Cities Index.
Agenda packet

Ontario City Council
April 16, 2024

Document
Agenda packet
Meeting
April 16, 2024
Body
Ontario City Council
Pages
100
Original file
112.8 MB
Text extracted from the city's file for reading and search. Open the original on d3n9y02raazwpg.cloudfront.net. That file is the official record.

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QC Sample Results
Client: Roux Associates, Inc. Job ID: 570-92691-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: 7471A - Mercury (CVAA)
Lab Sample ID: MB 570-227685/1-A Client Sample ID: Method Blank Matrix: Solid Prep Type: Total/NA
Analysis Batch: 227814 Prep Batch: 227685
RL MDL
Mercury ND 0.0794 mg/Kg 04/19/22 12:29 04/19/22 18:12 1 MB MB
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac Lab Sample ID: LCS 570-227685/2-A Client Sample ID: Lab Control Sample Matrix: Solid Prep Type: Total/NA
Analysis Batch: 227814 Prep Batch: 227685
Mercury 0.794 0.8214 mg/Kg 103 85 - 121
Analyte

LCS LCS
Result Qualifier Unit D %Rec
Spike
Added
%Rec
Limits
Lab Sample ID: LCSD 570-227685/3-A Client Sample ID: Lab Control Sample Dup Matrix: Solid Prep Type: Total/NA
Analysis Batch: 227814 Prep Batch: 227685
Mercury 0.847 0.8909 mg/Kg 105 85 - 121 8 10
Analyte

LCSD LCSD
Result Qualifier Unit D %Rec
Spike
Added
%Rec
Limits RPD Limit
RPD
Lab Sample ID: 570-92884-A-1-D MS Client Sample ID: Matrix Spike Matrix: Solid Prep Type: Total/NA
Analysis Batch: 227814 Prep Batch: 227685
Mercury ND 0.820 0.8433 mg/Kg 103 71 - 137
Analyte
MS MS
Result Qualifier Unit D %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits
Lab Sample ID: 570-92884-A-1-E MSD Client Sample ID: Matrix Spike Duplicate Matrix: Solid Prep Type: Total/NA
Analysis Batch: 227814 Prep Batch: 227685
Mercury ND 0.862 0.8893 mg/Kg 103 71 - 137 5 14
Analyte

MSD MSD
Result Qualifier Unit D %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits RPD Limit
RPD
Eurofins Calscience

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QC Association Summary
Client: Roux Associates, Inc. Job ID: 570-92691-1
Project/Site: First Indiustrial-Ontario / 3661.0016L

GC/MS VOA
Prep Batch: 227618
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 570-92691-1 IDW-Soil Total/NA Solid 5030C
MB 570-227618/3-A Method Blank Total/NA Solid 5030C
LCS 570-227618/1-A Lab Control Sample Total/NA Solid 5030C LCSD 570-227618/2-A Lab Control Sample Dup Total/NA Solid 5030C 570-92568-A-1-I MS Matrix Spike Total/NA Solid 5030C
570-92568-A-1-J MSD Matrix Spike Duplicate Total/NA Solid 5030C Analysis Batch: 227644
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 570-92691-1 IDW-Soil Total/NA Solid 8260B 227618
MB 570-227618/3-A Method Blank Total/NA Solid 8260B 227618 LCS 570-227618/1-A Lab Control Sample Total/NA Solid 8260B 227618 LCSD 570-227618/2-A Lab Control Sample Dup Total/NA Solid 8260B 227618 570-92568-A-1-I MS Matrix Spike Total/NA Solid 8260B 227618 570-92568-A-1-J MSD Matrix Spike Duplicate Total/NA Solid 8260B 227618 GC Semi VOA
Prep Batch: 227911
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 570-92691-1 IDW-Soil Total/NA Solid 3550C
MB 570-227911/1-A Method Blank Total/NA Solid 3550C
LCS 570-227911/2-A Lab Control Sample Total/NA Solid 3550C LCSD 570-227911/3-A Lab Control Sample Dup Total/NA Solid 3550C 570-92751-A-3-B MS Matrix Spike Total/NA Solid 3550C
570-92751-A-3-C MSD Matrix Spike Duplicate Total/NA Solid 3550C Analysis Batch: 228100
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 570-92691-1 IDW-Soil Total/NA Solid 8015B 227911
MB 570-227911/1-A Method Blank Total/NA Solid 8015B 227911 LCS 570-227911/2-A Lab Control Sample Total/NA Solid 8015B 227911 LCSD 570-227911/3-A Lab Control Sample Dup Total/NA Solid 8015B 227911 570-92751-A-3-B MS Matrix Spike Total/NA Solid 8015B 227911 570-92751-A-3-C MSD Matrix Spike Duplicate Total/NA Solid 8015B 227911 Metals
Prep Batch: 227685
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 570-92691-1 IDW-Soil Total/NA Solid 7471A
MB 570-227685/1-A Method Blank Total/NA Solid 7471A
LCS 570-227685/2-A Lab Control Sample Total/NA Solid 7471A LCSD 570-227685/3-A Lab Control Sample Dup Total/NA Solid 7471A 570-92884-A-1-D MS Matrix Spike Total/NA Solid 7471A
570-92884-A-1-E MSD Matrix Spike Duplicate Total/NA Solid 7471A Analysis Batch: 227814
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 570-92691-1 IDW-Soil Total/NA Solid 7471A 227685
MB 570-227685/1-A Method Blank Total/NA Solid 7471A 227685 LCS 570-227685/2-A Lab Control Sample Total/NA Solid 7471A 227685 Eurofins Calscience

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QC Association Summary
Client: Roux Associates, Inc. Job ID: 570-92691-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Metals (Continued)
Analysis Batch: 227814 (Continued)
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch LCSD 570-227685/3-A Lab Control Sample Dup Total/NA Solid 7471A 227685 570-92884-A-1-D MS Matrix Spike Total/NA Solid 7471A 227685 570-92884-A-1-E MSD Matrix Spike Duplicate Total/NA Solid 7471A 227685 Prep Batch: 671140
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 570-92691-1 IDW-Soil Total/NA Solid 3050B
MB 440-671140/1-A ^5 Method Blank Total/NA Solid 3050B
LCS 440-671140/2-A ^5 Lab Control Sample Total/NA Solid 3050B 570-92543-A-1-C MS ^5 Matrix Spike Total/NA Solid 3050B 570-92543-A-1-D MSD ^5 Matrix Spike Duplicate Total/NA Solid 3050B Analysis Batch: 671361
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 570-92691-1 IDW-Soil Total/NA Solid 6010B 671140
MB 440-671140/1-A ^5 Method Blank Total/NA Solid 6010B 671140 LCS 440-671140/2-A ^5 Lab Control Sample Total/NA Solid 6010B 671140 570-92543-A-1-C MS ^5 Matrix Spike Total/NA Solid 6010B 671140 570-92543-A-1-D MSD ^5 Matrix Spike Duplicate Total/NA Solid 6010B 671140 Eurofins Calscience

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Lab Chronicle
Client: Roux Associates, Inc. Job ID: 570-92691-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Client Sample ID: IDW-Soil Lab Sample ID: 570-92691-1
Date Collected: 04/14/22 15:01 Matrix: Solid
Date Received: 04/14/22 17:04
Prep 5030C 227618 04/19/22 09:43 UJHB ECL 4
Type
Batch
Method
Batch
Prep Type Run Analyst Lab
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
Factor Number
Dil
Total/NA 5.09 g 5 mL
Total/NA Analysis 8260B 1 5 mL 5 mL 227644 04/19/22 19:45 UJHB ECL 4 Instrument ID: GCMSLL
Total/NA Prep 3550C 10.12 g 10 mL 227911 04/20/22 08:05 KG5J ECL 4 Total/NA Analysis 8015B 1 228100 04/21/22 03:23 A1W ECL 4 Instrument ID: GC69A
Total/NA Prep 3050B 2.04 g 50 mL 671140 04/16/22 14:42 FIQ7 IRV 2 Total/NA Analysis 6010B 5 671361 04/20/22 18:56 P1R IRV 2 Instrument ID: ICP8
Total/NA Prep 7471A 0.61 g 100 mL 227685 04/19/22 12:29 VWJ7 ECL 4 Total/NA Analysis 7471A 1 227814 04/19/22 18:49 VWJ7 ECL 4 Instrument ID: HG8
Laboratory References:

ECL 4 = Eurofins Calscience Tustin, 2841 Dow Avenue, Tustin, CA 92780, TEL (714)895-5494 IRV 2 = Eurofins Calscience Tustin, 2841 Dow Avenue, Tustin, CA 92780, TEL (714)895-5494 Eurofins Calscience

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Accreditation/Certification Summary
Client: Roux Associates, Inc. Job ID: 570-92691-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Laboratory: Eurofins Calscience
The accreditations/certifications listed below are applicable to this report.

Authority Program Identification Number Expiration Date California State 2944 09-30-22
Oregon NELAP CA300001 01-31-23
Laboratory: Eurofins Calscience
All accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report.

Authority Program Identification Number Expiration Date California Los Angeles County Sanitation
Districts
10256 06-30-22
California State 2706 06-30-22
Kansas NELAP E-10420 07-31-22
Nevada State CA015312022-1 07-31-22
Washington State C900 09-03-22
Eurofins Calscience

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Method Summary
Client: Roux Associates, Inc. Job ID: 570-92691-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method Method Description Protocol Laboratory
8260B Volatile Organic Compounds (GC/MS) SW846 ECL 4
8015B Diesel Range Organics (DRO) (GC) SW846 ECL 4
6010B Metals (ICP) SW846 IRV 2
7471A Mercury (CVAA) SW846 ECL 4
3050B Preparation, Metals SW846 IRV 2
3550C Ultrasonic Extraction SW846 ECL 4
5030C Purge and Trap SW846 ECL 4
7471A Preparation, Mercury SW846 ECL 4
Protocol References:

SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.

Laboratory References:

ECL 4 = Eurofins Calscience Tustin, 2841 Dow Avenue, Tustin, CA 92780, TEL (714)895-5494 IRV 2 = Eurofins Calscience Tustin, 2841 Dow Avenue, Tustin, CA 92780, TEL (714)895-5494 Eurofins Calscience

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Sample Summary
Client: Roux Associates, Inc. Job ID: 570-92691-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Lab Sample ID Client Sample ID Matrix Collected Received 570-92691-1 IDW-Soil Solid 04/14/22 15:01 04/14/22 17:04

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Login Sample Receipt Checklist
Client: Roux Associates, Inc. Job Number: 570-92691-1
Login Number: 92691
Question Answer Comment
Creator: Skinner, Alma D
List Source: Eurofins Calscience
List Number: 1
Radioactivity wasn't checked or is </= background as measured by a survey True meter.

The cooler's custody seal, if present, is intact. N/A Not present Sample custody seals, if present, are intact. N/A Not Present The cooler or samples do not appear to have been compromised or True tampered with.

Samples were received on ice. True
Cooler Temperature is acceptable. True
Cooler Temperature is recorded. True
COC is present. True
COC is filled out in ink and legible. True
COC is filled out with all pertinent information. True
Is the Field Sampler's name present on COC? True
There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time (excluding tests with immediate True HTs)
Sample containers have legible labels. True
Containers are not broken or leaking. True
Sample collection date/times are provided. True
Appropriate sample containers are used. True
Sample bottles are completely filled. True
Sample Preservation Verified. N/A
There is sufficient vol. for all requested analyses, incl. any requested True MS/MSDs
Containers requiring zero headspace have no headspace or bubble is True <6mm (1/4").

Multiphasic samples are not present. True
Samples do not require splitting or compositing. True
Residual Chlorine Checked. N/A
Eurofins Calscience Page 28 of 28 4/25/2022
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ANALYTICAL REPORT
Eurofins Calscience
2841 Dow Avenue, Suite 100
Tustin, CA 92780
Tel: (714)895-5494
Laboratory Job ID: 570-93118-1
Client Project/Site: First Indiustrial-Ontario / 3661.0016L For:

Roux Associates, Inc.
5150 E Pacific Coast Highway
Suite 450
Long Beach, California 90804
Attn: David Smith
Authorized for release by:
4/26/2022 11:50:52 AM
Virendra Patel, Project Manager I
(714)895-5494
[email protected]
The test results in this report meet all 2003 NELAC, 2009 TNI, and 2016 TNI requirements for accredited parameters, exceptions are noted in this report. This report may not be reproduced except in full, and with written approval from the laboratory. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page.

This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature.

Results relate only to the items tested and the sample(s) as received by the laboratory. 1 2
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Table of Contents
Client: Roux Associates, Inc.

Project/Site: First Indiustrial-Ontario / 3661.0016L
Laboratory Job ID: 570-93118-1

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Eurofins Calscience
4/26/2022
Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 Definitions/Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48 QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49 QC Association Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 68 Lab Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69 Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 72 Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74 Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75 Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76 Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79 Air Canister Dilution . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80 1 2
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Definitions/Glossary
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Qualifiers
Air - GC/MS VOA
Qualifier Description
*- LCS and/or LCSD is outside acceptance limits, low biased.

Qualifier
me LCS Recovery is within Marginal Exdeedance (ME) control limit range (± 4 SD from the mean).

Glossary
These commonly used abbreviations may or may not be present in this report. ¤ Listed under the "D" column to designate that the result is reported on a dry weight basis Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference) Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level"
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown) NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Eurofins Calscience

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Case Narrative
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Job ID: 570-93118-1
Laboratory: Eurofins Calscience
Narrative
Job Narrative
570-93118-1
Comments
No additional comments.

Receipt
The samples were received on 4/19/2022 7:20 PM. Unless otherwise noted below, the samples arrived in good condition, and where required, properly preserved and on ice. The temperature of the cooler at receipt was 22.0º C.

Air Toxics
Method TO-15: The following analyte(s) recovered outside control limits for the LCSD associated with analytical batch 570-228550:
<AffectedAnalytes>. This is not indicative of a systematic control problem because these were random marginal exceedances. Qualified results have been reported.

No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

Eurofins Calscience Page 4 of 81 4/26/2022
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Detection Summary
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Client Sample ID: SV-1-10 Lab Sample ID: 570-93118-1
Acetone
RL

2.0 ppb v/v
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type

7.6 1 TO-15 Total/NA
Toluene 0.76 0.50 ppb v/v 1 TO-15 Total/NA
Trichlorofluoromethane 3.2 1.0 ppb v/v 1 TO-15 Total/NA Acetone
RL

4.8 ug/m3
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type 18 1 TO-15 Total/NA
Toluene 2.9 1.9 ug/m3 1 TO-15 Total/NA
Trichlorofluoromethane 18 5.6 ug/m3 1 TO-15 Total/NA
Client Sample ID: SV-1-20 Lab Sample ID: 570-93118-2
Acetone
RL

2.0 ppb v/v
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type

6.4 1 TO-15 Total/NA
Trichlorofluoromethane 4.0 1.0 ppb v/v 1 TO-15 Total/NA Acetone
RL

4.8 ug/m3
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type 15 1 TO-15 Total/NA
Trichlorofluoromethane 22 5.6 ug/m3 1 TO-15 Total/NA
Client Sample ID: SV-2-5 Lab Sample ID: 570-93118-3
Acetone
RL

2.0 ppb v/v
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type

8.7 1 TO-15 Total/NA
Toluene 0.71 0.50 ppb v/v 1 TO-15 Total/NA
Trichlorofluoromethane 3.6 1.0 ppb v/v 1 TO-15 Total/NA Acetone
RL

4.8 ug/m3
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type 21 1 TO-15 Total/NA
Toluene 2.7 1.9 ug/m3 1 TO-15 Total/NA
Trichlorofluoromethane 20 5.6 ug/m3 1 TO-15 Total/NA
Client Sample ID: SV-2-5-D Lab Sample ID: 570-93118-4
Acetone
RL

2.0 ppb v/v
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type

6.8 1 TO-15 Total/NA
Toluene 0.66 0.50 ppb v/v 1 TO-15 Total/NA
Acetone
RL

4.8 ug/m3
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type 16 1 TO-15 Total/NA
Toluene 2.5 1.9 ug/m3 1 TO-15 Total/NA
Client Sample ID: SV-2-15 Lab Sample ID: 570-93118-5
2-Butanone
RL

1.5 ppb v/v
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type

1.6 1 TO-15 Total/NA
Acetone 9.9 2.0 ppb v/v 1 TO-15 Total/NA
Tetrachloroethene 0.56 0.50 ppb v/v 1 TO-15 Total/NA
Toluene 1.0 0.50 ppb v/v 1 TO-15 Total/NA
Trichlorofluoromethane 20 1.0 ppb v/v 1 TO-15 Total/NA
2-Butanone
RL

4.4 ug/m3
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type

4.7 1 TO-15 Total/NA
Acetone 24 4.8 ug/m3 1 TO-15 Total/NA
Tetrachloroethene 3.8 3.4 ug/m3 1 TO-15 Total/NA
Toluene 3.8 1.9 ug/m3 1 TO-15 Total/NA
Trichlorofluoromethane 110 5.6 ug/m3 1 TO-15 Total/NA
Eurofins Calscience
This Detection Summary does not include radiochemical test results.

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Detection Summary
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Client Sample ID: SV-4-5 Lab Sample ID: 570-93118-6
2-Butanone
RL

1.5 ppb v/v
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type

5.9 1 TO-15 Total/NA
Acetone 26 2.0 ppb v/v 1 TO-15 Total/NA
Chloroethane 0.55 0.50 ppb v/v 1 TO-15 Total/NA
Chloromethane 1.2 0.50 ppb v/v 1 TO-15 Total/NA
Toluene 0.62 0.50 ppb v/v 1 TO-15 Total/NA
Trichlorofluoromethane 1.3 1.0 ppb v/v 1 TO-15 Total/NA 2-Butanone
RL

4.4 ug/m3
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type 17 1 TO-15 Total/NA
Acetone 62 4.8 ug/m3 1 TO-15 Total/NA
Chloroethane 1.4 1.3 ug/m3 1 TO-15 Total/NA
Chloromethane 2.6 1.0 ug/m3 1 TO-15 Total/NA
Toluene 2.3 1.9 ug/m3 1 TO-15 Total/NA
Trichlorofluoromethane 7.0 5.6 ug/m3 1 TO-15 Total/NA
Client Sample ID: SV-4-15 Lab Sample ID: 570-93118-7
2-Butanone
RL

1.5 ppb v/v
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type

1.6 1 TO-15 Total/NA
Acetone 11 2.0 ppb v/v 1 TO-15 Total/NA
Toluene 1.1 0.50 ppb v/v 1 TO-15 Total/NA
Trichlorofluoromethane 1.9 1.0 ppb v/v 1 TO-15 Total/NA 2-Butanone
RL

4.4 ug/m3
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type

4.9 1 TO-15 Total/NA
Acetone 27 4.8 ug/m3 1 TO-15 Total/NA
Toluene 4.2 1.9 ug/m3 1 TO-15 Total/NA
Trichlorofluoromethane 11 5.6 ug/m3 1 TO-15 Total/NA
Client Sample ID: SV-6-5 Lab Sample ID: 570-93118-8
Acetone
RL

2.0 ppb v/v
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type

2.5 1 TO-15 Total/NA
Acetone
RL

4.8 ug/m3
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type

6.0 1 TO-15 Total/NA
Client Sample ID: SV-6-15 Lab Sample ID: 570-93118-9
2-Butanone
RL

1.5 ppb v/v
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type

5.7 1 TO-15 Total/NA
Acetone 43 2.0 ppb v/v 1 TO-15 Total/NA
Isopropanol 5.7 5.0 ppb v/v 1 TO-15 Total/NA
o-Xylene 0.65 0.50 ppb v/v 1 TO-15 Total/NA
Tetrachloroethene 0.91 0.50 ppb v/v 1 TO-15 Total/NA
Toluene 1.7 0.50 ppb v/v 1 TO-15 Total/NA
Trichlorofluoromethane 8.7 1.0 ppb v/v 1 TO-15 Total/NA 2-Butanone
RL

4.4 ug/m3
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type 17 1 TO-15 Total/NA
Acetone 100 4.8 ug/m3 1 TO-15 Total/NA
Isopropanol 14 12 ug/m3 1 TO-15 Total/NA
o-Xylene 2.8 2.2 ug/m3 1 TO-15 Total/NA
Tetrachloroethene 6.1 3.4 ug/m3 1 TO-15 Total/NA
Toluene 6.3 1.9 ug/m3 1 TO-15 Total/NA
Eurofins Calscience
This Detection Summary does not include radiochemical test results.

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Detection Summary
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Client Sample ID: SV-6-15 (Continued) Lab Sample ID: 570-93118-9 Trichlorofluoromethane
RL

5.6 ug/m3
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type 49 1 TO-15 Total/NA
Client Sample ID: SV-9-5 Lab Sample ID: 570-93118-10
2-Butanone
RL

1.5 ppb v/v
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type

3.0 1 TO-15 Total/NA
Acetone 14 2.0 ppb v/v 1 TO-15 Total/NA
Tetrachloroethene 13 0.50 ppb v/v 1 TO-15 Total/NA
Toluene 0.54 0.50 ppb v/v 1 TO-15 Total/NA
Trichlorofluoromethane 2.3 1.0 ppb v/v 1 TO-15 Total/NA 2-Butanone
RL

4.4 ug/m3
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type

8.7 1 TO-15 Total/NA
Acetone 34 4.8 ug/m3 1 TO-15 Total/NA
Tetrachloroethene 86 3.4 ug/m3 1 TO-15 Total/NA
Toluene 2.0 1.9 ug/m3 1 TO-15 Total/NA
Trichlorofluoromethane 13 5.6 ug/m3 1 TO-15 Total/NA
Client Sample ID: SV-9-15 Lab Sample ID: 570-93118-11
2-Butanone
RL

1.5 ppb v/v
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type

5.3 1 TO-15 Total/NA
Acetone 24 2.0 ppb v/v 1 TO-15 Total/NA
Tetrachloroethene 0.83 0.50 ppb v/v 1 TO-15 Total/NA
Trichlorofluoromethane 3.2 1.0 ppb v/v 1 TO-15 Total/NA 2-Butanone
RL

4.4 ug/m3
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type 16 1 TO-15 Total/NA
Acetone 57 4.8 ug/m3 1 TO-15 Total/NA
Tetrachloroethene 5.7 3.4 ug/m3 1 TO-15 Total/NA
Trichlorofluoromethane 18 5.6 ug/m3 1 TO-15 Total/NA
Client Sample ID: SV-7-5 Lab Sample ID: 570-93118-12
1,3,5-Trimethylbenzene
RL

0.50 ppb v/v
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type

0.51 1 TO-15 Total/NA
2-Butanone 4.1 1.5 ppb v/v 1 TO-15 Total/NA
Acetone 23 2.0 ppb v/v 1 TO-15 Total/NA
Ethylbenzene 0.68 0.50 ppb v/v 1 TO-15 Total/NA
o-Xylene 0.71 0.50 ppb v/v 1 TO-15 Total/NA
m,p-Xylene 2.6 2.0 ppb v/v 1 TO-15 Total/NA
Tetrachloroethene 31 0.50 ppb v/v 1 TO-15 Total/NA
Toluene 1.2 0.50 ppb v/v 1 TO-15 Total/NA
Trichlorofluoromethane 13 1.0 ppb v/v 1 TO-15 Total/NA
1,3,5-Trimethylbenzene
RL

2.5 ug/m3
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type

2.5 1 TO-15 Total/NA
2-Butanone 12 4.4 ug/m3 1 TO-15 Total/NA
Acetone 54 4.8 ug/m3 1 TO-15 Total/NA
Ethylbenzene 3.0 2.2 ug/m3 1 TO-15 Total/NA
o-Xylene 3.1 2.2 ug/m3 1 TO-15 Total/NA
m,p-Xylene 11 8.7 ug/m3 1 TO-15 Total/NA
Tetrachloroethene 210 3.4 ug/m3 1 TO-15 Total/NA
Toluene 4.4 1.9 ug/m3 1 TO-15 Total/NA
Trichlorofluoromethane 71 5.6 ug/m3 1 TO-15 Total/NA
Eurofins Calscience
This Detection Summary does not include radiochemical test results.

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1751
Detection Summary
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Client Sample ID: SV-7-15 Lab Sample ID: 570-93118-13
2-Butanone
RL

1.5 ppb v/v
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type

5.4 1 TO-15 Total/NA
Acetone 17 2.0 ppb v/v 1 TO-15 Total/NA
Tetrachloroethene 1.4 0.50 ppb v/v 1 TO-15 Total/NA
Trichlorofluoromethane 14 1.0 ppb v/v 1 TO-15 Total/NA
2-Butanone
RL

4.4 ug/m3
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type 16 1 TO-15 Total/NA
Acetone 39 4.8 ug/m3 1 TO-15 Total/NA
Tetrachloroethene 9.8 3.4 ug/m3 1 TO-15 Total/NA
Trichlorofluoromethane 80 5.6 ug/m3 1 TO-15 Total/NA
Client Sample ID: SV-8-5 Lab Sample ID: 570-93118-14
2-Butanone
RL

1.5 ppb v/v
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type

1.5 1 TO-15 Total/NA
Acetone 7.3 2.0 ppb v/v 1 TO-15 Total/NA
Tetrachloroethene 0.81 0.50 ppb v/v 1 TO-15 Total/NA
Trichlorofluoromethane 4.1 1.0 ppb v/v 1 TO-15 Total/NA 2-Butanone
RL

4.4 ug/m3
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type

4.3 1 TO-15 Total/NA
Acetone 17 4.8 ug/m3 1 TO-15 Total/NA
Tetrachloroethene 5.5 3.4 ug/m3 1 TO-15 Total/NA
Trichlorofluoromethane 23 5.6 ug/m3 1 TO-15 Total/NA
Client Sample ID: SV-8-15 Lab Sample ID: 570-93118-15
2-Butanone
RL

1.5 ppb v/v
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type

1.8 1 TO-15 Total/NA
Acetone 9.8 2.0 ppb v/v 1 TO-15 Total/NA
Trichlorofluoromethane 4.3 1.0 ppb v/v 1 TO-15 Total/NA 2-Butanone
RL

4.4 ug/m3
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type

5.2 1 TO-15 Total/NA
Acetone 23 4.8 ug/m3 1 TO-15 Total/NA
Trichlorofluoromethane 24 5.6 ug/m3 1 TO-15 Total/NA
Eurofins Calscience
This Detection Summary does not include radiochemical test results.

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1752
Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air Client Sample ID: SV-1-10 Lab Sample ID: 570-93118-1
Date Collected: 04/18/22 08:21 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
1,1,1-Trichloroethane ND 0.50 ppb v/v 04/22/22 04:21 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 1.0 ppb v/v 04/22/22 04:21 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 1.5 ppb v/v 04/22/22 04:21 1 1,1,2-Trichloroethane ND 0.50 ppb v/v 04/22/22 04:21 1
1,1-Dichloroethane ND 0.50 ppb v/v 04/22/22 04:21 1
1,1-Dichloroethene ND 0.50 ppb v/v 04/22/22 04:21 1
1,1-Difluoroethane ND 2.0 ppb v/v 04/22/22 04:21 1
1,2,4-Trichlorobenzene ND 2.0 ppb v/v 04/22/22 04:21 1
1,2,4-Trimethylbenzene ND 1.5 ppb v/v 04/22/22 04:21 1
1,2-Dibromo-3-Chloropropane ND 1.5 ppb v/v 04/22/22 04:21 1 1,2-Dibromoethane ND 0.50 ppb v/v 04/22/22 04:21 1
1,2-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 04:21 1
1,2-Dichloroethane ND 0.50 ppb v/v 04/22/22 04:21 1
1,2-Dichloropropane ND 0.50 ppb v/v 04/22/22 04:21 1
1,3,5-Trimethylbenzene ND 0.50 ppb v/v 04/22/22 04:21 1 1,3-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 04:21 1
1,4-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 04:21 1
2-Butanone ND 1.5 ppb v/v 04/22/22 04:21 1
2-Hexanone ND 1.5 ppb v/v 04/22/22 04:21 1
4-Ethyltoluene ND 0.50 ppb v/v 04/22/22 04:21 1
4-Methyl-2-pentanone ND 1.5 ppb v/v 04/22/22 04:21 1
Acetone 7.6 2.0 ppb v/v 04/22/22 04:21 1
Benzene ND 0.50 ppb v/v 04/22/22 04:21 1
Benzyl chloride ND 1.5 ppb v/v 04/22/22 04:21 1
Bromodichloromethane ND 0.50 ppb v/v 04/22/22 04:21 1
Bromoform ND 0.50 ppb v/v 04/22/22 04:21 1
Bromomethane ND 0.50 ppb v/v 04/22/22 04:21 1
cis-1,2-Dichloroethene ND 0.50 ppb v/v 04/22/22 04:21 1 cis-1,3-Dichloropropene ND 0.50 ppb v/v 04/22/22 04:21 1 Carbon disulfide ND 2.0 ppb v/v 04/22/22 04:21 1
Carbon tetrachloride ND 0.50 ppb v/v 04/22/22 04:21 1
Chlorobenzene ND 0.50 ppb v/v 04/22/22 04:21 1
Chloroethane ND 0.50 ppb v/v 04/22/22 04:21 1
Chloroform ND 0.50 ppb v/v 04/22/22 04:21 1
Chloromethane ND 0.50 ppb v/v 04/22/22 04:21 1
Dibromochloromethane ND 0.50 ppb v/v 04/22/22 04:21 1
Dichlorodifluoromethane ND 0.50 ppb v/v 04/22/22 04:21 1 Dichlorotetrafluoroethane ND 2.0 ppb v/v 04/22/22 04:21 1 Ethylbenzene ND 0.50 ppb v/v 04/22/22 04:21 1
Hexachloro-1,3-butadiene ND 1.5 ppb v/v 04/22/22 04:21 1 Isopropanol ND 5.0 ppb v/v 04/22/22 04:21 1
Methylene Chloride ND 5.0 ppb v/v 04/22/22 04:21 1
Methyl-t-Butyl Ether (MTBE) ND 2.0 ppb v/v 04/22/22 04:21 1 n-Butylbenzene ND 1.5 ppb v/v 04/22/22 04:21 1
o-Xylene ND 0.50 ppb v/v 04/22/22 04:21 1
m,p-Xylene ND 2.0 ppb v/v 04/22/22 04:21 1
sec-Butylbenzene ND 1.5 ppb v/v 04/22/22 04:21 1
Styrene ND 1.5 ppb v/v 04/22/22 04:21 1
Eurofins Calscience

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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-1-10 Lab Sample ID: 570-93118-1
Date Collected: 04/18/22 08:21 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
trans-1,2-Dichloroethene ND 0.50 ppb v/v 04/22/22 04:21 1 Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac trans-1,3-Dichloropropene ND 1.0 ppb v/v 04/22/22 04:21 1 tert-Butylbenzene ND 1.5 ppb v/v 04/22/22 04:21 1
Tetrachloroethene ND 0.50 ppb v/v 04/22/22 04:21 1
Toluene 0.76 0.50 ppb v/v 04/22/22 04:21 1
Trichloroethene ND 0.50 ppb v/v 04/22/22 04:21 1
Trichlorofluoromethane 3.2 1.0 ppb v/v 04/22/22 04:21 1 Vinyl acetate ND 2.0 ppb v/v 04/22/22 04:21 1
Vinyl chloride ND 0.50 ppb v/v 04/22/22 04:21 1
RL MDL
1,1,1-Trichloroethane ND 2.7 ug/m3 04/22/22 04:21 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 6.9 ug/m3 04/22/22 04:21 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 11 ug/m3 04/22/22 04:21 1 1,1,2-Trichloroethane ND 2.7 ug/m3 04/22/22 04:21 1
1,1-Dichloroethane ND 2.0 ug/m3 04/22/22 04:21 1
1,1-Dichloroethene ND 2.0 ug/m3 04/22/22 04:21 1
1,1-Difluoroethane ND 5.4 ug/m3 04/22/22 04:21 1
1,2,4-Trichlorobenzene ND 15 ug/m3 04/22/22 04:21 1
1,2,4-Trimethylbenzene ND 7.4 ug/m3 04/22/22 04:21 1
1,2-Dibromo-3-Chloropropane ND 14 ug/m3 04/22/22 04:21 1 1,2-Dibromoethane ND 3.8 ug/m3 04/22/22 04:21 1
1,2-Dichlorobenzene ND 3.0 ug/m3 04/22/22 04:21 1
1,2-Dichloroethane ND 2.0 ug/m3 04/22/22 04:21 1
1,2-Dichloropropane ND 2.3 ug/m3 04/22/22 04:21 1
1,3,5-Trimethylbenzene ND 2.5 ug/m3 04/22/22 04:21 1
1,3-Dichlorobenzene ND 3.0 ug/m3 04/22/22 04:21 1
1,4-Dichlorobenzene ND 3.0 ug/m3 04/22/22 04:21 1
2-Butanone ND 4.4 ug/m3 04/22/22 04:21 1
2-Hexanone ND 6.1 ug/m3 04/22/22 04:21 1
4-Ethyltoluene ND 2.5 ug/m3 04/22/22 04:21 1
4-Methyl-2-pentanone ND 6.1 ug/m3 04/22/22 04:21 1
Acetone 18 4.8 ug/m3 04/22/22 04:21 1
Benzene ND 1.6 ug/m3 04/22/22 04:21 1
Benzyl chloride ND 7.8 ug/m3 04/22/22 04:21 1
Bromodichloromethane ND 3.4 ug/m3 04/22/22 04:21 1
Bromoform ND 5.2 ug/m3 04/22/22 04:21 1
Bromomethane ND 1.9 ug/m3 04/22/22 04:21 1
cis-1,2-Dichloroethene ND 2.0 ug/m3 04/22/22 04:21 1
cis-1,3-Dichloropropene ND 2.3 ug/m3 04/22/22 04:21 1
Carbon disulfide ND 6.2 ug/m3 04/22/22 04:21 1
Carbon tetrachloride ND 3.1 ug/m3 04/22/22 04:21 1
Chlorobenzene ND 2.3 ug/m3 04/22/22 04:21 1
Chloroethane ND 1.3 ug/m3 04/22/22 04:21 1
Chloroform ND 2.4 ug/m3 04/22/22 04:21 1
Chloromethane ND 1.0 ug/m3 04/22/22 04:21 1
Dibromochloromethane ND 4.3 ug/m3 04/22/22 04:21 1
Dichlorodifluoromethane ND 2.5 ug/m3 04/22/22 04:21 1
Dichlorotetrafluoroethane ND 14 ug/m3 04/22/22 04:21 1
Eurofins Calscience

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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-1-10 Lab Sample ID: 570-93118-1
Date Collected: 04/18/22 08:21 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
Ethylbenzene ND 2.2 ug/m3 04/22/22 04:21 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac Hexachloro-1,3-butadiene ND 16 ug/m3 04/22/22 04:21 1
Isopropanol ND 12 ug/m3 04/22/22 04:21 1
Methylene Chloride ND 17 ug/m3 04/22/22 04:21 1
Methyl-t-Butyl Ether (MTBE) ND 7.2 ug/m3 04/22/22 04:21 1 n-Butylbenzene ND 8.2 ug/m3 04/22/22 04:21 1
o-Xylene ND 2.2 ug/m3 04/22/22 04:21 1
m,p-Xylene ND 8.7 ug/m3 04/22/22 04:21 1
sec-Butylbenzene ND 8.2 ug/m3 04/22/22 04:21 1
Styrene ND 6.4 ug/m3 04/22/22 04:21 1
trans-1,2-Dichloroethene ND 2.0 ug/m3 04/22/22 04:21 1
trans-1,3-Dichloropropene ND 4.5 ug/m3 04/22/22 04:21 1 tert-Butylbenzene ND 8.2 ug/m3 04/22/22 04:21 1
Tetrachloroethene ND 3.4 ug/m3 04/22/22 04:21 1
Toluene 2.9 1.9 ug/m3 04/22/22 04:21 1
Trichloroethene ND 2.7 ug/m3 04/22/22 04:21 1
Trichlorofluoromethane 18 5.6 ug/m3 04/22/22 04:21 1
Vinyl acetate ND 7.0 ug/m3 04/22/22 04:21 1
Vinyl chloride ND 1.3 ug/m3 04/22/22 04:21 1
1,2-Dichloroethane-d4 (Surr) 100 66 - 132 04/22/22 04:21 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 119 70 - 130 04/22/22 04:21 1 Toluene-d8 (Surr) 120 70 - 130 04/22/22 04:21 1
Client Sample ID: SV-1-20 Lab Sample ID: 570-93118-2
Date Collected: 04/18/22 08:44 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
1,1,1-Trichloroethane ND 0.50 ppb v/v 04/22/22 05:11 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 1.0 ppb v/v 04/22/22 05:11 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 1.5 ppb v/v 04/22/22 05:11 1 1,1,2-Trichloroethane ND 0.50 ppb v/v 04/22/22 05:11 1
1,1-Dichloroethane ND 0.50 ppb v/v 04/22/22 05:11 1
1,1-Dichloroethene ND 0.50 ppb v/v 04/22/22 05:11 1
1,1-Difluoroethane ND 2.0 ppb v/v 04/22/22 05:11 1
1,2,4-Trichlorobenzene ND 2.0 ppb v/v 04/22/22 05:11 1
1,2,4-Trimethylbenzene ND 1.5 ppb v/v 04/22/22 05:11 1
1,2-Dibromo-3-Chloropropane ND 1.5 ppb v/v 04/22/22 05:11 1 1,2-Dibromoethane ND 0.50 ppb v/v 04/22/22 05:11 1
1,2-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 05:11 1
1,2-Dichloroethane ND 0.50 ppb v/v 04/22/22 05:11 1
1,2-Dichloropropane ND 0.50 ppb v/v 04/22/22 05:11 1
1,3,5-Trimethylbenzene ND 0.50 ppb v/v 04/22/22 05:11 1 1,3-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 05:11 1
1,4-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 05:11 1
2-Butanone ND 1.5 ppb v/v 04/22/22 05:11 1
2-Hexanone ND 1.5 ppb v/v 04/22/22 05:11 1
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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-1-20 Lab Sample ID: 570-93118-2
Date Collected: 04/18/22 08:44 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
4-Ethyltoluene ND 0.50 ppb v/v 04/22/22 05:11 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 4-Methyl-2-pentanone ND 1.5 ppb v/v 04/22/22 05:11 1
Acetone 6.4 2.0 ppb v/v 04/22/22 05:11 1
Benzene ND 0.50 ppb v/v 04/22/22 05:11 1
Benzyl chloride ND 1.5 ppb v/v 04/22/22 05:11 1
Bromodichloromethane ND 0.50 ppb v/v 04/22/22 05:11 1
Bromoform ND 0.50 ppb v/v 04/22/22 05:11 1
Bromomethane ND 0.50 ppb v/v 04/22/22 05:11 1
cis-1,2-Dichloroethene ND 0.50 ppb v/v 04/22/22 05:11 1 cis-1,3-Dichloropropene ND 0.50 ppb v/v 04/22/22 05:11 1 Carbon disulfide ND 2.0 ppb v/v 04/22/22 05:11 1
Carbon tetrachloride ND 0.50 ppb v/v 04/22/22 05:11 1
Chlorobenzene ND 0.50 ppb v/v 04/22/22 05:11 1
Chloroethane ND 0.50 ppb v/v 04/22/22 05:11 1
Chloroform ND 0.50 ppb v/v 04/22/22 05:11 1
Chloromethane ND 0.50 ppb v/v 04/22/22 05:11 1
Dibromochloromethane ND 0.50 ppb v/v 04/22/22 05:11 1
Dichlorodifluoromethane ND 0.50 ppb v/v 04/22/22 05:11 1 Dichlorotetrafluoroethane ND 2.0 ppb v/v 04/22/22 05:11 1 Ethylbenzene ND 0.50 ppb v/v 04/22/22 05:11 1
Hexachloro-1,3-butadiene ND 1.5 ppb v/v 04/22/22 05:11 1 Isopropanol ND 5.0 ppb v/v 04/22/22 05:11 1
Methylene Chloride ND 5.0 ppb v/v 04/22/22 05:11 1
Methyl-t-Butyl Ether (MTBE) ND 2.0 ppb v/v 04/22/22 05:11 1 n-Butylbenzene ND 1.5 ppb v/v 04/22/22 05:11 1
o-Xylene ND 0.50 ppb v/v 04/22/22 05:11 1
m,p-Xylene ND 2.0 ppb v/v 04/22/22 05:11 1
sec-Butylbenzene ND 1.5 ppb v/v 04/22/22 05:11 1
Styrene ND 1.5 ppb v/v 04/22/22 05:11 1
trans-1,2-Dichloroethene ND 0.50 ppb v/v 04/22/22 05:11 1 trans-1,3-Dichloropropene ND 1.0 ppb v/v 04/22/22 05:11 1 tert-Butylbenzene ND 1.5 ppb v/v 04/22/22 05:11 1
Tetrachloroethene ND 0.50 ppb v/v 04/22/22 05:11 1
Toluene ND 0.50 ppb v/v 04/22/22 05:11 1
Trichloroethene ND 0.50 ppb v/v 04/22/22 05:11 1
Trichlorofluoromethane 4.0 1.0 ppb v/v 04/22/22 05:11 1 Vinyl acetate ND 2.0 ppb v/v 04/22/22 05:11 1
Vinyl chloride ND 0.50 ppb v/v 04/22/22 05:11 1
RL MDL
1,1,1-Trichloroethane ND 2.7 ug/m3 04/22/22 05:11 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 6.9 ug/m3 04/22/22 05:11 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 11 ug/m3 04/22/22 05:11 1 1,1,2-Trichloroethane ND 2.7 ug/m3 04/22/22 05:11 1
1,1-Dichloroethane ND 2.0 ug/m3 04/22/22 05:11 1
1,1-Dichloroethene ND 2.0 ug/m3 04/22/22 05:11 1
1,1-Difluoroethane ND 5.4 ug/m3 04/22/22 05:11 1
1,2,4-Trichlorobenzene ND 15 ug/m3 04/22/22 05:11 1
1,2,4-Trimethylbenzene ND 7.4 ug/m3 04/22/22 05:11 1
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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-1-20 Lab Sample ID: 570-93118-2
Date Collected: 04/18/22 08:44 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
1,2-Dibromo-3-Chloropropane ND 14 ug/m3 04/22/22 05:11 1 Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,2-Dibromoethane ND 3.8 ug/m3 04/22/22 05:11 1
1,2-Dichlorobenzene ND 3.0 ug/m3 04/22/22 05:11 1
1,2-Dichloroethane ND 2.0 ug/m3 04/22/22 05:11 1
1,2-Dichloropropane ND 2.3 ug/m3 04/22/22 05:11 1
1,3,5-Trimethylbenzene ND 2.5 ug/m3 04/22/22 05:11 1
1,3-Dichlorobenzene ND 3.0 ug/m3 04/22/22 05:11 1
1,4-Dichlorobenzene ND 3.0 ug/m3 04/22/22 05:11 1
2-Butanone ND 4.4 ug/m3 04/22/22 05:11 1
2-Hexanone ND 6.1 ug/m3 04/22/22 05:11 1
4-Ethyltoluene ND 2.5 ug/m3 04/22/22 05:11 1
4-Methyl-2-pentanone ND 6.1 ug/m3 04/22/22 05:11 1
Acetone 15 4.8 ug/m3 04/22/22 05:11 1
Benzene ND 1.6 ug/m3 04/22/22 05:11 1
Benzyl chloride ND 7.8 ug/m3 04/22/22 05:11 1
Bromodichloromethane ND 3.4 ug/m3 04/22/22 05:11 1
Bromoform ND 5.2 ug/m3 04/22/22 05:11 1
Bromomethane ND 1.9 ug/m3 04/22/22 05:11 1
cis-1,2-Dichloroethene ND 2.0 ug/m3 04/22/22 05:11 1
cis-1,3-Dichloropropene ND 2.3 ug/m3 04/22/22 05:11 1
Carbon disulfide ND 6.2 ug/m3 04/22/22 05:11 1
Carbon tetrachloride ND 3.1 ug/m3 04/22/22 05:11 1
Chlorobenzene ND 2.3 ug/m3 04/22/22 05:11 1
Chloroethane ND 1.3 ug/m3 04/22/22 05:11 1
Chloroform ND 2.4 ug/m3 04/22/22 05:11 1
Chloromethane ND 1.0 ug/m3 04/22/22 05:11 1
Dibromochloromethane ND 4.3 ug/m3 04/22/22 05:11 1
Dichlorodifluoromethane ND 2.5 ug/m3 04/22/22 05:11 1
Dichlorotetrafluoroethane ND 14 ug/m3 04/22/22 05:11 1
Ethylbenzene ND 2.2 ug/m3 04/22/22 05:11 1
Hexachloro-1,3-butadiene ND 16 ug/m3 04/22/22 05:11 1
Isopropanol ND 12 ug/m3 04/22/22 05:11 1
Methylene Chloride ND 17 ug/m3 04/22/22 05:11 1
Methyl-t-Butyl Ether (MTBE) ND 7.2 ug/m3 04/22/22 05:11 1 n-Butylbenzene ND 8.2 ug/m3 04/22/22 05:11 1
o-Xylene ND 2.2 ug/m3 04/22/22 05:11 1
m,p-Xylene ND 8.7 ug/m3 04/22/22 05:11 1
sec-Butylbenzene ND 8.2 ug/m3 04/22/22 05:11 1
Styrene ND 6.4 ug/m3 04/22/22 05:11 1
trans-1,2-Dichloroethene ND 2.0 ug/m3 04/22/22 05:11 1
trans-1,3-Dichloropropene ND 4.5 ug/m3 04/22/22 05:11 1 tert-Butylbenzene ND 8.2 ug/m3 04/22/22 05:11 1
Tetrachloroethene ND 3.4 ug/m3 04/22/22 05:11 1
Toluene ND 1.9 ug/m3 04/22/22 05:11 1
Trichloroethene ND 2.7 ug/m3 04/22/22 05:11 1
Trichlorofluoromethane 22 5.6 ug/m3 04/22/22 05:11 1
Vinyl acetate ND 7.0 ug/m3 04/22/22 05:11 1
Vinyl chloride ND 1.3 ug/m3 04/22/22 05:11 1
Eurofins Calscience

