.
Section 3. Composition/information on ingredients
Substance/mixture : Mixture
Ingredient name % CAS number
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Limestone ≥10 - ≤25 1317-65-3
Fatty acids, tall-oil, reaction products with tetraethylenepentamine ≥10 - ≤25 68953-36-6 glass, oxide, chemicals ≥10 - ≤25 65997-17-3
Formaldehyde, polymer with benzenamine, hydrogenated ≥10 - ≤25 135108-88-2 3,6,9-triazaundecamethylenediamine <5 112-57-2
diiron trioxide ≤3 1309-37-1
Date of issue/Date of revision : Date of previous issue : Version : 2 2/14
7/25/2025
12/19/2022
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 301
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Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician.
Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses if easy to do. Continue to rinse for at least 10 minutes.
Chemical burns must be treated promptly by a physician.
Get medical attention immediately. Call a poison center or physician. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation : No known significant effects or critical hazards.
Ingestion : Harmful if swallowed.
Skin contact : Causes severe burns. May cause an allergic skin reaction.
Eye contact : Causes serious eye damage.
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
Adverse symptoms may include the following:
stomach pains
Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
:
:
:
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Potential acute health effects
Indication of immediate medical attention and special treatment needed, if necessary Date of issue/Date of revision : Date of previous issue : Version : 2 3/14
7/25/2025
12/19/2022
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 302
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Section 4. First aid measures
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
See toxicological information (Section 11)
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
metal oxide/oxides
No specific fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures :
: No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Provide adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
Date of issue/Date of revision : Date of previous issue : Version : 2 4/14
7/25/2025
12/19/2022
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 303
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Section 6. Accidental release measures
Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Avoid dust generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. Dispose of via a licensed waste disposal contractor. Note:
see Section 1 for emergency contact information and Section 13 for waste disposal.
Large spill :
Move containers from spill area. Avoid dust generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. Place spilled material in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor.
Small spill :
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not ingest. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. :
Precautions for safe handling
Limestone OSHA PEL 1989 (United States, 3/1989).
[Calcium carbonate]
TWA: 5 mg/m³ 8 hours. Form: Respirable
fraction
TWA: 15 mg/m³ 8 hours. Form: Total dust
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m³ 8 hours. Form: Respirable
fraction
TWA: 15 mg/m³ 8 hours. Form: Total dust
NIOSH REL (United States, 10/2020).
[calcium carbonate]
TWA: 5 mg/m³ 10 hours. Form: Respirable
fraction
TWA: 10 mg/m³ 10 hours. Form: Total
Fatty acids, tall-oil, reaction products with tetraethylenepentamine None. glass, oxide, chemicals NIOSH REL (United States, 10/2020).
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
Date of issue/Date of revision : Date of previous issue : Version : 2 5/14
7/25/2025
12/19/2022
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 304
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Section 8. Exposure controls/personal protection
[FIBROUS GLASS DUST]
TWA: 3 f/cc 10 hours. Form: Fibers of spec
length
TWA: 5 mg/m³ 10 hours. Form: Total
NIOSH REL (United States, 10/2020).
[MINERAL WOOL FIBER]
TWA: 3 f/cc 10 hours. Form: Fibers of spec
length
ACGIH TLV (United States, 1/2023).
[Continuous filament glass fibers]
TWA: 5 mg/m³ 8 hours. Form: Inhalable
fraction
TWA: 1 f/cc 8 hours. Form: Respirable fibers:
length greater than 5 uM; aspect ratio equal to
or greater than 3:1 as determined by the
membrane filter method at 400-450X
magnification (4-mm objective) phase contrast
illumination.
Formaldehyde, polymer with benzenamine, hydrogenated None. 3,6,9-triazaundecamethylenediamine OARS WEEL (United States, 4/2022).
Absorbed through skin Skin sensitizer.
TWA: 5 mg/m³ 8 hours.
diiron trioxide NIOSH REL (United States, 10/2020).
Notes: as Fe
TWA: 5 mg/m³, (as Fe) 10 hours. Form: Dust
and fumes
OSHA PEL 1989 (United States, 3/1989).
[Iron oxide dust and fume (as Fe)] Notes:
as Fe
STEL: 10 ppm, (as Fe) 15 minutes. Form:
Total particulates
ACGIH TLV (United States, 1/2023). Notes:
Refers to Appendix B -- Substances of
Variable Composition. Respirable fraction;
see Appendix C, paragraph C.
TWA: 5 mg/m³ 8 hours. Form: Respirable
fraction
OSHA PEL 1989 (United States, 3/1989).
[Rouge]
TWA: 5 mg/m³ 8 hours. Form: Respirable
fraction
TWA: 10 mg/m³ 8 hours. Form: Total dust
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m³ 8 hours. Form: Respirable
fraction
TWA: 15 mg/m³ 8 hours. Form: Total dust
Environmental exposure
controls
: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
: If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Date of issue/Date of revision : Date of previous issue : Version : 2 6/14
7/25/2025
12/19/2022
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 305
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Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Wear a respirator conforming to EN140 with type A/P2 filter or better.
Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/ or hazardous fumes. Wet sanding/flatting should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/ or face shield. If inhalation hazards exist, a full-face respirator may be required instead.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
:
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Section 9. Physical and chemical properties and safety
characteristics
Melting point/freezing point Not available.
Odor Amine-like.
pH
Color Red.
Not available. [DIN EN 1262]
Odor threshold Not available.
:
:
:
:
:
Appearance
The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.
Flash point : Closed cup: 101°C (213.8°F) [Pensky-Martens] Boiling point or initial
boiling point and boiling
range
: Not applicable.
Physical state : Solid.
Date of issue/Date of revision : Date of previous issue : Version : 2 7/14
7/25/2025
12/19/2022
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 306
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Section 9. Physical and chemical properties and safety
characteristics
Vapor pressure
Relative vapor density
Solubility(ies)
Auto-ignition temperature
Not applicable.
Viscosity Kinematic (room temperature): 143675 mm2/s (143675 cSt) [DIN EN ISO 3219] Kinematic (40°C (104°F)): 99998 mm2/s (99998 cSt) [DIN EN ISO 3219] Partition coefficient: noctanol/water
:
:
:
:
:
Flammability : Not available.
Decomposition temperature : Not available.
Particle characteristics
Median particle size : Not available.
Media Result
cold water Not soluble [OECD (TG 105)]
Percentage of particles
with aerodynamic diameter
≤ 10 μm
: 0
Not applicable.
: Not available.
Not applicable.
Density : 0.696 g/cm³ [DIN EN ISO 2811-1]
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
Chemical stability The product is stable.
No specific data.
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Irritation/Corrosion
Information on toxicological effects
3,6,9-triazaundecamethylenediamine LD50 Dermal Rabbit 660 uL/kg - LD50 Intraperitoneal Rat 205 mg/kg - LD50 Intravenous Mouse 320 mg/kg - LD50 Oral Rat 3990 mg/kg - Product/ingredient name Result Species Dose Exposure
Date of issue/Date of revision : Date of previous issue : Version : 2 8/14
7/25/2025
12/19/2022
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 307
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Section 11. Toxicological information
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Sensitization
Not available.
Information on the likely
routes of exposure
Inhalation : No known significant effects or critical hazards.
Ingestion : Harmful if swallowed.
Skin contact : Causes severe burns. May cause an allergic skin reaction.
Eye contact : Causes serious eye damage.
Symptoms related to the physical, chemical and toxicological characteristics Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
: Not available.
Potential acute health effects
Classification
glass, oxide, chemicals - 3 - diiron trioxide - 3 -
Product/ingredient name OSHA IARC NTP
3,6,9-triazaundecamethylenediamine Eyes - Moderate irritant Rabbit - 24 hours 100 mg
- Eyes - Moderate irritant Rabbit - 5 mg - Skin - Severe irritant Rabbit - 495 mg - Skin - Severe irritant Rabbit - 24 hours 5 mg
-
Product/ingredient name Result Species Score Exposure Observation Name Category
Formaldehyde, polymer with benzenamine, hydrogenated Category 2 oral - Route of exposure
Target organs
Not available.
Date of issue/Date of revision : Date of previous issue : Version : 2 9/14
7/25/2025
12/19/2022
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 308
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Section 11. Toxicological information
Not available.
May cause damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.
General :
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Skin contact
Ingestion
Inhalation No specific data.
Adverse symptoms may include the following:
stomach pains
Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
:
:
:
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure Potential immediate
effects
: Not available.
Short term exposure
Potential delayed effects : Not available.
Potential immediate
effects
: Not available.
Long term exposure
Potential delayed effects : Not available.
Reproductive toxicity : No known significant effects or critical hazards.
Numerical measures of toxicity
Acute toxicity estimates
Product/ingredient name
Product as-supplied 1534 24816.7 N/A N/A N/A
Fatty acids, tall-oil, reaction products with
tetraethylenepentamine
2500 N/A N/A N/A N/A
Formaldehyde, polymer with benzenamine,
hydrogenated
300 N/A N/A N/A N/A
3,6,9-triazaundecamethylenediamine 500 1100 N/A N/A N/A Oral (mg/
kg)
Dermal
(mg/kg)
Inhalation
(gases)
(ppm)
Inhalation
(vapors)
(mg/l)
Inhalation
(dusts and
mists) (mg/
l)
Section 12. Ecological information
Toxicity
Not available.
Persistence and degradability
Not available.
Date of issue/Date of revision : Date of previous issue : Version : 2 10/14
7/25/2025
12/19/2022
Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 309
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Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects : No known significant effects or critical hazards.
Product/ingredient name
Formaldehyde, polymer with
benzenamine, hydrogenated
- 209 to 219 Low
Soil/Water partition
coefficient
: Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Disposal methods :
Section 14. Transport information
The information provided in section 14 is based on a bulk package shipment via ground transport in North America. All shippers are responsible for ensuring the proper transportation classification and package/container requirements are followed for the relevant mode of transport.
CORROSIVE SOLID, N.O.S.
(Fatty acids, tall-oil, reaction
products with
tetraethylenepentamine,
Formaldehyde, polymer with
benzenamine, hydrogenated)
8 III
UN1759
CORROSIVE SOLID, N.O.S.
(Fatty acids, tall-oil, reaction
products with
tetraethylenepentamine,
Formaldehyde, polymer with
benzenamine, hydrogenated)
8 III
CORROSIVE SOLID, N.O.S.
(Fatty acids, tall-oil, reaction
products with
tetraethylenepentamine,
Formaldehyde, polymer with
benzenamine, hydrogenated)
UN1759
8 III
UN1759
DOT Classification IMDG IATA
No. Yes. The environmentally
hazardous substance mark is
not required.
UN number
UN proper shipping
name
Transport hazard
class(es)
Packing group
Environmental
hazards Marine Pollutant(s):
Date of issue/Date of revision : Date of previous issue : Version : 2 11/14
7/25/2025
12/19/2022
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Section 14. Transport information
Special precautions for user
Transport in bulk according
to IMO instruments
Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
: Not available.
:
Additional information
The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.
IMDG : Emergency schedules F-A, S-B
IATA : The environmentally hazardous substance mark may appear if required by other transportation regulations.
Fatty acids, tall-oil, reaction
products with
tetraethylenepentamine,
3,6,9-triazaundecamethylenediamine
Section 15. Regulatory information
U.S. Federal regulations :
United States inventory (TSCA 8b): All components are active or exempted.
SARA 311/312
Classification : ACUTE TOXICITY (oral) - Category 4
SKIN CORROSION - Category 1C
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Composition/information on ingredients
SARA 302/304
Composition/information on ingredients
No products were found.
SARA 304 RQ : Not applicable.
TSCA 5(e) substance consent order: No products found.
TSCA 5(a)2 final significant new use rules: No products found.
