granted based on information supplied by the owner that refuse in the landfill was placed below the ground water table.
Should you have any questions or comments, you may contact Mercedes A. Murillo at (213) 620-5444.
DENNIS DASKER
supervising water Resource
Control Engineer
RKD:MAM
cc: Mr. Jim Parsons, DWQ, SWRCB
~r. Fred w. Tahse, IT Corporation
I]]
INTERNATIONAL
TECHNOLOGY
·CORPORATION .
August 30, 1988
Project No. 240827-08-01
Ms. Mercedes A. Murillo
California Regional Water Quality
Control Board, Los Angeles Region
107 South Broadway, Room 4027
Los Angeles, California 90012-4596
Dear Ms. Murillo:
ADDENDUM
SOLID WASTE ASSESSMENT TEST PROPOSAL
MARKET PLACE SANITARY LANDFILL
As per your letter dated August 17, 1988 (copy attached), IT Corporation (IT), as consultants for and on behalf of our client, the Bixby Ranch Company, is hereby submitting to the Regional Water Quality Control Board, Los Angeles Region, a surface-water monitoring plan (Item No. 1) for the Market Place Sanitary Landfi 11. A work plan to identify the presence of multiple aquifers beneath the site (Item No. 2) will be submitted to Board staff prior to sampling of the monitoring wells. As per your letter, Items 3 through 6 will be included in the final SWAT report.
SURFACE WATER MONITORING PLAN
The following describes the surface water monitoring plan for the Market Place Sanitary Landfill, including: a map designating the locations of proposed water sampling, sampling protocol, analyses, and schedule.
Sample Location
One surf ace water runoff samp 1 e will be co 11 ected a 1 ong the northeastern boundary of the landfill where the surface runoff from precipitation onto the landfill surface drains (Ft~ure 1). The slope of the landfill on this side is steep enough to allow for the collection of the sample. Samples which may be representat 1ve of surface runoff from the 1 andftll cannot be collected from other areas of the landfill, st nee most of the 1 and fill surface area is covered with asphalt pavement.
Regional Office
17461 Derian Avenue. Suite 190 • Irvine. California 92714 • 714-261-6441 lT Corpor.ation is a wholly owned subsidiary of ln ternational Technology Corporation (,
\ )
)
Ms. Mercedes Murillo
August 30, 1988
Sampling Protocol
INTERNATIONAL TECHNOLOGY CORPORAT:CN
One set of surface water runoff samples will be collected from the north eastern boundary of the 1 andfi ll. One samp 1 e will be collected from the ·sample location shown on Figure 1 (MPSF-1). The sample will be collected by installing a catch basin, approximately 1 by 2 feet in dimension. The sample will be collected within approximately the first hour of a rain storm. If a sufficient volume of sample cannot be collected from the catch basin, a sample will be collected as close to the sampling point as possible.
The surface water sample will be collected in the proper containers, labeled, and. packed on ice for delivery to the laboratory. IT's chain-of-custody procedures will be fo 11 owed to ensure integrity of samp 1 es de 1 i vered to the laboratory.
Laboratory Analysis
Samples will be analyzed for the following constituents:
• EPA methods 601, 602, and 625
(If'
• MEK by EPA methods 602 ~ 8015
• Acetone by EPA method 624
• ICP metals: Sb, As, Ba, Be, Cd, Ca, Cr, Co, Cu, Fe,
Pb, Mn, Mo, Ni, K, Ag, Na, Tl, V, and Zn.
• Hg and Se by atomic absorption spectroscopy
• Phosphate
• Sulfate
• Chloride
• Nitrate
• Electrical conductivity
• pH
• TDS
• coo
• Alkalinity, TOC, BOD, oil and grease.
Ms. Mercedes Murillo
August 30, 1988
INTERNATIONAL TECHNOLOGY CORPORA~:Ol'-."
All analytical determinations will be made by a laboratory certified by the California Department of Health Services.
Sampling Schedule
Due to the uncertain and intermittent nature of precipitation in this area a specific sampling schedule cannot be determined. However, we expect to collect the surface water runoff sample by the end of December 1988.
If you have any questions concerning· this proposal, please call the under signed at (714) 261-6441.
Respectfully submitted,
IT; CfPORATION .
/~!Jt-L, {[c JL,;_,_,
~ hn Audinis
;;;:::~~
, ~ ~red W. Tahse
) Project Director
JA/FWT:et
Enclosures: Figure 1 - Natural Drainage System
SIX:0827-L9
California Regional Water Quality Control Board, Region letter Market Place Landfill - City Dump and Salvage 12 (File No. 88-50) T
<
r--
N
r--- (l)
'o
<;t
N
£
..; : .. .::
_;_
"'
~
.;
__ /
j
. ' . -
I
+
SIT~
SCALE
0 2000 4000 FEET
- LEGEND
···----- SURFACE WATER FLOW
S SURFACE' WATER SAMPLt LOCATION
REFERENCE:
USGS 7.5 MINUTE TOPOGRAPHIC MAP OF
LONG BEACH, LOS ALAMITOS AND SEAL BEACH,
CALIFORNIA QUADRANGLE; DATE: 1964, 1964 AND
1965 RESPECTIVELY; PHOTOREVISED: 1981; SCALE 1=24000
FIGURE
NATURAL DRAINAGE SYSTEM
MARKET PLACE LANDFILL
PREPARED FOR
BIXBY RANCH COMPANY
LONG BEACH, CALIFORNIA
... Creating a Sater Tomorrow &
;;,ST;,;;A;,;,T,:;E,;;O;;.,F,;;C,;;;;A~LI~F;;;,OR;,;,;N;,;I;;,A=========================~G EO i1G,E :: E L :< '·' :':.J;,:. \ G.:J, ~ ·-:· CALIFORNIA REGIONAL WATER QUALITY CONTROL BOARD
LOS ANGELES REGION
107 SOUTH BROADWAY. SUITE 4027
.:.as ANGELES, CALIFORNIA 90012-4596
(213) 620-4460
)
September 22, 1988
Ms. Judi McCaslin,
Construction Manager
Bixby Ranch Company
911 Studebaker Road
Long Beach, California
MARKET PLACE LANDFILL-CITY DUMP & SALVAGE #2 (FILE NO. 88-50) Board staff has reviewed the August 31, 1988 addendum to the revised SWAT proposal for the subject landfill. The proposed ~urface monitoring location, analyses, and tentative schedule are approved.
· Should you have any questions or comments, you may contact .Hercedes A. Murillo at (213) 620-5444.
RAYMOND K. DELACOURT
Senior Water Resource
Control Engineer
RKD:MAM
cc: ~r. Jim Parsons, DWQ, SWRCB
~Mr. Fred W. Tahse, IT Corporation
STATE OF CALIFORNIA
CALIFORNIA REGIONAL WATER QUALITY CONTROL BOARD
LOS ANGELES REGION
~ · ', 107 SOUTH BROADWAY. SUITE 4027
1 LOS ANGELES, CALIFORNIA 90012-4596
/ (213) 620-4460
October 20, 1988
Ms. Judi McCaslin,
Construction Manager
Bixby Ranch Company
911 Studebaker Road
Long Beach, California
MARKET PLACE LANDFILL-CITY DUMP & SALVAGE #2 (FILE NO. 88-50) Board staff has reviewed the September 14, 1988 SWAT Proposal for the subject landfill, which proposes to identify the presence of multiple aquifers by chemical analyses.
We recognize that the area may not be responsive to pump testing, due to nearby injection wells used to prevent seawater intrusion by creating a pressure barrier, and therefore approve the proposed aquifer identification plan. This work can begin immediately.
We would like to caution you, however, that anomalies in the general minerals analyses proposed may be present due to landfill contaminants, and an alternative means of aquifer definition may be necessary. Please submit such a contingency plan to us by November 7, 1988.
Should you have any questions or comments, you may contact Mercedes A. Murillo at (213) 620-5444.
RAYMOND K. DELACOURT
senior Water Resource
Control Engineer
cc: ~· Jim Parsons, DWQ, SWRCB
~r. Fred w. Tahse, IT Corporation
rn
INTERNATIONAL ·\ TECHNOLOGY
CORPORATION
November 8, 1988
Project No. 240827-05
Ms. Mercedes A. Murillo
California Regional Water Quality
Control Board - Los Angeles Region
107 South Broadway, Room 4027
Los Angeles, California 90012-4596
Dear Ms. Murillo:
As per our recent conversation, I am writing this letter to inform you that IT Corporation (IT) will be installing a ground-water monitoring well at the Bixby Ranch Company Market Place landfill to replace existing monitoring well MW-1, which was to be used as one of the SWAT monitoring wells (Figure 1).
Well MW-1, along with another. well, MW-2A, was inadvertently covered by 3 to 4 feet of soi 1 as a result of regrading the surface of the site. Wells MW-1 and MW-2A were constructed of 2-i nch diameter flush-threaded PVC well cas i n.g.
Both wells. were sealed at the surface within locked steel traffic boxes.
Copies of well construction details are attached.
An attempt was made to find the wells with geophysical surveying equipment after they were covered; however, the presence of numerous metallic fragments, such as nails and other pieces of scrap metal within the soil, interfered with the equipment's operation, and the wells could not be located. IT believes that these we 11 s will not serve as conduits for contaminants to enter the ground water, since well MW-2A was installed within refuse (well construction details), and both wells, MW-1 and MW-2A, were properly sealed with bentonite and gr.out and.locked prior to being covered with soil.
The new well, which will be drilled near well MW-1 (Figure 1), will be constructed of a 4-inch-diameter flush-threaded PVC well casing with the same construction details as outlined in the SWAT Proposal for the Market Place landfill.
As per your letter requesting the submittal of a contingency plan regarding the identification of multiple· aquifers at the Bixby Market Place,· Bixby Village, and Studebaker-Loynes landfills, IT proposes to include information from published reports ·and information such as boring logs of water wells, monitoring wells, and information from a recently completed study of a part of the Newport~Inglewood Fault Zone, which confirms our belie-f that all monitoring wells at the Bixby landfills are located within.a single aquifer.
Regional Office
17461 Derian Avenue • Suite 190. Irvine. Califo:r::nia 92714. 714-261-6441 IT Corporation is a wholly owned subsidiary of International Technology Corporation ~'
( )
Ms. Mercedes A. Murillo
November 8, 1988
INTERNATIONAL TECHNOLCGY CCRPCR.A.T:CN
A thorough interpretation of· the hydrogeology beneath the Bixby 1 and fills will be included in our SWAT report, which will be submitted to Bixby in approximately 5 weeks.
If you have any questions concerning this letter, please call the undersigned at (714) 261-6441.
Respectfully submitted,
d
CORPORATI1 ,
Mt~ ·~~
hn Audinis
Project Manager
-J-~ L- G . -r ~---
Fred W. Tahse
Project Director
Enclosure: Figure 1- Phase 1 Proposed Monitoring Well Location Map Well Construction Details -wells MW-1, MW-2, and MW-2A
SIX:0827-L12
\~~ 24,26
> ~ ••
"' ...
·.··. .. .. .··+. ·., __
LEGEND
MP-4$ PROPOSED WELL LOCATION
MW-1 S EXISTING MONITORING WELL
SCALE
r ___,
0 600 1200 FEET
REFERENCE:
BASE MAP- CITY OF· LONG BEACH, DEPARTMENT
OF ENGINEERING, 1978 THROUGH 1982.
Do Not Scale Th1s Draw1ng
, .
. ···
FIGU~E I
PHASE I
·- ~
PROPOSED MONI fOR1NG w;;_1_.:_
LOCATJOrJ rv1t-.P
MARKET· PLACE LANDF i !...L
PREPARED FOR
Bl X BY RANCH COMPANY
LONG BEACH 1 CALl FORNIA
+
rn ... Creating a Safer Tomorrow
(\
\
STATE OF CALIFORNIA
. CALIFORNIA REGIONAL WATER QUALITY CONTROL BOARD
LOS ANGELES REGION
107 SOUTH BROADWAY, SUITE 4027
LOS ANGELES, CALIFORNIA 90012-4596
(213) 620-4460
November 21, 1988
Ms. Judi McCaslin,
Construction Manager
Bixby Ranch Company
911 Studebaker Road
Long Beach, California
MARKET PLACE LANDFILL-CITY DUMP & SALVAGE #2 (FILE NO. 88.:...50) · Staff has reviewed IT's November 8, 1988 letter regarding monitoring wells MW-1 and MW-2A, which were accidentally buried by soil during regrading of the site. MW-2A was installed within refuse, and both wells were internally sealed, capped, locked and covered before they were buried, it will probably not be necessary that these wells be excavated prior to replacement. You will need concurrence from the County of Los Angeles, Department of Health Services.
Replacement well MW-1(R) is approved as proposed.
A replacement well for MW-2A was not proposed, and it is not clear whether MW-2 remains operable. Please clarify the situation regarding MW-2 in writing by December 1, 1988.
'";• ~~. ! ...... •. I• .. ~' .•.
· sta.ff finds it acceptable to include the study of the Newport Inglewood Fault Zone within the final SWAT Report.
:······ .. Should you have any questions or comments, you may contact Merc~des A. Murillo at (213) 620-5444 •.
RAYMOND K. DELACOURT
Senior Water Resource
Contr~l Engineer
cc: Mr. Jim Parsons, DWQ, SWRCB
~r. Fred w. Tahse, IT Corporation
Mr. Chuck Coffee, County of Los Angeles, Department 6f Health Services
rn
INTERNATIONAL
TECHNOLOGY
CORPORATION
December 7, 1988
Project No. 240827-02
Ms. Mercedes A. Murillo
California Regional Water Quality
Control Board, Los Angeles Region
107 South Broadway, Room 4027
Los Angeles, California 90012-4596
Dear Ms. Murillo:
SOIL DISPOSAL
Bixby Ranch Company Landfills
Long Beach, California
As per our conversation on December 5, 1988, IT Corporation (IT), requests that the Regional Water Quality Control Board, Los Angeles Region, issue a variance, if necessary, to allow the disposal of approximately four drums of soil at the Studebaker-Loynes Landfill, containing volatile organic com- \ pounds. Action levels for disposal of these substances have not been formally ) established. Out of 27 soi.l samples analyzed from the three Bixby Ranch Company Landfills (Market Place, Bixby Village, and Studebaker-Loynes}, only four samples contained concentrations of volatile organic substances above the laboratory detection levels.
None of the 27 soil samples exceeded their soluble or total threshold limit concentration (STLC and TTLC, respectively) values for the various substances listed in Title 22 of the California Code of Regulations. The remainder of the original 35 drums of soil (approximately 31 drums) will be disposed of at the Studebaker-Loynes Landfill, since they are not considered hazardous as per Title 22. Table 1 lists the volatile substances which were detected above the laboratory•s detection levels. A more detailed summary of the laboratory results will be included in the SWAT Report for each site.
Regional Office
17461 Derian Avenue • Suite 190 • Irvine. California 92714. 714-261-6441 IT Corporation is cr wholly owned subsidiary of lnternatJonal Technology Corporation (\
\
Ms. Mercedes 7. Murillo
December 5, 1988
INTERNATIONAL TECHNOLOGY CORPORNION
If you have any questions concerning this letter please call the undersigned at (714) 261-6441.
Sincerely,
l.
IT CORPORATION
~
Audinis
7~~
F~f' Fred W. Tahse
Project Director
JA/FWT:rg
Enclosures: Table 1 - Summary of Soil Analyses
Laboratory Certificates of Analysis
SIX:0827-Ll4
----'\, ·.
'-.____/
TABLE 1
SUMMARY Of SOIL ANALYSES
BIXBY RANCH COMPANY LANDFILLS
PROJECT NO. 240827-02
DICHLORODIFLUORO- VINYL
BORING & DEPTH METHANE
SAMPLE NO. (feet) (}Jg/kg)
BV-4-1 3.5 ND<5
BV-5-2 10 25
SL-4a-1 10 ND<5
SL-4a-2 15 ND<5
(11/kg) -micrograms per kilogram.
BV - Bixby Village Landfill.
SL - Studebaker-Loynes Landfill.
CHLORIDE BENZENE
(llg/kg) (lJg/kg)
ND<5 34
25 ND<5
ND<5 ND<5
.N0<5 150
ETHYL-
BENZENE
(lJg/kg)
100
ND<5
8.1 6,800
NO - the analyte was not detected at or above the stated detection limit.
SIX: 0827 -Ll4:rl
/
XYLENES TOLUENE
(lJg/kg) (lJg/kg)
130 ND<20
ND<5 ND<5
65 8.0
17,000 370
APPENDIX I
AIR-QUALITY SOLID WASTE ASSESSMENT TEST WORK PLAN
SCS ENGINEERS
AIR QUALITY SOLID WASTE
ASSESSMENT TEST PROPOSAL:
BIXBY RANCH COMPANY PROPERTIES
(CITY DUMP AND SALVAGE
SITE NOS. 1 THROUGH 4)
LONG BEACH, CALIFORNIA
Prepared for:
Bixby Ranch Company
911 Studebaker Road
Long Beach, California 90815
Prepared by:
SCS Engineers.
3711 Long Beach Boulevard
Ninth Floor
Long Beach, California 90807~3315
(213) 426-9544
August 1988
File No. 0187099.32
S C S E N G I N E E R s'
Section
l
2 3
4 5
CONTENTS
Introduction ..•.......•.•.•••.. ................... .1 Task
Task
Task
Task
l.
2. 3.
4. Meteorological Survey •.•....
Gas Stream Characterization •.
Ambient Air Monitoring .•.
Gas Migration Testing •••...•••.
Site Descriptions. ..................
Background. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 4
• 4
••• 4
.4
• 6
. . . . . . • 6
Air Quality Solid Waste Assessment Program. . . . . . . . . .12 Meteorological Survey •••••••
Gas Stream Characterization.
Ambient Air Monitoring ••••
Gas Migration Testing •••
. . . . ••.•.•• 12
. ..... 15
• 25"
• . 34
Quality Assurance Program. . . . . . . . . . . . . . . . . . . . . . . .41 Quality Assurance Objectives ••
Sampling Methods •••.•.•••••
Analysis Methods ••.•••••.•••
Preventative Maintenance •.••
Data Validation, Precision, Accuracy, and42
Completeness . .........••.....•..•.....
Quality Assurance Reports •••••••••••••••••••
.Air SWAT Report ••.•••••••••••••••••••••••••••
. •• 41
.41
•• 42
• • 42
. . . . . . .
.43
.43
.44
SCS ENGINEERS
Appendices
A Proposed Air SWAT Facilities, Loynes-Bixby Village
Property, Long Beach, California
B Proposed Air SWAT Test Facilities, Bixby Market
Place, Long Beach, California
C Proposed Air SWAT Test Facilities, Studebaker and
Cerritos Channel Dump, Long Beach, California
D Meteorological Data
E SCS Engineers Analytical Laboratory Qualifications
and Procedures for Determination of Parameters
Required Under Health and Safety Code Section 41805.5
(Calderon Program}
F Results of Subsurface LFG Migrtion Monitoring at
Loynes-Bixby Village and Bixby Market Place Sites
SCS ENGINEERS
TABLES
Number
1 Summary of Overall Air SWAT Work Plan .•.............. 3 2 Specified Air Contaminants .....•..•........•........ 18
SCS ENGINEERS
FIGURES
Number
l Site Location Map .................................... 7 2 Wind Rose: Loynes-Bixby Village ........ ~ ..... _ ...... 13 3 Wind Rose: Bixby Market Place .........•..•...•..... l4 4 Construction Details for LFG Vent Well, Bixby
Market P 1 ace •••..•.•••.••.••.•••.••••••••••••.••.•. _16 5 Construction Details- Driver Probe ••••••.••.•..•.•. l7 6 Integrated Surface Sampler and Grid Pattern ......•.. 22 7 Ambient Air Sampling Device ......••..•.•...••....•.. 29 8 Field Data Sheet ..•.•.•.......•....•... ; ..••........ 35 9 Construction Details for LFG Migration Test Wells,
Loynes-Bixby Village and Bixby Market Place ••••••.. 36
SCS ENGINEERS -
SECTION l
INTRODUCTION
This document presents the Bixby Ranch Company's proposed overall work plan to perform Air Quality Solid Waste Assessment Tests (Air SWATs) at the following former landfill sites:
• City Dump and Salvage Nos. 1 and 3 (Loynes-Bixby Village site) .
• City Dump and Salvage No. 2 (Bixby Market Place site). • City Dump and Salvage No. 4 (Studebaker and Cerritos
Channel Dump).
Each of the former landfill sites is located in Long Beach, California. The work is to be performe·d in accordance with requirements of th~ Calderon Bill (California H~alth and Safety Code Section 41805.5). The Calderon Bill requires that all owners of inactive solid waste disposal sites conduct subsurface landfill gas (LFG) and ambient air tests and report th~ results to the Local Air Pollution Control District by·January 1, 1988.
This comprehensive work plan is submitted for review and approval by the Air Pollution Control Officer (APCO) of the South Coast Air Quality Management District (AQMD). It has been pre pared to satisfy the intent of the Testing Guidelines for Active Solid Waste Disposal Sites adopted by the California Air Re~ources Board (ARB) in February 19ff7 ..
1 SCS ENGINEERS
Each of the Bixby properties is an inactive landfill site, according to the ARB guidelines. Separate screening question naires have been submitted to the AQMD which contain information on the history of refuse filling, adjacent land uses, and prev ious environmental monitoring conducted at the sites. Based on a review of these questionnaires, the AQMD has required that the Air SWAT report for each site must contain:
• Test results to determine if there is any underground LFG migration beyond the solid waste disposal site's peri
meter.
• Analyses for specified air contaminants in the ambient air adjacent to the solid waste disposal site to deter mine the effect o~ the site on air quality.
• ~hemical characterization test results to determine the composition of gas streams immediately above and within \ ; the solid waste disposal site. (At the Market Place site, the gas stream characterization above the site will be restricted to unpaved areas only.)
A four-task Air SWAT work plan has been developed in accor dance with the intent of the above requirements. Note that a limited work plan is proposed, which reflects the following:
• The respective sites' surroundings, age, extent of
deposited refuse, and surface improvements.
• Discussions with the AQMD during which tentative agree ment was reached to allow limited testing at the various sites.
A summary of the overall work plan for the three sites appears in Table 1. Details of this work plan are outlined below.
2 SCS ENGINEERS
TABLE 1. SUMMARY OF OVERALL AIR SWAT WORK PLAN:
BIXBY RANCH COMPANY PROPERTIES
LOYNES-BIXBY VILLAGE SITE
Gas Stream Characterization
• One internal gas sample
• One integrated surface sample
Ambient Air Monitoring
• Three days of sampling upwind and downwind
Gas Migration Testing
• Test existing migration probes
BIXBY MARKET PLACE SITE
Gas Stream Characterization
• One internal gas sample
• Surface scan over unpaved areas using an OVA
", )
Ambient Air Monitoring
• Three days of sampling upwind and downwind
Gas Migration Testing
·~ Test existing migration probes
STUDEBAKER/CERRITOS CHANNEL DUMP
Gas Stream Characterization
• One internal gas sample
• One integrated surface sample
Gas Migration Testing
• Install and test migration probes
3 )
SCS ENGINEERS
TASK l. METEOROLOGICAL SURVEY
Information on local wind flow patterns and wind speeds has been obtained and incorporated into this document.
TASK 2. GAS STREAM CHARACTERIZATION
One interior LFG sample will be obtained at each site. The samples will be obtained from an existing vent well at the Market Place site and from gas probes to be installed at the Loynes Bixby Village and Studebaker/Cerritos Channel sites. The samples ,, will be analyzed for the 10 contaminants specified in the ARB guidelines, as well as the major gas components of LFG.
One integrated surface sample will be obtained over a
50,000-sq-ft grid of the landfill surface at the both the Loynes Bixby Village and Studebaker/Cerritos Channel sites. The samples will be analyzed for total organics (as methane) and the speci fied air contaminants. In addition, a sur~ace scan over unpaved areas of the Market Place site will be performed, using an organic vapor analyzer (OVA). Field readings of total hydrocar bons (as methane) will be recorded on a site map.
TASK 3. AMBIENT AIR MONITORING
Ambient air samples will be taken at monitoring points both upwind and downwind of the Loynes-Bixby Village and Market Place sites and will be analyzed for the 10 specified air contaminants.
TASK 4. GAS MIGRATION TESTING
Monitoring for subsurface methane migration will be con ducted at existing LFG monitoring probes located in soils around the landfill perimeters at the Bixby-Loynes and Market Place 4 \ \ j
SCS ENGINEERS
sites. Test probes will be installed and similarly monitored at the Studebaker/Cerritos Channel site.
All sampling and analytical work associated with the above tasks will be performed in accordance with quality assurance previsions outlined in the guidelines. Results of the test pro gram will be presented in an Air SWAT Report to be submitted to the APCO.
Note that SCS Engineers is continuously striving ·to improve its Air SWAT capabilities in response to innovations in the field of LFG and air taxies sampling and analysis. For instance, newer and improved equipment is routinely acquired or fabricated according to the needs of each project. SCS makes every effort to follow the spirit and the letter of the ARB guidelines d.uring the planning and implementation stages of each Air SWAT pro gram. At the same time, SCS also applies an "identical or better" philosophy in order to provide the most up-to-date and technically correct approach to project execution.
5 \
./
SCS ENGINEERS
SECTION 2
SITE DESCRIPTIONS
BACKGROUND
The locations of the three former landfill sites are shown in Figure 1. Descriptions of past and current site uses are out lined below.
Loynes-Bixby Village Site
I
The Loynes-Bixby Village site is located at 6363 East
Pacific Coast Highway in Long Beach. The property occupies approximately 100 acres, the major portion of which was once utilized for landfill operations. Los Angeles County Department of Public Works (DPW) records indic~te that portions of this property overlie the northern part of the former City Dump and Salvage Nos. 1 and 3 sites. Records are unclear as to the dis tinction between these two former landfills.
According to DPW files, landfill operations occurred from 1949 until 1956. riuring that time, approximat~ly 900,000 cu yd of waste materials were landfilled on the Bixby property. Refuse materials deposited consist primarily of residential and commer cial wastes; reportedly, no liquid or hazardous materials were deposited. Refuse depths vary to a maximum of 33 ft.
The major portion of the property is now developed as a municipal golf course (primarily over the former landfill area). Other current site uses include single- and m.ultifamily 6 . .
..
=={= .. " 0 -~=--
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y = 8=~ ·--~=~:!. -~ ~
. ,..,.... ~===.-=
;: ..
· SA.N7'0S OR
.:=;:::.=--= = =..:::...
·-- ~ , ...... ~ ---=== . = ":t'
01:1-~~-=-'::"'"""- ··=-=== iH:h't _ __,. == ST • ~
. . . .. ... - _--.-....:......=. _,.
8,_
~: 'd' ~~--· ~mG
• =~~~~-=·=·=-=:
•..
.c::::\·· I
-\.r;. ..•..
DUMP AND
1 AND NO •
FORMER CITY DUMP AND
SALVAGE NO. 4
WeSTMINSTeR
Figure l. Site Location Map.
7 ~:~ = Ros
, .. ·
AVE:
, .
;''
/.
SCS ENGINEERS
residences in the northwest and northeast portions of the prop erty (these residences lie outside of the former landfill limits). Surrounding land uses also include single- and multi family residential dwellings located due east, west, and south.
Areas south of the property were also once utilized for landfill ing as part of the City Dump and Salvage sites.
In the late 1970's, various forms of subsurface LFG migra tion control were employed at the site. An air injection system was installed in natural soils around the northwest perimeter of the golf course, between adjacent homes and buried refuse mate rials. Fresh air is distributed to a network of 20 injection wells via a blower located west of Bixby Village Drive. The injected air serves to: (l) create a pressure barrier to prevent LFG migration from the former landfill; and (2) dilute methane which may diffuse through the pressure zone.
An impermeable membrane liner was installed under the foun dation slab of the golf course clubhouse. (The clubhouse was constructed atop landfilled wastes.) In addition, a passive LFG vent trench was installed in soils surrounding the northeast por ticn of the golf course between adjacent residences and the former landfill. The trench system includes a network of 27 passive vent pipes.
Routine operation and maintenance of the various subsurface LFG control systems at the Loynes-Bixby property is performed by SCS Field Services (of Carson, California), under contract to the Bixby Ranch Corporation.
A series.of subsurface LFG monitoring wells was installed between the former landfill and adjacent residences to monitor the effectiveness ~f the LFG controls. Monitoring is performed on a quarterly basis by SCS Field Services; results are reported to the City of Long Beach.
8 SCS ENGINEERS
A site plan showing the Loynes-Bixby Village property line, the limits of deposited refuse, and the LFG migration control and monitoring system layouts is presented in Appendix A.
Bixby Market Place Site
The Bixby Market Place is located at 6501 East Pacific Coast Highway in Long Beach. The Los Angeles County Tax Assessor's parcel numbers for the market place site on which the landfill is located are: 7237-020, 025, 026, 031,. 032, 033, 034, 035, and 036. About 5 acres within these parcels were once used as a landfill. DPW records identify the former landfill area as the City Dump and Salvage No. 2 site.
According to DPW files, approximately 200,000 cu yd of waste materials were landfilled at the site during 1960 and 1961.
Deposited refuse materials consist of residential, commercial, and demolition wastes. Reportedly, no liquid or hazardous materials were deposited. Refuse depths vary to 42 ft.
The parcels above have been developed as part of a commer cial plaza and consist of office buildings and a movie theater.
Approximately half of the former landfill surface has been paved over for use as a parking lot; the footprint area of Office Building No. 6 overlies buried refuse. Future land use of the undeveloped portion of the property has not yet been determined.
The property is bounded to the east by the San Gabriel River and to the northeast by an active oil field. Adjacent areas within the Market Place Plaza include retail and restaurant buildings. A hotel complex occupies the land west. of the property (across Pacific Coast Highway).
9 SCS ENGINEERS
Subsurface LPG control systems .were installed at the Market Place during site development. A passive trench/vent system was installed in soils outside the northern and western landfill perimeter, adjacent to the movie theater and Office Building Nos. 1 and 2. Included in the trench are a network.of eight passive vent pipes. Another seven passive vent wells were also installed in the landfilled wastes; they now extend to the atmosphere through planter boxes in the site parking lot.
Office Building No. 6 is protected from subsurface LPG by an active subfloor air ventilation sy~tem. Fresh air is distributed throughout the building crawlspace area via an air blower and a network of PVC diffuser pipes. Subfloor monitoring probes are used to test the system effectiveness.
As with the Bixby-Loyrtes site, routine operation and mainte nance of the various subsurface LPG control systems at the Market Place is performed by SCS Field Services, under contract to the Bixby Ranch Corporation.
A site plan showing the Bixby Market Place site, including limits of deposited refuse, LFG migration controls, and monitor i~ng system layout is presented in Appendix B.
Studebaker/Cerritos Channel Site
The Studebaker/Cerritos Channel site is located near the intersection of Loynes Drive and Studebaker Road in Long B~ach. ,The property occupies approxim~tely 9 acres, of which 4 acres were used as a landfill. The former landfill occupies a narrow strip ~long the eastern property line (adjacent to Studebaker Road), as well as two smaller, isolated area• adjacent to the Cerritos Channel. DPW records identify the former landfill as the City Dump and Salvage No. 4 site.
10 ~\ r 1
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SCS ENGINEERS
According to DPW records, approximately 160,000 cu yd of waste materials were landfilled during the early 1960's.
Deposited materials consist of residential, commercial, and demolition wastes. Reportedly, no liquid or hazardous wast~s were deposited at this site. The maximum refuse depth is estimated to be 25 ft.
At the present time, the property is used only for oil pro duction (there are active wells and a maintenance shed west and southwest of the former refuse fill). Proposed land uses include plans for construction of· single- and multifamily residences south of the former landfill. Lands north and west of the landfill (in the vicinity of Cerritos Channel) are at present considered to be degraded wetlands. As part of any future property development, the site owner will be required to convert this area into what is termed "restored wetlands." A portion of the northerly area will then be accessible to the public and most · likely fall under the administration of the Parks and Recreation Department.
Surrounding land uses north of the· landfill include single family residences. These homes are separated from the former landfill by the Cerritos Channel. Lands south of the property (across Westminster Avenue) are also used for oil production. 7 Directly east of the Studebaker/Cerritos Channel property is Southern California Edison's Haynes Ste~m Powe~ Plant. _ A site plan showing the Studebaker/Cerritos Channel site and the limits of deposited refuse is presented in Appendix C. 11 SCS ENGINEERS
SECTION 3
AIR QUALITY SOLID WASTE ASSESSMENT PROGRAM
METEOROLOGICAL SURVEY
Meteorological data were collected at two of the three sites by SCS Engineers and were used to determine local wind flow direct~ons and velocities. The data included hourly measurements of wind speed and direction for a 3-day period beginning June 9, 1988, for the Loynes-Bixby Village site data and beginning June 13, 1988, for the Bixby Market Place site. These data are sum marized in the wind roses shown in Figure 2 and Figure 3, respectively. The same data are tabularized in Appendix D~ The data for the two sites indicate the following:
• Loynes-Bixby Village site - Daytime breezes during the recording period were predominantly from the south
southwest at speeds of 4 miles per hour or less. Night time land (drainage) breezeG from the east and ~ast
northeast directions were observed on only one of the
test dates between the hours of 3 a.m. and 9 a.m. The
drainage breezes averaged 1 mile per hour.
• Bixby Market Place site - Daytime breezes during the
recording period were predominantly from the southwest
and south-southwest directions at speeds of approximately 3 to 4 miles per hour. Nighttime breezes from the east
were observed on one of the test dates between the hours of 4 a.m. and 8 a.m. These breezes averaged 1 mile per
hour.
12 N
w
2.00 ~.00
1 19.oo
8.00 18.00 l
a!
WINO SPEED CLASS BOUNDARIES
MPH
NOTES:
DIAGRAM OF THE FREQUENCY OF
OCCURRENCE FOR EACH WINO DIRECTION.
WINO DIRECTION IS THE DIRECTION
F'ROM WHICH THE WINO IS SLOWING.
EXAMPLE - WINO IS SLOWING FROM THE
NORTH .Q 'PERCENT OF THE TIME.
E
WIND ROSE
PERIOD: JUN 1988
-----------------------------scseNGINEERS Figure 2. Wind Rose: Loynes-Bixby Village. 13 N
2.00 5.00 1 ,g.oo
8.00 18.00 I
er
WIND SPEED CLASS BOUNDARIES
MPH
NOTES:
DIAGRAM OF THE F'REOUENCY OF
OCCURRENCE FOR EACH WINO DIRECTION.
WIND DIRECTION IS THE DIRECTION
F'ROM WHICH THE WINO IS BLOWING.
EXAMPLE - WIND IS BLOWING F'ROM THE
NORTH - .D ~RCENT OF' THE TIME .
E
WIND ROSE
PERIOD: JUN 1988
._ __________________________ SCSENGINEERS
Figure 3. Wind Rose: Bixby Market Place.
14 ()
SCS ENGINEERS
GAS STREAM CHARACTERIZATION
Thia portion of the Air SWAT test will involve c6llection and analysis of interior LFG samples and integrated surface sam ples as follows:
• One internal gas sample and one integrated surface sample at the Loynes-Bixby Village site.
• One internal gas sample and one surface scan {over
unpaved areas using an OVA) at the Bixby Market Place
site.
• One integrated surface sample and one internal gas sample at the Studebaker/Cerritos Channel Dump.
A description of both integrated surface and interior .LFG sampling follows.
Internal LFG Sample
One internal LFG sample will be.obtained at each site. The samples will be obtained from an existing LFG vent well {desig nated VP-3) at the Bixby Market Place site and from driven gas probes to be installed at the Loynes-Bixby Village and
Studebaker/Cerritos. Channel sites. Refer to the appropriate site plans {Appendices A through C) for sample locations; vent well and monitoring probe construction details are shown in Figures 4 and 5, respectively.
Following collection, the samples will be analyzed within 72 hours for the following:
• ARB guide~ine "Attachment l" compounds {listed in Table 2), using the "disposal site" detection limits.
r, 15
A.C.
V~RIES - DEPTH TO
MTTOM OF REFUSE
OR GROUND WATER
WHICHEVER OCCURS
FIRST
J;l{
/;
#2
i
8FT-V
;
3 GRAVEL
'
TEMPORARY 6-IN-DIA
SCH. 80 PVC CAP
fr3=ru
~ 6-IN-DIA SCH. 80 PVC
1/4-IN LABCOCK
;-VALVE
PLANTER
THREAD/SLIP PVC
COUPLING SCH. 80
Z SOIL COVER
6-IN-DIA SCH. 80
PVC PIPE
L REFUSE 7
PERFORATIONS ENTIRE
LENGTH BELOW CONCRETE
CAP
,.. .,
24 IN DIA
._ ____________________________ SCSENGINEERS
Figure'4. Construction Details for LFG Vent Well, Bixby Market Place.
16 UJ
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u..~
u..
-.ocr:::
UJ
OI
l-%
V'l
UJ UJ
- V'l
a::::>
~u..
:>UJ
a::
:I:' 1--1 a..
UJO
c V'l
PERFORATION DETAIL
111 SPACING
DRIVE TIP
LABCOCK VALVE
REFUSE MATERIAL
SCH. 80 IRON PIPE
31 PERFORATED
SECTION
........................................ .-.................. _. ........ SCSENGINEERS Figure 5. Construction Details - Driver Probe.
17 SCS ENGINEERS
TABLE 2. SPECIFIED AIR CONTAM!NANTS
Detection
Limits (EEb)
ComEound Air DiSEOSal Site
Chloroethene (Vinyl Chloride) 2 500
Benzene 2 500
1,2-Dibromoethane (Ethylene Dibromide) 0.5 1
1,2-Dichloroethane (Ethylene Dichloride) 0.2 20
Dichloromethane (Methylene Chloride) 1 60
Tetrachloroethene (Perchloroethylene) 0.2 10
Tetrachloromethane (Carbon Tetrachloride) 0.2 5
1,1,1-Trichloroethane (Methyl Chloroform) 0.5 10
\ Trichloroethylene 0.6 10
) ,,
Trichloromethane (Chloroform) 0.8 2
18 ,--\
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SCS ENGINEERS
• Methane, carbon dioxide, nitrogen, and oxygen (percent by volume).
T~st procedures and equipment specifications are· described below. Analytical methods are included in the laboratory quali fications section of this report (Appendix E).
Equipment Description--
• Internal gas sampling pump: Consists of 316 stainless steel and Teflon· tubing and a Brailsford and Company
Model TD-4N brushless DC pump with nonlubricated Viton
diaphragm (maximum no load flow rate of 4.5 liters per
minute [lpm]). The rotameter is made of borosilicate
glass with a flow rate between 0 and 2.0 lpm.
• Tedlar bags: 10-liter volume, contained in a light
sealed cardboard box at all times to prevent photo
chemical reactions from occurring during sampling and
transportation. The inlet valve i~ push-pull type con
structed of aluminum and stainless steel with a Viton
0-ring seal. Bags will be purged with ultrapure helium
gas and evacuated prior to use in the field.
• Field instruments:
- Pressure/vacuum: Magnehelic gauge.
- Methane/oxygen: Gastech Combination Indicat6r Model
GX-3N with a dual range for methane (0 to 100 percent
lower explosive limit, and 0 to 100 percent .by volume), and a range of 0 to 25 percent by volume for oxygen.
- Carbon dioxide: Pyrite Indicator with a range of 0 to 60 percent by volume.
19 \
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SCS ENGINEERS
Sampling Procedures--
Samples from the Loynes-Bixby Village and Studebaker/
Cerritos Channel sites will be taken at sample ports {labcock valves) located at the top of the driven test probes. A similar sample port will be installed in vent well VP-3 at the Market Place site. Use of such valves will preclude air infiltration into the samples. Note that for test purposes, vent well VP-3 will be temporarily capped.
During sampling, a technician will attach the pump inlet to the sample valve and withdraw at least one probe or vent well casing volume, as applicable. The technician will then attach the Tedlar bag to the pump outlet and draw a 10-liter sample, at a flow rate of 1 lpm. The samples will then be transported to the laboratory for analysis via chain-of-custody procedures {refer to Appendix E).
Prior to gas sampling, the test probe and vent well static pressure/vacuum readings will be taken using a field pressure gauge. Following gas sampling, methane, carbon dioxide, and oxy gen gas concentrations will be measu~ed using portable field instruments. The labcock valves will then be closed to prevent gas leakage.
Recordkeeping--
The date, time, atmospheric pressure, and sample location will be recorded during each sampling period.
Integrated Surface Sample
The integrated surface samples for the Loynes-Bixby Village and Studebaker/Cerritos Channel sites will be obtained by drawing 20 SCS ENGINEERS
ambient air from just above the landfill surface through the sam pling apparatus, while walking a prescribed course over a 50,000- sq-ft grid area. The proposed grid locations are shown in the site plans (Appendices A and C).
Following collection, the samples will be transferred to the laboratory via chain-of-custody procedures and analyzed within 72 hours for the compounds specified in Table 2, utilizing the "air" detection limits. The samples will also be tested in the labora tory for total hydrocarbons as methane.
At the Bixby Market Place site, a surface scan over unpaved areas of the site will be performed using a flame ionization detector (FID). Field readings of total hydrocarbons (as methane) will be recorded on a site map while walking a pre scribed course (refer to Appendix B for the course location).
Measurable concentrations of the compounds listed in ~able 2 are not expected to be found over paved areas. Primarily for this reason, the AQMD_has tentatively approved a surface scan at this site in lieu of integrated surface sampling.
Test procedures, equipment specifications, sample condi tions, and field quality assurance provisions are described below. Analytical methods are included in Appendix E.
During the sampling period, wind speed and·direction will be continuously recorded to verify that the meteorological condi tions set forth in the guideline$ are met.
Equipment Description--
The integrated surface sampling apparatus consists of a portable pump with internal power source, flow meter, stainless steel collection probe, and 10-liter Tedlar bag enclosed in a light-sealed cardboard box (refer to Figure 6}. The colleqtion 21 \ /
INLET
PROBE
500 FT
BRAILSFORD TD-4AS
PUMP WITH FLOW METER 10 LITER TEOLAR BAG IN
CARDBOARD ENCLOSURE
INTEGRATED SURFACE SAMPLER
........... -100 FT-- ..... ~
-.zs FT..,.
GRID PATTERN
._ ___________________________ SCSEHGINIIIII
Figure 6. Integrated Surface Sampler and Grid Pattern.
22 \
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SCS ENGINEERS
funnel and inlet tubing are constructed of 316 stainless steel and Teflon tubing, respectively. Specifications for the sampling and meteorological equipment are as follows:
• Pump: Brailsford and Company Model TD-4AS brushless DC pump with nonlubricated Viton diaphragm ~nd a maximum no load flow rate of 4.5 lpm. The rotameter is made of
borosilicate glass with a flow rate between 0 and 2.0
lpm.
• Tedlar bags: 10-liter volume, as specified above for the internal LPG samples.
• · Wind instrumentation: Climatronics Corporation Utility Wind System (continuously recording) with fully rota
tional vane and three-cup anemometer assembly. Ranges 0 to 25 and 0 to 50 miles per hour with minimum threshold of 0.75 miles per hour; strip chart recorder speed of 1 inch per hour.
For the surface scan at the Market Place site, the FID
utilized will be a Century Organic Vapor Analyzer (OVA) Model 108 w1th a lower detection limit of 1 part per million by volume (ppm). The OVA has a range of 0 to 10,000 ppm.
Sampling Conditions--
For both integrated surface sanpling and the s~rface scan, the wind recording system will be installed at a location which is representative of wind conditions for each grid area. The wind vane and anemometer will be positioned a minimum of 9 ft above grade in a location removed from any obstructions such as buildings or shrubbery. The wind vane will be oriented toward true north. The proposed wind sensor locations are shown in the site plans (Appendices A through C).
23 /
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SCS ENGINEERS
Wind velocity and direction will be continuously .recorded; acceptable sampling conditions will be as follows:
• Average wind speed (as determined on 10-minute intervals) will be less than 5 miles per hour. Sampling will be
terminated if the average wind speed exceeds 5 ,miles per hour or the instantaneous wind speed exceeds 10 miles per hour.
• Sampling will be conducted only when the site is dry, (i.e., no rain has fallen during the 72-hour period
preceding test activities).
Sampling Procedures--
During integrated surface sampling, a technician will walk the site grids through the courses shown in Appendices A and c over a continuous 25-minute period. During this time, the sample inlet probe will be held no ~ore than 3 inches from the landfill surface. An 8- to 10-liter sample will be obtained over the grid course, with the sample flow rate set at approximately 0.3 lpm.
During the surface scan at the Bixby Market Place site, a technician will walk the course shown in Appendix B at a pace similar to that detailed above for integrated surface sampling.
The inlet probe for the FID will be held no more than 3 inches above the site surface. The locations of all total hydrocarbon readings (as methane) which are above ambient levels will be recorded.on a site plan. Prior to test activities, the FID instrument will be calibrated according to the manufacturer's specifications .
24 SCS ENGINEERS
Recordkeeping--
The following will be recorded during the sampling periods:
• Date, time, and sample location.
• Starting and ending pump flow rates and calibration data. • Prevailing wind direction and maximum wind speed.
• Atmospheric pressure.
• Ambient FID readings (surface scan only).
AMBIENT AIR MONITORING
Results of the meteorological survey indicate that the
Loynes-Bixby Village and the Bixby Market Place sites experience different daytime and nighttime wind flow patterns. As such, SCS proposes that ambient air sampling at these sites conform to Option 2 of the ARB guidelines. Per discussions with AQMD per~ sonnel, ambient air monitoring at the Studebaker/Cerritos Channel site will not be required at this time. The need for future ambient air tests at the site will be determined by the AQMD based on results of the integrated surface sampling (see above).
In accordance with Option .2 of the guidelines, one 24-hour ambient air sampling station and one less-than-24-hour ambient air sampling station will be placed both upwind and downwind of both the Loynes-Bixby Village and Market Place sites, according to applicable daytime (prevailing) or drainage wind flows. An internal clock in the samplers will be programmed such that the les~-than-24-hour samples will be obtained during diainage condi tions only. The proposed sample station locations are shown in the site plans (Appendices A and B).
It should be noted that all ambient air sampling locations . were chosen with the assistance of Mr. Earl Roberts, former AQMD meteorologist, who was instrumental in the development of many of 25 SCS ENGINEERS
the Air SWAT procedures. The sample locations shown in Appen dices A and B reflect Mr. Roberts' familiarity with .wind patterns in the Long Beach area, as well as the following:
• The wind data obtained during the meteorological surveys (refer to Figures 2 and 3 and Appendix D).
• Past data for the project vicinity which indicate that drainage winds can typically be expected from the north east to east directions.
The reader should be aware that the Market Place site has a sizeable parking lot area; ambient air sampling locations have thus been chosen so as not to conflict with this site use.
However, on-site traffic (and/or that from the adjacent Pacific Coast Highway) may present random interferences to ambient air sampling. Similar interferences may also result due to emissions from oil production facilities on adjacent properties. At the Loynes-Bixby Vil~age site, the limits of the former landfill extend beyond the southern property line. Emissions from por tion~ of the former landfill upwind of the Bixby property could cause interferences with the samples obtained at the upwind (~revailing) sample location.
The ambient air samples will be analyzed in the laboratory for the contaminants shown in Table 2, with lower detection limits as listed in the "air" column. If vinyl chloride is detected in the LFG interior well sample at either of 'the sites (see Gas Stream Characterization above), all ambient samples (specific to that site only) will be analyzed solely for vinyl chloride.
26 \
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SCS ENGINEERS
Note that prior-to actual sampling, a 1-day meteorological survey will be performed at each site to verify that wind flow patterns during the test period are consistent with earlier observations. If necessary, sample station locations will be adjusted accordingly.
During the period in which the ambient air samples are col lected, wind speed and direction will.be continuously monitored and recorded at both sites to verify that the meteorological criteria set forth in the guidelines are met.
Ambient air sampling equipment, conditions, and procedures, and field QA/QC provisions are discussed below. Laboratory pro cedures are contained in Appendix E.
Equipment Description
• Ambient Air Sampling Station:
- Pump: Brailsford and Company Model TD-2N b~ushless DC pump with diaphragm made of nonlubricated Viton. The
maximum no load pump flow rate is 4.5 liters per
minute.
- Power: 12-volt DC marine battery.
- Rotameter: SKC West Model 320-5-245 (low flow) made of borosilicate glass with dual flbw range of 0 to 49 and
25 to 245 standard cc per minute.
Fittings, tubing, connectors, and air flow control
orifice: 316 stainless steel or Teflon.
- Bypass valve: Whitey Model IRS4.
27 )
SCS ENGINEERS
- Clock timer: Chrontrol Model CD-25 DC.
- Tedlar bags: 10-liter volume with push-pull valve con structed of aluminum and stainless steel with a Viton
0-ring seal.
• Wind instrumentation: Climatronics Corporation Utility Wind System.
A schematic diagram of the ambient air sampler is shown in Figure 7.
Sampling Conditions
Ambient air sampling will be independently conducted at each site over 3 successive days which are characterized by the following meteorological conditions:
• Stable nighttime conditions with average wind speeds of 5 miles per hour or less.
• Daytime conditions with average wind speeds of 10 miles per hour or less.
No sampling will be conducted under the following adverse meteorological conditions:
• During periods of precipitation.
• When 24-hour average wind speeds are greater than 10
miles. per hour.
28 ('
\ )
TEDLAR BAG IN
A CARDBOARD BOX
INLET
Clllallr
I 1 ... ••••
'' l•
1 2 3
011 ~ .... 41'•
4 5 8 1a.• .,.....
7 8 Q .... ~-... •• 10 ~ .... ~oea
PROGRAMMABLE CLOCK
12 V. DC
DEEP CYCLE
MARINE BATTERY
NLET
1.-----------------------------scsENQINIIM Figure 7. Ambient Air Sampling Device. 29 SCS ENGINEERS
Sampling Procedures
One separate ambient air sample will be obtained from each monitoring station over 3 consecutive days (for a total of 12 samples at each of the two sites). In addition, one duplicate sample, one trip blank, and one field blank sample will be obtained at both of the sites.
At both sites, the four ambient air stations will be pro grammed to sample as follows:
• The 24-hour samplers will operate continuously for the specified time period. To allow for a 10-liter sample,
the pump flow rates will be set at 6 cc/min.
•
-·
• The less-than-24-hour samplers wil~ operate when the wind direction during drainage conditions is across the dis posal site to the less-than-24-hour downwind sampler.
According to the data u~ed to prepare the wind roses,
drainage breezes generally occurred from 4 a.m. to 8 a~m. at the two sites. As such, the less-than-24-hour sam
plers will be programmed to simultaneously start at 4
a.m. and stop at 8 a.m. To allow for a 10-liter sample
volume, the pump flow rates will be set at 40 cc/min.
Specific procedures for setting up and collecting the
ambient samples are outlined below.
Sample Startup--
• Turn on the sampling pump by programming the timer can t rol to "ON" (manual mode) .
• Connect a bubble flow meter to the sampling system outlet orifice where the Tedlar bag would normally be attached. 30 .
SCS ENGINEERS
• Using the bypass valve, set the sampling system for the desired flow rate, as indicated qualitatively by the
rotameter reading. Allow the flow to stabilize for 1 or 2 minutes.
• Measure the flow rate, allowing at least 20 seconds for a measurement.
• Using the bypass valve and flow restriction valve, adjust the sampling system flow rate either higher or lower as required to attain the desired flow rate (within ±0.5 cc per minute).
• Repeat above steps as many cimes as required to attain a flow rate within ±0.5 cc per minute. Once this flow rate is attained, make two more flow measurements. If these
three consecutive measurements agree to within ±5 per
cent, the calibration is complete. If the measurements
do not agree, make the necessary adjustment and again
take three consecutive bubble flow meter measurements.
~ Record the rotameter reading.
• Attach the Tedlar bag inlet to the sampler outlet. Check that the bag valve is in the open posi~ion (valve stern pushed in and lock screw tightened).
• Observe the flow measurement on the rotameter. If a
significant reduction in flow is observed, adjust the
rotameter to the previous flow reading.
• Position clock timer to start and stop the pump at appro priate time intervals.
31 '
\
SCS ENGINEERS
• Record bag number, date, and time that sampling was
initiated and secure the lockbox doors~
Sample Collection--
• Disconnect the Tedlar bag.
• Attach the bubble flow meter to the sampling system out let, turn pump on, and measure the flow rate three times. • Initiate chain-of-custody procedure for sample transport and delivery to the laboratory. Each sample must be
analyzed within 72 hours.
Acceptance Testing--
The following service checks will be performed during field sampling:
• Flow meter: The flow meters will be kept at a constant flow rate during the sampling peridd.
• Leak check: Each sampling station will be checked daily for loose fittings and leaks in the sampling system.
• Power supply: Battery voltages will be tested daily.
Duplicate Sampling--
Ambient field sampling precision will be ensured by collect ing an additional ambient air sample through a "duplicate" sam pling station (i.e., a single enclosure which contains two independently controlled samplers). The duplicate sample inlets will be located a minimum of 6 ft apart. Generally, at least 10 percent of all samples collected should include a duplicate; therefore, one duplicate sample is proposed for each site being tested. One sampler will be designated as the primary sampler, 32 )
SCS ENGINEERS
and the other will be designated as the duplicate. The duplicate sample will be obtained at the point of maximum expected concen trations (i.e., the'downwind less-than-24-hour sampler location).
Field and Trip Blanks--
Field blanks--One field blank will be prepared at both the Bixby-Loynes and Market Place sites by introducing laboratory grade helium gas through one of the air sample pumps (the sample station location will be chosen in the field). The blank samples will be transported to the laboratory as ''blind" samples (i.e., they will not be distinguished from other ambient air samples on the chain-of-custody forms). The purpose of the field blank will be to determine if the sampling equipment contributes to con tamination of t~e samples in any way.
Trip blanks--During each air sampling program, one sample Tedlar bag (containing laboratory grade helium) will be prepared in the laboratory and transported to the field and back without otherwise being disturbed. Note that this trip blank will b~ transported like all other samples (i.e., in a light-sealed card board enclosure). The trip blank will be analyzed as if it were an ambient air sample, but will be designated as a trip blank on ail appropriate field data and chain-of-custody f~rms.
Recordkeeping--
Appropriate records will be kept on all sampling activities and equipment as follows:
• Operation records for the weather station, sample pump, power supply, and programmable timer must be kept with
the sample station at all times.
33 (
- •,
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)
SCS ENGINEERS
• Sampling records containing date, time, flow rate, loca- tion, and comments for sample period start and finish
will be kept with each sample bag, along with chain-of custody information. (A typical field data sheet is
shown in Figure 8.)
• Wind data (speed and direction) will be continuously
recorded and reported as an hourly average. Wind direc tion will be reported using a 16-point scale.
GAS MIGRATION TESTING
The guidelines require that one gas monitoring probe be installed per ~ach 1,000 ft of landfill perimeter; probes are to be placed between areas of refuse deposition and the areas off site where gas migration could potentially be a threai to p~bli~ health or safety.
At the Loynes-Bixby Village site, there are cutrently 19 subsurface gas monitoring wells (designated Wl through Wl9) in the north and east landfill perimeter areas (between the air injection wells/vent trenches and adjacent structures). Refer to Appendix A for monitoring well locations and to Figure 9 for well construction details.