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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) 1,2-Dichloroethane-d4 (Surr) 99 66 - 132 04/22/22 05:11 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 114 70 - 130 04/22/22 05:11 1 Toluene-d8 (Surr) 127 70 - 130 04/22/22 05:11 1
Client Sample ID: SV-2-5 Lab Sample ID: 570-93118-3
Date Collected: 04/18/22 09:25 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
1,1,1-Trichloroethane ND 0.50 ppb v/v 04/22/22 06:04 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 1.0 ppb v/v 04/22/22 06:04 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 1.5 ppb v/v 04/22/22 06:04 1 1,1,2-Trichloroethane ND 0.50 ppb v/v 04/22/22 06:04 1
1,1-Dichloroethane ND 0.50 ppb v/v 04/22/22 06:04 1
1,1-Dichloroethene ND 0.50 ppb v/v 04/22/22 06:04 1
1,1-Difluoroethane ND 2.0 ppb v/v 04/22/22 06:04 1
1,2,4-Trichlorobenzene ND 2.0 ppb v/v 04/22/22 06:04 1
1,2,4-Trimethylbenzene ND 1.5 ppb v/v 04/22/22 06:04 1
1,2-Dibromo-3-Chloropropane ND 1.5 ppb v/v 04/22/22 06:04 1 1,2-Dibromoethane ND 0.50 ppb v/v 04/22/22 06:04 1
1,2-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 06:04 1
1,2-Dichloroethane ND 0.50 ppb v/v 04/22/22 06:04 1
1,2-Dichloropropane ND 0.50 ppb v/v 04/22/22 06:04 1
1,3,5-Trimethylbenzene ND 0.50 ppb v/v 04/22/22 06:04 1 1,3-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 06:04 1
1,4-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 06:04 1
2-Butanone ND 1.5 ppb v/v 04/22/22 06:04 1
2-Hexanone ND 1.5 ppb v/v 04/22/22 06:04 1
4-Ethyltoluene ND 0.50 ppb v/v 04/22/22 06:04 1
4-Methyl-2-pentanone ND 1.5 ppb v/v 04/22/22 06:04 1
Acetone 8.7 2.0 ppb v/v 04/22/22 06:04 1
Benzene ND 0.50 ppb v/v 04/22/22 06:04 1
Benzyl chloride ND 1.5 ppb v/v 04/22/22 06:04 1
Bromodichloromethane ND 0.50 ppb v/v 04/22/22 06:04 1
Bromoform ND 0.50 ppb v/v 04/22/22 06:04 1
Bromomethane ND 0.50 ppb v/v 04/22/22 06:04 1
cis-1,2-Dichloroethene ND 0.50 ppb v/v 04/22/22 06:04 1 cis-1,3-Dichloropropene ND 0.50 ppb v/v 04/22/22 06:04 1 Carbon disulfide ND 2.0 ppb v/v 04/22/22 06:04 1
Carbon tetrachloride ND 0.50 ppb v/v 04/22/22 06:04 1
Chlorobenzene ND 0.50 ppb v/v 04/22/22 06:04 1
Chloroethane ND 0.50 ppb v/v 04/22/22 06:04 1
Chloroform ND 0.50 ppb v/v 04/22/22 06:04 1
Chloromethane ND 0.50 ppb v/v 04/22/22 06:04 1
Dibromochloromethane ND 0.50 ppb v/v 04/22/22 06:04 1
Dichlorodifluoromethane ND 0.50 ppb v/v 04/22/22 06:04 1 Dichlorotetrafluoroethane ND 2.0 ppb v/v 04/22/22 06:04 1 Ethylbenzene ND 0.50 ppb v/v 04/22/22 06:04 1
Hexachloro-1,3-butadiene ND 1.5 ppb v/v 04/22/22 06:04 1 Isopropanol ND 5.0 ppb v/v 04/22/22 06:04 1
Methylene Chloride ND 5.0 ppb v/v 04/22/22 06:04 1
Methyl-t-Butyl Ether (MTBE) ND 2.0 ppb v/v 04/22/22 06:04 1 Eurofins Calscience

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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-2-5 Lab Sample ID: 570-93118-3
Date Collected: 04/18/22 09:25 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
n-Butylbenzene ND 1.5 ppb v/v 04/22/22 06:04 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac o-Xylene ND 0.50 ppb v/v 04/22/22 06:04 1
m,p-Xylene ND 2.0 ppb v/v 04/22/22 06:04 1
sec-Butylbenzene ND 1.5 ppb v/v 04/22/22 06:04 1
Styrene ND 1.5 ppb v/v 04/22/22 06:04 1
trans-1,2-Dichloroethene ND 0.50 ppb v/v 04/22/22 06:04 1 trans-1,3-Dichloropropene ND 1.0 ppb v/v 04/22/22 06:04 1 tert-Butylbenzene ND 1.5 ppb v/v 04/22/22 06:04 1
Tetrachloroethene ND 0.50 ppb v/v 04/22/22 06:04 1
Toluene 0.71 0.50 ppb v/v 04/22/22 06:04 1
Trichloroethene ND 0.50 ppb v/v 04/22/22 06:04 1
Trichlorofluoromethane 3.6 1.0 ppb v/v 04/22/22 06:04 1 Vinyl acetate ND 2.0 ppb v/v 04/22/22 06:04 1
Vinyl chloride ND 0.50 ppb v/v 04/22/22 06:04 1
RL MDL
1,1,1-Trichloroethane ND 2.7 ug/m3 04/22/22 06:04 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 6.9 ug/m3 04/22/22 06:04 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 11 ug/m3 04/22/22 06:04 1 1,1,2-Trichloroethane ND 2.7 ug/m3 04/22/22 06:04 1
1,1-Dichloroethane ND 2.0 ug/m3 04/22/22 06:04 1
1,1-Dichloroethene ND 2.0 ug/m3 04/22/22 06:04 1
1,1-Difluoroethane ND 5.4 ug/m3 04/22/22 06:04 1
1,2,4-Trichlorobenzene ND 15 ug/m3 04/22/22 06:04 1
1,2,4-Trimethylbenzene ND 7.4 ug/m3 04/22/22 06:04 1
1,2-Dibromo-3-Chloropropane ND 14 ug/m3 04/22/22 06:04 1 1,2-Dibromoethane ND 3.8 ug/m3 04/22/22 06:04 1
1,2-Dichlorobenzene ND 3.0 ug/m3 04/22/22 06:04 1
1,2-Dichloroethane ND 2.0 ug/m3 04/22/22 06:04 1
1,2-Dichloropropane ND 2.3 ug/m3 04/22/22 06:04 1
1,3,5-Trimethylbenzene ND 2.5 ug/m3 04/22/22 06:04 1
1,3-Dichlorobenzene ND 3.0 ug/m3 04/22/22 06:04 1
1,4-Dichlorobenzene ND 3.0 ug/m3 04/22/22 06:04 1
2-Butanone ND 4.4 ug/m3 04/22/22 06:04 1
2-Hexanone ND 6.1 ug/m3 04/22/22 06:04 1
4-Ethyltoluene ND 2.5 ug/m3 04/22/22 06:04 1
4-Methyl-2-pentanone ND 6.1 ug/m3 04/22/22 06:04 1
Acetone 21 4.8 ug/m3 04/22/22 06:04 1
Benzene ND 1.6 ug/m3 04/22/22 06:04 1
Benzyl chloride ND 7.8 ug/m3 04/22/22 06:04 1
Bromodichloromethane ND 3.4 ug/m3 04/22/22 06:04 1
Bromoform ND 5.2 ug/m3 04/22/22 06:04 1
Bromomethane ND 1.9 ug/m3 04/22/22 06:04 1
cis-1,2-Dichloroethene ND 2.0 ug/m3 04/22/22 06:04 1
cis-1,3-Dichloropropene ND 2.3 ug/m3 04/22/22 06:04 1
Carbon disulfide ND 6.2 ug/m3 04/22/22 06:04 1
Carbon tetrachloride ND 3.1 ug/m3 04/22/22 06:04 1
Chlorobenzene ND 2.3 ug/m3 04/22/22 06:04 1
Chloroethane ND 1.3 ug/m3 04/22/22 06:04 1
Eurofins Calscience

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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-2-5 Lab Sample ID: 570-93118-3
Date Collected: 04/18/22 09:25 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
Chloroform ND 2.4 ug/m3 04/22/22 06:04 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac Chloromethane ND 1.0 ug/m3 04/22/22 06:04 1
Dibromochloromethane ND 4.3 ug/m3 04/22/22 06:04 1
Dichlorodifluoromethane ND 2.5 ug/m3 04/22/22 06:04 1
Dichlorotetrafluoroethane ND 14 ug/m3 04/22/22 06:04 1
Ethylbenzene ND 2.2 ug/m3 04/22/22 06:04 1
Hexachloro-1,3-butadiene ND 16 ug/m3 04/22/22 06:04 1
Isopropanol ND 12 ug/m3 04/22/22 06:04 1
Methylene Chloride ND 17 ug/m3 04/22/22 06:04 1
Methyl-t-Butyl Ether (MTBE) ND 7.2 ug/m3 04/22/22 06:04 1 n-Butylbenzene ND 8.2 ug/m3 04/22/22 06:04 1
o-Xylene ND 2.2 ug/m3 04/22/22 06:04 1
m,p-Xylene ND 8.7 ug/m3 04/22/22 06:04 1
sec-Butylbenzene ND 8.2 ug/m3 04/22/22 06:04 1
Styrene ND 6.4 ug/m3 04/22/22 06:04 1
trans-1,2-Dichloroethene ND 2.0 ug/m3 04/22/22 06:04 1
trans-1,3-Dichloropropene ND 4.5 ug/m3 04/22/22 06:04 1 tert-Butylbenzene ND 8.2 ug/m3 04/22/22 06:04 1
Tetrachloroethene ND 3.4 ug/m3 04/22/22 06:04 1
Toluene 2.7 1.9 ug/m3 04/22/22 06:04 1
Trichloroethene ND 2.7 ug/m3 04/22/22 06:04 1
Trichlorofluoromethane 20 5.6 ug/m3 04/22/22 06:04 1
Vinyl acetate ND 7.0 ug/m3 04/22/22 06:04 1
Vinyl chloride ND 1.3 ug/m3 04/22/22 06:04 1
1,2-Dichloroethane-d4 (Surr) 100 66 - 132 04/22/22 06:04 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 119 70 - 130 04/22/22 06:04 1 Toluene-d8 (Surr) 119 70 - 130 04/22/22 06:04 1
Client Sample ID: SV-2-5-D Lab Sample ID: 570-93118-4
Date Collected: 04/18/22 09:25 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
1,1,1-Trichloroethane ND 0.50 ppb v/v 04/22/22 06:56 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 1.0 ppb v/v 04/22/22 06:56 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 1.5 ppb v/v 04/22/22 06:56 1 1,1,2-Trichloroethane ND 0.50 ppb v/v 04/22/22 06:56 1
1,1-Dichloroethane ND 0.50 ppb v/v 04/22/22 06:56 1
1,1-Dichloroethene ND 0.50 ppb v/v 04/22/22 06:56 1
1,1-Difluoroethane ND 2.0 ppb v/v 04/22/22 06:56 1
1,2,4-Trichlorobenzene ND 2.0 ppb v/v 04/22/22 06:56 1
1,2,4-Trimethylbenzene ND 1.5 ppb v/v 04/22/22 06:56 1
1,2-Dibromo-3-Chloropropane ND 1.5 ppb v/v 04/22/22 06:56 1 1,2-Dibromoethane ND 0.50 ppb v/v 04/22/22 06:56 1
1,2-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 06:56 1
1,2-Dichloroethane ND 0.50 ppb v/v 04/22/22 06:56 1
1,2-Dichloropropane ND 0.50 ppb v/v 04/22/22 06:56 1
Eurofins Calscience