TSCA 8(a) PAIR: Siloxanes and Silicones, di-Me, reaction products with silica TSCA 8(a) CDR Exempt/Partial exemption: Not determined
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
: Listed
Clean Air Act Section 602
Class I Substances
: Not listed
Clean Air Act Section 602
Class II Substances
: Not listed
DEA List I Chemicals
(Precursor Chemicals)
: Not listed
DEA List II Chemicals
(Essential Chemicals)
: Not listed
Date of issue/Date of revision : Date of previous issue : Version : 2 12/14
7/25/2025
12/19/2022
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Section 15. Regulatory information
The following components are listed: CALCIUM CARBONATE; FIBROUS GLASS; TETRAETHYLENE PENTAMINE; ROUGE DUST
Massachusetts :
California Prop. 65
New York : None of the components are listed.
New Jersey : The following components are listed: CALCIUM CARBONATE; TETRAETHYLENEPENTAMINE; IRON OXIDE
Pennsylvania : The following components are listed: LIMESTONE; 1,2-ETHANEDIAMINE, N- (2-AMINOETHYL)-N'-[2-[(2-AMINOETHYL)AMINO]ETHYL]-; IRON OXIDE State regulations
Name % Classification
Fatty acids, tall-oil, reaction
products with
tetraethylenepentamine
≥10 - ≤25 SKIN CORROSION - Category 1C
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1
Formaldehyde, polymer with
benzenamine, hydrogenated
≥10 - ≤25 ACUTE TOXICITY (oral) - Category 3
SKIN CORROSION - Category 1C
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 2
3,6,9-triazaundecamethylenediamine <5 ACUTE TOXICITY (oral) - Category 4 ACUTE TOXICITY (dermal) - Category 4
SKIN CORROSION - Category 1B
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1
Australia : Not determined.
Canada : At least one component is not listed in DSL but all such components are listed in NDSL.
China : Not determined.
Japan : Japan inventory (CSCL): Not determined.
Japan inventory (ISHL): Not determined.
Republic of Korea : Not determined.
New Zealand : Not determined.
Philippines : Not determined.
Taiwan : Not determined.
Turkey : Not determined.
United States : All components are active or exempted.
Thailand : Not determined.
Viet Nam : Not determined.
Eurasian Economic Union : Russian Federation inventory: Not determined.
Inventory list
WARNING: This product can expose you to Silica, crystalline, which is known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov.
Crystalline Silica, respirable part in whole product, <10µm - - Ingredient name No significant risk
level
Maximum
acceptable dosage
level
Date of issue/Date of revision : Date of previous issue : Version : 2 13/14
7/25/2025
12/19/2022
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Section 16. Other information
History
Notice to reader
Indicates information that has changed from previously issued version.
Key to abbreviations :
Procedure used to derive the classification
Classification Justification
ACUTE TOXICITY (oral) - Category 4 Calculation method
SKIN CORROSION - Category 1C Calculation method
SERIOUS EYE DAMAGE - Category 1 Calculation method
SKIN SENSITIZATION - Category 1 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available
SGG = Segregation Group
UN = United Nations
Unique ID : 71E29F6ABAC11FD09AAC54C58D0B1179
Version : 2
Date of printing 8/12/2026
Date of issue/ Date of
revision
Date of previous issue
:
:
:
7/25/2025
12/19/2022
IMPORTANT NOTE: the information contained in this data sheet (as may be amended from time to time) is not intended to be exhaustive and is presented in good faith and believed to be correct as of the date on which it is prepared. It is the userˈs responsibility to verify that this data sheet is current prior to using the product to which it relates.
Persons using the information must make their own determinations as to the suitability of the relevant product for their purposes prior to use. Where those purposes are other than as specifically recommended in this safety data sheet, then the user uses the product at their own risk.
MANUFACTURER’S DISCLAIMER: the conditions, methods and factors affecting the handling, storage, application, use and disposal of the product are not under the control and knowledge of the manufacturer. Therefore the manufacturer does not assume responsibility for any adverse events which may occur in the handling, storage, application, use, misuse or disposal of the product and, so far as permitted by applicable law, the manufacturer expressly disclaims liability for any and all loss, damages and/or expenses arising out of or in any way connected to the storage, handling, use or disposal of the product. Safe handling, storage, use and disposal are the responsibility of the users. Users must comply with all applicable health and safety laws.
Unless we have agreed to the contrary, all products are supplied by us subject to our standard terms and conditions of business, which include limitations of liability. Please make sure to refer to these and / or the relevant agreement which you have with AkzoNobel (or its affiliate, as the case may be). © AkzoNobel
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12/19/2022
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SAFETY DATA SHEET
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Trade name or designation 905 TR Mold Prep Cleaner
of the mixture
Registration number -
Synonyms None.
Product number TR 905
Issue date 07-July-2015
Version number 02
Revision date 08-December-2020
Supersedes date 07-July-2015
1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Solvent.
Uses advised against None known.
1.3. Details of the supplier of the safety data sheet
Company name TR Industries a Division of Granitize Products Inc.
Address 11022 Vulcan Street
South Gate, CA 90280-0893
United States
Telephone (562) 923-5438
Emergency telephone CHEMTREC: (800) 424-9300
CHEMTREC International: 00 1-703-527-3887
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
The mixture has been assessed and/or tested for its physical, health and environmental hazards and the following classification applies.
Classification according to Regulation (EC) No 1272/2008 as amended H225 - Highly flammable liquid and
vapour.
Flammable liquids Category 2
Physical hazards
Skin corrosion/irritation Category 2 H315 - Causes skin irritation.
Health hazards
H319 - Causes serious eye
irritation.
Serious eye damage/eye irritation Category 2
H361d - Suspected of damaging
the unborn child.
Reproductive toxicity (the unborn child) Category 2
H335 - May cause respiratory
irritation.
Specific target organ toxicity - single Category 3 respiratory tract irritation exposure
H336 - May cause drowsiness or
dizziness.
Specific target organ toxicity - single Category 3 narcotic effects exposure
H373 - May cause damage to
organs (central nervous system)
through prolonged or repeated
exposure.
Specific target organ toxicity - repeated Category 2 (central nervous system) exposure
H304 - May be fatal if swallowed
and enters airways.
Aspiration hazard Category 1
H412 - Harmful to aquatic life with
long lasting effects.
Hazardous to the aquatic environment, Category 3
long-term aquatic hazard
Environmental hazards
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Hazard summary May be ignited by heat, sparks or flames. Causes skin irritation. Causes serious eye irritation.
Possible reproductive hazard. May cause irritation to the respiratory system. May cause drowsiness and dizziness. May cause damage to organs through prolonged or repeated exposure. May be fatal if swallowed and enters airways. Dangerous for the environment if discharged into watercourses. Occupational exposure to the substance or mixture may cause adverse health effects.
2.2. Label elements
Label according to Regulation (EC) No. 1272/2008 as amended Contains: 2-Butanone (Methyl ethyl ketone), Toluene
Hazard pictograms
Signal word Danger
Hazard statements
H225 Highly flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H361d Suspected of damaging the unborn child.
H373 May cause damage to organs (central nervous system) through prolonged or repeated exposure.
H412 Harmful to aquatic life with long lasting effects.
Precautionary statements
Prevention
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P260 Do not breathe mist/vapours.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTRE/doctor.
P331 Do NOT induce vomiting.
Storage
P403 + P235 Store in a well-ventilated place. Keep cool.
Disposal Not assigned.
Supplemental label information None.
This mixture does not contain substances assessed to be vPvB / PBT according to Regulation (EC) No 1907/2006, Annex XIII.
2.3. Other hazards
SECTION 3: Composition/information on ingredients
3.2. Mixtures
General information
Chemical name % CAS-No. / EC No. REACH Registration No. Index No. Notes Classification: Flam. Liq. 2;H225, Asp. Tox. 1;H304, Skin Irrit. 2;H315, Eye Irrit. 2;H319, STOT SE 3;H336, Repr. 2;H361d, STOT RE 2;H373, Aquatic Chronic 3;H412 Toluene 108-88-3 01-2119471310-51-0147 601-021-00-3 #
203-625-9
50 - 52
Classification: Flam. Liq. 2;H225, Eye Irrit. 2;H319, STOT SE 3;H335, STOT SE 3;H336 2-Butanone (Methyl ethyl ketone) 78-93-3 01-2119457290-43-0066 606-002-00-3 # 201-159-0
48 - 50
List of abbreviations and symbols that may be used above #: This substance has been assigned Union workplace exposure limit(s).
The full text for all H-statements is displayed in section 16.
All concentrations are in percent by weight unless otherwise indicated.
Composition comments
SECTION 4: First aid measures
Take off all contaminated clothing immediately. IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before reuse.
General information
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4.1. Description of first aid measures
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison centre or doctor/physician if you feel unwell.
Inhalation
Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention.
Skin contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Eye contact
Call a physician or poison control centre immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
Ingestion
Aspiration may cause pulmonary oedema and pneumonitis. May cause drowsiness and dizziness.
Narcosis. Headache. Nausea, vomiting. Behavioural changes. Decrease in motor functions.
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Skin irritation. May cause redness and pain. Prolonged exposure may cause chronic effects.
4.2. Most important symptoms
and effects, both acute and
delayed
Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. Keep victim under observation.
Symptoms may be delayed.
4.3. Indication of any
immediate medical attention
and special treatment needed
SECTION 5: Firefighting measures
General fire hazards Highly flammable liquid and vapour.
5.1. Extinguishing media
Suitable extinguishing Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). media
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media
Vapours may form explosive mixtures with air. Vapours may travel considerable distance to a source of ignition and flash back. During fire, gases hazardous to health may be formed.
5.2. Special hazards arising
from the substance or mixture
5.3. Advice for firefighters
Special protective Self-contained breathing apparatus and full protective clothing must be worn in case of fire. equipment for firefighters
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Cool containers exposed to flames with water until well after the fire is out.
Special fire fighting
procedures
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist/vapours. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
For non-emergency
personnel
Keep unnecessary personnel away. Wear appropriate protective equipment and clothing during clean-up.
For emergency responders
Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground.
6.2. Environmental precautions
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil etc) away from spilled material. Take precautionary measures against static discharge. Use only non-sparking tools. Prevent product from entering drains.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Following product recovery, flush area with water.
Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Wipe up with absorbent material. Clean surface thoroughly to remove residual contamination.
Never return spills to original containers for re-use.
6.3. Methods and material for
containment and cleaning up
6.4. Reference to other For personal protection, see section 8 of the SDS. For waste disposal, see section 13 of the SDS. sections
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SECTION 7: Handling and storage
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. When using do not smoke. Explosion-proof general and local exhaust ventilation. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Do not breathe mist/vapours. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Pregnant or breastfeeding women must not handle this product. Should be handled in closed systems, if possible. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices.
7.1. Precautions for safe
handling
Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Store in a cool, dry place out of direct sunlight. Store in tightly closed container. Store in a well-ventilated place. Store away from incompatible materials (see section 10 of the SDS).