Similarly, at the Market Place site there are a total of 15 subsurface monitoring wells (designated Ml through MlS) located between the vent trenches and adjacent structures. Refer to Appendix B for monitoring well locations and to Figure 9 for well construction details. I~ addition, there are another 29 subfloor monitoring probes in the crawlspace under Building No. 6.
As described in Sec~ion 2 of this report, the LFG migration w~lls/probes at both the Loynes-Bixby and Market Place sites are tested on a routine basis; results are reported quarterly to the 34 scs
•C•A•L•D•E•R•O•N•A•I•R•S•W .. A•T•F•IE•L•D .. D•A•T•A•S•H•E•E•T ............ ~~~~~~!,!s Personne 1:
Job No.:
Sample Location:.--------
Sample Station No.: -------
l~' 1 ~..)(IQ aucn ;,,o
't•tttni=·OOf
.. ~q Sucn ;.l
Sample r.o. No.:------- lOIQI
2'), t21S iSH
Bag No.: ---------- ..._'_.,_·l-'l·_·~-· ;_aol_..
Equipment I. D. No.: --------
Other: --------------
Sample Type: Ambient Air /Integrated Surface Sample /LFG /Migration Program Start: Date: ------
Program Stop: Date: ------
Pump Flow Calibration Tests:
Program
Start
Program
Stop
( 1)
(2)
(3)
( 4)
( 5)
( 1)
(2)
(3)
( 4)
( 5)
Rotameter Reading
Bag Off
·--
, Sample Analysis: Compounds
Attacnment 1
Vinyl Chloride
Methane
Fixed Gases o'tner
Time: -------
Time:
Bubble Flow Meter
Disp. Vol
(cc)
Time Flow
ll!sl (cc/nn)
Detection Limits
Air/LFG
Air/LFG
Air/LFG
Air/LFG
Average Flow
(cc/min
Sample Average
F 1 OW CC/nlll
Battery Check: OK/LOW Leak Check: OK
OBSERVATIONS Program· Start: -------------------
Program Stop:
1...-------------------------------•SCSIHGIHHM Figure 8. Field Data Sheet. 35 'I
)
0 1-
VALVE BOX SET 1 IN
ABOVE GRADE
FINISHED GRADE
CAP ENDS·
MONITORING PROBE - 1/2-IN
DIA SCH. 40 PVC PIPE;
BOTTOM 1 FT PERFORATED
WITH 1/8-IN-DIA HOLES~
WRAP END WITH FIBERGLASS
WOOL ('BULK MEDIA)
PEA GRAVEL
._ _____________________ ...,;, _______ SCSENGINEERS
Figure 9. Construction Details for LPG Migration Test Wells, Loynes-Bixby Village and Bixby Market Place.
36 ,--·
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SCS ENGINEERS
City of Long Beach. Historically, off-site migration of LFG has not been detected at either property. Reports summarizing monitoring results for the year 1988 are shown in Appendix F.
Note that monitoring for combustible gas is ·conducted using a Gastech Combination Indicator (or equivalent) with a lower d~tection limit of about 0.05 percent methane by volume.
It is proposed that no new migration monitoring probes be installed at either the Loynes-Bixby or Market Place sites and that the existing monitoring wells be utilized for gas migration testing as part of the Air SWAT program. It is opr opinion that the alignments of the existing perimeter monitoring systems are adequate to characterize meaningful gas migration patterns at both properties. Justification for this proposal is as follows:
• At the Loynes-Bixby site, no additional monitoring probes are proposed for installation along the southerly prop erty line. Areas south of the property overlie other
portions of the former City Dump and Salvage Nos. 1 and 3 landfills. Monitoring wells installed along the
southerly portion of the Bixby property would thus be in refuse and would not yield useful info~mation about off site subsurface. LFG migration.
• At the Market Place site, no additional monitoring probes are proposed for installation along the southerly or
westerly perim-eters of the landfill. The area to the
south is bounded by the San Gabriel River, which is, in our opinion, an effective barrier .to subsurface LFG ·
migration. Lands west of the site are currently open
space/wetlands and there are no threatened structures in that direction.
37 ( \
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SCS ENGINEERS
At the Studebaker/Cerritos Channel site, it is proposed that two driven probes be installed in soils around the former land fill perimeter. Proposed probe locations are shown in Appendix C; the probes will be constructed similar to those utilized for the gas stream characterization portion of this Air SWAT program (refer to Figure 5 for construction details).
Note that no probes are proposed for the northwestern or eastern perimeter areas of the former landfill for the following reasons:
• The nearest occupied structures to the former landfill are located north and northwest of the property, across the Cerritos Channel. Again, it is felt that this chan nel is an effective barrier to subsurface LFG migration. • Although not well documented, it appears that the li'mits of the former landfill extend beyond the Studebaker/
Cerritos Chahnel site property line into Studebaker Road (there is evidence of landfill settlement in the road
way). Testing outside the eastern perimeter of the
former landfili would thus req~ire ~ccess 6nto other
private and/or public property.
It should be mentioned that there are active oil wells
bordering the western extent of the former Studebaker/Cerritos Channel site landfill. It is not unusual to find evidencie of natural or petrogenic gases in the soils of such oil-producing areas. The reader should thus be aware that there is a potential for interference with the gas migration testing in this area.
The ARB guidelines state that if internal LFG testing is performed as part of the gas stream characterization portiori of the Air SWAT, then the migration testing will be limited to sam pling total organic gases as methane. At each of the three Bixby properties, it is proposed that existing or newly installed 38 r-" ' \ ! \
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SCS ENGINEERS
migration probes be tested for methane, using an FID. Monitoring wells/probes to be tested will include the following (refer also to the appropriate site plans Appendices A through C for monitor ing locations):
• Loynes Bixby site: W3, W9, Wl3, and Wl9. Note that
sampling will be restricted to the shallow probes (5-ft depth) .
• Bixby Market Place site: M4, M6, Mll, and Ml4. Sampling will be performed at the shallow probes only.
• Studebaker/Cerritos Channel site: Sampling will be per formed at the two newly installed test probes.
Equipment specifications and sampling procedures are out lined below.
Equipment Specifications
• Sample pump: As specified above for the internal gas
sample.
• Tedlar bags: 10-liter volume, enclosed in a cardb6ard container.
• FID: As specified above for the integrated surface
sampling.
Sampling Procedures
A noncontaminating pump will be used to draw the sample into a 10-liter Tedlar bag. The contents of the bag will be analyzed in the field for total organics as methane, using an FID. 39 \
SCS ENGINEERS
Specific gas migration test procedures are as follows:
• P!ior to sampling, calibrate flame ionization detector with 1,000 ppm methane in air standard.
• Purge the monitoring well by attaching pump inlet to the sample probe, and withdraw one probe volume of gas.
• Attach pump outlet to 10-liter Tedlar bag.
• Fill sample bag and draw sample from the bag through the FID.
The date, time, probe location, and methane concentration will be recorded for each probe sampled.
40 (~\
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SCS ENGINEERS
SECTION 4
QUALITY ASSURANCE PROGRAM
QUALITY ASSURANCE OBJECTIVES
The objectives of quality assurance provisions are to obtain accurate, precise, and complete data through both field sampling and analytical activities.
SAMPLING METHODS
Specific sampling methods for all field activities are
detailed in Section 3 and include equipment specifications, acceptance testing, sample handling, calibration, and duplicate sampling and recordkeeping provisions. Other general provisions are listed below.
Sample Protection
Field equipment left unattended will be housed in weather tight, locked enclosures to prevent damage due t-o adverse elements.
Chain-of-Custody
Chain-of-cust6dy records ~hall be kept from the time that sample collection is completed until the sample is delivered to 41 (\
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SCS ENGINEERS
the laboratory. Chain-of-custody information will include the following:
• Sample identification number and matrix.
• Date and time of ~ampling.
• Name of samplers.
• Sample flow rate (if applicable).
• Sample condition at time of collection (i.e., bag
volume).
Complete chain-of-custody provisions, including s~mple
forms, are outlined in detail in the laboratory qualifications section of this report (Appendix E).
ANALYSIS METHODS
Laboratory analyses of all samples will be performed by the scs Engineers Analytical Laboratory, a State-certified
facility. Laboratory qualifications, analytical methods, quality control provisions, and validation testing parameters are outlined in Appendix E.
PREVENTATIVE MAINTENANCE
To prevent loss of data, an additional sample pump, as well as spare sample tubing, fasteners, and electrical wire, will be kept in the field.
42 _ _)
SCS ENGINEERS
DATA VALIDATION, PRECISION, ACCURACY, AND COMPLETENESS
Average analytical precision and accuracy, and respective standard deviations will be calculated for the entire data set.
The following equation will be used to calculate data precision:
where:
P = Calculated data precision.
Y = Concentration from duplicate sampler of collocated pair.
X = Concentration from primary sampler of collocated pair.
Data completeness will be calculated as a percentage of valid data compared to the total amount of data possible if no invalidations had occurred. Data will be invalidated if the power is out at a sampling location and the duration of a sample cannot be verified, or if the sampling medium breaks during sampling or shipment for analysis.
QUALITY ASSURANCE REPORTS
Quality assurance activities and data will be summarized by the staff conducting the sampling and included as an attachment to the final data summary.
)
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SCS ENGINEERS
SECTION 5
AIR SWAT REPORT
A report summarizing Air SWAT activities at each of the three Bixby .properties will be submitted to the APCO. The report will include the following:
• General description of the former landfills and their surroundings.
• Description of test procedures and results.
• Maps showing the locations of sampling points and LFG ~ monitoring wells. /
• Results of sampling and analysis.
• Appended material with laboratory and quality assurance/ quality control backup.
44 (,
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APPENDIX A
PROPOSED AIR SWAT TEST FACILITIES,
LOYNES-BIXBY VILLAGE PROPERTY,
LONG BEACH, CALIFORNIA
)
SCS ENGINEERS
APPENDIX B
PROPOSED AIR SWAT TEST FACILITIES,
BIXBY MARKET PLACE,
LONG BEACH, CALIFORNIA
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APPENDIX C
PROPOSED AIR SWAT TEST FACILITIES,
STUDEBAKER AND CERRITOS CHANNEL DUMP,
LONG BEACH, CALIFORNIA
SCS ENGINEERS
APPENDIX D
METEOROLOGICAL DATA
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POUR DAY MET STUDY
Clock Tf•
Dlta: Wfnd Dfrtetia! ( 16 point tcllt)
Stltia!: 8~ tu.F ca.&
Pried: J.N, 1988
Drtt 0 1 2 3 • 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 1 - - - - - - - - - - - - - - - .. - - - -
2 - - - - - - - - - - - - - - - - - - - - - - -'-3 - - - - - - - - - - - - - - ' - - - - - - - - - - - - - - - -
5 - - - - - - - -
6 - - - - - - - - - - - - - -
7 - - - - - - - - - - - - - - - - - - - -
8 - - - - - - - - - - - - - - - -
9 - - - - - - - - - - - - 9 10 11 11 12 12 12 12
10 12 12 12 12 12 12 5 • 5 6 9 9 9 9 9 9 9 9 '10 9 11 9 10 10 11 10 10 10 10 10 10 10 10 9 9 9 9 9 9 9 9 9 9 9 8 6 9 8 8 12 10 10 10 • • • 3 3 3
'
7 8 9 9 9 g 9 9 9 9 9 9 9 9
13 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 - - - - -
('\
'\ )
)
\
j
Oltl
1 2
3 ' 5
6 7
I
9 10
11 12
13 AV
SD
0 1 2
-
- - --
0 0 0
2 2 1
2 1 1
1 1 1
1 1 ,.
0 0 0
3 '
5 6 7 8
- - - - - -- - - - -- - - - -- - - - -- - - - - -- - - -- - -- - - 0 0 0 1 1 . 1
1 2 0 0 1 2
1 1 1 1 1 1
0 0 0 0 0 1
0 1 0 0 1 1
0 0 0 0 0 0
scs ENGINEERS
POUR DAY MET STUDY
IMI: IHnd s.-1 (~)
Statitn: BDIY OClF CllRi
Friad: .AM, 1981
Cla:k Ti•
9 10 11 12 13 1' 15 16 17 18 19 20 21 22 23 *X Itt A~.
- - - - - - - - - - - - - 0 0.00
- - - - - - - - - 0 0.00
- - - - - - - - - 0 0.00
- - - - - - - - - - - - - 0 0.00
- - - - - - - - - - - - - 0 0.1»
- - - - - - - - - - - 0 0.00
- - - - - - - 0 0.00
- - - - - - - - - - - 0 0.00
3 3 2 2 1 1 1 0 3 11 O.Sl
2 2 2 3 3
'
3 3 3 3 2 2 2 2 2
'
1' 1.71
2 1 2 3
'
3 2 2 2 2 1 1 1 1 2
'
13 1.67
1 2 2 2 3 3
' '
2 2 1 1 1 1 1
'
15 1.67
1 2 2 3 3
' ' ,, 0. 79
1 1 2 2 3 3 2 2 2 2 1 1 1 1 1 1.28
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
SCS ENGINEERS
FOUR DAY MET STUDY
~: ltfnd bl
Stitial: 81~ rJJ.1 CC1R3E
Fried: ...... 09, 1988 - ...... 13, 1988
Ibn: 16 - 1C
ltlnd s.d nl Ofrctfm
~ Ofstrftutfal
Wind - (JAf) &a.,
Off'ICtfm 1 o-2 H H t-18 19t 'TOT A\f 9IEED
16 0.0 0.0 0.0 0.0 0.0 0.0 0.00 0.00
0.0 0.0 0.0 0.0 0.0 0.0 0.00 0.00
2 0.0 0.0 0.0 0.0 0.0 0.0 0.00 0.00
3 3.2 0.0 0.0 0.0 0.0 3.0 3.2S 1.00
c 5 •• 0.0 0.0 0.0 0.0 5.0 s.u 1.00
)
5 2.1 0.0 -0.0 0.0 0.0 2.0 2.17 1.00
6 2.1 0.0 .0.0 0.0 0.0 2.0 2.17 1.50
7 1.0" 0.0 0.0 0.0 0.0 1.0 1.01 2.00
8 •. 3 0.0 0.0 0.0 0.0 •• 0 •• 35 1.50
9 3C.O 16.0 0.0 0.0 o.o C7.0 51.01 1.M
10 tc.O 2.1 0.0 0.0 0.0 15.0 16.30 1.53
11 3.2 0.0 0.0 0.0 0.0 3.0 3.2S 2.00
12 10.0 0.0 0.0 0.0 0.0 10.0 10.87 0.30
13 0.0 0.0 0.0 0.0 0.0 0.0 0.00 0.00
1C 0.0 0.0 0.0 0.0 0.0 0.0 0.00 0.00
15 0.0 0.0 0.0 0.0 0.0 0.0 0.00 0.00
I& 0.0 0.0 0.0 0.0 0.0 0.0 0.00 0.00
_ _/
TOT 11.0 18.0 0.0 0.0 0.0 92.0 100.00 o.a
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SCS ENGINEERS
THREE DAY MET STUDY
Clock Tt.
~= ttfnd Oii'ICtiat (16 point ale)
Statiat: Blm liMa PIJCf
Pried: ..ul, 1988
Drtt 0 I 2 3 ' 5 6 7 8 9 10 11 12 13 1• 15 16 17 18 19 20 21 22 23 1 2
3 ' 5
6 7
. 8
9 10
11 12
13 ,.
15 16
-·-
' - - - - - - - - - - - -
~ - - - - - - - - - - -
- - - - - - - - - - - 10 10 10 10 10 9 9 9 10
8 7 6 6 ' ' • • ' 10 10 10 10 10 . 10 10 9 9 9 10 10 8 I I 8 8 9 10 10 10 10 10 10 10 9 10 9 9 9 9 .9 10 9 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 - - - - - - - ~ 0 1 2 3 4 5 5 7 8
1 - - - - - - -
2 - - - - - - -
3 - - - - - - -
• - - - - -
5 - - - - - - - - -
5 - - - - -
7 - - - - - - - - -
8 - - - - -
9 - - - - -
10 - - - - - - -
11 - - -
'\ 12 - - - - - - -
)
13 14 2 2 1 1 2 1 1
15 1 1 2 1 1 1 2
16 2 2 2 2 2 1 1
AV 1 1 1 1 1 1 1 1 1
so 0 0 0 0 0 0 0 0 0
;
SCS ENGINEERS
THREE DAY MET STUDY
Clack Till
9 10
"
12 13 14.15 16 17
- - - - - - -- - - - - - - - -- - - - - - - -- - - - - -- - - - - - - - -- - - - - - - - -- - - - -- - - - - -- - - - - - - - -- - - - - - - - -- - - - - - -s 5 4
3 4 5 5 7 5 5 5 4
1 1 2 • 3 4 4 5 5.
2 3 4 • 5 5
2 2 3 • • • • • 3
0 0 0 0 0 0 0 0 0
18 ---
-
4 4
•
3 0
~: Wind~ (Jitt).
Statf01: 8Wi*MT FUCf
Pried: .AI, 1.
19 20 21 22 23 MX Itt. A~.
0 0.00
- - - - 0 0.00
- - - 0 0.01
- - - 0 0.00
- - - 0 0.00
- - - 0 0.00
- 0 0.11
- - - - - 0 0.01
- - - - 0 o.oo
- - - 0 0.00
- - - - " 0 0.00
- - - - 0 0.00
3 4 3 2 2 5 15 1.33
3 2 1 1 1 7 13 2.83
4 3 3 2 .1 . 5 15 2.38
5 13 !.54
3 2 2 1 1 2.02
0 0 0 0 0
r' \. J scs ENGINEERS
THREE DAY MET STUDY
Dlrtl: IHndbl
Statia'l: 81~-..m PUCE·
Period: JUN 13, 1988 - JUN 16, 1988
Han: IS- 1•
Wind- ft Dirtctia'l
~ DistribJtia'l
Wind~{~)~
Di retia~ I o-2 H H ~18 19+ TOT 'TOT AVE SP£ED
16 0.0 0.0 0.0 ·o.o 0.0 0.0 0.00 0.00
0.0 0.0 0.0 0.0 0.0 0.0 0.00 0.00
2 0.0 0.0 0.0 0.0 0.0 0.0 0.00 0.00
3 0.0 0.0 0.0 0.0 0.0 0.0 0.00 0.00
/..--"'
( ) • 6.9 0.0 0.0 0.0 0.0 5.0 6.M 1.20
5 0.0 0.0 0.0 0.0 0.0 0.0 0.00 0.00
6 2.7 0.0 0.0 0.0 0.0 2.0 2.71 1.00
7 1.3 0.0 0.0 0.0 0.0 1.0 1.31 2.00
I 8.3 0.0 0.0 0.0 0.0 1.0 1.33 1.17
9 •• 1 15.0 0.0 0.0 0.0 IC.O 1U4 3.50
10 30.0 27.0 2.7 0.0 0.0 u.o 61.11 2.91
11 0.0 o.o 0.0 0.0 0.0 0.0 0.01 0.00
12 0.0 0.0 0.0 0.0 0.0 0.0 0.00 0.00
13 0.0 o.o 0.0 0.0 0.0 0.0 . 0.00 0.11
1. 0.0 0.0 o.o 0.0 0.0 0.0 0.00 0.00
15 0.0 o.o 0.0 0.0 0.0 0.0 0.00 0.11
a 0.0 0.0 0.0 0.0 0.0 0.0 0.00 0.11
\
j
TOT s..o 43.0 2.7 0.0 0.0 72.0 100.00 0.74
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SCS ENGINEERS
APPENDIX E
SCS ENGINEERS ANALYTICAL LABORATORY
QUALIFICATIONS AND PROCEDURES
FOR DETERMINATION OF PARAMETERS
REQUIRED UNDER HEALTH AND SAFETY CODE
SECTION 41805.5 (CALDERON PROGRAM)
APPENDIX E
SCS ENGINEERS ANALYTICAL LABORATORY QUALIFICATIONS
AND PROCEDURES FOR DETERMINATION OF PARAMETERS
REQUIRED UNDER HEALTH AND SAFETY CODE
SECTION 41805.5 (CALDERON PROGRAM)
INTRODUCTION
The SCS Engineers Analytical Laboratory is well equipped to perform analyses on water, wastewater, sludges, soils, gases, plants, leachates, and other types of samples. The laboratory specializes in the analyses of samples required in all aspects of pollution control and process residuals monitoring, sampling, characterization, treatment, reuse/recovery, and disposal.
This document describes specific procedures for determina tion of volatile halogenated hydrocarbons and aromatics in land fill gas (LFG) and ambient air and the determination of permanent gases (i.e., the four major components--methane, carbon dioxide, nitrogen, and oxygen). These procedures are based on the ARB Testing Guidelines published pursuant to the Calderon Air SWAT Program.
CHAIN-OF-CUSTODY PROCEDURES
From the moment a sample is collected in the field until the final assessment is complete, custody of the sample must be con trolled .. SCS's procedures assure that a sample with proper docu mentation has not been tampered with or mishandled during collec tion, transfer, storage or analysis.
A sample is considered in custody if one of the following requirements are met:
8/88
• It is in the physical possession of the sampler or labo ratory analyst.
• It is in view of the sampler or laboratory analyst.
• It was in the physical possession of the s~mpler or labo ratory analyst, and it has been stored so that no one can tamper with it.
• The sample is kept in a secured area which is restricted to authorized personnel only.
• The sample is placed in a container and then sealed with a custody seal that is broken when the container is
opened.
Field Chain-of-Custody
Sample custody is initiated at the time of sample
preparation by completing appropriate items on a Tedlar Bag Preparation Checklist (Figure E-1) and initiating a Chain-of Custody form (Figure E-2). When the bags are collected from the laboratory, the bag preparation checklist is completed by the person preparing the Tedlar bags. The custody form is completed and signed by the person collecting the sample. It is the responsibility of the person who collects the sample to ensure that the sample and sample descriptive forms are in custody and ~hat all descriptive information is accurate and complete. Each individual who subsequently signs a f1eld custody form, as shown in Figure E-2, has a similar responsibility until samples are received at the SCS Laboratory.
Laboratory Chain-of-Custody
Custody of samples is transferred to the sample custodian . when tfie samples arrive at the SCS Laboratory~ When transferring possession of samples, the individuals relinquishing (field sam- · plers, couriers, etc.) and those receiving (sample custodian) sign, date and note the time on a field chain-of-custody record.
Whenever samples are split to be shipped elsewhere, another chain-of-custody record is prepared for those samples.
All samples are inspected when they enter the laboratory.
Any breakage or other damage is documented and brought to the attention of the Project and/or Laboratory Director.
Samples are identified by appropriate information attached to the sample container (e.g., field.numbers, sample tags and/or sample labels). Sample information on the field chain-of-custody· form is then verified against the sample container information by laboratory personnel to ensure the accuracy and completeness of all documentation.
The SCS Laboratory is a secured area, with access restricted to SCS employees and escorted guests. Locks on all entrance ways ensure the security of laboratory areas, as well as the security of all samples stored within the laboratory.
The sample custodian places the samples in an assigned stor age area prior to analysis. The assigned area for each batch is clearly identified with project and batch numbers. The actual .location is documented on laboratory chain-of-custody forms and parameter request forms.
8/88
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TEOLAR BAG PREPARATION CHECKLIST scs
-----------------------ENGINEERS
:-. ·:'"""'!"''J ~~:'"-\
CHEMIST, ~ECHNICIAN:
LOCATION:
)111 •.Jf'q 8tK .. ~'•!!
'4•1111' ''f)OI'
• "'q !eiC" ·:A
l0107 ll'l
2' )1 ·~!1·9~··
=u ·Z'' ,,. ~ao~
BAG CONDITION (VISUAL CHECK FOR BAG INTEGRITY AND OTHER DEFECTS):
B.a.G PURG! NG
NUMBER OF PURGINGS (THREE MINIMUM):
TYPE OF GAS USED:
PURITY:
STATUS OF BAG AFTER PREPARATION: 0 FULL 0 EMPT'i
BAG 24-HOUR LEAK TEST (CARS METHOD 202): 0 PASS 0 FAIL
COMMENTS:
1--------------------------------scs!NGIHUM
Figure E-1. Tedlar Bag Preparation Checklist~
AIR SAMPLING CHAIN-OF-CUSTODY FORM scs
ENGINEERS
ti'IWONIWII"E~
]71Tl0ft9~81..-Q
?e!'3;:"!.n~.
Jlilll'lt" Floor
C""lllacnCA
!10107·ll1S
S.tmp~e' 3. :;:"'.a :~::-eo,· Pro)ecc Manaqer 2131 428·9544 F.U t2t]l •27 VIC!
s.~ • :~~:::Tt~:~.:n
.ProJect Sumber PrOJeCt ~OC4tlOn
ProJec: Nam• p .o. N,.mo•r
Sample lnformauon
I
S•mp;.e a•q '
S•mp~ I s•mp!.tr S1 tt O•tt -:'.:rlt S•mp~ t
=~
'
~YP• :o S•~P~ 1nq S•atpltd S••Pltd "'•t: • .x
:..cc•t•::n =~ I A.~ :" ~·II
I
I
Baq C:.nc1n1on ~pen sampl1nq Baq Conc14tlOn ~pen r•cupc 1 empc y ,l. 4, ._. 2. J.: 4, f,.ll.J r l c•mpey, :;<,: 2,J, •• f .. lll r l R•llnq,.uned oy: :late T1m• R•c•lv•d t:ly: Jolt• !~me
Re~1nq,.,snea by: Recu•;ea by:
Rei.~qu'"r.ea oy: Recuv•d cy:
Rel;~C:p.i;.Sr:ed cy: R•c•1v•a oy:
An,illys •s Req,.•sc•d
:.FC· At':C:'\
'
.: • .:.derQn --- f'1XId C•alll I CHol, C02. 02, •z l
:.rc A::.:r: -=• ~.ler.:n plua·: ---
HZ
--- 5::_!'1'/ ::Je~a:ent
---
C•roon ~cnca1dt
--- Xy:.:"IS --
'li.nyL Ch!..;,cJ.cll :~n!.y
---
":':~-·!'1·
--- tot•!. ~etn•n• nydr::u:•roons :-:"~HCI
---
XA __ Toti!. .'4tt!'1•n• •nC ~n·lltt!'!•n• ,ydr:~c•rocns -- ... :.Ct ---
I TMHC i ~!IIIHC l
--
•Jc:~er · :ipec~ !y 1
C~mment:s
~==~
1..-----------------------------SCSEHGINIIJIII
Figure E-2. Air Sampling Chain-of-Custody Form.
I
/
STANDARD SCS ANALYTICAL LABORATORY QUALITY CONTROL PROGRAM The standard SCS quality control program is a laboratory program that is applied to all samples and requires no lead time or additional start-up effort. The program is a continuing in house regimen, with its objectives being to:
• Provide a measure of precision and accuracy of analytical methods.
• Maintain a continuing assessment of the accuracy and pre cision of analyses.
• Identify weak methodologies and provide a continuing
source of research topics aimed at overcoming deficien cies.
• Provide a permanent record of instrument performance for data validation and preventive maintenance.
• Continuously upgrade the overall quality of laboratory performance.
The controls employed in this program are:
• Reagent blanks - to check for laboratory contamination.
Reagent blanks are run prior to the analysis of samples, after every 10 samples, after the last sample is
analyzed, and every time the matrix changes.
• Method standards - to check the accuracy of the method under optimum conditions, excluding any chemical inter ference from sample matrix.
• Duplicate samples - to check laboratory precision. Ten percent of samples are 'duplicated as a standard proce dure. More frequent use of duplicates may be required in some programs.
• Spiked samples - to check the recovery of parameters of interest, including any chemical interference from sample matrix. Ten percent of samples are routinely spiked with known standards.
• . Reference standards - used to check the accuracy of both digestion (extraction) and instrumental analysis.
Standard reference materials are obtained from NBS, EPA and other appropriate sources. When these are not available, inter nal interim reference materials· are utilized.
8/88
(-,: Source of Standard Reagents
Chemical reagents are purchased from major supply houses, e.g., VWR, Supelco, American Scientific, etc. Only the highest purity, spectre grades are utilized for sensitive analyses in volving instruments such as an atomic absorption spectrophoto meter or a gas chromatograph (GC). Incoming reagents, used for extraction and/or cleanup procedures prior to GC analysis, are analyzed by a GC to check for the presence of impurities.
Acceptable Quality Control Limits
The data are treated statistically to obtain precision, accuracy, and.limits of detection for all parameters of interest.
Table E-1 shows data for precision and accuraci, method detection limits, percent relative standard deviation, and correlation co efficients obtained during preparation of five-point calibration curves. The values detailed in Table E-1 represent a limited study of precision and accuracy on Scott-Marrin, Inc., CC62371 Stock Gas Standard. Note that the values in Table E-1 show pre cision for a known gas standard in one laboratory; true accuracy values can only be obtained from an interlaboratory round-robin testing program for Calderon type analysis. The method detection limits shown in Table E-1 are defined as the minimum concentra tion of a substance that can be measured and reported with 99 percent confidence to have a value above zero (none det~cted).
After data on a sufficient number of spiked samples or
duplicates have bee·n analyzed, control charts may be calculated.
Control charts are used to monitor the variations in the preci sion or accuracy of routine analyses and can detect trends in these var.iations. The upper and lower warning limits are estab lished at twice the standard deviation of the recovery value; the upper and lower control limits are established at three times the standard deviation of the recovery value. Some data may fall between the warning limits and the control limits but when sev eral values fall in this range in a single day or in consecutive days this indicates an out-of-control situation. Such a situa tion requires corrective action. Data falling outside the con trol limits will be considered an out-of-control situation.
When an out-of-control situation is detected (i.e., greater than± 3 standard deviations), efforts will be initiated to determine the cause. Corrective actions will be taken to bring the process under control. The out-of-control situation and cor rective actions taken must be fully documented. Data obtained since the last in-control sample will be considered invalid, and all such analyses will be repeated within 72 hours of sample col lection.
8/88
TABLE E-1. PERFORMANCE EVALUATION DATA (CALDERON ANALYSIS) Compound
Vinyl Chloride
Benzene
Methylene Chloride
. Chloroform
1,1,1-Trichloroethane
Carbon Tetrachloride
1,2-Dichloroethane
Trichloroethylene
Perchloroethyiene
1,2-Dibromoethane
Standard Gas
Concentration
(ppbv)*
5,050 ± 80
2' 110 ± 125
4,120 ± 130
560 ± 15.3
425 :t 13.2
49.5 ± 1.68
3,190 ± 272
333 ± 24.3
52.5 ± 5.53
3.3 ± 0.12
% RSDt
1.§8
5.92 3.16
2.73 3.11
3.39 8.52
7.29 10.5
3.64 MDL#
(ppbv)
1.33 2.48
0.105
0.008
0.023
0.012
0.014
0.005
0.025
0.025
Carr.
Coeff.**
0.999
0.997
0.993
0.999
0.997
0.999
0.999
0.999
0.998
0.961
* Concentration and one standard deviation (1s) for Stock Gas Standard· CC62371 from Scott-Marrin, Inc.
± Percent relative standard deviation (100s/x).
r J . # Method detect ion 1 imit for ambient air sample. **Correlation coefficient for linear regression performed on five-point calibration curve.
8/88-C
)
SPECIAL QUALITY CONTROL PRACTICES FOR CALDERON ANALYSES Gas chromatographs are calibrated with multi-point curves in a manner similar to procedures in the October 26, 1984, Federal Register. Concentrations are chosen to bracket the range of sam ple concentrations. Gas standards ha~e been obtained from Scott Marrin, Inc. These include a primary gas standard, a control gas standard, a surrogate gas standard, and a stock gas standard.
Analyses of these various gas standards are shown in Table E-2.
The curves are verified on a daily basis with a quality control standard.
Standard gas mixtures are prepared at intervals specified in the referenced methods. Where no limit is stated, they are re placed at intervals short enough to prevent detectable deteriora tion during the lifetime of the material.
Method blanks are introduced on a daily basis, at the start of a run, at a frequency of 1 in 10 if more than that number of determinations are run in a day, or if system contamination is suspected and after the analysis of the last sample. Blanks consist of pure helium which is carried through the same analytical scheme as the real ~amples.
A certified reference gas has been acquired from Scott Marrin. It is an NBS traceable standard. The control gas standard is analyzed daily as a laboratory control standard as the first sample of the day and after e~ery 10 samples or at least once per day for any set of less than 10 samples. If the response for each parameter of interest fall within ±15 percent of the established calibration value the method is in
calibration. The calibration check is repeated if the response of the instrument has changed by more than ±15 percent from the historically established values. If the response is still out of tolerance new calibration factors are calculated.
Every tenth sample is analyzed in duplicate. The duplicates are carried through the entire workup and analytical scheme. A comparison of duplicate results measures the precision of each analyte. Spiked samples are also run every 10 samples. The re covery of the resulting spiked sample relative to its theoretical value reflects the accuracy of the de~ermination.
External standardization is used to calculate analyte con centrations. Multi-point calibrations are carried out to gen erate curv~s for the parameters of interest. A five-point curve is generated using various volumes of the stock gas standard to provide a plot of area versus concentration in a range which brackets the expected levels of the parame~ers of interest. The calibration curves are calculated using least squares regression on a Hewlett-Packard HP-1000 computer system.
8/88
)
TABLE E-2. CONCENTRATIONS OF STANDARD GAS MIXTURES
Compound Concentration (ppb)
Primary Gas Standard (Scott-Marrin CC 62368)
Vinyl Chloride
Trichloromethane
Benzene
Tetrachloroethene
Tetrachloromethane
Primary Gas Standard (Scott-Marrin CC 62360)
1,2-Dichloroethane
1,1,1-Trichloroethane
Trichloroethene
1,2-Dibromoethane
Stock Gas Standard (Scott-Marrin CC 62371)
Vinyl Chloride
Dichloromethane
Trichloromethane
1,2-Dichloroethane
1,1,1-Trichloroethane
Benzene
Trichloroethene
Tetrachloromethane
1,2-Dibromoethane
Tetrachloroethene
Control Gas Standard (Scott-Marrin CC 62372)
1,1,1-Trichloroethane
Tetrachloromethane
Trichloroethene
1,2-Dibromoethane
Tetrachloroethene
Surrogate Gas Standard (Scott-Marrin CC 62382)
1,3-Bromochloropropane
8/88-C
102
98 99
94 95
100
103
97 93
5,050
4,120
560
3,190
425
2,110
333
49.5 3.3
52.5 3.59
0.27 1.70
1.55 0.95
34 (\ As was earlier stated, the method detection limit is defined ~ J as the minimum concentration of analyt~ which can be identified, measured, and reported with 99 percent confidence that the con centration is greater than zero. Detection limits are highly variable and depend on the instrument, the analyst, reagent pur ity, and other factors. In many instances, the detection limit will be dictated by the nature of interferences present in the sample matrix rather than instrumental considerations.
. /
Tedlar bags are prepared for field sampling by the labora tory, using a highly controlled process. The bags are permeable to certain gaseous substances; as such, the potential for sample contamination from the atmosphere outside the bag and from the polyvinyl fluoride material itself is very real. This problem is increased as required levels of detection are lowered.
The preparation process involves four steps:
1. Leak check.
2. Conditioning.
3. Quality control analyses.
4. Documentation of bag sampling history.
All bags are checked for leaks prior to conditioning. This involves exerting pressure on the bags by filling them with inert gas. A volume decrease over time indicates a leak. Bags that leak are discarded.
All bags used in sample collection are field quality assur ance conditioned prior to use in the field. Bags are filled with high-purity inert gas, then deflated. This process is .repeated until outgassing is reduced to a tolerable level. Quality con trol analysis determines background concentration of the analytes of interest. The bag is filled with gas once more after condi tioning. It is stored for 24 hours, then analyzed as a normal sample. Conditioning is accepted if background concentrations do not interfere in attaining required detection limits.
Each Tedlar bag is given a unique identification number, and a history is kept for each bag. The dates of leak checks, condi tioning, and sampling are documented. Quality assurance analyses for conditioning, sample type and sample analyses are also docu mented. Bags are used for the same sample matrix type throughout their sampling life.
References
8/88
• Official Methods of Analysis. Association of Analytical Chemists, 14th Edition, 1984.
• Testing Guidelines for Active Solid Waste Disposal Sites.
California AB 3374 (Calderon), 1986 .
r--· l \ . / • Annual ASTM Book of Standards. American Society for Testing and Materials, Philadelphia, 1980.
• U.S. EPA. "Test Methods for Evaluating Solid Waste."
SW-846, 3rd Edition, 1987.
STANDARD OPERATING PROCEDURES FOR ANALYTICAL METHODS
The following section describes procedures for the determi nation of volatile halogenated hydrocarbons and aromatics in LPG and ambient air and the procedure for determination of permanent gases, i.e., the four major (fixed) components of LPG (methane, carbon dioxide, nitrogen, oxygen).
Procedure for Ambient Air Analysis - Attachment 1 Compounds Ambient air is continuously sampled and collected in a Ted lar bag over a 24-hour (or less) period and immediately sent to the laboratory for analysis. For ambient air analysis, a sample from the bag is drawn through a sample valve attached to a Tekmar 5010 Automatic Desorber regulated by a mass flow controller at 50 cc/minute for 4 minutes (total sample volume: 200 cc). Sample volume may be adjusted for concentration as required. The organic constituents are trapped ori Tenax and when the collection is complete, the Tenax is purged foi 5 minutes with helium to remove any trapped moisture. The sample is then thermally desorbed and cryofocused for GC injection.
Procedure for Landflll Gas Analysis - Attachment 1 Compounds For landfill gas, a 1-ml sample is withdrawn with a gas syringe from the Tedlar bag and injected through the septum of the Tekmar 5010 injection port directly onto the Tenax trap.
Compounds eluting from the column are detected and quantified, first by a photoionization detector (PID) and then by an electron capture detector (ECD). The compounds are identified by reten-· tion time. Positive identification or confirmation is accom plished by the use of second column confirmation or by GC/MS.
Fixed Gases Analysis
Major component concentrations in LFG are determined by ac cepted chromatographic procedures, using a thermal conductivity detector.
Interfeiences/Limitations
. Components having similar GC retention times will interfere, causing misidentification and/or faulty quantitation. Because of the very .low sample concentrations, extreme care must be taken to insure that the sample is not degraded or contaminated by the Tedlar sampling bag, -sampling apparatus, or delayed delivery to 8/88
the laboratory. Exposure to the Tedlar
greater than 25°C should be minimized.
sample which can be detected by PID/ECD
fied.
bag to temperatures
Only components of the
detectors will be quanti-
Apparatus
l. Varian Model 3600 Gas Chromatograph with PID/ECD detec tors.
2. Nelson Analytical 2600 Chromatography Data System.
3. Tekmar 5010 Automatic Desorber equipped with two-stage trapping, sampling valves, and cryofocusing capabilities.
4. Gast vacuum pump.
5. Matheson Model 8240 Mass Flow Controller accurately
calibrated in the 5-100 cc/min range.
6. DB 624 0.32 mm column, 30 meter.
7. Tedlar bags.
Reagents
1. Two primary standard gases - Scott-Marrin gas (NBS trace able).
2. One stock gas standard - Scott-Marrin Blend (assayed against primary cylinders).
3. One control gas standard - Scott-Marrin Blend (assayed against primary cylinders).
4. Surrogate gas standard (Scott-Marrin Blend).
5. Pure helium (99.9995 percent).
6. Molecular sieve in-line gas filter.
7. Liquid nitrogen.
Procedures
1. Ambient Air
The system is flushed with helium. The Tedlar bag is
attached to the Tekmar 5010, and a 200-cc sample is trapped (50 cc/minute for 4 minutes). After sample trapping is complete, the Tenax trap is flushed for 5 minutes with helium to remove water vapor and any nonadsorbed reactive gases. The sample is then 8/88
desorbed in a two-stage process, the latter a desorption from a cryofocused trap directly onto the GC to allow the use of capil- . lary columns. The Tekmar 5010 is then baked out with a helium purge gas for 10 minutes at 225°C to prepare for the next cycle.
After bakeout, the trap is isolated from the system and is ready for the next sample.
2. Landfill Gas
The high concentration inlet is used for high concentration calibration standards and for other samples with concentrations higher than ambient levels. The system is flushed with helium gas. A 1-ml sample is withdrawn with a gas syringe from the Ted lar bag and injected through the septum of the Tekmar 5010 injec tion port directly onto the Tenax trap.
After sample trapping is complete, the Tenax trap is flushed with helium to remove water vapor and any nonadsorbed gases. The sample is then desorbed in a two-stage process, the latter a de sorption from a cryofocused trap directly onto the GC to allow the use of capillary columns. The Tekmar 5010 is then baked out with helium purge gas for 10 minutes at 225°C to prepare for the next cycle. After bakeout, the trap is isolated from the system and is ready for the next sample.
3. GC Conditions
Conditions are the same for both the landfill gas and ambi ent air samples.
Temperatures:
Injector:
PID Detector:
ECD Detector:
Oven:·
Flow Rates:
Carrier:
Desorb:
ECD Makeup:
Detectors:
210°C
250°C
310°C
30°C, hold for 3 minutes
l0°C/minute ramp to
150°C, hold for
13 minutes
2.5 ml/minute
10 ml/minute
N2 at 40 ml/minute
Electron Capture
Photoionization, 10.2 EV Lamp
4. Fixed Gases (Methane, Carbon Dioxide, Nitrogen, Oxygen) 8/88
Landfill gas samples are analyzed using a Varian 2700 GC with a TCD (thermal conductivity) detector and a Supelco Silica Gel 30/60 packed column along with a Molecular Sieve 30/60 packed c6lumn. A 0 .. 9-ml sample is injected with a gas syringe. The GC is operated isothermally at 200°C. If the concentration of meth ane is less than 1,000 ppm, the sample must be reanalyzed in the following manner. The sample is analyzed on a Varian 3400 gas chromatograph with an FID (flame ionization) detector and a 30-. meter, 0.32-mm HP-5 column. A 50-ul gas sample is injected into· the GC.
Calculations
1. The concentrations of ARB Guideline Attachment 1 compounds (in ppb) are calculated by external standard method using the Nelson Analytical 2600 chromatography systems.
2. The method of calculation is as follows:
Cone. Unknown= DF x [(Ax RF) + RO]/Amt. Inj.
where:
3. DF = Dilution factor entered by the chemist.
A= Area of the peak.
RF = Response factor which is taken from the method
file as the slope of the calibration curve.
RO = Intercept of the calibration curve.
Amt. Inj.= -Amount injected, as entered by the chemist.
Concentrations may be converted from ppb to mg;m3 by means of the following formula:
mg/m3 =(P x M.W. x ppb)/(82.05 X T)
where:
P = Pressure in atmospheres.
M.W. = Molecular weight o5 corresponding volatile compound.
82.05 = Gas constant in em x atm./K x mole.
T =Absolute temperature (K).
4. The concentration unit mg/m3 is equivalent to ng/cm 3 • 8/88
() PERFORMANCE AND SYSTEM AUDITS
/-\
\_ )
System audits and internal and external performance audits are required to monitor the capability and performance of the entire measurement system.
The system audit evaluates all components of the measurement system to determine their proper selection and use. Th~s encom passes a careful evaluation of laboratory quality control proce dures and completed paperwork.
The Laboratory Director is responsible for making recommen dations and submitting a report to the Project Manager. System audits are conducted quarterly by the Laboratory Director to alert the Project Manager of any deficiencies. Implementation of recommendations, if any, are made jointly by the Project Manager and Laboratory Director.
Internal performance audits are conducted regularly as part of the quality assurance procedure. Samples are introduced into the laboratory work flow unbeknownst to the laboratory staff.
Results are then reviewed with laboratory and project management.
Changes in quality assurance or operating procedures are then recommended and implemented, as necessary.
External audit samples are submitted to the laboratory by the EPA or an independent auditor. In order to obtain maximum information and benefit from the audit, the samples are analyzed using normal analytical methods and quality assurance/control procedures.
REVIEW OF ANALYTICAL RESULTS
Laboratory work, as it progresses, is reviewed by the Labor atory Director on a daily basis. Newly derived data are examined within the context of historical trends, if available.
All reports issued by the SCS laboratory require the signa tures of both the Chemist and the Laboratory Director. This pro vides a final review of all data prior to issuance of an official report.
INSTRUMENT MAINTENANCE
Systems and supply checks are performed daily. Necessary instrument supplies that are expendable are maintained on a monthly basis, or more frequently" as needed. Compressed gases for GC and AA are monitored daily.
8/88
i J.
8/88
Service agreements and emergency repairs are provided by:
Instrument
AA
TOC
Gas Chromatographs
Gas Chromatograph/Mass
Spectrometer
Mettler Balances
Spectrophotometers
5010 Desorber
Manufacturer
Perkin-Elmer
Beckman
Varian Instrument
Hewlett:-Packard
Mettler Instrument Co.
Genie Scientific
Tekmar
)
/ \
/
SCS ENGINEERS
APPENDIX F
RESULTS OF SUBSURFACE LFG MIGRATION
MONITORING AT LOYNES-BIXBY VILLAGE
AND BIXBY MARKET PLACE SITES
" )
.. \
\ /
SCS FIELD SERVICES
July 1, 1988
File No. 0787004.00
Mr. Dick Cannon
Bixby Ranch Company
911 Studebaker Road
Long Beach, California 90815
.JOBFLB
Ff-----
Subject: Inspection/Monitoring of Lan~{ij- .. · ~~-- . CLF. ;.~1 .. Migration Control Facilities, · .,.~:'<. ::_~"V-~P*It- .. ~ Courfe, Long Beach, California:·· - ..
Dear Mr. Cannon:
This letter provides the results of inspection/monitoring performed by SCS Field Services (SCS-FS) at the subject site.
Monitoring was performed to determine the effectiveness of the LFG migration control cutoff trench and air injection system.
This inspection and m~:mi to ring was conducted in accordance with the quarterly monitoring . frequency delineated in our letter dated November 2, 1982 •
Gas Testing
Testing for methane gas (the combustible component of LFG) was performed using a Gastech Model GX-3N Portable Combination Indicator. This instrument measures combustible gas
concentrations directly on either of two scales: One as a perce:1t by volume of the lower explosive limit (LEL) of methane in air (5 percent), the other as percent by volume of the gas sample { 0 to 100 percent) . The LEL scale is most accurate for combustible gas concentrations of 5 percent or less. If exposed to an ignition source, methane gas can be explosive at concentration of between 5 an~ 15 percent, and flammable at higher concentrations.
Testing for methane gas was performed at subsurface monitoring well Nos. S-1 through S-15 and w-1 through W-17; trench vent pipe Nos. v-1 through V-27; air injection well Nos. I-1 through I-15 were tested for pressure {see Figure 1).
on June 14, 1988, SCS-FS staff visited the site to perform the subject testing and inspection. Results of trench vent pipe and monitoring well testings are shown on Table 1. Results of air pressure testing of the injection wells are shown on Table 2.
Cincinnati Kansas C1ty Los Angeles Phoenix Son FranCISCO Seattle Tampa Wo~h1ngton D.C.
Mr. Dick Cannon
( .\ July 1, 1988
'\ ) Page Two
()
\
During our inspection visit, Monitoring Well No. 11 could not be located. We recommend this well be found as soon ·as pos sible to allow testing.
Also during our site visit, the manhole for the air injection header line drip trap was found to be full of sand, covering the drip trap and header. (This mannole is located in a sand trap.) · SCS-FS staff excavated the manhole to_ expose the drip trap. The trap was removed and found to be inoperable; it was subsequently cleaned, lubricated and re-installed.
on a follow-up visit, our staff found that sand had again filled the manhole. The sand was once again removed and a flexible membrane liner cover was installed over the manhole to prevent this occurence.
On two occasions during the
found electrical problems at
reported to the Bixby Ranch
problems corrected. ·
The surge condition observed
described in our letter dated
are currently investigating
condition.
Conclusions
reporting period, scs_-FS staff
the blower station. These were
Company, who in turn had these
in the air injection blower as
April 1, 1988 still exists. we
alternatives to correct this
Testing for methane gas at the accessible test locations, as described in this report, indicates that, as of the test date, the pass.ive trench vent and active air injection systems appeare~ to be adequately controlling subsurface gas migration along their respective lengths. This report speaks only as of its date. Accordingly, we assume no responsibility for any changes that may occur subsequent to- our monitoring which could affect the quantity of landfill-generated methane gas at the subject site.
our opinion regarding safety is predicated on continued operation of the LFG migration control air injection system.
As we become aware of difficulties with the operation of the system, additional testing may be necessary. We recommend a daily check by Bixby Golf course personnel to verify-operation of the air injection blower. SCS-FS staff should be notified of system shut-down.
( )
Mr. Dick Cannon
July 1, 1988
Page Three
In accordance with the recommended monitoring frequency, test visits are on a quarterly basis (more frequently if mohitoring results indicate the need). Our next routine site test visit will be conducted during the month of September 1988. In the interim, SCS-FS will inspect the air injection blower for proper operation on a monthly basis.
If you have any questions, please contact Mr. James D. Bier or the undersigned.
Very truly yours,
lzat:k/r !e-h1 .
Galen s. Petoyan
Vice President
Robert P. Stearns
President
SCS FIELD SERVICES
GSP/RPS:dw
Enclosures
cc: Mr. Dick stollenwerk, city of Long Beach
Judy McCaslin, Bixby Ranch Company
TABLE 1. MONITORING RESULTS,*
BIXBY VILLAGE GOLF COURSE,
r LONG BEACH, CALI FORNI A
', ) (June 14, 1988)
· .. )
Monitoring Methane Concentration
Location (Percent by Volume)
S-1 NO
S-2 NO
S-3 NO
S-4 NO
s-5 NO
S-~ NO
S-7 NO
S-8 NO
S-9 NO
S-10 NO
S-11 NO
S-12 NO
S-13 NO
S-14 NO
S-15 NO
W-10
W-2
W-3
W-4
W-5
W-6
W-7
W-8
W-9
W-10
W-11
W-12
W-13
W-14
W-15
W-16
W-17
V-1
V-2
V-3
V-4
V-5
V-6
V-7
V-8
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
t
NO
NO
NO
NO
NO
NO
NO
9.0 NO
NO
NO
ND ·
NO
NO
TABLE 1. (CONTINUED) MONITORING RESULTS*
BIXBY VILLAGE GOLF COURSE,
Monitoring
Location
V-9
V-10
V-11
V-12
V-13
V-14
V-15
V-16.
V-17
V-18
V-19
V-20
V-21
V-22
V-23
V-24
V-25
V-26
V-27
LONG BEACH, CALIFORNIA
(June 14, 1988)
Methane Concentration
(Percent by Volume)
NO
NO
NO
NO
NO
NO
NO
0.3 NO
NO
NO
NO
NO
NO
NO
ND
ND
·4.5
NO
* Instrument = Gastech Model GX-3N Portable Combination Indicator.
ND = None Detected.
# = Well could not be located in field.
Key:
S-1
W-1
V-1
=
=
=
Sample test well (for air injection system).
Sample test well (for cutoff trench).
Vertical vent pipe (for cuttoff trench).
TABLE 2. AIR INJECTION WELL PRESSURE TEST RESULTS,
BIXBY VILLAGE GOLF COURSE,
Monitoring
Location
I-1
I-2
I-3
I-4
I-5
I-6
I-7
I-8
I-9
·I-10
I-ll
I-12
I-13
I-14
I-15
LONG BEACH, CALIFORNIA
(June 14, 1988)
Pressure *
Initial
+2.7
+2.6
+2.6
+2.5
+2.5
+2.4
+2.4
+2.4
+2.1
+2.0
+1.9
+2.1
+1.6
+1.4
+1.4
* = Inches of Water Column; Instrument = Dwyer Maqnehelic I-1 = Air Injection Well No. 1
\_
-v ;;o
~
< h
~
I '
£NO Of TR£NCU V 12-
VII-
GOlf COURSE
\.--------~·
V10-
V9-
vs-
LLG£ND --·---·----------
• W-} = SAMPLE TEST WEll (FOR TRENCU)
• Vl = VERTICAl VlNT PIPE
a S-1 = SAMPLE TEST WELL (FOR INJECTION WHLS)
.i 1-1 = AIR INJECTION WELL
NOTE: WEllS NUMBERED CONSECUTIVELY
/\
!
~--------------------------------~-------------------------------------------------------------SCSE~EEAS Figure I. Londflll goa control a~atem.
I.
(---"
I
\ )
~ SCS Field Services
April 1, 1988
File No. F8704.00
Mr. Oick Cannon
Bixby Ranch Company
911 Studebaker Road
Lang Beach, California 90815
Subject: Inspection/~o~i~orin12. ._of .. Landf.ill_ Gas (LFGl ~igration Control Facllltle_s, ~'-'~*11 .. -, aalf r;our.,, Long Beach, California ··· ··· · ~ -- .... .-.. · ·· .. · --~---·~ Dear Mr. Cannon:
This letter provides the results of inspection/monitoring performed by SCS Field Services (SCS-FS) at the subject site.
Monitoring was performed to determine the effectiveness of the LFG. migration control cutoff trench end air injection system. this inspection and monitoring was conducted in accordance with the quarterli monitoring frequency delineated in our letter dated November 2, 1962.
Gas Testing
Testing for methane gas (the combustible component of LFG) was performed using a Gastech Model GX-3N Portable Combination Indicator. This instrument measures combustible gas
concentrations directly on either of two scales: One as a percent by volume of the lower explosive limit (LEL) of methane in air (5 percent), the other as percent by volume of the gas sample (0 to 100 percent). The LEL scale is most accurate for combustible gas concentrations of 5 percent or less. If exposed to an ignition source, methane gas can be explosive at concentrations of between 5 and 15 percent, and flammable at higher concentrations.
Testing for methene gas wa& performed at subsurface monitoring well No•. S-1 through S-15 end W-1 through W-17; trench vent pipe Nos. V-1 through V-27; air injection well Nos. I-1 through I-15 were tested for pressure (see Figure 1). In addition, the filter for the air injection system blower wea replaced as part of the routine maintenance program.
22010 s: Wilmington Ave. • Ste. 109 • Carson, CA 90745 • (213) 835-0235 Mr. Dick
April 1,
Page Two
Cannon
1988
On March 28, 1988, SCS-FS staff visited the site to perform the subject testing and inspection. Results of trench vent pipe and monitoring well testing are shown on Table 1. Results of air pressure testing of the injection wells are shown on Table 2.
During our visit, the following inspection/test points could not be located:
o .Air injection well No. 5
o Monitoring well No. 11
o Header line condensate trap
Additionally, a surge condition was observed in the header line adjacent to the air injection blower station.
Conc1usions
Testing for methane gas at the accessible test locations, as described in this report, indicates that, as of the test date, the passive trench vent and active air injection systems appeared to be adequately controlling subsurface gas migration along their respective lengths. This report speaks only as of its date. Accordingly, we assume no responsibility for any changes that may occur subsequent to our monitoring which could affect the quantity of landfill-generated methane gas at the subject site.
Our opinion regarding safety is predicated on continued operation of the LFG migration control air injection system. As we become aware of difficulties with the operation of the system, additional testing may be necessary. We recommend a daily check by Bixby Golf Course personnel to verify operation of the air injection blower. SCS-FS staff should be notiFied oF system shut-down.
Someone from our oFFice will be contacting you within the next week regarding locating the missing in•pection/test points and trouble •hooting the reported surge condition.