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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-2-5-D Lab Sample ID: 570-93118-4
Date Collected: 04/18/22 09:25 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
1,3,5-Trimethylbenzene ND 0.50 ppb v/v 04/22/22 06:56 1 Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,3-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 06:56 1
1,4-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 06:56 1
2-Butanone ND 1.5 ppb v/v 04/22/22 06:56 1
2-Hexanone ND 1.5 ppb v/v 04/22/22 06:56 1
4-Ethyltoluene ND 0.50 ppb v/v 04/22/22 06:56 1
4-Methyl-2-pentanone ND 1.5 ppb v/v 04/22/22 06:56 1
Acetone 6.8 2.0 ppb v/v 04/22/22 06:56 1
Benzene ND 0.50 ppb v/v 04/22/22 06:56 1
Benzyl chloride ND 1.5 ppb v/v 04/22/22 06:56 1
Bromodichloromethane ND 0.50 ppb v/v 04/22/22 06:56 1
Bromoform ND 0.50 ppb v/v 04/22/22 06:56 1
Bromomethane ND 0.50 ppb v/v 04/22/22 06:56 1
cis-1,2-Dichloroethene ND 0.50 ppb v/v 04/22/22 06:56 1 cis-1,3-Dichloropropene ND 0.50 ppb v/v 04/22/22 06:56 1 Carbon disulfide ND 2.0 ppb v/v 04/22/22 06:56 1
Carbon tetrachloride ND 0.50 ppb v/v 04/22/22 06:56 1
Chlorobenzene ND 0.50 ppb v/v 04/22/22 06:56 1
Chloroethane ND 0.50 ppb v/v 04/22/22 06:56 1
Chloroform ND 0.50 ppb v/v 04/22/22 06:56 1
Chloromethane ND 0.50 ppb v/v 04/22/22 06:56 1
Dibromochloromethane ND 0.50 ppb v/v 04/22/22 06:56 1
Dichlorodifluoromethane ND 0.50 ppb v/v 04/22/22 06:56 1 Dichlorotetrafluoroethane ND 2.0 ppb v/v 04/22/22 06:56 1 Ethylbenzene ND 0.50 ppb v/v 04/22/22 06:56 1
Hexachloro-1,3-butadiene ND 1.5 ppb v/v 04/22/22 06:56 1 Isopropanol ND 5.0 ppb v/v 04/22/22 06:56 1
Methylene Chloride ND 5.0 ppb v/v 04/22/22 06:56 1
Methyl-t-Butyl Ether (MTBE) ND 2.0 ppb v/v 04/22/22 06:56 1 n-Butylbenzene ND 1.5 ppb v/v 04/22/22 06:56 1
o-Xylene ND 0.50 ppb v/v 04/22/22 06:56 1
m,p-Xylene ND 2.0 ppb v/v 04/22/22 06:56 1
sec-Butylbenzene ND 1.5 ppb v/v 04/22/22 06:56 1
Styrene ND 1.5 ppb v/v 04/22/22 06:56 1
trans-1,2-Dichloroethene ND 0.50 ppb v/v 04/22/22 06:56 1 trans-1,3-Dichloropropene ND 1.0 ppb v/v 04/22/22 06:56 1 tert-Butylbenzene ND 1.5 ppb v/v 04/22/22 06:56 1
Tetrachloroethene ND 0.50 ppb v/v 04/22/22 06:56 1
Toluene 0.66 0.50 ppb v/v 04/22/22 06:56 1
Trichloroethene ND 0.50 ppb v/v 04/22/22 06:56 1
Trichlorofluoromethane ND 1.0 ppb v/v 04/22/22 06:56 1
Vinyl acetate ND 2.0 ppb v/v 04/22/22 06:56 1
Vinyl chloride ND 0.50 ppb v/v 04/22/22 06:56 1
RL MDL
1,1,1-Trichloroethane ND 2.7 ug/m3 04/22/22 06:56 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 6.9 ug/m3 04/22/22 06:56 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 11 ug/m3 04/22/22 06:56 1 1,1,2-Trichloroethane ND 2.7 ug/m3 04/22/22 06:56 1
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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-2-5-D Lab Sample ID: 570-93118-4
Date Collected: 04/18/22 09:25 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
1,1-Dichloroethane ND 2.0 ug/m3 04/22/22 06:56 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1-Dichloroethene ND 2.0 ug/m3 04/22/22 06:56 1
1,1-Difluoroethane ND 5.4 ug/m3 04/22/22 06:56 1
1,2,4-Trichlorobenzene ND 15 ug/m3 04/22/22 06:56 1
1,2,4-Trimethylbenzene ND 7.4 ug/m3 04/22/22 06:56 1
1,2-Dibromo-3-Chloropropane ND 14 ug/m3 04/22/22 06:56 1 1,2-Dibromoethane ND 3.8 ug/m3 04/22/22 06:56 1
1,2-Dichlorobenzene ND 3.0 ug/m3 04/22/22 06:56 1
1,2-Dichloroethane ND 2.0 ug/m3 04/22/22 06:56 1
1,2-Dichloropropane ND 2.3 ug/m3 04/22/22 06:56 1
1,3,5-Trimethylbenzene ND 2.5 ug/m3 04/22/22 06:56 1
1,3-Dichlorobenzene ND 3.0 ug/m3 04/22/22 06:56 1
1,4-Dichlorobenzene ND 3.0 ug/m3 04/22/22 06:56 1
2-Butanone ND 4.4 ug/m3 04/22/22 06:56 1
2-Hexanone ND 6.1 ug/m3 04/22/22 06:56 1
4-Ethyltoluene ND 2.5 ug/m3 04/22/22 06:56 1
4-Methyl-2-pentanone ND 6.1 ug/m3 04/22/22 06:56 1
Acetone 16 4.8 ug/m3 04/22/22 06:56 1
Benzene ND 1.6 ug/m3 04/22/22 06:56 1
Benzyl chloride ND 7.8 ug/m3 04/22/22 06:56 1
Bromodichloromethane ND 3.4 ug/m3 04/22/22 06:56 1
Bromoform ND 5.2 ug/m3 04/22/22 06:56 1
Bromomethane ND 1.9 ug/m3 04/22/22 06:56 1
cis-1,2-Dichloroethene ND 2.0 ug/m3 04/22/22 06:56 1
cis-1,3-Dichloropropene ND 2.3 ug/m3 04/22/22 06:56 1
Carbon disulfide ND 6.2 ug/m3 04/22/22 06:56 1
Carbon tetrachloride ND 3.1 ug/m3 04/22/22 06:56 1
Chlorobenzene ND 2.3 ug/m3 04/22/22 06:56 1
Chloroethane ND 1.3 ug/m3 04/22/22 06:56 1
Chloroform ND 2.4 ug/m3 04/22/22 06:56 1
Chloromethane ND 1.0 ug/m3 04/22/22 06:56 1
Dibromochloromethane ND 4.3 ug/m3 04/22/22 06:56 1
Dichlorodifluoromethane ND 2.5 ug/m3 04/22/22 06:56 1
Dichlorotetrafluoroethane ND 14 ug/m3 04/22/22 06:56 1
Ethylbenzene ND 2.2 ug/m3 04/22/22 06:56 1
Hexachloro-1,3-butadiene ND 16 ug/m3 04/22/22 06:56 1
Isopropanol ND 12 ug/m3 04/22/22 06:56 1
Methylene Chloride ND 17 ug/m3 04/22/22 06:56 1
Methyl-t-Butyl Ether (MTBE) ND 7.2 ug/m3 04/22/22 06:56 1 n-Butylbenzene ND 8.2 ug/m3 04/22/22 06:56 1
o-Xylene ND 2.2 ug/m3 04/22/22 06:56 1
m,p-Xylene ND 8.7 ug/m3 04/22/22 06:56 1
sec-Butylbenzene ND 8.2 ug/m3 04/22/22 06:56 1
Styrene ND 6.4 ug/m3 04/22/22 06:56 1
trans-1,2-Dichloroethene ND 2.0 ug/m3 04/22/22 06:56 1
trans-1,3-Dichloropropene ND 4.5 ug/m3 04/22/22 06:56 1 tert-Butylbenzene ND 8.2 ug/m3 04/22/22 06:56 1
Tetrachloroethene ND 3.4 ug/m3 04/22/22 06:56 1
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1762
Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-2-5-D Lab Sample ID: 570-93118-4
Date Collected: 04/18/22 09:25 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
Toluene 2.5 1.9 ug/m3 04/22/22 06:56 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac Trichloroethene ND 2.7 ug/m3 04/22/22 06:56 1
Trichlorofluoromethane ND 5.6 ug/m3 04/22/22 06:56 1
Vinyl acetate ND 7.0 ug/m3 04/22/22 06:56 1
Vinyl chloride ND 1.3 ug/m3 04/22/22 06:56 1
1,2-Dichloroethane-d4 (Surr) 100 66 - 132 04/22/22 06:56 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 119 70 - 130 04/22/22 06:56 1 Toluene-d8 (Surr) 119 70 - 130 04/22/22 06:56 1
Client Sample ID: SV-2-15 Lab Sample ID: 570-93118-5
Date Collected: 04/18/22 09:49 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
1,1,1-Trichloroethane ND 0.50 ppb v/v 04/22/22 07:52 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 1.0 ppb v/v 04/22/22 07:52 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 1.5 ppb v/v 04/22/22 07:52 1 1,1,2-Trichloroethane ND 0.50 ppb v/v 04/22/22 07:52 1
1,1-Dichloroethane ND 0.50 ppb v/v 04/22/22 07:52 1
1,1-Dichloroethene ND 0.50 ppb v/v 04/22/22 07:52 1
1,1-Difluoroethane ND 2.0 ppb v/v 04/22/22 07:52 1
1,2,4-Trichlorobenzene ND 2.0 ppb v/v 04/22/22 07:52 1
1,2,4-Trimethylbenzene ND 1.5 ppb v/v 04/22/22 07:52 1
1,2-Dibromo-3-Chloropropane ND 1.5 ppb v/v 04/22/22 07:52 1 1,2-Dibromoethane ND 0.50 ppb v/v 04/22/22 07:52 1
1,2-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 07:52 1
1,2-Dichloroethane ND 0.50 ppb v/v 04/22/22 07:52 1
1,2-Dichloropropane ND 0.50 ppb v/v 04/22/22 07:52 1
1,3,5-Trimethylbenzene ND 0.50 ppb v/v 04/22/22 07:52 1 1,3-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 07:52 1
1,4-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 07:52 1
2-Butanone 1.6 1.5 ppb v/v 04/22/22 07:52 1
2-Hexanone ND 1.5 ppb v/v 04/22/22 07:52 1
4-Ethyltoluene ND 0.50 ppb v/v 04/22/22 07:52 1
4-Methyl-2-pentanone ND 1.5 ppb v/v 04/22/22 07:52 1
Acetone 9.9 2.0 ppb v/v 04/22/22 07:52 1
Benzene ND 0.50 ppb v/v 04/22/22 07:52 1
Benzyl chloride ND 1.5 ppb v/v 04/22/22 07:52 1
Bromodichloromethane ND 0.50 ppb v/v 04/22/22 07:52 1
Bromoform ND 0.50 ppb v/v 04/22/22 07:52 1
Bromomethane ND 0.50 ppb v/v 04/22/22 07:52 1
cis-1,2-Dichloroethene ND 0.50 ppb v/v 04/22/22 07:52 1 cis-1,3-Dichloropropene ND 0.50 ppb v/v 04/22/22 07:52 1 Carbon disulfide ND 2.0 ppb v/v 04/22/22 07:52 1
Carbon tetrachloride ND 0.50 ppb v/v 04/22/22 07:52 1
Chlorobenzene ND 0.50 ppb v/v 04/22/22 07:52 1
Chloroethane ND 0.50 ppb v/v 04/22/22 07:52 1
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1763
Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-2-15 Lab Sample ID: 570-93118-5
Date Collected: 04/18/22 09:49 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
Chloroform ND 0.50 ppb v/v 04/22/22 07:52 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac Chloromethane ND 0.50 ppb v/v 04/22/22 07:52 1
Dibromochloromethane ND 0.50 ppb v/v 04/22/22 07:52 1
Dichlorodifluoromethane ND 0.50 ppb v/v 04/22/22 07:52 1 Dichlorotetrafluoroethane ND 2.0 ppb v/v 04/22/22 07:52 1 Ethylbenzene ND 0.50 ppb v/v 04/22/22 07:52 1
Hexachloro-1,3-butadiene ND 1.5 ppb v/v 04/22/22 07:52 1 Isopropanol ND 5.0 ppb v/v 04/22/22 07:52 1
Methylene Chloride ND 5.0 ppb v/v 04/22/22 07:52 1
Methyl-t-Butyl Ether (MTBE) ND 2.0 ppb v/v 04/22/22 07:52 1 n-Butylbenzene ND 1.5 ppb v/v 04/22/22 07:52 1
o-Xylene ND 0.50 ppb v/v 04/22/22 07:52 1
m,p-Xylene ND 2.0 ppb v/v 04/22/22 07:52 1
sec-Butylbenzene ND 1.5 ppb v/v 04/22/22 07:52 1
Styrene ND 1.5 ppb v/v 04/22/22 07:52 1
trans-1,2-Dichloroethene ND 0.50 ppb v/v 04/22/22 07:52 1 trans-1,3-Dichloropropene ND 1.0 ppb v/v 04/22/22 07:52 1 tert-Butylbenzene ND 1.5 ppb v/v 04/22/22 07:52 1
Tetrachloroethene 0.56 0.50 ppb v/v 04/22/22 07:52 1
Toluene 1.0 0.50 ppb v/v 04/22/22 07:52 1
Trichloroethene ND 0.50 ppb v/v 04/22/22 07:52 1
Trichlorofluoromethane 20 1.0 ppb v/v 04/22/22 07:52 1
Vinyl acetate ND 2.0 ppb v/v 04/22/22 07:52 1
Vinyl chloride ND 0.50 ppb v/v 04/22/22 07:52 1
RL MDL
1,1,1-Trichloroethane ND 2.7 ug/m3 04/22/22 07:52 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 6.9 ug/m3 04/22/22 07:52 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 11 ug/m3 04/22/22 07:52 1 1,1,2-Trichloroethane ND 2.7 ug/m3 04/22/22 07:52 1
1,1-Dichloroethane ND 2.0 ug/m3 04/22/22 07:52 1
1,1-Dichloroethene ND 2.0 ug/m3 04/22/22 07:52 1
1,1-Difluoroethane ND 5.4 ug/m3 04/22/22 07:52 1
1,2,4-Trichlorobenzene ND 15 ug/m3 04/22/22 07:52 1
1,2,4-Trimethylbenzene ND 7.4 ug/m3 04/22/22 07:52 1
1,2-Dibromo-3-Chloropropane ND 14 ug/m3 04/22/22 07:52 1 1,2-Dibromoethane ND 3.8 ug/m3 04/22/22 07:52 1
1,2-Dichlorobenzene ND 3.0 ug/m3 04/22/22 07:52 1
1,2-Dichloroethane ND 2.0 ug/m3 04/22/22 07:52 1
1,2-Dichloropropane ND 2.3 ug/m3 04/22/22 07:52 1
1,3,5-Trimethylbenzene ND 2.5 ug/m3 04/22/22 07:52 1
1,3-Dichlorobenzene ND 3.0 ug/m3 04/22/22 07:52 1
1,4-Dichlorobenzene ND 3.0 ug/m3 04/22/22 07:52 1
2-Butanone 4.7 4.4 ug/m3 04/22/22 07:52 1
2-Hexanone ND 6.1 ug/m3 04/22/22 07:52 1
4-Ethyltoluene ND 2.5 ug/m3 04/22/22 07:52 1
4-Methyl-2-pentanone ND 6.1 ug/m3 04/22/22 07:52 1
Acetone 24 4.8 ug/m3 04/22/22 07:52 1
Benzene ND 1.6 ug/m3 04/22/22 07:52 1
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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-2-15 Lab Sample ID: 570-93118-5
Date Collected: 04/18/22 09:49 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
Benzyl chloride ND 7.8 ug/m3 04/22/22 07:52 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac Bromodichloromethane ND 3.4 ug/m3 04/22/22 07:52 1
Bromoform ND 5.2 ug/m3 04/22/22 07:52 1
Bromomethane ND 1.9 ug/m3 04/22/22 07:52 1
cis-1,2-Dichloroethene ND 2.0 ug/m3 04/22/22 07:52 1
cis-1,3-Dichloropropene ND 2.3 ug/m3 04/22/22 07:52 1
Carbon disulfide ND 6.2 ug/m3 04/22/22 07:52 1
Carbon tetrachloride ND 3.1 ug/m3 04/22/22 07:52 1
Chlorobenzene ND 2.3 ug/m3 04/22/22 07:52 1
Chloroethane ND 1.3 ug/m3 04/22/22 07:52 1
Chloroform ND 2.4 ug/m3 04/22/22 07:52 1
Chloromethane ND 1.0 ug/m3 04/22/22 07:52 1
Dibromochloromethane ND 4.3 ug/m3 04/22/22 07:52 1
Dichlorodifluoromethane ND 2.5 ug/m3 04/22/22 07:52 1
Dichlorotetrafluoroethane ND 14 ug/m3 04/22/22 07:52 1
Ethylbenzene ND 2.2 ug/m3 04/22/22 07:52 1
Hexachloro-1,3-butadiene ND 16 ug/m3 04/22/22 07:52 1
Isopropanol ND 12 ug/m3 04/22/22 07:52 1
Methylene Chloride ND 17 ug/m3 04/22/22 07:52 1
Methyl-t-Butyl Ether (MTBE) ND 7.2 ug/m3 04/22/22 07:52 1 n-Butylbenzene ND 8.2 ug/m3 04/22/22 07:52 1
o-Xylene ND 2.2 ug/m3 04/22/22 07:52 1
m,p-Xylene ND 8.7 ug/m3 04/22/22 07:52 1
sec-Butylbenzene ND 8.2 ug/m3 04/22/22 07:52 1
Styrene ND 6.4 ug/m3 04/22/22 07:52 1
trans-1,2-Dichloroethene ND 2.0 ug/m3 04/22/22 07:52 1
trans-1,3-Dichloropropene ND 4.5 ug/m3 04/22/22 07:52 1 tert-Butylbenzene ND 8.2 ug/m3 04/22/22 07:52 1
Tetrachloroethene 3.8 3.4 ug/m3 04/22/22 07:52 1
Toluene 3.8 1.9 ug/m3 04/22/22 07:52 1
Trichloroethene ND 2.7 ug/m3 04/22/22 07:52 1
Trichlorofluoromethane 110 5.6 ug/m3 04/22/22 07:52 1
Vinyl acetate ND 7.0 ug/m3 04/22/22 07:52 1
Vinyl chloride ND 1.3 ug/m3 04/22/22 07:52 1
1,2-Dichloroethane-d4 (Surr) 100 66 - 132 04/22/22 07:52 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 118 70 - 130 04/22/22 07:52 1 Toluene-d8 (Surr) 117 70 - 130 04/22/22 07:52 1
Client Sample ID: SV-4-5 Lab Sample ID: 570-93118-6
Date Collected: 04/18/22 10:28 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
1,1,1-Trichloroethane ND 0.50 ppb v/v 04/22/22 08:57 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 1.0 ppb v/v 04/22/22 08:57 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 1.5 ppb v/v 04/22/22 08:57 1 1,1,2-Trichloroethane ND 0.50 ppb v/v 04/22/22 08:57 1
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1765
Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-4-5 Lab Sample ID: 570-93118-6
Date Collected: 04/18/22 10:28 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
1,1-Dichloroethane ND 0.50 ppb v/v 04/22/22 08:57 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1-Dichloroethene ND 0.50 ppb v/v 04/22/22 08:57 1
1,1-Difluoroethane ND 2.0 ppb v/v 04/22/22 08:57 1
1,2,4-Trichlorobenzene ND 2.0 ppb v/v 04/22/22 08:57 1
1,2,4-Trimethylbenzene ND 1.5 ppb v/v 04/22/22 08:57 1
1,2-Dibromo-3-Chloropropane ND 1.5 ppb v/v 04/22/22 08:57 1 1,2-Dibromoethane ND 0.50 ppb v/v 04/22/22 08:57 1
1,2-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 08:57 1
1,2-Dichloroethane ND 0.50 ppb v/v 04/22/22 08:57 1
1,2-Dichloropropane ND 0.50 ppb v/v 04/22/22 08:57 1
1,3,5-Trimethylbenzene ND 0.50 ppb v/v 04/22/22 08:57 1 1,3-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 08:57 1
1,4-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 08:57 1
2-Butanone 5.9 1.5 ppb v/v 04/22/22 08:57 1
2-Hexanone ND 1.5 ppb v/v 04/22/22 08:57 1
4-Ethyltoluene ND 0.50 ppb v/v 04/22/22 08:57 1
4-Methyl-2-pentanone ND 1.5 ppb v/v 04/22/22 08:57 1
Acetone 26 2.0 ppb v/v 04/22/22 08:57 1
Benzene ND 0.50 ppb v/v 04/22/22 08:57 1
Benzyl chloride ND 1.5 ppb v/v 04/22/22 08:57 1
Bromodichloromethane ND 0.50 ppb v/v 04/22/22 08:57 1
Bromoform ND 0.50 ppb v/v 04/22/22 08:57 1
Bromomethane ND 0.50 ppb v/v 04/22/22 08:57 1
cis-1,2-Dichloroethene ND 0.50 ppb v/v 04/22/22 08:57 1 cis-1,3-Dichloropropene ND 0.50 ppb v/v 04/22/22 08:57 1 Carbon disulfide ND 2.0 ppb v/v 04/22/22 08:57 1
Carbon tetrachloride ND 0.50 ppb v/v 04/22/22 08:57 1
Chlorobenzene ND 0.50 ppb v/v 04/22/22 08:57 1
Chloroethane 0.55 0.50 ppb v/v 04/22/22 08:57 1
Chloroform ND 0.50 ppb v/v 04/22/22 08:57 1
Chloromethane 1.2 0.50 ppb v/v 04/22/22 08:57 1
Dibromochloromethane ND 0.50 ppb v/v 04/22/22 08:57 1
Dichlorodifluoromethane ND 0.50 ppb v/v 04/22/22 08:57 1 Dichlorotetrafluoroethane ND 2.0 ppb v/v 04/22/22 08:57 1 Ethylbenzene ND 0.50 ppb v/v 04/22/22 08:57 1
Hexachloro-1,3-butadiene ND 1.5 ppb v/v 04/22/22 08:57 1 Isopropanol ND 5.0 ppb v/v 04/22/22 08:57 1
Methylene Chloride ND 5.0 ppb v/v 04/22/22 08:57 1
Methyl-t-Butyl Ether (MTBE) ND 2.0 ppb v/v 04/22/22 08:57 1 n-Butylbenzene ND 1.5 ppb v/v 04/22/22 08:57 1
o-Xylene ND 0.50 ppb v/v 04/22/22 08:57 1
m,p-Xylene ND 2.0 ppb v/v 04/22/22 08:57 1
sec-Butylbenzene ND 1.5 ppb v/v 04/22/22 08:57 1
Styrene ND 1.5 ppb v/v 04/22/22 08:57 1
trans-1,2-Dichloroethene ND 0.50 ppb v/v 04/22/22 08:57 1 trans-1,3-Dichloropropene ND 1.0 ppb v/v 04/22/22 08:57 1 tert-Butylbenzene ND 1.5 ppb v/v 04/22/22 08:57 1
Tetrachloroethene ND 0.50 ppb v/v 04/22/22 08:57 1
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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-4-5 Lab Sample ID: 570-93118-6
Date Collected: 04/18/22 10:28 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
Toluene 0.62 0.50 ppb v/v 04/22/22 08:57 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac Trichloroethene ND 0.50 ppb v/v 04/22/22 08:57 1
Trichlorofluoromethane 1.3 1.0 ppb v/v 04/22/22 08:57 1 Vinyl acetate ND 2.0 ppb v/v 04/22/22 08:57 1
Vinyl chloride ND 0.50 ppb v/v 04/22/22 08:57 1
RL MDL
1,1,1-Trichloroethane ND 2.7 ug/m3 04/22/22 08:57 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 6.9 ug/m3 04/22/22 08:57 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 11 ug/m3 04/22/22 08:57 1 1,1,2-Trichloroethane ND 2.7 ug/m3 04/22/22 08:57 1
1,1-Dichloroethane ND 2.0 ug/m3 04/22/22 08:57 1
1,1-Dichloroethene ND 2.0 ug/m3 04/22/22 08:57 1
1,1-Difluoroethane ND 5.4 ug/m3 04/22/22 08:57 1
1,2,4-Trichlorobenzene ND 15 ug/m3 04/22/22 08:57 1
1,2,4-Trimethylbenzene ND 7.4 ug/m3 04/22/22 08:57 1
1,2-Dibromo-3-Chloropropane ND 14 ug/m3 04/22/22 08:57 1 1,2-Dibromoethane ND 3.8 ug/m3 04/22/22 08:57 1
1,2-Dichlorobenzene ND 3.0 ug/m3 04/22/22 08:57 1
1,2-Dichloroethane ND 2.0 ug/m3 04/22/22 08:57 1
1,2-Dichloropropane ND 2.3 ug/m3 04/22/22 08:57 1
1,3,5-Trimethylbenzene ND 2.5 ug/m3 04/22/22 08:57 1
1,3-Dichlorobenzene ND 3.0 ug/m3 04/22/22 08:57 1
1,4-Dichlorobenzene ND 3.0 ug/m3 04/22/22 08:57 1
2-Butanone 17 4.4 ug/m3 04/22/22 08:57 1
2-Hexanone ND 6.1 ug/m3 04/22/22 08:57 1
4-Ethyltoluene ND 2.5 ug/m3 04/22/22 08:57 1
4-Methyl-2-pentanone ND 6.1 ug/m3 04/22/22 08:57 1
Acetone 62 4.8 ug/m3 04/22/22 08:57 1
Benzene ND 1.6 ug/m3 04/22/22 08:57 1
Benzyl chloride ND 7.8 ug/m3 04/22/22 08:57 1
Bromodichloromethane ND 3.4 ug/m3 04/22/22 08:57 1
Bromoform ND 5.2 ug/m3 04/22/22 08:57 1
Bromomethane ND 1.9 ug/m3 04/22/22 08:57 1
cis-1,2-Dichloroethene ND 2.0 ug/m3 04/22/22 08:57 1
cis-1,3-Dichloropropene ND 2.3 ug/m3 04/22/22 08:57 1
Carbon disulfide ND 6.2 ug/m3 04/22/22 08:57 1
Carbon tetrachloride ND 3.1 ug/m3 04/22/22 08:57 1
Chlorobenzene ND 2.3 ug/m3 04/22/22 08:57 1
Chloroethane 1.4 1.3 ug/m3 04/22/22 08:57 1
Chloroform ND 2.4 ug/m3 04/22/22 08:57 1
Chloromethane 2.6 1.0 ug/m3 04/22/22 08:57 1
Dibromochloromethane ND 4.3 ug/m3 04/22/22 08:57 1
Dichlorodifluoromethane ND 2.5 ug/m3 04/22/22 08:57 1
Dichlorotetrafluoroethane ND 14 ug/m3 04/22/22 08:57 1
Ethylbenzene ND 2.2 ug/m3 04/22/22 08:57 1
Hexachloro-1,3-butadiene ND 16 ug/m3 04/22/22 08:57 1
Isopropanol ND 12 ug/m3 04/22/22 08:57 1
Methylene Chloride ND 17 ug/m3 04/22/22 08:57 1
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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-4-5 Lab Sample ID: 570-93118-6
Date Collected: 04/18/22 10:28 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
Methyl-t-Butyl Ether (MTBE) ND 7.2 ug/m3 04/22/22 08:57 1 Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac n-Butylbenzene ND 8.2 ug/m3 04/22/22 08:57 1
o-Xylene ND 2.2 ug/m3 04/22/22 08:57 1
m,p-Xylene ND 8.7 ug/m3 04/22/22 08:57 1
sec-Butylbenzene ND 8.2 ug/m3 04/22/22 08:57 1
Styrene ND 6.4 ug/m3 04/22/22 08:57 1
trans-1,2-Dichloroethene ND 2.0 ug/m3 04/22/22 08:57 1
trans-1,3-Dichloropropene ND 4.5 ug/m3 04/22/22 08:57 1 tert-Butylbenzene ND 8.2 ug/m3 04/22/22 08:57 1
Tetrachloroethene ND 3.4 ug/m3 04/22/22 08:57 1
Toluene 2.3 1.9 ug/m3 04/22/22 08:57 1
Trichloroethene ND 2.7 ug/m3 04/22/22 08:57 1
Trichlorofluoromethane 7.0 5.6 ug/m3 04/22/22 08:57 1
Vinyl acetate ND 7.0 ug/m3 04/22/22 08:57 1
Vinyl chloride ND 1.3 ug/m3 04/22/22 08:57 1
1,2-Dichloroethane-d4 (Surr) 100 66 - 132 04/22/22 08:57 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 118 70 - 130 04/22/22 08:57 1 Toluene-d8 (Surr) 111 70 - 130 04/22/22 08:57 1
Client Sample ID: SV-4-15 Lab Sample ID: 570-93118-7
Date Collected: 04/18/22 10:24 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
1,1,1-Trichloroethane ND 0.50 ppb v/v 04/22/22 09:54 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 1.0 ppb v/v 04/22/22 09:54 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 1.5 ppb v/v 04/22/22 09:54 1 1,1,2-Trichloroethane ND 0.50 ppb v/v 04/22/22 09:54 1
1,1-Dichloroethane ND 0.50 ppb v/v 04/22/22 09:54 1
1,1-Dichloroethene ND 0.50 ppb v/v 04/22/22 09:54 1
1,1-Difluoroethane ND 2.0 ppb v/v 04/22/22 09:54 1
1,2,4-Trichlorobenzene ND 2.0 ppb v/v 04/22/22 09:54 1
1,2,4-Trimethylbenzene ND 1.5 ppb v/v 04/22/22 09:54 1
1,2-Dibromo-3-Chloropropane ND 1.5 ppb v/v 04/22/22 09:54 1 1,2-Dibromoethane ND 0.50 ppb v/v 04/22/22 09:54 1
1,2-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 09:54 1
1,2-Dichloroethane ND 0.50 ppb v/v 04/22/22 09:54 1
1,2-Dichloropropane ND 0.50 ppb v/v 04/22/22 09:54 1
1,3,5-Trimethylbenzene ND 0.50 ppb v/v 04/22/22 09:54 1 1,3-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 09:54 1
1,4-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 09:54 1
2-Butanone 1.6 1.5 ppb v/v 04/22/22 09:54 1
2-Hexanone ND 1.5 ppb v/v 04/22/22 09:54 1
4-Ethyltoluene ND 0.50 ppb v/v 04/22/22 09:54 1
4-Methyl-2-pentanone ND 1.5 ppb v/v 04/22/22 09:54 1
Acetone 11 2.0 ppb v/v 04/22/22 09:54 1
Benzene ND 0.50 ppb v/v 04/22/22 09:54 1
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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-4-15 Lab Sample ID: 570-93118-7
Date Collected: 04/18/22 10:24 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
Benzyl chloride ND 1.5 ppb v/v 04/22/22 09:54 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac Bromodichloromethane ND 0.50 ppb v/v 04/22/22 09:54 1
Bromoform ND 0.50 ppb v/v 04/22/22 09:54 1
Bromomethane ND 0.50 ppb v/v 04/22/22 09:54 1
cis-1,2-Dichloroethene ND 0.50 ppb v/v 04/22/22 09:54 1 cis-1,3-Dichloropropene ND 0.50 ppb v/v 04/22/22 09:54 1 Carbon disulfide ND 2.0 ppb v/v 04/22/22 09:54 1
Carbon tetrachloride ND 0.50 ppb v/v 04/22/22 09:54 1
Chlorobenzene ND 0.50 ppb v/v 04/22/22 09:54 1
Chloroethane ND 0.50 ppb v/v 04/22/22 09:54 1
Chloroform ND 0.50 ppb v/v 04/22/22 09:54 1
Chloromethane ND 0.50 ppb v/v 04/22/22 09:54 1
Dibromochloromethane ND 0.50 ppb v/v 04/22/22 09:54 1
Dichlorodifluoromethane ND 0.50 ppb v/v 04/22/22 09:54 1 Dichlorotetrafluoroethane ND 2.0 ppb v/v 04/22/22 09:54 1 Ethylbenzene ND 0.50 ppb v/v 04/22/22 09:54 1
Hexachloro-1,3-butadiene ND 1.5 ppb v/v 04/22/22 09:54 1 Isopropanol ND 5.0 ppb v/v 04/22/22 09:54 1
Methylene Chloride ND 5.0 ppb v/v 04/22/22 09:54 1
Methyl-t-Butyl Ether (MTBE) ND 2.0 ppb v/v 04/22/22 09:54 1 n-Butylbenzene ND 1.5 ppb v/v 04/22/22 09:54 1
o-Xylene ND 0.50 ppb v/v 04/22/22 09:54 1
m,p-Xylene ND 2.0 ppb v/v 04/22/22 09:54 1
sec-Butylbenzene ND 1.5 ppb v/v 04/22/22 09:54 1
Styrene ND 1.5 ppb v/v 04/22/22 09:54 1
trans-1,2-Dichloroethene ND 0.50 ppb v/v 04/22/22 09:54 1 trans-1,3-Dichloropropene ND 1.0 ppb v/v 04/22/22 09:54 1 tert-Butylbenzene ND 1.5 ppb v/v 04/22/22 09:54 1
Tetrachloroethene ND 0.50 ppb v/v 04/22/22 09:54 1
Toluene 1.1 0.50 ppb v/v 04/22/22 09:54 1
Trichloroethene ND 0.50 ppb v/v 04/22/22 09:54 1
Trichlorofluoromethane 1.9 1.0 ppb v/v 04/22/22 09:54 1 Vinyl acetate ND 2.0 ppb v/v 04/22/22 09:54 1
Vinyl chloride ND 0.50 ppb v/v 04/22/22 09:54 1
RL MDL
1,1,1-Trichloroethane ND 2.7 ug/m3 04/22/22 09:54 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 6.9 ug/m3 04/22/22 09:54 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 11 ug/m3 04/22/22 09:54 1 1,1,2-Trichloroethane ND 2.7 ug/m3 04/22/22 09:54 1
1,1-Dichloroethane ND 2.0 ug/m3 04/22/22 09:54 1
1,1-Dichloroethene ND 2.0 ug/m3 04/22/22 09:54 1
1,1-Difluoroethane ND 5.4 ug/m3 04/22/22 09:54 1
1,2,4-Trichlorobenzene ND 15 ug/m3 04/22/22 09:54 1
1,2,4-Trimethylbenzene ND 7.4 ug/m3 04/22/22 09:54 1
1,2-Dibromo-3-Chloropropane ND 14 ug/m3 04/22/22 09:54 1 1,2-Dibromoethane ND 3.8 ug/m3 04/22/22 09:54 1
1,2-Dichlorobenzene ND 3.0 ug/m3 04/22/22 09:54 1
1,2-Dichloroethane ND 2.0 ug/m3 04/22/22 09:54 1
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1769
Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-4-15 Lab Sample ID: 570-93118-7
Date Collected: 04/18/22 10:24 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
1,2-Dichloropropane ND 2.3 ug/m3 04/22/22 09:54 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,3,5-Trimethylbenzene ND 2.5 ug/m3 04/22/22 09:54 1
1,3-Dichlorobenzene ND 3.0 ug/m3 04/22/22 09:54 1
1,4-Dichlorobenzene ND 3.0 ug/m3 04/22/22 09:54 1
2-Butanone 4.9 4.4 ug/m3 04/22/22 09:54 1
2-Hexanone ND 6.1 ug/m3 04/22/22 09:54 1
4-Ethyltoluene ND 2.5 ug/m3 04/22/22 09:54 1
4-Methyl-2-pentanone ND 6.1 ug/m3 04/22/22 09:54 1
Acetone 27 4.8 ug/m3 04/22/22 09:54 1
Benzene ND 1.6 ug/m3 04/22/22 09:54 1
Benzyl chloride ND 7.8 ug/m3 04/22/22 09:54 1
Bromodichloromethane ND 3.4 ug/m3 04/22/22 09:54 1
Bromoform ND 5.2 ug/m3 04/22/22 09:54 1
Bromomethane ND 1.9 ug/m3 04/22/22 09:54 1
cis-1,2-Dichloroethene ND 2.0 ug/m3 04/22/22 09:54 1
cis-1,3-Dichloropropene ND 2.3 ug/m3 04/22/22 09:54 1
Carbon disulfide ND 6.2 ug/m3 04/22/22 09:54 1
Carbon tetrachloride ND 3.1 ug/m3 04/22/22 09:54 1
Chlorobenzene ND 2.3 ug/m3 04/22/22 09:54 1
Chloroethane ND 1.3 ug/m3 04/22/22 09:54 1
Chloroform ND 2.4 ug/m3 04/22/22 09:54 1
Chloromethane ND 1.0 ug/m3 04/22/22 09:54 1
Dibromochloromethane ND 4.3 ug/m3 04/22/22 09:54 1
Dichlorodifluoromethane ND 2.5 ug/m3 04/22/22 09:54 1
Dichlorotetrafluoroethane ND 14 ug/m3 04/22/22 09:54 1
Ethylbenzene ND 2.2 ug/m3 04/22/22 09:54 1
Hexachloro-1,3-butadiene ND 16 ug/m3 04/22/22 09:54 1
Isopropanol ND 12 ug/m3 04/22/22 09:54 1
Methylene Chloride ND 17 ug/m3 04/22/22 09:54 1
Methyl-t-Butyl Ether (MTBE) ND 7.2 ug/m3 04/22/22 09:54 1 n-Butylbenzene ND 8.2 ug/m3 04/22/22 09:54 1
o-Xylene ND 2.2 ug/m3 04/22/22 09:54 1
m,p-Xylene ND 8.7 ug/m3 04/22/22 09:54 1
sec-Butylbenzene ND 8.2 ug/m3 04/22/22 09:54 1
Styrene ND 6.4 ug/m3 04/22/22 09:54 1
trans-1,2-Dichloroethene ND 2.0 ug/m3 04/22/22 09:54 1
trans-1,3-Dichloropropene ND 4.5 ug/m3 04/22/22 09:54 1 tert-Butylbenzene ND 8.2 ug/m3 04/22/22 09:54 1
Tetrachloroethene ND 3.4 ug/m3 04/22/22 09:54 1
Toluene 4.2 1.9 ug/m3 04/22/22 09:54 1
Trichloroethene ND 2.7 ug/m3 04/22/22 09:54 1
Trichlorofluoromethane 11 5.6 ug/m3 04/22/22 09:54 1
Vinyl acetate ND 7.0 ug/m3 04/22/22 09:54 1
Vinyl chloride ND 1.3 ug/m3 04/22/22 09:54 1
1,2-Dichloroethane-d4 (Surr) 100 66 - 132 04/22/22 09:54 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 120 70 - 130 04/22/22 09:54 1 Toluene-d8 (Surr) 114 70 - 130 04/22/22 09:54 1
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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air Client Sample ID: SV-6-5 Lab Sample ID: 570-93118-8
Date Collected: 04/18/22 11:26 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
1,1,1-Trichloroethane ND 0.50 ppb v/v 04/22/22 10:42 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 1.0 ppb v/v 04/22/22 10:42 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 1.5 ppb v/v 04/22/22 10:42 1 1,1,2-Trichloroethane ND 0.50 ppb v/v 04/22/22 10:42 1
1,1-Dichloroethane ND 0.50 ppb v/v 04/22/22 10:42 1
1,1-Dichloroethene ND 0.50 ppb v/v 04/22/22 10:42 1
1,1-Difluoroethane ND 2.0 ppb v/v 04/22/22 10:42 1
1,2,4-Trichlorobenzene ND 2.0 ppb v/v 04/22/22 10:42 1
1,2,4-Trimethylbenzene ND 1.5 ppb v/v 04/22/22 10:42 1
1,2-Dibromo-3-Chloropropane ND 1.5 ppb v/v 04/22/22 10:42 1 1,2-Dibromoethane ND 0.50 ppb v/v 04/22/22 10:42 1
1,2-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 10:42 1
1,2-Dichloroethane ND 0.50 ppb v/v 04/22/22 10:42 1
1,2-Dichloropropane ND 0.50 ppb v/v 04/22/22 10:42 1
1,3,5-Trimethylbenzene ND 0.50 ppb v/v 04/22/22 10:42 1 1,3-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 10:42 1
1,4-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 10:42 1
2-Butanone ND 1.5 ppb v/v 04/22/22 10:42 1
2-Hexanone ND 1.5 ppb v/v 04/22/22 10:42 1
4-Ethyltoluene ND 0.50 ppb v/v 04/22/22 10:42 1
4-Methyl-2-pentanone ND 1.5 ppb v/v 04/22/22 10:42 1
Acetone 2.5 2.0 ppb v/v 04/22/22 10:42 1
Benzene ND 0.50 ppb v/v 04/22/22 10:42 1
Benzyl chloride ND 1.5 ppb v/v 04/22/22 10:42 1
Bromodichloromethane ND 0.50 ppb v/v 04/22/22 10:42 1
Bromoform ND 0.50 ppb v/v 04/22/22 10:42 1
Bromomethane ND 0.50 ppb v/v 04/22/22 10:42 1
cis-1,2-Dichloroethene ND 0.50 ppb v/v 04/22/22 10:42 1 cis-1,3-Dichloropropene ND 0.50 ppb v/v 04/22/22 10:42 1 Carbon disulfide ND 2.0 ppb v/v 04/22/22 10:42 1
Carbon tetrachloride ND 0.50 ppb v/v 04/22/22 10:42 1
Chlorobenzene ND 0.50 ppb v/v 04/22/22 10:42 1
Chloroethane ND 0.50 ppb v/v 04/22/22 10:42 1
Chloroform ND 0.50 ppb v/v 04/22/22 10:42 1
Chloromethane ND 0.50 ppb v/v 04/22/22 10:42 1
Dibromochloromethane ND 0.50 ppb v/v 04/22/22 10:42 1
Dichlorodifluoromethane ND 0.50 ppb v/v 04/22/22 10:42 1 Dichlorotetrafluoroethane ND 2.0 ppb v/v 04/22/22 10:42 1 Ethylbenzene ND 0.50 ppb v/v 04/22/22 10:42 1
Hexachloro-1,3-butadiene ND 1.5 ppb v/v 04/22/22 10:42 1 Isopropanol ND 5.0 ppb v/v 04/22/22 10:42 1
Methylene Chloride ND 5.0 ppb v/v 04/22/22 10:42 1
Methyl-t-Butyl Ether (MTBE) ND 2.0 ppb v/v 04/22/22 10:42 1 n-Butylbenzene ND 1.5 ppb v/v 04/22/22 10:42 1
o-Xylene ND 0.50 ppb v/v 04/22/22 10:42 1
m,p-Xylene ND 2.0 ppb v/v 04/22/22 10:42 1
sec-Butylbenzene ND 1.5 ppb v/v 04/22/22 10:42 1
Styrene ND 1.5 ppb v/v 04/22/22 10:42 1
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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-6-5 Lab Sample ID: 570-93118-8
Date Collected: 04/18/22 11:26 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
trans-1,2-Dichloroethene ND 0.50 ppb v/v 04/22/22 10:42 1 Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac trans-1,3-Dichloropropene ND 1.0 ppb v/v 04/22/22 10:42 1 tert-Butylbenzene ND 1.5 ppb v/v 04/22/22 10:42 1
Tetrachloroethene ND 0.50 ppb v/v 04/22/22 10:42 1
Toluene ND 0.50 ppb v/v 04/22/22 10:42 1
Trichloroethene ND 0.50 ppb v/v 04/22/22 10:42 1
Trichlorofluoromethane ND 1.0 ppb v/v 04/22/22 10:42 1
Vinyl acetate ND 2.0 ppb v/v 04/22/22 10:42 1
Vinyl chloride ND 0.50 ppb v/v 04/22/22 10:42 1
RL MDL
1,1,1-Trichloroethane ND 2.7 ug/m3 04/22/22 10:42 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 6.9 ug/m3 04/22/22 10:42 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 11 ug/m3 04/22/22 10:42 1 1,1,2-Trichloroethane ND 2.7 ug/m3 04/22/22 10:42 1
1,1-Dichloroethane ND 2.0 ug/m3 04/22/22 10:42 1
1,1-Dichloroethene ND 2.0 ug/m3 04/22/22 10:42 1
1,1-Difluoroethane ND 5.4 ug/m3 04/22/22 10:42 1
1,2,4-Trichlorobenzene ND 15 ug/m3 04/22/22 10:42 1
1,2,4-Trimethylbenzene ND 7.4 ug/m3 04/22/22 10:42 1
1,2-Dibromo-3-Chloropropane ND 14 ug/m3 04/22/22 10:42 1 1,2-Dibromoethane ND 3.8 ug/m3 04/22/22 10:42 1
1,2-Dichlorobenzene ND 3.0 ug/m3 04/22/22 10:42 1
1,2-Dichloroethane ND 2.0 ug/m3 04/22/22 10:42 1
1,2-Dichloropropane ND 2.3 ug/m3 04/22/22 10:42 1
1,3,5-Trimethylbenzene ND 2.5 ug/m3 04/22/22 10:42 1
1,3-Dichlorobenzene ND 3.0 ug/m3 04/22/22 10:42 1
1,4-Dichlorobenzene ND 3.0 ug/m3 04/22/22 10:42 1
2-Butanone ND 4.4 ug/m3 04/22/22 10:42 1
2-Hexanone ND 6.1 ug/m3 04/22/22 10:42 1
4-Ethyltoluene ND 2.5 ug/m3 04/22/22 10:42 1
4-Methyl-2-pentanone ND 6.1 ug/m3 04/22/22 10:42 1
Acetone 6.0 4.8 ug/m3 04/22/22 10:42 1
Benzene ND 1.6 ug/m3 04/22/22 10:42 1
Benzyl chloride ND 7.8 ug/m3 04/22/22 10:42 1
Bromodichloromethane ND 3.4 ug/m3 04/22/22 10:42 1
Bromoform ND 5.2 ug/m3 04/22/22 10:42 1
Bromomethane ND 1.9 ug/m3 04/22/22 10:42 1
cis-1,2-Dichloroethene ND 2.0 ug/m3 04/22/22 10:42 1
cis-1,3-Dichloropropene ND 2.3 ug/m3 04/22/22 10:42 1
Carbon disulfide ND 6.2 ug/m3 04/22/22 10:42 1
Carbon tetrachloride ND 3.1 ug/m3 04/22/22 10:42 1
Chlorobenzene ND 2.3 ug/m3 04/22/22 10:42 1
Chloroethane ND 1.3 ug/m3 04/22/22 10:42 1
Chloroform ND 2.4 ug/m3 04/22/22 10:42 1
Chloromethane ND 1.0 ug/m3 04/22/22 10:42 1
Dibromochloromethane ND 4.3 ug/m3 04/22/22 10:42 1
Dichlorodifluoromethane ND 2.5 ug/m3 04/22/22 10:42 1
Dichlorotetrafluoroethane ND 14 ug/m3 04/22/22 10:42 1
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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-6-5 Lab Sample ID: 570-93118-8
Date Collected: 04/18/22 11:26 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
Ethylbenzene ND 2.2 ug/m3 04/22/22 10:42 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac Hexachloro-1,3-butadiene ND 16 ug/m3 04/22/22 10:42 1
Isopropanol ND 12 ug/m3 04/22/22 10:42 1
Methylene Chloride ND 17 ug/m3 04/22/22 10:42 1
Methyl-t-Butyl Ether (MTBE) ND 7.2 ug/m3 04/22/22 10:42 1 n-Butylbenzene ND 8.2 ug/m3 04/22/22 10:42 1
o-Xylene ND 2.2 ug/m3 04/22/22 10:42 1
m,p-Xylene ND 8.7 ug/m3 04/22/22 10:42 1
sec-Butylbenzene ND 8.2 ug/m3 04/22/22 10:42 1
Styrene ND 6.4 ug/m3 04/22/22 10:42 1
trans-1,2-Dichloroethene ND 2.0 ug/m3 04/22/22 10:42 1
trans-1,3-Dichloropropene ND 4.5 ug/m3 04/22/22 10:42 1 tert-Butylbenzene ND 8.2 ug/m3 04/22/22 10:42 1
Tetrachloroethene ND 3.4 ug/m3 04/22/22 10:42 1
Toluene ND 1.9 ug/m3 04/22/22 10:42 1
Trichloroethene ND 2.7 ug/m3 04/22/22 10:42 1
Trichlorofluoromethane ND 5.6 ug/m3 04/22/22 10:42 1
Vinyl acetate ND 7.0 ug/m3 04/22/22 10:42 1
Vinyl chloride ND 1.3 ug/m3 04/22/22 10:42 1
1,2-Dichloroethane-d4 (Surr) 99 66 - 132 04/22/22 10:42 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 119 70 - 130 04/22/22 10:42 1 Toluene-d8 (Surr) 117 70 - 130 04/22/22 10:42 1
Client Sample ID: SV-6-15 Lab Sample ID: 570-93118-9
Date Collected: 04/18/22 11:13 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
1,1,1-Trichloroethane ND 0.50 ppb v/v 04/22/22 11:40 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 1.0 ppb v/v 04/22/22 11:40 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 1.5 ppb v/v 04/22/22 11:40 1 1,1,2-Trichloroethane ND 0.50 ppb v/v 04/22/22 11:40 1
1,1-Dichloroethane ND 0.50 ppb v/v 04/22/22 11:40 1
1,1-Dichloroethene ND 0.50 ppb v/v 04/22/22 11:40 1
1,1-Difluoroethane ND 2.0 ppb v/v 04/22/22 11:40 1
1,2,4-Trichlorobenzene ND 2.0 ppb v/v 04/22/22 11:40 1
1,2,4-Trimethylbenzene ND 1.5 ppb v/v 04/22/22 11:40 1
1,2-Dibromo-3-Chloropropane ND 1.5 ppb v/v 04/22/22 11:40 1 1,2-Dibromoethane ND 0.50 ppb v/v 04/22/22 11:40 1
1,2-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 11:40 1
1,2-Dichloroethane ND 0.50 ppb v/v 04/22/22 11:40 1
1,2-Dichloropropane ND 0.50 ppb v/v 04/22/22 11:40 1
1,3,5-Trimethylbenzene ND 0.50 ppb v/v 04/22/22 11:40 1 1,3-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 11:40 1
1,4-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 11:40 1
2-Butanone 5.7 1.5 ppb v/v 04/22/22 11:40 1
2-Hexanone ND 1.5 ppb v/v 04/22/22 11:40 1
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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-6-15 Lab Sample ID: 570-93118-9
Date Collected: 04/18/22 11:13 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
4-Ethyltoluene ND 0.50 ppb v/v 04/22/22 11:40 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 4-Methyl-2-pentanone ND 1.5 ppb v/v 04/22/22 11:40 1
Acetone 43 2.0 ppb v/v 04/22/22 11:40 1
Benzene ND 0.50 ppb v/v 04/22/22 11:40 1
Benzyl chloride ND 1.5 ppb v/v 04/22/22 11:40 1
Bromodichloromethane ND 0.50 ppb v/v 04/22/22 11:40 1
Bromoform ND 0.50 ppb v/v 04/22/22 11:40 1
Bromomethane ND 0.50 ppb v/v 04/22/22 11:40 1
cis-1,2-Dichloroethene ND 0.50 ppb v/v 04/22/22 11:40 1 cis-1,3-Dichloropropene ND 0.50 ppb v/v 04/22/22 11:40 1 Carbon disulfide ND 2.0 ppb v/v 04/22/22 11:40 1
Carbon tetrachloride ND 0.50 ppb v/v 04/22/22 11:40 1
Chlorobenzene ND 0.50 ppb v/v 04/22/22 11:40 1
Chloroethane ND 0.50 ppb v/v 04/22/22 11:40 1
Chloroform ND 0.50 ppb v/v 04/22/22 11:40 1
Chloromethane ND 0.50 ppb v/v 04/22/22 11:40 1
Dibromochloromethane ND 0.50 ppb v/v 04/22/22 11:40 1
Dichlorodifluoromethane ND 0.50 ppb v/v 04/22/22 11:40 1 Dichlorotetrafluoroethane ND 2.0 ppb v/v 04/22/22 11:40 1 Ethylbenzene ND 0.50 ppb v/v 04/22/22 11:40 1
Hexachloro-1,3-butadiene ND 1.5 ppb v/v 04/22/22 11:40 1 Isopropanol 5.7 5.0 ppb v/v 04/22/22 11:40 1
Methylene Chloride ND 5.0 ppb v/v 04/22/22 11:40 1
Methyl-t-Butyl Ether (MTBE) ND 2.0 ppb v/v 04/22/22 11:40 1 n-Butylbenzene ND 1.5 ppb v/v 04/22/22 11:40 1
o-Xylene 0.65 0.50 ppb v/v 04/22/22 11:40 1
m,p-Xylene ND 2.0 ppb v/v 04/22/22 11:40 1
sec-Butylbenzene ND 1.5 ppb v/v 04/22/22 11:40 1
Styrene ND 1.5 ppb v/v 04/22/22 11:40 1
trans-1,2-Dichloroethene ND 0.50 ppb v/v 04/22/22 11:40 1 trans-1,3-Dichloropropene ND 1.0 ppb v/v 04/22/22 11:40 1 tert-Butylbenzene ND 1.5 ppb v/v 04/22/22 11:40 1
Tetrachloroethene 0.91 0.50 ppb v/v 04/22/22 11:40 1
Toluene 1.7 0.50 ppb v/v 04/22/22 11:40 1
Trichloroethene ND 0.50 ppb v/v 04/22/22 11:40 1
Trichlorofluoromethane 8.7 1.0 ppb v/v 04/22/22 11:40 1 Vinyl acetate ND 2.0 ppb v/v 04/22/22 11:40 1
Vinyl chloride ND 0.50 ppb v/v 04/22/22 11:40 1
RL MDL
1,1,1-Trichloroethane ND 2.7 ug/m3 04/22/22 11:40 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 6.9 ug/m3 04/22/22 11:40 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 11 ug/m3 04/22/22 11:40 1 1,1,2-Trichloroethane ND 2.7 ug/m3 04/22/22 11:40 1
1,1-Dichloroethane ND 2.0 ug/m3 04/22/22 11:40 1
1,1-Dichloroethene ND 2.0 ug/m3 04/22/22 11:40 1
1,1-Difluoroethane ND 5.4 ug/m3 04/22/22 11:40 1
1,2,4-Trichlorobenzene ND 15 ug/m3 04/22/22 11:40 1
1,2,4-Trimethylbenzene ND 7.4 ug/m3 04/22/22 11:40 1
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1774
Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-6-15 Lab Sample ID: 570-93118-9
Date Collected: 04/18/22 11:13 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
1,2-Dibromo-3-Chloropropane ND 14 ug/m3 04/22/22 11:40 1 Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,2-Dibromoethane ND 3.8 ug/m3 04/22/22 11:40 1
1,2-Dichlorobenzene ND 3.0 ug/m3 04/22/22 11:40 1
1,2-Dichloroethane ND 2.0 ug/m3 04/22/22 11:40 1
1,2-Dichloropropane ND 2.3 ug/m3 04/22/22 11:40 1
1,3,5-Trimethylbenzene ND 2.5 ug/m3 04/22/22 11:40 1
1,3-Dichlorobenzene ND 3.0 ug/m3 04/22/22 11:40 1
1,4-Dichlorobenzene ND 3.0 ug/m3 04/22/22 11:40 1
2-Butanone 17 4.4 ug/m3 04/22/22 11:40 1
2-Hexanone ND 6.1 ug/m3 04/22/22 11:40 1
4-Ethyltoluene ND 2.5 ug/m3 04/22/22 11:40 1
4-Methyl-2-pentanone ND 6.1 ug/m3 04/22/22 11:40 1
Acetone 100 4.8 ug/m3 04/22/22 11:40 1
Benzene ND 1.6 ug/m3 04/22/22 11:40 1
Benzyl chloride ND 7.8 ug/m3 04/22/22 11:40 1
Bromodichloromethane ND 3.4 ug/m3 04/22/22 11:40 1
Bromoform ND 5.2 ug/m3 04/22/22 11:40 1
Bromomethane ND 1.9 ug/m3 04/22/22 11:40 1
cis-1,2-Dichloroethene ND 2.0 ug/m3 04/22/22 11:40 1
cis-1,3-Dichloropropene ND 2.3 ug/m3 04/22/22 11:40 1
Carbon disulfide ND 6.2 ug/m3 04/22/22 11:40 1
Carbon tetrachloride ND 3.1 ug/m3 04/22/22 11:40 1
Chlorobenzene ND 2.3 ug/m3 04/22/22 11:40 1
Chloroethane ND 1.3 ug/m3 04/22/22 11:40 1
Chloroform ND 2.4 ug/m3 04/22/22 11:40 1
Chloromethane ND 1.0 ug/m3 04/22/22 11:40 1
Dibromochloromethane ND 4.3 ug/m3 04/22/22 11:40 1
Dichlorodifluoromethane ND 2.5 ug/m3 04/22/22 11:40 1
Dichlorotetrafluoroethane ND 14 ug/m3 04/22/22 11:40 1
Ethylbenzene ND 2.2 ug/m3 04/22/22 11:40 1
Hexachloro-1,3-butadiene ND 16 ug/m3 04/22/22 11:40 1
Isopropanol 14 12 ug/m3 04/22/22 11:40 1
Methylene Chloride ND 17 ug/m3 04/22/22 11:40 1
Methyl-t-Butyl Ether (MTBE) ND 7.2 ug/m3 04/22/22 11:40 1 n-Butylbenzene ND 8.2 ug/m3 04/22/22 11:40 1
o-Xylene 2.8 2.2 ug/m3 04/22/22 11:40 1
m,p-Xylene ND 8.7 ug/m3 04/22/22 11:40 1
sec-Butylbenzene ND 8.2 ug/m3 04/22/22 11:40 1
Styrene ND 6.4 ug/m3 04/22/22 11:40 1
trans-1,2-Dichloroethene ND 2.0 ug/m3 04/22/22 11:40 1
trans-1,3-Dichloropropene ND 4.5 ug/m3 04/22/22 11:40 1 tert-Butylbenzene ND 8.2 ug/m3 04/22/22 11:40 1
Tetrachloroethene 6.1 3.4 ug/m3 04/22/22 11:40 1
Toluene 6.3 1.9 ug/m3 04/22/22 11:40 1
Trichloroethene ND 2.7 ug/m3 04/22/22 11:40 1
Trichlorofluoromethane 49 5.6 ug/m3 04/22/22 11:40 1
Vinyl acetate ND 7.0 ug/m3 04/22/22 11:40 1
Vinyl chloride ND 1.3 ug/m3 04/22/22 11:40 1
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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) 1,2-Dichloroethane-d4 (Surr) 100 66 - 132 04/22/22 11:40 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 115 70 - 130 04/22/22 11:40 1 Toluene-d8 (Surr) 117 70 - 130 04/22/22 11:40 1
Client Sample ID: SV-9-5 Lab Sample ID: 570-93118-10
Date Collected: 04/18/22 12:47 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
1,1,1-Trichloroethane ND 0.50 ppb v/v 04/22/22 12:34 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 1.0 ppb v/v 04/22/22 12:34 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 1.5 ppb v/v 04/22/22 12:34 1 1,1,2-Trichloroethane ND 0.50 ppb v/v 04/22/22 12:34 1
1,1-Dichloroethane ND 0.50 ppb v/v 04/22/22 12:34 1
1,1-Dichloroethene ND 0.50 ppb v/v 04/22/22 12:34 1
1,1-Difluoroethane ND 2.0 ppb v/v 04/22/22 12:34 1
1,2,4-Trichlorobenzene ND 2.0 ppb v/v 04/22/22 12:34 1
1,2,4-Trimethylbenzene ND 1.5 ppb v/v 04/22/22 12:34 1
1,2-Dibromo-3-Chloropropane ND 1.5 ppb v/v 04/22/22 12:34 1 1,2-Dibromoethane ND 0.50 ppb v/v 04/22/22 12:34 1
1,2-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 12:34 1
1,2-Dichloroethane ND 0.50 ppb v/v 04/22/22 12:34 1
1,2-Dichloropropane ND 0.50 ppb v/v 04/22/22 12:34 1
1,3,5-Trimethylbenzene ND 0.50 ppb v/v 04/22/22 12:34 1 1,3-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 12:34 1
1,4-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 12:34 1
2-Butanone 3.0 1.5 ppb v/v 04/22/22 12:34 1
2-Hexanone ND 1.5 ppb v/v 04/22/22 12:34 1
4-Ethyltoluene ND 0.50 ppb v/v 04/22/22 12:34 1
4-Methyl-2-pentanone ND 1.5 ppb v/v 04/22/22 12:34 1
Acetone 14 2.0 ppb v/v 04/22/22 12:34 1
Benzene ND 0.50 ppb v/v 04/22/22 12:34 1
Benzyl chloride ND 1.5 ppb v/v 04/22/22 12:34 1
Bromodichloromethane ND 0.50 ppb v/v 04/22/22 12:34 1
Bromoform ND 0.50 ppb v/v 04/22/22 12:34 1
Bromomethane ND 0.50 ppb v/v 04/22/22 12:34 1
cis-1,2-Dichloroethene ND 0.50 ppb v/v 04/22/22 12:34 1 cis-1,3-Dichloropropene ND 0.50 ppb v/v 04/22/22 12:34 1 Carbon disulfide ND 2.0 ppb v/v 04/22/22 12:34 1
Carbon tetrachloride ND 0.50 ppb v/v 04/22/22 12:34 1
Chlorobenzene ND 0.50 ppb v/v 04/22/22 12:34 1
Chloroethane ND 0.50 ppb v/v 04/22/22 12:34 1
Chloroform ND 0.50 ppb v/v 04/22/22 12:34 1
Chloromethane ND 0.50 ppb v/v 04/22/22 12:34 1
Dibromochloromethane ND 0.50 ppb v/v 04/22/22 12:34 1
Dichlorodifluoromethane ND 0.50 ppb v/v 04/22/22 12:34 1 Dichlorotetrafluoroethane ND 2.0 ppb v/v 04/22/22 12:34 1 Ethylbenzene ND 0.50 ppb v/v 04/22/22 12:34 1
Hexachloro-1,3-butadiene ND 1.5 ppb v/v 04/22/22 12:34 1 Isopropanol ND 5.0 ppb v/v 04/22/22 12:34 1
Methylene Chloride ND 5.0 ppb v/v 04/22/22 12:34 1
Methyl-t-Butyl Ether (MTBE) ND 2.0 ppb v/v 04/22/22 12:34 1 Eurofins Calscience