7.2. Conditions for safe
storage, including any
incompatibilities
7.3. Specific end use(s) Solvent.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
Austria. MAK List
Components Type Value
2-Butanone (Methyl ethyl MAK 295 mg/m3
ketone) (CAS 78-93-3)
100 ppm
STEL 590 mg/m3
200 ppm
Toluene (CAS 108-88-3) MAK 190 mg/m3
50 ppm
STEL 380 mg/m3
100 ppm
Belgium. Exposure Limit Values
Components Type Value
2-Butanone (Methyl ethyl STEL 900 mg/m3
ketone) (CAS 78-93-3)
300 ppm
TWA 600 mg/m3
200 ppm
Toluene (CAS 108-88-3) STEL 384 mg/m3
100 ppm
TWA 77 mg/m3
20 ppm
Bulgaria. OELs. Regulation No 13 on protection of workers against risks of exposure to chemical agents at work Components Type Value
2-Butanone (Methyl ethyl STEL 885 mg/m3
ketone) (CAS 78-93-3)
TWA 590 mg/m3
Toluene (CAS 108-88-3) STEL 384 mg/m3
100 ppm
TWA 192 mg/m3
50 ppm
Croatia. Dangerous Substance Exposure Limit Values in the Workplace (ELVs), Annexes 1 and 2, Narodne Novine, 13/09 Components Type Value
2-Butanone (Methyl ethyl MAC 600 mg/m3
ketone) (CAS 78-93-3)
200 ppm
STEL 900 mg/m3
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Croatia. Dangerous Substance Exposure Limit Values in the Workplace (ELVs), Annexes 1 and 2, Narodne Novine, 13/09 Components Type Value
300 ppm
Toluene (CAS 108-88-3) MAC 192 mg/m3
50 ppm
STEL 384 mg/m3
100 ppm
Czech Republic. OELs. Government Decree 361
Components Type Value
2-Butanone (Methyl ethyl Ceiling 900 mg/m3
ketone) (CAS 78-93-3)
TWA 600 mg/m3
Toluene (CAS 108-88-3) Ceiling 500 mg/m3
TWA 200 mg/m3
Denmark. Exposure Limit Values
Components Type Value
2-Butanone (Methyl ethyl TLV 145 mg/m3
ketone) (CAS 78-93-3)
50 ppm
Toluene (CAS 108-88-3) TLV 94 mg/m3
25 ppm
Estonia. OELs. Occupational Exposure Limits of Hazardous Substances. (Annex of Regulation No. 293 of 18 September 2001)
Components Type Value
2-Butanone (Methyl ethyl STEL 900 mg/m3
ketone) (CAS 78-93-3)
300 ppm
TWA 600 mg/m3
200 ppm
Toluene (CAS 108-88-3) STEL 384 mg/m3
100 ppm
TWA 192 mg/m3
50 ppm
Finland. Workplace Exposure Limits
Components Type Value
2-Butanone (Methyl ethyl STEL 300 mg/m3
ketone) (CAS 78-93-3)
100 ppm
Toluene (CAS 108-88-3) STEL 380 mg/m3
100 ppm
TWA 81 mg/m3
25 ppm
France. Threshold Limit Values (VLEP) for Occupational Exposure to Chemicals in France, INRS ED 984 Components Type Value
2-Butanone (Methyl ethyl VLE 900 mg/m3
ketone) (CAS 78-93-3)
Regulatory status: Regulatory binding (VRC)
300 ppm
Regulatory status: Regulatory binding (VRC)
VME 600 mg/m3
Regulatory status: Regulatory binding (VRC)
200 ppm
Regulatory status: Regulatory binding (VRC)
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France. Threshold Limit Values (VLEP) for Occupational Exposure to Chemicals in France, INRS ED 984 Components Type Value
Toluene (CAS 108-88-3) VLE 384 mg/m3
Regulatory status: Regulatory binding (VRC)
100 ppm
Regulatory status: Regulatory binding (VRC)
VME 76,8 mg/m3
Regulatory status: Regulatory binding (VRC)
20 ppm
Regulatory status: Regulatory binding (VRC)
Germany. DFG MAK List (advisory OELs). Commission for the Investigation of Health Hazards of Chemical Compounds in the Work Area (DFG)
Components Type Value
2-Butanone (Methyl ethyl TWA 600 mg/m3
ketone) (CAS 78-93-3)
200 ppm
Toluene (CAS 108-88-3) TWA 190 mg/m3
50 ppm
Germany. TRGS 900, Limit Values in the Ambient Air at the Workplace Components Type Value
2-Butanone (Methyl ethyl AGW 600 mg/m3
ketone) (CAS 78-93-3)
200 ppm
Toluene (CAS 108-88-3) AGW 190 mg/m3
50 ppm
Greece. OELs (Decree No. 90/1999, as amended)
Components Type Value
2-Butanone (Methyl ethyl STEL 900 mg/m3
ketone) (CAS 78-93-3)
300 ppm
TWA 600 mg/m3
200 ppm
Toluene (CAS 108-88-3) STEL 384 mg/m3
100 ppm
TWA 192 mg/m3
50 ppm
Hungary. OELs. Joint Decree on Chemical Safety of Workplaces Components Type Value
2-Butanone (Methyl ethyl STEL 900 mg/m3
ketone) (CAS 78-93-3)
TWA 600 mg/m3
Toluene (CAS 108-88-3) STEL 380 mg/m3
TWA 190 mg/m3
Iceland. OELs. Regulation 154/1999 on occupational exposure limits Components Type Value
2-Butanone (Methyl ethyl STEL 900 mg/m3
ketone) (CAS 78-93-3)
300 ppm
TWA 145 mg/m3
50 ppm
Toluene (CAS 108-88-3) STEL 188 mg/m3
50 ppm
TWA 94 mg/m3
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Iceland. OELs. Regulation 154/1999 on occupational exposure limits Components Type Value
25 ppm
Ireland. Occupational Exposure Limits
Components Type Value
2-Butanone (Methyl ethyl STEL 900 mg/m3
ketone) (CAS 78-93-3)
300 ppm
TWA 600 mg/m3
200 ppm
Toluene (CAS 108-88-3) STEL 384 mg/m3
100 ppm
TWA 192 mg/m3
50 ppm
Italy. OELs
Components Type Value
2-Butanone (Methyl ethyl STEL 900 mg/m3
ketone) (CAS 78-93-3)
300 ppm
TWA 600 mg/m3
200 ppm
Toluene (CAS 108-88-3) TWA 192 mg/m3
50 ppm
Latvia. OELs. Occupational exposure limit values of chemical substances in work environment Components Type Value
2-Butanone (Methyl ethyl STEL 900 mg/m3
ketone) (CAS 78-93-3)
300 ppm
TWA 200 mg/m3
67 ppm
Toluene (CAS 108-88-3) STEL 150 mg/m3
40 ppm
TWA 50 mg/m3
14 ppm
Lithuania. OELs. Limit Values for Chemical Substances, General Requirements (Hygiene Norm HN 23:2007) Components Type Value
2-Butanone (Methyl ethyl STEL 900 mg/m3
ketone) (CAS 78-93-3)
300 ppm
TWA 600 mg/m3
200 ppm
Toluene (CAS 108-88-3) STEL 384 mg/m3
100 ppm
TWA 192 mg/m3
50 ppm
Luxembourg. Binding Occupational exposure limit values (Annex I), Memorial A Components Type Value
2-Butanone (Methyl ethyl STEL 900 mg/m3
ketone) (CAS 78-93-3)
300 ppm
TWA 600 mg/m3
200 ppm
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Luxembourg. Binding Occupational exposure limit values (Annex I), Memorial A Components Type Value
Toluene (CAS 108-88-3) STEL 384 mg/m3
100 ppm
TWA 192 mg/m3
50 ppm
Malta. OELs. Occupational Exposure Limit Values (L.N. 227. of Occupational Health and Safety Authority Act (CAP. 424), Schedules I and V)
Components Type Value
2-Butanone (Methyl ethyl STEL 900 mg/m3
ketone) (CAS 78-93-3)
300 ppm
TWA 600 mg/m3
200 ppm
Toluene (CAS 108-88-3) STEL 384 mg/m3
100 ppm
TWA 192 mg/m3
50 ppm
Netherlands. OELs (binding)
Components Type Value
2-Butanone (Methyl ethyl STEL 900 mg/m3
ketone) (CAS 78-93-3)
TWA 590 mg/m3
Toluene (CAS 108-88-3) STEL 384 mg/m3
TWA 150 mg/m3
Norway. Administrative Norms for Contaminants in the Workplace Components Type Value
2-Butanone (Methyl ethyl TLV 220 mg/m3
ketone) (CAS 78-93-3)
75 ppm
Toluene (CAS 108-88-3) TLV 94 mg/m3
25 ppm
Poland. Ordinance of the Minister of Labour and Social Policy on 6 June 2014 on the maximum permissible concentrations and intensities of harmful health factors in the work environment, Journal of Laws 2014, item 817 Components Type Value
2-Butanone (Methyl ethyl STEL 900 mg/m3
ketone) (CAS 78-93-3)
TWA 450 mg/m3
Toluene (CAS 108-88-3) STEL 200 mg/m3
TWA 100 mg/m3
Portugal. OELs. Decree-Law n. 290/2001 (Journal of the Republic - 1 Series A, n.266) Components Type Value
2-Butanone (Methyl ethyl STEL 900 mg/m3
ketone) (CAS 78-93-3)
300 ppm
TWA 600 mg/m3
200 ppm
Toluene (CAS 108-88-3) STEL 384 mg/m3
100 ppm
TWA 192 mg/m3
50 ppm
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Portugal. VLEs. Norm on occupational exposure to chemical agents (NP 1796) Components Type Value
2-Butanone (Methyl ethyl STEL 300 ppm
ketone) (CAS 78-93-3)
TWA 200 ppm
Toluene (CAS 108-88-3) TWA 20 ppm
Romania. OELs. Protection of workers from exposure to chemical agents at the workplace Components Type Value
2-Butanone (Methyl ethyl STEL 900 mg/m3
ketone) (CAS 78-93-3)
300 ppm
TWA 600 mg/m3
200 ppm
Toluene (CAS 108-88-3) STEL 384 mg/m3
100 ppm
TWA 192 mg/m3
50 ppm
Slovakia. OELs. Decree of the government of the Slovak Republic concerning protection of health in work with chemical agents
Components Type Value
2-Butanone (Methyl ethyl TWA 600 mg/m3
ketone) (CAS 78-93-3)
200 ppm
Toluene (CAS 108-88-3) TWA 192 mg/m3
50 ppm
Slovakia. OELs. Regulation No. 300/2007 concerning protection of health in work with chemical agents Components Type Value
2-Butanone (Methyl ethyl STEL 900 mg/m3
ketone) (CAS 78-93-3)
300 ppm
Toluene (CAS 108-88-3) STEL 384 mg/m3
100 ppm
Slovenia. OELs. Regulations concerning protection of workers against risks due to exposure to chemicals while working (Official Gazette of the Republic of Slovenia)
Components Type Value
2-Butanone (Methyl ethyl TWA 600 mg/m3
ketone) (CAS 78-93-3)
200 ppm
Toluene (CAS 108-88-3) TWA 192 mg/m3
50 ppm
Spain. Occupational Exposure Limits
Components Type Value
2-Butanone (Methyl ethyl STEL 900 mg/m3
ketone) (CAS 78-93-3)
300 ppm
TWA 600 mg/m3
200 ppm
Toluene (CAS 108-88-3) STEL 384 mg/m3
100 ppm
TWA 192 mg/m3
50 ppm
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Sweden. OELs. Work Environment Authority (AV), Occupational Exposure Limit Values (AFS 2015:7) Components Type Value
2-Butanone (Methyl ethyl Ceiling 900 mg/m3
ketone) (CAS 78-93-3)
300 ppm
TWA 150 mg/m3
50 ppm
Toluene (CAS 108-88-3) Ceiling 384 mg/m3
100 ppm
TWA 192 mg/m3
50 ppm
Switzerland. SUVA Grenzwerte am Arbeitsplatz
Components Type Value
2-Butanone (Methyl ethyl STEL 590 mg/m3
ketone) (CAS 78-93-3)
200 ppm
TWA 590 mg/m3
200 ppm
Toluene (CAS 108-88-3) STEL 760 mg/m3
200 ppm
TWA 190 mg/m3
50 ppm
UK. EH40 Workplace Exposure Limits (WELs)
Components Type Value
2-Butanone (Methyl ethyl STEL 899 mg/m3
ketone) (CAS 78-93-3)
300 ppm
TWA 600 mg/m3
200 ppm
Toluene (CAS 108-88-3) STEL 384 mg/m3
100 ppm
TWA 191 mg/m3
50 ppm
EU. Indicative Exposure Limit Values in Directives 91/322/EEC, 2000/39/EC, 2006/15/EC, 2009/161/EU, 2017/164/EU Components Type Value
2-Butanone (Methyl ethyl STEL 900 mg/m3
ketone) (CAS 78-93-3)
300 ppm
TWA 600 mg/m3
200 ppm
Toluene (CAS 108-88-3) STEL 384 mg/m3
100 ppm
TWA 192 mg/m3
50 ppm
Biological limit values
Croatia. BLV. Dangerous Substance Exposure Limit Values at Workplace, Annexes 4 (as amended) Components Value Determinant Specimen Sampling Time
2,6 mg/g methyl ethyl
ketone
Creatinine in
urine
2-Butanone (Methyl ethyl *
ketone) (CAS 78-93-3)
4,08 mmol/mol methyl ethyl
ketone
Creatinine in
urine
*
2,5 g/g Hippuric acid Creatinine in
urine
Toluene (CAS 108-88-3) *
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Croatia. BLV. Dangerous Substance Exposure Limit Values at Workplace, Annexes 4 (as amended) Components Value Determinant Specimen Sampling Time
1 mg/g o-cresol
(Phenol,
2-methyl-)
Creatinine in
urine
*
1 mg/l Toluene Blood *
1,05 mmol/mol o-cresol
(Phenol,
2-methyl-)
Creatinine in
urine
*
1,58 mol/mol Hippuric acid Creatinine in
urine
*
20 ppm Toluene End-exhaled
air
*
10,85 umol/l Toluene Blood *
0,83 umol/l Toluene End-exhaled
air
*
* - For sampling details, please see the source document.