)
)
Mr. 0 i ck Carmon
April 1, 1988
Page Three
In accordance with the recomm~nded monitoring frequency, test visits are on a quarterly basis (more frequently if monitoring results indicate the need). Our next routine site test visit will be conducted during the month of June 1988. In the interim, SCS will inspect the air injection blower for proper operation on a monthly basis.
If you have any questions, please contact the undersigned.
Very truly yours,
? .Lt ~ /. !1/~-v,
I
Galen S. Petoyan
Vice President
) - .. I
. ).1 ·"-·' .;~ .,. ______ _
Robert P. Stearns
President
SCS FIELO SERVICES
GSP/RPS:dw
Enclosures
cc: Mr. Oick Stollenwerk~ City of Long Beach
't
/
Monitoring
Location
S-1
S-2
S-3
S-4
S-5
S-6
S-7
S-8
S-9
S-10
S-11
S-12
S-13
S-14
S-15
. W-1
W-2
W-3
W-4
W-5
W-6
'11-7
W-8
'11-9
W-10
W-11
W-12
W-13
W-14
W-15
W-16
W-17
V-1
V-2
V-3
V-4
V-5
V-6
V-7
v-a
V-9
V-10.
V-11
TABLE 1. MONITORING RESULTS:.:
(March 28, 1988)
Methane Concentration
(Percent by Volume)
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
................ ...............
NO
NO
NO
NO
NO
NO
11 • 0
5.0 NO
NO
NO
NO
NO
NO
NO
NO
NO
TABLE 1 (continued)
Monitoring
Location
Methane Concentration
(Percent by Volume)
V-12
V-13
V-14
V-15
V-16
V-17
V-18
V-19
V-20
V-21
V-22
V-23
V-24
V-25
V-26
V-27
NO
NO
NO
NO
0.3 NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
* Instrument = Gastech Model GX-3N Portable Combination Indicator
NO = None detected
# = Well could not be located in field.
** = Monitoring probe plugged with water.
:::::n:: = M i s s in g
S-1 =Sample test well (for air injection system).
W-1 =Sample test well (for cutoff trench).
V-1 =Vertical vent pipe (for cutoff trench).
TABLE 2. AIR INJECTION WELL PRESSURE TEST RESULTS
(March 28, 1988)
Monitoring
Location #
I-1
I-2
I-3
I-4
I-5
I-6
I-7
I-8
I-9
1-10
I-11
I-12
I-13
I-14
I-15
* Inches of water column
# Air injection well
::::::::: Missing
+++ Pressure not adjusted
Pressure ·'· .,.
Initial Adjusted
+0.24 +0.98
+0.48 +0.92
+0.79 +++
+0.47 +0.92
,.,,. .. , .... ·~ .............. ... , .... , .... , .. .., .... , .... , .. +0.72 +++
+0.26 +0.94
+0.86 +++
+0. 96. +++
+ 1 ~ 3 +++
+0.6 +0.86
.+0 .5 +0.85
+0.4 +0.8
+0.9 +++
+0.9 +++
RESIDENTI/\L
/
\
~/ V26
/,
II
WIS,~
w 17 w 16
. . ------- 1 '
/~~;:r9:B·~~5
GOLF COURSE
-u ::u ...._.
;;
-1
fT1
END OF TRENCH
GOLJ COURSE
Vl2-
Vll-
VIO-
V9-
V8-
L£GfND
•W-1 =SAMPLE TEST WELL (FOR TRENCH)
• Vl = VERTICAL VENT PIPE
• s-1 = SAMPLE TEST WELL (FOR INJECTION WELLS)
~1-1 =AIR INJECTION WELL
NOTE: WELLS NUMBERED CONSECUTIVELY
~--------------------------------~---------------------------------------------------------------------SCSENG~EERS figure I. landfill oas control system. ,.------..... \
I
"---
'\
)
• SCS Field Services
July 1, 1988
File No. 0787010.00
Mr. Dick Cannon
Bixby Ranch Company
911 Studebaker Road
Long Beach, California 90815
JOB FILE
F#
-----
Subject: Inspection/Monitoring of Landfill Gas (LFG)
Migra}ion Control Faci~itie~, The BiXby Ranch_~ark~
Placet l;..ong Beach, Cal~forn~a. ·
Dear Mr. Cannon:
This letter provides the results of inspection/monitoring performed by scs Field Services (SCS-FS) at the subject site. on June 9, 1988, SCS-FS conducted routine quarterly testing of the entire Market Place site. Test locations included trench vent pipes, landfill vent pipes, monitoring wells, and the subfloor monitoring probes beneath Building No. 6. Monitoring locations are shown on Figures 1 and 2.
Gas Testing
Testing for methane gas (the combustible component of LFG) was performed using a Gastech Model GX-3N Portable Combination Indicator. This instrument measures combustible gas
concentrations in air directly on either of two scales: one as percent by volume of the lower explosive limit (LEL). of methane in air (5 percent), the other as percent by volume of the gas sample (0 to 100 percent). The LEL scale is most accurate for combustible gas concentrations of 5 percent or less. If exposed to an ignition source, methane gas can be explosive at concentrations between 5 and 15 percent, and flammable at higher concen~rations.
Data from the landfill vent pipes (i.e., methane concentra tions as high as 25 percent) indicate that the landfill is continuing to decompose anaerobically, producing combustible gas. The test results from the trench vent pipes and
monitoring wells indicate that office Building Nos. 1, 2, and 6, the El Torito Restaurant, and United Artists Theater Building all appear to be adequately protected from migrating LFG. (Note that the subfloor ventilation system beneath Building No.. 6 was observed to be operating at the time of our inspection visit.) Test results are shown on Tables 1 and 2.
Trench vent pipe T4 which had been -previously reported as missing was replaced on May 16, 1988.
22010 S. Wilmington Ave. • Ste. 109 • Carson, CA 90745 • (213) 835-0235 \
i
Mr. Dick Cannon
July 1, 1988
Page Two
Conclusions
This report speaks of site conditions only as of the test date. Accordingly, we assume no responsibility for any
changes that may occur between or following the date of our inspections which may bear upon the nature and quantity of subsurface methane gas at the subject site.· Our opinion regarding safety at Building No. 6 (with respect to LFG migration) is predicted upon continued operation of the subfloor air ventilation system. SCS-FS should be notified if a system failure occurs. We additionally recommend that scs FS be notified to arrange for testing beneath any building at the site prior.tc entry by plumber, electricians, or any other personnel.
In accordance with the schedule for routine quarterly
monitoring delineated in our letter dated November 2, 1982, the next full site monitoring should be performed in September 1988. SCS-FS will continue to inspect the Building No. 6 blower for proper operation on a monthly basis. If you have any questions regarding this report, please contact Mr. James D. Bier or the undersigned.
Very truly yours,
~ti~~raL_
Galen s. PetoyJ
Vice President
CZ-UJ~I
Robert P. Stearns
President
SCS FIELD SERVICES
GSP/~PS:dw
Enclosures
cc,: Mr. Dick Stollenwerk, City of Lonc;r Beach
Ms. Judy Mccaslin, BiXby Ranch company
TABLE 1. SUBSURFACE LANDFILL GAS MONITORING RESULTS,
THE MARKET PLACE, LONG BEACH, CALIFORNIA
(~)
Methane Concentration*
Monito;r.:ing Location (Pe;r.:cent by Volume in A~r)
06/09/88
M-2 A NO
B NO
M-3 A NO
B 0.2
M-6** A NO
B NO
M-7** A NO
B NO
M-8** A NO
M-10 A NO
B NO-
M-11 A NO
B NO
)
NO ... ' M-12 A
B NO
M-13 A NO
B NO
M-14 A NO
B NO
M-15 A NO
B NO
' /
)
TABLE 1. (CONTINUED) SUBSURFACE
LANDFILL GAS MONITORING RESULTS,
THE MARKET PLACE, LONG BEACH, CALIFORNIA
Monitoring Location
VP-1
VP-2
VP-3
VP-4
VP-5
VP-6
VP-7
T-1
T-2
T-3
T-4
T-5
T-6
T-7
T-8
Methane Concentration*
(Percent by Volume in Airl
06/09/88
NO
25.0 1.5
0.4 NO
0.2 0.8
ND
NO
NO
NO
NO
0.25 NO
NO
* Instrument = Gastech Model GX-3N Portable Combination Indicator.
NO = None Detected.
**=Monitoring Well Reinstalled January 7, 1986.
Note: Monitoring Well Nos. 1, 4, 5, and 9 have been
permanently lost or destroyed. These wells have been replaced or are otherwise not considered important.
M-2 = Monitoring Well No. 2.
VP-1= Vent Pipe No. 1.
T-1 = Trench Vent ~ipe No. 1.
TABLE 2. RESULTS OF METHANE MONITORING, BUILDING NO. 6,
THE MARKET PLACE, LONG BEACH, CALIFORNIA
Subfloor Probe
Number
1 2
3 4
5 6
7 8
9 9A
9B
9C
10 . 11
12 13
14 15
16 17
18 19
20 21
. 22
23 24.
25 26
27 28
29 Methane (Percent by Volume)*
06/09/88
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.1 0.2
ND
ND
ND
NO
ND
NO
NO
NO
NO
0.1 NO
NO
0.25 0.2
0.25 0.1
NO
0.1 0.1
NO
* Instrument = Gastech Model GX-3N Portable Combination Indicator.
ND = None Detected.
"',__, ....
t-
THEATER
BUILDING
M-5
•
T-2
• . --
M-2
M-3
•
M-4
o-··
RESTAURANT
M-9
•
'---_/
VENTILATION
OLOWEf~
OFFICE OUILDING M6
(SEE FIGURE 2)
~
GAS INTERCEPTOR
VP-7
A
VP-2
A
VP-4
.A
VP-6
•
OFFICE OUILDING
, 1
VP-1
A
VP-3
•
VP-5
A
LEGEND
M-1
cNOT TO SCALE>
• MONITORING WELL
VP-1
• VENT PIPE IN REFUSE
T-1
• TRENCH VENT PIPE
-----GAS INTERCEPTOR TRENCH
- - CONNECTING HEADER
• •
M-14 M-15
OFFICE
OUILDING
"2.
T-8
___ Ll _figure _1. Hon.itoring locations at thJ Market Place. Long Beach. California. /
) (
\
9 9A9B 9 c
'
r'
. .
I
I.
vJ I ~·
I
I ~1.1 I i ! I I 6 L!(
I "'' ~;I i i
Vi I I. I I
(l I I
:I
. I
v; - i i! .
~; I
. I I I
SLOG. 6
Vi
i I
. I .
. ~ .
r I.
I 7"i;1 I
IBdl
~I
j : --
_...,..;__ ____ .,,
19 LEGEND
BLOWER 1 [!]subf1oor monitoring probe
Figure 2. Subfloor probe location, building No. 6,
Market Place, Long Beach, California.
)
~ SCS Field Services
March 31, 1988.
File No. F8710.00
Mr. Dick Cannon
Bixby Ranch Company
911 Studebaker Aoad
Long Beach, California 9D815
Subject: Inspection/Monitoring of_ Landf i 11 Gas
Migration ;ontrol Facilities, The Bixby
Market Placf, Long Beach, California ·
Dear Mr. Cannon:
(LFG)
Ranc1
This letter provided
performed by SCS Field
site.
the results of inspection/monitoring
Services (SCS-FS) at the subject
On March 28, 1988, SCS-FS conducted routine quarterly
testing of the entire Market Place site. Test lcaaticns inclyded trench v•nt pipes, landfill vent pipes, monitoring wells, and the subflccr monitoring probes beneath Building No. 6. Monitoring locations are shown en Figures 1 and 2. · Gas Testing
Testing fer methane gas (the combustible component of LFG) was performed using a Gastech Medel GX-3N Portable
Combination Indicator. This instrument measures combustible gas concentrations in air directly en either of two scales; one as percent by volume of the lower explosive limit (LEL) of methane in air (5 percent); the other as percent by
volume (0 tc 100 percent) in the gas sampled. The LEL scale is most accurate fer combustible gas concentrations of 5 percent cr less. If exposed to an ignition source, methane gas can be explosive at concentrations between 5 and 15 percent, and flammable at higher concentrations.
Data from the landfill vent pipes (i.e., methane.
concentrations as high as 12 percent) indicate that the landfill is continuing tc decompose anaercbicelly, producing combustible gas. The test results from the trench vent
pipes and monitoring wells indicate that office Building Nos. 1,2, and 6, and the El Tcrito Restaurant and United Artists Theater Building all· appear tc be adequately
protected from migrating LFG. (Note that the su~floor
ventilation system beneath Building No. 6 was observed tc be operating at the time cf cur inspection visit). Test
\ results are shewn en Tables 1 and 2. The filter en the I ~ subflccr air injection blower was replaced as part bf routine maintenance.
r)
)
Mr. Dick Cannon
Page Two
During the inspection visit, trench vent pipe No. T4 was found to be missing; a pipe stub was observed at the site surface.
Conclusions
This report speaks of site co~ditions only as of the test date. Accordingly, we assume no responsibility for any
changes that may occur between or following the date of our inspections which may bear upon the nature and quantity of subsurface methane gas at the subject site._ Our opinion regarding safety at Building No. 6 (with respect to LFG migration) is predicted upon continued operation of the subfloor air ventilation system. SCS-FS should be notified if a system failure occurs. We additionally recommend that SCS-FS be notified to arrange for testing beneath any
building at the site prior to entry by plumber, electricians, or any other personnel.
Someone from our office will be contacting you within the next week regarding repair of T4.
In accordance with the schedule for routine quarterly
monitoring delineated in our letter dated November 2, 1982, the ne~t full site monitoring should be performed in June 1988. SCS-FS will continue to inspect the Building No. 6 blower for proper operation on a monthly basis •. If you have any questions regarding this report, please contact either of the undersigned.
Very truly yours,
/· .. / r aL v1./L t.t-tA- . ,.___, ;-
Galen S. Petoyan
Vice President
Robert P. Stearns
President
SCS FIELD SERVICES
GSP:dw
Enclosures
cc: Mr. Dick Stollenwerk, City of Long Beech
)
TABLE 1. SUBSURFACE LANDFILL GAS MONITORING RESULTS,
THE MARKET PLACE, LONG BEACH, CALIFORNIA
(Methane Concentration~::
Monitor ins Location (Percent b;;t Volume in Air)
3/28/88
M-2 A NO#
B NO
M-3 A NO
B NO
M-6*~: A NO
B NO
M-7*~: A NO
B NO
M-S~o:: A NO
M-10 A NO
B NO
M-11 A NO
B NO
M-12 A NO
B NO
M-1.3 A NO
B 0. 1
M-14 A 0.1-
8 NO
M-15 A NO
8 NO
~)
I
\ )
\
j
TABLE 1 (Continued
Monitoring Location
VP-1
VP-2
VP-3
VP-4
VP-5
VP-6
VP-7
T-1
T-2
T-3
T-4
T-5
T-6
T-7
T-6
(Methane Concentration*
(Percent by Volume in Air)
3/28/86
NO
12.0 1. 2
0.7 NO
0.3 NO
NO
NO
NO
NO
NO
NO
NO
NO
* Instrument = Sastech Model GX-3N Portable Combination Indicator.
#NO = None detected.
** Monitoring well reinstalled January 7, 1986.
Note: Monitoring well Nos. 1,4,5, and 9, have been
permanently lost or destroyed. These wells have been
replaced or are ·otherwise not considered important.
)
J
TABLE 2. RESULTS OF METHANE MONITORING, BUILDING NO. 6,
THE MARKET PLACE, LONG BEACH, CALIFORNIA
Subfloor Probe
Number Methane (Percent by Volume):~
3/28/88
1 NO#
2 NO
3 NO
4 NO
5 NO
6 NO
7 NO
8 NO
9 NO
SA NO
98 0. 1
sc 0.2
10 NO
11 NO
12 NO
13 NO
14 NO
15 NO
16 0. 1
17 NO
18 0. 1
19 NO
20 0. 1
21 NO
22 0 .. 3
23 0.2
24 0.3
25 0.2
26 NO
27 0. 1
28 0. 1
29 NO
* Instrument - Gastech Model GX-3N Portable Combination Indicator.
# NO = None Detected.
t-
THEATER
BUILDING
M-5
•
T-2
• . --
M-2
M-3
•
M-4
o-··
RESTAURANT
M-9
•
'~·
·;-,.
"
"---~/
VENTILATION
BLOWER
OFFICE BUILDING M6
(SEE FIGURE 2)
~
GAS INTERCEPTOR
VP-7
•
VP-2
•
VP-4
-·
VP-6
•
OFFICE BUILDING
• 1
VP-1
•
VP-3
•
VP-5
•
LEGEND
M-1
<NOT TO SCA L£ >
e MONITORING WELL
VP-1
A VENT PIPE IN REFUSE
T-1
• TRENCH-VENT PIPE
-----GAS INTERCEPTOR TRENCH
- -CONNECTING HEADER
• •
M-14 M-1
OFFICE
BUILDING
112
T-8
_ _Ll ._figure _1. . Mon.itoring locations. at thJ Market Place. Long Beach. California. ,'I
12 131....,1----1 4 I ~...._ ___ .J
-.
I 9 20 2 I
9 9A 98 9C
BLDG. 6
-...,.;------111
_......,.. ___ ,.,
BLOWER
25-26
LEGEND
I[!] Subf1 oor monitoring probe
Figure 2. Subfloor probe location~ building No. 6,
Market Place, Long Beach, California.
l ~ • I
ADDENDUM REPORT
SOLID WASTE ASSESSMENT TEST
MARKET PLACE SANITARY LANDFILL
LONG BEACH, CALIFORNIA.
Project No. 240827
PREPARED FOR
BIXBY RANCH COMPANY
3010 Old Ranch Parkway, Suite 100
Seal Beach, California 90740
PREPARED BY
IT Corporation'
17461 Derian Avenue~·"Suite 190
Irvine, Califo~Via 92714
January 1991
.~ ~ '
'" " • 1 ·'- ~ r ;
''···-
INTERNATIONAL TECHNOLOGY CORPORATION
TABLE OF CONTENTS
PAGE
LIST OF TABLES .......... · ............................... ··.··· ii LIST OF FIGURES ......................................... · · · · ii
1.0 INTRODUCfiON ...................................... · · · 1
2.0 SOLID WASTE ASSESSMENT TEST SUMMARY ............. · · · 1
2.1 GROUND-WATER MONITORING AND SAMPLING ..... ····
2.1.1 Location and Description of the SWAT Monitoring Wells · · ·
2.1.2 Direction of Ground-Water Movement ............. · · · ·
2.1.3 Surface-Water Sampling ........................ · · · ·
2.2 WATER QUALITY IN THE VICINITY OF THE DISPOSAL SITE
2.2.1 General Water Chemistry ......... ~ .............. · · ·
2.2.2 Metals ...................... · . . . . . . . . . . . . . . . . . · · ·
2.2.3 Purgeable Halocarbons and Aromatics ... , . . . . . . . . . . . · · ·
2.2.4 Base/Neutral and Acid Extractable Organic Compounds .. · · ·
2.3 SUM:rviARY AND DISCUSSION OF WATER CHEMISTRY . · · ·
3.0 CONCLUSIONS ...................................... · · · · ··
4.0 PREPARATION AND CERTIFICATION ................... • · · ·
4.1 PREPARATION ................................... · · ·
4.1.1 Statement of Completeness and Accuracy of the SWAT . · · ·
4.1.2 Identification of Qualified Persons Preparing the SWAT . · · Report ..................................... · · ·
4.2 CERTIFICATION ........... · ..................... ; .. · · TABLES
FIGURES
4.2.1 Certifier's Name and Registration Number ........... ·
4.2.2 4.2.3
Certifier's Qualifications
Statement of Certification
. . . . . . . . . . . . . . . . . . . . . . . . . . .
. . •. . . . . . . . . . . . . . . . . . . •. . . .
APPENDIX A- MONITORING WELL DEVELOPMENT, GROUND-WATER
SAMPLE COLLECTION, AND ANALYTICAL PROCEDURES
2 2
3 3
3 4
5 6
6 6
.g
9 9
9 9
9 9
10 10
APPENDIX B - CERTIFICATES OF ANALYSIS AND CHAIN-OF-CUSTODY FORMS WP:0827R2.TOC i
INTERNATIONAL TECHNOLOGY CORPORATION
Benzene and, periodically, acetone, trans-1,2-dichloroethane, methyl ethyl ketone (MEK), methyl isobutyl ketone (MIK), toluene, and xylene( s) were detected in upgradient well MP-3.
Acetone, MEK, and MIK were detected in downgradient well MP-1. MEK and MIK were detected in downgradient well MP-2. The volatile organic compounds detected in MP-3 (upgradient) are probably from an off-site source. Ground water at several sites in the immediate vicinity is known to be contaminated with petroleum products.
WP:0827R2 7
)
INTERNATIONAL TECHNOLOGY CORPORATION
4.0 PREPARATION AND CERTIFICATION
4.1 PREPARATION
The preparation and certification of this addendum report are presented in the following sections.
4.1.1 Statement of Completeness and Accuracy of the SWAT This Solid Waste Assessment Test addendum report is considered complete and accurate to the best of the preparers' knowledge. The analyses and conclusions stated in the report are based on available hydrogeologic and water-quality data for the disposal site and vicinity.
4.1.2 Identification of Qualified Persons Preparing the SWAT Report The following qualified persons prepared this addendum report:
4.2 CERTIFICATION
Kevin B. Aardahl
Project Scientist II
~~ t:/'Hassan Am~
Project Manager
This constitutes certification of the SWAT addendum report for the Market Place Sanitary Landfill prepared by IT Corporation for the Bixby Ranch Company and submitted to the California Regional Water Quality Control Board, Los Angeles Region, in 1991.
4.2.1 Certifier's Name and Registration Number
The accuracy and completeness of the Market Place Sanitary Landfill SWAT addendum report have been certified by Hassan Amini, Ph.D. Dr. Amini is a Registered Geology with the State of California, Board of Registration for Geologists and Geophysicists, license number 4738, expiration date June 30, 1992.
WP:0827R2 9
)
)
INTERNATIONAL TECHNOLOGY CORPORATION
4.2.2 Certifier's Qualifications
Dr. Amini is an employee of IT Corporation and Program Director for IT's Regulatory Programs and Site Assessments Group. He received a bachelor's degree in Geology in 1974 from the University of Tabriz, Iran, and a master's in Geology in 1978 and a doctorate in Geological Sciences iill983, both from the University of Colorado at Boulder. He has more than five years of experience in the environmental field. In the last three years, he has been responsible for geologic and hydrogeologic investigations at various waste disposal facilities.
4.2.3 Statement of Certification
I, Hassan Amini, certify that, to the best of my knowledge, the data and information presented in this addendum report, which covers the proposed SWAT work plan, are accurate and complete. I further certify that the conclusions presented in the report are in accordance with accepted practices and procedures.
WP:0827R2 10
TABLES
./--...._
\
)
( )
WELL INFORMATION
Coordinates of well:
Northing
Easting
Elevation of well (ft above msl):
Top of well monument
Ground surface
Top of well casing
Total depth of well (ft):
TABLE 1
SITE MONITORING \E:LL INFORMATION
MARKET PLACE SANITARY LANDFILL
PROJECT NO. 240827
WELL NUMBER
MP·1 MP·2 MP-3
3665.66 3037.87 3240.28
5889.95 6390.57 5522.62
6.70 7.74 10.80
4.61 5.76 11.00
6.51 7.52 10.64
22.5 23.3 22.3
MP-4 MP-5
2846.94 2607.94
5812.35 5996.05
16.24 16.69
16.58 14.89
16.13 16.59
28.1 23.4
Depth of screened interval (ft): 7.5 - 22.5 8.3 - 23.3 7.3 - 22.3 13.1 - 28.1 8.4 - 23.4 Depth to water from top of well
casing (ft):
10/19/88 7.71 8.77 8.44 15.27
1/31/89 4.45 7.85 8.26 14.15
5/3/89 and 5/4/89 5.78 8.13 8.01 14.03
9!6!89 and 9/7/89 7.71 8.86 7.57 14.05
Depth to water from ground
surface (ft):
10/19/88 5.81 7.01 8.80 15.72
1/31/89 2.55 6.09 8.62 14.60
5/3/89 and 5/4/89 3.88 6.37 8.37 14.48
9!6!89 and 9/7/89 5.81 7.10 7.93 14.50
Elevation of water surface
(ft above msl):
10/19/88 -1.20 -1.25 2.20 0.86
1/31/89 2.06 -0.33 2.38 1.98
5/3/89 and 5/4/89 0.73 -0.61 2.63 2.10
9/6/89 and 9/7/89 -1.20 -1.34 3.07 2.08
Notes:
1. The coordinates of the wells were surveyed from six control points along Pacific Coast Highway from the San Gabriel River bridge north to Colorado Street (about 1.5 miles).
2. The elevations of the wells were surveyed from County of Los Angeles Survey Monument L.B. L-6, being assigned the elevation 20.46 feet.
3. NM - Not measured; the well was not installed by the date the other wells were measured.
NM
15.66 15.51
15.41 NM
13.96 13.81
14.89 NM
0.93 1.08
1.18 MPW1.XLS1
/---\
. ) TABLE 2
AVERAGE CHEMICAL C(J4P0SITION OF SEA WATER
MARKET PLACE SANITARY LANDFILL
PROJECT NO. 240827
PARAMETER (Symbol)
pH
Total Dissolved Solids- Fresh ~ater
Total Dissolved Solids - Brackish ~ater
Total Dissolved Solids- Saline ~ater
Total Dissolved Solids- Brine
Conductivity - Fresh ~ater
Conductivity- Saline ~ater
Conductivity - Brine
NOTES :
Chloride (Cl)
sulfate (S04)
Bicarbonate (HC03)
Bromide (Br)
Fluoride (F)
Aluninun CAL)
Antimony (Sb)
Arsenic (As)
Bariun (Ba)
Beryll i un (Be)
Boron (B)
Cadniun (Cd)
Calciun (Ca)
Ch romi un ( Cr)
Cobalt (Co)
Copper (CU)
Iron (Fe>
Lead (Pb)
Lithiun CL i)
Magnesiun (Mg)
Manganese (Mn)
Mercury (Hg)
Molybdenun (Mo)
Nickel (Ni)
Potassiun (K)
Seleniun (Se)
Silver (Ag)
Sodiun (Na)
Strontiun (Sr)
Thall iun (Tl)
Vanadiun (V)
Zinc (Zn)
AVERAGE CONCENTRATION (mg/l)
7.8 units
0 to 1,000
1,000 to 10,000
10,000 to 100,000
>100,000
30 to 2000
45,000 to 55,000
>100,000
19400
2712
142
67 1
0.001
0.00021
0.0021
0.02 0.000006
4.45 .00001 to .00011
412
.00008 to .0002
.00004 to .00039
.0001 to .003
.0013 to .0034
.000005 to .00003
0.17 1290
.0002 to .0004
.000011 to .0002
0.01 .0002 to .0066
392
.00004 to .00009
.00001 to .0003
10760
8 NO DATA
0.0019
.00001 to .010
1. Unless otherwise stated, the values of the parameters listed are for typical sea water and do not take into consideration the effects of direct saline water and fresh water mixing.
REFERENCES:
1. Matthess, Harvey, 1982, "The Properties of Groundwater," John ~iley and Sons, Inc., 401 pp.
2. Forstner, ~ittmann, 1979, "Metal Pollution in the Aquatic Environment," Springer- Verlag, Berlin, Heidelberg, New York, 486 pp.
SEA1.XLS1
DRINKING WATER STATE ACTION
ANALYSIS UNITS STANDARD LEVEL
pH units 6.5 - 8.5 NE
Conductivity Llltlos/cm 900 NE
Total Dissolved Solids mg/l 500 NE
Chemical Oxygen Demand mg/l NE NE
~ i ochemi cal Oxygen Demand mg/l NE NE
Total Organic Carbon mg/l NE NE
-----
~/
TABLE 3
SUMMARY OF GROUND-~nrER CHEMISTRY
GENERAL YATER CHEMISTRY
BIXBY RANCH CO.-MARKET PLACE LANDFILL
PROJECT NO. 240827
DATE OF
COLLECTION
1 2
3 4
1 2
3 4
1 2
3 4
1. 2
3 4
1 2
3 4
1 2
3 4
DETECTION
LIMIT
0.1 0.1
0.1 0.1
0.1 0.1
0.1 0.1
5 5
5 5
5 5
5 5
2 2
2 2
1 1
1 1
MP-1 MP-2
7.6 7.3
7.4 7.4
7.5 7.4
7.4 7.3
61600 108000
27300 95900
25700 96300
27800 107000
42000 75200
19300 73500
16300 88000
18260 94550
25 35
100 <50
40 5
40 25
18 25
4 4
8 5
5 2
9 14
24 12
30 5.3
77 22
MP-3 MP-4 MP-5
7.4 7.4 NT
7.4 7.4 7.7
7.5 7.4 7.6
7.5 7.3 7.4
68800 22000 NT
65400 23000 23000
62000 24000 17650
62000 22500 16000
45900 11000 NT
43000 14150 12800
48600 16000 10700
46800 15500 9985
25 185 NT
<50 100 50
30 20 25
40 5 15
19 18 NT
7 5 9
22 13 15
25 3 6
72 24 NT
46 15 8.6
51 11 8.7
95 28 56
FIELD
BLANK
8.5 6.4
5.7 7.6
2 3.1
2 2.7
NO
5 ND
ND
<1
5 NO
ND
<1
ND
NO
NO
<2
NO
NO
NO
TRAVEL
BLANK
--
8.2 6.4
I
5 10
2.5 I
3.6 10
5 I
10 ND
ND
I
NO
<1
ND
I
<1
12 1.3
I
NO
MPGC1.XLS1
'---- TABLE 3 (CONTINUED)
_)
Total Organic Hal ides mg/l NE NE 1 0.01 0.15 0.80 2.4 1 NT 0.016 NO 2 0.01 0.57 3 2.7 1 0.65 NO NO
3 0.01 0.65 2.2 2.6 1.3 0.84 NO I
4 0.01 1.1 NO 1.7 0.5 1.4 NO NO
Total Alkalinity as CaC03 mg/l NE NE 1 2.5 880 1230 2925 1425 NT 3 2 2 2.5 715 632 2788 1160 705 2.5 2.5
3 2.5 758 653 2913 1178 793 NO I
4 2.5 700 463 2838 1168 800 2.5 5
Hydroxide mg/l NE NE 1 0 NONE NONE NONE NONE NT NONE NONE 2 0 NONE NONE NONE NONE NONE NONE NONE
3 0 NONE NONE NONE NONE NONE NONE I
4 0 NONE NONE NONE NONE NONE NONE NONE
Carbonate mg/l NE NE 1 0 NONE NONE NONE NONE NT NONE NONE 2 0 NONE NONE NONE NONE NONE NONE NONE
3 0 NONE NONE NONE NONE NONE NONE I
4 0 NONE NONE NONE NONE NONE NONE NONE
Bicarbonate mg/l NE NE 1 3 1075 1500 3570 1740 NT 3 3
2 3 872 772 3401 1415 860 3 3
3 3 924 796 3253 1437 967 NO I
4 3 854 564 3462 1424 976 3 6
Chloride mg/l 250 NE 1 1 23000 50500 27000 6800 NT NO NO 2 1 9000 41000 36000 6900 7000 NO NO
3 1 8400 44000 26800 7000 5400 NO I
4 1 9200 52500 27800 nso 5250 NO NO
Fluoride mg/l 1.4 - 2.4 NE 1 0.1 0.6 1 2 2 NT NO NO
2 0.1 2 1 2.3 2.2 1.8 0.1 NO
3 0.1 1.9 0.9 2 2 1.7 NO I
4 0.1 2 1 2.4 2.3 1.7 0.1 NO
Nitrate mg/l 45 NE 1 1 250 330 320 230 NT ND NO
2 1 53 133 27 41 41 NO NO
3 1 NO NO NO <3 <3 NO I
4 1 <0.1 10 10 10 1 NO NO
--- -------
MPGC1.XLS2
--~j
TABLE 3 (CONTINUED)
Phosphate as Total P mg/l NE NE 1 0.03 40 56
2 0.03 2.8 1.4
3 0.03 0.6 0.5
4 0.03 0.4 0.2
Sulfate mg/l 250 NE 1 1 3420 8700
2 1 2200 10500
3 1 1340 6600
4 1 3450 6550
Bromide mg/l NE NE 1 1 NA NA
2 1 NA NA
3 1 38 199
4 1 35 <5
Calcil.m mg/l NE NE 1 1 425 780
2 1 230 760
3 1 172 750
4 1 206 830
Iron mg/l 0.3 NE 1 0.01 <0.05 0.05
2 0.01 0.04 0.10
3 0.01 0.02 0.05
4 0.01 0.02 NO
Magnesil.m mg/l NE NE 1 1 1500 3200
2 1 NA NA
3 1 NA NA
4 1 NA NA
Manganese mg/l 0.05 NE 1 0.01 1.8 2.8
2 0.01 0.66 2
3 0.01 0.39 2.6
4 0.01 0.55 3.3
Potassil.m mg/l NE NE 1 1 575 275
2 1 214 860
3 1 225 880
4 1 254 995
---- -- -~ -~- ------~ ------ --------
18 32
0.7 1.4
1 0.5
1.1 0.1
1430 1870
2400 1815
1580 1670
1600 1600
NA NA
NA NA
80 20
62 19
355 850
410 290
400 660
410 144
0.2 0.04
0.18 0.04
0.33 0.03
0.26 0.02
1750 340
NA NA
NA NA
NA NA
3 1.8
0.95 2
1.4 2.6
2 2.6
515 200
450 190
440 200
465 185
--- ---------
NT <0.01
5.6 <0.02
1. 7 NO
0.9 NO
NT NO
1240 NO
820 NO
2100 NO
NT NA
NA NA
20 NO
15 <5
NT NO
140 1
170 NO
188 1
NT 0.02
0.03 0.03
0.02 0.04
0.01 NO
NT NO
NA NA
NA NA
'
NA NA
NT NO
0.4 NO
0.53 NO
1.4 NO
NT NO
210 NO
178 NO
144 NO
L__ ____ ---- ----
<0.01
<0.02
I
NO
NO
NO
I
NO
NA
NA
I
<5
2 1
I
1 NO
0.03 I
0.02 I
NO I
NA
I
NA
NA
NO
•
NO I
I
NO
NO
NO
I
NO
---
\
I
MPGC1.XLS3
TABLE 3 (CONTINUED)
SodilJll mg/l NE NE 1
2 3
4 Oil and Grease mg/l 0 NE 1
2 3
4 NOTES:
NT- Not tested; The monitoring well was not installed at the time of sampling.
NA - Not analyzed.
I - Invalid travel blank; Sample improperly prepared by the laboratory. 1 1
1 1
1 1
1 1
ND- Not detected; The analyte was not detected at or above the stated detection limit.
NE -Not established.
Date of collection:
1 - First quarter (10/19/88).
2 - Second quarter (01/31/89).
3 - Third quarter (05/03/89).
4 - Fourth quarter (09/06/89).
14000
5800
5700
6200
NO
8 NO
16 31000 15800 4600 NT NO NO
30500 18000 4600 4900 NO NO
25000 15000 4600 3500 NO I
30000 15400 4650 3000 NO NO
NO NO NO NT NO NO
4 7 NO 1 NO NO
NO NO NO NO NO I
8 9 10 6 NO NO
MPGC1.XLS4
ANALYSIS
Antimony
Arsenic
Barillll
Beryllillll
caanillll
TABLE 4
SUMMARY OF GROUND-WATER CHEMISTRY
METALS
BIXBY RANCH CO. - MARKET PLACE LANDFILL
PROJECT NO. 240827
DRINKING WATER STATE ACTION DATE OF DETECTION
UNITS STANDARD LEVEL COLLECTION LIMIT MP-1 MP-2
mg/l NE NE 1 0.01 1 <1
2 0.01 <0.05 <0.05
3 0.01 <0.1 ND
4 0.01 ND 0.01
mg/l 0.05 NE 1 0.01 ND <0.1
2 0.01 0.01 <0.1
3 0.01 0.01 <0.1
4 0.01 0.01 ND
mg/l 1 NE 1 0.1 ND ND
2 0.1 ND ND
3 0.1 ND ND
4 0.1 ND ND
mg/l NE NE 1 0.01 <0.05 <0.05
2 0.01 ND <0.1
3 0.01 NO <0.05
4 0.01 NO <0.05
mg/l 0.01 NE 1 0.001 <0.01 <0.03
2 0.001 ND <0.01
3 0.001 <0.01 <0.01
4 0.001 <0.01 NO
--------- -- -- -·- ------------ ---- --··
~·"
FIELD TRAVEL
MP-3 MP-4 MP-5 BLANK BLANK
<1 <0.2 NT <0.2 <0.2
<0.05 <0.1 <0.05 . NO ND
<0.1 ND NO NO I
ND ND ND ND ND
<0.05 ND NT NO ND
0.04 ND NO ND NO
<0.1 ND <0.02 ND I
0.06 ND ND ND NO
2.8 ND NT ND ND
<2 ND ND NO ND
1 ND NO ND I
2.7 ND ND ND ND
<0.05 ND NT ND ND
0.01 ND ND ND ND
<0.05 ND NO ND I
<0.1 ND ND ND ND
<0.01 <0.01 NT ND ND
<0.01 <0.01 <0.01 <0.01 ND
<0.01 <0.01 NO NO I
I
NO <0.005 NO NO NO
-·· - ---- -
MPM1.XLS1
TABLE 4 (CONTINUED)
-,__,/'
Chromilln (Total) mg/l 0.05 NE 1 0.01 <0.1 <0.1 <0.1 <0.1 NT NO ND I 2 0.01 NO NO ND ND ND ND ND
3 0.01 <0.1 ND <0.1 ND ND ND I
4 0.01 NO NO NO NO NO NO NO
Cobalt mg/l NE NE 1 0.01 <0.05 0.06 <0.05 NO NT NO NO
2 0.01 0.01 0.1 0.02 ND NO NO NO
3 0.01 NO <0.05 NO NO NO NO I
4 0.01 NO 0.12 <0.1 NO NO NO NO
Copper mg/l 1 NE 1 0.01 0.06 0.1 0.08 0.02 NT NO NO
2 0.01 0.03 0.15 0.06 0.03 0.02 NO NO
3 0.01 0.04 0.15 0.09 0.04 0.02 NO I
4 0.01 0.02 0.10 <0.1 0.01 0.02 NO NO
Lead mg/l 0.05 NE 1 0.005 <0.3 <0.5 <0.3 <0.1 NT <0.01 <0.01 2 0.005 <0.03 0.2 <0.05 <0.05 <0.001 <0.001 NO
3 0.005 NO 0.08 0.04 NO 0.01 NO I
4 0.005 0.008 0.1 0.04 0.006 0.01 NO NO
Mercury mg/l 0.002 NE 1 0.001 NA NA NA NA NA NA NA
2 0.001 NO NO NO NO NO NO NO
3 0.001 NO NO NO NO NO NO I
4 0.001 NO NO NO NO NO NO NO
Mol ylxlellllll mg/l NE NE 1 0.1 <0.5 <0.5 <0.5 NO NT NO <0.05 2 0.1 NO <1 0.4 0.1 0.1 NO NO
3 0.1 NO <0.5 0.8 NO NO NO I
4 0.1 NO NO 0.9 NO NO NO NO
Nickel mg/l NE NE 1 0.01 <0.05 <0.05 0.05 NO NT NO NO
2 0.01 0.01 0.2 0.02 0.02 NO NO NO
3 0.01 NO <0.05 <0.05 NO NO NO I
4 0.01 NO 0.06 <0.1 NO NO NO NO
Selenilln mg/l 0.01 NE 1 0.005 NA NA NA NA NT NA NA
2 0.005 <0.05 <0.1 <0.01 NO NO NO NO
3 0.005 <0.05 <0.05 <0.05 <0.05 <0.01 NO I
4 0.005 NO NO <0.05 <0.025 <0.025 NO NO
-~~
------- -- --------~ ------------ L_ ___ - ~ -- ,_ - --~- - MPM1.XLS2
TABLE 4 (CONITINUEO)
Silver mg/l 0.05 NE 1 0.01
2 0.01
3 0.01
4 0.01
Thall il.lll mg/l NE NE 1 0.1
2 0.1
3 0.1
4 0.1
Vanadil.lll mg/l NE NE 1 0.1
2 0.1
3 0.1
4 0.1
Zinc mg/l 5 NE 1 0.01
2 0.01
3 0.01
4 0.01
NOTES:
NT- Not tested; The monitoring well was not installed at the time of sampling.
NA - Not analyzed. .
I - Invalid travel blank; Sample improperly prepared by the laboratory.
ND- Not detected; The analyte was not detected at or above the stated detection limit.
NE -Not established.
Date of collection:
1 - First quarter (10/19/88).
2 - Second quarter (01/31/89).
3 - Third quarter (05/03/89).
4 - Fourth quarter (09/06/89).
<0.05 <0.05
NO <0.05
NO <0.05
ND NO
0.6 1.5
0.2 2
0.6 1.5
0.2 1
<0.5 <0.5
NA NA
NA NA
NA NA
<0.05 <0.05
0.02 0.05
0.01 <0.05
NO 0.05
<0.05 <0.05 NT NO NO
NO NO NO NO NO
<0.05 NO NO NO I
NO NO NO NO NO
0.8 0.2 NT ND <0.05
0.3 0.1 0.1 NO NO
0.9 0.7 0.5 0.01 I
0.5 0.2 NO ND NO
<0.5 NO NT NO <0.05
NA NA NA NA NA
NA NA NA NA NA
NA NA NA NA NA
<0.05 <0.05 NT NO NO
0.08 0.01 0.02 0.02 0.01
0.09 NO 0.01 0.01 I
<0.1 0.01 0.02 0.01 0.01
---- --
MPM1.XLS3
DRINKING WATER STATE ACTION
ANALYSIS UNITS STANDARD LEVEL
Acetone ug/l NE NE
Acrolein Ug/l NE NE
Acrylonitrile ug/l NE NE
Benzene Ug/l 1 0.7
Bromodichloromethane ug/l 100 NE
TABLE 5
SUMMARY OF GROUND-~ft.ER CHEMISTRY
PURGEABLE HALOCARBONS AND AROMATICS
BIXBY RANCH CO.-MARKET PLACE LANDFILL
PROJECT NO. 240827
DATE OF
COLLECTION
DETECTION
LIMIT MP-1 MP-2
1 1 3.9 ND
2 10 98 ND
3 50 ND ND
4 0.5 ND ND
1 NA NA NA
2 NA NA NA
3 5 ND ND
4 0.5 ND ND
1 NA NA NA
2 NA NA NA
3 5 ND ND
4 0.5 ND NO
1 0.5 ND ND
2 0.5 ND ND
3 5 NO ND
4 0.5 ND ND
1 0.5 ND ND
2 0.5 NO NO
3 5 NO NO
4 0.5 NO NO
·~
FIELD TRAVEL
MP-3 MP-4 MP-5 BLANK BLANK
2 ND NT ND ND '
130 ND ND ND ND
ND ND ND ND ND
ND ND ND ND ND
NA NA NT NA NA
NA NA NA NA NA
ND NO ND ND NO
I NO ND NO NO ND
NA NA NT NA NA
NA NA NA NA NA
ND ND ND NO ND
ND ND NO NO ND
800 ND NT ND ND
220 ND ND ND ND
360 ND ND NO ND
310 ND NO ND NO
ND NO NT NO NO
NO NO NO NO ND
NO NO NO NO NO
NO NO NO NO NO
MPP1.XLS1
TABLE 5 (CoNTINUED)
Bromoform ug/l 100 NE 1 0.5
2 0.5
3 5
4 0.5
Bromomethane ug/l NE NE 1 0.5
2 0.5
3 5
4 0.5
Carbon Tetrachloride ug/l 0.5 0.5. 1 0.5
2 0.5
3 5
4 0.5
Chlorobenzene ug/l 30 30 1 0.5
2 0.5
3 5
4 0.5
Chloroethane ug/l NE NE 1 0.5
2 0.5
3 5
4 0.5
2-Chloroethylvinyl ether ug/l NE NE 1 1.00
2 1.00
3 5
4 0.5
Chloroform ug/l 100 NE 1 0.5
2 0.5
3 5
4 0.5
Chloromethane ug/l NE NE 1 0.5
2 0.5
3 5
4 0.5
ND ND ND ND
ND ND ND ND
NO NO NO NO
NO NO ND ND
NO NO NO NO
NO NO NO ND
ND NO NO NO
ND ND ND NO
ND ND ND ND
NO NO ND ND
ND ND ND NO
ND ND ND ND
ND ND ND ND
NO ND NO NO
NO NO NO ND
NO NO NO ND
ND NO NO ND
NO NO ND NO
NO NO NO ND
NO NO NO NO
NO NO NO NO
NO NO NO NO
NO NO NO NO
NO NO NO NO
NO NO NO NO
NO NO NO NO
NO NO NO NO
NO NO NO NO
NO NO NO NO
NO NO NO NO
NO NO NO NO
NO NO NO NO
NT NO
NO NO
NO NO
NO NO
NT NO
NO NO
NO ND
ND NO
NT ND
ND NO
ND ND
NO ND
NT ND
NO NO
NO NO
NO NO
NT ND
NO NO
NO ND
NO NO
NT NO
NO NO
NO NO
NO NO
NT NO
NO NO
NO NO
NO NO
NT NO
NO NO
NO NO
NO NO
l
) __ /
NO
NO
NO
ND
NO
NO
NO
ND
NO
NO
ND
ND
ND
NO
NO
NO
NO
ND
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
MPP1.XLS2
~
TABLE 5 (CONTINUED)
Dibromochloromethane ug/l 100 NE 1 0.5 NO NO NO NO NT NO NO 2 0.5 NO NO NO NO NO NO NO
3 5 NO NO NO NO NO NO NO
4 0.5 NO NO NO NO NO NO NO
1,2-Dichlorobenzene ug/l 130 130 1 0.5 NO ND ND ND NT ND ND 2 0.5 ND ND ND ND ND ND ND
3 5 ND ND ND ND ND ND ND
4 0.5 NO NO ND ND ND ND NO
1,3-Dichlorobenzene ug/l 130 130 1 0.5 ND ND ND NO NT ND NO 2 0.5 ND ND ND ND ND ND ND
3 5 ND ND ND ND ND ND ND
4 0.5 ND ND ND ND ND ND ND
1,4-Dichlorobenzene ug/l 5 0.5 1 0.5 ND ND ND ND NT ND ND 2 0.5 ND ND ND ND ND ND ND
3 5 ND ND ND ND ND ND NO
4 0.5 ND ND ND ND ND ND ND
1,1-Dichloroethane ug/l NE 5 1 0.5 NO ND ND ND NT ND NO 2 0.5 ND ND ND ND ND ND ND
3 5 NO ND ND ND ND ND ND
4 0.5 ND ND ND ND ND ND ND
1,2-Dichloroethane ug/l 0.5 0.5 1 0.5 ND ND ND NO NT ND ND 2 0.5 NO ND ND NO ND ND ND
3 5 ND ND ND ND ND ND ND
4 0.5 ND ND ND ND ND ND ND i
I
1,1-Dichloroethene ug/l NE NE 1 0.2 ND ND ND ND NT ND ND 2 0.5 ND ND ND ND ND ND ND
3 5 ND ND ND ND ND ND ND
4 0.5 ND ND ND ND ND ND NO I
trans-1,2-Dichloroethene Ug/l NE 10 1 0.5 NO NO NO NO NT NO NO 2 0.5 ND ND NO ND ND NO ND
3 5 ND NO NO ND ND ND NO
4 0.5 ND ND 0.6 NO ND ND ND
MPP1.XLS3
TABLE 5 (CONTINUED)
,4)/
"
Ethyl benzene Ug/l 680 680 1 0.5 NO
2 0.5 NO
3 5 NO
4 0.5 NO
Methylene chloride Ug/L NE 40 1 0.5 NO
2 0.5 NO
3 5 NO
4 0.5 NO
Methyl Ethyl Ketone Ug/L NE NE 1 5 NO
2 5 42
3 5 NO
4 0.5 NO
Methyl Isobutyl Ketone Ug/l NE NE 1 5 7.4
2 5 NO
3 5 NO
4 0.5 NO
1,1,2,2-Tetrachloroethane Ug/L 1 NE 1 0.5 NO
2 0.5 NO
3 5 NO
4 0.5 NO
Tetrachloroethene ug/L NE 5 1 0.5 NO
2 0.5 NO
3 5 NO
4 0.5 NO
Toluene ug/l NE 100 1 0.5 NO
2 0.5 NO
3 5 NO
4 0.5 NO
1,1,1-Trichloroethane ug/L 200 200 1 0.5 NO
2 0.5 NO
3 5 NO
4 0.5 NO
~I
0 )4ff
~--
NO
NO
NO
NO
NO
NO
NO
NO
9.4 NO
NO
NO
13.4 NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
)
JQ
100
20 11
18 NO
NO
NO
NO
8.4 NO
NO
NO
26 8.4
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
3.1 10
NO
NO
NO
NO
NO
NO
Lf
!./'()
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
~
/ J/l IJ : .... ...-~!.!"" f
NT NO NO
NO NO NO
NO NO NO
NO NO NO
NT NO NO
NO NO NO
NO NO NO
NO NO NO
NT NO NO
NO NO NO
NO NO NO
NO NO NO
NT NO NO
NO NO NO L
NO NO NO
NO NO NO
NT NO NO
NO NO NO ' I
NO NO NO
NO NO NO
NT NO NO I
NO NO NO
NO NO NO
NO NO NO
NT NO NO
NO NO NO
NO NO NO
NO NO NO
NT NO NO
NO NO NO
I NO NO NO
NO NO NO
,...--
MPP1.XLS4
'
TABLE 5 (CoNTINUED)
1,1,2-Trichloroethane ug/l 32 100 1 0.5
2 0.5
3 5
4 0.5
Trichlorofluoromethane ug/1 NE 150 1 0.5
2 0.5
3 5
4 0.5
Vinyl chloride ug/1 0.5 2 1 1
2 1
3 5
4 0.5
Xylene(s) ug/1 1750 620 1 0.5
2 0.5
3 5
4 0.5
NOTES:
NT - Not tested; The monitoring well was not installed at the time of sampling.
NA - Not analyzed. ·
NO- Not detected; The analyte was not detected at or above the stated detection limit.
NE- Not established.
Date of collection:
1 - First quarter (10/19/88).
2 - Second quarter (01/31/89).
3 - Third quarter (05/03/89).
4 - Forth quarter (09/06/89).
NO
NO
NO
NO
ND
ND
ND
NO
NO
NO
ND
NO
ND
NO
NO
NO
,-1
; -______ ,..-.