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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-9-5 Lab Sample ID: 570-93118-10
Date Collected: 04/18/22 12:47 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
n-Butylbenzene ND 1.5 ppb v/v 04/22/22 12:34 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac o-Xylene ND 0.50 ppb v/v 04/22/22 12:34 1
m,p-Xylene ND 2.0 ppb v/v 04/22/22 12:34 1
sec-Butylbenzene ND 1.5 ppb v/v 04/22/22 12:34 1
Styrene ND 1.5 ppb v/v 04/22/22 12:34 1
trans-1,2-Dichloroethene ND 0.50 ppb v/v 04/22/22 12:34 1 trans-1,3-Dichloropropene ND 1.0 ppb v/v 04/22/22 12:34 1 tert-Butylbenzene ND 1.5 ppb v/v 04/22/22 12:34 1
Tetrachloroethene 13 0.50 ppb v/v 04/22/22 12:34 1
Toluene 0.54 0.50 ppb v/v 04/22/22 12:34 1
Trichloroethene ND 0.50 ppb v/v 04/22/22 12:34 1
Trichlorofluoromethane 2.3 1.0 ppb v/v 04/22/22 12:34 1 Vinyl acetate ND 2.0 ppb v/v 04/22/22 12:34 1
Vinyl chloride ND 0.50 ppb v/v 04/22/22 12:34 1
RL MDL
1,1,1-Trichloroethane ND 2.7 ug/m3 04/22/22 12:34 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 6.9 ug/m3 04/22/22 12:34 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 11 ug/m3 04/22/22 12:34 1 1,1,2-Trichloroethane ND 2.7 ug/m3 04/22/22 12:34 1
1,1-Dichloroethane ND 2.0 ug/m3 04/22/22 12:34 1
1,1-Dichloroethene ND 2.0 ug/m3 04/22/22 12:34 1
1,1-Difluoroethane ND 5.4 ug/m3 04/22/22 12:34 1
1,2,4-Trichlorobenzene ND 15 ug/m3 04/22/22 12:34 1
1,2,4-Trimethylbenzene ND 7.4 ug/m3 04/22/22 12:34 1
1,2-Dibromo-3-Chloropropane ND 14 ug/m3 04/22/22 12:34 1 1,2-Dibromoethane ND 3.8 ug/m3 04/22/22 12:34 1
1,2-Dichlorobenzene ND 3.0 ug/m3 04/22/22 12:34 1
1,2-Dichloroethane ND 2.0 ug/m3 04/22/22 12:34 1
1,2-Dichloropropane ND 2.3 ug/m3 04/22/22 12:34 1
1,3,5-Trimethylbenzene ND 2.5 ug/m3 04/22/22 12:34 1
1,3-Dichlorobenzene ND 3.0 ug/m3 04/22/22 12:34 1
1,4-Dichlorobenzene ND 3.0 ug/m3 04/22/22 12:34 1
2-Butanone 8.7 4.4 ug/m3 04/22/22 12:34 1
2-Hexanone ND 6.1 ug/m3 04/22/22 12:34 1
4-Ethyltoluene ND 2.5 ug/m3 04/22/22 12:34 1
4-Methyl-2-pentanone ND 6.1 ug/m3 04/22/22 12:34 1
Acetone 34 4.8 ug/m3 04/22/22 12:34 1
Benzene ND 1.6 ug/m3 04/22/22 12:34 1
Benzyl chloride ND 7.8 ug/m3 04/22/22 12:34 1
Bromodichloromethane ND 3.4 ug/m3 04/22/22 12:34 1
Bromoform ND 5.2 ug/m3 04/22/22 12:34 1
Bromomethane ND 1.9 ug/m3 04/22/22 12:34 1
cis-1,2-Dichloroethene ND 2.0 ug/m3 04/22/22 12:34 1
cis-1,3-Dichloropropene ND 2.3 ug/m3 04/22/22 12:34 1
Carbon disulfide ND 6.2 ug/m3 04/22/22 12:34 1
Carbon tetrachloride ND 3.1 ug/m3 04/22/22 12:34 1
Chlorobenzene ND 2.3 ug/m3 04/22/22 12:34 1
Chloroethane ND 1.3 ug/m3 04/22/22 12:34 1
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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-9-5 Lab Sample ID: 570-93118-10
Date Collected: 04/18/22 12:47 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
Chloroform ND 2.4 ug/m3 04/22/22 12:34 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac Chloromethane ND 1.0 ug/m3 04/22/22 12:34 1
Dibromochloromethane ND 4.3 ug/m3 04/22/22 12:34 1
Dichlorodifluoromethane ND 2.5 ug/m3 04/22/22 12:34 1
Dichlorotetrafluoroethane ND 14 ug/m3 04/22/22 12:34 1
Ethylbenzene ND 2.2 ug/m3 04/22/22 12:34 1
Hexachloro-1,3-butadiene ND 16 ug/m3 04/22/22 12:34 1
Isopropanol ND 12 ug/m3 04/22/22 12:34 1
Methylene Chloride ND 17 ug/m3 04/22/22 12:34 1
Methyl-t-Butyl Ether (MTBE) ND 7.2 ug/m3 04/22/22 12:34 1 n-Butylbenzene ND 8.2 ug/m3 04/22/22 12:34 1
o-Xylene ND 2.2 ug/m3 04/22/22 12:34 1
m,p-Xylene ND 8.7 ug/m3 04/22/22 12:34 1
sec-Butylbenzene ND 8.2 ug/m3 04/22/22 12:34 1
Styrene ND 6.4 ug/m3 04/22/22 12:34 1
trans-1,2-Dichloroethene ND 2.0 ug/m3 04/22/22 12:34 1
trans-1,3-Dichloropropene ND 4.5 ug/m3 04/22/22 12:34 1 tert-Butylbenzene ND 8.2 ug/m3 04/22/22 12:34 1
Tetrachloroethene 86 3.4 ug/m3 04/22/22 12:34 1
Toluene 2.0 1.9 ug/m3 04/22/22 12:34 1
Trichloroethene ND 2.7 ug/m3 04/22/22 12:34 1
Trichlorofluoromethane 13 5.6 ug/m3 04/22/22 12:34 1
Vinyl acetate ND 7.0 ug/m3 04/22/22 12:34 1
Vinyl chloride ND 1.3 ug/m3 04/22/22 12:34 1
1,2-Dichloroethane-d4 (Surr) 100 66 - 132 04/22/22 12:34 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 114 70 - 130 04/22/22 12:34 1 Toluene-d8 (Surr) 107 70 - 130 04/22/22 12:34 1
Client Sample ID: SV-9-15 Lab Sample ID: 570-93118-11
Date Collected: 04/18/22 13:39 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
1,1,1-Trichloroethane ND 0.50 ppb v/v 04/22/22 22:42 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 1.0 ppb v/v 04/22/22 22:42 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 1.5 ppb v/v 04/22/22 22:42 1 1,1,2-Trichloroethane ND 0.50 ppb v/v 04/22/22 22:42 1
1,1-Dichloroethane ND 0.50 ppb v/v 04/22/22 22:42 1
1,1-Dichloroethene ND 0.50 ppb v/v 04/22/22 22:42 1
1,1-Difluoroethane ND 2.0 ppb v/v 04/22/22 22:42 1
1,2,4-Trichlorobenzene ND 2.0 ppb v/v 04/22/22 22:42 1
1,2,4-Trimethylbenzene ND 1.5 ppb v/v 04/22/22 22:42 1
1,2-Dibromo-3-Chloropropane ND 1.5 ppb v/v 04/22/22 22:42 1 1,2-Dibromoethane ND 0.50 ppb v/v 04/22/22 22:42 1
1,2-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 22:42 1
1,2-Dichloroethane ND 0.50 ppb v/v 04/22/22 22:42 1
1,2-Dichloropropane ND 0.50 ppb v/v 04/22/22 22:42 1
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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-9-15 Lab Sample ID: 570-93118-11
Date Collected: 04/18/22 13:39 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
1,3,5-Trimethylbenzene ND 0.50 ppb v/v 04/22/22 22:42 1 Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,3-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 22:42 1
1,4-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 22:42 1
2-Butanone 5.3 1.5 ppb v/v 04/22/22 22:42 1
2-Hexanone ND 1.5 ppb v/v 04/22/22 22:42 1
4-Ethyltoluene ND 0.50 ppb v/v 04/22/22 22:42 1
4-Methyl-2-pentanone ND 1.5 ppb v/v 04/22/22 22:42 1
Acetone 24 2.0 ppb v/v 04/22/22 22:42 1
Benzene ND 0.50 ppb v/v 04/22/22 22:42 1
Benzyl chloride ND *- 1.5 ppb v/v 04/22/22 22:42 1
Bromodichloromethane ND 0.50 ppb v/v 04/22/22 22:42 1
Bromoform ND 0.50 ppb v/v 04/22/22 22:42 1
Bromomethane ND 0.50 ppb v/v 04/22/22 22:42 1
cis-1,2-Dichloroethene ND 0.50 ppb v/v 04/22/22 22:42 1 cis-1,3-Dichloropropene ND 0.50 ppb v/v 04/22/22 22:42 1 Carbon disulfide ND 2.0 ppb v/v 04/22/22 22:42 1
Carbon tetrachloride ND 0.50 ppb v/v 04/22/22 22:42 1
Chlorobenzene ND 0.50 ppb v/v 04/22/22 22:42 1
Chloroethane ND 0.50 ppb v/v 04/22/22 22:42 1
Chloroform ND 0.50 ppb v/v 04/22/22 22:42 1
Chloromethane ND 0.50 ppb v/v 04/22/22 22:42 1
Dibromochloromethane ND 0.50 ppb v/v 04/22/22 22:42 1
Dichlorodifluoromethane ND 0.50 ppb v/v 04/22/22 22:42 1 Dichlorotetrafluoroethane ND 2.0 ppb v/v 04/22/22 22:42 1 Ethylbenzene ND 0.50 ppb v/v 04/22/22 22:42 1
Hexachloro-1,3-butadiene ND 1.5 ppb v/v 04/22/22 22:42 1 Isopropanol ND 5.0 ppb v/v 04/22/22 22:42 1
Methylene Chloride ND 5.0 ppb v/v 04/22/22 22:42 1
Methyl-t-Butyl Ether (MTBE) ND 2.0 ppb v/v 04/22/22 22:42 1 n-Butylbenzene ND 1.5 ppb v/v 04/22/22 22:42 1
o-Xylene ND 0.50 ppb v/v 04/22/22 22:42 1
m,p-Xylene ND 2.0 ppb v/v 04/22/22 22:42 1
sec-Butylbenzene ND 1.5 ppb v/v 04/22/22 22:42 1
Styrene ND 1.5 ppb v/v 04/22/22 22:42 1
trans-1,2-Dichloroethene ND 0.50 ppb v/v 04/22/22 22:42 1 trans-1,3-Dichloropropene ND 1.0 ppb v/v 04/22/22 22:42 1 tert-Butylbenzene ND 1.5 ppb v/v 04/22/22 22:42 1
Tetrachloroethene 0.83 0.50 ppb v/v 04/22/22 22:42 1
Toluene ND 0.50 ppb v/v 04/22/22 22:42 1
Trichloroethene ND 0.50 ppb v/v 04/22/22 22:42 1
Trichlorofluoromethane 3.2 1.0 ppb v/v 04/22/22 22:42 1 Vinyl acetate ND 2.0 ppb v/v 04/22/22 22:42 1
Vinyl chloride ND 0.50 ppb v/v 04/22/22 22:42 1
RL MDL
1,1,1-Trichloroethane ND 2.7 ug/m3 04/22/22 22:42 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 6.9 ug/m3 04/22/22 22:42 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 11 ug/m3 04/22/22 22:42 1 1,1,2-Trichloroethane ND 2.7 ug/m3 04/22/22 22:42 1
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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-9-15 Lab Sample ID: 570-93118-11
Date Collected: 04/18/22 13:39 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
1,1-Dichloroethane ND 2.0 ug/m3 04/22/22 22:42 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1-Dichloroethene ND 2.0 ug/m3 04/22/22 22:42 1
1,1-Difluoroethane ND 5.4 ug/m3 04/22/22 22:42 1
1,2,4-Trichlorobenzene ND 15 ug/m3 04/22/22 22:42 1
1,2,4-Trimethylbenzene ND 7.4 ug/m3 04/22/22 22:42 1
1,2-Dibromo-3-Chloropropane ND 14 ug/m3 04/22/22 22:42 1 1,2-Dibromoethane ND 3.8 ug/m3 04/22/22 22:42 1
1,2-Dichlorobenzene ND 3.0 ug/m3 04/22/22 22:42 1
1,2-Dichloroethane ND 2.0 ug/m3 04/22/22 22:42 1
1,2-Dichloropropane ND 2.3 ug/m3 04/22/22 22:42 1
1,3,5-Trimethylbenzene ND 2.5 ug/m3 04/22/22 22:42 1
1,3-Dichlorobenzene ND 3.0 ug/m3 04/22/22 22:42 1
1,4-Dichlorobenzene ND 3.0 ug/m3 04/22/22 22:42 1
2-Butanone 16 4.4 ug/m3 04/22/22 22:42 1
2-Hexanone ND 6.1 ug/m3 04/22/22 22:42 1
4-Ethyltoluene ND 2.5 ug/m3 04/22/22 22:42 1
4-Methyl-2-pentanone ND 6.1 ug/m3 04/22/22 22:42 1
Acetone 57 4.8 ug/m3 04/22/22 22:42 1
Benzene ND 1.6 ug/m3 04/22/22 22:42 1
Benzyl chloride ND *- 7.8 ug/m3 04/22/22 22:42 1
Bromodichloromethane ND 3.4 ug/m3 04/22/22 22:42 1
Bromoform ND 5.2 ug/m3 04/22/22 22:42 1
Bromomethane ND 1.9 ug/m3 04/22/22 22:42 1
cis-1,2-Dichloroethene ND 2.0 ug/m3 04/22/22 22:42 1
cis-1,3-Dichloropropene ND 2.3 ug/m3 04/22/22 22:42 1
Carbon disulfide ND 6.2 ug/m3 04/22/22 22:42 1
Carbon tetrachloride ND 3.1 ug/m3 04/22/22 22:42 1
Chlorobenzene ND 2.3 ug/m3 04/22/22 22:42 1
Chloroethane ND 1.3 ug/m3 04/22/22 22:42 1
Chloroform ND 2.4 ug/m3 04/22/22 22:42 1
Chloromethane ND 1.0 ug/m3 04/22/22 22:42 1
Dibromochloromethane ND 4.3 ug/m3 04/22/22 22:42 1
Dichlorodifluoromethane ND 2.5 ug/m3 04/22/22 22:42 1
Dichlorotetrafluoroethane ND 14 ug/m3 04/22/22 22:42 1
Ethylbenzene ND 2.2 ug/m3 04/22/22 22:42 1
Hexachloro-1,3-butadiene ND 16 ug/m3 04/22/22 22:42 1
Isopropanol ND 12 ug/m3 04/22/22 22:42 1
Methylene Chloride ND 17 ug/m3 04/22/22 22:42 1
Methyl-t-Butyl Ether (MTBE) ND 7.2 ug/m3 04/22/22 22:42 1 n-Butylbenzene ND 8.2 ug/m3 04/22/22 22:42 1
o-Xylene ND 2.2 ug/m3 04/22/22 22:42 1
m,p-Xylene ND 8.7 ug/m3 04/22/22 22:42 1
sec-Butylbenzene ND 8.2 ug/m3 04/22/22 22:42 1
Styrene ND 6.4 ug/m3 04/22/22 22:42 1
trans-1,2-Dichloroethene ND 2.0 ug/m3 04/22/22 22:42 1
trans-1,3-Dichloropropene ND 4.5 ug/m3 04/22/22 22:42 1 tert-Butylbenzene ND 8.2 ug/m3 04/22/22 22:42 1
Tetrachloroethene 5.7 3.4 ug/m3 04/22/22 22:42 1
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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-9-15 Lab Sample ID: 570-93118-11
Date Collected: 04/18/22 13:39 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
Toluene ND 1.9 ug/m3 04/22/22 22:42 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac Trichloroethene ND 2.7 ug/m3 04/22/22 22:42 1
Trichlorofluoromethane 18 5.6 ug/m3 04/22/22 22:42 1
Vinyl acetate ND 7.0 ug/m3 04/22/22 22:42 1
Vinyl chloride ND 1.3 ug/m3 04/22/22 22:42 1
1,2-Dichloroethane-d4 (Surr) 98 66 - 132 04/22/22 22:42 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 122 70 - 130 04/22/22 22:42 1 Toluene-d8 (Surr) 121 70 - 130 04/22/22 22:42 1
Client Sample ID: SV-7-5 Lab Sample ID: 570-93118-12
Date Collected: 04/18/22 13:30 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
1,1,1-Trichloroethane ND 0.50 ppb v/v 04/22/22 23:43 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 1.0 ppb v/v 04/22/22 23:43 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 1.5 ppb v/v 04/22/22 23:43 1 1,1,2-Trichloroethane ND 0.50 ppb v/v 04/22/22 23:43 1
1,1-Dichloroethane ND 0.50 ppb v/v 04/22/22 23:43 1
1,1-Dichloroethene ND 0.50 ppb v/v 04/22/22 23:43 1
1,1-Difluoroethane ND 2.0 ppb v/v 04/22/22 23:43 1
1,2,4-Trichlorobenzene ND 2.0 ppb v/v 04/22/22 23:43 1
1,2,4-Trimethylbenzene ND 1.5 ppb v/v 04/22/22 23:43 1
1,2-Dibromo-3-Chloropropane ND 1.5 ppb v/v 04/22/22 23:43 1 1,2-Dibromoethane ND 0.50 ppb v/v 04/22/22 23:43 1
1,2-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 23:43 1
1,2-Dichloroethane ND 0.50 ppb v/v 04/22/22 23:43 1
1,2-Dichloropropane ND 0.50 ppb v/v 04/22/22 23:43 1
1,3,5-Trimethylbenzene 0.51 0.50 ppb v/v 04/22/22 23:43 1 1,3-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 23:43 1
1,4-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 23:43 1
2-Butanone 4.1 1.5 ppb v/v 04/22/22 23:43 1
2-Hexanone ND 1.5 ppb v/v 04/22/22 23:43 1
4-Ethyltoluene ND 0.50 ppb v/v 04/22/22 23:43 1
4-Methyl-2-pentanone ND 1.5 ppb v/v 04/22/22 23:43 1
Acetone 23 2.0 ppb v/v 04/22/22 23:43 1
Benzene ND 0.50 ppb v/v 04/22/22 23:43 1
Benzyl chloride ND *- 1.5 ppb v/v 04/22/22 23:43 1
Bromodichloromethane ND 0.50 ppb v/v 04/22/22 23:43 1
Bromoform ND 0.50 ppb v/v 04/22/22 23:43 1
Bromomethane ND 0.50 ppb v/v 04/22/22 23:43 1
cis-1,2-Dichloroethene ND 0.50 ppb v/v 04/22/22 23:43 1 cis-1,3-Dichloropropene ND 0.50 ppb v/v 04/22/22 23:43 1 Carbon disulfide ND 2.0 ppb v/v 04/22/22 23:43 1
Carbon tetrachloride ND 0.50 ppb v/v 04/22/22 23:43 1
Chlorobenzene ND 0.50 ppb v/v 04/22/22 23:43 1
Chloroethane ND 0.50 ppb v/v 04/22/22 23:43 1
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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-7-5 Lab Sample ID: 570-93118-12
Date Collected: 04/18/22 13:30 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
Chloroform ND 0.50 ppb v/v 04/22/22 23:43 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac Chloromethane ND 0.50 ppb v/v 04/22/22 23:43 1
Dibromochloromethane ND 0.50 ppb v/v 04/22/22 23:43 1
Dichlorodifluoromethane ND 0.50 ppb v/v 04/22/22 23:43 1 Dichlorotetrafluoroethane ND 2.0 ppb v/v 04/22/22 23:43 1 Ethylbenzene 0.68 0.50 ppb v/v 04/22/22 23:43 1
Hexachloro-1,3-butadiene ND 1.5 ppb v/v 04/22/22 23:43 1 Isopropanol ND 5.0 ppb v/v 04/22/22 23:43 1
Methylene Chloride ND 5.0 ppb v/v 04/22/22 23:43 1
Methyl-t-Butyl Ether (MTBE) ND 2.0 ppb v/v 04/22/22 23:43 1 n-Butylbenzene ND 1.5 ppb v/v 04/22/22 23:43 1
o-Xylene 0.71 0.50 ppb v/v 04/22/22 23:43 1
m,p-Xylene 2.6 2.0 ppb v/v 04/22/22 23:43 1
sec-Butylbenzene ND 1.5 ppb v/v 04/22/22 23:43 1
Styrene ND 1.5 ppb v/v 04/22/22 23:43 1
trans-1,2-Dichloroethene ND 0.50 ppb v/v 04/22/22 23:43 1 trans-1,3-Dichloropropene ND 1.0 ppb v/v 04/22/22 23:43 1 tert-Butylbenzene ND 1.5 ppb v/v 04/22/22 23:43 1
Tetrachloroethene 31 0.50 ppb v/v 04/22/22 23:43 1
Toluene 1.2 0.50 ppb v/v 04/22/22 23:43 1
Trichloroethene ND 0.50 ppb v/v 04/22/22 23:43 1
Trichlorofluoromethane 13 1.0 ppb v/v 04/22/22 23:43 1
Vinyl acetate ND 2.0 ppb v/v 04/22/22 23:43 1
Vinyl chloride ND 0.50 ppb v/v 04/22/22 23:43 1
RL MDL
1,1,1-Trichloroethane ND 2.7 ug/m3 04/22/22 23:43 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 6.9 ug/m3 04/22/22 23:43 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 11 ug/m3 04/22/22 23:43 1 1,1,2-Trichloroethane ND 2.7 ug/m3 04/22/22 23:43 1
1,1-Dichloroethane ND 2.0 ug/m3 04/22/22 23:43 1
1,1-Dichloroethene ND 2.0 ug/m3 04/22/22 23:43 1
1,1-Difluoroethane ND 5.4 ug/m3 04/22/22 23:43 1
1,2,4-Trichlorobenzene ND 15 ug/m3 04/22/22 23:43 1
1,2,4-Trimethylbenzene ND 7.4 ug/m3 04/22/22 23:43 1
1,2-Dibromo-3-Chloropropane ND 14 ug/m3 04/22/22 23:43 1 1,2-Dibromoethane ND 3.8 ug/m3 04/22/22 23:43 1
1,2-Dichlorobenzene ND 3.0 ug/m3 04/22/22 23:43 1
1,2-Dichloroethane ND 2.0 ug/m3 04/22/22 23:43 1
1,2-Dichloropropane ND 2.3 ug/m3 04/22/22 23:43 1
1,3,5-Trimethylbenzene 2.5 2.5 ug/m3 04/22/22 23:43 1
1,3-Dichlorobenzene ND 3.0 ug/m3 04/22/22 23:43 1
1,4-Dichlorobenzene ND 3.0 ug/m3 04/22/22 23:43 1
2-Butanone 12 4.4 ug/m3 04/22/22 23:43 1
2-Hexanone ND 6.1 ug/m3 04/22/22 23:43 1
4-Ethyltoluene ND 2.5 ug/m3 04/22/22 23:43 1
4-Methyl-2-pentanone ND 6.1 ug/m3 04/22/22 23:43 1
Acetone 54 4.8 ug/m3 04/22/22 23:43 1
Benzene ND 1.6 ug/m3 04/22/22 23:43 1
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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-7-5 Lab Sample ID: 570-93118-12
Date Collected: 04/18/22 13:30 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
Benzyl chloride ND *- 7.8 ug/m3 04/22/22 23:43 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac Bromodichloromethane ND 3.4 ug/m3 04/22/22 23:43 1
Bromoform ND 5.2 ug/m3 04/22/22 23:43 1
Bromomethane ND 1.9 ug/m3 04/22/22 23:43 1
cis-1,2-Dichloroethene ND 2.0 ug/m3 04/22/22 23:43 1
cis-1,3-Dichloropropene ND 2.3 ug/m3 04/22/22 23:43 1
Carbon disulfide ND 6.2 ug/m3 04/22/22 23:43 1
Carbon tetrachloride ND 3.1 ug/m3 04/22/22 23:43 1
Chlorobenzene ND 2.3 ug/m3 04/22/22 23:43 1
Chloroethane ND 1.3 ug/m3 04/22/22 23:43 1
Chloroform ND 2.4 ug/m3 04/22/22 23:43 1
Chloromethane ND 1.0 ug/m3 04/22/22 23:43 1
Dibromochloromethane ND 4.3 ug/m3 04/22/22 23:43 1
Dichlorodifluoromethane ND 2.5 ug/m3 04/22/22 23:43 1
Dichlorotetrafluoroethane ND 14 ug/m3 04/22/22 23:43 1
Ethylbenzene 3.0 2.2 ug/m3 04/22/22 23:43 1
Hexachloro-1,3-butadiene ND 16 ug/m3 04/22/22 23:43 1
Isopropanol ND 12 ug/m3 04/22/22 23:43 1
Methylene Chloride ND 17 ug/m3 04/22/22 23:43 1
Methyl-t-Butyl Ether (MTBE) ND 7.2 ug/m3 04/22/22 23:43 1 n-Butylbenzene ND 8.2 ug/m3 04/22/22 23:43 1
o-Xylene 3.1 2.2 ug/m3 04/22/22 23:43 1
m,p-Xylene 11 8.7 ug/m3 04/22/22 23:43 1
sec-Butylbenzene ND 8.2 ug/m3 04/22/22 23:43 1
Styrene ND 6.4 ug/m3 04/22/22 23:43 1
trans-1,2-Dichloroethene ND 2.0 ug/m3 04/22/22 23:43 1
trans-1,3-Dichloropropene ND 4.5 ug/m3 04/22/22 23:43 1 tert-Butylbenzene ND 8.2 ug/m3 04/22/22 23:43 1
Tetrachloroethene 210 3.4 ug/m3 04/22/22 23:43 1
Toluene 4.4 1.9 ug/m3 04/22/22 23:43 1
Trichloroethene ND 2.7 ug/m3 04/22/22 23:43 1
Trichlorofluoromethane 71 5.6 ug/m3 04/22/22 23:43 1
Vinyl acetate ND 7.0 ug/m3 04/22/22 23:43 1
Vinyl chloride ND 1.3 ug/m3 04/22/22 23:43 1
1,2-Dichloroethane-d4 (Surr) 98 66 - 132 04/22/22 23:43 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 120 70 - 130 04/22/22 23:43 1 Toluene-d8 (Surr) 109 70 - 130 04/22/22 23:43 1
Client Sample ID: SV-7-15 Lab Sample ID: 570-93118-13
Date Collected: 04/18/22 13:19 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
1,1,1-Trichloroethane ND 0.50 ppb v/v 04/23/22 00:43 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 1.0 ppb v/v 04/23/22 00:43 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 1.5 ppb v/v 04/23/22 00:43 1 1,1,2-Trichloroethane ND 0.50 ppb v/v 04/23/22 00:43 1
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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-7-15 Lab Sample ID: 570-93118-13
Date Collected: 04/18/22 13:19 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
1,1-Dichloroethane ND 0.50 ppb v/v 04/23/22 00:43 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1-Dichloroethene ND 0.50 ppb v/v 04/23/22 00:43 1
1,1-Difluoroethane ND 2.0 ppb v/v 04/23/22 00:43 1
1,2,4-Trichlorobenzene ND 2.0 ppb v/v 04/23/22 00:43 1
1,2,4-Trimethylbenzene ND 1.5 ppb v/v 04/23/22 00:43 1
1,2-Dibromo-3-Chloropropane ND 1.5 ppb v/v 04/23/22 00:43 1 1,2-Dibromoethane ND 0.50 ppb v/v 04/23/22 00:43 1
1,2-Dichlorobenzene ND 0.50 ppb v/v 04/23/22 00:43 1
1,2-Dichloroethane ND 0.50 ppb v/v 04/23/22 00:43 1
1,2-Dichloropropane ND 0.50 ppb v/v 04/23/22 00:43 1
1,3,5-Trimethylbenzene ND 0.50 ppb v/v 04/23/22 00:43 1 1,3-Dichlorobenzene ND 0.50 ppb v/v 04/23/22 00:43 1
1,4-Dichlorobenzene ND 0.50 ppb v/v 04/23/22 00:43 1
2-Butanone 5.4 1.5 ppb v/v 04/23/22 00:43 1
2-Hexanone ND 1.5 ppb v/v 04/23/22 00:43 1
4-Ethyltoluene ND 0.50 ppb v/v 04/23/22 00:43 1
4-Methyl-2-pentanone ND 1.5 ppb v/v 04/23/22 00:43 1
Acetone 17 2.0 ppb v/v 04/23/22 00:43 1
Benzene ND 0.50 ppb v/v 04/23/22 00:43 1
Benzyl chloride ND *- 1.5 ppb v/v 04/23/22 00:43 1
Bromodichloromethane ND 0.50 ppb v/v 04/23/22 00:43 1
Bromoform ND 0.50 ppb v/v 04/23/22 00:43 1
Bromomethane ND 0.50 ppb v/v 04/23/22 00:43 1
cis-1,2-Dichloroethene ND 0.50 ppb v/v 04/23/22 00:43 1 cis-1,3-Dichloropropene ND 0.50 ppb v/v 04/23/22 00:43 1 Carbon disulfide ND 2.0 ppb v/v 04/23/22 00:43 1
Carbon tetrachloride ND 0.50 ppb v/v 04/23/22 00:43 1
Chlorobenzene ND 0.50 ppb v/v 04/23/22 00:43 1
Chloroethane ND 0.50 ppb v/v 04/23/22 00:43 1
Chloroform ND 0.50 ppb v/v 04/23/22 00:43 1
Chloromethane ND 0.50 ppb v/v 04/23/22 00:43 1
Dibromochloromethane ND 0.50 ppb v/v 04/23/22 00:43 1
Dichlorodifluoromethane ND 0.50 ppb v/v 04/23/22 00:43 1 Dichlorotetrafluoroethane ND 2.0 ppb v/v 04/23/22 00:43 1 Ethylbenzene ND 0.50 ppb v/v 04/23/22 00:43 1
Hexachloro-1,3-butadiene ND 1.5 ppb v/v 04/23/22 00:43 1 Isopropanol ND 5.0 ppb v/v 04/23/22 00:43 1
Methylene Chloride ND 5.0 ppb v/v 04/23/22 00:43 1
Methyl-t-Butyl Ether (MTBE) ND 2.0 ppb v/v 04/23/22 00:43 1 n-Butylbenzene ND 1.5 ppb v/v 04/23/22 00:43 1
o-Xylene ND 0.50 ppb v/v 04/23/22 00:43 1
m,p-Xylene ND 2.0 ppb v/v 04/23/22 00:43 1
sec-Butylbenzene ND 1.5 ppb v/v 04/23/22 00:43 1
Styrene ND 1.5 ppb v/v 04/23/22 00:43 1
trans-1,2-Dichloroethene ND 0.50 ppb v/v 04/23/22 00:43 1 trans-1,3-Dichloropropene ND 1.0 ppb v/v 04/23/22 00:43 1 tert-Butylbenzene ND 1.5 ppb v/v 04/23/22 00:43 1
Tetrachloroethene 1.4 0.50 ppb v/v 04/23/22 00:43 1
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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-7-15 Lab Sample ID: 570-93118-13
Date Collected: 04/18/22 13:19 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
Toluene ND 0.50 ppb v/v 04/23/22 00:43 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac Trichloroethene ND 0.50 ppb v/v 04/23/22 00:43 1
Trichlorofluoromethane 14 1.0 ppb v/v 04/23/22 00:43 1
Vinyl acetate ND 2.0 ppb v/v 04/23/22 00:43 1
Vinyl chloride ND 0.50 ppb v/v 04/23/22 00:43 1
RL MDL
1,1,1-Trichloroethane ND 2.7 ug/m3 04/23/22 00:43 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 6.9 ug/m3 04/23/22 00:43 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 11 ug/m3 04/23/22 00:43 1 1,1,2-Trichloroethane ND 2.7 ug/m3 04/23/22 00:43 1
1,1-Dichloroethane ND 2.0 ug/m3 04/23/22 00:43 1
1,1-Dichloroethene ND 2.0 ug/m3 04/23/22 00:43 1
1,1-Difluoroethane ND 5.4 ug/m3 04/23/22 00:43 1
1,2,4-Trichlorobenzene ND 15 ug/m3 04/23/22 00:43 1
1,2,4-Trimethylbenzene ND 7.4 ug/m3 04/23/22 00:43 1
1,2-Dibromo-3-Chloropropane ND 14 ug/m3 04/23/22 00:43 1 1,2-Dibromoethane ND 3.8 ug/m3 04/23/22 00:43 1
1,2-Dichlorobenzene ND 3.0 ug/m3 04/23/22 00:43 1
1,2-Dichloroethane ND 2.0 ug/m3 04/23/22 00:43 1
1,2-Dichloropropane ND 2.3 ug/m3 04/23/22 00:43 1
1,3,5-Trimethylbenzene ND 2.5 ug/m3 04/23/22 00:43 1
1,3-Dichlorobenzene ND 3.0 ug/m3 04/23/22 00:43 1
1,4-Dichlorobenzene ND 3.0 ug/m3 04/23/22 00:43 1
2-Butanone 16 4.4 ug/m3 04/23/22 00:43 1
2-Hexanone ND 6.1 ug/m3 04/23/22 00:43 1
4-Ethyltoluene ND 2.5 ug/m3 04/23/22 00:43 1
4-Methyl-2-pentanone ND 6.1 ug/m3 04/23/22 00:43 1
Acetone 39 4.8 ug/m3 04/23/22 00:43 1
Benzene ND 1.6 ug/m3 04/23/22 00:43 1
Benzyl chloride ND *- 7.8 ug/m3 04/23/22 00:43 1
Bromodichloromethane ND 3.4 ug/m3 04/23/22 00:43 1
Bromoform ND 5.2 ug/m3 04/23/22 00:43 1
Bromomethane ND 1.9 ug/m3 04/23/22 00:43 1
cis-1,2-Dichloroethene ND 2.0 ug/m3 04/23/22 00:43 1
cis-1,3-Dichloropropene ND 2.3 ug/m3 04/23/22 00:43 1
Carbon disulfide ND 6.2 ug/m3 04/23/22 00:43 1
Carbon tetrachloride ND 3.1 ug/m3 04/23/22 00:43 1
Chlorobenzene ND 2.3 ug/m3 04/23/22 00:43 1
Chloroethane ND 1.3 ug/m3 04/23/22 00:43 1
Chloroform ND 2.4 ug/m3 04/23/22 00:43 1
Chloromethane ND 1.0 ug/m3 04/23/22 00:43 1
Dibromochloromethane ND 4.3 ug/m3 04/23/22 00:43 1
Dichlorodifluoromethane ND 2.5 ug/m3 04/23/22 00:43 1
Dichlorotetrafluoroethane ND 14 ug/m3 04/23/22 00:43 1
Ethylbenzene ND 2.2 ug/m3 04/23/22 00:43 1
Hexachloro-1,3-butadiene ND 16 ug/m3 04/23/22 00:43 1
Isopropanol ND 12 ug/m3 04/23/22 00:43 1
Methylene Chloride ND 17 ug/m3 04/23/22 00:43 1
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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-7-15 Lab Sample ID: 570-93118-13
Date Collected: 04/18/22 13:19 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
Methyl-t-Butyl Ether (MTBE) ND 7.2 ug/m3 04/23/22 00:43 1 Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac n-Butylbenzene ND 8.2 ug/m3 04/23/22 00:43 1
o-Xylene ND 2.2 ug/m3 04/23/22 00:43 1
m,p-Xylene ND 8.7 ug/m3 04/23/22 00:43 1
sec-Butylbenzene ND 8.2 ug/m3 04/23/22 00:43 1
Styrene ND 6.4 ug/m3 04/23/22 00:43 1
trans-1,2-Dichloroethene ND 2.0 ug/m3 04/23/22 00:43 1
trans-1,3-Dichloropropene ND 4.5 ug/m3 04/23/22 00:43 1 tert-Butylbenzene ND 8.2 ug/m3 04/23/22 00:43 1
Tetrachloroethene 9.8 3.4 ug/m3 04/23/22 00:43 1
Toluene ND 1.9 ug/m3 04/23/22 00:43 1
Trichloroethene ND 2.7 ug/m3 04/23/22 00:43 1
Trichlorofluoromethane 80 5.6 ug/m3 04/23/22 00:43 1
Vinyl acetate ND 7.0 ug/m3 04/23/22 00:43 1
Vinyl chloride ND 1.3 ug/m3 04/23/22 00:43 1
1,2-Dichloroethane-d4 (Surr) 98 66 - 132 04/23/22 00:43 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 115 70 - 130 04/23/22 00:43 1 Toluene-d8 (Surr) 117 70 - 130 04/23/22 00:43 1
Client Sample ID: SV-8-5 Lab Sample ID: 570-93118-14
Date Collected: 04/18/22 14:16 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
1,1,1-Trichloroethane ND 0.50 ppb v/v 04/23/22 01:33 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 1.0 ppb v/v 04/23/22 01:33 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 1.5 ppb v/v 04/23/22 01:33 1 1,1,2-Trichloroethane ND 0.50 ppb v/v 04/23/22 01:33 1
1,1-Dichloroethane ND 0.50 ppb v/v 04/23/22 01:33 1
1,1-Dichloroethene ND 0.50 ppb v/v 04/23/22 01:33 1
1,1-Difluoroethane ND 2.0 ppb v/v 04/23/22 01:33 1
1,2,4-Trichlorobenzene ND 2.0 ppb v/v 04/23/22 01:33 1
1,2,4-Trimethylbenzene ND 1.5 ppb v/v 04/23/22 01:33 1
1,2-Dibromo-3-Chloropropane ND 1.5 ppb v/v 04/23/22 01:33 1 1,2-Dibromoethane ND 0.50 ppb v/v 04/23/22 01:33 1
1,2-Dichlorobenzene ND 0.50 ppb v/v 04/23/22 01:33 1
1,2-Dichloroethane ND 0.50 ppb v/v 04/23/22 01:33 1
1,2-Dichloropropane ND 0.50 ppb v/v 04/23/22 01:33 1
1,3,5-Trimethylbenzene ND 0.50 ppb v/v 04/23/22 01:33 1 1,3-Dichlorobenzene ND 0.50 ppb v/v 04/23/22 01:33 1
1,4-Dichlorobenzene ND 0.50 ppb v/v 04/23/22 01:33 1
2-Butanone 1.5 1.5 ppb v/v 04/23/22 01:33 1
2-Hexanone ND 1.5 ppb v/v 04/23/22 01:33 1
4-Ethyltoluene ND 0.50 ppb v/v 04/23/22 01:33 1
4-Methyl-2-pentanone ND 1.5 ppb v/v 04/23/22 01:33 1
Acetone 7.3 2.0 ppb v/v 04/23/22 01:33 1
Benzene ND 0.50 ppb v/v 04/23/22 01:33 1
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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-8-5 Lab Sample ID: 570-93118-14
Date Collected: 04/18/22 14:16 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
Benzyl chloride ND *- 1.5 ppb v/v 04/23/22 01:33 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac Bromodichloromethane ND 0.50 ppb v/v 04/23/22 01:33 1
Bromoform ND 0.50 ppb v/v 04/23/22 01:33 1
Bromomethane ND 0.50 ppb v/v 04/23/22 01:33 1
cis-1,2-Dichloroethene ND 0.50 ppb v/v 04/23/22 01:33 1 cis-1,3-Dichloropropene ND 0.50 ppb v/v 04/23/22 01:33 1 Carbon disulfide ND 2.0 ppb v/v 04/23/22 01:33 1
Carbon tetrachloride ND 0.50 ppb v/v 04/23/22 01:33 1
Chlorobenzene ND 0.50 ppb v/v 04/23/22 01:33 1
Chloroethane ND 0.50 ppb v/v 04/23/22 01:33 1
Chloroform ND 0.50 ppb v/v 04/23/22 01:33 1
Chloromethane ND 0.50 ppb v/v 04/23/22 01:33 1
Dibromochloromethane ND 0.50 ppb v/v 04/23/22 01:33 1
Dichlorodifluoromethane ND 0.50 ppb v/v 04/23/22 01:33 1 Dichlorotetrafluoroethane ND 2.0 ppb v/v 04/23/22 01:33 1 Ethylbenzene ND 0.50 ppb v/v 04/23/22 01:33 1
Hexachloro-1,3-butadiene ND 1.5 ppb v/v 04/23/22 01:33 1 Isopropanol ND 5.0 ppb v/v 04/23/22 01:33 1
Methylene Chloride ND 5.0 ppb v/v 04/23/22 01:33 1
Methyl-t-Butyl Ether (MTBE) ND 2.0 ppb v/v 04/23/22 01:33 1 n-Butylbenzene ND 1.5 ppb v/v 04/23/22 01:33 1
o-Xylene ND 0.50 ppb v/v 04/23/22 01:33 1
m,p-Xylene ND 2.0 ppb v/v 04/23/22 01:33 1
sec-Butylbenzene ND 1.5 ppb v/v 04/23/22 01:33 1
Styrene ND 1.5 ppb v/v 04/23/22 01:33 1
trans-1,2-Dichloroethene ND 0.50 ppb v/v 04/23/22 01:33 1 trans-1,3-Dichloropropene ND 1.0 ppb v/v 04/23/22 01:33 1 tert-Butylbenzene ND 1.5 ppb v/v 04/23/22 01:33 1
Tetrachloroethene 0.81 0.50 ppb v/v 04/23/22 01:33 1
Toluene ND 0.50 ppb v/v 04/23/22 01:33 1
Trichloroethene ND 0.50 ppb v/v 04/23/22 01:33 1
Trichlorofluoromethane 4.1 1.0 ppb v/v 04/23/22 01:33 1 Vinyl acetate ND 2.0 ppb v/v 04/23/22 01:33 1
Vinyl chloride ND 0.50 ppb v/v 04/23/22 01:33 1
RL MDL
1,1,1-Trichloroethane ND 2.7 ug/m3 04/23/22 01:33 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 6.9 ug/m3 04/23/22 01:33 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 11 ug/m3 04/23/22 01:33 1 1,1,2-Trichloroethane ND 2.7 ug/m3 04/23/22 01:33 1
1,1-Dichloroethane ND 2.0 ug/m3 04/23/22 01:33 1
1,1-Dichloroethene ND 2.0 ug/m3 04/23/22 01:33 1
1,1-Difluoroethane ND 5.4 ug/m3 04/23/22 01:33 1
1,2,4-Trichlorobenzene ND 15 ug/m3 04/23/22 01:33 1
1,2,4-Trimethylbenzene ND 7.4 ug/m3 04/23/22 01:33 1
1,2-Dibromo-3-Chloropropane ND 14 ug/m3 04/23/22 01:33 1 1,2-Dibromoethane ND 3.8 ug/m3 04/23/22 01:33 1
1,2-Dichlorobenzene ND 3.0 ug/m3 04/23/22 01:33 1
1,2-Dichloroethane ND 2.0 ug/m3 04/23/22 01:33 1
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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-8-5 Lab Sample ID: 570-93118-14
Date Collected: 04/18/22 14:16 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
1,2-Dichloropropane ND 2.3 ug/m3 04/23/22 01:33 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,3,5-Trimethylbenzene ND 2.5 ug/m3 04/23/22 01:33 1
1,3-Dichlorobenzene ND 3.0 ug/m3 04/23/22 01:33 1
1,4-Dichlorobenzene ND 3.0 ug/m3 04/23/22 01:33 1
2-Butanone 4.3 4.4 ug/m3 04/23/22 01:33 1
2-Hexanone ND 6.1 ug/m3 04/23/22 01:33 1
4-Ethyltoluene ND 2.5 ug/m3 04/23/22 01:33 1
4-Methyl-2-pentanone ND 6.1 ug/m3 04/23/22 01:33 1
Acetone 17 4.8 ug/m3 04/23/22 01:33 1
Benzene ND 1.6 ug/m3 04/23/22 01:33 1
Benzyl chloride ND *- 7.8 ug/m3 04/23/22 01:33 1
Bromodichloromethane ND 3.4 ug/m3 04/23/22 01:33 1
Bromoform ND 5.2 ug/m3 04/23/22 01:33 1
Bromomethane ND 1.9 ug/m3 04/23/22 01:33 1
cis-1,2-Dichloroethene ND 2.0 ug/m3 04/23/22 01:33 1
cis-1,3-Dichloropropene ND 2.3 ug/m3 04/23/22 01:33 1
Carbon disulfide ND 6.2 ug/m3 04/23/22 01:33 1
Carbon tetrachloride ND 3.1 ug/m3 04/23/22 01:33 1
Chlorobenzene ND 2.3 ug/m3 04/23/22 01:33 1
Chloroethane ND 1.3 ug/m3 04/23/22 01:33 1
Chloroform ND 2.4 ug/m3 04/23/22 01:33 1
Chloromethane ND 1.0 ug/m3 04/23/22 01:33 1
Dibromochloromethane ND 4.3 ug/m3 04/23/22 01:33 1
Dichlorodifluoromethane ND 2.5 ug/m3 04/23/22 01:33 1
Dichlorotetrafluoroethane ND 14 ug/m3 04/23/22 01:33 1
Ethylbenzene ND 2.2 ug/m3 04/23/22 01:33 1
Hexachloro-1,3-butadiene ND 16 ug/m3 04/23/22 01:33 1
Isopropanol ND 12 ug/m3 04/23/22 01:33 1
Methylene Chloride ND 17 ug/m3 04/23/22 01:33 1
Methyl-t-Butyl Ether (MTBE) ND 7.2 ug/m3 04/23/22 01:33 1 n-Butylbenzene ND 8.2 ug/m3 04/23/22 01:33 1
o-Xylene ND 2.2 ug/m3 04/23/22 01:33 1
m,p-Xylene ND 8.7 ug/m3 04/23/22 01:33 1
sec-Butylbenzene ND 8.2 ug/m3 04/23/22 01:33 1
Styrene ND 6.4 ug/m3 04/23/22 01:33 1
trans-1,2-Dichloroethene ND 2.0 ug/m3 04/23/22 01:33 1
trans-1,3-Dichloropropene ND 4.5 ug/m3 04/23/22 01:33 1 tert-Butylbenzene ND 8.2 ug/m3 04/23/22 01:33 1
Tetrachloroethene 5.5 3.4 ug/m3 04/23/22 01:33 1
Toluene ND 1.9 ug/m3 04/23/22 01:33 1
Trichloroethene ND 2.7 ug/m3 04/23/22 01:33 1
Trichlorofluoromethane 23 5.6 ug/m3 04/23/22 01:33 1
Vinyl acetate ND 7.0 ug/m3 04/23/22 01:33 1
Vinyl chloride ND 1.3 ug/m3 04/23/22 01:33 1
1,2-Dichloroethane-d4 (Surr) 98 66 - 132 04/23/22 01:33 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 122 70 - 130 04/23/22 01:33 1 Toluene-d8 (Surr) 112 70 - 130 04/23/22 01:33 1
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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air Client Sample ID: SV-8-15 Lab Sample ID: 570-93118-15
Date Collected: 04/18/22 14:05 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
1,1,1-Trichloroethane ND 0.50 ppb v/v 04/23/22 02:21 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 1.0 ppb v/v 04/23/22 02:21 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 1.5 ppb v/v 04/23/22 02:21 1 1,1,2-Trichloroethane ND 0.50 ppb v/v 04/23/22 02:21 1
1,1-Dichloroethane ND 0.50 ppb v/v 04/23/22 02:21 1
1,1-Dichloroethene ND 0.50 ppb v/v 04/23/22 02:21 1
1,1-Difluoroethane ND 2.0 ppb v/v 04/23/22 02:21 1
1,2,4-Trichlorobenzene ND 2.0 ppb v/v 04/23/22 02:21 1
1,2,4-Trimethylbenzene ND 1.5 ppb v/v 04/23/22 02:21 1
1,2-Dibromo-3-Chloropropane ND 1.5 ppb v/v 04/23/22 02:21 1 1,2-Dibromoethane ND 0.50 ppb v/v 04/23/22 02:21 1
1,2-Dichlorobenzene ND 0.50 ppb v/v 04/23/22 02:21 1
1,2-Dichloroethane ND 0.50 ppb v/v 04/23/22 02:21 1
1,2-Dichloropropane ND 0.50 ppb v/v 04/23/22 02:21 1
1,3,5-Trimethylbenzene ND 0.50 ppb v/v 04/23/22 02:21 1 1,3-Dichlorobenzene ND 0.50 ppb v/v 04/23/22 02:21 1
1,4-Dichlorobenzene ND 0.50 ppb v/v 04/23/22 02:21 1
2-Butanone 1.8 1.5 ppb v/v 04/23/22 02:21 1
2-Hexanone ND 1.5 ppb v/v 04/23/22 02:21 1
4-Ethyltoluene ND 0.50 ppb v/v 04/23/22 02:21 1
4-Methyl-2-pentanone ND 1.5 ppb v/v 04/23/22 02:21 1
Acetone 9.8 2.0 ppb v/v 04/23/22 02:21 1
Benzene ND 0.50 ppb v/v 04/23/22 02:21 1
Benzyl chloride ND *- 1.5 ppb v/v 04/23/22 02:21 1
Bromodichloromethane ND 0.50 ppb v/v 04/23/22 02:21 1
Bromoform ND 0.50 ppb v/v 04/23/22 02:21 1
Bromomethane ND 0.50 ppb v/v 04/23/22 02:21 1
cis-1,2-Dichloroethene ND 0.50 ppb v/v 04/23/22 02:21 1 cis-1,3-Dichloropropene ND 0.50 ppb v/v 04/23/22 02:21 1 Carbon disulfide ND 2.0 ppb v/v 04/23/22 02:21 1
Carbon tetrachloride ND 0.50 ppb v/v 04/23/22 02:21 1
Chlorobenzene ND 0.50 ppb v/v 04/23/22 02:21 1
Chloroethane ND 0.50 ppb v/v 04/23/22 02:21 1
Chloroform ND 0.50 ppb v/v 04/23/22 02:21 1
Chloromethane ND 0.50 ppb v/v 04/23/22 02:21 1
Dibromochloromethane ND 0.50 ppb v/v 04/23/22 02:21 1
Dichlorodifluoromethane ND 0.50 ppb v/v 04/23/22 02:21 1 Dichlorotetrafluoroethane ND 2.0 ppb v/v 04/23/22 02:21 1 Ethylbenzene ND 0.50 ppb v/v 04/23/22 02:21 1
Hexachloro-1,3-butadiene ND 1.5 ppb v/v 04/23/22 02:21 1 Isopropanol ND 5.0 ppb v/v 04/23/22 02:21 1
Methylene Chloride ND 5.0 ppb v/v 04/23/22 02:21 1
Methyl-t-Butyl Ether (MTBE) ND 2.0 ppb v/v 04/23/22 02:21 1 n-Butylbenzene ND 1.5 ppb v/v 04/23/22 02:21 1
o-Xylene ND 0.50 ppb v/v 04/23/22 02:21 1
m,p-Xylene ND 2.0 ppb v/v 04/23/22 02:21 1
sec-Butylbenzene ND 1.5 ppb v/v 04/23/22 02:21 1
Styrene ND 1.5 ppb v/v 04/23/22 02:21 1
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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-8-15 Lab Sample ID: 570-93118-15
Date Collected: 04/18/22 14:05 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
trans-1,2-Dichloroethene ND 0.50 ppb v/v 04/23/22 02:21 1 Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac trans-1,3-Dichloropropene ND 1.0 ppb v/v 04/23/22 02:21 1 tert-Butylbenzene ND 1.5 ppb v/v 04/23/22 02:21 1
Tetrachloroethene ND 0.50 ppb v/v 04/23/22 02:21 1
Toluene ND 0.50 ppb v/v 04/23/22 02:21 1
Trichloroethene ND 0.50 ppb v/v 04/23/22 02:21 1
Trichlorofluoromethane 4.3 1.0 ppb v/v 04/23/22 02:21 1 Vinyl acetate ND 2.0 ppb v/v 04/23/22 02:21 1
Vinyl chloride ND 0.50 ppb v/v 04/23/22 02:21 1
RL MDL
1,1,1-Trichloroethane ND 2.7 ug/m3 04/23/22 02:21 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 6.9 ug/m3 04/23/22 02:21 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 11 ug/m3 04/23/22 02:21 1 1,1,2-Trichloroethane ND 2.7 ug/m3 04/23/22 02:21 1
1,1-Dichloroethane ND 2.0 ug/m3 04/23/22 02:21 1
1,1-Dichloroethene ND 2.0 ug/m3 04/23/22 02:21 1
1,1-Difluoroethane ND 5.4 ug/m3 04/23/22 02:21 1
1,2,4-Trichlorobenzene ND 15 ug/m3 04/23/22 02:21 1
1,2,4-Trimethylbenzene ND 7.4 ug/m3 04/23/22 02:21 1
1,2-Dibromo-3-Chloropropane ND 14 ug/m3 04/23/22 02:21 1 1,2-Dibromoethane ND 3.8 ug/m3 04/23/22 02:21 1
1,2-Dichlorobenzene ND 3.0 ug/m3 04/23/22 02:21 1
1,2-Dichloroethane ND 2.0 ug/m3 04/23/22 02:21 1
1,2-Dichloropropane ND 2.3 ug/m3 04/23/22 02:21 1
1,3,5-Trimethylbenzene ND 2.5 ug/m3 04/23/22 02:21 1
1,3-Dichlorobenzene ND 3.0 ug/m3 04/23/22 02:21 1
1,4-Dichlorobenzene ND 3.0 ug/m3 04/23/22 02:21 1
2-Butanone 5.2 4.4 ug/m3 04/23/22 02:21 1
2-Hexanone ND 6.1 ug/m3 04/23/22 02:21 1
4-Ethyltoluene ND 2.5 ug/m3 04/23/22 02:21 1
4-Methyl-2-pentanone ND 6.1 ug/m3 04/23/22 02:21 1
Acetone 23 4.8 ug/m3 04/23/22 02:21 1
Benzene ND 1.6 ug/m3 04/23/22 02:21 1
Benzyl chloride ND *- 7.8 ug/m3 04/23/22 02:21 1
Bromodichloromethane ND 3.4 ug/m3 04/23/22 02:21 1
Bromoform ND 5.2 ug/m3 04/23/22 02:21 1
Bromomethane ND 1.9 ug/m3 04/23/22 02:21 1
cis-1,2-Dichloroethene ND 2.0 ug/m3 04/23/22 02:21 1
cis-1,3-Dichloropropene ND 2.3 ug/m3 04/23/22 02:21 1
Carbon disulfide ND 6.2 ug/m3 04/23/22 02:21 1
Carbon tetrachloride ND 3.1 ug/m3 04/23/22 02:21 1
Chlorobenzene ND 2.3 ug/m3 04/23/22 02:21 1
Chloroethane ND 1.3 ug/m3 04/23/22 02:21 1
Chloroform ND 2.4 ug/m3 04/23/22 02:21 1
Chloromethane ND 1.0 ug/m3 04/23/22 02:21 1
Dibromochloromethane ND 4.3 ug/m3 04/23/22 02:21 1
Dichlorodifluoromethane ND 2.5 ug/m3 04/23/22 02:21 1
Dichlorotetrafluoroethane ND 14 ug/m3 04/23/22 02:21 1
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Client Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Client Sample ID: SV-8-15 Lab Sample ID: 570-93118-15
Date Collected: 04/18/22 14:05 Matrix: Air
Date Received: 04/19/22 19:20
Sample Container: Summa Canister 1L
RL MDL
Ethylbenzene ND 2.2 ug/m3 04/23/22 02:21 1
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac Hexachloro-1,3-butadiene ND 16 ug/m3 04/23/22 02:21 1
Isopropanol ND 12 ug/m3 04/23/22 02:21 1
Methylene Chloride ND 17 ug/m3 04/23/22 02:21 1
Methyl-t-Butyl Ether (MTBE) ND 7.2 ug/m3 04/23/22 02:21 1 n-Butylbenzene ND 8.2 ug/m3 04/23/22 02:21 1
o-Xylene ND 2.2 ug/m3 04/23/22 02:21 1
m,p-Xylene ND 8.7 ug/m3 04/23/22 02:21 1
sec-Butylbenzene ND 8.2 ug/m3 04/23/22 02:21 1
Styrene ND 6.4 ug/m3 04/23/22 02:21 1
trans-1,2-Dichloroethene ND 2.0 ug/m3 04/23/22 02:21 1
trans-1,3-Dichloropropene ND 4.5 ug/m3 04/23/22 02:21 1 tert-Butylbenzene ND 8.2 ug/m3 04/23/22 02:21 1
Tetrachloroethene ND 3.4 ug/m3 04/23/22 02:21 1
Toluene ND 1.9 ug/m3 04/23/22 02:21 1
Trichloroethene ND 2.7 ug/m3 04/23/22 02:21 1
Trichlorofluoromethane 24 5.6 ug/m3 04/23/22 02:21 1
Vinyl acetate ND 7.0 ug/m3 04/23/22 02:21 1
Vinyl chloride ND 1.3 ug/m3 04/23/22 02:21 1
1,2-Dichloroethane-d4 (Surr) 98 66 - 132 04/23/22 02:21 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 123 70 - 130 04/23/22 02:21 1 Toluene-d8 (Surr) 124 70 - 130 04/23/22 02:21 1
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Surrogate Summary
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air Matrix: Air Prep Type: Total/NA
Lab Sample ID Client Sample ID (66-132) (70-130) (70-130)