Czech Republic. Limit Values for Indictators of Biological Exposure Tests in Urine and Blood, Annex 2, Tables 1 and 2, Government Decree 432/2003 Sb.
Components Value Determinant Specimen Sampling Time
1,6 µmol/mmol o-Cresol (with
hydrolysis)
Creatinine in
urine
Toluene (CAS 108-88-3) *
1,5 mg/g o-Cresol (with
hydrolysis)
Creatinine in
urine
*
* - For sampling details, please see the source document.
Finland. HTP-arvot, App 2., Biological Limit Values, (BRA/BGV) , Social Affairs and Ministry of Health Components Value Determinant Specimen Sampling Time
500 nmol/l Toluene
concentration
Toluene (CAS 108-88-3) Blood *
* - For sampling details, please see the source document.
France. Biological indicators of exposure (IBE) (National Institute for Research and Security (INRS, ND 2065) Components Value Determinant Specimen Sampling Time
2 mg/l Méthyléthylcéto
ne
2-Butanone (Methyl ethyl Urine *
ketone) (CAS 78-93-3)
2500 mg/g Acide
hippurique
Creatinine in
urine
Toluene (CAS 108-88-3) *
2500 mg/g Acide
hippurique
Creatinine in
urine
*
1 mg/l Toluène Venous
blood
*
* - For sampling details, please see the source document.
Germany. TRGS 903, BAT List (Biological Limit Values)
Components Value Determinant Specimen Sampling Time
2-Butanone (Methyl ethyl 2 mg/l 2-Butanon Urine *
ketone) (CAS 78-93-3)
Toluene (CAS 108-88-3) 600 µg/l Toluol Blood *
1,5 mg/l o-Kresol (nach
Hydrolyse)
Urine *
* - For sampling details, please see the source document.
Hungary. Chemical Safety at Workplace Ordinance Joint Decree No. 25/2000 (Annex 2): Permissible limit values of biological exposure (effect) indices
Components Value Determinant Specimen Sampling Time
1 mg/g o-crezol Creatinine in
urine
Toluene (CAS 108-88-3) *
1,05 µmol/mmol o-crezol Creatinine in
urine
*
* - For sampling details, please see the source document. 905 TR Mold Prep Cleaner SDS EU
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Slovakia. BLVs (Biological Limit Value). Regulation no. 355/2006 concerning protection of workers exposed to chemical agents, Annex 2
Components Value Determinant Specimen Sampling Time
Toluene (CAS 108-88-3) 600 µg/l Toluene Blood *
1600 mg/g Hippuric acid Creatinine in
urine
*
1,03 mg/g o-cresol
(Phenol,
2-methyl-)
Creatinine in
urine
*
2401 mg/l Hippuric acid Urine *
1,5 mg/l o-cresol
(Phenol,
2-methyl-)
Urine *
* - For sampling details, please see the source document.
Spain. Biological Limit Values (VLBs), Occupational Exposure Limits for Chemical Agents, Table 4 Components Value Determinant Specimen Sampling Time
2-Butanone (Methyl ethyl 2 mg/l Metiletilcetona Urine * ketone) (CAS 78-93-3)
Toluene (CAS 108-88-3) 0,08 mg/l Tolueno Urine *
0,05 mg/l Tolueno Blood *
* - For sampling details, please see the source document.
Switzerland. BAT-Werte (Biological Limit Values in the Workplace as per SUVA) Components Value Determinant Specimen Sampling Time
2 mg/l 2-Butanon
(MEK)
2-Butanone (Methyl ethyl Urine *
ketone) (CAS 78-93-3)
Toluene (CAS 108-88-3) 600 µg/l Toluol Blood *
2 g/g Hippursäure Creatinine in
urine
*
0,5 mg/l o-Kresol Urine *
* - For sampling details, please see the source document.
UK. EH40 Biological Monitoring Guidance Values (BMGVs)
Components Value Determinant Specimen Sampling Time
2-Butanone (Methyl ethyl 70 umol/l Butan-2-one Urine *
ketone) (CAS 78-93-3)
* - For sampling details, please see the source document.
Recommended monitoring Follow standard monitoring procedures. procedures
Derived no effect levels Not available.
(DNELs)
Predicted no effect
concentrations (PNECs)
Not available.
Exposure guidelines
EU Exposure Limit Values: Skin designation
Toluene (CAS 108-88-3) Can be absorbed through the skin.
Slovenia. OELs. Regulations concerning protection of workers against risks due to exposure to chemicals while working (Official Gazette of the Republic of Slovenia)
2-Butanone (Methyl ethyl ketone) (CAS 78-93-3) Can be absorbed through the skin.
Toluene (CAS 108-88-3) Can be absorbed through the skin.
8.2. Exposure controls
Explosion-proof general and local exhaust ventilation. Good general ventilation should be used.
Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. Provide easy access to water supply and eye wash facilities.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment Use personal protective equipment as required. Personal protection equipment should be chosen according to the CEN standards and in discussion with the supplier of the personal protective equipment.
General information
Wear safety glasses with side shields (or goggles). Wear face shield if there is risk of splashes.
Eye protection should meet standard EN 166.
Eye/face protection
Skin protection
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Wear suitable gloves tested to EN374. Be aware that the liquid may penetrate the gloves.
Frequent change is advisable. Nitrile or neoprene gloves are recommended. Other suitable gloves can be recommended by the glove supplier.
- Hand protection
- Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.
If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Use filter type A2 according to EN 14387.
Check with respiratory protective equipment suppliers.
Respiratory protection
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
Observe any medical surveillance requirements. When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.
Hygiene measures
Inform appropriate managerial or supervisory personnel of all environmental releases. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. Fume scrubbers, filters or engineering modifications to the process equipment may be necessary to reduce emissions to acceptable levels.
Environmental exposure
controls
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties Appearance
Physical state Liquid.
Form Clear liquid.
Colour Colourless.
Odour Hydrocarbon.
Odour threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boiling
range
> 79,4 °C (> 175 °F)
Flash point 0,8 °C (33,4 °F) Closed cup (Calculated)
Evaporation rate > 1 (n-Butyl acetate=1)
Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
1,3
Flammability limit - upper
(%)
11,5
Vapour pressure > 22 mmHg
Vapour density > 1 (Air=1)
Relative density 0,83 (Water=1)
Solubility(ies) Partially soluble in water.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Explosive properties Not explosive.
Oxidising properties Not oxidising.
9.2. Other information No relevant additional information available.
SECTION 10: Stability and reactivity
10.1. Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
10.2. Chemical stability Material is stable under normal conditions.
10.3. Possibility of hazardous No dangerous reaction known under conditions of normal use. reactions
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Protect against direct sunlight. Contact with incompatible materials.
10.4. Conditions to avoid
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10.5. Incompatible materials Strong oxidising agents. Amines. Ammonia. Caustics. Isocyanates.
Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours.
10.6. Hazardous
decomposition products
SECTION 11: Toxicological information
General information Occupational exposure to the substance or mixture may cause adverse effects.
Information on likely routes of exposure
Inhalation May cause drowsiness and dizziness. May cause irritation to the respiratory system. Prolonged inhalation may be harmful.
Skin contact Causes skin irritation. May be absorbed through the skin.
Eye contact Causes serious eye irritation.
Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia.
Symptoms Aspiration may cause pulmonary oedema and pneumonitis. May cause drowsiness and dizziness.
Narcosis. Headache. Nausea, vomiting. Behavioural changes. Decrease in motor functions.
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Skin irritation. May cause redness and pain. Prolonged exposure may cause chronic effects.
11.1. Information on toxicological effects
Acute toxicity Not expected to be acutely toxic.
Components Species Test Results
2-Butanone (Methyl ethyl ketone) (CAS 78-93-3)
Dermal
Acute
LD50 Rat 6400 mg/kg
Inhalation
LC50 Rat 34,5 mg/l, 4 Hours
Vapour
Oral
LD50 Rat 2600 mg/kg
Toluene (CAS 108-88-3)
Dermal
Acute
LD50 Rabbit 12200 mg/kg
Inhalation
LC50 Rat 28,1 mg/l, 4 Hours
Vapour
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/eye Causes serious eye irritation.
irritation
Respiratory sensitisation Based on available data, the classification criteria are not met.
Skin sensitisation Based on available data, the classification criteria are not met.
Germ cell mutagenicity Based on available data, the classification criteria are not met.
Carcinogenicity Based on available data, the classification criteria are not met.
IARC Monographs. Overall Evaluation of Carcinogenicity
Toluene (CAS 108-88-3) 3 Not classifiable as to carcinogenicity to humans.
Reproductive toxicity Suspected of damaging the unborn child.
Specific target organ toxicity -
single exposure
May cause respiratory irritation. May cause drowsiness and dizziness.
Specific target organ toxicity -
repeated exposure
May cause damage to organs (central nervous system) through prolonged or repeated exposure.
Aspiration hazard May be fatal if swallowed and enters airways.
Mixture versus substance No information available.
information
Other information Symptoms may be delayed.
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SECTION 12: Ecological information
12.1. Toxicity Harmful to aquatic life with long lasting effects.
Components Species Test Results
2-Butanone (Methyl ethyl ketone) (CAS 78-93-3)
Aquatic
Acute
Crustacea EC50 Daphnia magna 5091 mg/l, 48 Hours
Fish LC50 Pimephales promelas 3220 mg/l, 96 Hours
Toluene (CAS 108-88-3)
Aquatic
Acute
Crustacea EC50 Daphnia magna 11,5 mg/l, 48 hours
Fish LC50 Oncorhynchus kisutch 5,5 mg/l, 96 hours
Chronic
Crustacea NOEC Ceriodaphnia dubia 0,74 mg/l, 7 days
Fish NOEC Oncorhynchus kisutch 1,4 mg/l, 40 days
12.2. Persistence and No data is available on the degradability of this product. degradability
12.3. Bioaccumulative potential
Partition coefficient
n-octanol/water (log Kow)
2-Butanone (Methyl ethyl ketone) (CAS 78-93-3) 0,29
Toluene (CAS 108-88-3) 2,73
Bioconcentration factor (BCF) Not available.
12.4. Mobility in soil The product is slightly soluble in water. Expected to have low mobility in soil.
This mixture does not contain substances assessed to be vPvB / PBT according to Regulation (EC) No 1907/2006, Annex XIII.
12.5. Results of PBT and vPvB
assessment
12.6. Other adverse effects The product contains volatile organic compounds which have a photochemical ozone creation potential.
12.7. Additional information
Estonia Dangerous substances in groundwater Data
2-Butanone (Methyl ethyl ketone) (CAS 78-93-3) Pesticides (total) 0,5 ug/l Pesticides (total) 5 ug/l
Toluene (CAS 108-88-3) TOLUENE 0,5 ug/l
TOLUENE 50 ug/l
Estonia Dangerous substances in soil Data
2-Butanone (Methyl ethyl ketone) (CAS 78-93-3) Synthetic pesticides (total of active substances) 0,5 mg/kg Synthetic pesticides (total of active substances) 20 mg/kg Synthetic pesticides (total of active substances) 5 mg/kg Toluene (CAS 108-88-3) TOLUENE 0,1 mg/kg
TOLUENE 100 mg/kg
TOLUENE 3 mg/kg
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner.