NO NO NO NT NO NO
NO NO NO NO NO NO
NO NO NO NO NO NO
NO NO NO NO NO NO
ND ND ·No NT NO NO
NO ND NO NO NO NO
NO ND ND NO NO NO
NO ND NO ND ND NO
NO NO ND NT ND NO
NO NO NO NO NO NO
NO NO ND ND NO ND
NO NO NO NO NO NO
NO NO NO NT NO NO
NO 3.8 NO NO NO NO
NO NO NO NO NO NO
NO NO NO NO NO NO
MPP1.XLS5
I
ANAlYSIS
Acenaphthene
Acenaphthylene
Anthracene
Aldrin
Benzo(a)anthracene
Benzo(b)anthracene
~_______.---
TABlE 6
SUMMARY OF GROUND-~ATER CHEMISTRY
BASE/NEUTRAL AND ACID EXTRACTABlE ORGANIC COMPOUNDS
BIXBY RANCH CO.-MARKET PlACE lANDFill
PROJECT NO. 240827
DRINKING ~ATER STATE ACTION DATE OF DETECTION
UNITS STANDARD lEVEl COllECTION liMIT MP-1 MP-2 MP-3
-- -- - -- --
ug/l NE NE 1 10.00 NO NO NO
2 5.00 NO NO NO
3 5.00 NO NO NO
4 5.00 NO NO NO
ug/l NE NE 1 10.00 NO NO NO
2 5.00 NO NO NO
3 5.00 NO NO NO
4 5.00 NO NO NO
ug/L 0.7 0.7 1 10.00 NO NO NO
2 5.00 NO NO NO
3 5.00 NO NO NO
4 5.00 NO NO NO
ug/l 0.05 0.05 1 10.00 NO NO NO
2 0.01 NO NO NO
3 0.01 NO NO NO
4 0.01 NO NO NO
ug/l NE NE 1 10.00 NO NO NO
2 10.00 NO NO NO
3 10.00 NO NO NO
4 10.00 NO NO NO
ug/l NE NE 1 10.00 NO NO NO
2 10.00 NO NO NO
3 10.00 NO NO NO
4 10.00 NO NO NO
MP-4 MP-5
NO NT
NO NO
NO NO
NO NO
NO NT
NO NO
NO NO
NO NO
NO NT
NO NO
NO NO
NO NO
NO NT
NO NO
NO NO
NO NO
NO NT
NO NO
NO NO
NO NO
NO NT
NO NO
NO NO
NO NO
FIELD TRAVEl
BlANK BlANK
NO NO
NO NO
NO NO
NO NO
NO NO
NO NO
NO NO
NO NO
NO NO
NO NO
NO NO
NO NO
NO NO
NO NO
NO NO
NO NO
NO NO
NO NO
NO NO
NO NO
NO NO
NO NO
NO NO
NO NO
MPBA1.XLS1
')
~----------:;
TABLE 6 (CONTINUED)
Benzo(k)anthracene ug/l NE NE 1 10.00 NO NO NO NO NT NO NO 2 10.00 NO NO NO NO NO NO NO
3 10.00 NO NO NO NO NO NO NO
4 10.00 NO NO NO NO NO NO NO
Benzo(k)pyrene ug/l NE NE 1 10.00 NO NO NO NO NT NO NO
2 10.00 NO NO NO NO NO NO NO
3 10.00 NO NO NO NO NO NO NO
4 10.00 NO NO NO
I
NO NO NO NO
Benzo(ghi)perylene ug/l NE NE 1 10.00 NO NO NO NO NT NO NO 2 10.00 NO NO NO NO NO NO NO
3 10.00 NO NO NO NO NO NO NO
4 10.00 NO NO NO NO NO NO NO I
i
Benzyl butyl phthalate ug/l NE NE 1 10.00 NO NO NO NO NT NO NO I 2 10.00 NO NO NO NO NO NO NO
3 10.00 NO NO NO NO NO NO NO
4 10.00 NO NO NO NO NO NO NO
beta-BHC ug/l NE 0.3 1 10.00 NO NO NO NO NT NO NO
2 0.05 NO NO NO NO NO NO NO
3 0.05 NO NO NO NO NO NO NO
4 0.05 NO NO NO NO NO NO NO
delta-BHC ug/l NE NE 1 10.00 NO NO NO NO NT NO NO
2 0.05 NO NO 0.33 NO 0.06 NO NO
3 0.05 NO NO NO NO NO NO NO
4 0.05 NO NO NO NO NO NO NO
Bis(2-chloroethyl)ether ug/l NE NE 1 10.00 NO NO NO NO NT NO NO 2 5.00. NO NO NO NO NO NO NO
3 5.00 NO NO NO NO NO NO NO
4 5.00 NO NO NO NO NO NO NO
Bis(2-chloroethoxy)methane ug/l NE NE 1 10.00 NO NO NO NO NT NO NO I
2 5.00 NO NO NO NO NO NO NO
3 5.00 NO NO NO NO NO NO NO
4 5.00 NO NO NO NO NO NO NO
~
----·-
MPBA1.XLS2
_._j -~-
TABLE 6 (CONTINUED)
Bis(2-ethylhexyl)phthalate Ug/l NE NE 1 10.00 NO NO 30 NO NT NO NO 2 5.00 NO 8.5 21 NO NO . NO NO
3 5.00 14 NO 42 7.8 NO NO NO
4 5.00 NO NO NO NO NO NO NO
Bis(Z-chloroisopropyl)ether ug~l NE NE 1 10.00 NO NO NO NO NT NO NO z 5.00 NO NO NO NO NO NO NO
3 5.00 NO NO NO NO NO NO NO
4 5.00 NO NO NO NO NO NO NO
4-Bromophenyl phenyl ether ug/l NE NE 1 10.00 NO NO NO NO NT NO NO 2 5.00 NO NO NO NO NO NO NO
3 5.00 NO NO NO NO NO NO NO
4 5.00 NO NO NO NO NO NO NO
Chlordane ug/L NE 0.1 1 10.00 NO NO NO NO NT NO NO
z 0.05 NO NO NO NO NO NO NO
3 0.05 NO NO NO NO NO NO NO
4 0.05 NO NO NO NO NO NO NO
Z-Chloronapthalene ug/l NE NE 1 10.00 NO NO NO NO NT NO NO z 5.00 NO NO NO NO NO NO NO
3 5.00 NO NO NO NO NO NO NO
4 5.00 NO NO NO NO NO NO NO
4-Chlorophenyl phenyl ether ug/L NE NE 1 10.00 NO NO NO NO NT NO NO z 5.00 NO NO NO NO NO NO NO
3 5.00 NO NO NO NO NO NO NO
4 5.00 NO NO NO NO NO NO NO
Chrysene ug/L NE NE 1 10.00 NO NO NO NO NT NO NO
z 5.00 NO NO NO NO NO NO NO
3 5.00 NO NO NO NO NO NO NO
4 5.00 NO NO NO NO NO NO NO
4,4•-ooo Ug/l NE NE 1 10.00 NO NO NO NO NT NO ND
2 0.02 NO NO NO NO NO NO NO
3 0.02 NO NO NO NO NO NO NO
4 0.02 NO NO NO NO NO NO NO
... -------- ----- --·- --------- -· -- --- --- --- ---- MPBA1.XLS3
'
-~- -·--·-
TABLE 6 (CONTINUED)
4-4'-DDE Ug/l NE NE 1 10.00 NO NO NO NO NT NO NO
2 0.01 NO 0.03 NO NO NO NO NO
3 0.01 NO 0.02 NO NO NO NO NO
4 0.01 NO NO NO NO NO NO NO
4,4 1 -00T ug/l NE NE 1 10.00 NO NO NO NO NT NO NO
2 0.02 NO NO NO NO NO NO NO
3 0.02 NO NO NO NO NO NO NO
4 0.02 NO NO 0.07 NO NO NO NO
Oibenzo(a,h)anthracene ug/l NE NE .1 10.00 NO NO NO NO NT NO NO 2 5.00 NO NO NO NO NO NO NO
3 5.00 NO NO NO NO NO NO NO
4 5.00 NO NO NO NO NO NO NO
Oi-n-butylphthalate ug/l NE NE 1 10.00 NO NO NO NO NT NO NO 2 5.00 NO NO NO NO NO NO NO
3 5.00 NO NO NO NO NO NO 14
4 5.00 NO NO NO NO NO NO NO
1,3-0ichlorobenzene ug/l NE 130 1 10.00 NO NO NO NO NT NO NO 2 0.50 NO NO NO NO NO NO NO
3 0.50 NO NO NO NO NO NO NO
4 0.50 NO NO NO NO NO NO NO
1,2-0ichlorobenzene ug/l NE 130 1 10.00 NO NO NO NO NT NO NO 2 0.50 NO NO NO NO NO NO NO
3 0.50 NO NO NO NO NO NO NO
4 0.50 NO NO NO NO NO NO NO
1,4-0ichlorobenzene ug/l 5 5 1 10.00 NO NO NO NO NT NO NO 2 0.50 NO NO NO NO NO NO NO
3 0.50 NO NO NO NO NO NO NO
4 0.50 NO NO NO NO NO NO NO
3-3•-0ichlorobenzidine ug/l NE NE 1 10.00 NO NO NO NO NT NO NO 2 20.00 NO NO NO NO NO NO NO
3 20.00 NO NO NO NO NO NO NO
4 20.00 NO NO NO NO NO NO NO
MPBA1.XLS4
.~~ ~.,
",_. TABLE 6 -(cONTINUED)
Dieldrin ug/l NE 0.05 1 10.00 NO NO NO NO NT NO NO
2 0.50 NO NO NO NO NO NO NO
3 0.50 NO NO NO NO NO NO NO
4 0.50 NO NO NO NO NO NO NO
Diethyl phthalate ug/l NE NE 1 10.00 NO NO NO NO NT NO NO 2 5.00 NO NO NO NO NO NO NO
3 5.00 NO NO NO NO NO NO NO
4 5.00 NO NO NO NO NO NO NO
Dimethyl phthalate ug/l NE NE 1 10.00 NO NO NO NO NT NO NO ! 2 5.00 NO NO NO NO NO NO NO
3 5.00 NO NO NO NO NO NO NO
4 5.00 NO NO NO NO NO NO NO
2,4-Dinitrotoluene ug/l NE NE 1 10.00 NO NO NO NO NT NO NO 2 5.00 NO NO NO NO NO NO NO
3 5.00 NO NO NO NO NO NO NO
4 5.00 NO NO NO NO NO NO NO
2,6-Dinitrotoluene ug/l NE NE 1 10.00 NO NO NO NO NT NO NO 2 5.00 NO NO NO NO NO NO NO
3 5.00 NO NO NO NO NO NO NO
4 5.00 NO NO NO NO NO NO NO
Di-n-octylphthalate ug/l NE NE 1 10.00 NO NO 66 NO NT NO ND 2 5.00 NO NO NO NO NO NO NO
3 5.00 NO NO NO NO NO NO NO
4 5.00 NO ND NO NO NO NO ND
Endosulfan sulfate ug/l NE NE 1 10.00 NO NO NO NO NT NO NO 2 0.05 NO NO NO NO NO NO ND
3 0.05 NO NO NO NO NO NO ND
4 0.05 NO NO NO NO NO NO NO
Endrin aldehyde ug/l NE NE 1 10.00 NO NO NO NO NT ND NO 2 0.05 NO NO NO NO ND NO ND
3 0.05 NO NO NO NO ND NO NO
4 0.05 NO ND NO NO NO NO NO
MPBA1.XLS5
\ ____ /
Fluoroanthene ug/l NE
Fluorene ug/l NE
Heptachlor ug/l NE
Heptachlor epoxide ug/l NE
Hexachlorobenzene ug/l NE
Hexachlorobutadiene ug/l NE
Hexachloroethane ug/l NE
ldeno(1,2,3-cd) pyrene ug/l NE
- ---- -- - ---
NE
NE
0.01 0.01
NE
NE
NE
NE
-------------
~
TABLE 6 (CONTINUED)
1 10.00
2 5.00
3 5.00
4 5.00
1 10.00
2 5.00
3 5.00
4 5.00
1 10.00
2 0.02
3 0.02
4 0.02
1 10.00
2 0.10
3 0.01
4 0.01
1 10.00
2 5.00
3 5.00
4 5.00
1 10.00
2 5.00
3 5.00
4 5.00
1 10.00
2 5.00
3 5.00
4 5.00
1 10.00
2 10.00
3 10.00
4 10.00
----- --------
NO NO NO NO NT NO NO
NO NO NO NO NO NO NO
NO NO NO NO NO NO NO
NO NO NO NO NO NO NO
NO NO NO NO NT NO NO
NO NO NO NO NO NO NO
NO NO NO NO NO NO NO
NO NO NO NO NO NO NO
NO NO NO NO NT NO NO
NO NO NO NO NO NO NO
NO NO NO NO NO NO NO
NO 0.02 10 NO NO NO NO
NO NO NO NO NT NO NO
NO NO NO NO NO NO NO
NO NO NO NO NO NO NO
NO NO NO NO NO NO NO
NO NO NO NO NT NO NO
NO NO NO NO NO NO NO
NO NO NO NO NO NO NO
NO NO NO NO NO NO NO
NO NO NO NO NT NO NO
NO NO NO NO NO NO NO
NO NO NO NO NO NO NO
NO NO NO NO NO NO NO
NO NO NO NO NT NO NO
I
NO NO NO NO NO NO NO
NO NO NO NO NO NO NO
NO NO NO NO NO NO NO
NO NO NO NO NT NO NO
NO NO NO NO NO NO NO
NO NO NO NO NO NO NO
NO NO NO NO NO NO NO
-- --- ---- --- -
MPBA1.XLS6
\
'----~ ,'
___ /
TABLE 6 (CONTINUED)
lsophrone Ug/l NE NE 1 10.00 NO NO NO NO NT NO NO
2 10.00 NO NO NO NO NO NO NO
3 10.00 NO NO NO NO NO NO NO
4 10.00 NO NO NO NO NO ND NO
Napthalene ug/L NE NE 1 10.00 NO NO NO NO NT NO NO
2 5.00 NO NO NO NO NO NO NO
3 5.00 NO NO NO NO NO NO NO
4 5.00 NO NO NO NO NO NO NO
Nitrobenzene ug/L NE NE 1 10.00 NO NO NO NO NT NO NO
2 5.00 NO NO NO NO NO NO NO
3 5.00 NO NO NO NO NO NO NO
4 5.00 NO NO NO NO NO NO NO
N-Nitrosodi-n-propylamine ug/L NE NE 1 10.00 NO NO NO NO NT NO NO 2 5.00 NO NO NO NO NO NO NO
3 5.00 NO NO NO NO NO NO NO
4 5.00 NO NO NO NO NO NO NO
PCB-1016 ug/l NE NE 1 10.00 NO NO NO NO NT NO NO
2 0.02 NO NO NO NO NO NO NO
3 0.02 NO NO NO NO NO NO NO
4 0.02 NO NO NO NO NO NO NO
PCB-1221 UQ/L NE NE 1 10.00 NO NO NO NO NT NO NO
2 0.02 NO NO NO NO NO NO NO
3 0.02 NO NO NO NO NO NO NO
4 0.02 NO NO NO NO NO NO NO
PCB-1232 ug/L NE NE 1 10.00 NO NO NO NO NT NO NO
2 0.02 NO NO NO NO NO NO NO
3 0.02 NO NO NO NO NO NO NO
4 0.02 NO NO NO NO NO NO NO
PCB-1242 UQ/l NE NE 1 10.00 NO NO NO NO NT NO NO
2 0.02 NO NO NO NO NO NO NO
3 0.02 NO NO NO NO NO NO NO
4 0.02 NO NO NO NO NO NO NO
-~ ----- L__~~
MPBA1.XLS7
~ '--/
TABLE 6 (CONTINUED)
PCB-1248 ug/l NE NE 1 10.00 NO NO NO NO NT NO NO
2 0.20 NO NO NO NO NO NO NO
3 0.02 NO NO NO NO NO NO NO
4" 0.02 NO NO NO NO NO NO NO
PCB-1254 ug/l NE NE 1 10.00 NO NO · NO NO NT NO NO
2 0.20 NO NO NO NO NO NO NO
3 0.02 NO NO NO NO NO NO NO
4 0.02 NO NO NO NO NO NO NO
PCB-1260 ug/l NE NE 1 10.00 NO NO NO NO NT NO NO
2 0.20 NO NO NO NO NO NO NO
3 0.20 NO NO NO NO NO NO NO
I 4 0.20 NO NO NO NO NO NO NO
Phenanthrene ug/l NE NE 1 10.00 NO NO NO NO NT NO NO
I
I
2 5.00 NO NO NO NO NO NO NO
3 5.00 NO NO NO NO NO NO NO
4 5.00 NO NO NO NO NO NO NO
Pyrene ug/l NE NE 1 10.00 NO NO NO NO NT NO NO
2 5.00 NO NO NO NO NO NO NO
3 5.00 NO NO NO NO NO NO NO
4 5.00 NO NO NO NO NO NO NO
Toxaphene ug/l 5 5 1 10.00 NO NO NO NO NT NO NO
2 0.05 NO NO NO NO NO NO NO
3 0.05 NO NO NO NO NO NO NO
4 0.05 NO NO NO NO NO NO NO
1,2,4-Trichlorobenzene ug/l NE NE 1 10.00 NO NO NO NO NT NO NO 2 5.00 NO NO NO NO NO NO NO
3 5.00 NO NO NO NO NO NO NO
4 5.00 NO NO NO NO NO NO NO
4-Chloro-3-methylphenol ug/l NE NE 1 10.00 NO NO NO NO NT NO NO 2 5.00 NO NO NO NO NO NO NO
3 5.00 NO NO NO NO NO NO NO
4 5.00 NO NO NO NO NO NO NO
MPBA1.XLS8
2-Chlorophenol ug/l NE NE
2,4-Dichlorophenol ug/l NE NE
2,4-Dimethylphenol ug/l NE NE
2,4-Dinitrophenol ug/l NE NE
2-Methyl-4,6-dinitrophenol ug/l NE NE
2-Nitrophenol ug/l NE NE
'.,
4-Nitrophenol ug/l NE NE
Pentachlorophenol ug/l NE 30
-~/
TABLE 6 (CONTINUED)
1 10.00
2 5.00
3 5.00
4 5.00
1 10.00
2 5.00
3 5.00
4 5.00
1 10.00
2 5.00
3 5.00
4 5.00
1 10.00
2 5.00
3 5.00
4 5.00
1 10.00
2 5.00
3 5.00
4 5.00
1 10.00
2 5.00
3 5.00
4 5.00
1 10.00
2 5.00
3 5.00
4 5.00
1 10.00
2 0.50
3 0.50
4 0.50
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
ND
NO
ND
NO
NO
NO
NO
NO
NO
NO
NO NO NO
NO . NO NO
NO NO NO
NO NO NO
NO NO NO
NO NO NO
NO NO NO
NO NO NO
NO NO NO
NO NO NO
NO NO NO
NO NO NO
NO NO NO
NO NO NO
NO NO NO
NO NO NO
NO NO NO
NO NO NO
NO NO NO
NO NO NO
NO NO NO
NO NO NO
ND NO ND
ND NO ND
NO ND NO
NO NO NO
NO NO NO
NO NO NO
NO NO NO
NO NO NO
ND NO NO
NO NO NO
NT NO
NO NO
NO NO
NO NO
NT NO
NO NO
NO NO
NO NO
NT NO
NO NO
NO NO
NO NO
NT NO
NO NO
NO NO
NO NO
NT NO
NO NO
NO NO
NO NO
NT NO
ND NO
ND NO
ND NO
NT NO
NO NO
NO NO
NO NO
NT NO
ND NO
ND NO
NO NO
1 '-J
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
ND
ND
ND
NO
NO
NO
NO
NO
ND
ND
ND
I
I
HPBA1.XLS9
~-
1 '----'' ''---'/
TABLE 6 (CONTINUED)
Phenol ug/l NE NE 1 10.00 NO NO NO NO NT NO NO
2 5.00 NO NO NO NO NO NO NO
3 5.00 NO NO NO NO NO NO NO
4 5.00 NO NO NO NO NO NO NO
2,4,6-Trichlorophenol ug/l NE NE 1 10.00 NO NO NO NO NT NO NO 2 5.00 NO NO NO NO NO NO NO
3 5.00 NO NO NO NO NO NO NO
4 5.00 NO NO NO NO NO NO NO
Benzidine ug/l NE NE 1 10.00 NO NO NO NO NT NO NO
2 5.00 NO NO NO NO NO NO NO
3 5.00 NO NO NO NO NO NO NO
4 5.00 NO NO NO NO NO NO NO
alpha-BHC ug/l NE NE 1 10.00 NO NO NO NO NT NO NO
2 0.01 NO 0.03 0.04 NO 0.02 NO- NO
3 0.01 NO NO NO NO NO NO NO
4 0.01 NO NO NO NO NO NO NO
ganma-BHC ug/l 4 4 1 10.00 NO NO NO NO NT NO NO
2 0.01 0.02 NO 0.04 NO NO NO NO
3 0.01 NO NO NO NO NO NO NO
4 0.01 NO NO NO NO NO NO NO
Endosulfan I ug/l NE NE 1 10.00 NO NO NO NO NT NO NO
2 0.01 NO NO NO NO NO NO NO
3 0.01 NO NO NO 0.01 NO NO NO
4 0.01 NO NO NO NO NO NO NO
Endosulfan II ug/l NE NE 1 10.00 NO NO NO NO NT NO NO
2 0.01 NO NO NO NO NO NO NO
3 0.01 NO NO NO NO NO NO NO
4 0.01 NO NO NO NO NO NO NO
Enclrin ug/l 0.2 NE 1 10.00 NO NO NO NO NT NO NO
2 0.01 NO NO NO NO NO NO NO
3 0.01 NO NO NO NO NO NO NO
4 0.01 NO NO NO NO NO NO NO
MPBA1.XLS10
''---- '--
TABLE 6 (CONTINUED)
Hexachlorocyclopentadiene Ug/l NE NE 1
.2
3 4
N-Nitrosodimethylamine ug/L NE NE 1
2 3
4 N-Nitrosodiphenylamine ug/L NE NE 1
2 3
4 -------
NOTES:
NT - Not tested; The monitoring well was not installed at the time of sampling.
NA - Not analyzed.
10.00 20.00
20.00 20.00
10.00 5.00
5.00 5.00
10.00 5.00
5.00 5.00
NO - Not detected; The analyte was not detected at or above the stated detection limit.
NE- Not established.
Date of collection:
1 - First quarter (10/19/88).
2 - Second quarter (01/31/89).
3 - Third quarter (05/03/89).
4 - Forth quarter (09/06/89).
NO NO
NO NO
NO NO
NO NO
NO NO
NO NO
NO NO
NO NO
NO NO
NO NO
NO NO
NO NO
.. ,
)
'-._____/
NO NO NT NO NO
NO NO NO NO NO
NO NO NO NO NO
NO NO NO NO NO
NO NO NT NO NO
NO NO NO NO NO
NO NO NO NO NO
NO NO NO NO NO
NO NO NT NO NO
NO NO NO NO NO
NO NO NO NO NO
NO NO NO NO NO
MPBA1.XLS11
FIGURES
~
SITE~
SCALE
0 2000 4000 FEET
REFERENCE:
USGS 7.5 MINUTE TOPOGRAPHIC MAP OF
LONG BEACH, LOS ALAMITOS AND SEAL BEACH,
CALIFORNIA QUADRANGLE; DATE: 1964,1964 AND
FIGURE
TOPOGRAPHIC MAP
MARKET PLACE LANDFILL
PREPARED FOR
BIXBY RANCH COMPANY
SEAL BEACH, CALIFORNIA
1965 RESPECTIVELY; PHOTOREVISED= 1981; SCALE 1=24000 rn ... Creating a Safer Tomorrow L__n-,-,N-,-,,-S-c-ei_P_T_h>_S_n-,,,-W-Ir1-Q--------------------------------------------------------------------------~ ~ L{')
<t:
I
1'
C\J
co
0 '¢
C\J
LEGEND
-5-- TOPOGRAPHIC CONTOUR
SWAT MONITORING WELL
SCALE
r-----,
0 600 1200 FEET
REFERENCE:
BASE MAP- CITY OF LONG BEACH, DEPARTMENT
OF ENGINEERING, 1978 THROUGH 1982.
FOR TOPOGRAPHIC REFERENCE, SEE FIGURE I.
··oo Not Scale Th1S Draw1ng ..
FIGURE 2
DETAILED TOPOGRAPHIC MAP OF
MARKET PLACE LANDFILL
PREPARED FOR
BIXBY RANCH COMPANY
SEAL BEACH, CALIFORNIA
+
rn ... Creating a Safer Tomorrow
(()
<!
I
1'-
C\J
(l)
0 <;t
C\J
~
' ' .. ;/
LEGEND:
MP-1@ SWAT MONITORING WELL
(2.20) GROUND-WATER ELEVATION
(FEET ABOVE MEAN SEA LEVEL)
./7 GROUND-WATER ELEVATION
1.0_... / CONTOUR (FEET ABOVE MEAN SEA LEVEL)
~DIRECTION OF GROUND-WATER FLOW
S C A L E
0 REFERENCE:
200 400 FEET
B.~SE MAP-CITY OF LONG BEACH, DEPARTMENT
OF ENGINEERING, 1978 THROUGH 1982.
_____....-APPROXIMATE
LANDFILL.
BOUNDARY
/
FlGURE 3
GROUND-WATER ELEVATION
CONTOUR MAP FOR
10/19/88
MARKET PLACE LANDFILL
PREPARED FOR
BIXBY RANCH COMPANY
SEAL BEACH, CALIFORNIA
rn
INTERNATIONAL
TECHNOLOGY
CORPORATION
/
~
...
LEGEND=
MP-1@
(2.20)
... ~··"
;..;>"
-:'.J ....
~
SWAT MONITORING WELL
GROUND-WATER ELEVATION
(FEET ABOVE MEAN SEA LEVEL)
/'?GROUND- WATER ELEVATION
1.0 ........ / CONTOUR (FEET ABOVE MEAN SEA LEVEL)
c:==::::> DIRECTION OF GROUND-WATER FLOW
S C A L E
0 REFERENCE:
200 400 FEET
BASE MAP-CITY OF LONG BEACH, DEPARTMENT
OF ENGINEERING, 1978 THROUGH 1982.
......----.-.--APPROX.I MATE
/
LANDFILL,,
BOUNDARY
Fl GURE 4
GROUND-WATER ELEVATION
CONTOUR MAP FOR
01/31/89
MARKET PLACE LANDFILL
PREPARED FOR
BIXBY RANCH COMPANY
SEAL BEACH, CALIFORNIA
[I]
INTERNATIONAL
TECHNOLOGY
CORPORATION
c.o ' ' C\J ' '
<(
I
1'-
C\J
co
0 <j"
C\J
LEGEND:
MP-1@ SWAT MONITORING WELL
(2.20) GROUND-WATER ELEVATION (FEET ABOVE MEAN
SEA LEVEL)
{\.0)-- GROUND-WATER ELEVATION CONTOUR (FEET
_.- ABOVE MEAN SEA LEVEL)
~ DIRECTION OF GROUND-WATER FLOW
S C A L E
0 REFERENCE:
200 40(' FEET
B~SE MAP-CITY OF LONG BEACH, DEPARTMENT
OF ENGINEERING, 1978 THROUGH 1982.
APPROXIMATE
LANDFILL
BOUNDARY
/
FlGURE 5
GROUND-WATER ELEVATION
CONTOUR MAP FOR
MAY 4, 1989
MARKET PLACE LANDFILL
PREPARED FOR
BIXBY RANCH COMPANY
SEAL BEACH, CALIFORNIA
rn
INTERNATIONAL
TECHNOLOGY
CORPORATION
~ :;>''
<!
I
1'
C\.J
co
0 <;t
C\.J
./
PM
/ I 1289 ~~--.;_
M-8 1"'7. P:r? f'J 'I~'
.3 (t?·h1!/; /'
d.s·
. /J'
LEGEND:
MP-1@ SWAT MONITORING WELL
(2.20) GROUND-WATER ELEVATION (FEET ABOVE
MEAN SEA LEVEL)
ll 0)-- GROUND-WATER ELEVATION CONTOUR (FEET
_.. . ABOVE MEAN SEA LEVEL)
~ DIRECTION OF GROUND-WATER FLOW
S C A L E
0 200 400 FEET
REFERENCE:
B!I.SE MAP-CITY OF LONG BEACH, DEPARTMENT
OF ENGINEERING, 1978 THROUGH 1982.
_,--------.,.-----·APPROXIMATE
LANDFILL
UNDARY
/
~f(./
'" .
7 /
.,0
o.
/
;
""
FlGURE 6
GROUND-WATER ELEVATION
CONTOUR MAP FOR
SEPTEMBER 6,1989
MARKET PLACE LANDFILL
PREPARED FOR
. BIXBY RANCH COMPANY
SEAL BEACH, CALIFORNIA
rn
INTERNATIONAL
TECHNOLOGY
CORPORATION
APPENDIX A
MONITORING WELL DEVELOPMENT,
GROUND-WATER SAMPLE COLLECTION,
AND ANALYTICAL PROCEDURES
I~
()
APPENDIX A
MONITORING WELL DEVELOPMENT, GROUND-WATER
SAMPLE COLLECTION, AND ANALYTICAL PROCEDURES
This appendix describes the field procedures for the development and sampling of the monitoring wells, as well as the analytical procedures followed. Procedures for the following activities are discussed:
• Monitoring well development
• Equipment decontamination
• Monitoring well purging and sampling
• Ground-water disposal
• Sample handling, identification, and transportation
• Equipment decontamination.
A.l MONITORING WELL DEVELOPMENT
The monitoring wells were developed using a 3-inch outside diameter stainless steel bailer, a 3.5-inch diameter surge block, and an electric submersible pump. The wells were bailed and surged to remove any sand present and to clean and tighten the sand pack around the screen. Well development continued until very low turbidity water was charging the well.
The water extracted during well development was stored in Department of Transportation (D.O.T.) approved 55-gallon drums. The drums were transported and stored at the oil field adjacent to the Bixby Market Place Sanitary Landfill. This action was taken to avoid complaints by the public concerning the presence and origin of the drums.
A.2 EQUIPMENT DECONTAMINATION
All of the development, bailing, and sampling equipment was disassembled between wells, steam-cleaned or cleaned in a solution of trisodium phosphate and water, and rinsed with deionized water.
WP: 0827R2.AP A A-1
)
j
A.3 MONITORING WELL PURGING AND SAMPLING
Following development, and at each quarterly sampling, each well was purged of at least three water-column volumes of water. The purged water was stored in drums as previously described. The pH, electrical conductivity, and temperature were continually monitored during well purging. Purging continued until the values stabilized. A stainless-steel or TeflonR bailer equipped with a removable TeflonR bottom discharge valve was lowered down the well to collect water samples for SWAT chemical analyses. Care was taken to protect the integrity of all samples and to prevent cross-contamination. The 40-milliliter bottles for volatile organic analysis (VOA) were filled completely to prevent the inclusion of air bubbles. Ground water for metals analysis was filtered in the field using 0.45-micron filter paper. Sampling personnel used inert plastic gloves, which were disposed of after each sample was collected.
A.4 DISPOSAL OF DEVELOPMENT AND PURGE WATER
Ground water removed from the wells during development and from the first and second quarter sampling was stored and transported as previously described. This water was disposed of in an adjacent storm drain following approval by the RWQCB. Ground-water from the third and fourth quarter sampling were stored and transported as has been done previously. On June 15, 1990, the ground water from the drums was removed by a vacuum truck and disposed of at a wastewater recycling facility. The drums which contained the ground water were crushed and disposed of at a drum recycling facility.
A.5 SAMPLE HANDLING, IDENTIFICATION, AND TRANSPORTATION The ground-water samples were handled, preserved, and bottled as summarized in Table A-1.
WP: 0827R2.AP A A-2
,------"",\
TABLE A-1 ( )
SAMPLE ANALYSIS AND PRESERVATION
Analysis Filter( a) Preservative Sample Container
EPA Method 502.2 and 624, No Ice Two 40-milliliter volatile Methyl Ethyl Ketone and organic analysis (VOA)
and Acetone bottles
EPA Method 625 No Ice One 4-liter bottle or two
1-liter bottles
Metals Yes HN0 3,Ice One 1-Iiter plastic bottle
General Chemistry No Ice One 1-liter plastic bottle
Anions, BOD
COD, TOC No H2S04,Ice One 1-liter plastic bottle
TOX No Ice One 250-milliliter amber
) glass bottle with VOA cap
EPA Method 413.1 No H2S04,Ice One 500-milliliter glass
bottle
(a) Filtering was accomplished in the field using a 12-volt vacuum pump and Nalgene
0.45 micron filters. ·
WP: 0827R2.AP A A-3
Each sample container was labeled prior to filling. The following information was written on each label with indelible ink:
• Sample number
• Project name and number
• Sample location
• Collection date and time
• Type of sample (water)
• Collector's name
• Type of analysis
• Preservative
• Filtered or non-filtered
• Number of bottles.
Following the filling of a pre-labeled bottle, it was stored in a secure container. The water samples were transported by IT personnel to Edward S. Babcock and Sons, Inc. laboratory in Riverside, California, following IT chain-of-custody procedures. The individual who ( ) collected the samples prepared them for shipment, described them on the chain-of-custody form, and signed the form when transferring the samples to another individual or to Edward S. Babcock and Sons, Inc. The individual who accepted the samples also signed the form.
A.6 ANALYTICAL PROCEDURES
The chain-of-custody form submitted to the laboratory lists the analyses to be performed for each sample. The analytical procedures for each test are discussed in the following sections.
A.6.1 Volatile and Semivolatile Organic Compounds
Water samples from the wells were analyzed by either EPA Method 502.2 or 624 (Purgeables ), and EPA Method 625 (Base/Neutrals and Acids). EPA Method 502.2 employs a purge and trap extraction, followed by quantification of the organic compounds using gas chromatography coupled to a photoionization detector. EPA Method 624 utilizes the same extraction method except that quantification is accomplished using gas chromatography coupled to a mass spectrometer (GC/MS).
WP: 0827R2.AP A A-4
(---- 'j EPA Method 625 involves extracting a measured volume of sample with methylene chloride at a pH greater than 11 and again at pH less than 2. The methylene chloride extract was dried and concentrated to a volume of 1 milliliter The extract was then analyzed using GC/MS methods.
A.6.2 SWAT Metals
Water samples were analyzed for metals by two methods. The samples were analyzed by Atomic Absorbance Spectrophotometry or Atomic Absorbance Spectrophotometry/Graphite Furnace.
A.6.3 Anions
Water samples were analyzed directly for anions by Ion Chromatography, an application of high-pressure liquid chromatography.
A.6.4 General Chemical Parameters
) EC, pH, total filterable residue, total hardness, chemical oxygen demand (COD), biochem ical oxygen demand (BOD), and silica were determined by standard laboratory methods.
EC was measured with a Wheatstone bridge-type conductivity circuit. Measurement of pH was with a pH meter, using a combination silver/silver chloride electrode. Total filterable residue was measured as residue after drying. Total hardness was calculated from the results of the calcium and magnesium determinations. Chemical oxygen demand was measured by addition of an excess of a powerful oxidizing agent (potassium dichromate), digestion, then titrametric determination of the unreacted oxidizing agent. . Biochemical oxygen demand was determined by taking a sample of waste, or diluted portion, and incubating it for five days at 20°C in the dark. The reduction in dissolved oxygen concentration during the incubation period yields a measure of the biochemical oxygen demand. The concentration of silica was determined by filtering the sample through a 0.45-micron filter. Molybdate ion in acidic solution was added to the filtrate and the resulting color complex was proportional to the dissolved silica in the sample. The color complex was measured spectrophotometrically.
WP: 0827R2.AP A A-5
F,) A.6.5 Total Organic Halides and Total Organic Carbon Water samples were analyzed for total organic halides (TOX) following EPA Method 9020, and for total organic carbon (TOC) by EPA Method 9060.
EPA Method 9020 detects all organic halides containing chlorine, bromine, and iodine. The analytical procedure involves passing a water sample through a column containing 40 milligrams (mg) of activated carbon. The column was then washed to remove any trapped inorganic halides and was then combusted to convert the absorbed organic halides to HX.
The HX was contained and titrated electrolytically using a microcoulometric detector.
EPA Method 9060 was used to determine the concentration of organic carbon in water. The organic carbon in a water sample was measured using a carbonaceous analyzer. The analyzer converts the organic carbon in a sample to carbon dioxide (C0 2) by either catalytic combustion or wet chemical oxidation. The C02 was measured by an infrared detector or was converted to methane (CH4) and measured with a flame ionization detector. The amount of C02 produced is directly proportional to the concentration of carbonaceous material in the sample.
A.6.6 Oil and Grease /
Water samples were analyzed for oil and grease following EPA Method 413.1. This method is used for the determination of hydrocarbons, vegetable oils, animal fats, waxes, soaps, greases, and related matter.
The analytical method was performed by taking a sample and acidifying it to a pH less than 2, then extracting the sample with fluorocarbon-113. The oil and grease was determined by comparing the infrared absorbance of the sample extract with standards.
WP: 0827R2.AP A A-6
' \
)
APPENDIX B
CERTIFICATES OF ANALYSIS AND
CHAIN-OF-CUSTODY FORMS
FIRST QUARTER SAMPLING
)
)
""
')
· .. _,-'
\
#
ASSOCIATED LABORATORIES
806 North Batavia - Orange, California 92668 - 7141771-6900 C...IENT
SAMPLE
Edward s. Babcock & Sons, Inc.
P.O. Box 432
Riverside, CA 92502
Attn: Judy Baker
Water
IDENTIFICATION Market Place Landfill
Project #240827-04
BASED ON SAMPLE As Submitted
Total Organic carbons (TOC)
MP-1 9 mg/1
MP-2 14 mgjl
MP-3 72 mgjl
MP-4 24 mgjl
MP-Blank <2 mgjl
ES
(1124)
Total
LAB NO F55486
REPORTED 11/14/88
RECEIVED 10/24/88
Organic Halides (TOX)
0.15 mgjl
0.80 mgjl
2.4 mgjl
1.0 mgjl
0.016 mgjl
) NOTE: Unless notified in writing, all samples will be discarded C-1 10M
by appropriate disposal protocol 3 o days from date rr1P/i1JG"t&~NSULTING The reports of the Associated Laboratories are confidential property of our clients and may not be reproduced or used for publication in part or in full without our written permission. This is for the mutual protection of the public, our Clients, and ourselves.
Chem1cal •
Microbiological •
Environmental •
..
/ BACTERIOLOGY
,. WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED
PHONE (714) 884-1881
LABORATORIES
) 3215 CHICAGO AVE.
ESTABLISHED 1;oe
EDWARD S. BABCOCK & SONS, INC.
P.O. BOX432
RIVERSIDE, CALIFORNIA 92502
11/28/88
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Lab No. 881021-193
Attn: David L. Guth
Sample Marked:
Pj#240827-04 Marketplace
Landfill water sample
MP-1
Parameter Name Results
Total Hardness as CaC03 7300 rng/L
Calcium (Cal 425 rng/L
~gnesium (Mg) 1500 rng/L
)clium (Na) · 14000 rngjL
..:>tassium (K) 575 mg/L
Total Cations 770 me/L
Total Alkalinity as CaC03 880 mg/L
Hydroxide (OH) none mgjL
Carbonate (C03) none rngjL
Bicarbonate (HC03 ) 1075 rng/L
Sulfate (S04) 3420 mg/L
Chloride (Cl) 23000 rng/L
Nitrate (N03 ) 250 mgjL
Total Anions 740 me/L
Specific Conductance 61600 )..U11ho/cm
pH 7.6 units
Total Filterable Residue 42000 mg/L
Biochemical Oxygen DemandS 18 mg/L
Chemical Oxygen Demand 25 mg/L
Fluoride (F) 0.6mg/L
Oil and Grease <1 mg/L
Total Phosphorus (P) 40 mg/L
Silica (Si~) 9 mg/L
Invoice No. 94697
Submitted
DLG
10/21/88
13:30
I Sampled
IDLG
110/19/88
L
Chain of Custody on file: Y
Parameter Name Results
Antimony (Sb) 1 mgjL
Arsenic (As) <o·.o5 rng/L
Barium (Ba) <0.1 mg/L
Beryllium (Be) <0.05 mg/L
Cadmium (Cd) <0.01 rng/L
Total Chromium (Cr) <0.1 mg/L
Cobalt (Co) <0.05 mg/L
Copper (Cu} 0.06 mg/L
Iron (Fe) <0.05 mg/L
Lead (Pb) <0.3 mg/L
Manganese (Mn) 1.8 mg/L
Molyl:x:lenum (Mo) <0.5 mg/L
Nickel (Ni) <0.05 mg/L
Silver (Ag) <0.05 mg/L
Thallium (Tl) 0.6 mg/L
Vanadium (V) <0.5 mg/L
Zinc (Zn) <0.05 mg/L
Notes: Xetals analyses run on samples filtered and preserved in field. cc:
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED
PHONE (714) 684-1881
LABORATORIES
3215 CHICAGO AVE.
ESTABLISHED 19041
EDWARD S. BABCOCK & SONS, INC.
P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
11/28/88
To: International Tech. Corp. Lab No. 881021-194
17 461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 Marketplace
Landfill water sample
MP-2
Parameter Name Results
Total Hardness as cama 15300 mg/L
Calcium (Ca) 780 mgjL
Magnesium (Mg) 3200 mg/L
.<:::odium (Na) 31000 mg/L
)tassium (I{) 275 mg/L
· ... otal Cations 1660 me/L
Total Alkalinity as cama 1230 mg/L
Hydroxide (OH) none mg/L
Carbonate {CDa) none mg/L
Bicarbonate mma) 1500 mg/L
Sulfate (804) 8700 mgjL
Chloride (Cll 50500 mg/L
Nitrate (NOa) 330 mg/L
Total Anions 1630 me/L
Specific Conductance 108000 IJIIlho/cm
pH 7.3 units
Total Filterable Residue 75200 mg/L
Biochemical Oxygen DemandS 25 mg/L
Chemical Oxygen Demand 35 mg/L
Fluoride (Fl 1 mg/L
Oil and Grease <1 mg/L
Total Phosphorus (P) 56 mg/L
Silica {Si~) 6 mg/L
Invoice No. 94697
Sul::Jnitted
DLG
10/21/88
13:30
I Sampled
DLG
110/19/88
Chain of Custody on file: Y
Parameter Name Results
Antimony (Sb) -:<1 mg/L
Arsenic (As) <0.1 mg/L
Barium (Ba) <0.1 mg/L
Beryllium (Be) <0.05 mg/L
Cadmium (Cd) <0.03 mg/L
Total Chromium (Cr) <_0 .1 mg/L
Cobalt (Co) 0.06 mg/L
Copper (Cu) 0.1 mg/L
Iron (Fe) 0.05 mg/L
Lead (Pb) <0.5 mg/L
Manganese (Mn) 2.8 mg/L
Molybdenum (Mo) <0.5 mg/L
Nickel (Ni) <0.05 mg/L
Silver (Ag) <0.05 mg/L
Thallium (Tl) 1.5 mg/L
Vanadium (V) <0.5 mg/L
Zinc (Zn) <0.05 mg/L
Notes: Metals analyses run on samples filtered and preserved in field. ' _j
cc:
· BACTERIOLOGY
WATER TeSTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 111011
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
To: International Tech. Corp.
17 461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 Marketplace
Landfill water sample
:W-3
Parameter Name Results
Total Hardness as CaCOa 8200 mg/L
Calcium (Cal 355 mg/L
Magnesium (Mg) 1750 mg/L
~l<fium (Na) 15800 mg/L
Jtassium (K) 515 mg/L
.. otal Cations 864 me/L
Total Alkalinity as CaC03 2925 mg/L
Hydroxide (OH) none mg/L
Carbonate (C03) none mg/L
Bicarbonate (HCOa) 3570 mg/L
Sulfate (S04) 1430 mg/L
Chloride (Cl) 27000 mg/L
Nitrate (NOa) 320 mg/L
Total Anions 854 me/L
Specific Conductance 68800 j..IIIl.ho/cm
pH 7.4 units
Total Filterable Residue 45900 mg/L
Biochemical Oxygen DemandS 19 mg/L
Chemical Oxygen Dema.D;i_. · 25 mg/L
Fluoride (F) , 2 mg/L
Oil and Grease . ;.~.·
<1 mg/L
Total Phosphorus {P) : 18 mg/L
Silica (Si~) 14 mg/L
11/28/88
Lab No. 881021-195
Invoice No. 94697
Submitted
DLG
10/21/88
13:30
I Sampled
DLG
j10/19/88
I
Chain of Custody on file: Y
Parameter Name Results
.:;:.
Antimony (Sb) \ <1 mg/L
Arsenic (As) «i;05 mg/L
Barium (Ba.) 2.8 mg/L
Beryllium (Be) <0.05 mg/L
Cadmiurn (Cd) <0.01 mg/L
Total Chromi urn (Cr) <0.1 mg/L
Cobalt (Co) <0.05 mg/L
Copper (Cu) 0.08 mg/L
Iron (Fe) 0.2 mg/L
Lead (Pb) <0.3 mg/L
Manganese (Mn) 3.0 mg/L
Molybd.enurn (Mo) <0.5 mg/L
Nickel (Ni) 0.05 mg/L
Silver (Ag) <0.05 mg/L
Thalli urn (Tl) 0.8 mg/L
Vanadium (V) <0.5 mg/L
Zinc (Zn) .<0.05 mg/L
~otes: Metals analyses run on samples filtered and preserved in field. cc: IlllWARD S. I!AB(X](X &o ::;;;:t:1 . J.~j
I
· BACTERIOLOGY
• WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1!108
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 Marketplace
Landfill water sample
MP-4
Parameter Name Results
Total Hardness as CaCOa 3550 mg/L
Calcium (Ca) 850 mg/L
Magnesium (Mg) 340 mg/L
Sodium (Na) 4600 mg/L
)tassium (K) 200 rng/L
Jtal Cations 276 me/L
Total Alkalinity as CaCOa 1425 mg/L
Hydroxide (OH) none mg/L
Carbonate (COa) none mg/L
Bicarbonate (HCOa ) 1740 mg/L
Sulfate (S04) 1870 mg/L
Chloride (Cl) 6800 mg/L
Nitrate (N03) 230 mg/L
Total Anions 263 me/L
Specific Conductance 22000 IJ]Ilho/cm
pH 7.4 units
Total Filterable Residue 11000 rng/L
Biochemical Oxygen DemandS 18 mg/L
Chemical Oxygen Demand 185 mg/L
Fluoride (F) 2 mg/L
Oil and Grease <1 mg/L
Total Phosphorus (P) 32 mg/L
Silica (Si~) 18 rng/L
11/28/88
Lab No. 881021-196
Invoice No. 94697
Submitted Sampled
DLG
10/21/88
13:30 I
DLG
10/19/88
Chain of Custody on file: Y
Parameter Name Results
Antimony (Sb) <Q.2 mg/L
Arsenic (As) <{#01 mgJL
Barium (Ba) <0.1 mgJL
Beryllium (Be) <0.01 mg/L
cadmium (Cd) <0.01 mg/L
Total Chromi urn (Cr) <0.1 mg/L
Cobalt (Co) <0.01 mg/L
Copper (Cu) 0.02 mg/L
Iron (Fe) 0.04 mg/L
Lead (Pb) <0.1 mg/L
Manganese (Mn) 1.8 mg/L
Molybdenum (Mo) <0.1 mg/L
Nickel (Ni) <0.01 mg/L
Silver (Ag) <0.05 mg/L
Tli.allium (Tl) 0;2 mg/L
Vanadium (V) <0.1 mg/L
Zinc (Zn) 0.05 mg/L
Notes: Metals analyses run on samples filtered and preserved in field. cc:
.
"BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED
PHONE (714) 684-1881
LA BORA TORIES
3215 CHICAGO AVE.
ESTABLISHED 1;()8
EDWARD S. BABCOCK & SONS, INC.
P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
11!28/88
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Lab No. 881021-197
Attn: David L. Guth
Sample Marked:
Pj#240827-04 Marketplace
Landfill ~:.;ater sample
MP- BLANK
Parameter :Name Results
Total Hardness as CaCOa <1 mg/L
Calcium (Ca) <1 mg/L
Magnesium (Mg) <1 mg/L
~qdium (Na) <1 mg/L
)tassium (I() <1 mg/L
· ~otal Cations 0.00 me/L
Total Alkalinity as CaCOa 3 mg/L
Hydroxide (OH) none mg/L
Carbonate (COa) none mg/L
Bicarbonate (HCOa) 3 mg/L
Sulfate (S04) <1 mg/L
Chloride (Cl) <1 mg/L
Nitrate (NOa) <1 mg/L
Total Anions 0.05 me/L
Specific Conductance 2 IJIIlho/cm
pH 8.5 units
Total Filterable Residue <5 mg/L
Biochemical Oxygen Demands <1 mg/L
Chemical Oxygen Demand <1 mg/L
Fluoride (F)
,.
<0.1 mg/L
Oil and Grease <1 mg/L
Total Phosphorus (P) 0.01 mg/L
Silica ( Si()z ) <1 mg/L
Invoice No. 94697
Sul:mitted
DLG
10/21/88
13:30
I Sampled
DLG
!10/19/88
!
Chain of Custody on file: Y
Parameter Name Results ....
Antimony (Sb) (().2 mg/L
Arsenic (As) <0':01 mg/L
Barium (Ba) <0.1 mg/L
Beryllium (Be) <0.01 mg/L
Cadmium (Cd) <0.001 mg/L
Total Chromium (Cr) <0.01 mg/L
Cobalt (Co) <0.01 mg/L
Copper (Cu) <0.01 mg/L
Iron (Fe) 0.02 mg/L
Lead (Pb) <0.01 mg/L
Manganese (Mn) <0.01 mg/L
Molybdenum (Mo) <0.1 mg/L
Nickel (Ni) <0.01 mg/L
Silver {Ag) <0.01 mg/L
Thallium (Tl) <0.1 mg/L
Vanadium (V) <0.1 mg/L
Zinc (Zn) <0.01 mg/L
Notes: Metals analyses run on samples filtered and preserved in field. )
cc:
'/
,
BACTERIOLOGY
WATER TESTING
' HAZARDOUS WASTE TESTING
ESTABLISHED 1;oe CALIF. DHS CERTIFIED
PHONE (714) 684-1881
,-· . LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
( ) 3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
To: 5 December, 1988
International Tech. Corp.
17461 Derian Ave., Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked: Marketplace Landfill #240827-04
Sample # MP-1
Parameter ............................................. .._ ....
Acetone
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethylvinyl
Chloroform
ether
Chloromethane ·
bis (2-Chloroethyl) ether
'Dibromochloromethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethyl Benzene
Methylene chloride
Methyl Ethyl Ketone
Methyl Isobutyl Ketone
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes
E .. ~.§.:!:! . .1.t. ( u gIL )
3.9 ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
.ND
ND
ND
ND
ND
ND
ND
7.4 ND
ND
ND
ND
ND
ND
ND
ND
ND
Lab No. 881021-175
Invoice No. 94694
§_~.:!2.~tt .. t .. ~-~ .... __ ~-~.!!!.P..l~E.
By DLG DLG
Date 10121188 10119188
Time 13:30
Test Method: EPA 502.2
P. .. ~t..~ .. 9. .. tt..2.:n ....... ~.J .. m .. tt. ( ug I L )
1. 00
0.50 0.50
0.50 0.50
0.50 0.50
0.50 1. 00
0.50 0.50
5.00 0.50
0.50 0.50
0. 50
0.50 0.50
0.50 0.20
0.50 0.50
0.50 0.50
0.50 0.50
5.00 5.00
0.50 0.50
0.50 0.50
0.50 0.50
0.50 1. 00
0.50 BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
ESTABLISHED 1110f1 CALIF. OHS CERTIFIED
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
To: 5 December, 1988
International Tech. Corp.
17461 Derian Ave., Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked: Marketplace Landfill #240827-04
Sample # MP-2
Parameter .................................. "'''''-···-··· Acetone
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
R.~ .. §.~ . .J: .. :t. ( u g I L )
ND
ND
ND
ND
ND
ND
Chlorobenzene ND
Chloroethane ND
2-Chloroethylvinyl ether ND
Chloroform ND
Chloromethane
.bis (2-Chloroethyl) ether
Dibromochloromethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethyl Benzene
Methylene chloride
Methyl Ethyl Ketone
Methyl Isobutyl Ketone
1,1,2,.2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
9.4 13.4
ND
ND
ND
ND
ND
ND
ND
ND
ND
Lab No. 881021-176
Invoice No. 94694
§ .. !:l..!?..m:.:t. .. :t .. :t~.g-···-.§.~~1? . .:!: .. ~~ By DLG DLG
Date 10121188 10119188
Time 13:30
Test Method: EPA 502.2
:!2 .. ~~ .. ~ .. 9. .. :t.l . .9.}} __ ·-~ .. :t..m_t:t. ( u g I L )
1. 00
0.50 0.50
0.50 0.50
0.50 0.50
0. 50 "r
1. 00
0.50 0.50
5.00 0.50
0.50 0.50
0.50 0.50
0.50 0.50
0.20 0.50
0.50 0.50
0.50 0.50"
0.50 5.00
5.00 0.50
0.50 0.50
0.50 0.50
0.50 0.50
1. 00
0.50 ND = None Detected Date Analysis Completed: 11104188 Chain of Custody on File n/Jl.~ J72~J.f ~
Edwa~b~, Inc.
!
\
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1-
PHONE (714) 684-1881
LABORATORIES
EDWARDS. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
To: 5 December, 1988
International Tech. Corp.
17461 Derian Ave., Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked: Marketplace Landfill #240827-04
Sample # MP-3
E~.r. .. ~_m.~ .. t .. ~x.
Acetone
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethylvinyl ether
Chloroform
Chloromethane
bis (2-Chloroethyl) ether
Dibromochloromethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
trans-1,2-Dichloroethene
·1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethyl Benzene
Methylene chloride
Methyl Ethyl Ketone
Methyl Isobutyl Ketone
1,1,4,~~Tetrachloroethane
Tetraohioroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes
Result(ug/L)
······z·~-a··-
8oo
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
100
ND
8.4 26
ND
ND
3 . 1
ND
ND
ND
ND
ND
ND
Lab No. 881021-177
Invoice No. 94694
S Y:J?mJJ~.1..~.9.-.. §..~_ffi.R.!. e ~
By DLG DLG
Date 10/21/88 10/19/88
Time 13:30
Test Method: EPA 502.2
P..~!&.9. . .t. i o .!L ... !:! .. :!:.!!:I:.:!:.:t.. ( ug I L )
1. 00
0.50 0.50
0.50 0.50
0.50 0.50
0.50 1. 00
0.50 0.50
5.00 0.50
0.50 0.50
0.50 0.50
0.50 0.50
0.20 0.50
0.50 0.50
0.50 0.50
0.50 5.00
5.00 0.50
0.50 0.50
0.50 0.50
0.50 0.50
1. 00
0.50 ND = None Detected Date Analysis Completed: 11/04/88 iidw~~
Chain of Custody on File
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED
""'!
ESTABliSHED 180e
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
To: 5 December, 1988
International Tech. Corp.
17461 Derian Ave., Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked: Marketplace Landfill #240827-04
Sample # MP-4
Parameter
Acetone
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethylvinyl ether
Chloroform
Chloromethane
. bis (2-Chloroethyl) ether
bibromochloromethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethyl Benzene
Methylene chloride
Methyl Ethyl Ketone
Methyl Isobutyl Ketone
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes
g.~ .. ~-Y....l. .. t.. ( ug I L )
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND = None Detected Date Analysis
Chain of Custody on File
Lab No. 881021-178
Invoice No. 94694
§ u !?..!!!.t~ .. t.~.9: .. -... -~_aJl!El ... e d
By DLG DLG
Date 10121188 10119188
Time 13:30
Test Method: EPA 502.2
!?. .. ~-~~ .. ~1 .. t9..!!. ...... 1 .. i!!l:.i .. t.. ( ug I L )
1. 00
0.50 0.50
0.50 0.50
0.50 0.50
0.50 1. 00
0.50 0.50
5.00 0.50
0.50 0.50
0.50 0.50
0.50 0.50
0.20 0.50
0.50 0.50
0.50 0.50
0.50 5.00
5.00 0.50
0.50 0.50
0.50 0.50
0.50 0.50
1. 00
0.50 Edwird S . EabCOCk&SOils, Inc.
,.
.BACTERIOLOGY
, WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1;oe
PHONE (714) 684-1881
EDWARD S. BABCOCK & SONS, INC. \ I LABORATORIES
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
To: 5 December, 1988
International Tech. Corp.
17461 Derian Ave., Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked: Marketplace Landfill #240827-04
Sample # MP-Blank
P..~.!: .. ~!!!.~t...~.r. B..~ .. § .. ld .. Lt.. ( u g I L ) Acetone ND
Benzene ND
Bromodichloromethane ND
Bromoform ND
Bromomethane ND
Carbon tetrachloride ND
Chlorobenzene ND
Chloroethane ND
2-Chloroethylvinyl ether ND
Chloroform ND
Chloromethane ND
~bis (2-Chloroethyl) ether ND
Dibromochloromethane ND
1,2-Dichlorobenzene ND
1,3-Dichlorobenzene ND
1,4-Dichlorobenzene ND
Dichlorodifluoromethane ND
1,1-Dichloroethane ND
1,2-Dichloroethane ND
1,1-Dichloroethene ND
trans-1,2-Dichloroethene ND
1,2-Dichloropropane ND
cis-1,3-Dichloropropene ND
trans-1,3-Dichloropropene ND
Ethyl Benzene ND
Methylene chloride ND
Methyl ·Ethyl Ketone ND
Methyl Isobutyl Ketone ND
1,1,2,Z~Tetrachloroethane ND
Tetrach1oroethene ND
Toluene. ND
1,1,1-Trichloroethane ND
1,1,2-Trichloroethane ND
Trichloroethene ND
Trichlorofluoromethane ND
Vinyl chloride ND
Xylenes ND
Lab No. 881021-179
Invoice No. 94694
.§ u b fu..i.~.:t e ~;L ....... §~.!!Lt?.1!2_g
By DLG DLG
Date 10121188 10119188
Time 13:30
Test Method: EPA 502.2
p_~~.~-9..1.~ . .9.-P.: ...... ~ .. t. .. !!':.i.t.. ( u g I L )
1. 00
0.50 0.50
0.50 0.50
0.50 0.50
0.50 1. 00
0.50 0.50
5.00 0.50
0.50 0.50
0.50 0.50
0.50 0.50
0.20 0.50
0.50 0.50
0.50 0.50
0.50 5.00
5.00 0.50
0.50 0.50
0.50 0.50
0.50 0.50
1. 00
0.50 ND = None Detected Date Analysis Completed: 11104/88 Chain of Custody on File (J(f/~J:. ~~J'- ~
Edwa~~s·,--I-n-c.
t -'BACTERIOLOGY
WATER TESTJNG
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED
PHONE (714) 684-1881
LABORATORIES
ESTABLISHED 180e
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502Date of Report: 11/28/88
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked: Pj#240827-04 Marketplace
Landfill water sample
~1P-1
Lab No. 881021-211
Invoice No. 94700
Customer No. in0292
Sul:mitted
By DLG
Date 10/21/88
Time 13:30
Sampled
DLG
10/19/88
Chain of Custody on file: Y
Base Neutral and Acid Rxtractable Compounds
Parameter Results(
Acena;hthene ND
Acenaph:hylene )/])
Anth:acene ND
tLJ,.'