DCA BFB TOL
570-93118-1 100 119 120
Percent Surrogate Recovery (Acceptance Limits)
SV-1-10
570-93118-2 SV-1-20 99 114 127
570-93118-3 SV-2-5 100 119 119
570-93118-4 SV-2-5-D 100 119 119
570-93118-5 SV-2-15 100 118 117
570-93118-6 SV-4-5 100 118 111
570-93118-7 SV-4-15 100 120 114
570-93118-8 SV-6-5 99 119 117
570-93118-9 SV-6-15 100 115 117
570-93118-10 SV-9-5 100 114 107
570-93118-11 SV-9-15 98 122 121
570-93118-12 SV-7-5 98 120 109
570-93118-13 SV-7-15 98 115 117
570-93118-14 SV-8-5 98 122 112
570-93118-15 SV-8-15 98 123 124
LCS 570-228287/3 Lab Control Sample 97 109 100
LCS 570-228550/4 Lab Control Sample 100 115 102
LCSD 570-228287/4 Lab Control Sample Dup 98 114 101
LCSD 570-228550/5 Lab Control Sample Dup 98 114 101
MB 570-228287/7 Method Blank 98 119 98
MB 570-228550/8 Method Blank 96 128 99
Surrogate Legend
DCA = 1,2-Dichloroethane-d4 (Surr)
BFB = 4-Bromofluorobenzene (Surr)
TOL = Toluene-d8 (Surr)
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QC Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air Lab Sample ID: MB 570-228287/7 Client Sample ID: Method Blank Matrix: Air Prep Type: Total/NA
Analysis Batch: 228287
RL MDL
1,1,1-Trichloroethane ND 0.50 ppb v/v 04/21/22 19:40 1
MB MB
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 1.0 ppb v/v 04/21/22 19:40 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 1.5 ppb v/v 04/21/22 19:40 1 1,1,2-Trichloroethane ND 0.50 ppb v/v 04/21/22 19:40 1
1,1-Dichloroethane ND 0.50 ppb v/v 04/21/22 19:40 1
1,1-Dichloroethene ND 0.50 ppb v/v 04/21/22 19:40 1
1,1-Difluoroethane ND 2.0 ppb v/v 04/21/22 19:40 1
1,2,4-Trichlorobenzene ND 2.0 ppb v/v 04/21/22 19:40 1
1,2,4-Trimethylbenzene ND 1.5 ppb v/v 04/21/22 19:40 1
1,2-Dibromo-3-Chloropropane ND 1.5 ppb v/v 04/21/22 19:40 1 1,2-Dibromoethane ND 0.50 ppb v/v 04/21/22 19:40 1
1,2-Dichlorobenzene ND 0.50 ppb v/v 04/21/22 19:40 1
1,2-Dichloroethane ND 0.50 ppb v/v 04/21/22 19:40 1
1,2-Dichloropropane ND 0.50 ppb v/v 04/21/22 19:40 1
1,3,5-Trimethylbenzene ND 0.50 ppb v/v 04/21/22 19:40 1 1,3-Dichlorobenzene ND 0.50 ppb v/v 04/21/22 19:40 1
1,4-Dichlorobenzene ND 0.50 ppb v/v 04/21/22 19:40 1
2-Butanone ND 1.5 ppb v/v 04/21/22 19:40 1
2-Hexanone ND 1.5 ppb v/v 04/21/22 19:40 1
4-Ethyltoluene ND 0.50 ppb v/v 04/21/22 19:40 1
4-Methyl-2-pentanone ND 1.5 ppb v/v 04/21/22 19:40 1
Acetone ND 2.0 ppb v/v 04/21/22 19:40 1
Benzene ND 0.50 ppb v/v 04/21/22 19:40 1
Benzyl chloride ND 1.5 ppb v/v 04/21/22 19:40 1
Bromodichloromethane ND 0.50 ppb v/v 04/21/22 19:40 1
Bromoform ND 0.50 ppb v/v 04/21/22 19:40 1
Bromomethane ND 0.50 ppb v/v 04/21/22 19:40 1
cis-1,2-Dichloroethene ND 0.50 ppb v/v 04/21/22 19:40 1 cis-1,3-Dichloropropene ND 0.50 ppb v/v 04/21/22 19:40 1 Carbon disulfide ND 2.0 ppb v/v 04/21/22 19:40 1
Carbon tetrachloride ND 0.50 ppb v/v 04/21/22 19:40 1
Chlorobenzene ND 0.50 ppb v/v 04/21/22 19:40 1
Chloroethane ND 0.50 ppb v/v 04/21/22 19:40 1
Chloroform ND 0.50 ppb v/v 04/21/22 19:40 1
Chloromethane ND 0.50 ppb v/v 04/21/22 19:40 1
Dibromochloromethane ND 0.50 ppb v/v 04/21/22 19:40 1
Dichlorodifluoromethane ND 0.50 ppb v/v 04/21/22 19:40 1 Dichlorotetrafluoroethane ND 2.0 ppb v/v 04/21/22 19:40 1 Ethylbenzene ND 0.50 ppb v/v 04/21/22 19:40 1
Hexachloro-1,3-butadiene ND 1.5 ppb v/v 04/21/22 19:40 1 Isopropanol ND 5.0 ppb v/v 04/21/22 19:40 1
Methylene Chloride ND 5.0 ppb v/v 04/21/22 19:40 1
Methyl-t-Butyl Ether (MTBE) ND 2.0 ppb v/v 04/21/22 19:40 1 n-Butylbenzene ND 1.5 ppb v/v 04/21/22 19:40 1
o-Xylene ND 0.50 ppb v/v 04/21/22 19:40 1
m,p-Xylene ND 2.0 ppb v/v 04/21/22 19:40 1
sec-Butylbenzene ND 1.5 ppb v/v 04/21/22 19:40 1
Styrene ND 1.5 ppb v/v 04/21/22 19:40 1
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QC Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Lab Sample ID: MB 570-228287/7 Client Sample ID: Method Blank Matrix: Air Prep Type: Total/NA
Analysis Batch: 228287
RL MDL
trans-1,2-Dichloroethene ND 0.50 ppb v/v 04/21/22 19:40 1 MB MB
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac trans-1,3-Dichloropropene ND 1.0 ppb v/v 04/21/22 19:40 1 tert-Butylbenzene ND 1.5 ppb v/v 04/21/22 19:40 1
Tetrachloroethene ND 0.50 ppb v/v 04/21/22 19:40 1
Toluene ND 0.50 ppb v/v 04/21/22 19:40 1
Trichloroethene ND 0.50 ppb v/v 04/21/22 19:40 1
Trichlorofluoromethane ND 1.0 ppb v/v 04/21/22 19:40 1
Vinyl acetate ND 2.0 ppb v/v 04/21/22 19:40 1
Vinyl chloride ND 0.50 ppb v/v 04/21/22 19:40 1
RL MDL
1,1,1-Trichloroethane ND 2.7 ug/m3 04/21/22 19:40 1
MB MB
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 6.9 ug/m3 04/21/22 19:40 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 11 ug/m3 04/21/22 19:40 1 1,1,2-Trichloroethane ND 2.7 ug/m3 04/21/22 19:40 1
1,1-Dichloroethane ND 2.0 ug/m3 04/21/22 19:40 1
1,1-Dichloroethene ND 2.0 ug/m3 04/21/22 19:40 1
1,1-Difluoroethane ND 5.4 ug/m3 04/21/22 19:40 1
1,2,4-Trichlorobenzene ND 15 ug/m3 04/21/22 19:40 1
1,2,4-Trimethylbenzene ND 7.4 ug/m3 04/21/22 19:40 1
1,2-Dibromo-3-Chloropropane ND 14 ug/m3 04/21/22 19:40 1 1,2-Dibromoethane ND 3.8 ug/m3 04/21/22 19:40 1
1,2-Dichlorobenzene ND 3.0 ug/m3 04/21/22 19:40 1
1,2-Dichloroethane ND 2.0 ug/m3 04/21/22 19:40 1
1,2-Dichloropropane ND 2.3 ug/m3 04/21/22 19:40 1
1,3,5-Trimethylbenzene ND 2.5 ug/m3 04/21/22 19:40 1
1,3-Dichlorobenzene ND 3.0 ug/m3 04/21/22 19:40 1
1,4-Dichlorobenzene ND 3.0 ug/m3 04/21/22 19:40 1
2-Butanone ND 4.4 ug/m3 04/21/22 19:40 1
2-Hexanone ND 6.1 ug/m3 04/21/22 19:40 1
4-Ethyltoluene ND 2.5 ug/m3 04/21/22 19:40 1
4-Methyl-2-pentanone ND 6.1 ug/m3 04/21/22 19:40 1
Acetone ND 4.8 ug/m3 04/21/22 19:40 1
Benzene ND 1.6 ug/m3 04/21/22 19:40 1
Benzyl chloride ND 7.8 ug/m3 04/21/22 19:40 1
Bromodichloromethane ND 3.4 ug/m3 04/21/22 19:40 1
Bromoform ND 5.2 ug/m3 04/21/22 19:40 1
Bromomethane ND 1.9 ug/m3 04/21/22 19:40 1
cis-1,2-Dichloroethene ND 2.0 ug/m3 04/21/22 19:40 1
cis-1,3-Dichloropropene ND 2.3 ug/m3 04/21/22 19:40 1
Carbon disulfide ND 6.2 ug/m3 04/21/22 19:40 1
Carbon tetrachloride ND 3.1 ug/m3 04/21/22 19:40 1
Chlorobenzene ND 2.3 ug/m3 04/21/22 19:40 1
Chloroethane ND 1.3 ug/m3 04/21/22 19:40 1
Chloroform ND 2.4 ug/m3 04/21/22 19:40 1
Chloromethane ND 1.0 ug/m3 04/21/22 19:40 1
Dibromochloromethane ND 4.3 ug/m3 04/21/22 19:40 1
Dichlorodifluoromethane ND 2.5 ug/m3 04/21/22 19:40 1
Dichlorotetrafluoroethane ND 14 ug/m3 04/21/22 19:40 1
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1794
QC Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Lab Sample ID: MB 570-228287/7 Client Sample ID: Method Blank Matrix: Air Prep Type: Total/NA
Analysis Batch: 228287
RL MDL
Ethylbenzene ND 2.2 ug/m3 04/21/22 19:40 1
MB MB
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac Hexachloro-1,3-butadiene ND 16 ug/m3 04/21/22 19:40 1
Isopropanol ND 12 ug/m3 04/21/22 19:40 1
Methylene Chloride ND 17 ug/m3 04/21/22 19:40 1
Methyl-t-Butyl Ether (MTBE) ND 7.2 ug/m3 04/21/22 19:40 1 n-Butylbenzene ND 8.2 ug/m3 04/21/22 19:40 1
o-Xylene ND 2.2 ug/m3 04/21/22 19:40 1
m,p-Xylene ND 8.7 ug/m3 04/21/22 19:40 1
sec-Butylbenzene ND 8.2 ug/m3 04/21/22 19:40 1
Styrene ND 6.4 ug/m3 04/21/22 19:40 1
trans-1,2-Dichloroethene ND 2.0 ug/m3 04/21/22 19:40 1
trans-1,3-Dichloropropene ND 4.5 ug/m3 04/21/22 19:40 1 tert-Butylbenzene ND 8.2 ug/m3 04/21/22 19:40 1
Tetrachloroethene ND 3.4 ug/m3 04/21/22 19:40 1
Toluene ND 1.9 ug/m3 04/21/22 19:40 1
Trichloroethene ND 2.7 ug/m3 04/21/22 19:40 1
Trichlorofluoromethane ND 5.6 ug/m3 04/21/22 19:40 1
Vinyl acetate ND 7.0 ug/m3 04/21/22 19:40 1
Vinyl chloride ND 1.3 ug/m3 04/21/22 19:40 1
1,2-Dichloroethane-d4 (Surr) 98 66 - 132 04/21/22 19:40 1 MB MB
Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 119 70 - 130 04/21/22 19:40 1 Toluene-d8 (Surr) 98 70 - 130 04/21/22 19:40 1
Lab Sample ID: LCS 570-228287/3 Client Sample ID: Lab Control Sample Matrix: Air Prep Type: Total/NA
Analysis Batch: 228287
1,1,1-Trichloroethane 25.0 24.26 ppb v/v 97 67 - 135
Analyte

LCS LCS
Result Qualifier Unit D %Rec
Spike
Added
%Rec
Limits
1,1,2,2-Tetrachloroethane 25.0 20.79 ppb v/v 83 70 - 130 1,1,2-Trichloro-1,2,2-trifluoroetha
ne

25.0 24.74 ppb v/v 99 70 - 130
1,1,2-Trichloroethane 25.0 23.43 ppb v/v 94 69 - 131
1,1-Dichloroethane 25.0 24.66 ppb v/v 99 69 - 130
1,1-Dichloroethene 25.0 23.25 ppb v/v 93 64 - 135
1,1-Difluoroethane 25.0 20.02 ppb v/v 80 57 - 146
1,2,4-Trichlorobenzene 25.0 20.34 ppb v/v 81 51 - 134
1,2,4-Trimethylbenzene 25.0 20.09 ppb v/v 80 68 - 130
1,2-Dibromo-3-Chloropropane 25.0 21.92 ppb v/v 88 66 - 130 1,2-Dibromoethane 25.0 21.89 ppb v/v 88 70 - 130
1,2-Dichlorobenzene 25.0 20.61 ppb v/v 82 68 - 130
1,2-Dichloroethane 25.0 23.09 ppb v/v 92 65 - 136
1,2-Dichloropropane 25.0 23.16 ppb v/v 93 68 - 132
1,3,5-Trimethylbenzene 25.0 20.27 ppb v/v 81 69 - 130
1,3-Dichlorobenzene 25.0 20.84 ppb v/v 83 65 - 130
1,4-Dichlorobenzene 25.0 20.96 ppb v/v 84 64 - 130
2-Butanone 25.0 23.66 ppb v/v 95 66 - 143
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1795
QC Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Lab Sample ID: LCS 570-228287/3 Client Sample ID: Lab Control Sample Matrix: Air Prep Type: Total/NA
Analysis Batch: 228287
2-Hexanone 25.0 20.86 ppb v/v 83 64 - 139
Analyte

LCS LCS
Result Qualifier Unit D %Rec
Spike
Added
%Rec
Limits
4-Ethyltoluene 25.0 20.68 ppb v/v 83 69 - 130
4-Methyl-2-pentanone 25.0 22.70 ppb v/v 91 65 - 135
Acetone 25.0 25.09 ppb v/v 100 70 - 130
Benzene 25.0 23.47 ppb v/v 94 68 - 134
Benzyl chloride 25.0 19.69 ppb v/v 79 70 - 130
Bromodichloromethane 25.0 22.64 ppb v/v 91 69 - 132
Bromoform 25.0 21.91 ppb v/v 88 70 - 130
Bromomethane 25.0 25.47 ppb v/v 102 65 - 130
cis-1,2-Dichloroethene 25.0 24.99 ppb v/v 100 70 - 130
cis-1,3-Dichloropropene 25.0 22.33 ppb v/v 89 70 - 134
Carbon disulfide 25.0 27.65 ppb v/v 111 70 - 130
Carbon tetrachloride 25.0 22.97 ppb v/v 92 68 - 133
Chlorobenzene 25.0 22.39 ppb v/v 90 70 - 130
Chloroethane 25.0 24.98 ppb v/v 100 66 - 134
Chloroform 25.0 24.28 ppb v/v 97 67 - 131
Chloromethane 25.0 23.04 ppb v/v 92 60 - 137
Dibromochloromethane 25.0 22.03 ppb v/v 88 70 - 130
Dichlorodifluoromethane 25.0 25.00 ppb v/v 100 57 - 138 Dichlorotetrafluoroethane 25.0 25.66 ppb v/v 103 60 - 133 Ethylbenzene 25.0 21.44 ppb v/v 86 70 - 130
Hexachloro-1,3-butadiene 25.0 20.49 ppb v/v 82 58 - 130 Isopropanol 25.0 22.77 ppb v/v 91 64 - 133
Methylene Chloride 25.0 24.56 ppb v/v 98 65 - 130
Methyl-t-Butyl Ether (MTBE) 25.0 24.74 ppb v/v 99 70 - 130 n-Butylbenzene 25.0 20.54 ppb v/v 82 64 - 130
o-Xylene 25.0 20.78 ppb v/v 83 68 - 130
m,p-Xylene 50.0 42.34 ppb v/v 85 70 - 130
sec-Butylbenzene 25.0 20.80 ppb v/v 83 67 - 130
Styrene 25.0 21.62 ppb v/v 86 70 - 130
trans-1,2-Dichloroethene 25.0 25.79 ppb v/v 103 70 - 130 trans-1,3-Dichloropropene 25.0 22.60 ppb v/v 90 66 - 142 tert-Butylbenzene 25.0 20.72 ppb v/v 83 70 - 130
Tetrachloroethene 25.0 22.65 ppb v/v 91 70 - 130
Toluene 25.0 21.80 ppb v/v 87 70 - 130
Trichloroethene 25.0 22.68 ppb v/v 91 69 - 130
Trichlorofluoromethane 25.0 24.70 ppb v/v 99 62 - 139
Vinyl acetate 25.0 23.40 ppb v/v 94 64 - 139
Vinyl chloride 25.0 25.53 ppb v/v 102 65 - 130
1,1,1-Trichloroethane 140 132.4 ug/m3 97 67 - 135
Analyte

LCS LCS
Result Qualifier Unit D %Rec
Spike
Added
%Rec
Limits
1,1,2,2-Tetrachloroethane 170 142.7 ug/m3 83 70 - 130
1,1,2-Trichloro-1,2,2-trifluoroetha
ne
190 189.6 ug/m3 99 70 - 130
1,1,2-Trichloroethane 140 127.8 ug/m3 94 69 - 131
1,1-Dichloroethane 100 99.83 ug/m3 99 69 - 130
1,1-Dichloroethene 99 92.20 ug/m3 93 64 - 135
1,1-Difluoroethane 68 54.09 ug/m3 80 57 - 146
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1796
QC Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Lab Sample ID: LCS 570-228287/3 Client Sample ID: Lab Control Sample Matrix: Air Prep Type: Total/NA
Analysis Batch: 228287
1,2,4-Trichlorobenzene 190 151.0 ug/m3 81 51 - 134
Analyte

LCS LCS
Result Qualifier Unit D %Rec
Spike
Added
%Rec
Limits
1,2,4-Trimethylbenzene 120 98.76 ug/m3 80 68 - 130
1,2-Dibromo-3-Chloropropane 240 211.9 ug/m3 88 66 - 130 1,2-Dibromoethane 190 168.2 ug/m3 88 70 - 130
1,2-Dichlorobenzene 150 123.9 ug/m3 82 68 - 130
1,2-Dichloroethane 100 93.44 ug/m3 92 65 - 136
1,2-Dichloropropane 120 107.0 ug/m3 93 68 - 132
1,3,5-Trimethylbenzene 120 99.63 ug/m3 81 69 - 130
1,3-Dichlorobenzene 150 125.3 ug/m3 83 65 - 130
1,4-Dichlorobenzene 150 126.0 ug/m3 84 64 - 130
2-Butanone 74 69.79 ug/m3 95 66 - 143
2-Hexanone 100 85.47 ug/m3 83 64 - 139
4-Ethyltoluene 120 101.7 ug/m3 83 69 - 130
4-Methyl-2-pentanone 100 92.99 ug/m3 91 65 - 135
Acetone 59 59.61 ug/m3 100 70 - 130
Benzene 80 74.99 ug/m3 94 68 - 134
Benzyl chloride 130 101.9 ug/m3 79 70 - 130
Bromodichloromethane 170 151.7 ug/m3 91 69 - 132
Bromoform 260 226.4 ug/m3 88 70 - 130
Bromomethane 97 98.91 ug/m3 102 65 - 130
cis-1,2-Dichloroethene 99 99.06 ug/m3 100 70 - 130
cis-1,3-Dichloropropene 110 101.3 ug/m3 89 70 - 134
Carbon disulfide 78 86.10 ug/m3 111 70 - 130
Carbon tetrachloride 160 144.5 ug/m3 92 68 - 133
Chlorobenzene 120 103.1 ug/m3 90 70 - 130
Chloroethane 66 65.91 ug/m3 100 66 - 134
Chloroform 120 118.5 ug/m3 97 67 - 131
Chloromethane 52 47.57 ug/m3 92 60 - 137
Dibromochloromethane 210 187.7 ug/m3 88 70 - 130
Dichlorodifluoromethane 120 123.6 ug/m3 100 57 - 138
Dichlorotetrafluoroethane 170 179.3 ug/m3 103 60 - 133
Ethylbenzene 110 93.12 ug/m3 86 70 - 130
Hexachloro-1,3-butadiene 270 218.5 ug/m3 82 58 - 130
Isopropanol 61 55.96 ug/m3 91 64 - 133
Methylene Chloride 87 85.30 ug/m3 98 65 - 130
Methyl-t-Butyl Ether (MTBE) 90 89.20 ug/m3 99 70 - 130
n-Butylbenzene 140 112.8 ug/m3 82 64 - 130
o-Xylene 110 90.24 ug/m3 83 68 - 130
m,p-Xylene 220 183.9 ug/m3 85 70 - 130
sec-Butylbenzene 140 114.2 ug/m3 83 67 - 130
Styrene 110 92.10 ug/m3 86 70 - 130
trans-1,2-Dichloroethene 99 102.3 ug/m3 103 70 - 130
trans-1,3-Dichloropropene 110 102.6 ug/m3 90 66 - 142
tert-Butylbenzene 140 113.7 ug/m3 83 70 - 130
Tetrachloroethene 170 153.7 ug/m3 91 70 - 130
Toluene 94 82.14 ug/m3 87 70 - 130
Trichloroethene 130 121.9 ug/m3 91 69 - 130
Trichlorofluoromethane 140 138.8 ug/m3 99 62 - 139
Vinyl acetate 88 82.38 ug/m3 94 64 - 139
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1797
QC Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Lab Sample ID: LCS 570-228287/3 Client Sample ID: Lab Control Sample Matrix: Air Prep Type: Total/NA
Analysis Batch: 228287
Vinyl chloride 64 65.26 ug/m3 102 65 - 130
Analyte

LCS LCS
Result Qualifier Unit D %Rec
Spike
Added
%Rec
Limits
1,2-Dichloroethane-d4 (Surr) 66 - 132
Surrogate
97 LCS LCS
%Recovery Qualifier Limits
4-Bromofluorobenzene (Surr) 109 70 - 130
Toluene-d8 (Surr) 100 70 - 130
Lab Sample ID: LCSD 570-228287/4 Client Sample ID: Lab Control Sample Dup Matrix: Air Prep Type: Total/NA
Analysis Batch: 228287
1,1,1-Trichloroethane 25.0 23.08 ppb v/v 92 67 - 135 5 25 Analyte

LCSD LCSD
Result Qualifier Unit D %Rec
Spike
Added
%Rec
Limits RPD Limit
RPD
1,1,2,2-Tetrachloroethane 25.0 20.44 ppb v/v 82 70 - 130 2 25 1,1,2-Trichloro-1,2,2-trifluoroetha
ne

25.0 23.34 ppb v/v 93 70 - 130 6 25
1,1,2-Trichloroethane 25.0 22.11 ppb v/v 88 69 - 131 6 25 1,1-Dichloroethane 25.0 23.28 ppb v/v 93 69 - 130 6 25
1,1-Dichloroethene 25.0 21.91 ppb v/v 88 64 - 135 6 25
1,1-Difluoroethane 25.0 18.19 ppb v/v 73 57 - 146 10 25 1,2,4-Trichlorobenzene 25.0 20.27 ppb v/v 81 51 - 134 0 25 1,2,4-Trimethylbenzene 25.0 19.73 ppb v/v 79 68 - 130 2 25 1,2-Dibromo-3-Chloropropane 25.0 21.93 ppb v/v 88 66 - 130 0 25 1,2-Dibromoethane 25.0 21.45 ppb v/v 86 70 - 130 2 25
1,2-Dichlorobenzene 25.0 20.33 ppb v/v 81 68 - 130 1 25 1,2-Dichloroethane 25.0 21.94 ppb v/v 88 65 - 136 5 25
1,2-Dichloropropane 25.0 21.68 ppb v/v 87 68 - 132 7 25 1,3,5-Trimethylbenzene 25.0 19.80 ppb v/v 79 69 - 130 2 25 1,3-Dichlorobenzene 25.0 20.77 ppb v/v 83 65 - 130 0 25 1,4-Dichlorobenzene 25.0 20.66 ppb v/v 83 64 - 130 1 25 2-Butanone 25.0 22.13 ppb v/v 89 66 - 143 7 25
2-Hexanone 25.0 20.55 ppb v/v 82 64 - 139 1 25
4-Ethyltoluene 25.0 20.23 ppb v/v 81 69 - 130 2 25
4-Methyl-2-pentanone 25.0 20.99 ppb v/v 84 65 - 135 8 25 Acetone 25.0 23.82 ppb v/v 95 70 - 130 5 25
Benzene 25.0 22.03 ppb v/v 88 68 - 134 6 25
Benzyl chloride 25.0 19.62 ppb v/v 78 70 - 130 0 25
Bromodichloromethane 25.0 21.20 ppb v/v 85 69 - 132 7 25 Bromoform 25.0 21.56 ppb v/v 86 70 - 130 2 25
Bromomethane 25.0 24.11 ppb v/v 96 65 - 130 6 25
cis-1,2-Dichloroethene 25.0 23.84 ppb v/v 95 70 - 130 5 25 cis-1,3-Dichloropropene 25.0 20.96 ppb v/v 84 70 - 134 6 25 Carbon disulfide 25.0 26.17 ppb v/v 105 70 - 130 6 25
Carbon tetrachloride 25.0 21.65 ppb v/v 87 68 - 133 6 25 Chlorobenzene 25.0 21.12 ppb v/v 84 70 - 130 6 25
Chloroethane 25.0 23.49 ppb v/v 94 66 - 134 6 25
Chloroform 25.0 23.06 ppb v/v 92 67 - 131 5 25
Chloromethane 25.0 21.53 ppb v/v 86 60 - 137 7 25
Dibromochloromethane 25.0 21.38 ppb v/v 86 70 - 130 3 25 Eurofins Calscience

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1798
QC Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Lab Sample ID: LCSD 570-228287/4 Client Sample ID: Lab Control Sample Dup Matrix: Air Prep Type: Total/NA
Analysis Batch: 228287
Dichlorodifluoromethane 25.0 23.52 ppb v/v 94 57 - 138 6 25 Analyte

LCSD LCSD
Result Qualifier Unit D %Rec
Spike
Added
%Rec
Limits RPD Limit
RPD
Dichlorotetrafluoroethane 25.0 23.96 ppb v/v 96 60 - 133 7 25 Ethylbenzene 25.0 21.05 ppb v/v 84 70 - 130 2 25
Hexachloro-1,3-butadiene 25.0 19.97 ppb v/v 80 58 - 130 3 25 Isopropanol 25.0 21.27 ppb v/v 85 64 - 133 7 25
Methylene Chloride 25.0 23.30 ppb v/v 93 65 - 130 5 25
Methyl-t-Butyl Ether (MTBE) 25.0 23.56 ppb v/v 94 70 - 130 5 25 n-Butylbenzene 25.0 20.29 ppb v/v 81 64 - 130 1 25
o-Xylene 25.0 20.29 ppb v/v 81 68 - 130 2 25
m,p-Xylene 50.0 41.07 ppb v/v 82 70 - 130 3 25
sec-Butylbenzene 25.0 20.26 ppb v/v 81 67 - 130 3 25
Styrene 25.0 21.26 ppb v/v 85 70 - 130 2 25
trans-1,2-Dichloroethene 25.0 24.77 ppb v/v 99 70 - 130 4 25 trans-1,3-Dichloropropene 25.0 21.31 ppb v/v 85 66 - 142 6 25 tert-Butylbenzene 25.0 20.25 ppb v/v 81 70 - 130 2 25
Tetrachloroethene 25.0 22.06 ppb v/v 88 70 - 130 3 25
Toluene 25.0 21.31 ppb v/v 85 70 - 130 2 25
Trichloroethene 25.0 21.23 ppb v/v 85 69 - 130 7 25
Trichlorofluoromethane 25.0 23.56 ppb v/v 94 62 - 139 5 25 Vinyl acetate 25.0 22.08 ppb v/v 88 64 - 139 6 25
Vinyl chloride 25.0 23.85 ppb v/v 95 65 - 130 7 25
1,1,1-Trichloroethane 140 126.0 ug/m3 92 67 - 135 5 25
Analyte

LCSD LCSD
Result Qualifier Unit D %Rec
Spike
Added
%Rec
Limits RPD Limit
RPD
1,1,2,2-Tetrachloroethane 170 140.3 ug/m3 82 70 - 130 2 25 1,1,2-Trichloro-1,2,2-trifluoroetha
ne
190 178.8 ug/m3 93 70 - 130 6 25
1,1,2-Trichloroethane 140 120.6 ug/m3 88 69 - 131 6 25
1,1-Dichloroethane 100 94.23 ug/m3 93 69 - 130 6 25
1,1-Dichloroethene 99 86.86 ug/m3 88 64 - 135 6 25
1,1-Difluoroethane 68 49.13 ug/m3 73 57 - 146 10 25
1,2,4-Trichlorobenzene 190 150.4 ug/m3 81 51 - 134 0 25 1,2,4-Trimethylbenzene 120 97.00 ug/m3 79 68 - 130 2 25 1,2-Dibromo-3-Chloropropane 240 212.0 ug/m3 88 66 - 130 0 25 1,2-Dibromoethane 190 164.9 ug/m3 86 70 - 130 2 25
1,2-Dichlorobenzene 150 122.2 ug/m3 81 68 - 130 1 25
1,2-Dichloroethane 100 88.80 ug/m3 88 65 - 136 5 25
1,2-Dichloropropane 120 100.2 ug/m3 87 68 - 132 7 25
1,3,5-Trimethylbenzene 120 97.36 ug/m3 79 69 - 130 2 25 1,3-Dichlorobenzene 150 124.9 ug/m3 83 65 - 130 0 25
1,4-Dichlorobenzene 150 124.2 ug/m3 83 64 - 130 1 25
2-Butanone 74 65.26 ug/m3 89 66 - 143 7 25
2-Hexanone 100 84.22 ug/m3 82 64 - 139 1 25
4-Ethyltoluene 120 99.46 ug/m3 81 69 - 130 2 25
4-Methyl-2-pentanone 100 85.99 ug/m3 84 65 - 135 8 25
Acetone 59 56.58 ug/m3 95 70 - 130 5 25
Benzene 80 70.38 ug/m3 88 68 - 134 6 25
Benzyl chloride 130 101.6 ug/m3 78 70 - 130 0 25
Bromodichloromethane 170 142.1 ug/m3 85 69 - 132 7 25
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1799
QC Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Lab Sample ID: LCSD 570-228287/4 Client Sample ID: Lab Control Sample Dup Matrix: Air Prep Type: Total/NA
Analysis Batch: 228287
Bromoform 260 222.9 ug/m3 86 70 - 130 2 25
Analyte