Residual waste
Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal.
Contaminated packaging
EU waste code The Waste code should be assigned in discussion between the user, the producer and the waste disposal company.
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations.
Disposal methods/information
Special precautions Dispose in accordance with all applicable regulations. 905 TR Mold Prep Cleaner SDS EU
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SECTION 14: Transport information
ADR
14.1. UN number UN1993
14.2. UN proper shipping FLAMMABLE LIQUID, N.O.S. (TOLUENE, METHYL ETHYL KETONE) name
Class 3
14.3. Transport hazard class(es)
Subsidiary risk -
Label(s) 3
Hazard No. (ADR) 33
Tunnel restriction code D/E
14.4. Packing group II
14.5. Environmental hazards No
14.6. Special precautions Read safety instructions, SDS and emergency procedures before handling. for user
RID
14.1. UN number UN1993
14.2. UN proper shipping FLAMMABLE LIQUID, N.O.S. (TOLUENE, METHYL ETHYL KETONE) name
Class 3
14.3. Transport hazard class(es)
Subsidiary risk -
Label(s) 3
14.4. Packing group II
14.5. Environmental hazards No
14.6. Special precautions Read safety instructions, SDS and emergency procedures before handling. for user
ADN
14.1. UN number UN1993
14.2. UN proper shipping FLAMMABLE LIQUID, N.O.S. (TOLUENE, METHYL ETHYL KETONE) name
Class 3
14.3. Transport hazard class(es)
Subsidiary risk -
Label(s) 3
14.4. Packing group II
14.5. Environmental hazards No
14.6. Special precautions Read safety instructions, SDS and emergency procedures before handling. for user
IATA
14.1. UN number UN1993
14.2. UN proper shipping Flammable liquid, n.o.s. (Toluene, Methyl ethyl ketone) name
Class 3
14.3. Transport hazard class(es)
Subsidiary risk -
Label(s) 3
14.4. Packing group II
14.5. Environmental hazards No
ERG Code 3H
14.6. Special precautions Read safety instructions, SDS and emergency procedures before handling. for user
IMDG
14.1. UN number UN1993
14.2. UN proper shipping FLAMMABLE LIQUID, N.O.S. (TOLUENE, METHYL ETHYL KETONE) name
Class 3
14.3. Transport hazard class(es)
Subsidiary risk -
14.4. Packing group II
Marine pollutant No
14.5. Environmental hazards
EmS F-E, S̲-E̲
14.6. Special precautions Read safety instructions, SDS and emergency procedures before handling. for user
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14.7. Transport in bulk Not applicable.
according to Annex II of
MARPOL 73/78 and the IBC
Code
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulations
Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I and II, as amended Not listed.
Regulation (EC) No. 850/2004 On persistent organic pollutants, Annex I as amended Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 1 as amended Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 2 as amended Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 3 as amended Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex V as amended Not listed.
Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry, as amended Toluene (CAS 108-88-3)
Regulation (EC) No. 1907/2006, REACH Article 59(10) Candidate List as currently published by ECHA Not listed.
Authorisations
Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorisation, as amended Not listed.
Restrictions on use
Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended 2-Butanone (Methyl ethyl ketone) (CAS 78-93-3)
Toluene (CAS 108-88-3)
Directive 2004/37/EC: on the protection of workers from the risks related to exposure to carcinogens and mutagens at work, as amended.
Not listed.
Other EU regulations
Directive 2012/18/EU on major accident hazards involving dangerous substances, as amended 2-Butanone (Methyl ethyl ketone) (CAS 78-93-3)
Toluene (CAS 108-88-3)
The product is classified and labelled in accordance with Regulation (EC) 1272/2008 (CLP Regulation) as amended. This Safety Data Sheet complies with the requirements of Regulation (EC) No 1907/2006, as amended.
Other regulations
According to Directive 92/85/EEC as amended, pregnant women should not work with the product, if there is the least risk of exposure.
Young people under 18 years old are not allowed to work with this product according to EU Directive 94/33/EC on the protection of young people at work, as amended. Follow national regulation for work with chemical agents in accordance with Directive 98/24/EC, as amended.
National regulations
15.2. Chemical safety No Chemical Safety Assessment has been carried out. assessment
SECTION 16: Other information
List of abbreviations
ADN: European Agreement Concerning the International Carriage of Dangerous Goods by Inland Waterways.
ADR: European Agreement Concerning the International Carriage of Dangerous Goods by Road.
IATA: International Air Transport Association.
IBC Code: International Code for the Construction and Equipment of Ships Carrying Dangerous Chemicals in Bulk.
IMDG Code: International Maritime Dangerous Goods Code.
MARPOL: International Convention for the Prevention of Pollution from Ships.
RID: Regulations concerning the International Carriage of Dangerous Goods by Rail.
STEL: Short-Term Exposure Limit.
905 TR Mold Prep Cleaner SDS EU
913171 Version #: 02 Revision date: 08-December-2020 Issue date: 07-July-2015 17 / 18 Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 330
TWA: Time Weighted Average Value.
ACGIH Documentation of the Threshold Limit Values and Biological Exposure Indices EPA: AQUIRE database
HSDB® - Hazardous Substances Data Bank
IARC Monographs. Overall Evaluation of Carcinogenicity
National Toxicology Program (NTP) Report on Carcinogens References
The classification for health and environmental hazards is derived by a combination of calculation methods and test data, if available.
Information on evaluation
method leading to the
classification of mixture
H225 Highly flammable liquid and vapour.
Full text of any H-statements
not written out in full under
Sections 2 to 15
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H361d Suspected of damaging the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
H412 Harmful to aquatic life with long lasting effects.
Training information Follow training instructions when handling this material.
TR Industries cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available.
Disclaimer
905 TR Mold Prep Cleaner SDS EU
913171 Version #: 02 Revision date: 08-December-2020 Issue date: 07-July-2015 18 / 18 Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 331
SAFETY DATA SHEET
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Trade name or designation MR-910/MR-910FD/MR-910HS
of the mixture
Registration number -
Synonyms None.
Product number TR-910/TR-910FD/TR-910HS
Issue date 06-June-2017
Version number 04
Revision date 08-May-2021
Supersedes date 23-June-2020
1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Mold release.
Uses advised against None known.
1.3. Details of the supplier of the safety data sheet
Company name TR Industries a Division of Granitize Products Inc.
Address 11022 Vulcan Street
South Gate, CA 90280-0893
United States
Telephone (562) 923-5438
Emergency telephone CHEMTREC: (800) 424-9300
CHEMTREC International: 00 1-703-527-3887
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
The mixture has been assessed and/or tested for its physical, health and environmental hazards and the following classification applies.
Classification according to Regulation (EC) No 1272/2008 as amended H226 - Flammable liquid and
vapour.
Flammable liquids Category 3
Physical hazards
Skin corrosion/irritation Category 2 H315 - Causes skin irritation.
Health hazards
H319 - Causes serious eye
irritation.
Serious eye damage/eye irritation Category 2
H335 - May cause respiratory
irritation.
Specific target organ toxicity - single Category 3 respiratory tract irritation exposure
H336 - May cause drowsiness or
dizziness.
Specific target organ toxicity - single Category 3 narcotic effects exposure
H304 - May be fatal if swallowed
and enters airways.
Aspiration hazard Category 1
H411 - Toxic to aquatic life with
long lasting effects.
Hazardous to the aquatic environment, Category 2
long-term aquatic hazard
Environmental hazards
Hazard summary May be ignited by heat, sparks or flames. Causes skin irritation. Causes serious eye irritation. May cause irritation to the respiratory system. May cause drowsiness and dizziness. May be fatal if swallowed and enters airways. Dangerous for the environment if discharged into watercourses.
Occupational exposure to the substance or mixture may cause adverse health effects.
2.2. Label elements
Label according to Regulation (EC) No. 1272/2008 as amended Contains: Dibutyl ether, Naphtha (petroleum), hydrotreated heavy, Octane MR-910/MR-910FD/MR-910HS SDS EU
913176 Version #: 04 Revision date: 08-May-2021 Issue date: 06-June-2017 1 / 13 Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 332
Hazard pictograms
Signal word Danger
Hazard statements
H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statements
Prevention
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P273 Avoid release to the environment.
Response
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTRE/doctor.
P331 Do NOT induce vomiting.
P391 Collect spillage.
P363 Wash contaminated clothing before reuse.
Storage
P403 + P235 Store in a well-ventilated place. Keep cool.
Disposal Not assigned.
Supplemental label information None.
Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapour. May cause flash fire or explosion.
This mixture does not contain substances assessed to be vPvB / PBT according to Regulation (EC) No 1907/2006, Annex XIII.
2.3. Other hazards
SECTION 3: Composition/information on ingredients
3.2. Mixtures
General information
Chemical name % CAS-No. / EC No. REACH Registration No. Index No. Notes Classification: Flam. Liq. 3;H226, Asp. Tox. 1;H304, STOT SE 3;H336, Aquatic Chronic 3;H412 Naphtha (petroleum), hydrotreated 649-327-00-6
heavy
64742-48-9 -
265-150-3
60 - 100
Classification: Flam. Liq. 3;H226, Skin Irrit. 2;H315, Eye Irrit. 2;H319, STOT SE 3;H335, Aquatic Chronic 3;H412
Dibutyl ether 142-96-1 - 603-054-00-9
205-575-3
10 - 30
Classification: Flam. Liq. 2;H225, Asp. Tox. 1;H304, Skin Irrit. 2;H315, STOT SE 3;H336, Aquatic Acute 1;H400, Aquatic Chronic 1;H410
C
Octane 111-65-9 - 601-009-00-8
203-892-1
1 - 5
List of abbreviations and symbols that may be used above Note C: Some organic substances may be marketed either in a specific isomeric form or as a mixture of several isomers. In this case the supplier must state on the label whether the substance is a specific isomer or a mixture of isomers.
The full text for all H-statements is displayed in section 16.
All concentrations are in percent by weight unless otherwise indicated. Components not listed are either non-hazardous or are below reportable limits.
Composition comments
SECTION 4: First aid measures
Take off all contaminated clothing immediately. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse.
General information
4.1. Description of first aid measures
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison centre or doctor/physician if you feel unwell.
Inhalation
MR-910/MR-910FD/MR-910HS SDS EU
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Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse.
Skin contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Eye contact
Call a physician or poison control centre immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
Ingestion
Aspiration may cause pulmonary oedema and pneumonitis. May cause drowsiness and dizziness.
Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Skin irritation. May cause redness and pain.
4.2. Most important symptoms
and effects, both acute and
delayed
Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. Keep victim under observation.
Symptoms may be delayed.
4.3. Indication of any
immediate medical attention
and special treatment needed
SECTION 5: Firefighting measures
General fire hazards Flammable liquid and vapour.
5.1. Extinguishing media
Water fog. Alcohol resistant foam. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only.
Suitable extinguishing
media
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media
Vapours may form explosive mixtures with air. Vapours may travel considerable distance to a source of ignition and flash back. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. To reduce potential for static discharge, use proper bonding and grounding procedures.
This liquid may accumulate static electricity when filling properly grounded containers. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. During fire, gases hazardous to health may be formed.
5.2. Special hazards arising
from the substance or mixture
5.3. Advice for firefighters
Special protective Self-contained breathing apparatus and full protective clothing must be worn in case of fire. equipment for firefighters
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Cool containers exposed to flames with water until well after the fire is out.
Special fire fighting
procedures
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist/vapours. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Use appropriate containment to avoid environmental contamination. Transfer by mechanical means such as vacuum truck to a salvage tank or other suitable container for recovery or safe disposal. Local authorities should be advised if significant spillages cannot be contained.
For non-emergency
personnel
Keep unnecessary personnel away. Wear appropriate protective equipment and clothing during clean-up.
For emergency responders
Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Use appropriate containment to avoid environmental contamination.