... .1. ... .~.1n )/])
Benzo(a;ar.th1acene ND
Benzo(b;:luo~anthe~e ~ID
Ber.zo(k):l~ccan~hene ND
B::1ZO{l;?y~ene ND
Benzo(ghi)perylene }ID
Benzyl butyl phthalate ND
b-BHC liD
S-BHC liD
Eis ( 2-chloroethy l )ether }lD
Bis(2-chlcroethoxy)meth~,e ND
Bis(Z-ethylhexyl)phthalate ND
Bis(2-chloroisopropyl)ether ND
4-BroMophenyl phenyl ether ND
Chlordane liD
2-Chloronaphthalene ND
4-Chlorophenyl phenyl ether liD
Chrysene ND
4-Chloro-3-methylphenol
2-Chlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
Benzidine
a-BHC
y-BHC
ND
ND
ND
ND
ND
ND
ND
EPA ;.-Iethod 625
?:J.rameter Results( ~g/L ) Parameter Res:.:lts( ~g/L
Base/lleutral Eitractables .... , . , ....... , .. , . , ........................ ,
4.4'-DDD
4,4'-DDE
U'-DDT
Dibenzo(a,h)anthracene
D:-~-butylphthalate
1,3-Dichlorobenzene
1,2-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
Dieldrin
Diethyl phthalate
Dimethyl phthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octylphthalate
Endosulfan sulfate
Endrin aldehyde
Fluoranthene
Fluorene
Heptachlor
Heptachlor epoxide
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND.
ND
ND
ND
ND
ND
liD
ND
Acid Krtractables
2,4-Dinitrophenol ND
2-Methyl-4,6-dinitrophenol ND
2-Nitrophenol ND
4-Ni trophenol ND
Additional htractable Parueters
Endosulf an I ND
Endosulfan II ND
Endrin ND
Hexachlorobenzene ND
Hexachlorobutadiene ND
Hexachloroethane ND
Ideno(1,2,3-cd)pyrene ND
Isophorone ND
Naphthalene ND
Nitrobenzene ND
N-Nitrosodi-n-propylamine ND
PCB-1016 ND
PCB-1221 ml
PCB-1232 Nll
PCB-1242 liD
PCB-1248 ND
PCB-1254 ND
PCB-1260 ND
Phenanthrene ND
Pyrene ND
Toxaphene Nil
1,2,4-Trichlorobenzene ND
Pentachlorophenol ND
Phenol ND
2, 4, 5-Trichlorophenol ND
Hexachlorocyclopentadiene ND
H-Nitrosodimethy lamine ND
N-Nitrosodiphenylamine ND
\~=None detected, detection limit: 10 ug/L NI=Not identifiable Date analysis completed: 11/10/88
Notes:
cc:
' .. I
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
ESTABLISHED 1&108 CALIF. DHS CERTIFIED
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502{)ate of Report: 11/28/88
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: Da'v·id L. Guth
Sample Marked: Pj#240827-04 Marketplace
Landfill Hater sample
~!P-2
Lab No. 881021-212
Invoice No. 94700
Customer No. in0292
Sul::mitted
By DLG
Date 10/21/88
Time 13:30
I Sampled
DLG
10/19/88
Chain of Custody on file: Y
Base Neutral and Acid Rxtractable Compounds
( EPA Method 625
Parameter Results( ug/L ) Parameter Results( ug/L ) Paraaeter Results( ug/L ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, Base/leutral Krtractables lltllllllltlllltlllllltlllllll I lltlllllllllll Acenaphthene mJ 4,4'-DDD mJ Hexachlorobenzene mJ
Acenaphthylene mJ 4,4'-DDE mJ Hexachlorobutadiene })])
AJ1thracene Nil 4,4'-DDT ND Hexachloroethane mJ
Aldrin ND Dibenzo(a,h)anthracene ND Ideno(l,2,3-cd)pyrene Nil Benzo (a) a~thr>acene ND Di-n-butylphthalate ND Isophorone ND Benzo{b) :luoranthene ND 1,3-Dichlorobenzene ND Naphthalene ND Benzo (k l fluoranthene ND 1,2-Dichlorobenzene ND Nitrobenzene ND Benzo(a)pyrene ND 1,4-Dichlorobenzene ND N-Nitrosodi-n-propylaaine ND Benzo(gti);erylene Nil 3, 3' -Dichlcrcbenzidine ND FCB-1016 ND Benzy~ bu:yl phtha~a:e ND Dieldrin liD PCB-1221 })])
~-9HC ~ Diethyl phthalate liD PCB-1232 f!D
5-BHC ND Dimethyl phthalate mJ PCB-1242 mJ
9is ( 2-chloroethy l) ether ND 2,4-Dinitrotoluene })]) PCB-1248 ND Bis(2-chloroethoxy)methane Nil 2,6-Dinitrotoluene liD PCB-1254 liD Bis(2-eth;lhexyl)phthalate ND Di-n-octylphthalate ND PCB-1260 ND Bis(2-chloroisoprcpyl)ether ND Endosulfan sulfate ND ~henanthrene ND 4-Ercmophe~yl phe~yl ct~er mJ Endrin aldehyde ND Pyrene ND Chlodane mJ Fluoranthene ND Toxaphene ND
2-Chloronaphthalene ND Fluorene ND 1,2,4-Trichlorobenzene ND 4-Chlorophcnyl phenyl ether ND Heptachlor ND
Chrysene liD Heptachlor epoxide ND
,,,,,,,,,,,,,,,,,,,, ..................... Acid Rrtractables Olllllllllllllllllllllllllflllllflflllllllllll 4-Chloro-3-methyl~henol liD 2~4-Dinitrophenol liD Pentachlorophenol ND 2-Chlorcphenol ND 2-Kethyl-4,5-dinitrophenol ND Phenol ND 2,4-Dichlorophe~ol ND 2-Nitrophenol ND 2,4,6-Trichlorophenol ND 2,4-Dillethy lphenol mJ 4-Nitrophenol liD
................................ Additional Krtractable Puueters .......................................
Benzidine ND Endosulfan I
a-BHC ND Endosulfan II
y-BHC ND Endrin
ND=None detected, detection limit:
Date analysis completed: 11/10/88
Notes:
cc:
ND Hexachlorocyclopentadiene ND
liD N-Nitrosodimethylamine ND
ND N-Ni trosodipheny la.mine liD
10 ug/L NI=Not identifiable
_. BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
ESTABLISHED 111011 CALIF. DHS CERTIFIED
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
)
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502Da,te of Report: 11/28/88
To: Internatio~ Tech. Corp.
17461 Derian-Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample ~rked: Pj#240827-04 Marketplace
Landfill water sample
MP-3
Lab No. 881021-213
Invoice No. 94700
Customer No. in0292
Submitted
By DLG
Date 10/21/88
Time 13:30
Sampled
DLG
10/19/88
Chain of Custody on file: Y
Base Neutral and Acid Rxtractable Compounds
( EPA Method 625
Parameter Results( ug/L ) Parameter Results( ug/L ) Parameter Results( ~g/L ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, Base/leutral Rrtractables ........................... ,,,,,,,,,,,,,,,,,, Acenaph thene !ID 4,4'-DDD !ID Hexachlorobenzene !ID
Acenaphthy lene !ID 4,4'-DDR }ill Hexachlorobutadiene liD Anthracene !ID 4,4'-DDT !ID Hexachloroethane !ID
Aldrin liD Dibenzo(a,h)anthracene !ID Ideno(l,2,3-cd)pyrene ND Benzo(a)anth~acene ND Di-n-but]lphthalate !ID Isophorone liD Benzo(b)fluoranthene liD 1,3-Dichlorobenzene ND Haphthalene ND 3enzo(k)fluor~~thene liD 1,2-Dichlorobenzene ND Nitrobenzene ND Benzo(a)pyrene liD 1,4-Dichlorobenzene ND N-Nitrosodi-n-propylamine liD Benzo~ghi)per]l~ne NJ) 3,3'-Dichlorobenzidine !ID PCB-1016 ND Benzyl butyl phthalate ND Dieldrin ~'D PCB-1221 ND
b-BH~ !ID Diethyl phthalate HD PCB-1232 liD
5-BHC ND Dimethyl phthalate ND PCB-1Z42 liD
Bis(2-chloroethyl)ether liD 2,4-Dinitrotoluene ND PCB-1248 ND Bis(2-chloroethcxy)methane liD 2,5-Dinitrotoluene ND PCB-1254 liD Bis( 2-ethylhexy 1) phthalate 30 Di-n-octylphtbalate 56 PCB-1260 liD Bis(~-chloroisopropyl)ether ND Endosulfan sulfate ND Phenanthrene liD 4-Bromophenyl phenyl :ther ND Rndrin aldehyde ND Pyrene liD Chlordane liD Fluoranthene liD Toxaphene liD
2-Chlcronapbthalene ND Fluorene ND 1,2,4-Trichlorobenzene !ID 4-Chlorcphenyl phenyl ether HD Heptachlor ND
Chrysene liD Heptachlor epoxide liD
,,,,,,,,,,,,, .............................. Acid Rrtractables ,,,,,,,,,,,,,,,,,,,,,,,,,,.,, ...... ,,,,,,,,,,, 4-Chloro-3-methylphenol .ND 2,~-Dinitrophenol ND Pentachlorophenol ND 2-Chlorophenol ND 2-Methyl-4,6-dinitrophenol ND Phenol ND 2,4-Dich~orophenol liD 2-Nitrophenol ND 2,4,6-Trichlorophenol liD 1,~-Dime:hylphenol liD Hitrophenol !ID
.... ,,,,,,,,,,,,,,,,,,,,,,,,,,,, AdditiOD&l Rrtractable Paraleters ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, Benzidine ND Endosulfan I
a-BHC liD Rndosulfan II
y-BHC ND Rndrin
ND=None detected, detection limit:
Date analysis completed: 11/10/88
Notes:
cc:
ND Hexachlorocyclopentadiene liD
!ID N-Nitrosodimethylamine liD
ND N-Nitrosodiphenylaaine !ID
10 wt/L NI=Not identifiable
EDWARD s. BABCOCK & ~'. F§
L~L_e~
.·::
·f.·
BAcTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
ESTABLISHED 180e CALIF. DHS CERTIFIED
PHONE (714) 884-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
P.O. BOX 432 3215 CHICAGO AVE.
RIVERSIDE, CALIFORNIA 92so2Date of Report: 11/28/88
To: InternationaJ Tech. Corp.
17461 Derian.Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked: Pj#240827-04 Marketplace
Landfill water sample
MP-4
Lab No. 881021-214
Invoice No. 94700
Customer No. in0292
Submitted Sampled
By DLG
Date 10/21/88
Time 13:30
DLG
10/19/88
Chain of Custody on file: Y
Base Neutral and Acid R~tractable Compounds
EPA Method 625
Pa:-:.meter ?.esults( ~g,'L Parameter Results( ug/L ) Parameter Results( ~g/L .................................. Base/leutral htractahles llllllflllllllltlllllillillltllllllllllllllll Acenaphthene ND 4, 4' -DDD. ND Hexachlorobenzene liD
Acenaphthyl:ne ND 4,4'-DDE ND Hexachlorobutadiene ND
Anthracene ND 4, 4' -DDT ND Hexachloroethane liD
Aldrin liD Dibenzo(a,h)anthracene ND Ideno(1,Z,3-cd)pyrene liD Benzo(a)anth~acene liD Di-n-butylphthalate ND Isophorone liD Benzo(b}fluoranthene ND 1, 3-Dichlorobenzene ND Naphthalene ND Benzo(k)fluoranthene ND l,Z-DichlorGbenzene ND Nitrobenzene ND Benzo(a)pyrene ND 1,4-Dichlorobenzene ND N-Nitrosodi-n-propylamine ND Benzo(ghi)perylene Hil 3,3'-Dichlorobenzidine ND PCB-1016 ND Benzyl butyl phthalate ND Dieldrin ND PCB-1221 ND
b-BHC ND Diethyl phthalate ND PCB-1232 ND
HHC ND Dimethyl phthalate ND PCB-1242 ND
Bis(2-chloroethyl)ether ND 2, 4-Dinitrotoluene ND PCB-1248 ND Bis(2-chloroethoxy)methane ND 2, 6-Dinitrotoluene ND PCB-1254 ND Bis(2-ethylhexyl)phthalate ND Di-n-octylphthalate ND PCB-1260 ND Bis(2-chloroisopropyl}ether ND Endosulfan sulfate ND Phenanthrene ND 4~Bromophenyl phenyl ether ND Endrin aldehyde ND Pyrene ND Chlordane ND Fluoranthene ND Toxaphene ND
2-Chloronaphthalene ND Fluorene liD 1,2,4-Trichlorobenzene ND 4-Chlorophenyl phenyl ether YD Heptachlor ND
Chrysene HD Heptachlor epoxide ND
,,,,,,,,,,,,,,,, ..................... , ... Acid :Krtractahles ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 4-Chloro-3-methylphenol ND Z,4-Dinitrophenol ND Pentachlorophenol ND Z-Chlorophenol ND 2-Methyl-4,6-dinitrophenol ND Phenol ND 2,4-Dichlorophenol ND 2-Nitrophenol ND 2,4,6-Trichlorophenol ND 2,4-Dimethylphencl ND 4-Ni trcpheno l ND
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, Additional :Krtractahle Parueters .......................................
Benzidine ND Endosulfan I
a-BHC ND Endosulfan II
y-BHC ND Endrin
ND=None detected, detection limit:
Date analysis completed: 11/10/88
Notes:
cc:
ND Hexachlorocyclopentadiene ND
ND N-Nitrosodimethylamine ND
ND N-Nitrosodiphenylaaine ND
10 llg/L NI=Not identifiable
.. . ¥
I I
/
)
-- -------- ----~-------
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1;oe
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502Date of Re"JX)rt; 11/28/88
To: International Tech. Corp.
17461 Derian· Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample ~rked: Pj#240827-04 Marketplace
Landfill water sample
~-Blank
Lab No. 881021-215
Invoice No. 94700
!Customer No. in0292
Submitted
By DLG
Date 10/21/88
Time 13:30
Sampled
DLG
10/19/88
Chain of Custody on file: Y
Base Neutral and Acid R~tractable Compounds
( EPA Method 625
ParaJneter ~esults( ug/L I Parameter Results( ~g/L I Parameter Results( ~g/L .................................. Base/lfeutral Rrtractables ltllllflllllllllllllllllllltllltllllllltlllll Acenaphthene liD 4141-DDD ND Hexachlorobenzene ND
Acenaphthylene ND 4141-DDE ND Hexachlorobutadiene liD
Anthracene ND 4,4'-DDT ND Hexachloroethane ND
Aldrin ND Dibenzo(a,hlanthracene ND Ideno(112,3-cdlpyrene ND Benzo(a)anthtacene ND Di-n-butylphthalate ND Isophorone ND Benzo(b)fluoranthene ND 11 3-Dichlorobenzene liD Naphthalene ND Benzo (k) fluoranthene ND 1~2-Dichlorobenzene ND Nitrobenzene ND Benzo(a)pyrene ND 114-Dichlorobenzene ND N-Nitrosodi-n-propylamine ND Benzo(ghi)perylene },1]) 313'-Dichlorobenzidine ND PCB-1016 liD Benzyl butyl phthalate ND Dieldrin ND PCB-1221 liD
b-BHC ND Diethyl phthalate ND PCB-:232 ND
o-BHC ND Dimethyl phthalate ND PCB-1242 ND
Bis(2-chloroethyl)ether liD 2,4-Dinitrotoluene ND PCB-1248 ND Bis(2-chloroethoxy)methane ND 216-Dinitrotoluene ND PCB-1254 liD Bis(2-ethylhexyl)phthalate ND Di-n-octylphthalate ND PCB-1260 liD Bis(2-chlJroisopropyl)ether ~ Endosulfan sulfate ND Phenanthrene ND 4-Bromophenyl phenyl e:her ND Endrin aldehyde ND Pyrene liD Chlordane ND Fluoranthene ND Toxaphene ND
2-Chloronaphthalene ND Fluorene ND 1,214-Trichlorobenzene ND 4-Chlorophenyl phenyl ether MD Heptachlor ND
Cbrysene MD Heptachlor epoxide ND
llllllllllllllllllllllllltlt••••········· Acid &rtractables 1111111111111111111111111111111111111111111111 4-Chloro-3-tethylphenol MD 214-Dinitrophenol ND Pentachlorophenol ND 2-Chloropb.enol ND 2-Methyl-416-dinitrophenol ND Phenol ND 21 4-Dichlorophenol ND 2-Nitrophenol ND 2,416-Trichlorophenol ND 214-Dimethylphenol ND 4-Nitrophenol ND
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, Additional Rrtractahle Paraaeters 111111111111111111111111111111111111111 Benzidine ND Endosulfan I
a-BHC ND Endosulf an II
y-BHC ND Endrin
ND=None detected, detection limit:
Date analysis completed: 11/10/88
Notes:
cc:
ND Hexachlorocyclopentadiene ND
liD N-Nitrosodimethylaaine ND
ND N-Nitrosodiphenylamine ND
10 llg/L NI=Not identifiable
EDrlARD S. BABCOCK & ..... S)NS, ~ /1
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Date/Time Received by:. Relinquished by: Date I Time Received by (S ~ -~ . % ,( (3J6 ((!g~%e) .. (S igtulture) (Signature) 1~, • MA.U -
RelinquisHed by: Dat"(Time ReceivedUby: Relinquished by: Date/Time Received by (Signature) (Signature) (Signature)
I
(Signature)
Relinquished by: nat~~Time Received for Laboratory by: Date /TiCle Remarks (Signature) (Signature)
L____ -- - --·-
Chain of Custody Record
·.
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C·l 10M
ASSOCIATED LABORATORIES
806 North Batavia - Orange, California 92668 - 7141771-6900 S:\MPLE
Edward s. Babcock & Sons, Inc.
P.O. Box 432
Riverside, CA 92502
Attn: Judy Baker
Water
(1124) LAB NO F55488
REPORTED 11/14/88
RECEIVED 10/24/88
fDENTfFIC .. ~.T!ON
BASED ON SAMPLE
Project # 240829-04, Studebaker-Loynes Landfill
As submitted
Total Organic Total organic
Carbons (TOC) Halogens (TOX)
SL-1 < 2 rng/1 1.5 rng/1
SL-4A 6 mg/1 0.72 rng/.1
SL-Blank < 2 rng/1 0.034 rng/1
~
12 rng/1 ----------
ASSOCIATED LABORATORIES
Espoy
HME/hl
NOTE: Unless notified in writing, all samples will be discarded by appropriate disposal protocol 30 days from date reported.
The reports of the Associated Laboratories are confidential property o' our clients and may not be reproduced or used for publication in part or in full ~ithout our written permission. This is for the mutual protection of the publ-.:, our clients, and ourselves.
TESTING & CONSUi..TING
Chemtcof •
Microbtofogtcoi •
EnVIronmental •
,--
{
\
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED
PHONE (714) 684·1881
LABORATORIES
3215 CHICAGO AVE.
ESTABLISHED II!Oe
EDWARD S. BABCOCK & SONS, INC.
P.O. BOX 432
RIVERSIDE. CALIFORNIA 92502
11!28/88
To: International Tech. Corp.
174Gl Derian Avenue Suite 190
Irvine, CA 92714
r~~b No. 881021-210
Attn: David L. Guth
Sample Marked:
Pj#240829-04
Studebal\er-Lo:rnes
Landfill t--ater sample ESB
~avel bl~
Parameter Name
Total Hardness as CaCOJ
_Calcium (Ca)
gnesium (Mg)
/
lium (Na)
.1:-'otassium (K)
Total Cations
Total Alkalinity as Cn.COJ
Hydroxide (OH)
Carbonate (COJ)
Bicarbonate (HCOJ)
Sulfate (S04)
Chloride (Cl)
Nitrate (NOJ)
Total Anions
Specific Conductance
pH
Total Filterable Residue
Biochemical Oxygen DemandS
Chemical Oxygen Demand
Fluoride (F)
Oil and Grease
Total Phosphorus (P)
Silica (Si~)
Results
5 mg/L
2 mg/L
<1 mg/L
<1 mg/L
<1 mg/L
0.10 me/L
2 mg/L
none mg/L
none mg/L
3 mg/L
<1 mg/L
<1 mg/L
<1 mg/L
0.10 me/L
10 l..lffi}lo/cm
8. 2 units
10 rng/L
<1 mg/L
<5 mg/L
<0.1 mg/L
<1 mg/L
<0.01 m.g/L
<1 mg/L
Invoice No. 91699
Chain
Parameter Name
Antimony (Sb)
Arsenic (As)
Barium (Ba)
Beryllium (Be)
Cadmium (Cd)
Submitted
DLG
10/21/88
13:30
of Custody
Total Chromium (Cr)
Cobalt (Co)
Copper (Cu)
Iron (Fe)
Lead (Pb)
~!anganese ( l"ln)
~lolyb::l.enum ( ~1o)
Nickel (Ni)
Silver (Ag)
Thallium (Tl)
Vanadium (V)
Zinc (Zn)
I Sampled
DLG
10/18/88
am
on file: y
Results
<0.2 rng/L
<0.01 m,t;/L
<0. 1 n!,g/L
<0.01 mg/L
<0.001 rng/L
<0.01 mg/L
<0.01 ITlg/L
<0.01 mg/L
<0.01 mg/L
<0.01 mg/L
<0.01 mg/L
<0.05 mg/L
<0. 01 n~/L
<0.01 rng/L
<0.05 rn.<;/L
<0.05 nlg/L
<0.01 rng/L
Notes: l"letals analyses run on sample filtered and presen:ed. in field. cc:
7 I
)
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1 ;oe
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P 0 BOX 432
RIVERSIDE, CALIFORNIA 92502
To: 5 December, 1988
International Tech. Corp.
17461 Derian Ave., Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Parameter
oooooOoooOooo-ooooooO"N~-oRo--oo--oo-0
Acetone
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethylvinyl ether
Chloroform
Chloromethane
bis (2-Chloroethyl) ether
Dibromochloromethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethyl Benzene
Methylene chloride
Methyl Ethyl Ketone
Methyl Isobutyl Ketone
1,1.2,2-Tetrachloroethane
Tetrachlor6ethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
Lab No. 881021-192
Invoice No. 9469fi
By
Date
Time
/124082 9-04
?. u bfll. b .. tt~<) ..... -s nrn pl c c
DLG DLG
10/21/88 10/18/8
13:30
Test Method: EPA 502.2
l?...§: .. t..§:S:_.ti() n ... ~ i m i t. ( u g I L l
1 . 00
0.50 0.50
0.50 0.50
O.GO
0.50 0.50
"1.00
0.50 0.50
5.00 0.50
0.50 0.50
0.50 0.50
0.50 0.50
0.20 0.50
0.50 0.50
0.50 O.:iO
0.50 5.00
5.00 0.50
0.:50
0.50 0.50
0.50 0.50
O.GO
1. 00
0.50 ND = None Detected Date Analysis Completed: 11/04/88 Chain of Custody on File Ed!:l~f[fd;7fJ,nS","
Inc.
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED
~~~~-~- ~---- ~ -~~~--------~---~ ~~----- -~
( ) PHONE (714) 664-1681
LA BORA TORIES
ESUBLISHEO tgoe
EDWARD S. BABCOCK & SONS, INC.
i
)
3215 CHICAGO AVE. P 0. BOX 432
RIVERSIDE, CALIFORNIA 9250f>a.te of Report: 11/28/88
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked: Pj#240829-04
Studebaker-Loynes
~ter sample
Lab No. 881021-228
Invoice No.. 94702
Customer No. in0292
Sul::mitted
By DLG
Date 10/21/88
Time 13:30
Sampled
DLG
10/18/88
am
Chain of Custody on file: Y
Base Neutral and Acid Extractable Compounds
( EPA Method 625 )
ParMeter &esults( ~g/L ) ParMeter Results( ~g/L ) Paraaeter Results ( ug/L ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, Base /lieu tra.l KI tnc tab 1 e1 ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, Acenaphthene Nil 4,4'-DDD Nil Hexachlorobentene ND
Acenaph thylene NO 4,4'-0DB Nil Hexachlorobut!diene Nil Anthracene NO 4,4'-DOT NO Hexachloroethane Nil
Aldrin liD Dibenzo(a,h)anthracene liD Ideno(l,2,3-cd)pyrene ND Bente( a) anthracene liD Di-n-butylphtbalate liD Isophorone liD Benzo(b) fluoranthene ND 1,3-0ichlorobenzene Nil Naphthalene Hi) Benzo(k)fluoranthene Hi) 1,2-0ichlorobenzene liD Nitrobentene liD Benzo(a)pyrene liD 1,4-Dichlorobeozene liD N-Nitrosodi-n-propylanine NO Benzo(ghi)perylene liD 3,3'-0ichlorobenzidine Hi) PCB-1015 liD Benzyl butyl phthalate liD Dieldrin liD PCB-1221 ND
b-BHC ND Diethyl phthalate Hi) PCB-1232 liD
HHC ND Di~etbyl phthalate ND PCB-IZH ND
Bis(2-chloroethyl)ether ND 2,4-Dinitrotoluene liD PCB-1248 NO Bis(2-cbloroethoxy)~ethane NO 2,6-Dinitrotoluene NO PCB-1254 NO Bis(2-etbylhexyl)phthalate NO Di-n-octylphthalate Hi) PCB-1250 liD Bis(Z-chloroisopropyl)etber liD Endosulfan sulfate liD Phenanthrene liD 4-Bromophenyl phenyl ether HD Bndrin aldehyde NO Pyrene NO Chlordane ND Fluoranthene liD Toxaphene liD
2-Cbloronaphthalene ND Fluorene ND 1,2,4-TrichlorobenEene Hi) 4-Chlorophenyl phenyl ether ND Heptachlor NO
Chrysene Hi) Heptachlor eporide Hi)
......................................... Acid Kxtraclables ·············································· (-Chloro-3-~ethylphenol liD 2,4-0initropbenol liD Pentachlorophenol ND Z-Chlorophenol ND Z-Hetbyl-4,6-dinitropbenol ND Phenol N1l 2,4-Dichlorophenol HD 2-H i tropheno l ND 2,4,5-Trichlorophenol ND 2,4-Dimethylphenol ND 4-Nitrophenol liD
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, Addition.al Kitraclable Puueten ······································· BenLidine ND Kndosulfan f N1l Herachlorocyclopentadiene ND a-BHC NO Bndosulfan ri ND N-Hi trosodi11ethy !Mine NO
y-BHC Hi) Bndrin HD N-Nitrosodiphenylaaine N1l
ND=None detected, detection limit: 10 ug/L NI=Not identifiable Date analysis completed: 11/19/88
Notes:
cc: EDWARD S. BA.BCCXX &. SONS. INC.
.Y;;ow,
\__<
/-- \
~'
ED~ARD S. BABCOC~ & SONS, INC.
toj. ·No. l'roj ect Nzme l
!!t'off)_'f _ 5-ruoe-B/IJI.£'(1._-LYAI~-'3 ,f-vOFn-L
.
~ta. No.- I Data I TiDe I .D
_ ~I StAtion Location
(:>
St. -t
Sl-YA
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ll~-l/t"'1f0
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No.
of
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7 ~1.lJ=I~Z(flj~
Received by: - ·
~~&I!Atur~)
{!_ __ ~~
~eltnquisned by: I Date/Tice
(Si&nAture) I
Receiv~ by:
(Sianature)
")
'----•'
0~ QjR_
l ''-J ~-
/ \ ~ 0 '
v1,., l~lt--'l._..-1.....- 1..-- l/1iMLs---51/JJ.S.$t:LJ v 1 vi _.I o.-- 1.- 1-~ l7/{.,. Lr. G.{ ... J;. f[,)'f, tf/J<:_A> I I. I I\ lfti .. M·.J<.A,.~ 11 ~zn
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yjv I vlv I J lv l y ( CLJ17~. R, ~r_
'fi~LYLe AI:
g,u 'lo "f1 eciWF
O~oa_A. /'f7o3s
Relinquhhed by: I D~te{T1me I Received by
(Si&nature) (Signature)
Relinquhhed by: I Date/Time I Received by
(Sianature) I (Si&nAture)
~eltnquished by: IDate/Time
(Sianature) I
Received for L.abontory ~ite[Tice
(S1an.ature) I I
Rec.trk"s
Chain of Custody Record
·.
I :
I
SECOND QUARTER SAMPLING
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 19013
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#2-10827-04 QM-Marltet
Place SWATs water sample
~1P-1
P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
02/27/89
Chain
Parameter Name Results Parameter Name
EPA Method 9060
Total Organic Carbon
Practical Quantitation.Limit
Notes:
cc:
24 mg/L
1.0 mg/L
Lab No. 890203-320
Invoice No. 97431
Submitted Sampled
DLG DLG
02/03/89 jOl/31/89
9:10 I
of Custody on file: Y
Results
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1908
PHONE (714} 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
To: International Tech. Corp.
17161 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
P j#240827 -04 @'H'1arli::et
Place SWATs water sample
:VlP-1
P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
02/27/89
Chain
Lab No. 890203-314
Invoice No. 97431
Submitted I Sampled
DLG IDLG '
02/03/89 !Ol/31/89
9:10 I
of Custody on file: Y
Parameter Name Results Parameter Name Results
EPA :VIethod 9020
Total Organic Halides
Practical Quantitation Limit
~otes:
)
I CC:
0.57 mg/L
0.25 mg/L
EDWARD S. BABCOCK & SONS, INC.
C/JL~-~
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1908
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 Qr-1-Market
Place SWATs hater sample
tvlP-2
P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
02/27/89
Chain
Lab No. 890203-321
Invoice No. 97431
Submitted I Sampled
DLG IDLG 02/03/89 01/31/89
9:10 I
of Custcx:ly on file: Y
Parameter Name Results Parameter Name Results
EPA Method 9060
Total Organic Carbon
Practical Quantitation Limit
)
Notes:
cc:
12 mg/L
1.0 mg/L
EDWARDS. BABCOCK & SONS, INC.
~~~
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
ESTABLISHED 1906 CALIF. DHS CERTIFIED
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 QM-Market
Place SWATs Hater sample
l'1P-2
P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
02/27/89
Lab No. 890203-315
Invoice No. 97431
Submitted I Sampled
DLG
02/03/89
9:10
DLG
01/31/89
Chain of Custody on file: Y
Parameter Name Results Parameter Name Results
EPA Nethod 9020
Total Organic Halides
_Practical Quantitation Limit
)
-\Notes:
cc:
3.0 mg/L
1.0 mg/L
EDWARD S. BABCOCK & SONS, INC.
~~
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1906
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 Q\'1-Ma.rket
Place SWATs water sample
MP-3
P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
02/27/89
Chain
Lab No. 890203-322
Invoice No. 97431
Submitted Sampled
DLG DLG
02/03/89 01/31/89
9:10 I
of Custody on file: Y
Parameter Name Results Parameter Name Results
EPA Method 9060
Total Organic Carbon
Practical Quantitation Limit ) .
Notes:
cc:
46 mg/L
1.0 mg/L
EDWARDS. BABCOCK & SONS, INC.
~~
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHEO 1908
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 Q."I-Market
Place SWATs >v-ater sample
::VlP-3
P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
02/27/89
Chain
Lab No. 890203-316
Invoice No. 97431
Submitted Sampled
DLG DLG
02/03/89 01/31/89
9:10 I
of Custody on file: Y
Parameter Name Results Parameter Name Results
EPA Method 9020
Total Organic Halides
Practical Quantitation Limit
)
;..)'otes:
cc:
2.7 rngjL
0.5 rng/L
EDWARD S. BABCOCK & SONS, INC.
~1'14y
( )
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
ESTABLISHED 1908 CALIF. DHS CERTIFIED
PHONE (714) 684·1681
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
P j#240827 -04 cyv1-Ma.rket
Place SWATs ~ater sample
~lP-4
P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
02/27/89
Chain
Lab No. 890203-323
Invoice No. 97431
Submitted j Sampled
DLG IDLG
02/03/89 101/31/89
9:10
of Custody on file: Y
Parameter Name Results Parameter Name Results
EPA Method 9060
Total Organic Carbon
Practical Quantitation Limit
Notes:
cc:
15 mg/L
1.0 rng/L
EDWARDS. BABCOCK & SONS, INC.
~~
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
ESTABLISHED 1908 CALIF. DHS CERTIFIED
PHONE (714) 684-1881
LABORATORIES
EDWARDS_ BABCOCK & SONS, INC.
3215 CHICAGO AVE.
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 QM-~arket
Place SWATs water sample
MP-4
P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
02/27/89
Chain
Lab No. 890203-317
Invoice No. 97431
Submitted
I
Sampled
DLG jDLG
02/03/89 I Ol/31/89
9:10 I
of Custody on file: Y
Parameter Name Results Parameter Name Results
EPA Method 9020
Total Organic Halides
Practical Quantitation Limit
~otes:
)
cc:
1.0 mg/L
0.25 mg/L
EDWARD S. BABCOCK & SONS, INC.
rJt~~
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1906
,- . \
I
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 Cl-'1-Market
Place SWATs water sample
MP-5
P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
02/27/89
Chain
Lab No. 890203-324
Invoice No. 97431
Submitted I Sampled
DLG DLG
02/03/89 101/31/89
9:10 I
of Custody on file: Y
Parameter Name Results Parameter Name Results
EPA Method 9060
Total Organic Carbon
Practical Quantitation Limit ) .
Notes:
cc:
8.6 mg/L
1.0 mg/L
EDWARDS. BABCOCK & SONS, INC.
r/Jiu:. /(2uL,.:-.
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
ESTABLISHED 1906 CALIF. DHS CERTIFIED
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 QM-Market
Place SWATs h-ater sample
:-IP-5
P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
02/27/89
Chain
Lab No. 890203-318
Invoice No. 97431
Submitted I Sampled
DLG IDLG
02/03/89 I 01/31189
9:10 I
of Custody on file: Y
Parameter Name Results Parameter Name Results
EPA Method 9020
Total Organic Halides
)Tactical ~antitation Limit
Notes:
cc:
0.65 mg/L
0.25 mg/L
EDWARDS. BABCOCK & SONS, INC.
9/M~~
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1908
PHONE (714) 684-1881
LABORATORIES
EDWARD s_ BABCOCK & SONS, INC.
3215 CHICAGO AVE.
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 @'!-Market
Place SWATs water sample
~IP- Blank ( _.trrowhead D I
Kater)
P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
02/27/89
Chain
Lab No. 890203-325
Invoice No. 97431
Submitted I Sampled
DLG IDLG
02/03/89 !Ol/31/89
9:10 I
of Custody on file: Y
Parameter Name Results Parameter Name Results
EPA Method 9060
Total Organic Carbon
lractical Quantitation Limit
ND = None Detected at PQL.
Notes:
cc:
ND rng/L
1. 0 rngjL
EDWARD S. BABCOCK & SONS, INC.
r;a~~
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1906
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
P ji¢240827 -04 QM-~Jarket
Place SWATs water sample
:viP-Blank (Arrowhead DI
water)
P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
02/27/89
Chain
Lab No. 890203-319
Invoice No. 97431
Submitted Sampled
DLG DLG
02!03/89 01/31/89
9:10 I
of Custody on file: Y
Parameter Name Results Parameter Name Results
EPA Hethod. 9020
Total Organic Halides
Practical Quantitation Limit
\ill = None D~tected at PQL.
Notes:
cc:
]\JD mgJL
0.010 mg/L
EDWARD S. BABCOCK & SONS, INC.
rJA.o----~
'BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
ESTABLISHED 1908 CALIF. DHS CERTIFIED
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 QM-Market
Place SWATs Water
Sample MP-1
Parameter Name Results
Calch.nn (Ca.) 230 mg/L
sodh.un (Na) 5800 mg/L
·· "?otassit.un 'K) 214 mg/L
.lotal Alkalinity as CaC03 715 mg/L
Hydroxide (OH) none mg/L
Carbonate (~) none mg/L
Bicarbonate (HC03 ) 872 mg/L
Sulfate (S04) 2200 mg/L
Chloride (Cl) 9000 mg/L
Nitrate Nitrogen (N03-N) 12 mg/L
Fluoride (F) 2.0 mg/L
Biochemical Oxygen DemandS 4 mg/L
Chemical Oxygen Demand 100 mgjL
Oil and Grease 8 mg/L
Total Phosphorus (P) 2.8 mg/L
pH 7.4 units
Specific Conductance 27,300 ~o/cm
Total Filterable Residue 19,300 mgjL
03/01/89
Lab No. 890203-296
Invoice No. 97 429
Submitted Sampled
DLG
02/03/89
9:10
DLG
1/31
Chain of Custody on file: Y
Parameter Name Results
Antimony (Sb) <0.05 mg/L
Arsenic (As) 0.01 mg/L
Baritm (Ba) <0.1 mg/L
Beryllitm (Be) <0.01 mg/L
Boron (B) 3.3 mg/L
Cadmitm (Cd) (0.01 mg/L
Total Chromium (Cr) <0.01 mg/L
Cobalt (Co) 0.01 mg/L
Copper (Cu) 0.03 mg/L
Iron (Fe) 0.04 mg/L
Lead (Pb) <0.03 mg/L
Manganese (Mn) 0.66 mg/L
Mercury (Hg) <0.001 mgjL
Molybienum (Mo) <0.1 mg/L
Nickel (Ni) 0.01 mg/L
Selenium (Se) <0.05 mg/L
Silver (Ag) <0.01 mg/L
Zinc (Zn) 0.02 mg/L
Thallium (Tl) 0.2 mg/L
Notes: Metals run on samples filtered and preserved in field.
Oil and Grease preserved w/sulfuric acid.
cc:
EDWARDS. BABCOCK & SONS, INC.
~fllLr
'BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED
-~---- --~------ --- -- -
ESTABLISHED 1906
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE. CALIFORNIA 92502
To: Internati<mal Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 QM-Market
Place SWATs Water
Sample MP-2
Parameter Name Results
Calcium (Ca) 760 mg/L
Sodium (Na) 30,500 mg/L
Potassium. (K) 860 mg/L
Total Alkalinity as Cac::Da 632 mg/L
~jydroxide (-OH) none mg/L
~arbonate (COa) none mg/L
Bicarbonate (HC03 ) 772 mg/L
Sulfate (804) 10,500 mg/L
Chloride (Cl) 41,000 mg/L
Nitrate Nitrogen (NOa -N) 30 mg/L
Fluoride (F) 1.0 mg/L
Biochemical Oxygen Demand~ 4 mg/L
Chemical Oxygen Demand <50 mg/L
Oil and Grease 4 mg/L
Total Phosphorus (P) 1.4 mg/L
pH 7.4 units
Specific Conductance 95,900 j.IIIlho/cm
Total Filterable Residue 73,500 mg/L
03/01/89
Lab No. 890203-297
Invoice No. 97 429
Submitted Sampled
DLG DLG
02/03/89 1/31
9:10
Chain of Custody on file: Y
Parameter Name Results
Antimony (Sb) <0.05 mg/L
Arsenic (As) <0.1 mg/L
Barium (Ba) <0.1 mg/L
Beryllium (Be) <0.1 mg/L
Boron (B) 20 mg/L
Cadmium. (Cd) <0.01 mg/L
Total Chromium (Cr) <0.01 mg/L
Cobalt (Co) 0.1 mg/L
Copper (Cu) 0.15 mg/L
Iron (Fe) 0.10 mg/L
Lead (Pb) 0.2 mg/L
Manganese (Mn) 2.0 mg/L
Mercury (Hg) <0.001 mg/L
Molybdenum (Mo) <1 mg/L
Nickel (Ni) 0.2 mg/L
Selenium (Se) <0.1 mg/L
Silver (Ag) <0.05 mg/L
Zinc (Zn) 0.05 mg/L
Thallium. (Tl) 2.0 mg/L
Notes: Metals run on samples filtered and preserved in field.
Oil and Grease preserved w/sulfuric acid.
cc:
EDWARD S. BABCOCK & SONS, INC.
~;r!uLy?
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED
PHONE (714) 684·1881
LABORATORIES
3215 CHICAGO AVE.
ESTABLISHED 1906
EDWARD S. BABCOCK & SONS, INC.
P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
03/01/89
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Lab No. 890203-298
Attn: David L. Guth
Sample Marked:
Pj#Z40827-04 QM-Market
Place SWATs Water
Sample MP-3
Parameter Name
Calcium ( Ca)
Sodium (Na)
Potassium (K)
Total Alkalinity as Ca~
·:rydroxide fOH)
I
..:arl::x:>na te ( COa )
Bicarbonate (HOOa )
Sulfate (804)
Chloride (Cl)
Nitrate Nitrogen (NOa-N)
Fluoride (F)
Biochemical Oxygen Demands
Chemical Oxygen Demand
Oil and Grease
Total Phosphorus ( P)
pH
Specific Conductance
Total Filterable Residue
Results
410 mg/L
18,000 mg/L
450 mg/L
2788 rng/L
none mgjL
none mg/L
3401 rng/L
2400 mg/L
·35,000 mg/L
6.1 mg/L
2.3 mg/L
7 mg/L
<50 mg/L
7 mg/L
0.7 rng/L
7.4 nnits
65,400 j.!lllho/cm
43,000 mg/L
Invoice No. 97 429
Submitted Sampled
DLG
02/03/89
9:10
DLG
1!31
Chain of CUstody on file: Y
Parameter Name
Antimony ( Sb)
Arsenic (As)
Barium (Ba)
Beryllium (Be)
Boron (B)
Cadmium ( Cd)
Total· Chromium ( Cr)
Cobalt (Co)
Copper (Cu)
Iron (Fe)
Lead (Pb)
Manganese ( Mn)
Mercury (Hg)
Molybdem.Dil (Mo)
Nickel (Ni)
Selenium (Se)
Silver (Ag)
Zinc (Zn)
Thallium (Tl)
Results
<0.05 .mg/L
0.04 rng/L
<2 mg/L
0.01 mg/L
9.2 mg/L
<0.01 mg/L
<0.01 mg/L
0.02 mg/L
0.06 mg/L
0.18 mg/L
<0.05 mg/L
0.95 mg/L
<0.001 mg/L
0.4 mg/L
0.02 mg/L
<0.1 mg/L
<0.01 mg/L
0.01 mg/L
0.3 mg/L
Notes: Metals rnn on samples filtered and preserved in field.
Oil and Grease preserved w/sulfuric acid.
cc:
. BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1906
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 QM-Market
Place SWATs Water
Sample MP-4
ParaiEter Name Results
Calcium (Ca) 290 mgjL
Sodium (Na) 4600 mgjL
Potassium (K) 190 mg/L
\otal Alkalinity as Ca<:Xl:! 1160 mg/L
Jydroxide (OH) none mg/L
Carbonate (OOa) none mgjL
Bicarbonate (H003) 1415 mg/L
Sulfate (S04) 1815 mg/L
Chloride (Cl) 6900 mg/L
Nitrate Nitrogen (NOa-N) 9.3 mgjL
Fluoride (F) 2.2 mg/L
Biochemical Oxygen Demands 5 mgjL
Chemical Oxygen Demand 100 mg/L
Oil and Grease <1 mgjL
Total Phosphorus (P) 1.4 mgjL
pH 7.4 tmits
Specific Conductance 23,000 umho/cm
Total Filterable Residue 14,150 mg/L
03/01/89
Lab No. 890203-299
Invoice No. 97 429
Sul:mitted
DLG
02/03/89
9:10
I Sampled
DLG
11/31
Chain of Custody on file: Y
Parameter Name Results
Antimony (Sb) <0.1 mgjL
Arsenic (As) <0.01 mg/L
Barium (Ba) <0.1 mgjL
Beryllium (Be) <0.01 mg/L
Boron (B) 3.8 mg/L
Cadmium (Cd) <0.01 mg/L
Total Chromi urn (Cr) <0.01 mg/L
Cobalt (Co) <0.01 mg/L
Copper (Cu) 0.03 mg/L
Iron (Fe) 0.04 mg/L
Lead (Pb) <0.05 mg/L
Manganese (Mn) 2.0 mg/L
Mercury (Hg) <0.001 mg/L
Molybdenum (Mo) 0.1 mg/L
Nickel (Ni) 0.02 mg/L
Selenium (Se) <0.05 mg/L
Silver (Ag) <0.01 mg/L
Zinc (Zn) 0.01 mgjL
Thalli tun (Tl) 0.1 mg/L
Notes: Metals run on samples filtered and preserved in field.
Oil and Grease preserved w/sulfuric acid.
cc:
EDWARDS. BABCOCK & SONS, INC.
~;TUy
\.
' BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1906
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE. CALIFORNIA 92502
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth.
Sample ~ed:
Pj#240827-04 QM-Market
Place SWATs Water
Sample MP-5
Parameter Name Results
Calcium (Ca) 140 mg/L
Sodium (Na) 4900 mg/L
Potassium (K) 210 mg/L
Total Alkalinity as CaCOa 705 mg/L
'fydroxide 'OH) none mg/L
.~arbonate (CO.d none mg/L
Bicarbonate (HCOa) 860 mg/L
Sulfate (S04) 1240 mg/L
Chloride (Cl) 7000 mg/L
Nitrate Nitrogen (NOa -N) 9.3 mg/L
Fluoride (F) 1.8 mg/L
Biochemical Oxygen DemandS 9 mg/L
Chemical Oxygen Demand 50 mgjL
Oil and Grease 1 mg/L
Total Phosphorus (P) 5.6 mg/L
pH 7.7 units
Specific Conductance 23,000 J.!IIlho/cm
Total Filterable Residue 12,800 mg/L
03/01/89
Lab No. 890203-300
Invoice No. 97 429
Sul:mitted Sampled
DLG DLG
02/03/89 1/31
9:10
Chain of Custody on file: Y
Parameter Name Results
Antimony (Sb) <0.05 mg/L
Arsenic (As) <0.01 mg/L
Barium (Ba) <0.1 mg/L
Beryllium (Be) <0.01 mg/L
Boron (B) 5.0 mg/L
Cadmium (Cd) <0.01 mg/L
Total Chromium (Cr) <0.01 mg/L
Cobalt (Co) <0.01 mg/L
Copper (Cu) 0.02 mg/L
Iron (Fe) 0.03 mg/L
Lead (Pb) <0.05 mg/L
Manganese (Mn) 0.4 mg/L
Mercury (Hg) <0.001 mg/L
Molybdenum (Mo) 0.1 mg/L
Nickel (Ni) <0.01 mg/L
Selenium (Se) <0.05 mg/L
Silver (Ag) <0.01 mg/L
Zinc (Zn) 0.02 mg/L
Thallium (Tl) 0.1 mg/L
Notes: Metals run on samples filtered and preserved in field.
Oil and Grease preserved w/sulfuric acid.
cc:
EDWARD S. BABCOCK & SONS, INC.
~~
(
• BACTERIOLOGY
WATER TESTING
---- -------
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1906
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 QM-Market
Place SWATs Water
Sample MP-Blank Arrowhead
Parameter Name Results
Calcium (Ca) 1 mg/L
Sodium (Na) <1 mg/L
Potassium (K) <1 mg/L
Total Alkalinity as CaOOa 2.5 mg/L
- Rydroxide (.OH) none mg/L
.ax bonate (OOa) none mg/L
Bicarbonate ( Hcx:h ) 3 mg/L
Sulfate (804) <1 mg/L
Chloride (Cl) <1 mg/L
Nitrate Nitrogen (NOa-N) <0.1 mg/L
Fluoride {F) 0.1 mg/L
Biochemical Oxygen Demands <2 mg/L
Chemical Oxygen Demand 5 mg/L
Oil and Grease <1 mgjL
Total Phosphorus (P) <0.02 mg/L
pH 6.4 units
Specific Conductance 3. 1 IJ.lllho/cm
Total Filterable Residue 5 mg/L
03/01/89
Lab No. 890203-301
Invoice No. 97429
Submitted Sampled
DLG DLG
02/03/89 1/31
9:10
Chain of Custody on file: Y
Parameter Name Results
Antimony (Sb} <0.01 mg/L
Arsenic (As) <0.01 mg/L
Barium (Ba) <0.1 mg/L
Beryllium (Be) <0.01 mg/L
Boron (B) <0.1 mg/L
Cadmium (Cd) <Q.001 mg/L
Total Chromium (Cr) <0.01 mg/L
Cobalt (Co) <0.01 mg/L
Copper (Cu) <0.01 mg/L
Iron (Fe) 0.03 mg/L
Lead (Ph) <0.005 mg/L
Manganese (Mn) <0.01 mg/L
Mercury (Hg) <0.001 mg/L
Molybdenum (Mo) <0.1 mg/L
Nickel (Ni) <0.01 mg/L
Selenium (Se) <0.005 mg/L
Silver (Ag) <0.01 mg/L
Zinc (Zn) 0.02 mg/L
Thallium (Tl) <0.1 mg/L
Notes: Metals run on samples filtered and preserved in field.
Oil and Grease preserved w/sulfuric acid.
cc:
EDWARDS. BABCOCK & SONS, INC.
~~?
- ' ( )
BACTi!RIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1908
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
04/07/89
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked: SWATs Pj#240827-04
QM-Market Place water
sample MP-1
P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
Lab No. 890203-302
Invoice No. 97430
Customer No. in0292
Suhnitted
By DLG
Date 02/03/89
Time 9:10
Sampled
DLG
01/31/89
Chain of Custody on file: Y
Purgeable Halocarbons and Aromatics
EPA Method 502 . 2
Results Results
Parameter ~/L Parameter llg/L
Benzene ND trans-1,2-Dichloroethene ND
Bromodichloromethane ND 1,2-Dichloropropane ND
Bromoform ND cis-1,3-Dichloropropene ND
Bromomethane ND trans-1,3-Dichloropropene ND
Carbon tetrachloride ND Ethyl benzene ND
Chlorobenzene ND Methylene chloride ND
Chloroethane ND 1,1,2,2-Tetrachloroethane ND
2-Chloroethylvinyl ether ND* Tetrachloroethene ND
Chloroform ND Toluene ND
Chloromethane ND 1,1,1-Trichloroethane ND
Dibrornochloromethane ND 1,1,2-Trichloroethane ND
1,2-Dichlorobenzene ND Trichloroethene ND
1,3-Dichlorobenzene ND Trichlorofluoromethane ND
1,4-Dichlorobenzene ND Vinyl chloride ND*
Dichlorodifluoromethane ND Methyl Ethyl Ketone 42**
1,1-Dichloroethane ND Methyl Isobutyl Ketone NDU
1,2-Dichloroethane ND Xylenes, total ND
1,1-Dichloroethene ND Xis-Jrt2-Dichloroethene ~ cet e
ND=None detected, detection limit: 0.5 ~/L NI=Not identifiable : Date analysis completed: 02/08/89
Notes: * FQL = 1. 0~/L ** FQL = 5 . 0~/L *** PQL = 10~/L cc:
F..dJ.m.rd s. Babcock & Sons, Inc.
L~LC~
(
BACT!RIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
ESTABLISHED 1906 CALIF. DHS CERTIFIED
PHONE (714) 684-1881
1 LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
04/07/89
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked: SWATs Pj#240827-04
'-l-1-Ma.rket Place water
sample MP-2
P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
Lab No. 890203-303
Invoice No. 97430
Customer No. in0292
Submitted
By DLG
Date 02/03/89
Time 9:10
Sampled
DLG
01/31/89
Chain of Custody on file: Y
Purgeable Halocarbons and Aromatics
Parameter
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethylvinyl ether
Chloroform
Chloromethane
Dibromochloromethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
EPA Method 502. 2
Results
llg/L
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Parameter
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethy 1 benzene
Methylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Methyl Ethyl Ketone
Methyl Isobutyl Ketone
Xylenes, total
cis-1,2-Dichloroethene
Acetone.
Results
~/L
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND*
NDU
ND**
ND
ND
NDk**
ND=None detected, detection limit: 0.5 llg/L NI=Not identifiable · Date analysis completed: 02/08/89
Jbtes: * PQL = 1. Ollg/L ** PQL = 5. Ollg/L
cc:
*** PQL = 101lg/L
Edward s. Babcock & Sons, Inc.
L~ lCb-f/
II
(
BACT~IOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1908
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
04/07/89
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked: SWATsPj#240827-04
QM-Market Place water
sample MP-3
P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
Lab No. 890203-304
Invoice No. 97430
Customer No. in0292
Sul:mitted
By DLG
Date 02/03/89
Time 9:10
Sampled
DLG
01/31/89
Chain of Custody on file: Y
Purgeable Halocarbons and Aromatics
EPA Method 502. 2
Results Results
Parameter
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethylvinyl ether
Chloroform
Chloromethane
Dibromochloromethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
J..ig/L
220
ND
ND
ND
ND
ND
ND
ND*
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND=None detected, detection limit:
Date analysis completed: 02/08/89
Parameter
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethy 1 benzene
Methylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Methyl Ethyl Keotne
Methyl Isobutyl Keotne
Xylenes, total
cis-1,2-Dichloroethene
Acetone
J..ig/L
ND
ND
ND
ND
20 ND
ND
ND
10 ND
ND
ND
ND
ND*
NDU
8.4**
3.8 ND
ND***
0.5 ~/L NI=Not identifiable
_ jotes: * FQL = 1. Ojlg/L ** FQL = 5. Ollg/L *** FQL = lOilg/L cc:
Edward s. Babcock & Sons, Inc.
La~£.0r!L ))
)
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
ESTABLISHED 1908 CALIF. DHS CERTIFIED
PHONE (714) 684-1881
LABORATORIES EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
04/07/89
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked: SWATs Pj#240827-04
QM-Market Place water
sample MP-4
P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
Lab No. 890203-305
Invoice No. 97430
Customer No. in0292
Sul::mitted
By DLG
Date 02/03/89
Time 9:10
Sampled
DLG
01/31/89
Chain of Custody on file: Y
Purgeable Halocarbons and Aromatics
Parameter
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethylvinyl ether
Chlorofonn
Chloromethane
Dibromochloromethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
EPA Method 502. 2
Results
~/L
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Parameter (
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethy !' benzene
Methylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Methyl Ethyl Ketone
Methyl Isobutyl Ketone
Xylenes, total
cis-1,2-Dichloroethene
Results
~/L
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND*
ND**
ND**
ND
ND
Acetone. 0.5 ~/L ND=None detected, detection limit: NI=Not i~fiable \ Date analysis completed: 02/08/89 .
. otes: * PQL = 1. Ollg/L ** PQL = 5. 0~/L *** PQL = 10~/L cc:
Edward s. Babcock & Sons' Inc.
L~JCfrl/
c-·.)
s..;..c"l'le:RIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1908
PHONE (714) 684-1881
LABORATORIES EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
04/07/89
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irv·ine, CA 92714
Attn: David L. Guth
Sample Marked: SWATs Pj#240827-04
'l1-Market Place water
sample MP-5
P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
Lab No. 890203-306
Invoice No. 97430
Customer No. in0292
Sul::mitted
By DLG
Date 02/03/89
Time 9:10
Sampled
DLG
01/31/89
Chain of Custody on file: Y
Purgeable Halocarbons and Aromatics
Parameter
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethylvinyl
Chloroform
Chloromethane
ether
Dibromochloromethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
·1,2-Dichloroethane
1,1-Dichloroethene
EPA Method 502.2
Results
1-lg/L
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Parameter
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethyl benzene
Methylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Methy 1 Ethy 1 Keotne
Methyl Isobutyl Keotne
Xylenes, total
cis-1,2-Dichloroethene
Acetone
Results
~/L
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND*
NDU
NDU
ND
ND
ND=None detected, detection lim.i t: 0.5 ~/L NI=Not
NO***
identifiable
Date analysis completed: 02/08/89
.t:.rotes: * FQL = 1 • 0~/L * * FQL = 5 • 01-lg/L *** PQL = 10~/L cc:
Edward s. Babcock ct. Sons J Inc.
~drERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 190e
PHONE (714) 684-1881
LABORATORIES EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
04/07/89
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked: SWATs Pj#240827-04
QM-Market Place water
sample MP-Blank
P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
Lab No. 890203-307
Invoice No. 97430
Customer No. in0292
Sul:mitted
By DLG
Date 02/03/89
Time 9:10
Sampled
DLG
01/31/89
Chain of Custody on file: Y
Purgeable Halocarbons and Aromatics
EPA Method 502.2
Results Results
Parameter
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethylvinyl ether
Chloroform
Chloromethane
Dibromochloromethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
!Jg/L
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Parameter
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethy 1 benzene
Methylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Methyl Ethyl Ketone
Methyl Isobutyl Keotne
Xylenes, total
cis-1,2-Dichloroethene
~/L
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND*
NDU
NDU
ND
Acetone
ND
NDk**
ND=None detected, detection limit:
1 Date.analysis completed: 02/08/89
1 1otes: * ~ = 1. O!Jg/L ** ~ = 5, O!Jg/L
cc:
0.5 ~/L NI=Not identifiable
*** ~ = 10~/L
J?.dt.m.rd. s. Babcock & Sons, Inc.
L~de4p£/ 2r
-
'"-- l ()~.=,3D/_) ( -31 f/ 7ZJ - 3
1 i) (- 3:-o - s,:;s)
'~\
'.__.~---
-'
Edward s. Babcock & Sons, Inc. CHAIN OF CUSTODY RECORD
3215 Chicago Avenue
Client. s NaM.ti r I r'_oP-POAATtD~ Riverside, CA 92507 (714) 684-1881 lab :Js: Q2ll . -:s-~1~· ?tL-'? Invoice No. 9]L/Z-~~ Project No. Project Name/Location Determination Requested N C Condition of Sample\q1ij~f u 0 p
01'-10<6~1- 0'1 MA-~,,e.r ft.A-c..E. $wAT 1 ~ ~3 m n r lr::; "' ~ b t c e £)adt)J.}J;-
~
0 .. Samplers: < 1..3 ':IC e a s h s
(Signature) l
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e e
-: ~
n a 1 r
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Sampled ~ e
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f r e e e .,
s Description Date Time ~ w
~ ~ ~ d d d Remarks ( ~ u s w
MP-1 WEt..L WA-Tt .. .<. '1~1g~ y v ./ ,/ v / v <3 ME'IM..s~ Sb.As .& lk Mf-Z LJE..u.. lJArtL I / / ,/ / v ,/ .,
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MP-L/ lt.JE. t.L.. LJA-n,( ,/ / ./ ~ frl z(} U-t.s~.
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MP-5 ~(... lJAf£tt.. /
y' / .,/ g MIsc.. :: Po, I soH
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MP- t3t.AtJK t)rroWHUI> t IST•'-"J> t..JAM.. ./ ~ A)o, C I Sr ~ £~ ,,It , \
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Ltt-4 Y-~/0
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t!::. rt:t··
. ~ta/T1aa Rocotvod "''~ Reltnqutahed By: Data/Tt•• Recatved By: - (,£~ - _,__ Wfl 0'~ ~~
--
~l
Reltnqutahed lly:
~
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Date/Ttaa Recetved ly:
I
······~
Data/Tt•• ~etved ly:
~A'~UUMN?
D•f• I Ttae
I ~ ~ r3 ICA3CJ -- l I , I
ACHICUL. TURAt.. CON~UL.TANT&
CNL.MIST$
APPHOYLD ~AT£R ~AbORATORV
PHONE 664.166 I
Att£A coot: 7 ••
LABORATORIES
JZ.I5 CHICAGO AVE.
EDWARDS. BABCOCK 8c SONS. INC.
P.o. aox 43Z
RW£R81C£, CALIFORNIA az,oa
BASE/NEUTRALS 'AND ACIDS
ORGANIC ANALYSES
Date of Report: __ Mar_c_h_3o_,_l9_,8,...9 ____ Lab Sample ID No. 890203-308 Laboratory signature Lab~ ----C-7-;.--L'--/)
Name: E S. Babcock & Sons. Inc. Director: £.~ ./ _f~
Name of Dav1.'d L. Guth .sampler . / Sampler: Employed By: LT. Cor!ff.
Date/Time Sample Date/Tl~e S~mple -~W~e-r-e~H-o~1d~in_g _______ Y_e_s __ Collected: 01-31-89 RecitiVed @ Lab: 2-3-89 I 0930 'Times Observed? Were all the constituents lis~t-ed~--
Test Met.hods: __ _;6:.;:2;..;;5..._/6;;..0;.;.;;8;...._ ______ . below quantified? Yes System SWATs Project No. 240827-04 System
Narne=~~----~-----------------------------------Number: _____________ __ Description of Q{.J.farket Place
Sampling Point:~---------------~~~-------County Name: _____________ ___ Name/No. Of Sample Station .source: ~-1 Number:
Date &
Time of I I I I I I I 1~1 I. I
Sample: Y.Y MMD D T ~ ~ T
Water
Type:
I I I f I I I I I I I I I I
User I I I I Submitted to S~QI
ID: By: --------
() Place a:n "X11 in box to del§te all data. tor this atationjdate/time. U REPORTING CONSTITUENT T STORET · ANALYSES OETECTIC!:
UNITS T CODE RESULTS LIMIT
Date Analyses Co~leted 73672 s19 1 o13 1 11o I I I I I
Y Y M K D D
Analvzinq Aqency Code (Lab) 28 I I I I
Intensive surve_y Nutnber 116 I I I !
ug/L Acenaphthane 34205 I N n ST. I o · o
uq/L Acenaphthvlene 3~200 I 1 N n 51 • I o I o
uq/L Anthracene 34220 _l _j_ 1 N 1 n 5T. I o I o
uq/L Aldr~n 39330 I 1 N 11 o I . I o 11
uq/L Benzo a )anthracene 34526 I , N ll 1 0 I • I o I o uq/L Benzo b )fluoranthene 34230 ; N I f) 1 0 I • I 0 I 0 uq/L Benzo k lfluoranthene l4242 _I N n l 0 I • I 0 I 0 uq/L Benzo a )pyrene 34247 _j _l 1 N n 1 0 I • I 0 I o
uq/L Benzo ghi) pe_nrlene 34521 I I I N I) 1 01. IQJ_Q_ uq/L Benzyl butvl phthalate 34292 _j I IND 1 ol.lolo
ug/L' B - DHC 39338 N ll o I • I 0 15
uq/L 6 -·BHC 34259 N J!) o I • IOI5
ug/L b~s(2-chloroethvl)ether 34273 _t _t 1N1D sT. I o 10 ug}L. bis(2-chloroethoxv)rnethane 34278 _i _l N D 51 . I 0 I 0 uq/L bis_(2-ethv1hexyl}phthalate 39100 I N IJ 5 I • I o I o uq/L b~s(2-chloroisopropyl)ether 34203 _1_. N n 51.1010 ucr}L 4-Bromophenvl phenvl ether 3.: 63 6 1 • N n 5 I • I o I o uq/L Chlordane 39350 I I , N ]) 0 I. IO 15
ug/L 2-Chloronaphthalene 34581 I "" n 51.10fo
OHS 8351 a {l/87)
r----\ . I
/
(
Base;Neutrals and Acids (Continued)
SYSTEM NAME & NUMBER I.T.Com. SWATs P;.t!240827-04 Q~-!1arket Place MP-1
REPORTING
UNITS
UO/L
ug/L
uo/L
ug_/L
ugjL
ug/L
uq/L
uq/L
Ug/L
uq/L
uq;L
Lab No. 890203-308
ADDITIONAL EXTRACTABLE PARAMETERS
CONSTITUENT T STORET ANALYSES
T CODE RESULTS
Phenol 3469~ I N 1 D
2 4,6-Trichlorophenol 34621 I _j N D
Be:nzidine 39120 J I N lJ
a - BHC 39337 ~N D
y - BHC 39340 I 0 1 • 10 ,2
Endosulfan I 34361 I I N,JJ
Endosulfan II 34356 j_ _l_ _Nln
Endrin 39390 l_ _l ,_N _D
Hexachlorocyclopentadiene 34386 N1D
N-Nitrosodimethylarnine 3~438 I N D
H-Nitrosodiphenylarnine 34433 I I N j__D
Note any unidentified peaks below.
OHS 8351 B (3/17)
PAGE 3 OF 3
DE·rEC':'!ON
LIMIT
I 151.! 0 I 0
I 151. I 0 i o
I 151. I 0 I o
I I o I. I o 11
I I 01. l 0 !1
I I o I. I o 11
I I o I . I o 11
I I 0 I . I o 11
1210j.IOIO
I I 51. I OJ 0
I I 51. I o; o
A..;HICUL. TVHA'-. CON:.O\.IL fANT&
..;"~,. •• u:.r~
A~~NUVLO ~ATLH ~AUQHAfOHl
PHONE o84·1 88 I
AHLA COD~ 7 14 ·EDWARD 5. BABCOCK & SONS. INC.
P. a. aox 43Z
. L.AUOAA.TOAIES RIV .. R.IO ... CAL.lf'ORNIA ·az:toz
':.l;t. I:. CHICACiO AVE.
BASE/NEUTRALS 'AND ACIDS
ORGANIC ANALYSES
Date of Report: __ "Mar_c_h_3o_,_l9....,8,_9 ____ Lab Sample ID No. 890203-309 Laboratory Signature Lab · 1 /J
Name: E S. Babcock & Sons. Inc. Director: kt:%'4'-<=-< ./ C/~lj Naro~ of . .sampler · / ~ Sampler: Davld L. Guth Employed By: I.T. Com; Date/Time Sample Date/Tl~e Sampla --~w~e-r-e~H~o~l~d
7 i-ng ________ Y_e-~----
Collected: 01-31-89 RecQiVed @ Lab: 2-3-89 I 0930 'Times Observed? · Were all the consti~u~nts lis~t-e~d~---
Test Methods: ____ ~6~2~.5~/~6n~8~------------' below quantified? Yes ~~:;~m SWATs Project No. 240827-04 ~~=~:
Descr~l-p~t~i-o_n __ o_f~-------------------------------------- ---------------- 1 i P i Q1-Market Place Samp ng o nt:~------------------~~~-------County Name: ________ ~------ Name/No. Of sample Station
Source: MP-2 Number:
Date &
Time of I I I I I I I I~ I I J
samplQ: Y.Y H MD D T ~ ~ T
Water
Type:
I I I t I I I I I I I I I I I
User I I 1 I Submitted to S~QIS
ID: By: -----------
1', ';Place an. 11 X11 in box to deljto All ctAtA. tor thia ~tation/dAte;time. u ' "- .-- REPORTING CONSTITUENT T STORET · ANALYSES DETECTIC!:
UNITS T CODE RESULTS LIMIT
Date Analyses Completed 73672 s19 t Ot3 11 1o I I I I I Yl'MMDD
Anal_y_z_in_g_ A_g_encv Co~e (Lab) 28 I I J I I I 1 Intensive surve~ Nu~er 116 I I I I I :
ugjL Ac~naphthene 34205 _l_ N D I I 51 . I o · o
ug}L Acenaphthylene 34200 1 N n J 151.1010
uq/L Anthracene 34220 t N ll I I 51 . I 0 I 0
Ug/L Aldr1n ')9330 _N_d) I I 0 I . I o I 1
·Ug/L Benzo(a)anthracene 34526 N ll Jll 0 I ·I 0 I 0
uq/L Benzo(b)fluoranthene 34230 ; _N ll 11101-10'0
Ug/L Benzo(k)fluor~nthene )~242 _N ll Jl!OI.IOIO
ug/L Benzo(a)pyrene 34247 l I N ll 1110 I. IOJO
ug/L Benzo(ghi}Eerylena 34521 N ll 1110 I. JOJO
Ug/L Benzyl butyl phthalate 34292 l I N ll Ill 0 I . I o I 0 ug/L' 11 - DHC 39338 N ll I I 0 I. I 015
uq/L I~ -. BHC 34259 N ll I I o I . I o I 5
ug/L bis(2-chloroethyl)ether 3427:l I N1D I I 51 . I o I o ug/L. bis 2-chloroethoxy)methane 34278 N I) I I 51 . I 0 l 0 u_gLL b1s 2-ethylhexyl)phthalate :l9100 ,8 .._ Ls J 151 .jOJO ug/L bl.S 2-chloroiso~ropyl)ether 34203 N D I 151. I 0 I o ug/L 4-Bromophenvl phenyl ether 3t.636 N ll I J5J.JOJO
uqi_L Chlordane 39350 I N I) I I o l • I o 15
u_gj_L 2-Chloronaphthalene 34501 I M ]) I I 51 . I o I o OHS 11351 6 (l/117)
Base;Neutrals and Acids (Continued) PAGE 3 OF 3
SYSTEM NJI.ME & NUMBER I.T.Corn. SWATs Pj#240827-04 Q'1-!1arket Place MP-2 r--, Lab No. 890203-309
\ I
ADDITIONAL EXTRACTABLE PARAMETERS
REPORTING CONSTITUENT T STORET ANJ..LYSES DE·rEC':':!:ON
UNITS T CODE RESULTS LIMIT
UO/L Phenol 3469~ I I _L 1N ,D I IS!. I 0 I 0
ug/L 2 4,6-Trichlorophenol 34621 1N 1D I lSI. I o i o
uq/L Benzidine 39120 I I N D I 151. I o I 0 u_g_LL a - BHC 39337 Q, ~o 3 I I o I . I o L 1 ug/L y - BHC 39340 I IN tD I I o I. I o 11
ug/L Endosulfan I 34361 I I N 1D I I o I. I o 11
Ug/L Endosulfan II 34356 N D I J o I . ! o 11
ug/L Endrin 39390 I ! ~ D I lOJ.IOI1
ugjL Hexachlorocy~lopentadiene 34386 I I J ~,D I2IOI.IOLO ug/L N-Nitrosodirnethylarnine 3~438 ~ D I 151. I o I o
uq/L H-N i trosodipheny_larnine 34433 I I I ~ ID I 151. I o; o Note any unidentified peaks below.
' \ ')
DHS 8351 B (3/87)
A~"ICULTL.IN4&. CON~Uir..f4Nf5
..:u~••:.r~
A..- .. 11~VL.Q WAILM L.AUON4TOttY
PHONE ci84-llllll
AHLA Coo~,,.
L.AUCRA TORIE:5
:J~ I :0 CI-IICACiO AVE:.
EDWARD S. BABCOCK & SONS. INC.
P.o. eox ~3a
RIV&l:R810i:, CALIFORNIA &2~02
BASE/NEUTRALS 'AND ACIDS
ORCANIC ANAL"iSES
· ..
Date of Report: __ Mar_c_l_t _3o_._19...,8,_9 ____ Lab Sample ID No. 890203-310 Laboratory Signature Lab ) · 11 ,1·
Harne: E ,S Bnbcock & Sons. Inc. , Director: lau._-zf.i'o~-'72Lj{_%u'*4- Nam~ of David L. Guth .. SCimpler rnf' I Sampler: EmplQyed By: I.T. Co . · Date/Time Sample Date/Time Samplu --~W~e-r-e~H-o~l~d7in_g ________ __ Collected: 01-31-89 R.ecaived @ Lab: 2-3-89 I 0930 'Times Observed? Yes · Were all the consti~uuncg listed
Test Methods: 625/608 • . below quanti!' ied? Yes
••••••••~----~--------a5~••••••~~-sa•~------a•-••-~a-•--a•---------------• systetu SWATs ProJ· ect No. 240827-04 system
N~rne: Number:
Descr·~l-p~t~i~o~n--o~f~----q-
1 ~-----t--P_1_a_ce------------------------ --------------- Sampling Point: county Name: ______________ _
N~m~/Nc. or Saro-p•l-e----------------~S~t-a~t~l-o_n ____ __ Source; ______________ ~ __ -3 _________ Number: I I I I I I I I I O~t~ '
Tim~ ot I I I I I I I 1~1 I I
S4mpl-: v.Y M M 0 D T T ~ T
Water
TypQ:
I I I I i
User I I I I Submitted to Sh'QI~
ID: ay: ____________ _
, ,\ Place iU\ 11 X11 in box to daljtO All data. tor this &Jti:ltion/dAtejtilDe. U '
REPORT INC CONSTI'l'UENT T STORET · ANALYSES DETECTIC!:
UNITS T .CODE RESULTS LIMIT
Date Analyses Completed 73672 8}! l 0 13 11 10 I I I I I "i Y M M 0 D
Analyzing Agency Co~e _(Labj_ 28 _j_ _j_ I I I I
Int&::nQive: Surve_y_ Number 116 _j I I I :
uq/L · Ac~na.phthene 34205 _j_ N ll I 5-1.1o·c
uq/L Acenaphthylene )~200 I I ~~ l\ I 5 I . I 0 I 0
uq/L Anthro.cen~ 34220 J N ll I I 5 I • I 0 I 0-
uq/L Aldr:-.Ln )9)30 N I\ I 0 I • I 0 I 1
.uq-/L Benzo(a,anthracene 34 526 __l N ll ll 01.1010
ug/L Benzo(b)fluoranth~ne 34230 N ll 11 01.\0'Q
uq/L Benzo(k\fluoranthene )~242 __l. N II 11 0 I • I 0 I 0 ug/L Benzo(a)pyrene 34247 N ll ·11 0 I . I o I o
UCf/L Benzo (g_hi )pervleno 34521 N ll 11 o I. J o I o
uq/L Bt::nzyl butvl phthdlate 34292 __l_ __l_ N ll 11 0-1 . I 0 I 0 UCf/L' 1i - DHC l9Jl8 N ll I 0 I. I 015
uq/L 6 --BHC :14259 0 3.3 I o I . I 0 I 5
u'r/L bAs_{2-chloroethy1)ether )427) I N I ll I 51. I O! o uq/L. ~~s_l2-chloroetho~)~ethane )4278 N ll I 51 • I 0 I a ug/L bis!2-ethylhex~l}Ehth41Qte 39100 2 1 I 51. I 0 I 0 ug/L b.i.o(2-chloroi~opropyl)t:ther 3420) N ll I 51 . 1 a 1 a uq/L 4-Bromooht:nvl phenyl t:ther :l-!636 N IJ I 51 . I 0 I 0 uq/L Chlordane 39350 I~ II I 0 I • I 0 I 5
ug/L 2-Chloronaphthalene J450l H I I 51 • I 0 I 0
OHS ll51 8 (l/1171
Base/Neutrals ana Acids (Continued) PAGE 3 OF 3
SYSTEM NAME & NUMBER I.T.Corn. SWATs Pi#240827-04 Q1-!1arket Place MP-3 · Lab No. 890203-310
.ADDITIONAL EXTRACTABLE PARAMETERS
REPORTING CONSTITUENT T STORET ANALYSES DE'I'EC':'ION
UNITS T CODE RESULTS LIMIT
ucr/L Phenol 34l69~ I .N D
'
51. I 0 I 0
ug/L 2 4,6-Trichlorophenol 34621 I .N D I 51. I 0 i 0
uq/L Benzidine 39120 I I .N D I 51. I 0 I 0
ugLL a - BHC 39337 o . ~o 4 I o I. I o 11
uq/L y - BHC 39340 I 01. 10 14 I OJ. I 011
ugj_L Endosulfan I 34361 I I ~ ID I OJ • I 011
ug/L Endosulfan II 34356 I ~~ ID I o I.! o 11
ug/L Endrin 39390 I I ~ D I 01. I 011
ug_L_L Hexachlorocyclopentadiene 34386 I I l ,N 1D 12 0 I. I 010 ug/L N-Hi trosodimeth_y_lamine 3t.438 .N D I 51 . I o I o ug/L N-Nitrosodiphenylarnine 34433 I I I N ,D I 51. I o 1 o Note any unidentified peaks below.
)
DHS 8351 B (3/87)
PHONE 684-1881
AH£A Coo.: 714
LABORATORIES
3215 CHICAGO AVE.
&.r.o.ai.I81<1UI 1eoe
EDWARD S. BABCOCK 6: SONS. INC.
P.o. aox 43Z
RIV£R810£. CAL.If'ORN1A 112:102
BASE/NEUTRALS 'AND ACIDS
ORGANIC ANALYSES
AGHICUL TUR4L. CONSULTANT&
CNLMIST:a,
A~PHOV&Q ¥tAT£A LAUOAATORY
Date of Report: __ Mar_c_h_3o_,_l9_,8,...9 ____ Lab Sample ID No. 890203-311 Labor a tory S iqna ture Lab , 1 /
Name: E.S Babcock & Sons. Toe. , Director: ~~:£.· /f%~~ Nama of D .d 1 G th .. Sampler T Sampler: aV1 • u EmplQyed By: I.T. Co ·· · Date/Time Sample Date/Time Sample --~w~e-r-e~H~o~l~d~i-n_g ______ Y_es--- Collected: 01-31-89 RecQiVed @ Lab: 2-3-89 I 0930 'Times Observed? Were all the constituents lis~t-e~d----
Test Methods: __ _;6;.;;2;,;;.5"-/6,;;,0:.;.;;8;,_ ___ ... ___ . below quantified? Yes ~~•••a•~~-=~=~w===;===a55••••••aA-:cm•~------a=-•a=a~---=a=----------~----· System SWATs Project No. 240827-04 System
Name:~~----~------------------------------------Number: Description of Q{-Market Place ------------- Sampling Point: County Name: Name/No. Of sam-p~l-e-------------~S~t-a~t~i~o-n______ --------------- source : !'11?-4 Number: I I I t I I I I I I I I I l
Date &
Time of I I I I I I I lot:! I I I Water u· User I I I I Submitted to Sh'QI:
Sample: Y.Y' M M 0 D T T ~ T Type: . G/S ID: ay: ____________ _ ) Pla.ce an 11 X11 in box to deljte all data.tor this atationjdate/time. U REPORTING CONSTITUENT T STORET · ANALYSES DETECTIC!:
UNITS T CODE RESULTS LIMIT
Date Analyses Completed 73672 8 I 9 10 1311 J 8 I I I I I YYMMDO
Analyzing Agency Code (Lab) 28 I I I I Intensive surve_y Number 116 I I I I I I ug/L Acenaphthane 34205 1 N n I 5_1 0 o·o
ug/L Acenaphthylene 34200 I 1 I N 1) I 51 . 0 0
ug/L Anthracene 34220 _l_ .1 _l Nd1 I 5 I . 0 0
u_gj_L AldJ:"ln 39330 1 N D I 1 o 1 • 1 o 11
. ug/L Benzo alanthracene 34526 I I 1 I N l) 11 o I . 010 ug/L Benzo b)fluoranthene 34230 N n 11 o I· O!Q
u_g/_L Benzo k)fluoranthene 34242 I N ll 11 0 I . 0 0
uq/L ·Benzo a)pyrene 34247 J I _lNI) 11 o I . 0 0
ug/L Benzo ~hi) peryleno 34521 _l_ _l_ Ntll 11 o I . 0 0 ug/L Benzyl butyl phthalate 34292 I I N D 11 0 ,. 0 0
uq/L" B - BHC 39338 _l_ _l_ N ll _l o I. 0 5
uq/L 6 -·BHC 34259 N D I 0 I • 0 5
uq/L bis 2-chloroethvllether 34273 I I N .ll I 5 I • 0 0 ug/L. bis 2-ch1oroethoXY)methane 34278 I N n I 5 I • 0 a u_gLL bis 2-ethylhexv1}phthalate 39100 _l _l N [) I 51. 0 0 j ug/L blS 2-ch1oro~sopropyl)ether 34283 N D I 5 I • 0 0 uq/L 4-Bromophenv1 phenyJ ether 3<!636 N n I 5 L. 0 0
ug/L Chlordane 39350 I N ll I
0 '·
0 5
ug/L 2-Chloronaphthalene 34581 I M n I 51 . 0 0
OHS 8351 e (3/87)
Base;Neutrals and Acids (Continued)
SYSTEM NAME & ~BER I. T.Corn. SWATs P;tF240827-04 (!1-!1arket Place MP-4
REPORTING
UNITS
ucrjL
uq/L
uq/L
ug/L
ug/L
ug/_L
ug/L
uq/L
ug/L
ug/L
ug/L
Lab No. 890203-311
ADDITIONAL EXTRACTABLE PARAMETERS
CONSTITUENT T STORET ANALYSES
T CODE RESULTS
Phenol 3469.; I N D
2 4 6-Trichlorophenol 34621 I N D
Benzidine 39120 I I N,D
a - BHC 39337 ~N U
_y_ - BHC 39340 J I ,N I D
Endosulfan I 34361 L I ,N I u
Endosulfan II 34356 I_ ,N I D
Endrin 39390 ,N U
Hexachlorocyclopentadiene 34386 I N,D
N-Nitrosodirnethylarnine 3~438 L IN _D
H-Nitrosodiphenylarnine 34433 I I N1n
Note any unidentified peaks below.
OHS 8351 B (3/87)
PAGE 3 OF 3
DE·rEC':'ION
LIMIT
_l lSI. I 0 I 0
I lSI. I 0 i 0
I 151. I 0 I o
I 1 o I . I o 11
I 101.1011
I I 0 I. I o 11
I I 0 I. I OJ1
! I 0 I . I o 11
I 2 I Oj_. I 0 I 0
I 151. I o I o
I 151. I o I o
A~HICUL.TUHAL CON:.tUL.TANT6
~uL,..,=-r•
A~fo'HO'tt'LQ WAT£R LAiaOttATOHY
PHONE o84·1881
AKa:A Coc~ 11•
L.A60RA TORIES
:.1~ 15 CHICAGO AVE.
EDWARD S. BABCOCK Be SONS. INC.
P.o. aox 432
RIVER81CE. CALIFORNI"' &2~02
BASE/NEUTRALS "AND ACIDS
ORGANIC ANALYSES
Date of Report: __ Mar_c_1_1 _3o_._l9_,8,_9 ____ Lab Sample ID No. 890203-312 Laboratory Signaturi! Lab 1 . 1 /
Name: E.S Babcock & Sons. Inc. Director: ,L~£-c.rJ~~~c4- Nam~ ot . .SCLmpler . ·/ / Sampler: Dav~d L. Guth ElnplQyed By: I.T. Com.
Date/Time Sample DatQ/Tl~e SamplQ --~W~e-r-e~H-o~1~d~in_g _____________ _ Yes Collected: 01-31-89 Rec,dved i Lab: 2-3-89 I 0930 'Times Observed? · Were all the constitu~nts lis~t-e~d~---
Te&t Methods: _____ 6~2~5~L-6~0-8 _____________ . below quantified? Yes system SWATs ProJ· ect No. 240827-04 system Name: Number:
Oescr~l-p~t~i-o_n __ o_f~----q-
1 ~-.---ke-t __ P_1_a_ce ________ ~-------------- ---------------- Sampling Point:~------------------~~~-------County Name: ______________ __ Nam~/No. Of Sample Station
. source: ~-5 NUUlber: I I I t I I I I I I I I I I I
Da.te "
Time of I I I I I I I 1~1 l J Water U· Use!: I I I I Submitted to SWQIS SetmplQ: Y. Y M M 0 D T 'J.' '1' T Type: G/S ID: By: ______ _ . () Place an uxu in box to deljte all datA. tor this atationjda.tejtime. U REPORTING CONSTITUENT T STORET · ANALYSES DETECTIC!: UNITS T CODE RESULTS LIMIT Date Analyses Completed 73672 a19 1o 13 11 1 a I I I I I Y Y M M 0 0
Analvzinq Aqency Code (Lab} 28 I I I I I I
Intensive Survey_ Nuln.ber 116 I I I I I
uq/L Acenaphthane 34205 _j N ll I 51. 10.0
uq/L Acenaphthylene 34200 1 N n I 51 • 1 ol o uq)L Anthracene 34220 I I N II I 51 • I o I o Uq/L AldJ,"l.n 39330 I N I\ I o1.1011 .uq)L Benzol a) anthracene 34526 l N ll 11 0 I . I 0 I 0 uq/L Benzo b\fluoranth~ne 34230 .I. . N I) 11 0 I . I 0' 0 ua/L Benzo k)fluoranthene l4242 N ll 11 0 I. I o I o
uq7L Benzo a)pyrene 34247 I I N ll . 11 o I . I o I o
uq/L Benzo qhi\Pervleno 34521 I N ll 11 oj. I ojo
uq/L Benzyl butyl phtha.late 34292 ...1. _j_ I N. I) 11 0 I • I 0 I 0 uq/L' B - DHC 39330 _j_ ...l __l I N I) I 0 I . I 015
uq/L 6 -·BHC 34259 JL_. 0,6 I o I • I 0 I 5
U'f/L bis 2-chloroethyl)ether 34273 ...l _L N1D I SJ .[ o I o uCI'/L. bis 2-chloroethoXYlmethane 34278 ...l N J) I 51 • I 0 I 0 uq/L b1s 2-ethylhexylJ~htha.late 39100 N ll I 51. I 0 I o uq/L bls(2-chloroisopropyl}ether 34203 N I) I 5 I • I 0 I 0 ua/L 4-Brornoohenvl ohenvl ether 3~636 I N fl 1 5 I • I 0 I 0 uq)L Chlordane 39350 Noll I o I . I o 15
uq/L 2-Chloronaphthalene 34581 "''n I 51. I o I o
OHS 1351 8 (l/fi7)
Base/Neutrals and Acids (Continued) PAGE 3 OF 3
SYSTEM NAME & NUMBER I.T.Corn. SWATs P;tfo240827-04 Q1-!1arket Place MP-5 · ·Lab No. 890203-312
ADDITIONAL EXTRACTABLE PARAMETERS
REPORTING CONSTITUENT T STORET ANALYSES DE'I'Ec:roN
UNITS T CODE RESULTS LIMIT
ucr/L Phenol 3469..; I N 1D I j5J.IOIO
ug/L 2 1 4l6-Trichlorophenol 34621 L J_ N D I 151. I 010 uq/L Benzidine 39120 N D l 151. I 0 I 0
ugjL a - BHC 39337 tO I !0 2 I I a I. I a 11
uq/L y - BHC 39340 N 1D I I a I. I a 11
uq/L Endosulfan I 34361 l 1 N 1D I I a I . I a 11
ugL_L Endosulfan II 34356 .N D l I o I . ! o 11
uq/L Endrin 39390 N D I I a I. I a 11
ug/L Hexachlorocyclopentadiene 34386 I ;N ID 12 I OJ. I 0 I 0 uq/L N-Nitrosodirnethylamine 3~438 l ~- D I 151.1010
uq/L H-NitrosodiQhenylamine 34433 I N D I !51. I o I a
Note any unidentified peaks below.
OtiS 8351 B (3/87)
A~HICUL.TURAL. CON5UL.TANTa
CMEMIST$
A~PHOV&::C WATlR L.ASOAATQRY
PHONE 664-1661
AtUA coo~ ,,,. EDWARD S. BABCOCK & SONS. INC.
P.o. eox 432
LABORATORIES
'3215 CHICAGO AVE.
RIVER81CE. CAL.IFORNIA &2502
BASE/NEUTRALS "AND ACIDS
ORGANIC ANALYSES
Date of Report: __ Mar_c_r_1 _3_o_, _1_98 .... 9 ____ Lab Sample ID No. 890203-313 " Labor a tory Signature Lab J ; . ~
Name: E.S. Babcock & Sops. Tpc. , Director: LdwW~ {Kul::!::/E4_ Nam& of D 'd 1 Guth .sampler -r- 7
sampler: aVJ. • Emp 1 Qyed By: _r~. T_._eo~w.,_ . ....,·:-:-;:------- Date/Time Sample Date/Ti~e S~mple Were Holding Yes
Collected: 01-31-89 R.ecQiVed @ Lab: 2-3-89 I 0930 'Times Observed? · Were all the constituents lis_t_e~d~---
Test Methods: __ --~6~2~5~/~60~.8~------------ below quantified? Yes System SWATs Project No. 240827-04 System
Name:~~----~---------------------------------------Number: ______________ __ Description of q1-Market Place
Samplinq Point:~------------------~~~-------County Name: ______________ __ Name/No. Of sample Station
.Source: MP-Blank Number: I I I 1 I I I I I I I I I I I Use~ I I I I Submitted to SWQIS
Date &
Time of I I I I I I I 1~1 I I
Sample: Y.Y MMD D T T ~ T
Water
Type: ID: By: ______ _
, ~ ) Place a.n· "X" in box to cialtte all datA. tor thia atation/date/time. U REPORTING CONSTITUENT T STORET · ANALYSES DETECTIC!:
UNITS T CODE RESULTS LIMIT
Date Analyses Completed 73672 81910131118 I I I I I
Y Y·M K D 0
Analyzing Agency Co~e (Lab} 28 I I
Intensive survey Number 116 I I
uqJL Acanaphthane 34205 I Nd) 5 . o·o
uq/L Acenaphthvlene 34200 I N l) 5 . 0 0
uq/L Anthracene 34220 _t • N n 5 . 0 0
ug/L Aldr~n 39330 N1D 0 . 011 .
·UQ/L Benz a a} anthracene 34526 I I N ]) 110 . 010
uqJL Benzo b} fluoranthene 34230 ..L · N 1 n 1 0 . 0'0
uq/L Benzo k}fluoranthene l4242 N ll 1 0 . 0 0
uq/L ·Benzo a)pyrene 34247 _1_ _f. N D 1 0 . 0 0
uq/L Benzo(ghi)pervleno 34521 I N1D l 0 . 0 0
Ug/L Benzyl butyl phthalate 34292 I I I N D l 0 . 0 0
uq/L' B - BHC 39338 I N n 0 . 0 5
uq/L 6 -·BHC 34259 N I) 0 . 0 5
uq/L bis 2-chloroethJlllether 34273 _._ _L _1_ N .1) 5 . 0 0 ug/L. b-is 2-ch1oroethoxv)methane 34278 _l_ ..L N D 5 • I 0 0 uq/L bis 2-ethvlhexvl)phthalate 39100 I N U I 5 . 0 0
)
uq/L b~s(2-ch1oroisopropyl)ether 34203 _1_ N D I 5 . 0 0 uqJL 4-Bromophenvl ohenvl ether 3~636 I 1 N n 5 . 0 0
uq/L Chlordane 39350 _1. _L NtH 0 . 0 5-
uq/L 2-Chloronaphthalene 34581 _1_ I ·M I 1'1 5 . 0 0
OHS 8351 8 (J/8 7)
•i )
BasejNeutrals and Acids (Continued) PAGE 3 OF 3
SYSTEM NAME & NUMBER I. T.Corn. SWATs Pi#240827-04 Q1-Harket Place MP-Blank
REPORTING
UNITS
ucr/L
Ug/L
uqj_L
Ug/L
uq/L
ugLL
ugLL
uq/L
Ug/L
uq/L
uq/L
Lab No. 890203-313
ADDITIONAL EXTRACTABLE PARAMETERS
CONSTITUENT T STORET ANJ..LYSES DE'rEc:roN
T CODE RESULTS LIMIT
Phenol 3469.; I IN I D I 151_.1010
2 14,6-TrichloroQhenol 34621 I ,N U I !51. I o i o
Benzidine 39120 I I N D I 15 I .. 1 o I o
a - BHC 39337 ~N U I I o I. I o 11
y - BHC 39340 I I IN I D I lOL.IOil
Endosulfan I 34361 I I N 1 D I I OJ. I 011
Endosulfan II 34356 J NID I 101_.10[1
Endrin 39390 _l I IN D I I 0 I. I o 11
Hexachlorocyclopentadiene 34386 N1n 121 0 I. I o I o
N-Nitrosodirnethylamine 3~438 I 1N n I 15J. I o I o
N-Nitrosodi]:lheny_lamine 34433 _I _I I_ IN ,D I 151. I o: o Note any unidentified peaks below.
OHS 8351 S (3/87)
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABliSHED 1110e
PHONE (714) 684·1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240829-04
QM-Studebaker-Loynes
SWA er Sample
L-Trip Blank:
P.O. BOX 432
RIVERSIDE. CALIFORNIA 92502
03/01/89
Lab No. 890203-236
Invoice No. 97423
Submitted Sampled
DLG DLG
02/03/89 2/2
9:10
Chain of Custody on file: Y
Parameter Name Results Parameter Name Results
Calcium (Ca) 1 mg/L Antimony (Sb) <0.01 mg/L
'-,od.i urn ( Na) <1 mg/L Arsenic (As) <0.01 mg/L
!,tassium (K) <1 mg/L Barium (Ba) <O.lmg/L
_Jtal Alkalinity as CaC03 2.5 mg/L Beryllium (Be) <0.01 mg/L Hydroxide (OH) none mg/L Boron (B) '<0.1 mg/L
Carbonate (COJ) none rng/L Cadmium (Cd) <0.001 mg/L
Bicarbonate (HCOl) 3 mg/L Total Chromium (Cr) <0.01 mg/L Sulfate (S04) <1 rng/L Cobalt (Co) <0.01 mg/L
Chloride (Cl) <1 rng/L Copper (Cu) <0.01 mg/L
Nitrate Nitrogen (N0J -N) <0.1 mg/L Iron (Fe) 0.03 mg/L Fluoride (F) <0.1 mg/L Lead (Pb) <0.005 mg/L
Biochemical Oxygen Demands <2 rng/L Manganese. (Mn) <0.01 mg/L Chemical Oxygen Demand <5 rng/L Mercury (Hg) <0.001 mg/L Oil and Grease <1 mg/L Molybdenum (Mo) <0.1 mg/L
Total Phosphorus (P) <0.02 mg/L Nickel (Ni) <0. 01 ntg/L pH 6.4 units Selenium (Se) <0.005 mg/L
Specific Conductance 2.5 jJIIJho/cm Silver {Ag) <0.01 mg/L Total Filterable Residue 5 rng/L Zinc (Zn) 0.01 mg/L
Thallium (Tl) <0.1 mg/L
/Notes: Metals run on samples filtered and preserved in field.
Oil and Grease preserved w/sulfuric acid.
co:
EDWARDS. BABCOCK & SONS, INC.
c/Jl~~J ~JL~ ~
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED tooe
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240829-04
QM-Studeba.ker Loynes SWAT
water sample SL-6)
~
P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
02/27/89
Lab No. 890203-260
Invoice No. 97125
Submitted
DLG
02/03/89
9:10
Sampled
DLG
02/02/89
Chain of Custody on file: Y
Parameter Name Results Parameter Name Results
EPA Method 9060
Total Organic Carbon
I
;~tical Quantitation Limit
Notes:
cc:
1.3 mg/L
1.0 mg/L
EDWARD S. BABCOCK & SONS, INC.
rxl! t1, . -:· ((} ___ ·' j)
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1;oe
PHONE (71<1) 684-1881
1 LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240829-04
Q-1-Studeba.ker La~ SWAT
water sample SL~
~'
P 0. BOX 432
RIVERSIDE, CALIFORNIA 92502
02/27/89
Chain
Lab No. 890203-251
Invoice No. 97125
Submitted So..mplE..'Ci
DLG DLG
02/03/89 02/02/89
9:10
of Custody on file·: Y
Parameter Name Results Parameter Name Results
____ EPA Method 9020
Jotal Organic Halides
· ·actical Quantitation Limit
• ,.1) = None Detected at PQL.
Notes:
cc:
ND mg/L
0.010 mg/L
EDWARD S. BABCOCK & SONS, INC.
r/;!l .~ rrr~ ";J. ~~
(
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. OHS CERTIFIED ESTABLISHED 1;oe
PHONE (714) 684·1881
LABORATORIES EDWARD S. BABCOCK & SONS, INC.
.,_, 3215CHICAGOAVE. P 0. BOX 432
RIVERSIDE. CALIFORNIA 92502
03/29/89
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked: SWATs
QM-Studebaker-Loynes
Pj#24082:-~
sample s~
Lab No. 890203-242
Invoice No. 97424
Customer No. in0292
Submitted Sampled
By DLG
Date 02/03/89
Time 9:30
DLG
02/02/89
Chain of Custody on file: Y
Purgeable Halocarbons and Aromatics
Parameter
Benzene
Bromodichloromethane
Bromofonn
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethylvinyl ether
Chlorofonn
Chloromethane
Dibromochloromethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
EPA Method 502. 2
Results
llg/L
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Parameter
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethy 1 benzene
Methylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Methyl Ethyl Ketone
Methyl Isobutyl Ketone
Xylenes, total
cis-1,2-Dichloroethene
Acetone
Results
~/L
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND*
NDU
NDU
ND
ND
ND"'rir*
' ND=None detected, detection limit:
· Date analysis completed: 02/05/89
0.5 llg/L NI=Not identifiable
. -dotes: * FQL = 1. 01Jg/L U FQL : 5. Ollg/L
cc: EDWARDS. BABCOCK & SONS, INC.
1\1~-'
}.
•.__.,.
\ )
l .
AGAICUL. TURAL. CONSUL. rANT
CHE)o415TS
APPIIOVtO WAT£10 L .. uO~ATC
PHONE 684-1881
A'"'" eeoc 71• EDWARD S. BABCOCK Be SONS. INC.
LABORATORIES
321~ CHICAGO AVE.
P. 0. BOX 432
RIIIER&ICE. CAL.IFORNIA 112502
BASE/NEUTRALS AND ACIDS
ORGANIC ANALYSES
M h 28 1989 890203-248 Date of Report: .arc ' · Lab Sample ID No.
Laboratory Signature I.~ab ~--------~~
Name: E.S.Babcock & Sons Inc. Director: ~·tb'C..< /(){_£1 ztf._..
Name of David L .. f;uth Sample·r . I. T. Cori(.' 7
Sampler: Employed By:
Date/Tim-e~S-a-mp~l-e ____ D~a-t_e_/~T=i~m-e-S~a-m-p~le · --~w~e-r-e~H~o~l~d~i-n_g _____ __ Collected: 02-02-Rg Received @ Lab: 2-3-89 'I 0930 Times Observed? Yes · Were all the constituents listed
· Test Methods: 625/608 below quantified? Yes
z•=-•••••;m•=~==--===••----•aaa.amcaacaaaa==••Q=a~=am=caaa•=••===a~==a=::
system . '·~"~ '2 04 Name: S W A Ts Pro.1ect No. 2'+\)8 9- system Number: ____________ _ Descrlption of 01_Studebaker:_Loynes
Sampling Point:~--·--~====~----~~~~------County Name: ____________ _ Name/No. Of Sample ::; ~ Station Source: SL~J.n IH~ Number:
Date &
Time of I I I I I I I I I I I Water
Sample: Y Y M M D 0 T T T T Type: u G/S
I I I I I I I I I I I I I I
Use~ I I I I Submitted to SWQ
ID: By: .
Place an "X" in box to delete All dAtA !or this station/dAte/time. U REPORTING CONSTITUENT T STORET ANALYSES DETECTIC!; UNITS T CODE RESULTS LIMIT Date Analyses Completed 73672 819 1 0!3 1019 I I I I I
"i Y M M 0 D
Analyzing Aqencv Code (Lab} 28 I I I I I I I
Intensive survev Number 116 _I I I I I I ~
uq/L Acenaphthene 34205 I I N.n I 5 I • I o · c
Uq/L Acenaphthylene 34200 I I N,D I 51 . I o I (
Uq/L Anthracene 34220 I • N1n I 5 I • I o I ( . Uq/L Aldrl.n 39330 J I I I NID I 0 I • I 0 I :
Uq/L Benzo(a)anthracene 34526 I IN D 11 o I • I o I (
uq/L Benzo(b)fluoranthene 34230 I ~~~ 11 o 1 • I o! (
ug/L Benzo(k)fluoranthene 3-<.242 _I I IN D 110 I . I 0 I c uq)L Benzo(a)pyrene 34247 1 I Moll 11 o I • I o I c
Uq/L Benzo(gh~~crvlene 34521 I I IN D 11 o I . I 0 I c
uq/L Benzvl butyl phthalate 34292 _j ·J I N1IT liOI.IOIC uq/L. B - BHC 39338 I I 1 1 N~n I 0 I • I 0 I:
uq/L 6 --BHC 34259 I ,-N ,J..J I o I • I o I:
uq/L bis(2-chloroethvl)ether 34273 I I NID I 51 . I o I c uci7L . bis(2-chloroethoxV1methane 34278 I NIIJ I 5 I • I o I c Uq/L bJ.s(2-ethylhexvl)phthalate 39100 I N J I 5 I . I o I c uq/L bis(2-chloroisooroovl)ether 34283 N~ ISI.IOJC
uq/L 4-Brornophenyl phenyl ether 3-<.636 I I N I!) I 5 I . I o I c uq/L Chlordane 39350 I 1 H1D I 0 I • IO f 5
uq/L 2-Chloronaphthalene 34581 I N 1 U I 5 I • I o I c
Chain of Custody on File: Yes
BasejN~utrals and Acids (Continued) PJ..GE 2 OF 3 . . .
SYSTEM NAME &c NUMBER I.T.Co~. Sl.JATs l?jf/240829-04 qvf-Studebaker-Loynes SL-kio Bl~ REPORTING CONSTITUENT T STORET ANALYSES DETECTION . UNITS T CODE .RESULTS LIMIT Ug/L 4-Chlorophenyl phenyl ether 34641 _l 1 l_ N D 5 . 0 0 u_gjL Crysene 34320 I I I N ID 5 . 0 0
Ug/L 4,4 1 -DDD 39310 I I 1 N D J o 1 • 1 o 12
Uq/L 4 1 4 1 -DDE 39320 N ,D 0 . 0 1
ugLL 4,4 1 -DDT 39300 I 1:1 D 0 . 0 2
Ug/L D~benzo(a h)anthracene 34556 I I ,N D 5 . 0 0
Ug/L Di-n-buty~hthalate 39110 I 114 ,Q 5 . 0 0
Ug/L lL3-Dtchlorobenzene 34566 1 1 N 1n 0 . 5 0
Uq/L 1,2-Dichlorobenzene 34536 l\1 Lil 0 . 5 0
Ug/L 1,4-Dichlorobenzene 34571 I I N f) 0 . 5 0
Ug/L 3,3 1 -Dichlorobenzidine 34631 I I N f) 2 0 . 0 0
Ug/L D~eldr1n 39380 _l L N )f) 0 . 5 ()
ugjL Diethy1 phthalate 34336 N ,n 5 . 0 0
ugjL D~methyl phthalate 34341 I I I N In 5 . 0 0
Ug/L 2 4-Dinitrotoluene 34611 I N ,n_ s . 0 0
Ug/L 2 6-Dinitrotoluene 34626 I I I N tD 5 . o. 0
Ug/L Di-n-octylphtha1ate 34596 1 N 1D 5 . 0 0
ugjL Endosulfan sulfate 34351 I I N ID 0 . 0 5
ucr/L Endrin aldehyde 34366 J I I N ID 0 . 0 5
Ug/L Fluoranthene 34376 I I I _N_ _!_D 5 . 0 0
Uq/L Fluorene 34381 J I I N ID s • 0 0
Ug/L Heptachlor 39410 I I ,D 0 . 0 2
ugjL Heptachlor epoxide 39420 I I I N ,D 0 • 1 0
) ugjL Hexachlorobenzene 39700 I ,_ ,D 5 . 0 0
Ug/L Hexachlorobutadiene 34391 _l_ t J ,D 5 . 0 0
u_gjL Hexachloroethane 34396 1 I I ,D .s . 0 0
Ug/L Indeno(l 2,3-cd)Pyrene 34403 I I ID 1 0 . 0 0
u_gjL Isophorone 34408 N_ _lD 1 0 . 0 0
ugjL Na_ghthalene 34696 I I I ID 5 • ! 0 0
ugjL N~trobenzene 34447 I I f'J lu 5 • I 0 0
ug/L N-Nltrosodi-n-propylamine 34428 I I ID 5 . 0 0
Ug/L PCB-1016 34671 I I N D 0 . 2 0
Uq/L PCB-1221 39488 I I I ID 0 . 2 0
ug/L PCB-1232 39492 I 1D 0 . 2 0
ug/L PCB-1242 39496 I I I ,D 0 . 2 0
Ug/L PCB-1248 39SOO I I I D 0 . 2 0
ug_lL PCB-12S4 39504 I l L N_ til 0 . 2 0
ug/L PCB-1260 39508 .I I I N ID 0 . 2 0
ug/L Phenanthrene 34461 I I I NJD 5 . 0 0
u_gjL _Pyrene 34469" _l_ I t-1 1J 5 . 0 0
ug/L Toxaphene 39400 1 1 ' }1__t_D 0 . 5 0
Ug/L 1 2 4-Trichlorobenzene 34S51 l I ,N D s . 0 0
ACID EXTRACTABLES
uq/L 4-Chloro-3-methylphenol 34452 l 1N n IS • I o J o
ug/L 2-Chlorophenol 34586 I IN f) 15 . l OJ 0
ug/L 2,4-Dich1orophenol 34601 l_ L _l ,N_ _l D IS . I o I o / ug/L 2 1 4-Dimethylphenol 34606 I I oN n 15 . I o I o ug/L 2,4-Dinitrophenol 34616 L • lhl_ _l D 15 . I o I o ug/L 2-Het:hy_1-4 6-dinitropheno1 34657 I 1N f) 15 • I o l o ug/L 2-Nitropheno1 34591 I I I N 1 C IS . I o I 0
u_gjL 4-Nitropheryo1 34646 I IN I c I IS .l 010
Ug/L Pentachl · ·henol 39032 _l j_ N j__ L J I o • 15[ 0 - .. ,. DHS 8351 B 131171
Base/Heutrals and Acids (Continued) . ' PAGE :l OF J
SYSTEM N/1.1-lE It NUMBER.
ADDITIONAL EXTRACTABLE PARAMETERS
R"ft'oHTr.u1 CONSTITUEl:l'. 'I' STORET A.NJ..LY S ES DETEC.:Ol/ UNITS T CODE RESULTS LHE'!'
Ua/L -Phenol 3469~ I I I IN I D I 51 . I 0 I 0
Uc.'/L ~. ~-6-Tr ichlorophenol 34621 I N D I 5 I . I 0 I 0 uc: /L LE!i: id 1na 39120 _I I I ~'1 I D I 51. I 0 I 0
uoLL a - BHC 39337 tN D I I 0 I . I 0 I l
ugjL y - BHC 39340 N ,n I o I . I o 11
ugjL En:!osulfan I 34361 I I i'I I D I O__Lj_O I 1
uajL E:--,dosul fan II 34356 I I N tD I I 0-1. I OjT
uq/L Endrin 39390 _t N D_ I 0 I. I 0 If
u_gLL ~G>:achlorocyc~entadlene 34306 ,N 1 U ~j_O!. I 01 o f-LigLL 11-1-1 ~ trosod imethylamine 3~430 I I ,N u· T TSI.IOIO
uq/L H-r~ i tro~odinhonylamine 34433 I I 0 ,N I u I 51 • I 0; 0 Note any unidentified peaks below.
) __________________________________________________________________________________________ _____ ..
OHS 8351 B (3/87)
I
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Edward S. Babcock & Sons, Inc.
3215 Chicago Avenue
Riverside, CA 92507
(714) 684-1881
.~
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( -~-
CHAIN OF CUSTODY RECORD
Client's Name: :rr CoR /'o£.4-r"ro.,.V
lab Is: Invoice No.
Project No. Project Name/Location Determination Requested N C Condition of Sample\ ;li-(IJ8Z 9- Oi ~
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Description Date Time ~ ~ ~ ~ 1.1! w s d d d Remarks lU -
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THIRD QUARTER SAMPLING
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
eSTABLISHeD 1906 CALIF. DHS CERTIFIED
PHONE (714) 684-1881
f , LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
) 3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
P j #240827 -04 f'Jarh:et
Place SWAT Wq.ter Sample
i"IP-1
Parameter Name
Calcium (Ca)
8~-i.it.ml (Na)
\ .l:tssium (K) ·
Tucal Alkalinity as CaC03
Hydroxide (OH)
Carbonate (COJ)
Bicarbonate (HCOJ)
Sulfate (S04)
Chloride (Cl)
Nitrate (N03)
Fluoride (F)
Biochemical Oxygen Demands
Chemical Oxygen Demand
Oil and Grease
Ortho Phosphate Phosphorus
Bromide (Br)
pH
Specific Conductance
Total Filterable Residue
Results
172 mg/L
5700 mg/L
225 mg/L
758 mg/L
none mg/L
none mg/L
924 mg/L
1340 mg/L
8400 mg/L
<1 mg/L
1. 9 mg/L
8 mg/L
40 mg/L
<1 mg/L
1. 3 mg/L
38 mg/L
7.5 units
25,700 JJ.ITiho/cm
16,300 mg/L
06/02/89
Lab No. 890508-4
Invoice No. 50038
Submitted I Sampled
KBA
05/08/89
11:30
KBA/DLG
5/3
Chain of Custody on file: Y
Parameter Name
Antimony ( Sb)
Arsenic (As)
Barium (Ba)
Beryllium (Be)
Cadmi urn ( Cd)
Total Chromium (Cr)
Cobalt (Co)
Copper (Cu)
Iron (Fe)
Lead (Pb)
1:-langanese ( tvln)
Mercury (Hg)
Molybdenum (Mo)
Nickel (Ni)
Selenium (Se)
Silver (Ag)
Zinc (Zn)
Thallium (Tl)
Results
<0.1 mg/L
0.01 mg/L
<0.1 mg/L
<0.01 mg/L
<0.01 mg/L
<0.1 mg/L
<0.01 mg/L
0.04 mg/L
0.02 mg/L
<0.005 mg/L
0.39 mg/L
<0.001 mg/L
<0.1 mg/L
<0.01 mgjL
<O. 05 rng/L
<0.01 mg/L
0.01 mg/L
0.6 mg/L
'otes: Metals run on samples filtered and preserved in field. cc: Edward S. Babcock & Sons, Inc.
~l~
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
ESTABLISHED 1908 CALIF. DHS CERTIFIED
PHONE {714) 684-1881
EDWARD S. BABCOCK & SONS, INC.
i LABORATORIES
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 Market
Place SWAT Water Sample
MP-2
Parameter Name Results
Calcium (Ca) 750 mg/L
Sodium (Na) 25,000 mg/L
·assium (K) 880 mg/L
i1 Alkalini-ty as CaC03 653 mg/L
Hydroxide (OH) none mg/L
Carbonate (C03) none mg/L
Bicarbonate (HCOa) 796 mg/L
Sulfate (S04) 6600 mg/L
Chloride (Cl) 44,000 mg/L
Nitrate (N03 ) <1.mg/L
Fluoride (F) 0.9 mg/L
Biochemical Oxygen Demands 5 mg/L
Chemical Oxygen Demand 5 mg/L
Oil and Grease <1 mg/L
Ortho Phosphate Phosphorus 1.1 mg/L
Bromide (Br) 199 mg/L
pH 7.4 units
Specific Conductance 96,300 j..UIJho/cm
Total Filterable Residue 88,000 mg/L
06/02/89
Lab No. 890508-5
Invoice No. 50038
Submitted Sampled
KBA KBA/DLG
05/08/89 5/3
11:30
Chain of Custody on file: Y
Parameter Name 'Results
Antimony (Sb) <0.01 rng/L
Arsenic (As) <0 .1 rng/L
Barium (Ba) <O .1 rng/L
Beryllium (Be) <0.05 rng/L
Cadmium (Cd) <0.01 rng/L
Total Chromium (Cr) <0.01 mg/L
Cobalt (Co) <0.05 rng/L
Copper (Cu) 0.15 mg/L
Iron (Fe) 0.05 rng/L
Lead (Pb) 0.08 rng/L
Manganese (~ln) 2.6 rng/L
l"lercury (Hg) <0.001 mg/L
Molybdenum (Mo) <0.5 rng/L
Nickel (Ni) <0.05 rng/L
Selenium (Se) <0.05 rng/L
Silver (Ag) <0.05 rng/L
Zinc (Zn) <0.05 rng/L
Thallium (Tl) 1. 5 rng/L
.;rates: Metals run on· samples filter~ and preserved in field. cc: Edward S. Bal:x::ock & Scms, Inc.
cjJt.; '~
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED I 90e
PHONE (714) 684-1881
i ~BORATORIES
EDWARD S. BABCOCK & SONS, INC.