LCSD LCSD
Result Qualifier Unit D %Rec
Spike
Added
%Rec
Limits RPD Limit
RPD
Bromomethane 97 93.61 ug/m3 96 65 - 130 6 25
cis-1,2-Dichloroethene 99 94.51 ug/m3 95 70 - 130 5 25
cis-1,3-Dichloropropene 110 95.11 ug/m3 84 70 - 134 6 25 Carbon disulfide 78 81.49 ug/m3 105 70 - 130 6 25
Carbon tetrachloride 160 136.2 ug/m3 87 68 - 133 6 25
Chlorobenzene 120 97.24 ug/m3 84 70 - 130 6 25
Chloroethane 66 61.99 ug/m3 94 66 - 134 6 25
Chloroform 120 112.6 ug/m3 92 67 - 131 5 25
Chloromethane 52 44.45 ug/m3 86 60 - 137 7 25
Dibromochloromethane 210 182.1 ug/m3 86 70 - 130 3 25
Dichlorodifluoromethane 120 116.3 ug/m3 94 57 - 138 6 25 Dichlorotetrafluoroethane 170 167.5 ug/m3 96 60 - 133 7 25 Ethylbenzene 110 91.42 ug/m3 84 70 - 130 2 25
Hexachloro-1,3-butadiene 270 213.0 ug/m3 80 58 - 130 3 25 Isopropanol 61 52.29 ug/m3 85 64 - 133 7 25
Methylene Chloride 87 80.94 ug/m3 93 65 - 130 5 25
Methyl-t-Butyl Ether (MTBE) 90 84.95 ug/m3 94 70 - 130 5 25 n-Butylbenzene 140 111.4 ug/m3 81 64 - 130 1 25
o-Xylene 110 88.11 ug/m3 81 68 - 130 2 25
m,p-Xylene 220 178.3 ug/m3 82 70 - 130 3 25
sec-Butylbenzene 140 111.2 ug/m3 81 67 - 130 3 25
Styrene 110 90.56 ug/m3 85 70 - 130 2 25
trans-1,2-Dichloroethene 99 98.21 ug/m3 99 70 - 130 4 25 trans-1,3-Dichloropropene 110 96.71 ug/m3 85 66 - 142 6 25 tert-Butylbenzene 140 111.2 ug/m3 81 70 - 130 2 25
Tetrachloroethene 170 149.6 ug/m3 88 70 - 130 3 25
Toluene 94 80.30 ug/m3 85 70 - 130 2 25
Trichloroethene 130 114.1 ug/m3 85 69 - 130 7 25
Trichlorofluoromethane 140 132.4 ug/m3 94 62 - 139 5 25 Vinyl acetate 88 77.75 ug/m3 88 64 - 139 6 25
Vinyl chloride 64 60.98 ug/m3 95 65 - 130 7 25
1,2-Dichloroethane-d4 (Surr) 66 - 132
Surrogate
98 LCSD LCSD
%Recovery Qualifier Limits
4-Bromofluorobenzene (Surr) 114 70 - 130
Toluene-d8 (Surr) 101 70 - 130
Lab Sample ID: MB 570-228550/8 Client Sample ID: Method Blank Matrix: Air Prep Type: Total/NA
Analysis Batch: 228550
RL MDL
1,1,1-Trichloroethane ND 0.50 ppb v/v 04/22/22 21:48 1
MB MB
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 1.0 ppb v/v 04/22/22 21:48 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 1.5 ppb v/v 04/22/22 21:48 1 1,1,2-Trichloroethane ND 0.50 ppb v/v 04/22/22 21:48 1
1,1-Dichloroethane ND 0.50 ppb v/v 04/22/22 21:48 1
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1800
QC Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Lab Sample ID: MB 570-228550/8 Client Sample ID: Method Blank Matrix: Air Prep Type: Total/NA
Analysis Batch: 228550
RL MDL
1,1-Dichloroethene ND 0.50 ppb v/v 04/22/22 21:48 1
MB MB
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1-Difluoroethane ND 2.0 ppb v/v 04/22/22 21:48 1
1,2,4-Trichlorobenzene ND 2.0 ppb v/v 04/22/22 21:48 1
1,2,4-Trimethylbenzene ND 1.5 ppb v/v 04/22/22 21:48 1
1,2-Dibromo-3-Chloropropane ND 1.5 ppb v/v 04/22/22 21:48 1 1,2-Dibromoethane ND 0.50 ppb v/v 04/22/22 21:48 1
1,2-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 21:48 1
1,2-Dichloroethane ND 0.50 ppb v/v 04/22/22 21:48 1
1,2-Dichloropropane ND 0.50 ppb v/v 04/22/22 21:48 1
1,3,5-Trimethylbenzene ND 0.50 ppb v/v 04/22/22 21:48 1 1,3-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 21:48 1
1,4-Dichlorobenzene ND 0.50 ppb v/v 04/22/22 21:48 1
2-Butanone ND 1.5 ppb v/v 04/22/22 21:48 1
2-Hexanone ND 1.5 ppb v/v 04/22/22 21:48 1
4-Ethyltoluene ND 0.50 ppb v/v 04/22/22 21:48 1
4-Methyl-2-pentanone ND 1.5 ppb v/v 04/22/22 21:48 1
Acetone ND 2.0 ppb v/v 04/22/22 21:48 1
Benzene ND 0.50 ppb v/v 04/22/22 21:48 1
Benzyl chloride ND 1.5 ppb v/v 04/22/22 21:48 1
Bromodichloromethane ND 0.50 ppb v/v 04/22/22 21:48 1
Bromoform ND 0.50 ppb v/v 04/22/22 21:48 1
Bromomethane ND 0.50 ppb v/v 04/22/22 21:48 1
cis-1,2-Dichloroethene ND 0.50 ppb v/v 04/22/22 21:48 1 cis-1,3-Dichloropropene ND 0.50 ppb v/v 04/22/22 21:48 1 Carbon disulfide ND 2.0 ppb v/v 04/22/22 21:48 1
Carbon tetrachloride ND 0.50 ppb v/v 04/22/22 21:48 1
Chlorobenzene ND 0.50 ppb v/v 04/22/22 21:48 1
Chloroethane ND 0.50 ppb v/v 04/22/22 21:48 1
Chloroform ND 0.50 ppb v/v 04/22/22 21:48 1
Chloromethane ND 0.50 ppb v/v 04/22/22 21:48 1
Dibromochloromethane ND 0.50 ppb v/v 04/22/22 21:48 1
Dichlorodifluoromethane ND 0.50 ppb v/v 04/22/22 21:48 1 Dichlorotetrafluoroethane ND 2.0 ppb v/v 04/22/22 21:48 1 Ethylbenzene ND 0.50 ppb v/v 04/22/22 21:48 1
Hexachloro-1,3-butadiene ND 1.5 ppb v/v 04/22/22 21:48 1 Isopropanol ND 5.0 ppb v/v 04/22/22 21:48 1
Methylene Chloride ND 5.0 ppb v/v 04/22/22 21:48 1
Methyl-t-Butyl Ether (MTBE) ND 2.0 ppb v/v 04/22/22 21:48 1 n-Butylbenzene ND 1.5 ppb v/v 04/22/22 21:48 1
o-Xylene ND 0.50 ppb v/v 04/22/22 21:48 1
m,p-Xylene ND 2.0 ppb v/v 04/22/22 21:48 1
sec-Butylbenzene ND 1.5 ppb v/v 04/22/22 21:48 1
Styrene ND 1.5 ppb v/v 04/22/22 21:48 1
trans-1,2-Dichloroethene ND 0.50 ppb v/v 04/22/22 21:48 1 trans-1,3-Dichloropropene ND 1.0 ppb v/v 04/22/22 21:48 1 tert-Butylbenzene ND 1.5 ppb v/v 04/22/22 21:48 1
Tetrachloroethene ND 0.50 ppb v/v 04/22/22 21:48 1
Toluene ND 0.50 ppb v/v 04/22/22 21:48 1
Trichloroethene ND 0.50 ppb v/v 04/22/22 21:48 1
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1801
QC Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Lab Sample ID: MB 570-228550/8 Client Sample ID: Method Blank Matrix: Air Prep Type: Total/NA
Analysis Batch: 228550
RL MDL
Trichlorofluoromethane ND 1.0 ppb v/v 04/22/22 21:48 1
MB MB
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac Vinyl acetate ND 2.0 ppb v/v 04/22/22 21:48 1
Vinyl chloride ND 0.50 ppb v/v 04/22/22 21:48 1
RL MDL
1,1,1-Trichloroethane ND 2.7 ug/m3 04/22/22 21:48 1
MB MB
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane ND 6.9 ug/m3 04/22/22 21:48 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 11 ug/m3 04/22/22 21:48 1 1,1,2-Trichloroethane ND 2.7 ug/m3 04/22/22 21:48 1
1,1-Dichloroethane ND 2.0 ug/m3 04/22/22 21:48 1
1,1-Dichloroethene ND 2.0 ug/m3 04/22/22 21:48 1
1,1-Difluoroethane ND 5.4 ug/m3 04/22/22 21:48 1
1,2,4-Trichlorobenzene ND 15 ug/m3 04/22/22 21:48 1
1,2,4-Trimethylbenzene ND 7.4 ug/m3 04/22/22 21:48 1
1,2-Dibromo-3-Chloropropane ND 14 ug/m3 04/22/22 21:48 1 1,2-Dibromoethane ND 3.8 ug/m3 04/22/22 21:48 1
1,2-Dichlorobenzene ND 3.0 ug/m3 04/22/22 21:48 1
1,2-Dichloroethane ND 2.0 ug/m3 04/22/22 21:48 1
1,2-Dichloropropane ND 2.3 ug/m3 04/22/22 21:48 1
1,3,5-Trimethylbenzene ND 2.5 ug/m3 04/22/22 21:48 1
1,3-Dichlorobenzene ND 3.0 ug/m3 04/22/22 21:48 1
1,4-Dichlorobenzene ND 3.0 ug/m3 04/22/22 21:48 1
2-Butanone ND 4.4 ug/m3 04/22/22 21:48 1
2-Hexanone ND 6.1 ug/m3 04/22/22 21:48 1
4-Ethyltoluene ND 2.5 ug/m3 04/22/22 21:48 1
4-Methyl-2-pentanone ND 6.1 ug/m3 04/22/22 21:48 1
Acetone ND 4.8 ug/m3 04/22/22 21:48 1
Benzene ND 1.6 ug/m3 04/22/22 21:48 1
Benzyl chloride ND 7.8 ug/m3 04/22/22 21:48 1
Bromodichloromethane ND 3.4 ug/m3 04/22/22 21:48 1
Bromoform ND 5.2 ug/m3 04/22/22 21:48 1
Bromomethane ND 1.9 ug/m3 04/22/22 21:48 1
cis-1,2-Dichloroethene ND 2.0 ug/m3 04/22/22 21:48 1
cis-1,3-Dichloropropene ND 2.3 ug/m3 04/22/22 21:48 1
Carbon disulfide ND 6.2 ug/m3 04/22/22 21:48 1
Carbon tetrachloride ND 3.1 ug/m3 04/22/22 21:48 1
Chlorobenzene ND 2.3 ug/m3 04/22/22 21:48 1
Chloroethane ND 1.3 ug/m3 04/22/22 21:48 1
Chloroform ND 2.4 ug/m3 04/22/22 21:48 1
Chloromethane ND 1.0 ug/m3 04/22/22 21:48 1
Dibromochloromethane ND 4.3 ug/m3 04/22/22 21:48 1
Dichlorodifluoromethane ND 2.5 ug/m3 04/22/22 21:48 1
Dichlorotetrafluoroethane ND 14 ug/m3 04/22/22 21:48 1
Ethylbenzene ND 2.2 ug/m3 04/22/22 21:48 1
Hexachloro-1,3-butadiene ND 16 ug/m3 04/22/22 21:48 1
Isopropanol ND 12 ug/m3 04/22/22 21:48 1
Methylene Chloride ND 17 ug/m3 04/22/22 21:48 1
Methyl-t-Butyl Ether (MTBE) ND 7.2 ug/m3 04/22/22 21:48 1 n-Butylbenzene ND 8.2 ug/m3 04/22/22 21:48 1
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1802
QC Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Lab Sample ID: MB 570-228550/8 Client Sample ID: Method Blank Matrix: Air Prep Type: Total/NA
Analysis Batch: 228550
RL MDL
o-Xylene ND 2.2 ug/m3 04/22/22 21:48 1
MB MB
Analyte Result Qualifier Unit D Prepared Analyzed Dil Fac m,p-Xylene ND 8.7 ug/m3 04/22/22 21:48 1
sec-Butylbenzene ND 8.2 ug/m3 04/22/22 21:48 1
Styrene ND 6.4 ug/m3 04/22/22 21:48 1
trans-1,2-Dichloroethene ND 2.0 ug/m3 04/22/22 21:48 1
trans-1,3-Dichloropropene ND 4.5 ug/m3 04/22/22 21:48 1 tert-Butylbenzene ND 8.2 ug/m3 04/22/22 21:48 1
Tetrachloroethene ND 3.4 ug/m3 04/22/22 21:48 1
Toluene ND 1.9 ug/m3 04/22/22 21:48 1
Trichloroethene ND 2.7 ug/m3 04/22/22 21:48 1
Trichlorofluoromethane ND 5.6 ug/m3 04/22/22 21:48 1
Vinyl acetate ND 7.0 ug/m3 04/22/22 21:48 1
Vinyl chloride ND 1.3 ug/m3 04/22/22 21:48 1
1,2-Dichloroethane-d4 (Surr) 96 66 - 132 04/22/22 21:48 1 MB MB
Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 128 70 - 130 04/22/22 21:48 1 Toluene-d8 (Surr) 99 70 - 130 04/22/22 21:48 1
Lab Sample ID: LCS 570-228550/4 Client Sample ID: Lab Control Sample Matrix: Air Prep Type: Total/NA
Analysis Batch: 228550
1,1,1-Trichloroethane 25.0 22.05 ppb v/v 88 67 - 135
Analyte

LCS LCS
Result Qualifier Unit D %Rec
Spike
Added
%Rec
Limits
1,1,2,2-Tetrachloroethane 25.0 18.94 ppb v/v 76 70 - 130 1,1,2-Trichloro-1,2,2-trifluoroetha
ne

25.0 22.61 ppb v/v 90 70 - 130
1,1,2-Trichloroethane 25.0 21.47 ppb v/v 86 69 - 131
1,1-Dichloroethane 25.0 21.72 ppb v/v 87 69 - 130
1,1-Dichloroethene 25.0 21.47 ppb v/v 86 64 - 135
1,1-Difluoroethane 25.0 18.24 ppb v/v 73 57 - 146
1,2,4-Trichlorobenzene 25.0 15.50 ppb v/v 62 51 - 134
1,2,4-Trimethylbenzene 25.0 17.89 ppb v/v 72 68 - 130
1,2-Dibromo-3-Chloropropane 25.0 17.14 ppb v/v 69 66 - 130 1,2-Dibromoethane 25.0 19.88 ppb v/v 80 70 - 130
1,2-Dichlorobenzene 25.0 18.06 ppb v/v 72 68 - 130
1,2-Dichloroethane 25.0 20.70 ppb v/v 83 65 - 136
1,2-Dichloropropane 25.0 21.07 ppb v/v 84 68 - 132
1,3,5-Trimethylbenzene 25.0 18.19 ppb v/v 73 69 - 130
1,3-Dichlorobenzene 25.0 19.11 ppb v/v 76 65 - 130
1,4-Dichlorobenzene 25.0 18.76 ppb v/v 75 64 - 130
2-Butanone 25.0 20.94 ppb v/v 84 66 - 143
2-Hexanone 25.0 19.02 ppb v/v 76 64 - 139
4-Ethyltoluene 25.0 18.69 ppb v/v 75 69 - 130
4-Methyl-2-pentanone 25.0 20.64 ppb v/v 83 65 - 135
Acetone 25.0 20.93 ppb v/v 84 70 - 130
Benzene 25.0 21.26 ppb v/v 85 68 - 134
Benzyl chloride 25.0 17.39 ppb v/v 70 70 - 130
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1803
QC Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Lab Sample ID: LCS 570-228550/4 Client Sample ID: Lab Control Sample Matrix: Air Prep Type: Total/NA
Analysis Batch: 228550
Bromodichloromethane 25.0 20.96 ppb v/v 84 69 - 132
Analyte

LCS LCS
Result Qualifier Unit D %Rec
Spike
Added
%Rec
Limits
Bromoform 25.0 20.48 ppb v/v 82 70 - 130
Bromomethane 25.0 22.84 ppb v/v 91 65 - 130
cis-1,2-Dichloroethene 25.0 22.84 ppb v/v 91 70 - 130
cis-1,3-Dichloropropene 25.0 21.54 ppb v/v 86 70 - 134
Carbon disulfide 25.0 21.11 ppb v/v 84 70 - 130
Carbon tetrachloride 25.0 21.05 ppb v/v 84 68 - 133
Chlorobenzene 25.0 20.04 ppb v/v 80 70 - 130
Chloroethane 25.0 22.51 ppb v/v 90 66 - 134
Chloroform 25.0 21.78 ppb v/v 87 67 - 131
Chloromethane 25.0 21.09 ppb v/v 84 60 - 137
Dibromochloromethane 25.0 20.16 ppb v/v 81 70 - 130
Dichlorodifluoromethane 25.0 22.36 ppb v/v 89 57 - 138
Dichlorotetrafluoroethane 25.0 22.52 ppb v/v 90 60 - 133 Ethylbenzene 25.0 19.70 ppb v/v 79 70 - 130
Hexachloro-1,3-butadiene 25.0 15.63 ppb v/v 63 58 - 130 Isopropanol 25.0 20.51 ppb v/v 82 64 - 133
Methylene Chloride 25.0 22.43 ppb v/v 90 65 - 130
Methyl-t-Butyl Ether (MTBE) 25.0 22.07 ppb v/v 88 70 - 130 n-Butylbenzene 25.0 17.59 ppb v/v 70 64 - 130
o-Xylene 25.0 19.07 ppb v/v 76 68 - 130
m,p-Xylene 50.0 38.28 ppb v/v 77 70 - 130
sec-Butylbenzene 25.0 18.21 ppb v/v 73 67 - 130
Styrene 25.0 19.64 ppb v/v 79 70 - 130
trans-1,2-Dichloroethene 25.0 21.54 ppb v/v 86 70 - 130 trans-1,3-Dichloropropene 25.0 21.01 ppb v/v 84 66 - 142 tert-Butylbenzene 25.0 18.51 ppb v/v 74 70 - 130
Tetrachloroethene 25.0 20.56 ppb v/v 82 70 - 130
Toluene 25.0 19.65 ppb v/v 79 70 - 130
Trichloroethene 25.0 20.97 ppb v/v 84 69 - 130
Trichlorofluoromethane 25.0 22.10 ppb v/v 88 62 - 139
Vinyl acetate 25.0 21.09 ppb v/v 84 64 - 139
Vinyl chloride 25.0 22.81 ppb v/v 91 65 - 130
1,1,1-Trichloroethane 140 120.3 ug/m3 88 67 - 135
Analyte

LCS LCS
Result Qualifier Unit D %Rec
Spike
Added
%Rec
Limits
1,1,2,2-Tetrachloroethane 170 130.0 ug/m3 76 70 - 130
1,1,2-Trichloro-1,2,2-trifluoroetha
ne
190 173.2 ug/m3 90 70 - 130
1,1,2-Trichloroethane 140 117.2 ug/m3 86 69 - 131
1,1-Dichloroethane 100 87.90 ug/m3 87 69 - 130
1,1-Dichloroethene 99 85.14 ug/m3 86 64 - 135
1,1-Difluoroethane 68 49.27 ug/m3 73 57 - 146
1,2,4-Trichlorobenzene 190 115.1 ug/m3 62 51 - 134
1,2,4-Trimethylbenzene 120 87.96 ug/m3 72 68 - 130
1,2-Dibromo-3-Chloropropane 240 165.6 ug/m3 69 66 - 130 1,2-Dibromoethane 190 152.8 ug/m3 80 70 - 130
1,2-Dichlorobenzene 150 108.6 ug/m3 72 68 - 130
1,2-Dichloroethane 100 83.79 ug/m3 83 65 - 136
Eurofins Calscience

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1804
QC Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Lab Sample ID: LCS 570-228550/4 Client Sample ID: Lab Control Sample Matrix: Air Prep Type: Total/NA
Analysis Batch: 228550
1,2-Dichloropropane 120 97.39 ug/m3 84 68 - 132
Analyte

LCS LCS
Result Qualifier Unit D %Rec
Spike
Added
%Rec
Limits
1,3,5-Trimethylbenzene 120 89.43 ug/m3 73 69 - 130
1,3-Dichlorobenzene 150 114.9 ug/m3 76 65 - 130
1,4-Dichlorobenzene 150 112.8 ug/m3 75 64 - 130
2-Butanone 74 61.76 ug/m3 84 66 - 143
2-Hexanone 100 77.95 ug/m3 76 64 - 139
4-Ethyltoluene 120 91.91 ug/m3 75 69 - 130
4-Methyl-2-pentanone 100 84.53 ug/m3 83 65 - 135
Acetone 59 49.71 ug/m3 84 70 - 130
Benzene 80 67.91 ug/m3 85 68 - 134
Benzyl chloride 130 90.01 ug/m3 70 70 - 130
Bromodichloromethane 170 140.4 ug/m3 84 69 - 132
Bromoform 260 211.7 ug/m3 82 70 - 130
Bromomethane 97 88.69 ug/m3 91 65 - 130
cis-1,2-Dichloroethene 99 90.57 ug/m3 91 70 - 130
cis-1,3-Dichloropropene 110 97.76 ug/m3 86 70 - 134
Carbon disulfide 78 65.73 ug/m3 84 70 - 130
Carbon tetrachloride 160 132.4 ug/m3 84 68 - 133
Chlorobenzene 120 92.24 ug/m3 80 70 - 130
Chloroethane 66 59.41 ug/m3 90 66 - 134
Chloroform 120 106.3 ug/m3 87 67 - 131
Chloromethane 52 43.55 ug/m3 84 60 - 137
Dibromochloromethane 210 171.7 ug/m3 81 70 - 130
Dichlorodifluoromethane 120 110.6 ug/m3 89 57 - 138
Dichlorotetrafluoroethane 170 157.4 ug/m3 90 60 - 133
Ethylbenzene 110 85.54 ug/m3 79 70 - 130
Hexachloro-1,3-butadiene 270 166.7 ug/m3 63 58 - 130
Isopropanol 61 50.43 ug/m3 82 64 - 133
Methylene Chloride 87 77.90 ug/m3 90 65 - 130
Methyl-t-Butyl Ether (MTBE) 90 79.58 ug/m3 88 70 - 130
n-Butylbenzene 140 96.54 ug/m3 70 64 - 130
o-Xylene 110 82.80 ug/m3 76 68 - 130
m,p-Xylene 220 166.2 ug/m3 77 70 - 130
sec-Butylbenzene 140 99.97 ug/m3 73 67 - 130
Styrene 110 83.65 ug/m3 79 70 - 130
trans-1,2-Dichloroethene 99 85.39 ug/m3 86 70 - 130
trans-1,3-Dichloropropene 110 95.34 ug/m3 84 66 - 142
tert-Butylbenzene 140 101.6 ug/m3 74 70 - 130
Tetrachloroethene 170 139.4 ug/m3 82 70 - 130
Toluene 94 74.04 ug/m3 79 70 - 130
Trichloroethene 130 112.7 ug/m3 84 69 - 130
Trichlorofluoromethane 140 124.2 ug/m3 88 62 - 139
Vinyl acetate 88 74.26 ug/m3 84 64 - 139
Vinyl chloride 64 58.31 ug/m3 91 65 - 130
1,2-Dichloroethane-d4 (Surr) 66 - 132
Surrogate
100

LCS LCS
%Recovery Qualifier Limits
4-Bromofluorobenzene (Surr) 115 70 - 130
Eurofins Calscience

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1805
QC Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Lab Sample ID: LCS 570-228550/4 Client Sample ID: Lab Control Sample Matrix: Air Prep Type: Total/NA
Analysis Batch: 228550
Toluene-d8 (Surr) 70 - 130
Surrogate
102

LCS LCS
%Recovery Qualifier Limits
Lab Sample ID: LCSD 570-228550/5 Client Sample ID: Lab Control Sample Dup Matrix: Air Prep Type: Total/NA
Analysis Batch: 228550
1,1,1-Trichloroethane 25.0 20.98 ppb v/v 84 67 - 135 5 25 Analyte

LCSD LCSD
Result Qualifier Unit D %Rec
Spike
Added
%Rec
Limits RPD Limit
RPD
1,1,2,2-Tetrachloroethane 25.0 18.49 ppb v/v 74 70 - 130 2 25 1,1,2-Trichloro-1,2,2-trifluoroetha
ne

25.0 21.40 ppb v/v 86 70 - 130 5 25
1,1,2-Trichloroethane 25.0 20.30 ppb v/v 81 69 - 131 6 25 1,1-Dichloroethane 25.0 20.54 ppb v/v 82 69 - 130 6 25
1,1-Dichloroethene 25.0 20.14 ppb v/v 81 64 - 135 6 25
1,1-Difluoroethane 25.0 17.08 ppb v/v 68 57 - 146 7 25
1,2,4-Trichlorobenzene 25.0 17.35 ppb v/v 69 51 - 134 11 25 1,2,4-Trimethylbenzene 25.0 17.27 ppb v/v 69 68 - 130 4 25 1,2-Dibromo-3-Chloropropane 25.0 17.87 ppb v/v 71 66 - 130 4 25 1,2-Dibromoethane 25.0 18.84 ppb v/v 75 70 - 130 5 25
1,2-Dichlorobenzene 25.0 17.74 ppb v/v 71 68 - 130 2 25 1,2-Dichloroethane 25.0 19.72 ppb v/v 79 65 - 136 5 25
1,2-Dichloropropane 25.0 19.80 ppb v/v 79 68 - 132 6 25 1,3,5-Trimethylbenzene 25.0 17.67 ppb v/v 71 69 - 130 3 25 1,3-Dichlorobenzene 25.0 18.39 ppb v/v 74 65 - 130 4 25 1,4-Dichlorobenzene 25.0 18.33 ppb v/v 73 64 - 130 2 25 2-Butanone 25.0 19.90 ppb v/v 80 66 - 143 5 25
2-Hexanone 25.0 18.37 ppb v/v 73 64 - 139 3 25
4-Ethyltoluene 25.0 18.06 ppb v/v 72 69 - 130 3 25
4-Methyl-2-pentanone 25.0 19.26 ppb v/v 77 65 - 135 7 25 Acetone 25.0 19.91 ppb v/v 80 70 - 130 5 25
Benzene 25.0 20.00 ppb v/v 80 68 - 134 6 25
Benzyl chloride 25.0 16.94 *- me ppb v/v 68 70 - 130 3 25 Bromodichloromethane 25.0 19.77 ppb v/v 79 69 - 132 6 25 Bromoform 25.0 19.72 ppb v/v 79 70 - 130 4 25
Bromomethane 25.0 21.59 ppb v/v 86 65 - 130 6 25
cis-1,2-Dichloroethene 25.0 21.63 ppb v/v 87 70 - 130 5 25 cis-1,3-Dichloropropene 25.0 20.54 ppb v/v 82 70 - 134 5 25 Carbon disulfide 25.0 19.89 ppb v/v 80 70 - 130 6 25
Carbon tetrachloride 25.0 19.93 ppb v/v 80 68 - 133 5 25 Chlorobenzene 25.0 19.13 ppb v/v 77 70 - 130 5 25
Chloroethane 25.0 21.17 ppb v/v 85 66 - 134 6 25
Chloroform 25.0 20.55 ppb v/v 82 67 - 131 6 25
Chloromethane 25.0 19.65 ppb v/v 79 60 - 137 7 25
Dibromochloromethane 25.0 19.12 ppb v/v 76 70 - 130 5 25 Dichlorodifluoromethane 25.0 20.99 ppb v/v 84 57 - 138 6 25 Dichlorotetrafluoroethane 25.0 21.28 ppb v/v 85 60 - 133 6 25 Ethylbenzene 25.0 18.75 ppb v/v 75 70 - 130 5 25
Hexachloro-1,3-butadiene 25.0 17.51 ppb v/v 70 58 - 130 11 25 Isopropanol 25.0 19.33 ppb v/v 77 64 - 133 6 25
Eurofins Calscience

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1806
QC Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Lab Sample ID: LCSD 570-228550/5 Client Sample ID: Lab Control Sample Dup Matrix: Air Prep Type: Total/NA
Analysis Batch: 228550
Methylene Chloride 25.0 21.24 ppb v/v 85 65 - 130 5 25
Analyte

LCSD LCSD
Result Qualifier Unit D %Rec
Spike
Added
%Rec
Limits RPD Limit
RPD
Methyl-t-Butyl Ether (MTBE) 25.0 21.03 ppb v/v 84 70 - 130 5 25 n-Butylbenzene 25.0 17.18 ppb v/v 69 64 - 130 2 25
o-Xylene 25.0 18.06 ppb v/v 72 68 - 130 5 25
m,p-Xylene 50.0 36.87 ppb v/v 74 70 - 130 4 25
sec-Butylbenzene 25.0 17.43 ppb v/v 70 67 - 130 4 25
Styrene 25.0 18.97 ppb v/v 76 70 - 130 3 25
trans-1,2-Dichloroethene 25.0 20.48 ppb v/v 82 70 - 130 5 25 trans-1,3-Dichloropropene 25.0 19.75 ppb v/v 79 66 - 142 6 25 tert-Butylbenzene 25.0 17.81 ppb v/v 71 70 - 130 4 25
Tetrachloroethene 25.0 19.42 ppb v/v 78 70 - 130 6 25
Toluene 25.0 18.66 ppb v/v 75 70 - 130 5 25
Trichloroethene 25.0 19.66 ppb v/v 79 69 - 130 6 25
Trichlorofluoromethane 25.0 20.65 ppb v/v 83 62 - 139 7 25 Vinyl acetate 25.0 20.04 ppb v/v 80 64 - 139 5 25
Vinyl chloride 25.0 21.60 ppb v/v 86 65 - 130 5 25
1,1,1-Trichloroethane 140 114.5 ug/m3 84 67 - 135 5 25
Analyte

LCSD LCSD
Result Qualifier Unit D %Rec
Spike
Added
%Rec
Limits RPD Limit
RPD
1,1,2,2-Tetrachloroethane 170 126.9 ug/m3 74 70 - 130 2 25 1,1,2-Trichloro-1,2,2-trifluoroetha
ne
190 164.0 ug/m3 86 70 - 130 5 25
1,1,2-Trichloroethane 140 110.8 ug/m3 81 69 - 131 6 25
1,1-Dichloroethane 100 83.13 ug/m3 82 69 - 130 6 25
1,1-Dichloroethene 99 79.85 ug/m3 81 64 - 135 6 25
1,1-Difluoroethane 68 46.14 ug/m3 68 57 - 146 7 25
1,2,4-Trichlorobenzene 190 128.7 ug/m3 69 51 - 134 11 25 1,2,4-Trimethylbenzene 120 84.88 ug/m3 69 68 - 130 4 25 1,2-Dibromo-3-Chloropropane 240 172.7 ug/m3 71 66 - 130 4 25 1,2-Dibromoethane 190 144.8 ug/m3 75 70 - 130 5 25
1,2-Dichlorobenzene 150 106.7 ug/m3 71 68 - 130 2 25
1,2-Dichloroethane 100 79.82 ug/m3 79 65 - 136 5 25
1,2-Dichloropropane 120 91.50 ug/m3 79 68 - 132 6 25
1,3,5-Trimethylbenzene 120 86.86 ug/m3 71 69 - 130 3 25 1,3-Dichlorobenzene 150 110.6 ug/m3 74 65 - 130 4 25
1,4-Dichlorobenzene 150 110.2 ug/m3 73 64 - 130 2 25
2-Butanone 74 58.69 ug/m3 80 66 - 143 5 25
2-Hexanone 100 75.28 ug/m3 73 64 - 139 3 25
4-Ethyltoluene 120 88.77 ug/m3 72 69 - 130 3 25
4-Methyl-2-pentanone 100 78.91 ug/m3 77 65 - 135 7 25
Acetone 59 47.28 ug/m3 80 70 - 130 5 25
Benzene 80 63.90 ug/m3 80 68 - 134 6 25
Benzyl chloride 130 87.71 *- me ug/m3 68 70 - 130 3 25
Bromodichloromethane 170 132.4 ug/m3 79 69 - 132 6 25
Bromoform 260 203.8 ug/m3 79 70 - 130 4 25
Bromomethane 97 83.83 ug/m3 86 65 - 130 6 25
cis-1,2-Dichloroethene 99 85.78 ug/m3 87 70 - 130 5 25
cis-1,3-Dichloropropene 110 93.23 ug/m3 82 70 - 134 5 25 Carbon disulfide 78 61.95 ug/m3 80 70 - 130 6 25
Eurofins Calscience

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1807
QC Sample Results
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Lab Sample ID: LCSD 570-228550/5 Client Sample ID: Lab Control Sample Dup Matrix: Air Prep Type: Total/NA
Analysis Batch: 228550
Carbon tetrachloride 160 125.4 ug/m3 80 68 - 133 5 25
Analyte

LCSD LCSD
Result Qualifier Unit D %Rec
Spike
Added
%Rec
Limits RPD Limit
RPD
Chlorobenzene 120 88.06 ug/m3 77 70 - 130 5 25
Chloroethane 66 55.87 ug/m3 85 66 - 134 6 25
Chloroform 120 100.3 ug/m3 82 67 - 131 6 25
Chloromethane 52 40.57 ug/m3 79 60 - 137 7 25
Dibromochloromethane 210 162.9 ug/m3 76 70 - 130 5 25
Dichlorodifluoromethane 120 103.8 ug/m3 84 57 - 138 6 25 Dichlorotetrafluoroethane 170 148.8 ug/m3 85 60 - 133 6 25 Ethylbenzene 110 81.40 ug/m3 75 70 - 130 5 25
Hexachloro-1,3-butadiene 270 186.8 ug/m3 70 58 - 130 11 25 Isopropanol 61 47.51 ug/m3 77 64 - 133 6 25
Methylene Chloride 87 73.77 ug/m3 85 65 - 130 5 25
Methyl-t-Butyl Ether (MTBE) 90 75.82 ug/m3 84 70 - 130 5 25 n-Butylbenzene 140 94.31 ug/m3 69 64 - 130 2 25
o-Xylene 110 78.44 ug/m3 72 68 - 130 5 25
m,p-Xylene 220 160.1 ug/m3 74 70 - 130 4 25
sec-Butylbenzene 140 95.69 ug/m3 70 67 - 130 4 25
Styrene 110 80.83 ug/m3 76 70 - 130 3 25
trans-1,2-Dichloroethene 99 81.20 ug/m3 82 70 - 130 5 25 trans-1,3-Dichloropropene 110 89.63 ug/m3 79 66 - 142 6 25 tert-Butylbenzene 140 97.76 ug/m3 71 70 - 130 4 25
Tetrachloroethene 170 131.7 ug/m3 78 70 - 130 6 25
Toluene 94 70.33 ug/m3 75 70 - 130 5 25
Trichloroethene 130 105.6 ug/m3 79 69 - 130 6 25
Trichlorofluoromethane 140 116.0 ug/m3 83 62 - 139 7 25 Vinyl acetate 88 70.55 ug/m3 80 64 - 139 5 25
Vinyl chloride 64 55.21 ug/m3 86 65 - 130 5 25
1,2-Dichloroethane-d4 (Surr) 66 - 132
Surrogate
98 LCSD LCSD
%Recovery Qualifier Limits
4-Bromofluorobenzene (Surr) 114 70 - 130
Toluene-d8 (Surr) 101 70 - 130
Eurofins Calscience

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1808
Marginal Exceedance (ME) Summary
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air Lab Sample ID: LCSD 570-228550/5 Client Sample ID: Lab Control Sample Dup Matrix: Air Prep Type: Total/NA
1,1,1-Trichloroethane 25.0 20.98 ppb v/v 84 67 - 135
Analyte

LCSD LCSD
Result Qualifier Unit %Rec
Spike
Added
%Rec.

Limits
ME %Rec.

Limits
56 - 146
Marginal Exceedance
Status
1,1,2,2-Tetrachloroethane 25.0 18.49 ppb v/v 74 70 - 130 60 140 - 1,1,2-Trichloro-1,2,2-trifluoroetha
ne

25.0 21.40 ppb v/v 86 70 - 130 60 140 -
1,1,2-Trichloroethane 25.0 20.30 ppb v/v 81 69 - 131 59 141 - 1,1-Dichloroethane 25.0 20.54 ppb v/v 82 69 - 130 59 140 - 1,1-Dichloroethene 25.0 20.14 ppb v/v 81 64 - 135 52 147 - 1,1-Difluoroethane 25.0 17.08 ppb v/v 68 57 - 146 42 161 - 1,2,4-Trichlorobenzene 25.0 17.35 ppb v/v 69 51 - 134 37 148 - 1,2,4-Trimethylbenzene 25.0 17.27 ppb v/v 69 68 - 130 58 140 - 1,2-Dibromo-3-Chloropropane 25.0 17.87 ppb v/v 71 66 - 130 55 141 - 1,2-Dibromoethane 25.0 18.84 ppb v/v 75 70 - 130 60 140 - 1,2-Dichlorobenzene 25.0 17.74 ppb v/v 71 68 - 130 58 140 - 1,2-Dichloroethane 25.0 19.72 ppb v/v 79 65 - 136 53 148 - 1,2-Dichloropropane 25.0 19.80 ppb v/v 79 68 - 132 57 143 - 1,3,5-Trimethylbenzene 25.0 17.67 ppb v/v 71 69 - 130 59 140 - 1,3-Dichlorobenzene 25.0 18.39 ppb v/v 74 65 - 130 54 141 - 1,4-Dichlorobenzene 25.0 18.33 ppb v/v 73 64 - 130 53 141 - 2-Butanone 25.0 19.90 ppb v/v 80 66 - 143 53 156 -
2-Hexanone 25.0 18.37 ppb v/v 73 64 - 139 52 152 -
4-Ethyltoluene 25.0 18.06 ppb v/v 72 69 - 130 59 140 -
4-Methyl-2-pentanone 25.0 19.26 ppb v/v 77 65 - 135 53 147 - Acetone 25.0 19.91 ppb v/v 80 70 - 130 60 140 -
Benzene 25.0 20.00 ppb v/v 80 68 - 134 57 145 -
Benzyl chloride 25.0 16.94 *- me ppb v/v 68 70 - 130 60 140 - ME Bromodichloromethane 25.0 19.77 ppb v/v 79 69 - 132 59 143 - Bromoform 25.0 19.72 ppb v/v 79 70 - 130 60 140 -
Bromomethane 25.0 21.59 ppb v/v 86 65 - 130 54 141 -
cis-1,2-Dichloroethene 25.0 21.63 ppb v/v 87 70 - 130 60 140 - cis-1,3-Dichloropropene 25.0 20.54 ppb v/v 82 70 - 134 59 145 - Carbon disulfide 25.0 19.89 ppb v/v 80 70 - 130 60 140 - Carbon tetrachloride 25.0 19.93 ppb v/v 80 68 - 133 57 144 - Chlorobenzene 25.0 19.13 ppb v/v 77 70 - 130 60 140 -
Chloroethane 25.0 21.17 ppb v/v 85 66 - 134 55 145 -
Chloroform 25.0 20.55 ppb v/v 82 67 - 131 56 142 -
Chloromethane 25.0 19.65 ppb v/v 79 60 - 137 47 150 -
Dibromochloromethane 25.0 19.12 ppb v/v 76 70 - 130 60 140 - Dichlorodifluoromethane 25.0 20.99 ppb v/v 84 57 - 138 44 152 - Dichlorotetrafluoroethane 25.0 21.28 ppb v/v 85 60 - 133 48 145 - Ethylbenzene 25.0 18.75 ppb v/v 75 70 - 130 60 140 -
Hexachloro-1,3-butadiene 25.0 17.51 ppb v/v 70 58 - 130 46 142 - Isopropanol 25.0 19.33 ppb v/v 77 64 - 133 53 145 -
Methylene Chloride 25.0 21.24 ppb v/v 85 65 - 130 54 141 - Methyl-t-Butyl Ether (MTBE) 25.0 21.03 ppb v/v 84 70 - 130 60 140 - n-Butylbenzene 25.0 17.18 ppb v/v 69 64 - 130 53 141 -
o-Xylene 25.0 18.06 ppb v/v 72 68 - 130 58 140 -
m,p-Xylene 50.0 36.87 ppb v/v 74 70 - 130 60 140 -
sec-Butylbenzene 25.0 17.43 ppb v/v 70 67 - 130 57 141 - Styrene 25.0 18.97 ppb v/v 76 70 - 130 60 140 -
trans-1,2-Dichloroethene 25.0 20.48 ppb v/v 82 70 - 130 60 140 - Eurofins Calscience

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1809
Marginal Exceedance (ME) Summary
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Lab Sample ID: LCSD 570-228550/5 Client Sample ID: Lab Control Sample Dup Matrix: Air Prep Type: Total/NA
trans-1,3-Dichloropropene 25.0 19.75 ppb v/v 79 66 - 142 Analyte

LCSD LCSD
Result Qualifier Unit %Rec
Spike
Added
%Rec.

Limits
ME %Rec.

Limits
53 - 155
Marginal Exceedance
Status
tert-Butylbenzene 25.0 17.81 ppb v/v 71 70 - 130 60 140 - Tetrachloroethene 25.0 19.42 ppb v/v 78 70 - 130 60 140 - Toluene 25.0 18.66 ppb v/v 75 70 - 130 60 140 -
Trichloroethene 25.0 19.66 ppb v/v 79 69 - 130 59 140 - Trichlorofluoromethane 25.0 20.65 ppb v/v 83 62 - 139 49 152 - Vinyl acetate 25.0 20.04 ppb v/v 80 64 - 139 52 152 -
Vinyl chloride 25.0 21.60 ppb v/v 86 65 - 130 54 141 -
Summary
Number of
Analytes Reported
57 Number of Marginal
Exceedances Allowed
3 Number of Marginal
Exceedances Found
1 ME = Marginal Exceedance
1,1,1-Trichloroethane 140 114.5 ug/m3 84 67 - 135
Analyte

LCSD LCSD
Result Qualifier Unit %Rec
Spike
Added
%Rec.

Limits
ME %Rec.

Limits
56 - 146
Marginal Exceedance
Status
1,1,2,2-Tetrachloroethane 170 126.9 ug/m3 74 70 - 130 60 140 - 1,1,2-Trichloro-1,2,2-trifluoroetha
ne
190 164.0 ug/m3 86 70 - 130 60 140 -
1,1,2-Trichloroethane 140 110.8 ug/m3 81 69 - 131 59 141 - 1,1-Dichloroethane 100 83.13 ug/m3 82 69 - 130 59 140 - 1,1-Dichloroethene 99 79.85 ug/m3 81 64 - 135 52 147 -
1,1-Difluoroethane 68 46.14 ug/m3 68 57 - 146 42 161 -
1,2,4-Trichlorobenzene 190 128.7 ug/m3 69 51 - 134 37 148 - 1,2,4-Trimethylbenzene 120 84.88 ug/m3 69 68 - 130 58 140 - 1,2-Dibromo-3-Chloropropane 240 172.7 ug/m3 71 66 - 130 55 141 - 1,2-Dibromoethane 190 144.8 ug/m3 75 70 - 130 60 140 -
1,2-Dichlorobenzene 150 106.7 ug/m3 71 68 - 130 58 140 - 1,2-Dichloroethane 100 79.82 ug/m3 79 65 - 136 53 148 - 1,2-Dichloropropane 120 91.50 ug/m3 79 68 - 132 57 143 - 1,3,5-Trimethylbenzene 120 86.86 ug/m3 71 69 - 130 59 140 - 1,3-Dichlorobenzene 150 110.6 ug/m3 74 65 - 130 54 141 - 1,4-Dichlorobenzene 150 110.2 ug/m3 73 64 - 130 53 141 - 2-Butanone 74 58.69 ug/m3 80 66 - 143 53 156 -
2-Hexanone 100 75.28 ug/m3 73 64 - 139 52 152 -
4-Ethyltoluene 120 88.77 ug/m3 72 69 - 130 59 140 -
4-Methyl-2-pentanone 100 78.91 ug/m3 77 65 - 135 53 147 - Acetone 59 47.28 ug/m3 80 70 - 130 60 140 -
Benzene 80 63.90 ug/m3 80 68 - 134 57 145 -
Benzyl chloride 130 87.71 *- me ug/m3 68 70 - 130 60 140 - ME Bromodichloromethane 170 132.4 ug/m3 79 69 - 132 59 143 - Bromoform 260 203.8 ug/m3 79 70 - 130 60 140 -
Bromomethane 97 83.83 ug/m3 86 65 - 130 54 141 -
cis-1,2-Dichloroethene 99 85.78 ug/m3 87 70 - 130 60 140 - cis-1,3-Dichloropropene 110 93.23 ug/m3 82 70 - 134 59 145 - Carbon disulfide 78 61.95 ug/m3 80 70 - 130 60 140 -
Carbon tetrachloride 160 125.4 ug/m3 80 68 - 133 57 144 - Chlorobenzene 120 88.06 ug/m3 77 70 - 130 60 140 -
Chloroethane 66 55.87 ug/m3 85 66 - 134 55 145 -
Eurofins Calscience

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Marginal Exceedance (ME) Summary
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued) Lab Sample ID: LCSD 570-228550/5 Client Sample ID: Lab Control Sample Dup Matrix: Air Prep Type: Total/NA
Chloroform 120 100.3 ug/m3 82 67 - 131
Analyte

LCSD LCSD
Result Qualifier Unit %Rec
Spike
Added
%Rec.

Limits
ME %Rec.