6.2. Environmental precautions
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil etc) away from spilled material. Take precautionary measures against static discharge. Use only non-sparking tools. Prevent entry into waterways, sewer, basements or confined areas.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Following product recovery, flush area with water.
Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Wipe up with absorbent material. Clean surface thoroughly to remove residual contamination.
Never return spills to original containers for re-use.
6.3. Methods and material for
containment and cleaning up
MR-910/MR-910FD/MR-910HS SDS EU
913176 Version #: 04 Revision date: 08-May-2021 Issue date: 06-June-2017 3 / 13 Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 334
6.4. Reference to other For personal protection, see section 8 of the SDS. For waste disposal, see section 13 of the SDS. sections
SECTION 7: Handling and storage
Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. When using do not smoke. Explosion-proof general and local exhaust ventilation. Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Handling operations that can promote accumulation of static charges include but are not limited to: mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Avoid breathing mist/vapours. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices.
For additional information on equipment bonding and grounding, refer to the Canadian Electrical Code in Canada, (CSA C22.1), or the American Petroleum Institute (API) Recommended Practice 2003, "Protection Against Ignitions Arising out of Static, Lightning, and Stray Currents" or National Fire Protection Association (NFPA) 77, "Recommended Practice on Static Electricity" or National Fire Protection Association (NFPA) 70, "National Electrical Code".
7.1. Precautions for safe
handling
Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Eliminate sources of ignition. Avoid spark promoters.
Ground/bond container and equipment. These alone may be insufficient to remove static electricity. Store in a cool, dry place out of direct sunlight. Store in tightly closed container. Store in a well-ventilated place. Store away from incompatible materials (see section 10 of the SDS).
7.2. Conditions for safe
storage, including any
incompatibilities
7.3. Specific end use(s) Mold release.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
Austria. MAK List
Components Type Value
Octane (CAS 111-65-9) MAK 1400 mg/m3
300 ppm
STEL 5600 mg/m3
1200 ppm
Belgium. Exposure Limit Values
Components Type Value
Octane (CAS 111-65-9) STEL 1775 mg/m3
375 ppm
TWA 1420 mg/m3
300 ppm
Bulgaria. OELs. Regulation No 13 on protection of workers against risks of exposure to chemical agents at work Components Type Value
Octane (CAS 111-65-9) STEL 1800 mg/m3
TWA 1450 mg/m3
Czech Republic. OELs. Government Decree 361
Components Type Value
Naphtha (petroleum), Ceiling 1000 mg/m3
hydrotreated heavy (CAS
64742-48-9)
TWA 200 mg/m3
Denmark. Exposure Limit Values
Components Type Value
Naphtha (petroleum), TLV 25 ppm
hydrotreated heavy (CAS
64742-48-9)
Octane (CAS 111-65-9) TLV 935 mg/m3
MR-910/MR-910FD/MR-910HS SDS EU
913176 Version #: 04 Revision date: 08-May-2021 Issue date: 06-June-2017 4 / 13 Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 335
Denmark. Exposure Limit Values
Components Type Value
200 ppm
Estonia. OELs. Occupational Exposure Limits of Hazardous Substances. (Annex of Regulation No. 293 of 18 September 2001)
Components Type Value
Naphtha (petroleum), STEL 300 mg/m3
hydrotreated heavy (CAS
64742-48-9)
50 ppm
TWA 150 mg/m3
25 ppm
Octane (CAS 111-65-9) STEL 1400 mg/m3
300 ppm
TWA 900 mg/m3
200 ppm
Finland. Workplace Exposure Limits
Components Type Value
Naphtha (petroleum), TWA 500 mg/m3
hydrotreated heavy (CAS
64742-48-9)
Octane (CAS 111-65-9) STEL 1800 mg/m3
380 ppm
TWA 1400 mg/m3
300 ppm
France. Threshold Limit Values (VLEP) for Occupational Exposure to Chemicals in France, INRS ED 984 Components Type Value Form
Octane (CAS 111-65-9) VLE 1500 mg/m3 Vapour.
Regulatory status: Indicative limit (VL)
VME 1450 mg/m3
Regulatory status: Indicative limit (VL)
300 ppm
Regulatory status: Indicative limit (VL)
Germany. DFG MAK List (advisory OELs). Commission for the Investigation of Health Hazards of Chemical Compounds in the Work Area (DFG)
Components Type Value
Naphtha (petroleum), TWA 300 mg/m3
hydrotreated heavy (CAS
64742-48-9)
50 ppm
Octane (CAS 111-65-9) TWA 2400 mg/m3
500 ppm
Greece. OELs (Decree No. 90/1999, as amended)
Components Type Value
Octane (CAS 111-65-9) STEL 2350 mg/m3
500 ppm
TWA 2350 mg/m3
500 ppm
Hungary. OELs. Joint Decree on Chemical Safety of Workplaces Components Type Value
Octane (CAS 111-65-9) STEL 9400 mg/m3
TWA 2350 mg/m3
MR-910/MR-910FD/MR-910HS SDS EU
913176 Version #: 04 Revision date: 08-May-2021 Issue date: 06-June-2017 5 / 13 Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 336
Iceland. OELs. Regulation 154/1999 on occupational exposure limits Components Type Value
Octane (CAS 111-65-9) TWA 935 mg/m3
200 ppm
Ireland. Occupational Exposure Limits
Components Type Value
Octane (CAS 111-65-9) TWA 1450 mg/m3
300 ppm
Italy. OELs
Components Type Value
Octane (CAS 111-65-9) TWA 300 ppm
Latvia. OELs. Occupational exposure limit values of chemical substances in work environment Components Type Value
Octane (CAS 111-65-9) STEL 300 mg/m3
TWA 100 mg/m3
Lithuania. OELs. Limit Values for Chemical Substances, General Requirements (Hygiene Norm HN 23:2007) Components Type Value
Octane (CAS 111-65-9) STEL 1400 mg/m3
300 ppm
TWA 900 mg/m3
200 ppm
Norway. Administrative Norms for Contaminants in the Workplace Components Type Value
Octane (CAS 111-65-9) TLV 725 mg/m3
150 ppm
Poland. Ordinance of the Minister of Labour and Social Policy on 6 June 2014 on the maximum permissible concentrations and intensities of harmful health factors in the work environment, Journal of Laws 2014, item 817 Components Type Value
Naphtha (petroleum), STEL 900 mg/m3
hydrotreated heavy (CAS
64742-48-9)
TWA 300 mg/m3
Octane (CAS 111-65-9) STEL 1800 mg/m3
TWA 1000 mg/m3
Portugal. VLEs. Norm on occupational exposure to chemical agents (NP 1796) Components Type Value
Octane (CAS 111-65-9) TWA 300 ppm
Romania. OELs. Protection of workers from exposure to chemical agents at the workplace Components Type Value
Dibutyl ether (CAS STEL 50 mg/m3
142-96-1)
9 ppm
TWA 30 mg/m3
6 ppm
Octane (CAS 111-65-9) STEL 2000 mg/m3
429 ppm
TWA 1500 mg/m3
322 ppm
MR-910/MR-910FD/MR-910HS SDS EU
913176 Version #: 04 Revision date: 08-May-2021 Issue date: 06-June-2017 6 / 13 Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 337
Slovakia. OELs. Decree of the government of the Slovak Republic concerning protection of health in work with chemical agents
Components Type Value
Octane (CAS 111-65-9) TWA 900 mg/m3
200 ppm
Slovakia. OELs. Regulation No. 300/2007 concerning protection of health in work with chemical agents Components Type Value
Octane (CAS 111-65-9) STEL 1400 mg/m3
300 ppm
Slovenia. OELs. Regulations concerning protection of workers against risks due to exposure to chemicals while working (Official Gazette of the Republic of Slovenia)
Components Type Value
Octane (CAS 111-65-9) TWA 2400 mg/m3
500 ppm
Spain. Occupational Exposure Limits
Components Type Value
Octane (CAS 111-65-9) TWA 1420 mg/m3
300 ppm
Sweden. OELs. Work Environment Authority (AV), Occupational Exposure Limit Values (AFS 2015:7) Components Type Value
Naphtha (petroleum), STEL 300 mg/m3
hydrotreated heavy (CAS
64742-48-9)
50 ppm
TWA 150 mg/m3
25 ppm
Octane (CAS 111-65-9) STEL 1400 mg/m3
300 ppm
TWA 900 mg/m3
200 ppm
Switzerland. SUVA Grenzwerte am Arbeitsplatz
Components Type Value
Naphtha (petroleum), STEL 600 mg/m3
hydrotreated heavy (CAS
64742-48-9)
100 ppm
TWA 300 mg/m3
50 ppm
Octane (CAS 111-65-9) STEL 2800 mg/m3
600 ppm
TWA 1400 mg/m3
300 ppm
Biological limit values No biological exposure limits noted for the ingredient(s).
Recommended monitoring Follow standard monitoring procedures. procedures
Derived no effect levels Not available.
(DNELs)
Predicted no effect
concentrations (PNECs)
Not available.
8.2. Exposure controls
Explosion-proof general and local exhaust ventilation. Good general ventilation should be used.
Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. Provide easy access to water supply and eye wash facilities.
Appropriate engineering
controls
MR-910/MR-910FD/MR-910HS SDS EU
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Individual protection measures, such as personal protective equipment Use personal protective equipment as required. Personal protection equipment should be chosen according to the CEN standards and in discussion with the supplier of the personal protective equipment.
General information
Wear safety glasses with side shields (or goggles). Wear face shield if there is risk of splashes.
Eye protection should meet standard EN 166.
Eye/face protection
Skin protection
Wear suitable gloves tested to EN374. Be aware that the liquid may penetrate the gloves.
Frequent change is advisable. Rubber gloves, butyl rubber, neoprene or PVC gloves are recommended. Other suitable gloves can be recommended by the glove supplier. - Hand protection
- Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.
If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Use respiratory equipment with combination filter, type A2/P2. Respiratory protection should meet standard EN 14387. Check with respiratory protective equipment suppliers.
Respiratory protection
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.
Hygiene measures
Inform appropriate managerial or supervisory personnel of all environmental releases. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. Fume scrubbers, filters or engineering modifications to the process equipment may be necessary to reduce emissions to acceptable levels.
Environmental exposure
controls
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties Appearance
Physical state Liquid.
Form Liquid.
Colour Colourless.
Odour Mild solvent.
Odour threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boiling
range
141 °C (285,8 °F) (1013 hPa)
Flash point 31,0 °C (87,8 °F)
Evaporation rate Slower than ether.
Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limits
Explosive limit - lower ( %) 1,5 %
Explosive limit – upper
(%)
7,6 %
Vapour pressure Not available.
Vapour density Heavier than air.
Relative density 0,754 (Water=1)
Solubility(ies) Not miscible or difficult to mix with water.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Explosive properties Not explosive.
Oxidising properties Not oxidising.
9.2. Other information
VOC 99,25%; 749 g/l
MR-910/MR-910FD/MR-910HS SDS EU
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SECTION 10: Stability and reactivity
10.1. Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Risk of ignition. If stored for long periods, product may form explosive peroxides. When inhibited to prevent peroxides, product is stable under normal temperatures and pressures.
10.2. Chemical stability
10.3. Possibility of hazardous No dangerous reaction known under conditions of normal use. reactions
Contact with incompatible materials. Avoid heat, sparks, open flames and other ignition sources.
Protect against direct sunlight. Avoid temperatures exceeding the flash point.
10.4. Conditions to avoid
10.5. Incompatible materials Strong oxidising agents. Prolonged contact with air may cause formation of explosive peroxides.
10.6. Hazardous May form explosive peroxides. Hydrocarbons. decomposition products
SECTION 11: Toxicological information
General information Occupational exposure to the substance or mixture may cause adverse effects.
Information on likely routes of exposure
Inhalation May cause drowsiness and dizziness. May cause irritation to the respiratory system. Prolonged inhalation may be harmful.
Skin contact Causes skin irritation.
Eye contact Causes serious eye irritation.
Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia.
Symptoms Aspiration may cause pulmonary oedema and pneumonitis. May cause drowsiness and dizziness.
Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Skin irritation. May cause redness and pain.
11.1. Information on toxicological effects
Acute toxicity Not expected to be acutely toxic.
Components Species Test Results
Dibutyl ether (CAS 142-96-1)
Oral
Acute
LD50 Rat 3230 - 3920 mg/kg
Octane (CAS 111-65-9)
Dermal
Acute
LD50 Rat 20000 mg/kg
Inhalation
LC50 Rat 24,88 mg/l, 4 hours
Oral
LD50 Rat 5000 mg/kg
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/eye Causes serious eye irritation.
irritation
Respiratory sensitisation Due to partial or complete lack of data the classification is not possible.
Skin sensitisation Due to partial or complete lack of data the classification is not possible.
Germ cell mutagenicity Based on available data, the classification criteria are not met.
Carcinogenicity Due to partial or complete lack of data the classification is not possible.
Hungary. 26/2000 EüM Ordinance on protection against and preventing risk relating to exposure to carcinogens at work (as amended)
Naphtha (petroleum), hydrotreated heavy (CAS 64742-48-9) IARC Monographs. Overall Evaluation of Carcinogenicity
Naphtha (petroleum), hydrotreated heavy
(CAS 64742-48-9)
3 Not classifiable as to carcinogenicity to humans.
Reproductive toxicity Due to partial or complete lack of data the classification is not possible.
Specific target organ toxicity -
single exposure
May cause respiratory irritation. May cause drowsiness and dizziness.
MR-910/MR-910FD/MR-910HS SDS EU
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Specific target organ toxicity -
repeated exposure
Due to partial or complete lack of data the classification is not possible.
Aspiration hazard May be fatal if swallowed and enters airways.
Mixture versus substance No information available.
information
Other information Symptoms may be delayed.
SECTION 12: Ecological information
12.1. Toxicity Toxic to aquatic life with long lasting effects.
Components Species Test Results
Octane (CAS 111-65-9)
Aquatic
Acute
Crustacea EC50 Aquatic Invertebrates 0,3 mg/l, 48 hours Chronic
Crustacea EC50 Aquatic Invertebrates 0,64 mg/l, 48 hours 0,23 mg/l, 21 days
LOEC Aquatic Invertebrates 0,32 mg/l, 21 days
NOEC Aquatic Invertebrates 0,17 mg/l, 21 days
12.2. Persistence and No data is available on the degradability of this product. degradability
12.3. Bioaccumulative potential
Partition coefficient
n-octanol/water (log Kow)
Dibutyl ether (CAS 142-96-1) 3,21
Octane (CAS 111-65-9) 5,18
Bioconcentration factor (BCF) Not available.
12.4. Mobility in soil No data available for this product.
This mixture does not contain substances assessed to be vPvB / PBT according to Regulation (EC) No 1907/2006, Annex XIII.
12.5. Results of PBT and vPvB
assessment
12.6. Other adverse effects The product contains volatile organic compounds which have a photochemical ozone creation potential.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner.
Residual waste
Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal.
Contaminated packaging
EU waste code 04 02 14* The Waste code should be assigned in discussion between the user, the producer and the waste disposal company.
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations.
Disposal methods/information
Special precautions Dispose in accordance with all applicable regulations.
SECTION 14: Transport information
ADR
14.1. UN number UN1866
14.2. UN proper shipping Resin solution, flammable
name
Class 3
14.3. Transport hazard class(es)
Subsidiary risk -
Label(s) 3
Hazard No. (ADR) 30
Tunnel restriction code D/E
14.4. Packing group III
14.5. Environmental hazards Yes
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14.6. Special precautions Read safety instructions, SDS and emergency procedures before handling. for user
RID
14.1. UN number UN1866
14.2. UN proper shipping Resin solution, flammable
name
Class 3
14.3. Transport hazard class(es)
Subsidiary risk -
Label(s) 3
14.4. Packing group III
14.5. Environmental hazards Yes
14.6. Special precautions Read safety instructions, SDS and emergency procedures before handling. for user
ADN
14.1. UN number UN1866
14.2. UN proper shipping Resin solution, flammable
name
Class 3
14.3. Transport hazard class(es)
Subsidiary risk -
Label(s) 3
14.4. Packing group III
14.5. Environmental hazards Yes
14.6. Special precautions Read safety instructions, SDS and emergency procedures before handling. for user
IATA
14.1. UN number UN1866
14.2. UN proper shipping Resin solution, Flammable
name
Class 3
14.3. Transport hazard class(es)
Subsidiary risk -
Label(s) 3
14.4. Packing group III
14.5. Environmental hazards Yes
ERG Code 3L
14.6. Special precautions Read safety instructions, SDS and emergency procedures before handling. for user
IMDG
14.1. UN number UN1866
14.2. UN proper shipping RESIN SOLUTION, FLAMMABLE
name
Class 3
14.3. Transport hazard class(es)
Subsidiary risk -
Label(s) 3
14.4. Packing group III
Marine pollutant Yes
14.5. Environmental hazards
EmS F-E, S̲-E̲
14.6. Special precautions Read safety instructions, SDS and emergency procedures before handling. for user
14.7. Transport in bulk Not applicable.
according to Annex II of
MARPOL 73/78 and the IBC
Code
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulations
Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I and II, as amended Not listed.
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913176 Version #: 04 Revision date: 08-May-2021 Issue date: 06-June-2017 11 / 13 Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 342
Regulation (EC) No. 850/2004 On persistent organic pollutants, Annex I as amended Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 1 as amended Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 2 as amended Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 3 as amended Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex V as amended Not listed.
Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry, as amended Not listed.
Regulation (EC) No. 1907/2006, REACH Article 59(10) Candidate List as currently published by ECHA Not listed.
Authorisations
Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorisation, as amended Not listed.
Restrictions on use
Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended Octane (CAS 111-65-9)
Naphtha (petroleum), hydrotreated heavy (CAS 64742-48-9) Directive 2004/37/EC: on the protection of workers from the risks related to exposure to carcinogens and mutagens at work, as amended.
Naphtha (petroleum), hydrotreated heavy (CAS 64742-48-9) Other EU regulations
Directive 2012/18/EU on major accident hazards involving dangerous substances, as amended Dibutyl ether (CAS 142-96-1)
Octane (CAS 111-65-9)
The product is classified and labelled in accordance with Regulation (EC) 1272/2008 (CLP Regulation) as amended. This Safety Data Sheet complies with the requirements of Regulation (EC) No 1907/2006, as amended.
Other regulations
Follow national regulation for work with chemical agents in accordance with Directive 98/24/EC, as amended.
National regulations
15.2. Chemical safety No Chemical Safety Assessment has been carried out. assessment
SECTION 16: Other information
List of abbreviations
ADN: European Agreement Concerning the International Carriage of Dangerous Goods by Inland Waterways.
ADR: European Agreement Concerning the International Carriage of Dangerous Goods by Road.
IATA: International Air Transport Association.
IBC Code: International Code for the Construction and Equipment of Ships Carrying Dangerous Chemicals in Bulk.
IMDG Code: International Maritime Dangerous Goods Code.
MARPOL: International Convention for the Prevention of Pollution from Ships.
RID: Regulations concerning the International Carriage of Dangerous Goods by Rail.
STEL: Short-Term Exposure Limit.
TWA: Time Weighted Average Value.
ACGIH Documentation of the Threshold Limit Values and Biological Exposure Indices EPA: AQUIRE database
HSDB® - Hazardous Substances Data Bank
IARC Monographs. Overall Evaluation of Carcinogenicity
National Toxicology Program (NTP) Report on Carcinogens References
The classification for health and environmental hazards is derived by a combination of calculation methods and test data, if available.
Information on evaluation
method leading to the
classification of mixture
H225 Highly flammable liquid and vapour.
Full text of any H-statements
not written out in full under
Sections 2 to 15
H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
MR-910/MR-910FD/MR-910HS SDS EU
913176 Version #: 04 Revision date: 08-May-2021 Issue date: 06-June-2017 12 / 13 Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 343
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
Training information Follow training instructions when handling this material.
TR Industries cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available.
Disclaimer
MR-910/MR-910FD/MR-910HS SDS EU
913176 Version #: 04 Revision date: 08-May-2021 Issue date: 06-June-2017 13 / 13 Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 344
37WA137CLB_SDS.PDF
SAFETY DATA SHEET
1. Identification
TR-930 Mold ReleaseProduct identifier
None.Other means of identification
Mold release.Recommended use
None known.Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
TR Industries a Division of Granitize Products Inc.Company name 11022 Vulcan StreetAddress
South Gate, CA 90280-0893
United States
(562) 923-5438Telephone
CHEMTREC: (800) 424-9300Emergency telephone
CHEMTREC International: 00 1-703-527-3887
2. Hazard(s) identification
Category 3Flammable liquidsPhysical hazards
Category 2Skin corrosion/irritationHealth hazards
Category 2ASerious eye damage/eye irritation
Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure Category 3 narcotic effectsSpecific target organ toxicity, single exposure Category 1Aspiration hazard
Category 2Hazardous to the aquatic environment, acute
hazard
Environmental hazards
Category 2Hazardous to the aquatic environment,
long-term hazard
Not classified.OSHA defined hazards
Label elements
Signal word Danger
Hazard statement Flammable liquid and vapor. May be fatal if swallowed and enters airways. Causes skin irritation.
Causes serious eye irritation. May cause drowsiness or dizziness. May cause respiratory irritation.
Toxic to aquatic life with long lasting effects.
Precautionary statement
Prevention Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting// equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear protective gloves/eye protection/face protection.
Response If swallowed: Immediately call a poison center/doctor/. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin 9/18/26, 6:09 PM 37WA137CLB_SDS.pdf | Revchem Composites https://www.revchem.com/document/37wa137clb_sds-pdf/ 1/10 Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 345
irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical advice/attention. Call a poison center/doctor// if you feel unwell. In case of fire: Use water fog, alcohol resistant foam, dry chemical powder, carbon dioxide to extinguish. Collect spillage.
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Storage Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up. Not assigned.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Not assigned.
Hazard(s) not otherwise
classified (HNOC)
Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion.
Supplemental information None.
3. Composition/information on ingredients
Mixtures
64742-48-9 60-100Naphtha (petroleum),
hydrotreated heavy
CAS number %Chemical name
142-96-1 10 – 30Dibutyl Ether
90622-56-3 1 – 5Alkanes, C7-10-iso111-65-9 1 – 5Octane All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
Composition comments
4. First-aid measures
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.
Inhalation
Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention.
Skin contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Eye contact
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn’t get into the lungs.
Ingestion
Skin irritation. May cause redness and pain. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause drowsiness and dizziness. May cause respiratory irritation. Headache. Nausea, vomiting. Swallowing of the liquid, or vomiting as a result, 9/18/26, 6:09 PM 37WA137CLB_SDS.pdf | Revchem Composites https://www.revchem.com/document/37wa137clb_sds-pdf/ 2/10 Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 346
may result in aspiration into the lungs. Aspiration may cause pulmonary edema and pneumonitis.
Be aware that symptoms of lung edema (shortness of breath) may develop up to 24 hours after exposure.
Most important
symptoms/effects, acute and
delayed
Provide general supportive measures and treat symptomatically. Keep victim under observation.
Symptoms may be delayed.
Indication of immediate
medical attention and special
treatment needed
Take off all contaminated clothing immediately. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse.
General information
5. Fire-fighting measures
Water fog. Alcohol resistant foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing media
Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. To reduce potential for static discharge, use proper bonding and grounding procedures.
This liquid may accumulate static electricity when filling properly grounded containers. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. During fire, gases hazardous to health may be formed.
Specific hazards arising from
the chemical
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment and precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Cool containers exposed to flames with water until well after the fire is out.