..>215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 i"1arket Place
SHAT Water Sample MP-3
Parameter Name
Calcium (Ca)
f~ ')urn. ( Na)
F .ss1um (K)
Total Alkalinity as CaC03
Hydroxide (OH)
Carbonate (C03)
Bicarbonate (HC03)
Sulfate (S04 )
Chloride (Cl)
Nitrate (N03)
Fluoride (F)
Siochemical Oxygen Demands
Chemical Oxygen Demand
Oil and Grease
Ortho Phosphate Phosphorus
Bromide (Br)
pH
Specific Conductance
Total Filterable Residue
Results
400 mg/L
15,000 mg/L
440 mg/L
2913 rng/L
none mg/L
none rng/L
3253 mg/L
1580 mg/L
26800 mg/L
<1 mg/L
2.0 mg/L
22 mg/L
30 mg/L
<1 mg/L
2.3 mg/L
80 mg/L
7.5 units
62000 )..LIIlho/cm
48600 mg/L
06/02/89
Lab No. 890508-6
Invoice No. 50038
Submitted
KDA
05/08/89
11:30
I Sampled
EBA/DLG
5/3
Chain of Custod)· on file: Y
Parameter Name
Antimony (Sb)
Arsenic (As)
Barium (Ba)
Beryllium (Be)
Cadmi urn ( Cd)
Total Chromium (Cr)
Co"balt (Co)
Copper (Cu)
Iron (Fe)
Lead (Pb)
P.Ianganese (Mn)
Mercury ( Hg )
Molybdenum (No)
Nicl{el (Ni)
Selenium (Se)
Silver (Ag)
Zinc (Zn)
Thallium (Tl)
Results
<0.1 mg/L
<0.1 mg/L
1 mg/L
<0.05 mg/L
<0.01 mg/L
<0."1 mg/L
<0.01 mg/L
0.09 mg/L
0.33 mg/L
0.04 mg/L
1.4 mg/L
<0.001 rng/L
0.8 mg/L
<0.05 mg/L
<0.05 mg/L
<0.05 mg/L
0.09 rng/L
0.9 mg/L
::>tes: Metals run on· samples filtered and preserved in field. cc: Edward S. Babcock & Sons, Inc.
~~
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTAB~ISHED 1908
.- - PHONE (714) 684-1881
) LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 Market
Place SWAT Water Sample
MP-4
Parameter Name
Calci urn { Ca)
Sodium (Na)
assium (K)
!al Alltalini ty as CaC03
Hydroxide (OH)
Carbonate (C03)
Bicarbonate (HC03)
Sulfate (S04)
Chloride (Cl)
Nitrate (N03)
Fluoride (F)
Biochemical Oxygen Demands
Chemical Oxygen Demand
Oil and Grease
Ortho Phosphate Phosphorus
Bromide ( Br)
pH
Specific Conductance
Total Filterable Residue
Results
660 mg/L
4600 mg/L
200 mg/L
1178 mg/L
none mg/L
none mg/L
1437 mg/L
1670 mg/L
7000 mg/L
<3 mg/L
2.0 mg/L
13 rng/L
20 mg/L
<1 mg/L
1.1 mg/L
20 mg/L
7.4 units
24,000 wnho/cm
16,000.mg/L
06/02/89
Lab No. 890508-7
Invoice No. 50038
Chain
Parameter Name
Antimony ( Sb)
Arsenic (As)
Barium (Ba)
Beryllium (Be)
Cadmi urn ( Cd)
Submitted
KBA
05/08/89
11:30
of Custody
Total Chromium (Cr)
Cobalt (Co)
Copper (Cu)
Iron (Fe)
Lead (Pb)
Manganese ( t-1n)
·Mercury (Hg)
Molybdenum ( Mo)
Nickel (Ni)
Selenium (Se)
Silver (Ag)
Zinc (Zn)
Thallium (Tl)
Sampled
.KBA/DLG
5/3
on file: Y
Results
<0.01 mg/L
<0.01 mg/L
<0.1 rng/L
<0.01 mg/L
0.01 mg/L
<0.01 mg/L
<0.01 mg/L
0.04 rng/L
0.03 mg/L
<0.005 mg/L
2.6 mg/L
<0.001 mg/L
<0.1 mg/L
<0.01 mg/L
<0.05 mg/L
<0.01 mg/L
<0.01 mg/L
0.7 mg/L
~otes: Metals run on· samples filtered and preserved in field. cc: Edward S. Babcock & Sons, Inc.
r;IJa~f!Uy
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1110<!1
_ PHONE (714) 684-1881
EDWARD S. BABCOCK & SONS, INC.
1\BORATORIES
.!15 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 Market
Place SWAT Water Sample
MP-5
Parameter Name
Calcium (Ca)
Sodiwn (Na)
f 'assium (K)
' /,1 Alkalinity as CaC03
Hydroxide (OH)
Carbonate (COJ }
Bicarbonate (HCOJ)
Sulfate (S04)
Chloride (Cl)
Nitrate (N03 )
Fluoride (F)
Biochemical Oxygen Demands
Chemical OA7gen Demand
Oil and Grease
Ortho Phosphate Phosphorus
Bromide (Br)
pH
Specific Conductance
Total Filterable Residue
\
Results
170 mg/L
3500 mg/L
.178 mg/L
793 mgjL
none rng/L
non~ mg/L
967 rng/L
820 mg/L
5400 mgjL
<3 mg/L
1. 7 mg/L
15 mg/L
25 rng/L
<1 rng/L
4.0 mg/L
20 mg/L
7.6 units
17,650 j..!IDho/cm
10,700 rng/L
06/02/89
lab No. 890508-8
Invoice No. 50038
Submitted Sampled
KBA
05/08/89
11:30
KBA/DLG
5/4
Chain of Custody on file: Y
Parameter Name
Antimony (Sb)
Arsenic (As)
Barium (Ba}
Bery lli urn (Be)
Cadmi urn ( Cd)
Total Chromi urn ( Cr)
Cobalt (Co)
Copper (Cu)
Iron (Fe)
Lead (Pb)
Manganese ( Mn)
Mercury (Hg)
Molybdenum (Mo)
Nickel (Ni}
Selenium (Se)
Silver (Ag)
Zinc (Zn)
Thallium (Tl)
Results
<0.01 mgjL
<0.02 mg/L
<0.1 rng/L
<0.01 mg/L
<0.001 rng/L
<0.01 rng/L
<0.01 rng/L
0.02 mg/L
0.02 mg/L
0.01 mg/L
0.53 mg/L
<0.001 mg/L
<0.1 mg/L
<0.01 rng/L
<0.01 rng/L
<0.01 mg/L
0.01 rng/L
0.5 mg/L
lotes: Metals run on samples filtered and preserved in field. · co: Edward S. .Ba~k & Sons, Inc.
~~
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED
PHONE (714) 684-1881
• ABORATORIES
3215 CHICAGO AVE.
ESTABLISHED 19oe
EDWARD S. BABCOCK & SONS, INC .
P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
06/02/89
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Lab No. 890508-9
Attn: David L. Guth
Sample Marked:
Pj#240827-04 ~~ket
Place SWAT Water Sample
MP-Blank(Arroh'head DI)
Parameter Name
Calcium (Ca)
Sodium (Na)
r assium (K)
il Alkalini-ty as CaC03
Hydroxide (OH)
Carbonate (C03)
Bicarbonate (IIC03)
Sulfate (S04)
Chloride (Cl)
Nitrate (NOJ)
Fluoride (F)
Biochemical Oxygen Demands
Chemical Oxygen Demand
Oil and Grease
Ortho Phosphate Phosphorus
Bromide (Br)
pH
Specific Conductance
Total Filterable Residue
Results
<1 mg/L
<1 .mgjL
<1 mg/L
<2.5 mg/L
none mg/L
none mg/L
<3 mg/L
<1 mg/L
<1 mg/L
<1 mg/L
<0.1 mg/L
<2 mg/L
<5 mg/L
<1 mg/L
<0.03 mg/L
<1 mg/L
5.7 units
2.0 j..!II1ho/cm
<5 mg/L
Invoice No. 50038
Chain
Parameter Name
Antimony ( Sb)
Arsenic (As)
Barium (Ba.)
Beryllium (Be)
Cadmi urn ( Cd)
Submitted
KBA
05/08/89
11:30
of Custody
Total Chromium (Cr)
Cobalt (Co)
Copper (Cu)
Iron (Fe)
Lead (Pb)
Manganese ( Hn)
Mercury ( Hg)
Molybdenum (Mo)
Nickel (Ni)
Selenium (Se)
Silver (Ag)
Zinc (Zn)
Thallium (Tl)
1 Sampled
EBA/DLG
5/4
on file: Y
Results
<0.01 mg/L
<0.01 mg/L
<0.1 mg/L
<0.01 mg/L
<0.001 mg/L
<0.02 mg/L
<0.01 mgjL
<0.01 mg/L
0.04 mg/L
<0.005 mg/L
<0.01 mg/L
<0.001 mg/L
<0.1 mg/L
<0.01 mgjL
<0.005 mg/L
<0.01 mg/L
0.01 mg/L
<0.1 mg/L
:~otes: Metals run on samples fil tere;ct and preserved in field. cc: Edward S. Babcock & Sons, Inc.
~!!7wLr
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1 Q08
PHONE (714) 684·1881
A BORA TORIES
EDWARD S. BABCOCK & SONS, INC.
.3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 ~arket Place
SWAT water sample MP-1
Parameter Name Results
EPA Method 9060
T- L.al Organic Carbon
: )::tical Quanti tation Lirni t
Date analysis completed: 05/11/89
totes: ND = None Detected @· FQL.
cc:
30 mgjL
1 mgjL
06/08/89
Lab No. 890508-10
Invoice No. 50039
Sulxnitted Sampled
KBA KBA/DLG ·
05/08/89 05/03/89
11:30
Chain of Custod.y on file: Y
Parameter Name Results
Edward S. Babcock & Sons, Inc.
r/.1& ~ ,!fUy?
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1906
PHONE (714) 684-1881
ABORATORIES
>215 CHICAGO AVE.
EDWARD S. BABCOCK & SONS, INC.
P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 Market Place
SWAT water sample MP-2
Parameter Name
EPA Method 9060
Total Organic Carbon
~tical Quantitation Limit
)
Re~ults
5.3 mg/L
1 mg/L
Date analysis completed: 05/ll/89
Iotes: · ND = None Detected @ FQL.
cc:
06/08/89
Lab No. 890508-11
Invoice No. 50039
Subnitted
KBA
05/08/89
11:30
Sampled
KBA/DLG
05/03/89
Chain of Custody on file: Y
Parameter Name Results
Edward S. Ba.bcock. & Sons, Inc.
~/t1Jr
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 11l0e
~-----PHONE (714) 684-1881
( ) ABORATORIES
J215 CHICAGO AVE.
EDWARDS. BABCOCK & SONS, INC.
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 Market Place
SWAT water sample MP-3
P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
06/08/89
Chain
Parameter Name Results Parameter Name
EPA Method 9060
Total Organic Carbon
~ ~tical Quantitation Limit
)
Date analysis completed: 05/11/89
:otes: ND = None Detected @ FQL.
51 mg/L
1 mg/L
Lab No. 890508-12
Invoice No. 50039
Sul:mitted Sampled
KBA KBA/DLG
05/08/89 05/03/89
11:30
of Custody on file: Y
Results
cc: F.dJ.Jard S • .Ba.l:x::xx::k & Sons , Inc •
~~2
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1908
.•• ----..PHONE (714) 684-1881
( I '\BORATORIES
EDWARD S. BABCOCK & SONS, INC.
-' 215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
To: International Tech. Corp.
17 461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 Market Place
SWAT water sample t--IP-4
Parameter Name Results
EPA Method 9060
Total Organic Carbon
p- ·-ctical Quanti tation Limit
I
Date analysis completed: 05/11/89
lotes: ND = None Detected @ PQL.
cc:
11 mg/L
1 mg/L
06/08/89
Lab No. 890508-13
Invoice No. 50039
Sul::mitted
KBA
05/08/89
11:30
Sampled
KBA/DLG
05/03/89
Chain of Custody on file: Y
Parameter Name Results
Edward S. .Ba.bcock &. Sons, Inc.
•---flUr
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 190e
( -1HONE (714) 684-1881
', 1
\BORA TORIES
EDWARD S. BABCOCK & SONS, INC.
.>215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth.
Sample Marked:
Pj#240827-04 Market Place
SWAT water sample MP-5
Parameter Name
EPA Method 9060
Total Organic Carbon
r· ~tical Quantitation Limit
I ) •
Results
8.7 mg/L
1 mg/L
Date analysis completed: 05/12/89
4otes: ND = None Detected @ PQL.
cc:
06/08/89
Lab No. 890508-14
Invoice No. 50039
Sul::mi tted Sampled
.KBA
05/08/89
11:30
KBA/DLG
05/04/89
Chain of Custody on file: Y
Parameter Name Results
Edward S. Babcock & Sons, Inc.
~()hrlp
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
ESTABliSHED 19oe
(
CALIF. DHS CERTIFIED
PHONE (714) 684·1881
,i ABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
To: International Tech.· Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 Market Place
SWAT water sample
MP-Blank (Arrowhead DI)
Parameter Name
EPA Method 9060
Total Organic Carbon
r-· ftical Quan~i tation Limit
Results
ND mg/L
1 mg/L
Date analysis completed: 05/12/89
,~otes: ND = None Detected @ PQL.
cc:
. 06/08/89
Lab No. 890508-15
Invoice No. 50039
Submitted Sampled
KBA
05/08/89
11:30
KBA/DLG
05/04/89
Chain of Custody on file: Y
Parameter Name ·Results
Edward S. Babcock & Sons, Inc.
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 19Cle
PHONE (714) 684-1881
)BORA TORIES
EDWARD S. BABCOCK & SONS, INC.
.:.1s CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
To: International Tech. Corp.
17 461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 Market Place
SWAT water sample MP-1
Parameter Name Results
EPA Method 9020
Total Organic Halides
P:r"''1tical Quantitation Limit
. ')
0.65 mg/L
0.5 mg/L
Date analysis completed: 05/22/89
)tes: · ND = None Detected @ PQL.
cc:
06/08/89
Lab No. 890508-16
Invoice No. 50039
Submitted Sampled
KBA
05/08/89
11:30
KBA/DLG
05/03/89
Chain of Custody on file: Y
Parameter Name Results
~ S. Babcock &. Sons, Inc.
~/!lJ__ .¥
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
ESTABLISHED taoe CALIF. OHS CERTIFIED
PHONE (714) 684·1881
( )ABORATORIES
EDWARD S. BABCOCK & SONS, INC.
· 215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 ~arket Place
SWAT water sample MP-2
Parameter Name .
EPA Method 9020
Total Organic Halides
~r.~ctical Quantitation Limit
J
Results
2.2 mg/L
2.0 mg/L
Date analysis completed: 05/22/89
)otes: ND = None Detected @ PQL.
cc:
06/08/89
Lab No. 890508-17
Invoice No. 50039
Submitted Sampled
KBA
05/08/89
11:30
.KBA/DLG
05/03/89
Chain of Custody on file: Y
Parameter Name Results
Edward S. Babcock & Sons, Inc.
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 11106
( .. ,PHONE (714) 684·1881
)ABORATOAIES
EDWARD S. BABCOCK & SONS, INC.
J215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 Market Place
SWAT water sample MP-3
Parameter Name Results
EPA Method 9020
Total Organic Halides
F- '•)tical Quanti tation Limit . )
"
2.6 mg/L
1.0 mg/L
Date analysis completed: 05/22/89
otes: ND = None Detected @ PQL.
co:
06/08/89
Lab No. 890508-18
Invoice No. 50039
Submitted Sampled
KBA
05/08/89
11:30
KBA/DLG
05/03/89
Chain of Custody on file: N
Parameter Name Results
Edward S. Babcock &. Sons, Inc.
L~
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
ESTABLISHED 1Q08 CALIF. OHS CERTIFIED
';'HONE (714) 684·1881
I "-BORA TORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
To: International Tech. Corp.
17 461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 Market Place
SWAT water sample MP-4
Parameter Name
EPA Method 9020
Total Organic Halides
'- ,. <Jtical Quanti ta tion Limit
!
Results
1.3 mg/L
0.5 mg/L
Date analysis completed: 05/22/89
·~otes: ND = None Detected @ ~,
cc:
06/08/89
Lab No. 890508-19
Invoice No. 50039
Sul:xni tted Sampled
KBA
05/08/89
11:30
KBA/DLG
05/03/89
Chain of Custody on file: Y
Parameter Name Results
Edward S. Babcock & Sons, Inc.
~!f4ulr
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1110e
,,PHONE (714) 684-1881
1.ABORATORIES
EDWARD S. BABCOCK & SONS, INC.
J215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
To: International Tech. Corp.
17461 .Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 Market Place
SWAT water sample MP-5
Parameter Name Results
EPA Method 9020
Total Organic Halides
~actical Quantitation Limit
• 't
0.84 mg/L
0.2 mg/L
Date analysis completed: 05/23/89
Totes: ND = None Detected @ PQL.
cc:
06/08/89
Lab No. 890508-20
Invoice No. 50039
Submitted Sampled
KBA KBA/DLG
05/08/89 05/04/89
11:30
Chain of Custody on file: Y
Parameter Name Results
F..ciward S. Babcock & Sons, Inc.
cj!k~flat-r
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1908
.. PHONE (714) 684-1661
).ABORATORIES
EDWARD S. BABCOCK & SONS, INC.
J215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE. CALIFORNIA 92502
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-04 Market Place
SWAT water sample
MP-Blank (Arrowhead DI)
Parameter Name ~sults
EPA Method 9020
Total Organic Halides
Practical Quantitation Limit . \
i
ND rngjL
0.01 rng/L
Date analysis completed: 05/23/89
yates:· ND = None Detected@ PQL.
cc:
06/08/89
Lab No. 890508-21
Invoice No. 50039
Submitted Sampled
KBA
05/08/89
11:30
KBA/DLG
05/04/89
Chain of Custody on file: Y
Parameter Name Results
EdJ.mrd S. Babcock & Sons, Inc.
~/IIJ . =~
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1110&
PHONE (714) 684-1881
:'.ABORATORIES
EDWARD S. BABCOCK & SONS, INC.
.3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
06/30/89
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked: Pj#240827-04 Market Place
SWAT water sample .MP-1
Lab No. 890508-22
Invoice No. 50040
Customer No. in0292
Sutmitted
By KBA
Date 05/08/89
Time 11:30
Sampled
KBA/DLG
05/03/89
Chain of Custody on file: Y
) Purgeable Halocarbons and Aromatics
/
EPA Method 624
Parameter Results( ~/L
Acrolein ND
Acrylonitrile ND
Benzene ND
Bromodichloromethane ND
Bromoform ND
Bromomethane ND
Carbon tetrachloride ND
Chlorobenzene ND
Chloroethane ND
2-Chloroethylvinyl ether ND
Chloroform ND
Chloromethane ND
Dibromochloromethane ND
1,2-Dichlorobenzene ND
1,3-Dichlorobenzene ND
1,4-Dichlorobenzene ND
1,1-Dichloroethane ND
1,2-Dichloroethane ND
ND=None detected, detection limit:
Date analysis completed: 05/15/89
--'tes: ** 1?QL = 50 J..lg/L
cc:
Parameter Results ( J..lg/L
1,1-Dichloroethene ND
trans-1,2-Dichloroethene ND
1,2-Dichloropropane ND
cis-1,~-Dichloropropene ND
trans-1,3-Dichloropropene ND
Ethy 1 benzene ND
Methylene chloride ND
1,1,2,2-Tetrachloroethane ND
Tetrachloroethene ND
Toluene ND
1,1,1-Trichloroethane ND
1,1,2-Trichloroethane ND
Trichloroethane ND
Trichlorofluoromethane ND
Vinyl chloride ND
Me thy 1 Ethy 1 Ketone ND
Acetone NDU
5 ~/L NI=Not identifiable
Edward s. Balx:xlck & Sons, !IX!.
~1!:&4--v
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1908
/ ', PHONE (714) 684-1881
EDWARD S. BABCOCK & SONS, INC.
L )LABORATORIES
)
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
06/30/89
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Lab No. 890508-23
Invoice No. 50040
Customer No. in0292
Subnitted Sampled
Sample Marked: Pj#240827-04 Market Place
SWAT water sample MP-2
By KBA
Date 05/08/89
Time 11:30
KBA/DLG
05/03/89
Chain of Custody on file: Y
Purgeable Halocarbons and Aromatics
EPA Method 624
Parameter Results ( ~/L
Acrolein ND
Acrylonitrile ND
Benzene ND
Bromodichloromethane ND
Bromoform ND
Bromomethane ND
Carbon tetrachloride ND
Chlorohenzene ND
Chloroethane ND
2-Chloroethylvinyl ether ND
Chloroform ND
Chloromethane ND
Dibromochloromethane ND
1,2-Dichlorobenzene ND
1,3-Dichlorobenzene ND
1,4-Dichlorobenzene ND
1,1-Dichloroethane ND.
1,2-Dichloroethane ND
Parameter Results ( 1-lg/L
1,1-Dichloroethene ND
trans-1,2~Dichloroethene ND
1,2-Dichloropropane ND
cis-1,3-Dichloropropene ND
trans-1,3-Dichloropropene ND
Ethyl benzene ND
Methylene chloride ND
1,1,2,2-Tetrachloroethane ND
Tetrachloroethene ND
Toluene. ND
1,1,1-Trichloroethane ND
1,1,2-Trichloroethane ND
Trichloroethene ND
Trichlorofluoromethane ND
Vinyl chloride ND
Me thy 1 Ethy 1 Ketone ND
Acetone NDU
. ND=None detected, detection limit:
.) Date analysis completed: 05/15/89
Aotes: ** PQL = 50 ~/L
5 1-lg/L NI=Not identifiable
cc:
Edward S. Babcock & Sons, Inc.
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTAB~ISHEO 1Q08
PHONE (714) 684·1881
. !ABORATORIES
EDWARD S. BABCOCK & SONS, INC .
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
06/30/89
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Lab No. 890508-24
Invoice No. 50040
Customer No. in0292
Sutmitted Sampled
Sample Marked: Pj#240827-04 Market Place
SWAT water sample MP-3
By KBA
Date 05/08/89
Time 11:30
KBA/DLG
05/03/89
Chain of Custody on file: Y
) Purgeable Halocarbons and Aroma tics
EPA Method 624
Parameter
Acrolein
Acrylonitrile
Benzene
Bromodichloromethane
Bromofonn
Bromomethane
Results(
ND
ND
~/L ) Parameter Results ( llg/L
Carbon tetrachloride
Chlorobenzene
·360
ND
ND
ND
ND
ND
ND
ether ND
ND
Chloroethane
2-Chloroethylvinyl
Chlorofonn
Chloromethane
Dibromochloromethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
ND
ND
ND
ND
ND
ND
ND
ND=None detected, detection limit:
pate analysis completed:.05/l5/89
_ .Jtes: ** PQL = 50 llg/L
cc:
1,1-Dichloroethene ND
trans-1,2-Dichloroethene ND
1,2-Dichloropropane ND
cis-1,3-Dichloropropene ND
trans-1,3-Dichloropropene ND
Ethyl benzene 11
Methylene chloride ND
1,1,2,2-Tetrachloroethane ND
Tetrachloroethene ND
Toluene ND
1,1,1-Trichloroethane ND
1,1,2-Trichloroethane ND
Trichloroethene ND
Trichlorofluoromethane ND
Vinyl chloride ND
Me thy 1 Ethy 1 Ketone ND
Acetone 130**
5 llg/L NI=Not identifiable
Edward s. Babcock &; Sons' Inc •
... rfitL;_.~
(
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1908
~HONE (714) 684-1881
EDWARD S. BABCOCK & SONS, INC.
ABORATORIES
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
06/30/89
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Lab No. 890508-25
Invoice No. 50040
Customer No, in0292
Sutmitted Sampled
Sample Marked: Pj#240827-04 Market Place
SWAT water sample MP-4
By KBA
Date 05/08/89
Time 11:30
KBA/DLG
05/03/89
Chain of Custody on file: Y
) Purgeable Ha.locarbons and Aromatics
EPA Method 624
Parameter Results( ~/L
Acrolein ND
Acrylonitrile ND
Benzene ND
Bromodichloromethane ND
Bromofonn ND
Bromomethane ND
Carbon tetrachloride ND
Chlorobenzene ND
Chloroethane ND
2-Ghloroethylvinyl ether ND
Chloroform ND
Chloromethane ND
Dibromochloromethane ND
1,2-Dichlorobenzene ND
1,3-Dichlorobenzene ND
1,4-Dichlorobenzene ND
1,1-Dichloroethane ND
1,2-Dichloroethane ND
ND=None detected, detection limit:
)Date analysis completed: 05/15/89
_,otes: ** PQL = 50 ~/L
co:
Parameter Results( ~/L
1,1-Dichloroethene ND
trans-1,2-Dichloroethene ND
1,2-Dichloropropane ND
cis-1,3-Dichloropropene ND
trans-1,3-Dichloropropene ND
Ethyl benzene ND
Methylene chloride ND
1,1,2,2-Tetrachloroethane ND
Tetrachloroethene ND
Toluene ND
1,1,1-Trichloroethane ND
1,1,2-Trichloroethane ND
Trichloroethene ND
Trichlorofluoromethane ND
Vinyl chloride ND
Methy 1 Ethy 1 Ketone ND
Acetone ND**
5 ~/L NI=Not identifiable
Edward s. Babcock & Sons, ~.
v1~./ak
\
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED
PHONE (714) 684-1881
ESTABLISHED 11~08
! '-ABORATORIES
EDWARD S. BABCOCK & SONS, INC.
I
)
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
06/30/89
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Lab No. 890508-26
Invoice No. 50040
Customer No. in0292
Suhnitted Sampled
Sample Marked: Pj#240827-04 Market Place
SWAT water sample MP-5
By KBA
Date 05/08/89
Time 11:30
KBA/Dl..G
05/04/89
Chain of Custody on file: Y
Purgeable Halocarbons and Aromatics
EPA Method 624
Parameter Results{ ~/L Parameter Results( ~/L
Acrolein ND 1,1-Dichloroethene ND
Acrylonitrile ND trans-1,2-Dichloroethene ND
Benzene ND 1,2-Dichloropropane ND
Bromodichloromethane ND cis-1,3-Dichloropropene ND
Bromoform ND trans-1,3-Dichloropropene ND
Bromomethane ND Ethy 1 benzene ND
Carbon tetrachloride ND Methylene chloride ND
Chlorobenzene ND 1,1,2,2-Tetrachloroethane ND
Chloroethane ND Tetrachloroethene ND
2-Chloroethylvinyl ether ND Toluene ND
Chloroform ND 1,1,1-Trichloroethane ND
Chloromethane ND 1,1,2-Trichloroethane ND
Dibromochloromethane ND Trichloroethene ND
1,2-Dichlorobenzene ND Trichlorofluoramethane ND
1,3-Dichlorobenzene ND Vinyl chloride ND
1,4-Dichlorobenzene ND Methyl Ethyl Ketone ND
1,1-Dichloroethane ND Acetone ND**
1,2-Dichloroethane ND
ND=None detected, detection limit:
)Date analysis completed: 05/15/89
Aotes: ** FQL = 50 ~/L
5 ~g/L NI=Not identifiable
cc:
Emm.rd. s. Babcock &. Sons, 1m.
~~
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1808
PHONE (714) 684-1881
\ABORATORIES
EDWARD S. BABCOCK & SONS, INC.
J215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
06/30/89
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Lab No. 890508-27
Invoice No. 50040
Customer No. in0292
Subni tted Sampled
Sample Marked: Pj#240827-04 Market Place
SWAT water sample
MP-Blank (Arrowhead DI)
By KBA
Date 05/08/89
Time 11:30
KBA/Dl..G
05/04/89
Chain of Custody on file: Y
) Purgeable Halocarbons and Aromatics
EPA Method 624
Parameter Results( ~/L
Acrolein ND
Acrylonitrile ND
Benzene ND
Bromodichloromethane ND
Bromoform ND
Bromomethane ND
Carbon tetrachloride ND
Chlorobenzene ND
Chloroethane ND
2-Chloroethylvinyl ether ND
Chloroform ND
Chloromethane ND
Dibromochloromethane ND
1,2-Dichlorobenzene ND
1,3-Dichlorobenzene ND
1,4-Dichlorobenzene ND
1,1-Dichloroethane ND
1,2-Dichloroethane ND
ND=None detected, detection limit:
)ate analysis completed: 05/15/89
ites: ** PQL = 50 ~/L
cc:
Parameter Results( ~g/L
1,1-Dichloroethene ND
trans-1,2-Dichloroethene ND
1,2-Dichloropropane ND
cis-1,3~Dichloropropene ND
trans-1,3-Dichloropropene ND
Ethy 1 benzene ND
Methylene chloride ND
1,1,2,2-Tetrachloroethane ND
Tetrachloroethene ND
Toluene ND
1,1,1-Trichloroethane ND
1,1,2-Trichloroethane ND
Trichloroethene ND
Trichlorofluoromethane ND
Vinyl chloride ND
Methy 1 Ethy 1 Ketone ND
Acetone ND**
5 ~/L NI=Not identifiable
Ei:bolard. s. Babcock & Sons , Inc.
~/a.Lp
. r
F'HONE 684-1881
AREA COllE 71" EDWARD S. BABCOCK & SONS. INC .
ACRICUL.TUIIIAL CONSUL.T.t.NTI
CHEWISTS
AP,~ROV£0 WATER UaOIIIATOIII'I'
_/ LABORATORIES
f'. o. •ox -432
RIVER$10£. CALIFORNIA .2502
3215 CHICAGO AVE. . .
BASE/~UTRALS AND ACIDS
ORGANIC ANALYSES
Date of Report: Jtme 30, 1?89 Lab ·sample ID No. 890508-28 Laboratory Siqnature La~-!~~~--.--~-------
Name: E.S. Babcock & Sons. Iqc. Director: -~ l~_?
Name ot Sampler . Sampler: K.B.A. I D.L.r;. , Employed By: I. T. Corp.
Date/Time Sample DatetTime.Sa=ple --~w~e-r-e~H~o~l~d~i-n_q _____ Y_e_s __ Collected: 5 ..... 3-89 Received I Lal:l: 5-8-89 11:30 'rimes Observed? Were a.ll the constituents lis~t-ed~--
Test Methods: 625/6'h8 below quantitied? :yes
==•••••••••••~•=-==a=a•--•••••--•••••••---••••==••=•-=••--••-----•••••a=== system . .
Name= SHATs Project No. 240827-04
System
Numbe~=--------------Description of
Sa.mplinq Point:~_~ ___ ke_t __ P_1_ac_e ______ ~~~~------County Name: ____________ __ Name/No. Ot Sample Stat1on
Source: ~-1 ·Number:
Date·& I I I I I I l I I I I I I I
Time ot l I J I I I I t I I I
Sample: Y Y M M D D T T T T
Water U . trse~ I I I I Su.bmi ttecl to SWQI 'l'ype: · G/S ID: By: _______ _ PlaCJe an "X" in box to d.e~ete all data tor.thia station/date/time. U REPORTING CONSTI'l'tTEN'l'
• 0 T S'l'ORET ANALYSES DETECTIC!:
UNITS T CODE RESULTS LIMIT
Date Analyses completed 73672 8!9!0 !6 11 14 I I I I I
YYMMOO
Ana.lyzinq Agency Code (Lab) 28 L l T I I
Intens~ve survey Number 116 _.1_ _L _.1_ I ~
uq7L Acenaphthene 34205 I N,n 5 • JO·c
uq/L Acenaphthylene 34200 _.1_ 1 N n 5 • I 0 I 0
uq/L Anthracene 34220 L N n 5 • I 0 I C
uq/L Aldrl.n 39330 N n 0 • I o 11
Uq/L Benzo(a)anthracene 34526 _.1_ N,D 1 0 • I 0 I 0
uq/L Benzo(b)fluoranthene 34230 I I N n 1 0 • I 0' C
ug/L Benzo k)fluoranthene 34242 N T1 1 0 • ToTe
Uq/L Benzo a)pyrene 34247 I_ l I I N 'D 1 0 • I 0 I C
uq/L Benzo ~ghi) p_erylene 34521 L l I N D 1 0 • 1 aTe
uq}L Benzyl butyl _ph~halata 34292 _L _j 1-NI D 1 0 .IOIC uqJL' B - BHC 39338 L l N D 0 • I 015
uq/L 6 --BHC 34259 NIT) 0 • I o I 5
uq/L bis(2-chloroethJ[l1ether 34273 I I NtD 5 • I 0 I C uq/L. bis{2-chloroethoXY)meth&ne 34278 t t N D 5 • 1 ol c ug/L bl.s(2-ethylhexvl)~hthal•te 39100 1 .6. 5 • I o I c uqJL bl.s(2-chloroisopr.opyl)ether 34283 ,· N.D 5 • ·1 0 I C ug/L 4-Bromophenyl phenyl ether 34636 L _l_ _L I NID 5 • -I 0 I C uq/L Chlordane . 39350 1 N.n 0 . -, 0 f 5
uq/L 2-Chloronaphtha.lene 34581 -~ I lo.T T'l 5 • I 0 I o Base/N~utrals and Acids (Continued) PAGE 2 OF 3
AME & NUMBER I T Coro SWAT P ':Jft240827 04 M ke Pl '1Pl SYSTEM N . s . .'1', - ar t ace -. '
REPORTING CONSTITUENT T STORET ANALYSES DETECTION
UNITS T CODE RESULTS LIMIT
ug/L 4-Chlorophenyl phenyl ether 34641 I I N tfi 5 . 0 0 uq/L Cry sene 34320 I I 1 N ID 5 . 0 0
Uq/L 4 t4 1 -QDD'" 39310 I N tD 0 . 0 2
uq/L 4,4 1 -DDE 39320 NID 0 . 0 1
ug/L 4,4 1 -DDT 39300 1 l _I IN ID 0 • 0 2
ug/L Dibenzo(a,h)anthracene 34556 I I I N ,o 5 • 0 0
Ug/L Di-n-butylphthalate 39110 I I I ND 5 • 0 0
ug/L 1,3-Dichlorobenzene 34566 I I t IN ,D 0 •. 5 0
uq/L 1L2-Dichlorobenzene 34536 I N D 0 . 5 0
Ug/L 1,4-Dichlorobenzene 34571 I I IN ID 0 I • 5 0
ug/L 3,3'-Dichlorobenzidine 34631 I I I l N tD 2 0 . 0 0 Uq/L Dieldrln 39380 I I IN ID 0 . 5 0
Ug/L Diethyl phthalate 34336 I IN tD 15 • 0 0
uq/L Dimethyl phthalate 34341 I tN U1 5 . 0 0
Ug/L 2,4-Dinitrotoluene 34611 I I N.D 5· . 0 I ·-
ug/L 2,6-Dln~trotoluene 34626 I I I IN JJ ·5 . c
ugJL Di-n-octylphthalate 34596 I I I IN JJ 5 • Oi
ug/L Endosultan sulfate 34351 I I N D 0 . 0 >• ...
Ug/L Endrin aldehyde 34366 I I I IN J) 0 • 0 5
ug/L Fluoranthene 34376 I I I IN D 5 • 0 0
uqJL Fluorene 34381 I I IN p 5 • 0 0
Ug/L Heptachlor 39410 1_ I I IN j) 0 • 0 2
uqJL Heptachlor epoxide 39420 I I I IN j) 0 • 1 ,.
uqJL Hexachlorobenzene 39700 , , 1 N 10 5 . 0 ' ug/L Hexachlorobutadiene 34391 I I I rN rD 5 • 0 0 ug/L Hexachloroethane 34396 I I I ·N 1n 5 . 0 0
ug/L Indeno(1,2,3-cd)Pyrena 34403 I I I I til rf) 1 0 • 0 0 ug/L Isophorone 34408 _L I I . IN d) 1 0 . 0 0
u_gjL Na~hthalene 34696 LN l) 5 . 0 0
ug/L Nitrobenzene 34447 I · I t-1 l) 5 . 0 0
ug/L N-Nltrosodi-n-pro~lam~ne 34428 l I IN i) 5 • ;0 0
ug/L PCB-1016 34671 L L tN l) 0 • .2 0
ug/L PCB-1221 39488· I I I M 1n 0 . 2 0
Ug/L PCB-1232 39492 I I M1n 0 • 2 0
ug/L PCB-1242 39496 I I.M 1n 0 . 2 0
ug/L PCB-1248 39500 I 1 t-~.n 0 . 2 0
ug/L PCB-1254 39504 I I I til In_ 0 • '2 0
uq/L PCB-1260 39508 _ _l_ ,t.J .n 0 . 2 0
Ug/L Phenanthrene 34461 I I I 1N 1D 5 • 0 0
ug/L py_rene 34469' I I I IN oTl 5 • 0 0
ug/L Toxaphene 39400 1 1 L ,t-1 of) 0 . 5 0
Ug/L 1,2,4-Trichlorobenzene 34551 1_ I 1N n 5 • 0 0
ACID EX'l'RACTABLES
UCJ/L 4-Ch1oro-3-methv1phenol 34452 ~ 1 1 1M on 5 • 0 0 ug/L 2-Chlorophenol 34586 I ; M .n 5 . ,.0 0
uqJL 2,4-Dichlorophenol 34601 1 M1 n 5 0 ,.. •
ug/L 2L4-D~methylphenol 34606 l I I I Mt n_ 5 I_ • 0
UCJ/L 2,4-D1n1tropheno1 34616 I • 1 M1 n 5 • .0 (J
UCJ/L 2-Methyl-4L6-d~nitrophenol 34657 I I I I Ml n 5 • :o 0 UCJ/L 2-Nitrophenol 34591 1 1 N1 D 5 .. .0 0
UCJ/L 4-Nitrophenol 34646 '- NtD 5 • -.. 0 0
ugLL Pentachlor.o~henol 39032 ' I N, D 0 • 5 0
CHS 8351 B (3/17)
Base/Neutrals and Acids (Continued)
SYSTEM NAME & NUMBER I.T. Coro. S1:.JATs Pji,£240827-04 Market Place MP-1
REPORTING
UNITS
ua/L
ug/_L
uqL_L
ug/L
uq/L
uq/L
uq/L
uq/L
ugjL
uq/L
uq/L
Lab No. 890508-28
ADDITIONAL EXTRACTABLE PARAMETERS
CONSTITUENT T STORET A.NhLl!'SES _..,__ T CODE RESULTS
Phenol 3465~ 1 N D
2,4,6-Trichlorophenol 34621 N D
Banzidl.ne 39120 N_LD
a - BHC 39337 N D
-y - BHC 39340 1 t 1 N ,D
Endosulfan I 34361 N_!D_
Endosulfan II 34356 N 1D
Endrl.n 39390 N,D
Hexachlorocvclopentadiene 34386 N D
N-Hitrosodimethylaml.ne 3~.;38 N D
H-N i trosodl._p_henylaml.ne 34433 N D
Note any unidentified peaks below.
CMS 8351 B (3il7l
PAGE 3 OF 3
DETEC':!ON
LIMIT
I I 5l. I 0 I 0
I 151. I OJO
I I 51. I 0 I o
I f o I. I o 11
I I 0 I. I OJl
I I 0 t. I o 11
I I 0 I. I o 11
I I OJ. I 0 11
12JOJ.JOIO
I I 51. I 0 I 0
I 151. I o; o
AGRICUI.. TUlliA I. CONSUr.'f.AHT&
C>U .. I5Ta
~~~MOV'D ~AT'N ~aONATOMY
ppjQNE llllo4-1881
'/ ~~ ~Nu Cog' 714 EDWARD S. BABCOCK"& SONS. INC.
L.~60RATORICS
321:1 CHICAGO AVE.
"· o. eox •3z
RIV£QJDE. CAL..IfrORNIA tll150Z
. .
BASE/NJUTRALS AND ACIDS
ORGANIC ANALYSES
Date of Report: Jtme 30, 1989 Lab Sample ID He. 890508-29 Laboratory Siqnatura Lab r ;j ,;,1-. -~,Yk£,~-...... ---- Name; E.S. Babcock & $ons. I~c. Director: 1,llk'Jb,~ _,-? Name ct SAmpler . I
Sampler: K.B.A. I D.L.~. Emplcyeci By: I. T. Corp.
Date/Time samcl.e DAte!'riliia. Sqple ---:W::-e-r-e--:-:H:-c':"l"';"ci!T"'n-q----- eolle.cted: s-·:':l-H9 Received I ·La};): 5-8-89 11:30 'l'imea Observed? Yes Were all the constituents listed Test Methccis: 625/608 below quantified? yes Q••--••••••••~•·----•••--•••••••••••------•••••--••••v••--••--•-----••---=• system .
Name~ St.JATs "Pro4ect No. 240827-04
system
Numbe~=---------------Desorlptlcn of
Samplinq Point:~~~-_ke_t_P_la_c_e_. ______ ~~~-------Ccunty Name: _____________ _ Name/No. Ot Sample ~-2 St&t!on
source=---------...---- ·Number: I I J I I I t I I I I I ! I i Date·& Time ot l I I I I I I t I I I
Sample1 Y Y M M D D T T T f Water U . Use: ! I I I Submitted to SWQI~ 'rype:' G/S ID: By: ___ . __ _
Pla.oe an 11 X11 in box to da~ete all c:ta.ta tor.thia atation/date/tima. D REPORTING CONSTI'l'UEN'l' T STORET ANALYSES DETECTIC!: I 0 I
! UNITS T CODE RESULTS LIMIT
Date Analyses Comoleteci 73672 8L9 10 I 6 11 1 4 I I I I I ! YYMMDD \
Analvzincr Ag_encv Code (Lab} 28 L I_ _1 I I I I
Intensive survey Number 116 I I ~ I
uq/L Acenaphthene 34205 I N n 51 . I 0 · 0
ua/L Acenaphthylene 34200 N n 51 . I 0 I 0
uq/L Anthracene 34220 1 _l N n 51 • I 0 I 0'
ua/L Aldrln 39330 N n 0 I • I 0 11!
ua/L Benzo(a)anthracene 34526 N n 1 0 I • I 0 I 0;
uq/L Benzo(b)fluoranthene 34230 i NtD 1 0 I • I 0 I 0!
ua/L Benzo k)fluoranthene 34242 N D 1 0 I • I 0 I 0 1
ua7L Benzo a)pyrene 34247 N n 1 o I • I oTo:
uq/L Benzo ghi)perylene 34521 I N D 11 0 I • I 0 I 0:
uq/L Benzyl butvl Phthalate 34292 _I_ _j _l N I D l 0 I • I 0 I 0 1 ug/L' 8. - BHC 39338 N D 0 I. I 015:
uq/L 6 --BHC 34259 N tl) 0-1 . I 0 I 5:
uq/L bis 2-chloroethy~Jether 34273 L _t N1 D 51 . I oT o! uq/L. bis 2-chloroethoxY)meta&ne 34278 N D -1 5 I • I 0 I 0 ug/L bl.s 2-ethylhexyl)phthal•te 39100 _I_ N.n 51 . I 0 I 0 ua/L b-is 2-chloroiso~r.oPvl)ether 34283 N D 51 .·1 0 I 0' ua/L 4-Bromophenyl phenyl ether 34636 I I L _1 N 1 n 51 . I 0 I 0, uq/L Chlordane . 39350 1 N.n Ol.!OIS'
ua/L 2-Chloronaphthalene 34581 M n 51. I 0 I 0:
Base/N~utrals and Acids (Continued) PAGE 2 OF 3
S~STEM NAME & NUMBER I T ~ ro SWAT p·#240827 04 Marke Pl ·. .. 'vO . •, s .'1~ - t ace~-2 REl?ORTING CONSTITUENT T STORET ANALYSES DETECTION '
UNITS T CODE RESULTS LIMIT
ucr/L 4-Chlorophenvl phenyl ether 34641 J. L _l _t__N_ ill_ 5 I 0 0 ucr/L Cry sene 34320 I I .~ tN tD 5 I 0 0
Ug/L 4,4 1 -DDD 39310 .I I _l_ N .n 0 • 0 2
ua)L 4, 4 '-ODE""- 39320 .. L .tO. J. tO I ? 0 . 0 1
ua/L 4,4 1 -DDT 39300 .L _t _L IN .o 0 • 0 2
ua/L Dibenzo(a,h)anthracene 34556 ..1. .1. _l ,N ,n 5 • 0 0 ug/L Di-n-butylphthalate 39110 •.. t. _L 1 N.n 5 • 0 0
uq/L 1,3-Dichlorobenzene 34566 I I I NtD 0 .. 5 0 Uq/L 1,2-Dichlorobenzene 34536 L L L IN D 0 . 5 0 uq/L 1,4-Dichlorobenzene 34571 _l _l IN J) 0 • 5 0
uq/L 3,3 1 -Dichlorobenzidine 34631 I I I IN _J) 2 0 . 0 0 Ug/L Dieldrin . 39380 I I IN J) 0 . 5 ('l
ua/L Diethvl phthalate 34336 _L .L _L _L N J) 5 . 0 0
uq/L Dimethyl phthalate 34341 I I IN J) 5 I I 0 0
ua7L 2,4-Dinitrotoluene 34611 _L L NJ) 5 I 0'
uq/L 2,6-Dinitrotoluene 34626 L _L .t.N .. tD 5 I o: uq/L Di-n-octylphthalate 34596 I I INJl 5 • 01 ua/L Endosultan sulfate 34351 l I I ,N D 0 • 0 ~
ua/L Endrin aldehvde 34366 l I I IN ;n 0 • 0 5
ua/L Fluoranthene 34376 .l l I IN D 5 • 0 0
ua/L Fluorene 34381 _l L .t. IN p 5 • 0 0 ug/L Heptachlor 39410 I _t _t _.tN _p 0 • 0 2 uaJL Heptachlor epoxida 39420 I 1 1 1N Jl 0 • 1 0 ucr/L Hexachlorobenzene 39700 _t . 1 1. IN ID 5 . 0 ( ua/L Hexachlorobutadien• 34391 I I I IN .n 5 . 0 L
ucr/L Hexachloroethane 34396 1 I l IN If) 5 • 0 0
ucr/L Indeno(1,2,3-cd)Pyrene 34403 _l l 1 IN ll 1 0 ··:·. 0 0 ucr/L Isophorone 34408 _L _L _L _L~fl 1 0 • 0 0
ucr/L Naphthalene 34696 I _lllfl 5 .. ·0 0
ua/L Nitrobenzene 34447 l l L. IN fl 5 . 0 0
ua/L N-N1trosod1-n~pro~lam~ne 34428 _L l t •ti n 5 • 0 0 ua/L PCB-1016 34671 _1. _L _L ...tN n 0 . 2 0
uq/L PCB-1221 39488· t I .1. ..L N 1n 0 •. 2 0
ucrlL PCB-1232 39492 I t N tn 0 • 2 0
uq/L PCB-1242 39496 I I ~·,.,~n 0 • 2 0
Uq/L PCB-1248 39500 I I
'"" .n 0 . 2 0
ucr/L PCB-1254 39504 j_ .L L l K_tll 0 • 2 0
Uq/L PCB-1260 39508 _L _L _L ..t1L .n 0 . 2 0
UQ'/L Phenanthrene 34461 L l _t ttl. i\ 5 • 0 0
ucr/L PYrena 34469' L I. L tti_ll_ 5 • 0 0
ucr/L ToxaDhene 39400 j_ _L _L ll.ll 0 . 5 0
ucr/L 1,2,4-Trichlorobenzena 34551 l I. _L .t.H. n 5 • 0 0 ACID EX'l'RAC'I'ABLES
ua/L 4-Ch1oro-3-methylphenol 34452 • 1 1 N 1n 5 .. lO 0 uqJL 2-Chlorophenol 34586 l t l ~ K..tn 5 .·ro 0
uq/L 2,4-Dichlorophenol 34601 _l . .L _.L _L..Hl T'l 5 . ro 0 ua/L 2,4-DimethvlDhenol 34606 I I N1 T'l 5 ·o r
I .
ua/L 2,4-DinitroDheno1 34616 L .L • Ml.T'I 5 ···" 0 •
ucr/L 2-Methyl-4 6-din1tropheno1 34657 I _t _t. Mt T'l 5 ..
0 0 •
ua/L 2-NitroDhenol 34591 _l _L _L .L N D 5 • "0 0
ucr/L 4-Nitrophenol 34646 I I l NtD 5 • 0 0
uq/L Pentachlo~o~henol 39032 . I I N, D 0 • 5 0
CHS 8351 B (3/17)
Base/Neutrals and Acids (Continued) PAGE 3 OF 3
SYSTEM NAME & NUMBER I.T. Coro. SWATs P4#240827-04 Market Place ~-Z ,r Lab No. 890508-29
ADDITIONAL EXTRACTABLE PARAMETERS
REPORTING CONSTITUENT T STORET ANhLYSES DE'I'EC':!ON
UNITS -.<:- T CODE RESULTS LIMIT
UO/L Phenol 3469~ I N j_D I I 51 . I 0 l 0
ug/L 2,4 6-Trichlorophenol 34621 N D I I 5 L. I 0 I 0
uqjL Banzidl.ne 39120 I _I N D I ISI.JOIO
u_g/L a - BHC 39337 N D L 1 o L. I o 11
ugJL r_ - BHC 39340 N _1D I I o I. I o 11
Ug/L Endosulfan I 34361 I I N j_D I I 0 I. I o 11
ug/L Endosulfan II 34356 _l N 1D I I 0 I. I OJl
u_gjL Endrl.n 39390 _I _I IN D I I OJ. I 011
uq/L Hexachlorocyclopentadiene 34386 I N ,D 1210J.J010
Ug/L N-Hitrosodimethylaml.ne 3~438 N D l I 51 . I o I o ug/L H-Nitrosodl.phenvlaml.ne 34433 I I N 1D I I 5J.J 0; o Note any unidentified peaks below.
)
/
OHS 8351 B (3/17)
-- L..
AGAICUL..TU .. AL. CCNSUL..TAHTS
Ct<UOiaTI
,t.l'tf'IIOVlD WATl" uaoiiATDIIY
P~ONE 684-1881
r'-------.. AREA Coo& 71• EDWARD S. BABCOCK ·a: SONS. INC.
LABOR A TOAICS
321 ~ CHICAGO AVE.
-- .L
1'1. o. aox 432
RIVItUICE. CALI,.ORNIA •:r.soa
. .
BASE/~'l'RALS AND ACIDS
ORGANIC ANALYSES
Data ot Report: June 30, 1989 L&b sample IO llo. 890508-30 Laboratory Siqnatura Lal::t Jtdl-~ ··------~~-----..---.-- Name: E S. Babcock & Sops, Iijc, Director: '>~_c:/
Name ot Sampler 1
Sampler: K. B .A. I D. L. r.;. Elllpl oyec:i By: _':':I:-. _T_. _Co':':"-rpo::-:-. ,------- Data/Time sampl~ Date~Iia.S~pla Were Holdinq C:ollecteci: 5-J-89 Received I Lab: 5-8-89 11:30 '!'imea observed? Yes Were all the constituents listed
Test Methods: 625/608 below quAnti tied? . yes
c••-••••••••~··--•••-•••••••••••--••••-•m••••••••---·•--=:
system -
Name~ St.rA.Ts "Proiect No. 240827-04
system
Numbe~=------------Description of
Samplinq Point:~_~_ke_t __ P_la_c_e_. ______ ~~~-------County Name: ____________ __ Name/No. ot Sample St&t!cn
.source: MP-3 ·Number: I I ! I I I I I I I I I I I
Date·&
Time ct l I I I I I I t I I I
Sample~ Y Y M M D D ¥ T T !
Water . U . Use%: I I I I Submitted to SWQI.
Type:' G/S ID: By: __ .------
Plaoe an "X" in box to cie~ete all d.ata tor.thia atation/date;time. 0 REPOR'l'ING CONSTI'l'UENT .. 'I' S'l'ORE-r ANALYSES DETECTIC!: UNITS T CODE RESULTS LIMIT Date Analyses completed 73672 8t9 10 I 6 11 I 4 I I I I I YYMHDD
Analyzing Agency_ Code _(Lab) 28 )_ _)_ _l I I
Intensive survey Number 116 I I !
ug7L Acenaphthene 34205 .1. N n 5 • I 0 · C
UQ'/L Acenaphthv1ene 34200 ' N n 5 • I 0 I 0
ug/L Anthracene 34220 I N n 5 • l 0 I o
uq/L Aldrln 39330 _1. N1n 0 • I 0 11
ucOL Benzo alanthra.cene 34526 N,D 1 0 • I 0 I 0
uq7L Benzo b)fluoranthene 34230 L N n l 0 • I 0! 0
uq/L Benzo k)fluoranthene 3~242 N n l 0 • -~ 0 I 0
uq/L Benzo(a)Pvrene 34247 N n 1 0 • I 0 I 0
uq/L Ben·zo (qhi) perylene 34521 N D l 0 • I 0 I 0
uq/L Benzyl butvl phthalate 34292 I I N D l 0 • I 0 I 0 ug/L' 8 - BHC 39338 l l _l N D 0 • 1 a·r s
uq/L 6 --BHC 34259 N1D 0 • I 015
uq/L bis(2-chloroethyl)ether 34273 t I l N,D 5 • I 010
uq:JL. ors(2-chlorcethoxY)meth&ne 34278 L t N D 5 • 1010 Ug/L bls(2-ethylh~xyl}p~hal•te 39100 t;.? I 5 • I 0 I 0 uq/L bis{2-chloroiso~roovl)ather 34283 N D 5 • ·1 aT o
ug/L 4-Bromophenyl ohenvl ether 3<.636 1 _l _l I Nl n 5 • I 0 I 0 uq/L Chlordane . 39350 1 N,n 0 • I 015
uq/L 2-Chlorcnaphthalene 34581 MtT'I 5 • I 0 I 0
DHS 1.351 B 131&71
Base/N~utrals and Acids (Continued) PAGE 2 OF 3 .