Limits
56 - 142
Marginal Exceedance
Status
Chloromethane 52 40.57 ug/m3 79 60 - 137 47 150 -
Dibromochloromethane 210 162.9 ug/m3 76 70 - 130 60 140 - Dichlorodifluoromethane 120 103.8 ug/m3 84 57 - 138 44 152 - Dichlorotetrafluoroethane 170 148.8 ug/m3 85 60 - 133 48 145 - Ethylbenzene 110 81.40 ug/m3 75 70 - 130 60 140 -
Hexachloro-1,3-butadiene 270 186.8 ug/m3 70 58 - 130 46 142 - Isopropanol 61 47.51 ug/m3 77 64 - 133 53 145 -
Methylene Chloride 87 73.77 ug/m3 85 65 - 130 54 141 -
Methyl-t-Butyl Ether (MTBE) 90 75.82 ug/m3 84 70 - 130 60 140 - n-Butylbenzene 140 94.31 ug/m3 69 64 - 130 53 141 -
o-Xylene 110 78.44 ug/m3 72 68 - 130 58 140 -
m,p-Xylene 220 160.1 ug/m3 74 70 - 130 60 140 -
sec-Butylbenzene 140 95.69 ug/m3 70 67 - 130 57 141 -
Styrene 110 80.83 ug/m3 76 70 - 130 60 140 -
trans-1,2-Dichloroethene 99 81.20 ug/m3 82 70 - 130 60 140 - trans-1,3-Dichloropropene 110 89.63 ug/m3 79 66 - 142 53 155 - tert-Butylbenzene 140 97.76 ug/m3 71 70 - 130 60 140 -
Tetrachloroethene 170 131.7 ug/m3 78 70 - 130 60 140 -
Toluene 94 70.33 ug/m3 75 70 - 130 60 140 -
Trichloroethene 130 105.6 ug/m3 79 69 - 130 59 140 -
Trichlorofluoromethane 140 116.0 ug/m3 83 62 - 139 49 152 - Vinyl acetate 88 70.55 ug/m3 80 64 - 139 52 152 -
Vinyl chloride 64 55.21 ug/m3 86 65 - 130 54 141 -
Summary
Number of
Analytes Reported
57 Number of Marginal
Exceedances Allowed
3 Number of Marginal
Exceedances Found
1 ME = Marginal Exceedance
Eurofins Calscience

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QC Association Summary
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Air - GC/MS VOA
Analysis Batch: 228287
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 570-93118-1 SV-1-10 Total/NA Air TO-15
570-93118-2 SV-1-20 Total/NA Air TO-15
570-93118-3 SV-2-5 Total/NA Air TO-15
570-93118-4 SV-2-5-D Total/NA Air TO-15
570-93118-5 SV-2-15 Total/NA Air TO-15
570-93118-6 SV-4-5 Total/NA Air TO-15
570-93118-7 SV-4-15 Total/NA Air TO-15
570-93118-8 SV-6-5 Total/NA Air TO-15
570-93118-9 SV-6-15 Total/NA Air TO-15
570-93118-10 SV-9-5 Total/NA Air TO-15
MB 570-228287/7 Method Blank Total/NA Air TO-15
LCS 570-228287/3 Lab Control Sample Total/NA Air TO-15
LCSD 570-228287/4 Lab Control Sample Dup Total/NA Air TO-15 Analysis Batch: 228550
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 570-93118-11 SV-9-15 Total/NA Air TO-15
570-93118-12 SV-7-5 Total/NA Air TO-15
570-93118-13 SV-7-15 Total/NA Air TO-15
570-93118-14 SV-8-5 Total/NA Air TO-15
570-93118-15 SV-8-15 Total/NA Air TO-15
MB 570-228550/8 Method Blank Total/NA Air TO-15
LCS 570-228550/4 Lab Control Sample Total/NA Air TO-15
LCSD 570-228550/5 Lab Control Sample Dup Total/NA Air TO-15 Eurofins Calscience

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Lab Chronicle
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Client Sample ID: SV-1-10 Lab Sample ID: 570-93118-1
Date Collected: 04/18/22 08:21 Matrix: Air
Date Received: 04/19/22 19:20
Analysis TO-15 1 228287 04/22/22 04:21 QD3U ECL 4
Type
Batch
Method
Batch
Prep Type Run Analyst Lab
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
Factor Number
Dil
Total/NA 250 mL 250 mL
Instrument ID: GCMSNN
Client Sample ID: SV-1-20 Lab Sample ID: 570-93118-2
Date Collected: 04/18/22 08:44 Matrix: Air
Date Received: 04/19/22 19:20
Analysis TO-15 1 228287 04/22/22 05:11 QD3U ECL 4
Type
Batch
Method
Batch
Prep Type Run Analyst Lab
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
Factor Number
Dil
Total/NA 250 mL 250 mL
Instrument ID: GCMSNN
Client Sample ID: SV-2-5 Lab Sample ID: 570-93118-3
Date Collected: 04/18/22 09:25 Matrix: Air
Date Received: 04/19/22 19:20
Analysis TO-15 1 228287 04/22/22 06:04 QD3U ECL 4
Type
Batch
Method
Batch
Prep Type Run Analyst Lab
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
Factor Number
Dil
Total/NA 250 mL 250 mL
Instrument ID: GCMSNN
Client Sample ID: SV-2-5-D Lab Sample ID: 570-93118-4
Date Collected: 04/18/22 09:25 Matrix: Air
Date Received: 04/19/22 19:20
Analysis TO-15 1 228287 04/22/22 06:56 QD3U ECL 4
Type
Batch
Method
Batch
Prep Type Run Analyst Lab
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
Factor Number
Dil
Total/NA 250 mL 250 mL
Instrument ID: GCMSNN
Client Sample ID: SV-2-15 Lab Sample ID: 570-93118-5
Date Collected: 04/18/22 09:49 Matrix: Air
Date Received: 04/19/22 19:20
Analysis TO-15 1 228287 04/22/22 07:52 QD3U ECL 4
Type
Batch
Method
Batch
Prep Type Run Analyst Lab
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
Factor Number
Dil
Total/NA 250 mL 250 mL
Instrument ID: GCMSNN
Client Sample ID: SV-4-5 Lab Sample ID: 570-93118-6
Date Collected: 04/18/22 10:28 Matrix: Air
Date Received: 04/19/22 19:20
Analysis TO-15 1 228287 04/22/22 08:57 QD3U ECL 4
Type
Batch
Method
Batch
Prep Type Run Analyst Lab
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
Factor Number
Dil
Total/NA 250 mL 250 mL
Instrument ID: GCMSNN
Eurofins Calscience

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1813
Lab Chronicle
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Client Sample ID: SV-4-15 Lab Sample ID: 570-93118-7
Date Collected: 04/18/22 10:24 Matrix: Air
Date Received: 04/19/22 19:20
Analysis TO-15 1 228287 04/22/22 09:54 QD3U ECL 4
Type
Batch
Method
Batch
Prep Type Run Analyst Lab
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
Factor Number
Dil
Total/NA 250 mL 250 mL
Instrument ID: GCMSNN
Client Sample ID: SV-6-5 Lab Sample ID: 570-93118-8
Date Collected: 04/18/22 11:26 Matrix: Air
Date Received: 04/19/22 19:20
Analysis TO-15 1 228287 04/22/22 10:42 QD3U ECL 4
Type
Batch
Method
Batch
Prep Type Run Analyst Lab
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
Factor Number
Dil
Total/NA 250 mL 250 mL
Instrument ID: GCMSNN
Client Sample ID: SV-6-15 Lab Sample ID: 570-93118-9
Date Collected: 04/18/22 11:13 Matrix: Air
Date Received: 04/19/22 19:20
Analysis TO-15 1 228287 04/22/22 11:40 QD3U ECL 4
Type
Batch
Method
Batch
Prep Type Run Analyst Lab
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
Factor Number
Dil
Total/NA 250 mL 250 mL
Instrument ID: GCMSNN
Client Sample ID: SV-9-5 Lab Sample ID: 570-93118-10
Date Collected: 04/18/22 12:47 Matrix: Air
Date Received: 04/19/22 19:20
Analysis TO-15 1 228287 04/22/22 12:34 QD3U ECL 4
Type
Batch
Method
Batch
Prep Type Run Analyst Lab
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
Factor Number
Dil
Total/NA 250 mL 250 mL
Instrument ID: GCMSNN
Client Sample ID: SV-9-15 Lab Sample ID: 570-93118-11
Date Collected: 04/18/22 13:39 Matrix: Air
Date Received: 04/19/22 19:20
Analysis TO-15 1 228550 04/22/22 22:42 QD3U ECL 4
Type
Batch
Method
Batch
Prep Type Run Analyst Lab
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
Factor Number
Dil
Total/NA 250 mL 250 mL
Instrument ID: GCMSNN
Client Sample ID: SV-7-5 Lab Sample ID: 570-93118-12
Date Collected: 04/18/22 13:30 Matrix: Air
Date Received: 04/19/22 19:20
Analysis TO-15 1 228550 04/22/22 23:43 QD3U ECL 4
Type
Batch
Method
Batch
Prep Type Run Analyst Lab
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
Factor Number
Dil
Total/NA 250 mL 250 mL
Instrument ID: GCMSNN
Eurofins Calscience

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1814
Lab Chronicle
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Client Sample ID: SV-7-15 Lab Sample ID: 570-93118-13
Date Collected: 04/18/22 13:19 Matrix: Air
Date Received: 04/19/22 19:20
Analysis TO-15 1 228550 04/23/22 00:43 QD3U ECL 4
Type
Batch
Method
Batch
Prep Type Run Analyst Lab
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
Factor Number
Dil
Total/NA 250 mL 250 mL
Instrument ID: GCMSNN
Client Sample ID: SV-8-5 Lab Sample ID: 570-93118-14
Date Collected: 04/18/22 14:16 Matrix: Air
Date Received: 04/19/22 19:20
Analysis TO-15 1 228550 04/23/22 01:33 QD3U ECL 4
Type
Batch
Method
Batch
Prep Type Run Analyst Lab
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
Factor Number
Dil
Total/NA 250 mL 250 mL
Instrument ID: GCMSNN
Client Sample ID: SV-8-15 Lab Sample ID: 570-93118-15
Date Collected: 04/18/22 14:05 Matrix: Air
Date Received: 04/19/22 19:20
Analysis TO-15 1 228550 04/23/22 02:21 QD3U ECL 4
Type
Batch
Method
Batch
Prep Type Run Analyst Lab
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
Factor Number
Dil
Total/NA 250 mL 250 mL
Instrument ID: GCMSNN
Laboratory References:

ECL 4 = Eurofins Calscience Tustin, 2841 Dow Avenue, Tustin, CA 92780, TEL (714)895-5494 Eurofins Calscience

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1815
Accreditation/Certification Summary
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Laboratory: Eurofins Calscience
Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below.

Authority Program Identification Number Expiration Date California State 2944 09-30-22
The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes for which the agency does not offer certification.

Analysis Method Prep Method Matrix Analyte
TO-15 Air 1,1,1-Trichloroethane
TO-15 Air 1,1,2,2-Tetrachloroethane
TO-15 Air 1,1,2-Trichloro-1,2,2-trifluoroethane
TO-15 Air 1,1,2-Trichloroethane
TO-15 Air 1,1-Dichloroethane
TO-15 Air 1,1-Dichloroethene
TO-15 Air 1,1-Difluoroethane
TO-15 Air 1,2,4-Trichlorobenzene
TO-15 Air 1,2,4-Trimethylbenzene
TO-15 Air 1,2-Dibromo-3-Chloropropane
TO-15 Air 1,2-Dibromoethane
TO-15 Air 1,2-Dichlorobenzene
TO-15 Air 1,2-Dichloroethane
TO-15 Air 1,2-Dichloropropane
TO-15 Air 1,3,5-Trimethylbenzene
TO-15 Air 1,3-Dichlorobenzene
TO-15 Air 1,4-Dichlorobenzene
TO-15 Air 2-Butanone
TO-15 Air 2-Hexanone
TO-15 Air 4-Ethyltoluene
TO-15 Air 4-Methyl-2-pentanone
TO-15 Air Acetone
TO-15 Air Benzene
TO-15 Air Benzyl chloride
TO-15 Air Bromodichloromethane
TO-15 Air Bromoform
TO-15 Air Bromomethane
TO-15 Air Carbon disulfide
TO-15 Air Carbon tetrachloride
TO-15 Air Chlorobenzene
TO-15 Air Chloroethane
TO-15 Air Chloroform
TO-15 Air Chloromethane
TO-15 Air cis-1,2-Dichloroethene
TO-15 Air cis-1,3-Dichloropropene
TO-15 Air Dibromochloromethane
TO-15 Air Dichlorodifluoromethane
TO-15 Air Dichlorotetrafluoroethane
TO-15 Air Ethylbenzene
TO-15 Air Hexachloro-1,3-butadiene
TO-15 Air Isopropanol
TO-15 Air m,p-Xylene
TO-15 Air Methylene Chloride
TO-15 Air Methyl-t-Butyl Ether (MTBE)
TO-15 Air n-Butylbenzene
Eurofins Calscience

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1816
Accreditation/Certification Summary
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Laboratory: Eurofins Calscience (Continued)
Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below.

Authority Program Identification Number Expiration Date The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes for which the agency does not offer certification.

Analysis Method Prep Method Matrix Analyte
TO-15 Air o-Xylene
TO-15 Air sec-Butylbenzene
TO-15 Air Styrene
TO-15 Air tert-Butylbenzene
TO-15 Air Tetrachloroethene
TO-15 Air Toluene
TO-15 Air trans-1,2-Dichloroethene
TO-15 Air trans-1,3-Dichloropropene
TO-15 Air Trichloroethene
TO-15 Air Trichlorofluoromethane
TO-15 Air Vinyl acetate
TO-15 Air Vinyl chloride
Oregon NELAP CA300001 01-31-23
Eurofins Calscience

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1817
Method Summary
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Method Method Description Protocol Laboratory
TO-15 Volatile Organic Compounds in Ambient Air EPA ECL 4 Protocol References:

EPA = US Environmental Protection Agency
Laboratory References:

ECL 4 = Eurofins Calscience Tustin, 2841 Dow Avenue, Tustin, CA 92780, TEL (714)895-5494 Eurofins Calscience

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1818
Sample Summary
Client: Roux Associates, Inc. Job ID: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Lab Sample ID Client Sample ID Matrix Collected Received Asset ID 570-93118-1 SV-1-10 Air 04/18/22 08:21 04/19/22 19:20 Air Canister (1-Liter) #LC1022 570-93118-2 SV-1-20 Air 04/18/22 08:44 04/19/22 19:20 Air Canister (1-Liter) #LC675 570-93118-3 SV-2-5 Air 04/18/22 09:25 04/19/22 19:20 Air Canister (1-Liter) #LC293 570-93118-4 SV-2-5-D Air 04/18/22 09:25 04/19/22 19:20 Air Canister (1-Liter) #LC976 570-93118-5 SV-2-15 Air 04/18/22 09:49 04/19/22 19:20 Air Canister (1-Liter) #LC1279 570-93118-6 SV-4-5 Air 04/18/22 10:28 04/19/22 19:20 Air Canister (1-Liter) #LC815 570-93118-7 SV-4-15 Air 04/18/22 10:24 04/19/22 19:20 Air Canister (1-Liter) #LC1169 570-93118-8 SV-6-5 Air 04/18/22 11:26 04/19/22 19:20 Air Canister (1-Liter) #SLC024 570-93118-9 SV-6-15 Air 04/18/22 11:13 04/19/22 19:20 Air Canister (1-Liter) #LC770 570-93118-10 SV-9-5 Air 04/18/22 12:47 04/19/22 19:20 Air Canister (1-Liter) #LC578 570-93118-11 SV-9-15 Air 04/18/22 13:39 04/19/22 19:20 Air Canister (1-Liter) #LC363 570-93118-12 SV-7-5 Air 04/18/22 13:30 04/19/22 19:20 Air Canister (1-Liter) #LC152 570-93118-13 SV-7-15 Air 04/18/22 13:19 04/19/22 19:20 Air Canister (1-Liter) #SLC018 570-93118-14 SV-8-5 Air 04/18/22 14:16 04/19/22 19:20 Air Canister (1-Liter) #LC645 570-93118-15 SV-8-15 Air 04/18/22 14:05 04/19/22 19:20 Air Canister (1-Liter) #LC483 Eurofins Calscience Page 75 of 81 4/26/2022
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1819
1 Patel, Virendra
From: Peter Shimer <[email protected]>
Sent: Wednesday, April 20, 2022 10:04 AM
To: Patel, Virendra
Cc: David Smith; Ian Cross
Subject: Re: <RESPONSE REQUESTED> Eurofins Calscience sample confirmation files from 570-93118-1 First Indiustrial-Ontario / 3661.0016L
Attachments: mime-attachment.jpg; mime-attachment.jpg; SampleLoginAck_570-93118-1 [Std_Tal_Login_Ack].pdf; COC 570-93118 (202204192023).pdf EXTERNAL EMAIL*

Please report ug/m3 as well, thank you.

Peter
Sent from my iPhone
On Apr 20, 2022, at 10:00 AM, Virendra Patel <[email protected]> wrote:

This message originated outside your organization. Please use caution! Hello,
Attached please find the sample confirmation files for job 570-93118-1; First Indiustrial-Ontario / 3661.0016L

1. The TO-15 results are set to report with "ppb v/v" units ACTION - Please advise at your earliest convienience if you reuqire results with alternate units or dual units.

Please feel free to contact me if you have any questions.

Thank you.

Virendra Patel
Project Manager
Eurofins Calscience

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1820
2 Phone: 714-895-5494
Mobile: 714-887-9901
E-mail: [email protected]
www.eurofinsus.com/env

Reference: [570-311869]
Attachments: 2
> > Bank information has changed, please refer to remittance information on invoice. < <

* WARNING ‐ EXTERNAL: This email originated from outside of Eurofins Environment Testing America. Do not click any links or open any attachments unless you trust the sender and know that the content is safe!

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1821

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Login Sample Receipt Checklist
Client: Roux Associates, Inc. Job Number: 570-93118-1
Login Number: 93118
Question Answer Comment
Creator: Cruise, Noel
List Source: Eurofins Calscience
List Number: 1
Radioactivity wasn't checked or is </= background as measured by a survey N/A meter.

The cooler's custody seal, if present, is intact. True
Sample custody seals, if present, are intact. True
The cooler or samples do not appear to have been compromised or True tampered with.

Samples were received on ice. False Thermal preservation not required.

Cooler Temperature is acceptable. True
Cooler Temperature is recorded. True
COC is present. True
COC is filled out in ink and legible. True
COC is filled out with all pertinent information. True
Is the Field Sampler's name present on COC? True
There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time (excluding tests with immediate True HTs)
Sample containers have legible labels. True
Containers are not broken or leaking. True
Sample collection date/times are provided. True
Appropriate sample containers are used. True
Sample bottles are completely filled. True
Sample Preservation Verified. True
There is sufficient vol. for all requested analyses, incl. any requested True MS/MSDs
Containers requiring zero headspace have no headspace or bubble is <6mm True (1/4").

Multiphasic samples are not present. True
Samples do not require splitting or compositing. True
Residual Chlorine Checked. N/A
Eurofins Calscience Page 79 of 81 4/26/2022
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1823
Summa Canister Dilution Worksheet
Client: Roux Associates, Inc. Job No.: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Canister
Lab Sample ID (L) ("Hg) (atm) (L) (psig) (atm) (L) Factor Factor Date Volume Pressure Analyst
Preadjusted Adjusted
Pressure
Preadjusted Preadjusted
Volume Pressure
Adjusted
Pressure
Adjusted
Volume Dilution
Final
Dilution
Initial
Volume
("Hg) (mL) Initials
Pressure
Presampling
570-93118-11 -29.5 -5.4 0.82 0.82 -2.65223 0.82 0.82 1.00 1.00 04/22/22 12:05 QD3U ID
Pressure
Gauge
AIR MG-4
570-93118-21 -29.5 -2.8 0.91 0.91 -1.37523 0.91 0.91 1.00 1.00 AIR MG-4 04/22/22 12:05 QD3U 570-93118-31 -29.5 -4.4 0.85 0.85 -2.16108 0.85 0.85 1.00 1.00 AIR MG-4 04/22/22 12:05 QD3U 570-93118-41 -29.5 -5.0 0.83 0.83 -2.45577 0.83 0.83 1.00 1.00 AIR MG-4 04/22/22 12:05 QD3U 570-93118-51 -29.5 -6.6 0.78 0.78 -3.24162 0.78 0.78 1.00 1.00 AIR MG-4 04/22/22 12:05 QD3U 570-93118-61 -29.5 -8.6 0.71 0.71 -4.22393 0.71 0.71 1.00 1.00 AIR MG-4 04/22/22 12:06 QD3U 570-93118-71 -29.5 -6.8 0.77 0.77 -3.33985 0.77 0.77 1.00 1.00 AIR MG-4 04/22/22 12:06 QD3U 570-93118-81 -29.5 -7.6 0.75 0.75 -3.73277 0.75 0.75 1.00 1.00 AIR MG-4 04/22/22 12:06 QD3U 570-93118-91 -29.5 -6.8 0.77 0.77 -3.33985 0.77 0.77 1.00 1.00 AIR MG-4 04/22/22 12:06 QD3U 570-93118-101 -29.5 -4.4 0.85 0.85 -2.16108 0.85 0.85 1.00 1.00 AIR MG-4 04/22/22 12:06 QD3U 570-93118-111 -29.5 -5.0 0.83 0.83 -2.45577 0.83 0.83 1.00 1.00 AIR MG-4 04/22/22 12:06 QD3U 570-93118-121 -29.5 -8.0 0.73 0.73 -3.92923 0.73 0.73 1.00 1.00 AIR MG-4 04/22/22 12:07 QD3U 570-93118-131 -29.5 -7.6 0.75 0.75 -3.73277 0.75 0.75 1.00 1.00 AIR MG-4 04/22/22 12:07 QD3U 570-93118-141 -29.5 -5.2 0.83 0.83 -2.554 0.83 0.83 1.00 1.00 AIR MG-4 04/22/22 12:07 QD3U 570-93118-151 -29.5 -7.6 0.75 0.75 -3.73277 0.75 0.75 1.00 1.00 AIR MG-4 04/22/22 12:07 QD3U Eurofins Calscience

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Summa Canister Dilution Worksheet
Client: Roux Associates, Inc. Job No.: 570-93118-1
Project/Site: First Indiustrial-Ontario / 3661.0016L
Formulae:

Preadjusted Volume (L) = ((Preadjusted Pressure ("Hg) + 29.92 "Hg) * Vol L ) / 29.92 "Hg Adjusted Volume (L) = (( Adjusted Pressure (psig) + 14.7 psig )* Vol L ) / 14.7 psig Dilution Factor = Adjusted Volume (L) / Preadjusted Volume (L) Where:

29.92 "Hg = Standard atmospheric pressure in inches of Mercury (“Hg)

14.7 psig = Standard atmospheric pressure in pounds per square inch gauge (psig) Eurofins Calscience

Page 81 of 81 ends

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Environmental Consulting
& Management
+1.800.322.ROUX
rouxinc.com

Human Health Screening
Evaluation
________________________________
2042 South Grove Avenue
Ontario, California
December 14, 2022
Prepared for:

First Industrial Realty Trust, Inc., First Industrial, L.P.

Prepared by:

Roux Associates, Inc.
5150 E. Pacific Coast Highway, Suite 450
Long Beach, California, 90804
3661.0016L109/R
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Table of Contents
Executive Summary ......................................................................................................................................iii Introduction ............................................................................................................................................. 1

2. Background............................................................................................................................................. 2

3. Exposure Pathways and Media of Concern ........................................................................................... 3

3.1 Soil Pathway .................................................................................................................................... 3

3.2 Groundwater/Surface Water Pathway............................................................................................. 3

3.3 Air Pathway...................................................................................................................................... 3

3.4 Exposure Pathway Analysis ............................................................................................................ 4

4. Exposure Concentrations and Chemicals .............................................................................................. 5

4.1 Exposure Concentrations and Chemicals ........................................................................................ 5

4.2 Quantification of Exposure ............................................................................................................... 6

5. Toxicity Values........................................................................................................................................ 7

5.1 Toxicity Information for Non-Carcinogenic Effects ......................................................................... 7

5.2 Toxicity Information for Carcinogenic Effects .................................................................................. 7

6. Risk Characterization Summary ............................................................................................................. 9

6.1 Cancer Risks ................................................................................................................................... 9

6.2 Non-Cancer Hazards..................................................................................................................... 10

6.3 Uncertainty..................................................................................................................................... 11

7. References ........................................................................................................................................... 13 Table

1. Summary of Hazard Indices and Incremental Lifetime Cancer Risk - Indoor Air Evaluation Based on Soil Vapor Concentrations: Indoor Commercial/Industrial Worker Exposure Scenario (Attenuation Factor 0.03)
Attachment

1. ProUCL Output
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Human Health Screening Evaluation
2042 South Grove Avenue
Ontario, California
December 14, 2022
Prepared By:

Ariel Newman, MS
Senior Scientist
Andrew Shapero, MPH
Senior Engineer
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Executive Summary
On behalf of First Industrial Realty Trust, Inc., First Industrial, L.P., First Industrial Acquisitions II, LLC and their affiliates and assigns (Client), Roux Associates, Inc. (Roux) has prepared this limited Human Health Risk Assessment (HHRA) for the property located at 2042 South Grove Avenue, Ontario, California (the Subject Property). The objective of the limited HHRA was to provide a conservative evaluation of the potential risk to indoor commercial/industrial workers from exposure to chemicals detected in the soil vapor at the Subject Property in April 2022. The limited HHRA determined that carcinogenic risk and non-carcinogenic hazard to human receptors for current and future commercial/industrial indoor air scenarios at the Subject Property are within acceptable ranges.

The limited HHRA calculated the estimated risks associated with the presence of these chemicals of potential concern (COPCs) where exposure pathways are considered potentially complete pursuant to the Department of Toxic Substance Control (DTSC) Preliminary Endangerment Assessment Guidance Manual (PEA Guidance; DTSC, 2015).

The risk characterization process integrates the results of the data evaluation, exposure assessment, and toxicity assessment to provide a quantitative estimation of cumulative non-carcinogenic and carcinogenic risks for indoor commercial/industrial exposure to indoor air at the Subject Property as summarized in the table below.

Cumulative Cancer and Non-Cancer Risks
Risk Target
Threshold
Indoor Commercial/Industrial Exposure to
Indoor Air
Estimated Risk Exceed Risk
Threshold?
Cancer
Risk
1E-06 to
1E-04 3E-06
Within risk
management target
threshold range
NonCancer
Hazard
1 4E-02 No
The cancer risk estimate for an indoor commercial/industrial scenario is within the risk management target cancer threshold range of 1E-06 to 1E-04. The non-cancer hazard estimate is below the non-cancer hazard target threshold of 1.
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Introduction
On behalf of First Industrial Realty Trust, Inc., First Industrial, L.P., First Industrial Acquisitions II, LLC and their affiliates and assigns (Client), Roux Associates, Inc. (Roux) has prepared this limited Human Health Risk Assessment (HHRA) for the property located at 2042 South Grove Avenue, Ontario, California (the Subject Property). This limited HHRA was conducted to evaluate if chemicals of potential concern (COPCs) in soil vapor, collected by Roux in April 2022, pose an unacceptable level of risk to current and future indoor commercial/industrial worker receptors. To prepare the limited HHRA, Roux used the Department of Toxic Substance Control (DTSC) Preliminary Endangerment Assessment Guidance Manual (DTSC, 2015) as guidance. The HHRA consists of four components:
• Evaluation of Exposure Pathways: Exposure to chemicals may occur via inhalation of chemicals of potential concern (COPCs) present in soil vapor at the Subject Property. • Evaluation of Exposure to COPCs and Exposure Point Concentrations: Identifies contaminants found in soil vapor at the Subject Property and determines appropriate exposure point concentrations (EPCs) for COPCs.
• Evaluation of Chemical Toxicity: Assesses the potential adverse effects of the COPCs and compiles non-carcinogenic and carcinogenic toxicity values for use in numerical risk estimates. • Risk Characterization: Integrates the results of the hazard assessment to provide a quantitative estimation of non-carcinogenic and carcinogenic risks.

Default exposure parameters and toxicity criteria from the DTSC and United States Environmental Protection Agency (USEPA) were utilized to represent a Reasonable Maximum Exposure (RME) scenario. An RME scenario is the highest exposure that is reasonably expected to occur at a Subject Property. The limited HHRA evaluates current and future commercial/industrial worker exposure to indoor air at the Subject Property.
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2. Background
The Subject Property consists of a 4.2-acre parcel located in the City of Ontario, San Bernardino County, California. From a review of available resources in the Phase I ESA concurrently completed by Roux, the Subject Property was undeveloped prior to 1933. By 1946, the Subject Property had been cultivated for agricultural purposes as an orchard. The Subject Property remained agricultural until 1966. The Subject Property was then operated as a lumberyard in 1985. The South Coast Air Quality Management District (SCAQMD) issued a permit to operate (ID 9007543) for a gasoline storage and dispensing facility for the former tenant, Grove Lumber & Building Supplies, on October 6, 1981. By 1985, the Subject Property was developed with two buildings, the present-day main building and another building to the south, and associated asphalt-parking areas. The Subject Property had two 1,000-gallon underground storage tanks (USTs) (gasoline and diesel) until their removal in August 1990. Results of confirmation soil sampling following removal of the USTs revealed no detectable concentrations of total petroleum hydrocarbons (TPH), and the San Bernardino County Fire Department (SBCFD) subsequently issued a No Further Action (NFA) letter in 1991. The City of Ontario issued a building permit for the installation of a 4,500 square foot storage area in May 1999. By 2002, the previous southern building had been demolished and replaced with the present-day secondary building, likely associated with the storage area building permit issued in 1999. It is noted the western and southern portion of the Subject Property appeared unpaved by 2002, consistent with the present-day storage area for excavated material generated off-site. HHS Construction has occupied the Subject Property since June 2009. Since 2012, the exterior western lot has been used to store vehicles and other material.

Based on the preliminary findings of the subject Phase I ESA, Roux performed a concurrent Phase II subsurface investigation at the Subject Property. The Phase II was conducted to assess the following:
• Staged material originating off-site;
• Historical agricultural use;
• Former gasoline and diesel underground storage tanks (USTs); and • Potential for vapor intrusion.

Roux’s Phase II Subsurface Investigation Report (Phase II Report) concluded the following:
• In soil (from the ground surface to 10 feet below ground surface (bgs)), volatile organic compounds (VOCs), metals, polychlorinated biphenyls (PCBs), organochlorine pesticides (OCPs) and asbestos are not considered to be COPCs at the locations sampled across the Subject Property. • Limited detections of TPH in the diesel and motor oil ranges was identified in shallow soil in the area of below grade fill soil located in the southeast portion of the staging area. Roux understands that the fill soil in the staging area will be excavated and disposed of off-site in accordance with applicable regulations during future Subject Property redevelopment activities. • In soil vapor, although several VOCs were detected above laboratory reporting limits, they were all below applicable screening levels, with the exception of tetrachloroethylene (PCE) in samples SV7-5 and SV-9-5. PCE concentrations in these two samples exceeded the commercial/industrial DTSC Air Screening Level (SL) with a conservative 0.03 attenuation factor applied but did not exceed the USEPA Regional Screening Level (RSL).
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3. Exposure Pathways and Media of Concern
Exposure pathways describe the course a chemical or physical agent takes from the source to the receptor (USEPA, 1989). Four components must be present for an exposure pathway to be complete:
• A primary source and mechanism of chemical release;
• A secondary source or transport medium (or media);
• A point of potential human contact with the contaminated medium (i.e., an exposure point); and • An exposure route (e.g., ingestion, dermal contact, or inhalation).

The current and future intended use of the Subject Property is for industrial/commercial purposes, and this limited HHRA was completed to evaluate the current and future indoor commercial/industrial worker scenario. Use of the Subject Property for residential purposes was not quantitatively evaluated because there is no current or proposed residential use. However, residential use of the Subject Property is not prohibited by a Land Use Covenant (LUC). Future industrial/commercial receptor indoor air exposure is considered protective of current exposure because the maximum concentration or a 95% UCL of the mean concentration of COPCs in environmental soil vapor was assumed for the exposure scenario, regardless of sample location. As discussed below, points of potential future contact with COPCs are limited to indoor air.

3.1 Soil Pathway
Per the Phase II Report (Roux, 2022b), arsenic was detected in concentrations above screening values.

However, the maximum detected arsenic concentration (5.30 mg/kg at B-5-3) was below the Southern California background arsenic concentration of 12 mg/kg (DTSC, 2020a). It is noted that limited detections of TPH were found in shallow soil at the area of below grade fill soil located within the staging area, which will reportedly be removed from the Subject Property. All other COPCs were detected at concentrations below screening values. As such, a quantitative evaluation of exposures to COPCs in soil was not completed as a part of this limited HHRA.

3.2 Groundwater/Surface Water Pathway
Per the Phase II Report (Roux, 2022b), depth to groundwater in the vicinity of the Subject Property is encountered at approximately 270 to 295 feet bgs. Roux did not collect groundwater data as part of the Phase I ESA or the Phase II Subsurface Investigation. Groundwater at the Subject Property is deeper than the maximum anticipated excavation depth during a construction worker scenario (down to 15 feet below surface). Consumption or ingestion of groundwater at the Subject Property is not prohibited; however, no groundwater wells are present on the Subject Property and current/future buildings are/will be connected to the municipal water source. As such, the groundwater pathway is not considered a complete exposure pathway and is not quantitatively evaluated as part of this limited HHRA.

3.3 Air Pathway
VOCs have been detected at the Subject Property in soil vapor samples that were collected 5 to 20 feet bgs. Therefore, vapor intrusion into indoor air is considered a potentially complete exposure pathway and was quantitatively evaluated in this HHRA.
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3.4 Exposure Pathway Analysis
The current and future intended use of the Subject Property is for commercial/industrial space. Potential future receptors could include outdoor workers, construction workers, trespassers, and residents (as there is no LUC prohibiting residential use). However, based on the aforementioned information discussed in previous sections, this HHRA was limited to looking at the future indoor commercial/industrial receptor. Therefore, the conceptual site model (CSM) presented below illustrates potentially complete exposure pathways at the Subject Property evaluated in this limited HHRA:

Primary
Source
Secondary
Source
Exposure
Media Exposure Route Receptor
Potential
Historical
Release(s)
Impacted
Vadose Zone
Soil Vapor
Indoor Air Inhalation
•Indoor
Commercial/Industrial
Worker
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4. Exposure Concentrations and Chemicals

4.1 Exposure Concentrations and Chemicals
Soil vapor sampling data utilized in the limited HHRA included samples collected by Roux in April 2022.

Exposure point concentrations (EPCs) for each media were equal to the following:
• Soil vapor: All compounds detected in soil vapor (VOCs) from the Roux April 2022 sampling event (Roux, 2022) were evaluated as COPCs:1,3,5-trimethylbenzene, 2-butanone, acetone, chloroethane, chloromethane, ethylbenzene, isopropanol, m,p-xylene, o-xylene, tetrachloroethene (PCE), toluene, and trichlorofluoromethane. For COPCs that were detected in ten or more samples, a 95% upper confidence limit (UCL) of the mean for samples up to 15 feet bgs was selected as the EPC for soil vapor. For the three contaminants detected in ten or more samples, no concentration measurements were statistical outliers (i.e., there are no hot spots). Therefore, the use of maximums and 95% UCLs is health protective. For COPCs that were detected in fewer than ten samples, the maximum detected concentration for samples up to 15 feet bgs was selected as the EPC for soil vapor. Roux April 2022 soil vapor samples were collected at 5 feet bgs, 10 feet bgs, 15 feet bgs, and 20 feet bgs. Soil vapor samples collected at 20 feet bgs (one sample) were excluded from this HHRA, consistent with guidance in Section 2A.3 of the Draft DTSC Supplemental Guidance (DTSC, 2020b).

Potential indoor air concentrations were calculated from soil vapor concentrations described above using methodology described in DTSC’s Preliminary Endangerment Assessment Guidance Manual (PEA Guidance; DTSC, 2015) and DTSC’s Vapor Intrusion Guidance (DTSC, 2011):

Cindoor = α x Csoil vapor
Where:

Cindoor= Indoor air concentration in µg/m3
α= Attenuation factor (assumed to be equal to 0.03 consistent with assumptions for future commercial/industrial scenarios using HERO and USEPA media-specific assumptions, respectively per DTSC, 2015, DTSC, 2020b, and DTSC, 2011).

Csoil vapor=Soil vapor air concentration in µg/m3
The table below provides a summary of the soil vapor data (excluding SV-1-20) utilized in the HHRA.

Summary of Soil Vapor Data Included in the HHRA
COPC Number of Soil
Vapor Samples
Number of
Detections
Range of
Detections
(µg/m3)
Soil Vapor
Concentration
(µg/m3)
EPC
Statistic
1,3,5-Trimethylbenzene 14 1 2.5 - 2.5 2.5E+00 Maximum
2-Butanone 14 10 4.3 - 17 1.1E+01 95% UCL
Acetone 14 14 6 - 100 4.7E+01 95% UCL
Chloroethane 14 1 1.4 - 1.4 1.4E+00 Maximum
Chloromethane 14 1 2.6 - 2.6 2.6E+00 Maximum
Ethylbenzene 14 1 3 - 3 3.0E+00 Maximum
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COPC Number of Soil
Vapor Samples
Number of
Detections
Range of
Detections
(µg/m3)
Soil Vapor
Concentration
(µg/m3)
EPC
Statistic
Isopropanol 14 1 14 - 14 1.4E+01 Maximum
m,p-Xylene 14 1 11 - 11 1.1E+01 Maximum
o-Xylene 14 2 2.8 - 3.1 3.1E+00 Maximum
Tetrachloroethene 14 7 3.8 - 210 2.1E+02 Maximum
Toluene 14 9 2 - 6.3 6.3E+00 Maximum
Trichlorofluoromethane 14 12 7 - 110 8.2E+01 95% UCL
(1) µg/m3 = micrograms per cubic meter.
(2) Data includes Roux April 2022 sampling event.
(3) Samples were collected from 13 unique location-depths. A duplicate sample was collected at SV2-5.

4.2 Quantification of Exposure
This HHRA assumed default exposure factors in EPA RSL User’s Guide for carcinogenic risk assessment of indoor worker exposure to air (USEPA, 2022b) and DTSC Note 1 (DTSC, 2019c). These exposure factors assume that the commercial/industrial worker is on-site 8 hours/day for 250 days/year for 25 years. For the cancer risk calculation, the lifetime averaging time is 70 years. If any of these default exposure assumptions is found to be invalid for this Subject Property, the HHRA may need to be revised. More details on calculation of risk and hazard from EPCs and the exposure factors presented here are described in Sections 6.1 and

6.2. 1835
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5. Toxicity Values
The toxicity assessment describes the quantitative relationship between the extent of exposure to a contaminant and the increased likelihood and/or severity of adverse effects. This quantitative relationship generally takes the form of toxicity values that are identified for use in risk evaluations. Toxicity values are used to quantify the chance of observing cancer or non-cancer effects in exposed receptors. Toxicity values may be based on epidemiological studies or animal studies.

Toxicity Values Utilized in the HHRA Indoor Air Evaluation COPC
Non-Cancer
Inhalation Reference
Concentration (RfC)
(µg/m3)
Cancer Inhalation
Unit Risk
(IUR)
(µg/m3)-1
Source
1,3,5-Trimethylbenzene 6.0E+01 -- EPA RSLs
2-Butanone 5.0E+03 -- EPA RSLs
Acetone -- -- EPA RSLs
Chloroethane 4.0E+03 -- EPA RSLs
Chloromethane 9.0E+01 -- EPA RSLs
Ethylbenzene 1.0E+03 2.5E-06 EPA RSLs
Isopropanol 2.0E+02 -- EPA RSLs
m,p-Xylene 1.0E+02 -- EPA RSLs
o-Xylene 1.0E+02 -- EPA RSLs
Tetrachloroethene 4.0E+01 6.1E-06 DTSC Note 10
Toluene 3.0E+02 -- DTSC Note 10
Trichlorofluoromethane 1.2E+03 -- DTSC Note 10
(1) Only compounds detected in soil vapor samples were evaluated herein; compounds below the laboratory reporting limit in all samples were not evaluated. (2) “--" = no toxicity value developed
(3) Toxicity values based on DTSC HHRA Note 10 (DTSC, 2019a) or USEPA’s November 2022 RSLs (USEPA, 2022a).

5.1 Toxicity Information for Non-Carcinogenic Effects
In assessing the potential for non-cancer health effects, USEPA assumes there is a toxicological threshold below which no adverse health effects are observable (USEPA, 1993). These toxicological thresholds are represented by reference concentrations (RfCs) for inhalation exposures. The RfCs are estimates (with uncertainty spanning, in some cases, an order of magnitude) of daily exposures to the human population (including sensitive subgroups) that are likely to be without an appreciable risk of deleterious effects during a lifetime. USEPA derives RfCs using a standardized approach, considering available information from human and animal studies, which establish the levels below which toxicological effects are not observed and the uncertainties inherent in the available information (USEPA, 1993).

5.2 Toxicity Information for Carcinogenic Effects
USEPA uses a two-part evaluation in assessing potentially carcinogenic substances. In the first part, a chemical is assigned a weight-of-evidence classification, which reflects USEPA’s assessment of the 1836
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likelihood that the chemical is a human carcinogen. For chemicals that are classified as possible, probable, or known human carcinogens, USEPA calculates an inhalation unit risk (IUR) for inhalation exposures when sufficient information is available to support the calculation. USEPA guidance indicates that a linear, nothreshold dose-response model is appropriate for carcinogenic risk assessment (USEPA, 2005). An extremely low level of exposure to a carcinogen may result in chromosomal or enzyme changes leading to cancer. Therefore, USEPA does not generally estimate thresholds for carcinogens. IURs are used to estimate the probability of a cancer effect occurring in a receptor exposed over their lifetime. 1837
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6. Risk Characterization Summary
The risk characterization process integrates the results of the data evaluation, exposure assessment, and toxicity assessment to provide a quantitative estimation of cumulative non-carcinogenic and carcinogenic risks for an indoor industrial/commercial worker’s exposure to indoor air as summarized in the table below:
• Indoor Commercial/Industrial Worker: The cancer risk estimate for an indoor commercial/industrial scenario is within the risk management target cancer threshold range of 1E06 to 1E-04. The non-cancer hazard estimate is below the non-cancer hazard target threshold of 1.

Cumulative Cancer and Non-Cancer Risks
Risk Target
Threshold
Indoor Commercial/Industrial Exposure to
Indoor Air
Estimated Risk Exceed Risk
Threshold?
Cancer
Risk
1E-06 to
1E-04 3E-06
Within risk
management target
threshold range
NonCancer
Hazard
1 4E-02 No
As specified in DTSC HERO’s Note 4 (DTSC, 2019b), risk estimates have been calculated using USEPA’s attenuation factor of 0.03 (see Table 1).

6.1 Cancer Risks
For carcinogens, risk is expressed as the probability that an individual will develop cancer over a lifetime because of exposure to the carcinogen and is expressed as incremental lifetime cancer risk (ILCR).

Carcinogenic risk for each compound is calculated according to the below equation, which is a modified version of the EPA RSL User’s Guide carcinogenic screening level derivation equation indoor worker exposure to air (USEPA, 2022b):

𝐼𝐼𝐼𝐼𝐼𝐼𝐼𝐼 = 𝐸𝐸𝐸𝐸 × 𝐼𝐼𝐼𝐼𝐼𝐼 × 𝐸𝐸𝐸𝐸𝑖𝑖𝑖𝑖𝑖𝑖 × 𝐸𝐸𝐸𝐸𝑖𝑖𝑖𝑖𝑖𝑖 × 𝐸𝐸𝐸𝐸𝑖𝑖𝑖𝑖𝑖𝑖 × 1 × 2
Where:

ILCR = incremental lifetime cancer risk (unitless)
EPC = indoor air concentration (µg/m3)
IUR = inhalation unit risk (µg/m3)-1
EFind = exposure frequency (days/year)
EDind = exposure duration (years)
ETind = exposure time (hours)
LT = lifetime averaging time
C1 = 365 days/year
C2 = 24 hours/day
This HHRA assumed default exposure factors in EPA RSL User’s Guide for carcinogenic risk assessment of indoor worker exposure to air (USEPA, 2022b) and DTSC Note 1 (DTSC, 2019c). 1838
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The combined risk from exposure to multiple constituents is evaluated by adding the risks from individual constituents, and multiple exposure pathways (as applicable) known as cumulative risk. The National Oil and Hazardous Substances Pollution Contingency Plan (NCP; 40 CFR 300) indicates that the ILCR posed by a site should not exceed a range of 1E-04 to 1E-06. The estimated cancer risks at the Subject Property are within the risk management target cancer risk threshold range (1E-06 to 1E-04) for an indoor commercial/industrial worker.

Cumulative Cancer Risk
Media
Indoor Commercial/Industrial
Exposure to Indoor Air
Estimated Risk Exceed
1E-04?
Soil
Vapor 3E-06 No
Risk estimates are provided in Table 1.

6.2 Non-Cancer Hazards
The non-carcinogenic hazard estimate is calculated according to the below equation to arrive at a Hazard Quotient (HQ) for each chemical. The below equation is a modified version of the EPA RSL User’s Guide non-carcinogenic screening level derivation equation indoor worker exposure to air (USEPA, 2022b):1 𝐻𝐻𝐻𝐻 =
𝐸𝐸𝐸𝐸
𝑅𝑅 × 𝐸𝐸𝐸𝐸𝑖𝑖𝑖𝑖𝑖𝑖 × 𝐸𝐸𝐸𝐸𝑖𝑖𝑖𝑖𝑖𝑖 × 𝐸𝐸𝐸𝐸𝑖𝑖𝑖𝑖𝑖𝑖
𝐸𝐸𝐸𝐸𝑖𝑖𝑖𝑖𝑖𝑖 × 1 × 2
Where:

HQ = hazard quotient (unitless)
EPC = indoor air concentration (µg/m3)
RfC = reference concentration (µg/m3)
EFind = exposure frequency (days/year)
EDind = exposure duration (years)
ETind = exposure time (hours)
C1 = 365 days/year
C2 = 24 hours/day
This HHRA assumed default exposure factors in EPA RSL User’s Guide for non-carcinogenic risk assessment of indoor worker exposure to air (USEPA, 2022b) and DTSC Note 1 (DTSC, 2019c).