Fire fighting
equipment/instructions
Use standard firefighting procedures and consider the hazards of other involved materials.Specific methods Flammable liquid and vapor.General fire hazards
TR-930 Mold Release SDS US
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6. Accidental release measures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate 9/18/26, 6:09 PM 37WA137CLB_SDS.pdf | Revchem Composites https://www.revchem.com/document/37wa137clb_sds-pdf/ 3/10 Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 347
closed spaces before entering them. Use appropriate containment to avoid environmental contamination. Transfer by mechanical means such as vacuum truck to a salvage tank or other suitable container for recovery or safe disposal. Local authorities should be advised if significant spillages cannot be contained.
Personal precautions,
protective equipment and
emergency procedures
Use water spray to reduce vapors or divert vapor cloud drift. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Take precautionary measures against static discharge. Use only non-sparking tools. Prevent entry into waterways, sewer, basements or confined areas.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Following product recovery, flush area with water.
Small Spills: Absorb spill with vermiculite or other inert material. Clean surface thoroughly to remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Methods and materials for
containment and cleaning up
Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Use appropriate containment to avoid environmental contamination.
Environmental precautions
7. Handling and storage
Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. When using do not smoke. Explosion-proof general and local exhaust ventilation. Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Handling operations that can promote accumulation of static charges include but are not limited to: mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Do not taste or swallow. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices.
For additional information on equipment bonding and grounding, refer to the Canadian Electrical Code in Canada, (CSA C22.1), or the American Petroleum Institute (API) Recommended Practice 2003, “Protection Against Ignitions Arising out of Static, Lightning, and Stray Currents” or National Fire Protection Association (NFPA) 77, “Recommended Practice on Static Electricity” or National Fire Protection Association (NFPA) 70, “National Electrical Code”.
Precautions for safe handling
Store locked up. Keep away from heat, sparks and open flame. Keep at temperature not exceeding 48.8 C. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Eliminate sources of ignition. Avoid spark promoters. Ground/bond container and 9/18/26, 6:09 PM 37WA137CLB_SDS.pdf | Revchem Composites https://www.revchem.com/document/37wa137clb_sds-pdf/ 4/10 Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 348
equipment. These alone may be insuf
ficient to remove static electricity. Store in a cool, dry place out of direct sunlight. Store in original tightly closed container. Store in a well-ventilated place.
Keep in an area equipped with sprinklers. Avoid contact with oxidizing agents. Store away from incompatible materials (see Section 10 of the SDS).
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type
PEL 2350 mg/m3Octane (CAS 111-65-9)
500 ppm
US. ACGIH Threshold Limit Values
ValueComponents Type
TWA 300 ppmOctane (CAS 111-65-9)
TR-930 Mold Release SDS US
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US. NIOSH: Pocket Guide to Chemical Hazards
ValueComponents Type
Ceiling 1800 mg/m3Octane (CAS 111-65-9)
385 ppm
TWA 350 mg/m3
75 ppm
No biological exposure limits noted for the ingredient(s).Biological limit values Explosion-proof general and local exhaust ventilation. Good general ventilation should be used.
Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide easy access to water supply and eye wash facilities.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles). Wear face shield if there is risk of splashes.Eye/face protection Skin protection
Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove supplier. Be aware that the liquid may penetrate the gloves. Frequent change is advisable. Nitrile gloves are recommended. Other suitable gloves can be recommended by the glove supplier.
Hand protection
Skin protection
Wear appropriate chemical resistant clothing.Other
In case of inadequate ventilation or risk of inhalation of vapors, suitable respiratory equipment with particulate filter and organic vapor cartridges can be used. If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. If engineering controls do not maintain airborne concentrations below recommended exposure limits (where 9/18/26, 6:09 PM 37WA137CLB_SDS.pdf | Revchem Composites https://www.revchem.com/document/37wa137clb_sds-pdf/ 5/10 Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 349
applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Check with respiratory protective equipment suppliers.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.
General hygiene
considerations
9. Physical and chemical properties
Appearance
Liquid.Physical state
Colorless liquid.Form
Colorless.Color
Mild. Solvent.Odor
Odor threshold Not available.
pH Not available.
Melting point/freezing pointNot determined.
Initial boiling point and boiling
range
> 233.6 F (> 112 C)
Boiling point pressure 1013 hPa
Flash point 87.8 F (31.0 C) (Tagliabue Closed Cup)
Evaporation rate Slower than ether.
Not applicable.Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit – lower
(%)
Not available.
Flammability limit – upper
(%)
Not available.
Explosive limit – lower (%)Not available.
Explosive limit – upper (%)Not available.
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Vapor pressure Not available.
Vapor density Heavier than air.
Relative density 0.754 (H2O=1)
Solubility(ies)
Solubility (water) Slightly soluble in water.
Solubility (solvents) Soluble in organic solvents.
Partition coefficient
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(n-octanol/water)
Not available.
Auto-ignition temperature > 392 F (> 200 C) (Value for solvent) Decomposition temperature Not available.
Viscosity Not available.
Other information
Not explosive.Explosive properties
Not oxidizing.Oxidizing properties
VOC 754 g/l (of coating)
10. Stability and reactivity
The product is stable and non reactive under normal conditions of use, storage and transport.Reactivity Risk of ignition.Chemical stability
Hazardous polymerization does not occur.Possibility of hazardous reactions
Avoid heat, sparks, open flames and other ignition sources. Static discharge may cause ignition at temperatures at or above flashpoint. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Spray mist may be flammable at temperatures below the flash point.
Conditions to avoid
Strong oxidizing agents.Incompatible materials
Thermal decomposition can lead to release of irritating gases and vapors. Carbon oxides.
Hydrocarbons.
Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
Inhalation May cause drowsiness and dizziness. May cause respiratory irritation. Prolonged inhalation may be harmful.
Skin contact Causes skin irritation.
Eye contac
t Causes serious eye irritation.
Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia.
Symptoms related to the
physical, chemical and
toxicological characteristics
Skin irritation. May cause redness and pain. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause drowsiness and dizziness. May cause respiratory irritation. Headache. Nausea, vomiting. Swallowing or vomiting of the liquid may result in aspiration into the lungs. Aspiration may cause pulmonary edema and pneumonitis. Be aware that symptoms of lung edema (shortness of breath) may develop up to 24 hours after exposure.
Information on toxicological effects
Acute toxicit
y Not expected to be acutely toxic.
Test ResultsComponents Species
Dibutyl Ether (CAS 142-96-1)
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Oral
Acute
LD50 Rat 3230 – 3920 mg/kg
Causes skin irritation.Skin corrosion/irritation
Causes serious eye irritation.Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitizationNot a respiratory sensitizer.
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This product is not expected to cause skin sensitization.Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity Not classifiable as to carcinogenicity to humans.
IARC Monographs. Overall Evaluation of Carcinogenicity
Naphtha (petroleum), hydrotreated heavy
(CAS 64742-48-9)
3 Not classifiable as to carcinogenicity to humans.
NTP Report on Carcinogens
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) Not listed.
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity Specific target organ toxicity –
single exposure
May cause respiratory irritation. May cause drowsiness and dizziness.
Specific target organ toxicity –
repeated exposure
Not classified.
Aspiration hazard May be fatal if swallowed and enters airways.
Chronic effects Prolonged inhalation may be harmful.
Further information Symptoms may be delayed.
12. Ecological information
Toxic to aquatic life with long lasting effects.Ecotoxicity Components Test ResultsSpecies
Octane (CAS 111-65-9)
Aquatic
LC50Crustacea 0.38 mg/l, 48 hoursDaphnia magna
No data is available on the degradability of this product.Persistence and degradability No data available on bioaccumulation.Bioaccumulative potential Partition coefficient n-octanol / water (log Kow)
Dibutyl Ether (CAS 142-96-1) 3.21
Octane (CAS 111-65-9) 5.18
9/18/26, 6:09 PM 37WA137CLB_SDS.pdf | Revchem Composites https://www.revchem.com/document/37wa137clb_sds-pdf/ 8/10 Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 352
This product is slightly water soluble and may disperse in soil.Mobility in soil Other adverse effects The product contains volatile organic compounds which have a photochemical ozone creation potential.
13. Disposal considerations
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulations D001: Waste Flammable material with a flash point <140 F The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues.
This material and its container must be disposed of in a safe manner (see: Disposal instructions). Waste from residues / unused products Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Contaminated packaging 14. Transport information DOT UN1866UN number Resin SolutionUN proper shipping name 3Class Transport hazard class(es) TR-930 Mold Release SDS US 3628 Version #: 04 Revision date: 24-November-2020 Issue date: 10-April-2014 6 / 9 - Subsidiary risk 3Label(s) IIIPacking group YesMarine pollutant Environmental hazards Read safety instructions, SDS and emergency procedures before handling.Special precautions for user B1, B52, IB3, T2, TP1Special provisions 150Packaging exceptions 173Packaging non bulk 242Packaging bulk IATA UN1866UN number Resin Solution, FlammableUN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk 3Label(s) IIIPacking group YesEnvironmental hazards 3LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user IMDG UN1866UN number Resin Solution, FlammableUN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk 3Label(s) IIIPacking group YesMarine pollutant Environmental hazards F-E, S-EEmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Not applicable.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Dibutyl Ether (CAS 142-96-1) Listed. Octane (CAS 111-65-9) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) Not listed. Toxic Substances Control Act (TSCA) SARA 302 Extremely hazardous substance Superfund Amendments and Reauthorization Act of 1986 (SARA) Not listed. YesSARA 311/312 Hazardous chemical TR-930 Mold Release SDS US 3628 Version #:
04 Revision date: 24-November-2020 Issue date: 10-April-2014 7 / 9 Flammable (gases, aerosols, liquids, or solids) Skin corrosion or irritation Serious eye damage or eye irritation Specific target organ toxicity (single or repeated exposure) Aspiration hazard Hazard not otherwise classified (HNOC) Classified hazard categories SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated.Safe Drinking Water Act (SDWA) US state regulations US. Massachusetts RTK - Substance List Dibutyl Ether (CAS 142-96-1) Octane (CAS 111-65-9) US. New Jersey Worker and Community Right-to-Know Act Dibutyl Ether (CAS 142-96-1) Octane (CAS 111-65-9) US. Pennsylvania Worker and Community Right-to-Know Law Dibutyl Ether (CAS 142-96-1) Naphtha (petroleum), hydrotreated heavy (CAS 64742-48-9) Octane (CAS 111-65-9) US. Rhode Island RTK Dibutyl Ether (CAS 142- 96-1) Octane (CAS 111-65-9) California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 2016 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. For more information go to www.P65Warnings.ca.gov. US.
California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a)) Naphtha (petroleum), hydrotreated heavy (CAS 64742-48-9) Octane (CAS 111-65-9) International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australian Inventory of Chemical Substances (AICS) YesAustralia Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) NoCanada Inventory of Existing Chemical Substances in China (IECSC) YesChina European Inventory of Existing Commercial Chemical Substances (EINECS) YesEurope European List of Notified Chemical Substances (ELINCS) NoEurope Inventory of Existing and New Chemical Substances (ENCS) NoJapan Existing Chemicals List (ECL) YesKorea New Zealand Inventory YesNew Zealand Philippine Inventory of Chemicals and Chemical Substances (PICCS) YesPhilippines Taiwan Chemical Substance Inventory (TCSI) YesTaiwan *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico TR-930 Mold Release SDS US 9/18/26, 6:09 PM 37WA137CLB_SDS.pdf | Revchem Composites https://www.revchem.com/document/37wa137clb_sds-pdf/ 9/10 Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 353
3628 Version #: 04 Revision date: 24-November-2020 Issue date: 10-April-2014 8 / 9 16. Other information, including date of preparation or last revision 10- April-2014Issue date 24-November-2020Revision date Version # 04 NFPA ratings 02 3 TR Industries cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. Disclaimer TR-930 Mold Release SDS US 3628 Version #: 04 Revision date: 24-November-2020 Issue date: 10-April-2014 9 / 9 9/18/26, 6:09 PM 37WA137CLB_SDS.pdf | Revchem Composites https://www.revchem.com/document/37wa137clb_sds-pdf/ 10/10 Docusign Envelope ID: 18624A2E-3496-860F-815E-02847CC36CC5 Docusign Envelope ID: 0770A90D-3A7E-80AE-8206-7662CFD9C9A0 354