To assess the potential for non-carcinogenic health effects posed by exposure to multiple constituents, a Hazard Index (HI) approach is used. This approach assumes that non-carcinogenic hazards associated with exposure to more than one constituent are additive (HI = sum of the HQs). Synergistic or antagonistic interactions between constituents are not considered. The HI is then compared to the DTSC threshold of 1 1 Per DTSC Note 3 (DTSC, 2022), DTSC uses the same equations as USEPA RSLs to derive its own DTSC screening levels.
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(DTSC, 2015). The non-cancer hazard estimates for a future indoor commercial/industrial worker receptor does not exceed this threshold, as shown below.

Cumulative Non-Cancer Hazard
Media
Indoor Commercial/Industrial
Exposure to Indoor Air
Estimated Risk
Exceed
1?
Soil
Vapor 4E-02 No
Hazard estimates are provided in Table 1. For a more detailed description of the HHRA’s conservative methodology, see the Section 6.3.

6.3 Uncertainty
Risk and hazard estimates resulting from application of this evaluation do not represent absolute estimates at a specific site because generic assumptions for commercial/industrial land use are utilized. Overall, carcinogenic excess lifetime cancer risk ILCR and non-carcinogenic HI presented in the HHRA are based upon conservative assumptions that are intended to be protective of human health by likely overestimating exposure to account for parameter uncertainty (RME exposure scenario). Therefore, the evaluation of current and future exposures in the HHRA is considered conservative.

Reliance on exposure point concentrations to quantify risk estimates inherently introduces uncertainty into risk and hazard estimates, due to uncertainty surrounding site characterization, and heterogeneity. Use of maximum concentrations or 95% UCLs of the mean as EPCs similarly introduces uncertainty, as these statistics almost certainly overestimate actual risk encountered. In particular, the maximum detected concentration was conservatively used to characterize the EPC for the main risk driver PCE. Additionally, for the indoor commercial/industrial worker indoor air exposure scenario, the attenuation factor of 0.03 is a conservative assumption, as DTSC will on occasion allow an attenuation factor of 0.0005 for vapor intrusion calculations.

For the indoor commercial/industrial worker exposure to indoor air pathway, toxicity values were not provided in DTSC HHRA Note 10 or USEPA 2022 RSLs for acetone. Therefore, this compound was not quantitatively evaluated in the HHRA. This omission is considered an area of uncertainty in the HHRA. However, given adoption of numerous conservative assumptions, this uncertainty is not considered to impact conclusions of the HHRA.

Uncertainty also lies in the exposure pathways and receptors evaluated. This limited HHRA only quantitatively evaluated indoor commercial/industrial worker exposure to indoor air. However, risk from the soil and groundwater consumption/ingestion pathways may exist, and other receptors may access the Subject Property in the future. Dermal contact with groundwater at the Subject Property for a construction worker is not considered given the depth to groundwater, but consumption or ingestion of groundwater at the Subject Property is possible as there are no restrictions on groundwater use at the Subject Property. No groundwater data was available, and if groundwater at the Subject Property becomes accessible in the future (through a potable or non-potable groundwater well) groundwater exposure would be a complete pathway 1840
3661.0019L000 HHRA | ROUX | 12
and the HHRA should be revised. Risk was not quantified for a construction worker, resident, outdoor commercial/industrial worker, or trespasser to soils. Even if TPH-soils are removed from the Subject Property in the future, other detected COPCs in soil that were well below screening levels may pose additional minimal, although non-zero, risk and hazard to construction workers, residents, outdoor commercial/industrial workers, and trespassers. The HHRA also did not evaluate the potential future residential exposure to indoor air, and the risk and hazard estimates from the commercial/industrial indoor air pathway evaluated in this HHRA would likely underestimate risk to residential receptors. 1841
3661.0019L000 HHRA | ROUX | 13

7. References
DTSC. 2011. DTSC Guidance for the Evaluation and Mitigation of Subsurface Vapor Intrusion to Indoor Air (Vapor Intrusion Guidance). October. Accessed at:
https://www.dtsc.ca.gov/assessingRisk/upload/Final_VIG_Oct_2011.pdf DTSC. 2015. Preliminary Endangerment Assessment Guidance Manual: A guidance manual for evaluating hazardous substance release sites: October. https://dtsc.ca.gov/wpcontent/uploads/sites/31/2018/04/DTSC-Preliminary-Endangerment-Assessment-Guidance-ManualOctober-2015.pdf DTSC. 2019a. Human Health Risk Assessment Note Number 10, Table 1: Toxicity Criteria Required by Rule and DTSC-Recommended Toxicity Criteria. February.

DTSC. 2019b. Human Health Risk Assessment Note 4: Screening Level Human Health Risk Assessments.

Accessed at: https://dtsc.ca.gov/wp-content/uploads/sites/31/2019/05/HHRA-Note-Number-4-May-14- 2019.pdf
DTSC. 2019c. Human Health Risk Assessment Note 1: Recommended DTSC Default Exposure Factors for Use in Risk Assessment at California Hazardous Waste Sites and Permitted Facilities. Accessed at:
https://dtsc.ca.gov/wp-content/uploads/sites/31/2021/10/HHRA-Note-1-April-2019-21A.pdf DTSC, 2020a. Note 11 Southern California Ambient Arsenic Screening Level. December 28, 2020.

DTSC, 2020b. Supplemental Guidance: Screening and Evaluating Vapor Intrusion (Draft for Public Comments).

February 2020. Accessed at: https://dtsc.ca.gov/wp-content/uploads/sites/31/2020/02/Public-DraftSupplemental-VI-Guidance_2020-02-14.pdf. DTSC, 2022. Human Health Risk Assessment (HHRA) Note Number 3, DTSC-modified Screening Levels (DTSC-SLs). Accessed at: https://dtsc.ca.gov/wpcontent/uploads/sites/31/2022/02/HHRA-Note-3-June2020-Revised-May2022A.pdf Roux, 2022a. Phase I Environmental Site Assessment of the Property Located at 2042 South Grove Avenue, Ontario, California, Assessor’s Parcel Number (APN) 105-049-111.

Roux, 2022b. Phase II Subsurface Investigation Report for 2042 South Grove Avenue, Ontario, California.

USEPA. 1989. Risk Assessment Guidance for Superfund. Volume I: Human health evaluation manual (Part A). Interim Final. Office of Emergency and Remedial Response. EPA/540/1-89/002. https://www.epa.gov/sites/default/files/2015-09/documents/rags_a.pdf USEPA. 1993. Reference Dose: Description and Use in Health Risk Assessments Background Document 1A: March 15.

USEPA. 1998. Toxicological Review of Hexavalent Chromium. August 1998. Accessed at:
https://cfpub.epa.gov/ncea/iris/iris_documents/documents/toxreviews/0144tr.pdf USEPA. 2005. Supplemental Guidance for Assessing Susceptibility from Early-Life Exposure to Carcinogens. Risk Assessment Forum. EPA/630/R-03/003F: March.

USEPA. 2022a. November 2022 Regional Screening Levels. Accessed at:
https://www.epa.gov/risk/regional-screening-levels-rsls-generic-tables USEPA, 2022b. November 2022 Regional Screening Levels (RSLs) – User’s Guide. Accessed at:
https://www.epa.gov/risk/regional-screening-levels-rsls-users-guide 1842
Human Health Screening Evaluation
2042 South Grove Avenue, Ontario, California
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TABLES

1. Summary of Hazard Indices and Incremental Lifetime Cancer Risk - Indoor Air Evaluation Based on Soil Vapor Concentrations:

Indoor Commercial/Industrial Worker Exposure Scenario
(Attenuation Factor 0.03)
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Table 1: Summary of Hazard Indices and Incremental Lifetime Cancer Risk:

Indoor Commercial/Industrial Soil Vapor (0.03 AF)
2042 S Grove Avenue,
Ontario, California
Compound Cas No.

Soil Vapor
Concentration
(µg/m3
)
Attenuation
Factor
(AF)
EPC
(µg/m3
)
IUR
(µg/m3
)
-1
RfC
(µg/m3
)
Incremental
Lifetime
Cancer Risk
(ILCR)
Hazard
Quotient
(HQ)
(3) (4)
1,3,5-Trimethylbenzene 108-67-8 2.50E+00 3.00E-02 7.50E-02 NC 6E+01 -- 3E-04 2-Butanone 78-93-3 1.14E+01 3.00E-02 3.43E-01 NC 5E+03 -- 2E-05 Acetone 67-64-1 4.74E+01 3.00E-02 1.42E+00 NC NS -- --
Chloroethane 75-00-3 1.40E+00 3.00E-02 4.20E-02 NC 4E+03 -- 2E-06 Chloromethane 74-87-3 2.60E+00 3.00E-02 7.80E-02 NC 9E+01 -- 2E-04 Ethylbenzene 100-41-4 3.00E+00 3.00E-02 9.00E-02 3E-06 1E+03 2E-08 2E-05 Isopropanol 67-63-0 1.40E+01 3.00E-02 4.20E-01 NC 2E+02 -- 5E-04 m,p-Xylene 108-38-3 1.10E+01 3.00E-02 3.30E-01 NC 1E+02 -- 8E-04 o-Xylene 95-47-6 3.10E+00 3.00E-02 9.30E-02 NC 1E+02 -- 2E-04 Tetrachloroethene 127-18-4 2.10E+02 3.00E-02 6.30E+00 6E-06 4E+01 3E-06 4E-02 Toluene 108-88-3 6.30E+00 3.00E-02 1.89E-01 NC 3E+02 -- 1E-04 Trichlorofluoromethane 75-69-4 8.18E+01 3.00E-02 2.45E+00 NC 1E+03 -- 5E-04 Total ILCR: 3E-06
Total HI: 4E-02
Exposure Factors and Conversion Factors: (5)
Lifetime (LT)= 70 years C1 = 365 days/year
Exposure frequency (EFind)= 250 days/year C2 = 24 hours/day Exposure Duration (EDind)= 25 years
Exposure Time (ETind)= 8 hours/day
Notes:
(7) µg/m3 = micrograms per cubic meter
(6) NC = Not carcinogenic, NS = No standard, -- = No Risk Estimate (1) (2)
(1) Indoor Air Exposure Point Concentration (EPC) = soil gas concentration (µg/m3)*AF where AF=steady state attenuation factor. AF assumed to be equal to 0.03 for Soil Gas in Table: Medium-Specific Attenuation Factors for VI to Indoor Air. DTSC's Supplemental Guidance: Screening and Evaluating Vapor Intrusion (Draft for Public Comments). February 2020.
(2) Toxicological values as provided in HHSE text; utilized Human Health Risk Assessment Note 10, and USEPA Regional Screening Levels (RSLs) dated November 2022 when unavailable in Note 10.
(3) ILCR = [EPC * IUR * EFind * EDind * ETind * (1/C2)]/(LT * C1) (4) HQ = [EPC * (1/RfC) * EFind * EDind * ETind * (1/C2)]/(EDind * C1) (5) This HHRA assumed default exposure factors in EPA RSL User’s Guide for carcinogenic risk assessment of indoor worker exposure to air (USEPA, 2022b) and DTSC Note 1 (DTSC, 2019c).

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Human Health Screening Evaluation
2042 South Grove Avenue, Ontario, California
3661.0016L109/CVRS ROUX
ATTACHMENT 1
ProUCL Output
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55 A B C D E F G H I J K L
Gamma ROS Statistics using Imputed Non-Detects
GROS may not be used when data set has > 50% NDs with many tied observations at multiple DLs GROS may not be used when kstar of detects is small such as <1.0, especially when the sample size is small (e.g., <15-20) For such situations, GROS method may yield incorrect values of UCLs and BTVs Mean (detects) 10.58
Theta hat (MLE) 3.003 Theta star (bias corrected MLE) 4.177 nu hat (MLE) 70.47 nu star (bias corrected) 50.66
Detected data follow Appr. Gamma Distribution at 5% Significance Level Gamma Statistics on Detected Data Only
k hat (MLE) 3.523 k star (bias corrected MLE) 2.533
K-S Test Statistic 0.243 Kolmogorov-Smirnov GOF
5% K-S Critical Value 0.268 Detected data appear Gamma Distributed at 5% Significance Level Gamma GOF Tests on Detected Observations Only
A-D Test Statistic 0.835 Anderson-Darling GOF Test
5% A-D Critical Value 0.731 Detected Data Not Gamma Distributed at 5% Significance Level

97.5% KM Chebyshev UCL 18.13 99% KM Chebyshev UCL 23.67 95% KM (z) UCL 11.25 95% KM Bootstrap t UCL 11.78
90% KM Chebyshev UCL 13.27 95% KM Chebyshev UCL 15.31
KM SD 5.309 95% KM (BCA) UCL 11.34
95% KM (t) UCL 11.43 95% KM (Percentile Bootstrap) UCL 11.19 Detected Data appear Approximate Normal at 5% Significance Level Kaplan-Meier (KM) Statistics using Normal Critical Values and other Nonparametric UCLs KM Mean 8.786 KM Standard Error of Mean 1.496
Lilliefors Test Statistic 0.234 Lilliefors GOF Test
5% Lilliefors Critical Value 0.262 Detected Data appear Normal at 5% Significance Level Normal GOF Test on Detects Only
Shapiro Wilk Test Statistic 0.816 Shapiro Wilk GOF Test 5% Shapiro Wilk Critical Value 0.842 Detected Data Not Normal at 5% Significance Level Mean of Logged Detects 2.21 SD of Logged Detects 0.595
Median Detects 10.35 CV Detects 0.529
Skewness Detects 0.0427 Kurtosis Detects -2.167
Variance Detects 31.33 Percent Non-Detects 28.57%
Mean Detects 10.58 SD Detects 5.597
Minimum Detect 4.3 Minimum Non-Detect 4.4
Maximum Detect 17 Maximum Non-Detect 4.4
Number of Detects 10 Number of Non-Detects 4
Number of Distinct Detects 8 Number of Distinct Non-Detects 1 General Statistics
Total Number of Observations 14 Number of Distinct Observations 9 Number of Bootstrap Operations 2000
2-Butanone
From File sv_ProUCL_Input.xls
Full Precision OFF
Confidence Coefficient 95%
UCL Statistics for Data Sets with Non-Detects
User Selected Options
Date/Time of Computation ProUCL 5.15/23/2022 10:47:56 AM 1846
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DL/2 is not a recommended method, provided for comparisons and historical reasons Nonparametric Distribution Free UCL Statistics
Detected Data appear Approximate Normal Distributed at 5% Significance Level SD in Original Scale 6.093 SD in Log Scale 0.831
95% t UCL (Assumes normality) 11.07 95% H-Stat UCL 15.34 DL/2 Statistics
DL/2 Normal DL/2 Log-Transformed
Mean in Original Scale 8.186 Mean in Log Scale 1.804
KM SD (logged) 0.586 95% Critical H Value (KM-Log) 2.168 KM Standard Error of Mean (logged) 0.165
KM SD (logged) 0.586 95% Critical H Value (KM-Log) 2.168 KM Standard Error of Mean (logged) 0.165 95% H-UCL (KM -Log) 12.42 Statistics using KM estimates on Logged Data and Assuming Lognormal Distribution KM Mean (logged) 1.996 KM Geo Mean 7.357
95% BCA Bootstrap UCL 11.19 95% Bootstrap t UCL 11.52
95% H-UCL (Log ROS) 13.83
SD in Original Scale 5.782 SD in Log Scale 0.709
95% t UCL (assumes normality of ROS data) 11.25 95% Percentile Bootstrap UCL 11.05 Detected Data appear Approximate Lognormal at 5% Significance Level Lognormal ROS Statistics Using Imputed Non-Detects
Mean in Original Scale 8.509 Mean in Log Scale 1.914
Lilliefors Test Statistic 0.227 Lilliefors GOF Test
5% Lilliefors Critical Value 0.262 Detected Data appear Lognormal at 5% Significance Level Lognormal GOF Test on Detected Observations Only
Shapiro Wilk Test Statistic 0.818 Shapiro Wilk GOF Test 5% Shapiro Wilk Critical Value 0.842 Detected Data Not Lognormal at 5% Significance Level 95% Gamma Approximate KM-UCL (use when n>=50) 12.15 95% Gamma Adjusted KM-UCL (use when n<50) 12.7 Gamma Kaplan-Meier (KM) Statistics
Approximate Chi Square Value (61.58, α) 44.53 Adjusted Chi Square Value (61.58, β) 42.61 80% gamma percentile (KM) 13.01 90% gamma percentile (KM) 16.71 95% gamma percentile (KM) 20.23 99% gamma percentile (KM) 27.98 nu hat (KM) 76.67 nu star (KM) 61.58
theta hat (KM) 3.208 theta star (KM) 3.995
Variance (KM) 28.19 SE of Mean (KM) 1.496
k hat (KM) 2.738 k star (KM) 2.199
Estimates of Gamma Parameters using KM Estimates
Mean (KM) 8.786 SD (KM) 5.309
Approximate Chi Square Value (36.34, α) 23.54 Adjusted Chi Square Value (36.34, β) 22.18 95% Gamma Approximate UCL (use when n>=50) 12.75 95% Gamma Adjusted UCL (use when n<50) 13.53 nu hat (MLE) 44.55 nu star (bias corrected) 36.34
Adjusted Level of Significance (β) 0.0312
k hat (MLE) 1.591 k star (bias corrected MLE) 1.298
Theta hat (MLE) 5.192 Theta star (bias corrected MLE) 6.365 Maximum 17 Median 5.05
SD 6.063 CV 0.734
For gamma distributed detected data, BTVs and UCLs may be computed using gamma distribution on KM estimates Minimum 0.524 Mean 8.26
This is especially true when the sample size is small.
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A B C D E F G H I J K L
Lognormal GOF Test
Shapiro Wilk Test Statistic 0.969 Shapiro Wilk Lognormal GOF Test Assuming Gamma Distribution
95% Approximate Gamma UCL (use when n>=50)) 50.34 95% Adjusted Gamma UCL (use when n<50) 52.78 Adjusted Level of Significance 0.0312 Adjusted Chi Square Value 36.6 MLE Mean (bias corrected) 35.57 MLE Sd (bias corrected) 25.54 Approximate Chi Square Value (0.05) 38.37
Theta hat (MLE) 14.77 Theta star (bias corrected MLE) 18.34 nu hat (MLE) 67.41 nu star (bias corrected) 54.3
Gamma Statistics
k hat (MLE) 2.408 k star (bias corrected MLE) 1.939
5% K-S Critical Value 0.231 Detected data appear Gamma Distributed at 5% Significance Level Detected data appear Gamma Distributed at 5% Significance Level 5% A-D Critical Value 0.745 Detected data appear Gamma Distributed at 5% Significance Level K-S Test Statistic 0.146 Kolmogorov-Smirnov Gamma GOF Test Gamma GOF Test
A-D Test Statistic 0.296 Anderson-Darling Gamma GOF Test 95% Student's-t UCL 47.42 95% Adjusted-CLT UCL (Chen-1995) 49.31 95% Modified-t UCL (Johnson-1978) 47.85
Data appear Approximate Normal at 5% Significance Level Assuming Normal Distribution
95% Normal UCL 95% UCLs (Adjusted for Skewness)
Lilliefors Test Statistic 0.205 Lilliefors GOF Test
5% Lilliefors Critical Value 0.226 Data appear Normal at 5% Significance Level Normal GOF Test
Shapiro Wilk Test Statistic 0.867 Shapiro Wilk GOF Test 5% Shapiro Wilk Critical Value 0.874 Data Not Normal at 5% Significance Level Coefficient of Variation 0.704 Skewness 1.427
Maximum 100 Median 25.5
SD 25.04 Std. Error of Mean 6.692
Number of Missing Observations 0
Minimum 6 Mean 35.57
Acetone
General Statistics
Total Number of Observations 14 Number of Distinct Observations 14 Recommendations are based upon data size, data distribution, and skewness.

These recommendations are based upon the results of the simulation studies summarized in Singh, Maichle, and Lee (2006).

However, simulations results will not cover all Real World data sets; for additional insight the user may want to consult a statistician.

When a data set follows an approximate (e.g., normal) distribution passing one of the GOF test When applicable, it is suggested to use a UCL based upon a distribution (e.g., gamma) passing both GOF tests in ProUCL Note: Suggestions regarding the selection of a 95% UCL are provided to help the user to select the most appropriate 95% UCL.

Suggested UCL to Use
95% KM (t) UCL 11.43
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A B C D E F G H I J K L
Lilliefors Test Statistic 0.32 Lilliefors GOF Test
5% Lilliefors Critical Value 0.243 Detected Data Not Normal at 5% Significance Level Normal GOF Test on Detects Only
Shapiro Wilk Test Statistic 0.808 Shapiro Wilk GOF Test 5% Shapiro Wilk Critical Value 0.859 Detected Data Not Normal at 5% Significance Level Mean of Logged Detects 3.27 SD of Logged Detects 0.856
Median Detects 21.5 CV Detects 0.893
Skewness Detects 1.294 Kurtosis Detects 0.621
Variance Detects 1091 Percent Non-Detects 14.29%
Mean Detects 37 SD Detects 33.04
Minimum Detect 7 Minimum Non-Detect 5.6
Maximum Detect 110 Maximum Non-Detect 5.6
Number of Detects 12 Number of Non-Detects 2
Number of Distinct Detects 11 Number of Distinct Non-Detects 1 General Statistics
Total Number of Observations 14 Number of Distinct Observations 12 Recommendations are based upon data size, data distribution, and skewness.

These recommendations are based upon the results of the simulation studies summarized in Singh, Maichle, and Lee (2006).

However, simulations results will not cover all Real World data sets; for additional insight the user may want to consult a statistician.

Trichlorofluoromethane
When a data set follows an approximate (e.g., normal) distribution passing one of the GOF test When applicable, it is suggested to use a UCL based upon a distribution (e.g., gamma) passing both GOF tests in ProUCL Note: Suggestions regarding the selection of a 95% UCL are provided to help the user to select the most appropriate 95% UCL.

Suggested UCL to Use
95% Student's-t UCL 47.42
90% Chebyshev(Mean, Sd) UCL 55.65 95% Chebyshev(Mean, Sd) UCL 64.74

97.5% Chebyshev(Mean, Sd) UCL 77.37 99% Chebyshev(Mean, Sd) UCL 102.2 95% Hall's Bootstrap UCL 52.29 95% Percentile Bootstrap UCL 46.64 95% BCA Bootstrap UCL 48.86
95% CLT UCL 46.58 95% Jackknife UCL 47.42
95% Standard Bootstrap UCL 46.17 95% Bootstrap-t UCL 54.29 Nonparametric Distribution Free UCL Statistics
Data appear to follow a Discernible Distribution at 5% Significance Level Nonparametric Distribution Free UCLs
95% Chebyshev (MVUE) UCL 67.36 97.5% Chebyshev (MVUE) UCL 80.96 99% Chebyshev (MVUE) UCL 107.7
Assuming Lognormal Distribution
95% H-UCL 58.52 90% Chebyshev (MVUE) UCL 57.57
Maximum of Logged Data 4.605 SD of logged Data 0.713
Lognormal Statistics
Minimum of Logged Data 1.792 Mean of logged Data 3.35
5% Lilliefors Critical Value 0.226 Data appear Lognormal at 5% Significance Level Data appear Lognormal at 5% Significance Level
5% Shapiro Wilk Critical Value 0.874 Data appear Lognormal at 5% Significance Level Lilliefors Test Statistic 0.138 Lilliefors Lognormal GOF Test 1849
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A B C D E F G H I J K L
Lognormal GOF Test on Detected Observations Only
Shapiro Wilk Test Statistic 0.943 Shapiro Wilk GOF Test 5% Shapiro Wilk Critical Value 0.859 Detected Data appear Lognormal at 5% Significance Level 95% Gamma Approximate KM-UCL (use when n>=50) 55.56 95% Gamma Adjusted KM-UCL (use when n<50) 59.83 Gamma Kaplan-Meier (KM) Statistics
Approximate Chi Square Value (25.11, α) 14.69 Adjusted Chi Square Value (25.11, β) 13.65 80% gamma percentile (KM) 52.76 90% gamma percentile (KM) 76.9 95% gamma percentile (KM) 101.3 99% gamma percentile (KM) 158.3 nu hat (KM) 30.26 nu star (KM) 25.11
theta hat (KM) 30.09 theta star (KM) 36.26
Variance (KM) 978.3 SE of Mean (KM) 8.731
k hat (KM) 1.081 k star (KM) 0.897
Estimates of Gamma Parameters using KM Estimates
Mean (KM) 32.51 SD (KM) 31.28
Approximate Chi Square Value (12.03, α) 5.247 Adjusted Chi Square Value (12.03, β) 4.665 95% Gamma Approximate UCL (use when n>=50) 72.72 95% Gamma Adjusted UCL (use when n<50) 81.78 nu hat (MLE) 13.61 nu star (bias corrected) 12.03
Adjusted Level of Significance (β) 0.0312
k hat (MLE) 0.486 k star (bias corrected MLE) 0.43
Theta hat (MLE) 65.23 Theta star (bias corrected MLE) 73.82 Maximum 110 Median 19
SD 33.23 CV 1.048
For gamma distributed detected data, BTVs and UCLs may be computed using gamma distribution on KM estimates Minimum 0.01 Mean 31.72
Gamma ROS Statistics using Imputed Non-Detects
GROS may not be used when data set has > 50% NDs with many tied observations at multiple DLs GROS may not be used when kstar of detects is small such as <1.0, especially when the sample size is small (e.g., <15-20) For such situations, GROS method may yield incorrect values of UCLs and BTVs This is especially true when the sample size is small.

Mean (detects) 37
Theta hat (MLE) 22.96 Theta star (bias corrected MLE) 29.27 nu hat (MLE) 38.68 nu star (bias corrected) 30.34
Detected data follow Appr. Gamma Distribution at 5% Significance Level Gamma Statistics on Detected Data Only
k hat (MLE) 1.612 k star (bias corrected MLE) 1.264
K-S Test Statistic 0.261 Kolmogorov-Smirnov GOF
5% K-S Critical Value 0.249 Detected Data Not Gamma Distributed at 5% Significance Level Gamma GOF Tests on Detected Observations Only
A-D Test Statistic 0.587 Anderson-Darling GOF Test
5% A-D Critical Value 0.745 Detected data appear Gamma Distributed at 5% Significance Level

97.5% KM Chebyshev UCL 87.04 99% KM Chebyshev UCL 119.4 95% KM (z) UCL 46.88 95% KM Bootstrap t UCL 54.36
90% KM Chebyshev UCL 58.71 95% KM Chebyshev UCL 70.57
KM SD 31.28 95% KM (BCA) UCL 46.73
95% KM (t) UCL 47.98 95% KM (Percentile Bootstrap) UCL 46.19 Detected Data Not Normal at 5% Significance Level
Kaplan-Meier (KM) Statistics using Normal Critical Values and other Nonparametric UCLs KM Mean 32.51 KM Standard Error of Mean 8.731
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A B C D E F G H I J K L
Recommendations are based upon data size, data distribution, and skewness.

These recommendations are based upon the results of the simulation studies summarized in Singh, Maichle, and Lee (2006).

However, simulations results will not cover all Real World data sets; for additional insight the user may want to consult a statistician.

When a data set follows an approximate (e.g., normal) distribution passing one of the GOF test When applicable, it is suggested to use a UCL based upon a distribution (e.g., gamma) passing both GOF tests in ProUCL Note: Suggestions regarding the selection of a 95% UCL are provided to help the user to select the most appropriate 95% UCL.

Suggested UCL to Use
95% KM Adjusted Gamma UCL 59.83 95% GROS Adjusted Gamma UCL 81.78 DL/2 is not a recommended method, provided for comparisons and historical reasons Nonparametric Distribution Free UCL Statistics
Detected Data appear Approximate Gamma Distributed at 5% Significance Level SD in Original Scale 32.83 SD in Log Scale 1.132
95% t UCL (Assumes normality) 47.65 95% H-Stat UCL 93.41 DL/2 Statistics
DL/2 Normal DL/2 Log-Transformed
Mean in Original Scale 32.11 Mean in Log Scale 2.95
KM SD (logged) 0.932 95% Critical H Value (KM-Log) 2.681 KM Standard Error of Mean (logged) 0.26
KM SD (logged) 0.932 95% Critical H Value (KM-Log) 2.681 KM Standard Error of Mean (logged) 0.26 95% H-UCL (KM -Log) 65.1 Statistics using KM estimates on Logged Data and Assuming Lognormal Distribution KM Mean (logged) 3.049 KM Geo Mean 21.09
95% BCA Bootstrap UCL 49.36 95% Bootstrap t UCL 56.01
95% H-UCL (Log ROS) 85.41
SD in Original Scale 32.74 SD in Log Scale 1.084
95% t UCL (assumes normality of ROS data) 47.71 95% Percentile Bootstrap UCL 46.11 Detected Data appear Lognormal at 5% Significance Level Lognormal ROS Statistics Using Imputed Non-Detects
Mean in Original Scale 32.21 Mean in Log Scale 2.978
Lilliefors Test Statistic 0.209 Lilliefors GOF Test
5% Lilliefors Critical Value 0.243 Detected Data appear Lognormal at 5% Significance Level 1851
DATE: June 8, 2023
TO: Nicole Morse, T&B Planning, Inc.

FROM: Haseeb Qureshi
Ali Dadabhoy
Shannon Wong
JOB NO: 15067-02 AQ & GHG Assessment

FIRST GROVE AIR QUALITY & GREENHOUSE GAS ASSESSMENT
Nicole Morse,
Urban Crossroads, Inc. is pleased to provide the following Air Quality & Greenhouse Gas Assessment for the First Grove (Project), which is located north of E. Philadelphia Street and west of S. Grove Ave in the City of Ontario.

PROJECT OVERVIEW
It is our understanding that the Project is to consist of a 61,867 square foot industrial warehouse building on 4.20 acres (see Exhibit 1).

The Project site land use is currently designated as Business Park under The Ontario Plan (TOP) 2050. The currently adopted General Plan Business Park land use allows for the development of up to 109,817 square feet of business park use, calculated using a floor-to-area ratio (FAR) of 0.60. The Business Park land use designation is defined as “employee-intensive office uses including corporate offices, technology centers, research and development, “clean” industry, light manufacturing, and supporting retail within a business park setting.”

SUMMARY OF FINDINGS
Results of the assessment indicate that the Project would result in a less than significant with respect to air quality and greenhouse gases. 1852
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EXHIBIT 1: SITE PLAN

PROJECT AIR QUALITY IMPACTS

AIR QUALITY SETTING

SOUTH COAST AIR BASIN (SCAB)
The Project site is located in the SCAB within the jurisdiction of South Coast Air Quality Management District (SCAQMD) (1). The SCAQMD was created by the 1977 Lewis-Presley Air Quality Management Act, which merged four county air pollution control bodies into one regional district. Under the Act, the SCAQMD is responsible for bringing air quality in areas under its jurisdiction into conformity with federal and state air quality standards. As previously stated, the Project site is located within the SCAB, a 6,745-square mile subregion of the SCAQMD, which includes portions of Los Angeles, Riverside, and San Bernardino Counties, and all of Orange County.

The SCAB is bounded by the Pacific Ocean to the west and the San Gabriel, San Bernardino, and San Jacinto Mountains to the north and east. The Los Angeles County portion of the Mojave Desert Air Basin is bounded by the San Gabriel Mountains to the south and west, the Los Angeles / Kern County border to the north, and the Los Angeles / San Bernardino County border to the east. The Riverside County portion of the Salton Sea Air Basin is bounded by the San Jacinto Mountains in the west and spans eastward up to the Palo Verde Valley.

Regional Climate
The regional climate has a substantial influence on air quality in the SCAB. In addition, the temperature, wind, humidity, precipitation, and amount of sunshine influence the air quality. 1853
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The annual average temperatures throughout the SCAB vary from the low to middle 60s degrees Fahrenheit (°F). Due to a decreased marine influence, the eastern portion of the SCAB shows greater variability in average annual minimum and maximum temperatures. January is the coldest month throughout the SCAB, with average minimum temperatures of 47°F in downtown Los Angeles and 36°F in San Bernardino. All portions of the SCAB have recorded maximum temperatures above 100°F.

Although the climate of the SCAB can be characterized as semi-arid, the air near the land surface is quite moist on most days because of the presence of a marine layer. This shallow layer of sea air is an important modifier of SCAB climate. Humidity restricts visibility in the SCAB, and the conversion of sulfur dioxide (SO2) to sulfates (SO4) is heightened in air with high relative humidity.

The marine layer provides an environment for that conversion process, especially during the spring and summer months. The annual average relative humidity within the SCAB is 71 percent (%) along the coast and 59% inland. Since the ocean effect is dominant, periods of heavy early morning fog are frequent and low stratus clouds are a characteristic feature. These effects decrease with distance from the coast.

More than 90% of the SCAB’s rainfall occurs from November through April. The annual average rainfall varies from approximately nine inches in Riverside to fourteen inches in downtown Los Angeles. Monthly and yearly rainfall totals are extremely variable. Summer rainfall usually consists of widely scattered thunderstorms near the coast and slightly heavier shower activity in the eastern portion of the SCAB with frequency being higher near the coast.

Due to its generally clear weather, about three-quarters of available sunshine is received in the SCAB. The remaining one-quarter is absorbed by clouds. The ultraviolet portion of this abundant radiation is a key factor in photochemical reactions. On the shortest day of the year there are approximately 10 hours of possible sunshine, and on the longest day of the year there are approximately 14½ hours of possible sunshine.

The importance of wind to air pollution is considerable. The direction and speed of the wind determines the horizontal dispersion and transport of the air pollutants. During the late autumn to early spring rainy season, the SCAB is subjected to wind flows associated with the traveling storms moving through the region from the northwest. This period also brings five to ten periods of strong, dry offshore winds, locally termed “Santa Anas” each year. During the dry season, which coincides with the months of maximum photochemical smog concentrations, the wind flow is bimodal, typified by a daytime onshore sea breeze and a nighttime offshore drainage wind.

Summer wind flows are created by the pressure differences between the relatively cold ocean and the unevenly heated and cooled land surfaces that modify the general northwesterly wind circulation over southern California. Nighttime drainage begins with the radiational cooling of the mountain slopes. Heavy, cool air descends the slopes and flows through the mountain passes and canyons as it follows the lowering terrain toward the ocean. Another characteristic wind regime in the SCAB is the “Catalina Eddy,” a low level cyclonic (counterclockwise) flow centered over Santa Catalina Island which results in an offshore flow to the southwest. On most spring and summer days, some indication of an eddy is apparent in coastal sections.

In the SCAB, there are two distinct temperature inversion structures that control vertical mixing of air pollution. During the summer, warm high-pressure descending (subsiding) air is undercut by a shallow layer of cool marine air. The boundary between these two layers of air is a persistent 1854
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marine subsidence/inversion. This boundary prevents vertical mixing which effectively acts as an impervious lid to pollutants over the entire SCAB. The mixing height for the inversion structure is normally situated 1,000 to 1,500 feet above mean sea level.

A second inversion-type forms in conjunction with the drainage of cool air off the surrounding mountains at night followed by the seaward drift of this pool of cool air. The top of this layer forms a sharp boundary with the warmer air aloft and creates nocturnal radiation inversions.

These inversions occur primarily in the winter when nights are longer and onshore flow is weakest. They are typically only a few hundred feet above mean sea level. These inversions effectively trap pollutants, such as nitrogen oxides (NOX) and carbon monoxide (CO) from vehicles, as the pool of cool air drifts seaward. Winter is therefore a period of high levels of primary pollutants along the coastline.

Wind Patterns and Project Location
The distinctive climate of the Project area and the SCAB is determined by its terrain and geographical location. The SCAB is located in a coastal plain with connecting broad valleys and low hills, bounded by the Pacific Ocean in the southwest quadrant with high mountains forming the remainder of the perimeter.

Wind patterns across the south coastal region are characterized by westerly and southwesterly onshore winds during the day and easterly or northeasterly breezes at night. Winds are characteristically light although the speed is somewhat greater during the dry summer months than during the rainy winter season.

Criteria Pollutants
Both the U.S. Environmental Protection Agency (EPA) and the California Air Resources Board (CARB) have established ambient air quality standards for common pollutants. These ambient air quality standards are levels of contaminants representing safe levels that avoid specific adverse health effects associated with each pollutant. The ambient air quality standards cover what are called “criteria” pollutants because the health and other effects of each pollutant are described in criteria documents. The six criteria pollutants are ozone (O3) (precursor emissions include NOX and reactive organic gases (ROG), CO, particulate matter (PM), nitrogen dioxide (NO2), sulfur dioxide (SO2), and lead. Areas that meet ambient air quality standards are classified as attainment areas, while areas that do not meet these standards are classified as nonattainment areas. The Riverside County portion of the SCAB is designated as a nonattainment area for the federal O3 and PM2.5 standards and is also a nonattainment area for the state standards for O3, PM10, and PM2.5.

Toxic Air Contaminants (TAC) Trend
In 1984, as a result of public concern for exposure to airborne carcinogens, CARB adopted regulations to reduce the amount of TAC emissions resulting from mobile and area sources, such as cars, trucks, stationary products, and consumer products. According to the Ambient and Emission Trends of Toxic Air Contaminants in California journal article (2) which was prepared for CARB, results show that between 1990-2012, ambient concentration and emission trends for the seven TACs responsible for most of the known cancer risk associated with airborne exposure in California have declined significantly (between 1990 and 2012). The seven TACs studied include those that are derived from mobile sources: diesel particulate matter (DPM), benzene (C6H6), and 1855
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1,3-butadiene (C4H6); those that are derived from stationary sources: perchloroethylene (C2Cl4) and hexavalent chromium (Cr(VI)); and those derived from photochemical reactions of emitted VOCs: formaldehyde (CH2O) and acetaldehyde (C2H4O)1. The decline in ambient concentration and emission trends of these TACs are a result of various regulations CARB has implemented to address cancer risk.

Some people are especially sensitive to air pollution and are given special consideration when evaluating air quality impacts from projects. These groups of people include children, the elderly, and individuals with pre-existing respiratory or cardiovascular illness. Structures that house these persons or places where they gather are defined as “sensitive receptors”. These structures typically include uses such as residences, hotels, and hospitals where an individual can remain for 24 hours. Consistent with the LST Methodology, the nearest land use where an individual could remain for 24 hours to the Project site has been used to determine construction and operational air quality impacts for emissions of PM10 and PM2.5, since PM10 and PM2.5 thresholds are based on a 24-hour averaging time.

Receptors in the Project study area are described below. All distances are measured from the Project site boundary to the outdoor living areas (e.g., backyards) or at the building façade, whichever is closer to the Project site. Receptors in the Project study area are shown on Exhibit 2 under the Localized Construction Emissions section later in the report. • Receptor R1 represents the existing residence at 2125 S Cucamonga Ave, approximately 596 feet southwest of the Project site.
• Receptor R2 represents Home of the Christian-Bethel Church at 1147 E Philadelphia St, approximately 439 feet south of the Project site.
• Receptor R3 represents the existing residence at 1456 E Philadelphia St, approximately 824 feet southeast of the Project site.
• Receptor R4 represents The Grove Apartments at 1110 E Philadelphia St, approximately 756 feet south of the Project site.
• Receptor R5 represents Bon View Elementary at 2121 S Bon View Ave, approximately 1,521 feet west of the Project site.
• Receptor R6 represents Tech Industrial Machine Corp at 2124 S Grove Ave Unit J, adjacent south of the Project site.

REGULATORY BACKGROUND

FEDERAL REGULATIONS
The EPA is responsible for setting and enforcing the national ambient air quality standards (NAAQS) for O3, CO, NOX, SO2, PM10, and lead (Pb) (3). The EPA has jurisdiction over emissions sources that are under the authority of the federal government including aircraft, locomotives, 1 It should be noted that ambient DPM concentrations are not measured directly. Rather, a surrogate method using the coefficient of haze (COH) and elemental carbon (EC) is used to estimate DPM concentrations. 1856
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and emissions sources outside state waters (Outer Continental Shelf). The EPA also establishes emission standards for vehicles sold in states other than California. Automobiles sold in California must meet the stricter emission requirements of CARB.

The Federal Clean Air Act (CAA) was first enacted in 1955 and has been amended numerous times in subsequent years (1963, 1965, 1967, 1970, 1977, and 1990). The CAA establishes the federal air quality standards, the NAAQS, and specifies future dates for achieving compliance (4). The CAA also mandates that each state submit and implement state implementation plans (SIPs) for local areas not meeting these standards. These plans must include pollution control measures that demonstrate how the standards will be met.

The 1990 amendments to the CAA that identify specific emission reduction goals for areas not meeting the NAAQS require a demonstration of reasonable further progress toward attainment and incorporate additional sanctions for failure to attain or to meet interim milestones. The sections of the CAA most directly applicable to the development of the Project site include Title I (Non-Attainment Provisions) and Title II (Mobile Source Provisions) (5) (6). Title I provisions were established with the goal of attaining the NAAQS for the following criteria pollutants O3, NO2, SO2, PM10, CO, PM2.5, and Pb. The NAAQS were amended in July 1997 to include an additional standard for O3 and to adopt a NAAQS for PM2.5.

Mobile source emissions are regulated in accordance with Title II provisions. These provisions require the use of cleaner burning gasoline and other cleaner burning fuels such as methanol and natural gas. Automobile manufacturers are also required to reduce tailpipe emissions of hydrocarbons and NOX. NOX is a collective term that includes all forms of NOX which are emitted as byproducts of the combustion process.

CALIFORNIA REGULATIONS
CARB
The CARB, which became part of the California EPA (CalEPA) in 1991, is responsible for ensuring implementation of the California Clean Air Act (AB 2595), responding to the federal CAA, and for regulating emissions from consumer products and motor vehicles. AB 2595 mandates achievement of the maximum degree of emissions reductions possible from vehicular and other mobile sources in order to attain the state ambient air quality standards by the earliest practical date. The CARB established the California ambient air quality standards (CAAQS) for all pollutants for which the federal government has NAAQS and, in addition, establishes standards for SO4, visibility, hydrogen sulfide (H2S), and vinyl chloride (C2H3Cl). However, at this time, H2S and C2H3Cl are not measured at any monitoring stations in the SCAB because they are not considered to be a regional air quality problem. Generally, the CAAQS are more stringent than the NAAQS (7) (8).

Local air quality management districts, such as the SCAQMD, regulate air emissions from stationary sources such as commercial and industrial facilities. All air pollution control districts have been formally designated as attainment or non-attainment for each CAAQS.

Serious non-attainment areas are required to prepare Air Quality Management Plans (AQMP) that include specified emission reduction strategies in an effort to meet clean air goals. These plans are required to include:
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