S'iSTEM N .. ~ . •, s .'J - t AME & NUMBER I T Coro SWAT P '4/:240827 04 Marke Pl ace REPORTING CONSTITUEN'r T STORET ANALYSES DETECTION
UNITS T CODE RESULTS LIMIT
ugjL 4-Chlorophenyl phenyl ether 34641 I I N.n 5 . 0 0
ug/L casene 34320 I I N'tD 5 . 0 0
Uq/L 4,4 1 -DDD 39310 I I N ~n 10 . 0 2
uq/L 4 1 4 1 -UDE" 39320 I I N~ 0 • 0 1
ug/L 4 1 4 1 -DDT 39300 I I I N 1D 0 • 0 2
ug/L Dibenzo(a 1 h)anthracene 34556 I I I N 1D 5 • 0 0
Ug/L Di-n-butylphthalate 39110 I NtD 5 • 0 0
UgjL 1 3-Dich1orobenzene 34566 I I I N 1D 0 L 5 0
Ug/L 1 2-Dich1orobenzene 34536 I LN D 0 . 5 0
Ug/L 1 1 4-Dichlorobenzene 34571 I I N ,n .0 • 5 0
Uq/L 3L3'-Dichlorobenzidine ·34631 I I I NtD 2 0 . 0 0
Ug/L Dieldrin 39380 _L I l tN til 0 . 5 " Ug/L Diethyl phthalate 34336 I IN J) 5 . 010 Ug/L Dimethyl phthalate 34341 I L 1NtD 5 • 0 0 Ug/L 2t4-Dinitrotoluene 34611 I N.D 5 • 01
ug/L 2L6-D1nitroto1uene 34626 I I I IN J) 5 • o:
uq/L oi-n-octylphthalate 34596 I I I IN .n 5 • 01
ug/L Endosu1fan sulfate 34351 I I L IN j) 0 • 0 :I
Ug/L Endrin aldehyde 34366 I I I tN .n 0 .. 0 5
Ug/L Fluoranthene 34376 I I I ,N p 5 •·. 0 0
ug/L Fluorene 34381 I I I IN j) 5 • 0 0 uq/L Heptachlor 39410 I I I N j) 0 • 0 2 ug/L Heptachlor epoxida 39420 I l L IN j) 0 • 1 0 uq/L Hexachlorobenzene 39700 I I IN' 10 5 . 0 r Ug/L Hexachlorobutadiena 34391 I L L IN' til 5 . 0 I.
ug/L Hexachloroethane 34396 I I 1N_fi 5 • 0 0
uqjL Indeno(1,2 3-cd)P¥rena 34403 I I I IN il 1 0 • 0 0 u_g/L Isophorone 34408 I I I IN il l 0 • 0 0
ug/L Nat>hthalene 34696 I I I IN il 5 . 0 0
Ug/L Nitrobenzene 34447 I· IN' fl 5 . 0 0
Ug/L N-N~trosodi-n-propylamine 34428 I tN' il 5 . 0 0
uqJL PCB-1016 34671 I I I IN' ll 0 • 2 0
Ug/L PCB-1221 39488· I ,· I t N tTl 0 • 2 0
uqjL PCB-1232 39492 L I I I N.tn 0 . 2 0
uqJL PCB-1242 39496 t I 1 1.N 1n 0 • 2 0
ug/L PCB-1248 39500 L _L .LY. ,n 0 . 2 0
Ug/L PCB-1254 39504 I 1 ,.,., 1n 0 . 2 0
Uq/L PCB-1260 39508 I I IN ~n 0 . 2 0
Ug/L Phenanthrene 34461 I I I IN 10 5 • 0 0
Uq/L PYrena 34469' I I t'N fl 5 • 0 0
uqJL Toxaphene 39400 I I I , N il 0 . 5 0
Ug/L 1 2,4-Trichlorobenzene 34551 I I 1N n 5 . 0 0
ACID EX'l'RACTABLES
Uq/L 4-Chloro-3-methvlphenol 34452 t l I N ,n_ 5 • 0 0
uq/L 2-Chlorophenol- 34586 I ; N ,n 5 . 0 0
UCJ/L 2,4-Dichlorophenol 34601 1 N'1 n 5 . 0 0
uqjL 2 4-D1methylpheno1 34606 I I , t N't n 5 0 r .
uqJL 2,4-Dinitrophenol 34616 I • N'1n 5 • 0
uq/L 2-Methyl-4,6-dinitrophenol 34657 I I N'tn 5 • 0 0
uqJL 2-Nitrophenol 34591 I I N1D 5 • 0 0
ug/L 4-Nitrophenol 34646 I NtD 5 • 0 0
uq/L Pentachlnro?henol 39032 ' I I Nt D 0 • 5 0
CI-IS Sl51 B (3/17)
Base/Neutrals and Acids (Continued) PAGE 3 OF 3
SYSTEM NAME & NUMBER I. T. Coro. SI.JA.Ts Pjif.-240827-04 Market Place MP-3 C Lab No. 890508- 30
ADDITIONAL EXTRACTABLE PARAMETERS
REPORTING CONSTITUENT T STORET AN.hLYSES OETEC'!ION
UNITS - L_ T CODE RESULTS LIMIT
ua/L Phenol 3469~ I N ,D I I 51. I 0 l 0
uq/L 2,4 6-Trichlorophenol 34621 N D \ I 51. I 0 I 0
uq/L Ber.zid~ne 39120 I N D I I 51. I 0 I o
ugJL a - BHC 39337 N D I I o I. I 011
ug/L y - BHC 39340 t l N tD I I 0 I. I 0 11
uq/L Endosulfan I 34361 I L LN p I I 0 I . I 0 11
ugjL Endosulfan II 34356 I N ,D I I 0 I. I OJl
uqjL Endr~n 39390 I ,N D I I 0 I. I 011
ug/L Hexachloroc~clo~entadiene 34386 N_~_D 12101.1010
ugLL N-lH trosodimethylam~ne 34.-38 N D I ISI.IO_LO
ug/L ll-Nitrosod~_phenylam~ne 34433 l _L L _l N _~_D I I 51. I o; o Note any unidentified peaks below.
OHS 8351 B (3/17)
-- ~-
AGRICU~TUaAL.. CONSUL..TANT.
c ... ~•uara
A~~ROYIO ~ATIR ~80RATORY
PHONE 584-11181
ARU. coo& 11" EDWARD S. BABCOCK"& SONS. INC.
L.ABORATORIES
32.1 !1 CHICACiO A.VE.
L_
"· o. •ox ~32
RIVEUICE. CAL.II'ORNIA t:il502
. .
BASE/~'l'RALS AND ACIDS
ORGANIC ANALYSES
Data of Report: June 30, 1989 Lab ·sample ID No. 890508-31 Laboratory SiqnAtura Lab!'AJ 11--~ __ ............. /:'~~~--1,··--- Name: E s Babcock & Sons. Iqc. Director: ~~ ~!_l4.<R 0? Nama ot sampler . 1
Sampler; K.B.A. I D.L.f;. Employed By: I. T. Corp.
Date/Time Sample D&te/'l'lia. ~qpla . -=w:-e-r-e-:H:":"o~l=-a':""I,_n_q ____ _ C:ollecteci: 5-3-89 Received I La.b: 5-8-89 11:30 !'imes Observed? Yes Were all the constituents listeci Test Methocis: 625/6'iJ8 below quo.ntifiecl? . yes ---·---------~--------------------·-------·---------.a·------------------Q system .
Namec SHATs 'Proiect No. 240827-04 system
Numbe~=--------------Description of
Sampling Point:~_Mar ___ ke_t __ P_1a_c_e_·------~~~-------County Name: ____________ __ Name/No. Ot Sample St&t1on
.source: ?-11?-4 ·NWD.ber: I I I J I I I I I I I I I I Date·& Time ot 1 I I I I I I t I I I
Sample: Y Y M M D D T '1' 'l' '1' Water U . User I I I I Submitted to SWQI 'rypa: ' G/S ID: By: _____ _ / Placaa an "X" in box to cie~ete all elate. tor .thia station/elate/time. 0 REPORTING CONSTI'l'UEN'l' .. T STORE'l' ANALYSES DE'rECTIC!: UNITS T CODE RESULTS LIMIT Date Analyses Com~leteci 73672 8t9t0 t6t1 t4 I I I I I
YYMHDD
Analyzing AgencY_ Code (La.b) 28 L J f -1 I I
Intensive survev Number 116 ..1. _1_ I I I !
UCJ/L AcenaJJhthene 34205 N D 51 • I 0 · C
ucr7L Acenaphthvlene 34200 I ; N n 51 . I 0 I 0 uq/L Anthracene 34220 ~ 1 1 N1n 51 • I 0 I 0 uq/L Alcirl.n 39330 l N n 0 I • I 0 11
uq/L Benzo(a)anthracene '34526 N n 1 01 . I 0 I 0
uq/L Benzo(b)tluoranthene 34230 1 N.n 1 0 I. I 0' 0
uq/L Benzo klfluoranthene 3,242 N D 1 0 I • I 0 I 0 uq/L Benzo a)pyrene 34247 • 1 N n l 01.10To uq/L Ben-zo ~ghi) perylene 34521 I IN D l 0 I • I 0 I 0 uq/L Benzyl butvl phthalate 34292 _t l_ I N I D 1 0 I • I 0 I 0 Ug/L' B - BHC 39338 l_ N D 0 I. I 015
uq/L o -·BHC 34259 I NtD O!. I 015
uq/L bis(2-chloroethyl}ether 34273 l 1 l I N.D 51 • I 0 I 0 uq/L. bis(2-chloroethoxv}meta&ne 34278 I N ,n 51 • -10 I 0 uq/L bl.s(2-ethvlhexvl)~hthal•te 39100 l_ 7 . 8 51 • I 0 I 0 uc:r/L bis(2-chloroisopr.opylJether 34283 N n Sf .·1010 ug/L 4-Bromophenvl phenyl ether 3,636 I 1 N1 n 51 • I 0 I 0 uq/L Chlordane . 39350 l_ ..1. , N.n 0 I • I 0 I 5
uc:i/L 2-Chlorona.phthalene 34581 MIT'\ 51 • I 0 I 0
Base/N~utrals and Acids (Continued) PAGE 2 OF 3
SYSTEM NAME & NUMBER I T Coro SWAT P .f/:240827 04 Marke Pl .. .. . •, s . .'J - t ace :W-4
REPORTING CONSTITUENT T STORET ANALYSES DETECTION
UNITS T CODE RESULTS LIMIT
uq/L 4-Chlorophenyl phenyl ether 34641 I I IN Ln_ 5 . 0 0 ugjL Crysene 34320 .. J L t , N ,n 5 . 0 0
ug/L 4,4 1 -DDD 39310 .1 I l N ,n 0 . 0 2
ug/L 4 4 1 -no~- 39320 I I NtD 0 . 0 1
ug/L 4,4 1 -DDT 39300 I I I 1 N rD 0 • 0 2
ugLL Dibenzo(a h)anthracene 34556 l I l IN ID 5 • 0 0
ugjL Di-n-butylphthalate 39110 I I 1N ,n 5 • 0 0
Ug/L 1,3-Dichlorobenzene 34566 I l J IN ID 0 .. 5 0
u_gjL 1t2-Dichlorobenzene 34536 I N D 0 • 5 0
ug/L 1 4-Dichlorobenzene 34571 I I 1N rD 0 • 5 0
Ug/L 3,3 1 -Dichlorobenzidine 34631 L I I NtD 2 0 • 0 0 Ug/L D_ieldrin . 39380 I 1 1N rD 0 . 5
" Uq/L Diethyl· phthalate 34336 I I I IN J) 5 • 0 0
Ug/L Dimethyl phthalate 34341 I I IN J) 5 • 0 0
ugjL 2 4-Dinitrotoluene 34611 l N.D . - I 151. I 0 I
uq/L 2 6-Dinitrotoluene 34626 I I I IN J) . 15 • o:
ug/L Di-n-octylphthalate 34596 I I I 1N D 15 • 01
ug/L Endosul!an sul!ate 34351 I I I 1N D 0 • 0 ~
ugjL Endrin aldehyde 34366 I I I IN .D 0 0 0 5
ugjL Fluoranthene 34376 I I I 1N D 5 • 0 0
ug/L Fluorene 34381 l I I IN j) 5 0 0 0
ug/L Heptachlor 39410 I l L IN j) 0 • 0 2
uqJL He~~ach1or epoxide 39420 I I I IN p 0 0 l 0 ug/L Hexachlorobenzene 39700 L I 1 1N ,n 5 • 0 r uqJL Hexach1orobutad~ene 34391 I I 1 11>1 rn 5 o I o 1.. ug/L Hexachloroethane 34396 1 I I , N .n 5 0 0 0
Ug/L Indeno(1,2 3-cd)PYrene 34403 I I I IN ll 1 0 0 0 0 ug/L Isophorone 34408 L I L 11'1 ll 1 0 • 0 0
Ug/L Naphthalene 34696 I tN_ n 5 . 0 0
Ug/L N_itrobenzene 34447 l 1 · 1N ll 5 •. 0 0
ug/L N-Nitrosod~-n-pro~vlamine 34428 I 1 I 1N il 5 •. 0 0 Ug/L PCB-1016 34671 L I 1 1N n 0 . 2 0
uq/L PCB-1221 39488· I l_ ·L tM 1n 0 • 2 0
uqJL PCB-1232 39492 L _1_ t M 1n 0 • 2 0
Ug/L PCB-1242 39496 I L I ,·N 1n 0 0 2 0
ug/L PCB-1248 39500 I 1N ,n 0 . 2 0
ug/L PCB-1254 39504 I 1 1 N 1n 0 . 2 0
ug/L PCB-1260 39508 L L tK .n 0 . 2 0
UqjL Phenanthrene 34461 I I I IN tJl 5 0 0 0
uqJL Pyrena 34469' I I . I tN il 5 • 0 0
UQ'/L Toxaphene 39400 I I L IN il 0 . 5 0
ug/L ~.2,4-Trichlorobenzena 34551 I I tN D 5 • 0 0
ACID BX'l'RACTABLES
UQ'/L 4-Chloro-3-methylphenol 34452 . I I M on 5 . 0 0
uq/L 2-Chlorophenol 34586 I ;N .n 5 0 0 0
ug/L 2,4-Dichlorophenol 34601 l L I N'l l) 51 • 0 0
UQ'/L 2L4-D1methylphenol 34606 I I , M1 n 1 I IS!· I o I_,. ug/L 2,4-D1nitro~heno1 34616 L l • , M•n 5 . .0 '-
ug/L 2-Methvl-4,6-dinitrophenol 34657 I L _1_ Mt n 5 • 0 0 ug/L 2-Nitrophenol 34591 L I I L N,D 5 • 0 0
ug/L 4-Nitro_phenol 34646 I IN. D 5 • 0 0
uqJL Pentachloro~henol 39032 . I Nl D 0 0 5 0
CHS 8351 8 (3"7)
Base/Neutrals and Acids (Continued) PAGE 3 OF 3
SYSTEM NAME & NUMBER I.T. Coro. Sl:.JA.Ts Piif240827-04Market Place MP-4
REPORTING
UNITS
ua_LL
uq/L
uq/L
ugJL
uq/L
uq/L
ug}L
ug/L
ugL_L
ug/L
uq/L
Lab No. 890508-31
ADDITIONAL EXTRACTABLE PARAMETERS
CONSTITUENT T STORET ANAL~S.ES _..c._
T CODE RESULTS
Phenol 346S.; _l_ _l_ 1 N 1D
2 4 6-Trichlorophenol 34621 I N D
Benzidl.ne 39120 I N D
a - BHC 39337 I. _1_N D
y - BHC 39340 N ID
Endosulfan I 34361 I 01. 01l
Endosulfan II 34356 N D
Endrl.n 39390 ND
Hexachlorocvclopentadiene 34386 N D
N-Hitrosodimethylaml.ne 34438 N D
H-N i trosodl._p_henvlamine 34433 l l j_ _1_N D
Note any unidentified peaks below.
D.ET.EC'!!ON
LIMIT
I 151. I 0 I 0
l 151. I o I 0
I I 5 I . I 0 I o
I l o I. I o 11
I JOj.JOil
I I OJ. I 011
I I 0 l. LO 11
I I Oj. I 011
1210J.IOLO
I 151. I o I o
I I SJ. t 0; 0
'··· .. -------------------------------------)
CHS 8351 B (l/17}
_.r_
AGRICULTU,.AL CONS\.ILTANTa
Ct1"015T&
A~~OV&O ~AT&~ ~·O~ATO~Y
F'HONE 084-11181
(--,, ARU.C00&71. EDWARDS. BABCOCK"& SONS. INC.
)
LABORATORIES
3Z1:! CHICAGO AilE.
f'. o. •ox -432
RllfEIUiiCE. CAI.IfrORNIA .ll.502
. .
BASE/.NJ:UTRALS AND ACIDS
ORGANIC ANALYSES
Data of Report: June 30, 1989 Lab sample IO Ho. 890508-32 Laboratory Siqnatura Lab rl!J~~----;..,.~~-.--_--
Name: E.S. Babcock & Sons. Ittc· Director: ~U-
Name ot Sampler --.--~~~~_.~~~~~---
Sampler: K.B.A. / D.L,I';, Employec:i By: I. T. Corp.
Data/Time sample D&tenlie. ~upla --:::w=-e-r-e-==a-o~lci":"'iT"'n_q ____ _ C:ollecteci: 5-3-89 rtec::aiv&£1 I :t.ab: 5-8-89 11:30 'l'imea Ob&erveci? Yes Were all the ccnstituene& listed Test Methods: '625/6"08 below quantitieci? yes Q-----------------------------------------·--·aa.··--····-----------------· system .
Name~ St~Ts 'Proiect No. 240827-04
system
Numbe~=--------------Description of
Sampling Pointz~_~ __ ke __ t __ P_la_c_e_. ______ ~~~-------County Nama: ______________ _ Name/No. Of Sample ~-S St&t!on source: _____________ .Number: .\ I I I J I I I I I I I I I I Data·&
Time ct l I I I I I I t I I I
Sample1 Y Y M M 0 D ~ T T !
Water U . Use~ I I I I Submittec1 to SWQI;
Type:' G/S ID: By: _____ _
. Plaoe an "X" in box to cle~ete all clata tor .thia station/date/time. O REPORTING CONS'l'I'l'UEN'l' • 0 '1' STORET ANALYSES DETECTIC!:
UNITS '1' CODE RESULTS LIMIT
Date Analyses Comoleted 73672 8J 9 10 1 6Jl 1 4 I I I I I YYMHDO
Analvzina Agency Cocie {Lab} 28 _l_ _1_ _1_ I I T I
Intensive Survey Number ll6 I !
UCJ/L Acenaphthene 34205 l N n 5 . o·o
ua/L Acenaphthvlene 34200 · N n 5 . oTo
ucilL Anthracene 34220 I ~ n 5 . 010
uq/L Aldrln 39330 1_ N n 0 . 011
uci/L Benzo a\anthracena 34526 N.n 1 0 . 010
ug/L Benzo b)fluoranthena 34230 N.n 1 0 . 0'0
Uq/L Benzo k)fluoranthene 3~242 _1 ~ n 1 0 . 010
uq/L Benzo(a)pvrene 34247 _t_t_ 1ND 1 0 . 010
uq/L Benzo'qhi)pervlene 34521 _1_ _1_ N D 1 0 . 010
uq/L Benzyl butvl phthalate 34292 I I N D l 0 . 010 uq/L. 8 - BHC 39338 _1 _1_ _1 N D 0 . 015 uqJL 6 -·BHC 34259 __1_ ~ I Nl D 10 • I 015
ua/L bis(2-chloroethyl)ether 34273 N1D 5 . 010
uq/L. b~s_{2-chloroethcxY}meth&ne 34278 I N D 5 . 010
uq/L bis(2-ethvlhexvl)phthal•te 39100 N.n 5 . 010
ua7L bisl2-chloroisopr.opvl)•ther 34283 N,D 5 . · 0 I 0 ua/L 4-Bromophenvl phenyl_ ether 34636 I 1 N n 5 • ! 0 I o ua/L Chlordane . 39350 _j _1_ 1 N1 n 0 • I 015
uq/L 2-Chloronaphthalene 34581 __1_ u n 5 • I 0( 0
Base/N~utrals and Acids {Continued) PAGE 2 OF 3
S~STEM NAME & NUMBE R I T Coro SWAT p·#240827 04 Marke Pl •, •, . •, s .']' - t ace MP-5
REPORTING CONSTITUENT T STORET ANALYSES DETECTION
UNITS T CODE RESULTS LIMIT
uqjL 4-Chlorophenyl phen~l ether 34641 I I I N.n 5 . 0 0 ucr/L Cr.y_sene 34320 I I Ntn 5 . 0 0
uq/L 4,4 1 -DDD 39310 I N 1D 0 . 0 2
uq/L 4 1 4 1 -fiDE' 39320 I I NtD 0 . 0 1
ug/L 4,4 1 -DDT 39300 I I I N .n 0 • 0 2
ug/L Dibenzo(aLhlanthracene 34556 I I N 1D 5 • 0 0
ug/L Di-n-butylphthalata 39110 I 1 N 1D 5 • 0 0
uq{L 1L3-Dhchlorobenzene 34566 ·1 I I N 1D 0 .. 5 0
Uq/L 1,2-Dichlorobenzena 34536 I N D 0 . 5 0
ug/L 1~4-Dichlorobenzena 34571 I I _J{_ ill_ 0 • 5 0
ug/L 3 1 3 1 -Dichlorobenzidine 34631 I I I N ,n 2 0 . 0 0 ug/L D_i_eldrin 39380 1 t I IN .0 0 . 5
" uq/L Diethyl phthalate 34336 I IN J) 5 • 0 0
ug/L Dj.methyl phthalate 34341 I l l IN J) 15 . 0 0
uq/L 2,4-Dinitrotoluene 34611 I I N J)_ 5 . Of
uq/L 2,6-Dinitrotoluene 34626 I I I IN J) 5 • o:
ug/L Di-n-octyl~hthalate 34596 I I I IN .n 5 • 0
uq/L Endosul!an sulfate 34351 I I L ,N J) 0 • 0 :l
ug/L Endrin aldehyde 34366 I I I tN 1J 0 • 0 5
ug/L Fluoranthene 34376 I I I tN IJ 5 • 0 0
ug/L Fluorene 34381 I I IN p 5 • 0 0
ugjL He~tachlor 39410 I I -1 N 1J 0 • 0 2
ug/L Heptachlor epoxida 39420 I 1 t 1N P 0 • 1 0
ug/L Hexachlorobenzene 39700 I I 1N tO 5 • 0 r
uq/L Hexachlorobutadiene 34391 I I t IN ll 5 • 0 L
ug/L Hexachloroethane 34396 I _I_ di .n 5 • 0 0
ug/L Indeno(l,2,3-cd)PYrene 34403 I I I IN' il 1 0 • 0 0 uq/L Isophorone 34408 I I ,N ll 1 0 • 0 0
ug/L Naphthalene 34696 I I I IN ll 5 •. 0 0
uq/L N_ltrobenzene 34447 I. IN il 5 . ,0 0
Uq/L N-Nitrosodi-n-propylamine 34428 ' I IN' il 5 • 0 0 Uq/L PCB-1016 34671 I I 1 1N n 0 • 2 0
Uq/L PCB-1221 39488· I_ I I IN' 1n 0 . 2 0
ug/L PCB-1232 39492 I I I IN' 10 0 • 2 0
uq/L PCB-1242 39496 I_ I 1 1.N' 1n 0 • 2 0
ugJL PCB-1248 39500 L l 1 t K .n 0 • ·2 0
ug/L PCB-1254 39504 I , 1 N 1n 0 . .2 0
Ug/L PCB-1260 39508 I
'
1N' 1n 0 • i2 0
uq/L Phenanthrene 34461 I I I I N' tl) 5 • .0 0
uq/L PYrena 34469" t I I IN' l\ 5 • 0 0
uq/L Toxaphene 39400 I I I N'll 0 •. 5 0
ugLL 1,2,4-Trichlorobenzene 34551 I I -~ D 5 • .0 0
ACID EX'I'RACTABLES
uq/L 4-Chloro-3-methylphenol 34452 I 1 t N' .n 5 • .o L o uqJL 2 -Chlorop_henol 34586 I t IN oO 5 • . 010
uq/L 2,4-Dich1oropheno1 34601 I I N1n 5 • '0 I o
UQ'/L 2,4-D1methy1pheno1 34606 l l_ I . N'1_n 5 • otr
ug/L 2,4-Dinitrophenol 34616 ' • · 1 N1 n 5 • :o l1.
ugjL 2-Methyl-4,6-dinitropheno1 34657 L I I N1_n 5 • ,:o I o ugjL 2-Nitrophenol 34591 I I I I NID 5 • iO I 0
uq/L 4-Nitrophenol 34646 I I I N. D 5 • 1:0 L o
uqJL Pentachlorophenol 39032 . , NtD 0 ~- 51 0
--
CHS U51 B (3/17)
Base/Neutrals ana Acias (Continuea) PAGE 3 OF 3
SYSTEM NAME & NUMBER LT. Coro. SI:.JATs Pi4ft240827-04 Market Place MP-5
REPORTING
UNITS
ua/L
uq/L
uq/L
uq/L
uq/L
uq/L
uq/L
uq/L
uq/L
ug/L
uq/L
Lab No. 8905G8-32
ADDITIONAL EXTRACTABLE PARAMETERS
CONSTITUENT T S'I'ORE'I' ANALYSES
_..r:_ T CODE RESULTS
Phenol 3469~ I N ,D
2 4 6-Trichlorophenol 34621 1 N D
Banzid~ne 39120 I N1 D
a - BHC 39337 N D
'Y - BHC 39340 N tD
Endosulfan I 34361 1 l ,N D
Endosulfan II 34356 _t N ,D
Endrin 39390 _l _t _~_N D
Hexachlorocvclopentadiene 34386 __l N ,D
U-HitrosodimethvlamJ.ne 3~ .. 38 N D
H-NitrosodJ.phenvlam~ne 34433 I I N ,D
Note any unidentified peaks below.
DETEC':!ON
LIMIT
I I 51. I 0 I 0
I I 51. I 0 I 0
I I 51 .1 0 I 0
I I 0 I. 1011
I 10!.-\011
I I 0 I. I o 11
I I 0 I. I 011
1 10 I. I Oil
12101. lOIO
I I 51 • I 0 I 0
I I 51. I 0; 0
) ---------------------------------------------------------- OH$ 8351 B (3/17)
-.c...
~_,,,-,\.
.GRICU\.TU·A~ CON&UI..TAHT.
CH~MI&Ta
Af!f'IIOV~O WAUII LJ.80IIATOO
PHONE 6114-la&l
ARU Coo~ 714 EOWARO S. BABCOCK ·a: SONS. INC.
LABORATORIES
321:1 CHICAGO AVE.
"'· o. aox <43a
RIVIEUIDE. CAL.IFORNIA .lU102
. .
BASE/~'rRALS AND ACIDS
ORGANIC ANALYSES
Date of Report: June 30, 1989 LAb Sample IO No. 890508-33 Laboratory SiqnAtura Labrif;!J ;. ;·~~·, ?
Name: E S. Babcock & Sons. I'Q'c. Director: '.A!f~ -~-~ Name ot Sampler
Sampler: K.B .A. I D.L.r;. Employed. By:_=I~. _T_. -:Co:-:--:rp::-.~----- Date/Time Sam;le D&tejTiia.~~ple Were Holdinq eollected: .J-4-89 Rec:aivea I Lab: 5-8-89 11:30 'l'imea Observed? Yes Were all the constituents listed Test Method.s: 625/608 below quanti tied? ·yes c••--•••••••••••----•••--•••••••••••------••••---•••••••••••-----••••~ system . ·
Namec St~Ts Project No. 240827-04
system
Numba~=------------Description of
Sampling Point: Market Place· county Nama: ______ _ Name/No. ot Sam-p~l-e~~----------~S~t-&~·t~!~o-n ____ __ source: 1vfP-B1an..k: (Arrowhead DI)Nu:m.bar: l I I I t I I I I I t I I I 1 Data·& '
Time ot 1 I I I I I I ~ I I I
Sample: Y Y M M 0 D i T T f Water U . TJser I I I I Submitted. to swc Type: ' G/S ID: &y: .
. Placaa an "X" in box to cie~ete all data tor .thia station/ciate/tiaa·. O REPORTING CONSTI'1'UEN'l' .. T STORET ANALYSES OETECTIC! UNITS T CODE RESULTS LIMIT Date Analyses Comoleted. 73672 81 9JO l 6 11 1 4 I I I I YYMMDO
Analvzinq Aqencv- code fLa.b} 28 I I I I
Intensive Survav Number 116 I I I
UQ'/L Acenaphthene 34205 1 N n 5 I • I 0
uq/L AcenaQhthvlene 34200 • ; » n sT. I o uq/L Anthracene 34220 I »,n 51 • I 0 uq/L Aldr1n 39330 »on 0 I • I 0
uq/L Benzo aj_anthracene 34526 N n 1 oT. I o u-q/L Benzo b):!luoranthene 34230 » n 1 0 I • I 0 ug]L Benzo k)fluoranthene 3-<.242 » n 1 0 I • I 0 uq/L Benzo a\pvrene 34247 I I IN' D 1 0 I • I 0
uq/L Benzo 'qhi) per{ lena 34521 I I ' N D 1 0 I • I 0
ug/L Benzyl butyl ohthalate 34292 i I I· N I D 1 oT. 1 o uq/L' B - BHC 39338 I N D 0 I • I 0
ug/L 6 -·BHC 34259 .N".n 0 I • I 0
uq/L bisl2-chloroeth'Vl\ather 34273 l N n 51 • I o
ug/L. bis(2-chloroethoxv\meth&ne 34278 N D 51 • I 0
uq/L bls(2-ethy1hexvl\nhthal•te 39100 .N .n 5 I • I 0
uq7L bis(2-ch1oroisopr.onvl\ather 34283 t-~,n 51 •. , 0 uq/L 4-Bromophenyl -oherivl ether 34636 ' , N ~n 51 . I 0 uq/L Chlordane . 39350 t 1 w~n 0 I • I 0
uq/L 2-Chloron~phthalena 34581 tJ 1'1 I sT. I o
1"'\.WC a~C.\ A 1~1&1\
Base/N~utrals and Acids {Continued) PAGE 2 OF J
I T Coro SWAT p·#240827 04 Marke Pl SYSTEM NAME & NUMBER ~ .. . s .. ]~ - t ace ~-Blank (Arrowhead D ..
REPORTING CONSTITUENT 'I' STORET ANALYSES DETECTION
UNITS T CODE RESULTS LIMIT
ug/L 4-Chlorophenyl phenyl ether 34641 I I Nln 5 . 0 0
ug/L err sene 34320 I dltn 5 . 0 0
ugjL 4,4 1 -DDD I 39310 I , N ,n 0 0 2 •
uq/L 4, 4 1 -DOE'· 39320 T\T _n 0 . 0 1
uq/L 4,4 1 -DDT . 39300 I IN ID 0 • 0 2
u_gL_L Dibenzo(a,h)anthracene 34556 I I. J N tD 5 • 0 0 ugjL Di-n-butylphthalate 39110 I . I l .N n 5 • 0 0
ug/L 1,3-Dichlorobenzene 34566 I N ,D 0 .. 5 0
uq/L 1L2-Dichlorobenzene 34536 I I N D 0 • 5 0
ug/L 1,4-Dichlorobenzene 34571 I 1 1N 1D 0 . 5 0
ug/L 3 1 3 1 -Dichlorobenz~d!ne 34631 I N.D 2 0 • 0 0
u_g.LL D_ieldri_n 39380 I I NtD 0 . 5 (\
ug/L Diethyl phthalate 34336 I I IN J) 15 • 0 0
uq/L Dimethyl phthalate 34341 I I I IN J) 5 . 0 0
Ug/L 2,4-Dinitrotoluene 34611 I I NoD 5 • 01 ·-
Ug/L 2 1 6-Dinitrotoluene 34626 I I I IN J) 5 • Q!
ugjL D~-n-octylphthalate 34596 I I .IN J) 5 . 0
ug/L Endosul!an sulfate 34351 I I I IN .D 0 . 0
~
....
ug/L Endrin aldehyde 34366 I I I IN J) 0 • 0 5
ug/L Fluoranthene 34376 I I I IN j) 5 • 0 c
ug/L Fluorene 34381 I I I IN J) 5 .. 0
ugLL He_Qtachlor 39410 L t t ,N J) 0 • 0
ug/L Heptachlor epoxide 39420 I I I N p 0 • 11 o.
ug/L Hexachlorobenzene 39700 I I I IN tO 5 . 0 (
ug/L Hexachlorobutadiene 34391 I I 1 1Non 5 • 0 (..
Ug/L Hexachloroethane 34396 I I I IN .n 5 • 0 0
uqJL Indeno(l 2,3-cd)pyrena 34403 I I I IN il 1 0 • 0 0 ug/L Isophorone 34408 I I I 11\1 il l 0 • 0 0
\,lq/L Naphthalene 34696 I I 11\1 fl_ 5 • 0 0
ug/L Nitrobenzene 34447 I I· 1N il 5 . 0 0
ug/L N-Nitrosodi-n-propylamine 34428 f I IN il I 5 . 0 0 Ug/L PCB-1016 34671 I I 1 •N n 0 . 2 0
ug/L PCB-1221 39488· L _!_ L t N. 1n 0 • 2 0
ug/L PCB-1232 39492 L t L IN. tn 0 • 2 0
ug/L PCB-1242 39496 I 1 ~y_~n 0 • 2 0
ug/L PCB-1248 39500 I 1N .n 0 . 2 0
ug/L PCB-1254 39504 I I 11111n 0 . 2 0
u_gjL PCB-1260 39508 I_ L 1111 1n 0 • 2 0
ug/L Phenanthrene 34461 I I I I Ill If) 5 • 0 0
ug/L PYrena 34469' I I I 11\1 oJ) 5 . 0 0
uqJL Toxaphene 39400 I I L IN .n 0 . 5 0
uqJL 1,2,4-Trichlorobenzene 34551 I ,N D 5 . 0 0
ACID EX'I'RACTABLES
ug/L 4-Chloro-3-methvlphenol 34452 I I J M on 5 • 0 0
ugLL 2-Chlorophenol 34586 1 1 'N .n 5 • 0 0
UCJ/L 2,4-Dichlorophenol 34601 I , 1 1111n 5 • 0 0
uqJL 2L4-D~methy1phenol 34606 I I M1n 5 . 0 (
ucr/L 2,4-Dinitrophenol 34616 I I ' I Mt n_ 5 ,. 0
uqJL 2-Methyl-4 6-dinitrophenol 34657 I I _I_ 1\11 " I 5 • 0 0 ug/L 2-Nitrophenol 34591 L I I N,D 5 '. 0 0
UCJ/L 4-Nitrophenol 34646 I I I Nt D 5 • 0 0
ug/L Pentachloro~henol 39032 . _.. t NtD 0 • 5 0
CHS 8351 B (3/17)
Base/Neutrals and Acids (Continued) PAGE 3 OF 3
SYSTEM NAME & NUMBER I. T. Coro. SI.JA.Ts Pi1f240827-()4 Market Place NIP-Blank (Arrowhead 1 Lab No. 890508-33
ADDITIONAL EXTRACTABLE PARAMETERS
REPORTING CONSTITUENT T STORET A.Nh!.YSES DETEC':'!ON
UNITS
-L
T CODE RESULTS LIMIT
UO'/L Phenol 34 69~ I N ,D I 15 • I 0 I 0
ugjL 2 4,6-Trichlorophenol 34621 N D I 15 • I OJ 0
uqjL Benzidine 39120 I N D \ \ 5 I. I o I o
ug/L a - BHC 39337 I IN D I IO • I o 11
ug/L y - BHC 39340 I N ,D I !0 ·1 0 11
ugjL Endosulfan I 34361 I I N,D I 10 • I 011
ug/L Endosulfan II 34356 N 1D I J 0 . I o 11
ug/L Endrin 39390 I ND l \ 0 • I 0 11
ugjL Hexachlor,ocyclopentadiene 34386 N 1D 1210 • I o I C uq/L N-Hitrosodimethvlarn~ne 34438 N D I 15 -l 0 I C·
uq/L H-Nitrosodiphenvlarnine 34433 I I I IN ,D I 15 .1 OiC Note any unidentified peaks below.
OHS 8351 B (3/a?)
)
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF DHS CERTIFIED
PHONE (714) 684·1881
LABORATORIES
3215 CHICAGO AVE
To: Kevin t'l P. £. D~ 1-+ L
I. T. Corp.
ESTABLISHED 1906
EDWARD S. ~ABCOCK & SONS, INC.
P 0. BOX 432
RIVERSIDE. CALIFORNIA 92502
December 15, 1989
Re: Bixby Travel
Blank 5/8/89
At the time the laboratory travel blank was prepared for LT. Corp. and the Bixby Village SWAT project, an error was made by the field staff at Edward S.
Babcock & Sons, Inc.
Due to poor communications, the person who prepared the travel blank filled all the containers with organically pure water. Unfortunately, the organically pure. water is not demineralized. This error was only discovered after the sample was analyzed, by which time it was too late to correct the problem.
Therefore, for this particular sample collection, there is no meaningful Travel Blank analysis available.
We regret the error, and hope the field blank analyses are sufficient for the reporting requirements.
Sincerely,
#~frlV
Allison Hackenzie
-t/ -· / ~ I - I - ,'./ j '-----/
Edward S. Babcock & Sons, Inc. ~
3215 Chicago Avenue Q r·-._W, (1(1'1 ')' ,
Riverside, CA 92507 · \j' '\'-'\: t _,.\ -
(714) 684-1881
CHAIN OF CUSTODY RECORD
c 1 i ent' s Name: ~r·r Cor<..t''o;:?.ATIDA/
Lab fs: ~10S'08"-l0(· =b? 33 Invoice No . .$1?03~
Project No. Project Name/Location Determination Requested ~i-/0~?-7-0t-/ AA ., _ mN C Condition of
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J>~v' D L • 6~ pt w .:.:..! I I I I I I I I r ~
Samplers:
(Signature) . I :
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Samp 1 e s-oo~o
Description
-~~ MP-1 Wet-L WAIER.. Is--3-~'l
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Date I Tt•e
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FOURTH QUARTER SAMPLING
)
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1908
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
P.O. BOX 432 3215 CHICAGO AVE. RIVERSIDE, CALIFORNIA 92502 - L..
'l'o: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA. 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-06 Market Place
SWATS Water Sample MP-1
~ter Name Results
Calcium {Ca) 206 mg/L
Sodium {Na) 6200 mg/L
)tassium ( K) 254 mg/L
]tal Cations 323 me/L
Total Alkalinity as CaCO:J 700 mg/L
Hydroxide {OH) none mg/L
Carbonate (CO:J) none mg/L
Bicarbonate (H<X>J ) 854 mg/L
Sulfate {804) 3450 mg/L
Chloride (Cl) 9200 mg/L
Nitrate (~) <0.1 mg/L
Fluoride {F) 2.0 mg/L
Total Anions 345 me/L
Biochemical Oxygen DemandS 5 mg/L
Chemical Oxygen Demand 40 mg/L
Oil and Grease 16 mgJL
Ortho Phosphate Phosphorus 0.88 mg/L
pH 7.4 units
Specific Conductance 27800 J,.llllho/cm
. Total Filterable Residue 18260 mg/L
10/05/89
Lab No. 890908-478
Invoice No. 53526
Submitted Sampled
DLG
09/07/89
22:42
DLG(KBA
9/6
Chain of CUstody on file: Y
Parameter Name Results
Antimony (Sb) <0.01 mg/L
Arsenic (As) 0.01 mg/L
Barium (Ba) <0.1 mg/L
Beryllium (Be) <0.01 mg/L
Bromide (Br) 35 mg/L
Cadmium (Cd) <0.01 mg/L
Total Chromium (Cr) <0.01 mg/L
Cobalt (Co) <0.01 mg/L
Copper (Cu) 0.02 mg/L
Iron (Fe) 0.02 mg/L
Lead (Pb) 0.008 mg/L
Manganese {Mn) 0.55 mg/L
Mercury (Hg) <0.001 mg/L
Molybdemmt (Mo) <0.1 mg/L
Nickel (Ni) <0.01 mgjL
Selenium (Se) <0.05 mg/L
Silver (Ag) <0.01 mgjL
Thallium (Tl) 0.2 mg/L
Zinc (Zn) <0.01 mg/L
Notes: Metals run on samples filtered & preserved in field. cc: BdNard s. Babxdr & SalS, Inc.
~c&,U
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1906
)
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
P.O. BOX 432 3215 CHICAGO AVE.
RIVERSIDE. CALIFORNIA 92502
- .L_
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-06 Market Place
SWAT Water Sample MP-2
Parameter Name Results
Calcitm (Ca) 830 mg/L
Soditm1 (Na) 30000 mgjL
Potassium (K) 995 mg/L
'>tal Cations 1676 me/L
~tal Alkalinity as caeca 463 mg/L
Hydroxide (OH) none mg/L
Carbonate ( ffi.J ) none mg/L
Bicarbonate ( Hffi.J ) 564 mg/L
Sulfate (SOd 6550 mg/L
Chloride (Cl) 52500 mgjL
Nitrate (Neh) 10 mg/L
Fluoride (F) 1.0 mg/L
Total Anions 1625 me/L
Biochemical Oxygen DemandS 2 mg/L
Chemical Oxygen Demand 25 mg/L
Oil and Grease 8 mg/L
Ortho Phosphate Phosphorus 0.43 mgjL
pH 7.3 units
Specific Conductance 107000 umbo/em
Total Filterable Residue 94,550 mgjL
10/05/89
Lab No. 890908-479
Invoice No. 53526
Submitted Sampled
DLG
09/07/89
22:42
DLG/KBA
9/6
Chain of Custody on file: Y
Pa.rallleter Na.e Results
Antinxmy (Sb) 0.01 mg/L
Arsenic (As) <0.01 mg/L
Bariun (Ba.) <0.1 mg/L
Berylliun (Be) <0.05 mg/L
Bromide (Br) <5 mg/L
Cadmium (Cd) <0.01 mgjL
Total Chromium (Cr) <0.01 mg/L
Cobalt (Co) 0.12 mgjL
Copper (Cu) 0.10 mg/L
Iron (Fe) <0.01 mgjL
Lead (Pb) 0.1 mg/L
Manganese (Mn) 3.3 mg/L
Mercury (Hg) <0.001 mgjL
Molybdenum (Mo) <0.1 mg/L
Nickel (Ni) 0.06 mg/L
Selenium (Se) <0.05 mg/L
Silver (Ag) <0.01 mg/L
Thallium (Tl) 1.0 mg/L
Zinc (Zn) 0.05 mg/L
Notes: Metals n.m on samples filtered & preserved in field. cc:
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTA8LISHED 1908
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
-..c...
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Simple ~ed:
Pj#240827-06 Market Place
SWAT Water Sample MP-3
P.O. BOX 432
RIVERSIDE. CALIFORNIA 92502
10/05/89
Lab No. 890908-480
Invoice No. 53526
Submitted Sampled
D.LG DLG/KBA
09/07/89 9/7
22:42
Chain of Custody on file: Y
Parameter ~ Results .Pa.ra.eter Name Results
Calciun (Ca) 410 mg/L Antimony (Sb) <0.01 mg/L
Sodil.lll (Na) 15400 mg/L Arsenic (As) 0.06 mg/L
Potassium ( K) 465 mg/L Bariun (Ba) 2.7 mg/L
1tal Cations 869 me/L Berylliun (Be) <0.1 mgjL
~tal Alkali~i ty as CaCOa 2838 mg/L Brcmide (Br) 62 mg/L .Hydroxide (OH) none mg/L Cadmium (Cd) <0.01 mg/L
Carbonate (COa) none mg/L Total Chromium (Cr) <0.01 mg/L Bicarbonate (H<Xh) 3462 mgjL Cobalt (Co) <0.1 mg/L
Sulfate (SO.) 1600 mg/L Copper (Cu) <0.1 mg/L
Chloride (Cl) 27800 mg/L Iron (Fe) 0.26 mg/L
Nitrate (~) 10 mgjL Lead (Pb) 0.04 mg/L
Fluoride (F) 2.4 mg/L Manganese (Mn) 2 mgjL
Total Anions 873 me/L Mercury (Hg) <0.001 mg/L
Biochemical Oxygen DemandS 25 mg/L Molybdenun (Mo) 0.9 mgjL Chemical Oxygen Demand 40 mg/L Nickel (Ni) <0.1 mgjL
Oil and Grease 9 mgjL Seleniun (Se) <0.05 mgjL
Ortho Phos~te PhosTX1orus 2.6 mgjL Silver (Ag) <0.01 mg/L pH 7.5 units Thalliun (Tl) 0.5 mg/L
Specific Conductance 62000 J,.Unho/cm Zinc (Zn) <0.1 mg/L Total Filterable Residue 46800 mgjL
Notes: Metals run on samples filtered & preserved in field. cc:
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1908
PHONE (714) 684-1881
EDWARD S. BABCOCK & SONS, INC.
/
) LABORATORIES
P.O. BOX 432 3215 CHICAGO AVE. RIVERSIDE. CALIFORNIA 92502 To: Inte:rna.ti onar-TeCh . Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-06 Market Place
SWAT Water Sample MP-4
~ter Name Results
Calcium (Ca) 114 mg/L
Sodium (Na) 4650 mg/L
Potassium (K) 185 mg/L
!tal Catio~ 255 me/L
Jtal Alkalinity as Ca~ 1168 mg/L
H.ydroxide (OH) none mg/L
Carbonate {~) none mg/L
Bicarbonate (~) 1424 mg/L
Sulfate {SO.) 1600 mg/L
Chloride (Cl) 7250 rng/L
Nitrate (NO:J ) 10 mg/L
Fluoride (F) 2.3 mg/L
Total Anions 261 me/L
Biochemical Oxygen DemandS 3 mg/L
Chemical Oxygen Demand 5 mg/L
Oil and Grease 10 mg/L
Ortho Phosphate Phosphorus 0.19 mg/L
pH 7.3 units
Speci fie Conductance 22500 umbo/em
Total Filterable Residue 15500 mg/L
10/05/89
Lab No. 890908-481
Invoice No. 53526
Subni tted Sampled
DLG
09/07/89
22:42
DLGIKBA
9/7
Chain of Custody on file: Y
~ter~ Results
Antimoey (Sb) <0.01 mgjL
Arsenic (As) <0.01 mgjL
Baril.El (Ba) <0.1 mg/L
.Bery lli \DD (Be) <0.01 mgjL
Bromide (Br) 19 mg/L
Cadmitm (Cd) <0.005 mg/L
Total Chromium (Cr) <0.01 mg/L
Cobalt {Co) <0.01 mg/L
Copper {Cu) 0.01 mg/L
Iron (Fe) 0.02 mg/L
Lead (Pb) 0.006 mg/L
.Manganese (Mn) 2.6 mg/L
Mercury (Hg) <0.001 mgjL
Molytdemt.lll (Mo) <0.1 mg/L
Nickel (Ni) <0.01 mg/L
Seleniun {Se) <0.025 mg/L
Silver (Ag) <0.01 mg/L
Thallium (Tl) 0.2 mgjL
Zinc (Zn) 0.01 mg/L
Notes: Metals run on samples filtered & preserved in field. cc: ~ s. Babxx* ... Sons, Inc.
l~/c4.1J
/
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1906
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
P.O. BOX 432 3215 CHICAGO AVE.
RIVERSIDE, CALIFORNIA 92502
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-06 Market Place
SWAT Water Sample MP-5
Parameter Name Results
Calcium (Cal 188 mg/L
Sodium (Na) 3000 mg/L
ptassium (K) 144 mgjL
otal Cations 167 me/L
Total Alkalinity as CaCOa 800 mgjL
Hydroxide (OH) none mg/L
Carbonate (C'Oa) none mg/L
Bicarbonate (HC'Oa) 976 mgjL
Sulfate (804 ) 2100 mg/L
Chloride (Cl) 5250 mgjL
Nitrate (~) 1 mg/L
Fluoride (F) 1. 7 mgjL
Total Anions 208 me/L
Biochemical Oxygen DemandS 6 mg/L
Chemical Oxygen Demand 15 mg/L
Oi 1 and Grease 6 mg/L
Ortho Phosphate Phosphorus 2.1 mg/L
pH 7.4 l.U'lits
Speci fie Cond~tance 16000 J,.UDho/cm
Total Filterable Residue 9985 mg/L
10/05/89
Lab No. 890908-482
Invoice No. 53526
Submitted Sampled
DI...G
09/07/89
22:42
Dl..G/KBA
9/6
Chain of Custody on file: y
Parameter .Na.e Results
Antimony (Sb) <0.01 mg/L
Arsenic (As) <0.01 mg/L
Barium (Ba) <0.1 mg/L
BeryllilBD (Be) <0.01 mg/L
Bromide (Br) 15 mg/L
Cadmium (Cd) <0.001 mg/L
Total Chromil.Dil (Cr) <0.01 mg/L
Cobalt (Co) <0.01 mg/L
Copper (Cu) 0.02 mg/L
Iron (Fe) 0.01 rogjL
Lead (Pb) 0.01 mg/L
Manganese (Mn) 1.4 mgJL
Mercury (Hg) <0.001 mgjL
Molyl:xienum (Mo) <0.1 mgjL
Nickel (Ni) <0.01 mg/L
Selenit.lll. (Se) <0.025 mgjL
Silver (Ag) <0.01 mg/L
Thallium (Tl) <0.1 mg/L
Zinc (Zn) 0.02 rog/L
Notes: Metals rl.D1 on samples filtered & preserved in field. cc: Fdward s. 'flalxxrl[ A:. Sons J Inc.
c4rd
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED
PHONE (714) 684-1881
LABORATORIES
3215 CHICAGO AVE.
- .L.
ESTABLISHED 1908
EDWARD S. BABCOCK & SONS, INC.
P.O. BOX 432
RIVERSIDE. CALIFORNIA 92502
10/05/89
To: International Tech. Corp. Lab No. 890908-483
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-06 Market Place
SWAT Water Sample
MP-Blank
Parallleter Na.e
Calcium (Ca)
Sodium (Na)
Po tass i urn ( K)
)tal Alkalinity as CatX>3
.1droxide (OH)
Carbonate ( tX>3 )
Bicarl:xJnate (~)
Sulfate (so. )
Chloride (Cl)
Nitrate (N03)
Fluoride (F)
Biochemical Oxygen DemandS
Chemical Oxygen Demand
Oil and Grease
Ortho Phosphate Phosphorus
pH
Specific Conductance
Total Filterable Residue
Results
1 mg/L
<1 mg/L
<1 mg/L
2.5 mg/L
none mg/L
none mg/L
3 mg/L
<1 mg/L
<1 mg/L
<1 mg/L
0.1 mg/L
<1 mg/L
<5 mg/L
<1 mg/L
<0.01 mg/L
7.6 tmits
2.7 umho/cm
<5 mg/L
Invoice No. 53526
Sul::mi tted I Sampled
DW
09/07/89
22:42 I
DW/KBA
9/7
Chain of Custody on file: Y
Antimony (Sb)
Arsenic (As)
Barium (Ba)
Berylli\..111 (Be)
Bromide ( Br)
Cadmi tml ( Cd)
Total Chromium (Cr)
Cobalt (Co)
Copper (Cu)
Iron (Fe)
Lead (Pb)
Manganese ( Mn)
Mercury ( Hg)
Molybdenum (Mo)
Nickel (Ni)
Seleniun (Se)
Silver (Ag)
Thallium (Tl)
Zinc (Zn)
Results
<0.01 mg/L
<0.01 mg/L
<0.1 mg/L
<0.01 mg/L
<5 mg/L
<0.001 mg/L
<0.01 mg/L
<0.01 mg/L
<0.01 mgjL
<0.01 mg/L
<0.005 mg/L
<0.01 mg/L
<0.001 mg/L
<0.1 mg/L
<0.01 mg/L
<0.005 mg/L
<0.01 mg/L
<0.1 mgjL
0.01 mg/L
Notes: Metals run on samples filtered & preserved in field. cc:
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1901!
PHONE (714) 684-1881
) LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
P.O. BOX 432 3215 CHICAGO AVE.
RIVERSIDE. CALIFORNIA 92502
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827/8/9 Bixby SWATS
Water Sample Travel Blank
Pa.ra.eter Name Results
Calcium (Ca) 1 mg/L
Sodium (Na) <1 mg/L
..,otassium 0{) <1 mg/L
hal Alkalinity as Ca~· 5 mg/L
Hydroxide (OH) none mg/L
Carbonate (ffi3) none rng/L
Bicarbonate (lKX>3 ) 6 rng/L
Sulfate (S04) <1 rng/L
Chloride (Cl) <1 mg/L
Nitrate (NOa) <0.1 mg/L
Fluoride (F) <0.1 mg/L
Biochemical Oxygen DemandS <1 mg/L
Chemical Oxygen Demand <5 mg/L
Oil and Grease <1 rng/L
Ortho Phosphate Phosphorus 0.02 rng/L
pH 5.0 tmits
Specific Conductance 3.6 iJIII}lo/cm
Total Filterable Residue 10 mg/L
10/05/89
Lab No. 890909-665
Invoice No. 53579
Submitted Sampled
Dill
09/08/89 9/1
22:14
Chain of Custody on file: Y
Parameter Na.e Results
Antimony (Sb) <0.01 mg/L
Arsenic (As) <0.01 mg/L
Barium (Ba) <0.1 mg/L
Bery 11 i 1..ID (Be) <0.01 mg/L
Bromide (Br) <5 mg/L
Cadmium (Cd) <0.001 mg/L
Total Chromil..ID (Cr) <0.01 mg/L
Cobalt (Co) <0.01 mg/L
Copper (Cu) <0.01 mg/L
Iron (Fe) 0.02 mg/L
Lead (Pb) <0.005 mg/L
Manganese (Mn) <0.01 mg/L
Mercury (Hg) <0.001 mg/L
Molytxiem.n (Mo) <0.1 mg/L
Nickel (Ni) <0.01 mg/L
Selenium (Se) <0.005 mg/L
Silver (Ag) <0.01 mg/L
Thallium (Tl) <0.1 mg/L
Zinc (Zn) 0.01 mg/L
Notes: Metals run on samples filtered & preserved in field. cc: &herd s. Babcock & Sons t Inc.
b~/C4pkl . I
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED \906
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
- . .L,_
To: Intenati<Dl.l Tech. Corp.
17 461 Derian Avenue Suite 190
Irvine, CA. 92714
Attn: David L. Guth
Sa.ple Marked:
Pjt240827-06
Marketplace SWATs
water sample MP-1
P.O. BOX 432
RIVERSIDE. CALIFORNIA 92502
10/12/89
EPA Method 9060
Total Organic Carbon 77 mg/L
Date analysis completed: 09/15/89
Notes: Practical Quanti tat ion Limit =
ND = None Detected at FQL
cc:
l.Omg/L
Lab No. 890908-484
Invoice No. 53527
Sul:nitted. Sampled
DLG
09/07/89
22:42
DW!KBA
09/06/89
Chain of Custody an file: Y
Results
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1906
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE. CALIFORNIA 92502
- -L
To: International Tedl. Corp.
17461 Derian Avenue SUite 190
Irvine, CA 92714
Attn: Dsvi.d L. Guth
&.ple Marked:
Pj#240827-06
Marketplace SWATs
water samples MP-2
EPA Method 9060
Total Organic Carbon
J8Ctical Quanti tat ion Linli t
Results
22 mg/L
1.0 mg/L
Date analysis completed: 09/15/89
10/12/89
Notes: Practical Quanti tat ion Limit = 1 • Omg/L
ND = None Detected at IQL
lab Ho. 890908-485
Invoice Ho. 53527
Subnitted Sampled
DLG
09/07/89
22:42
DLG/KBA
09/06/89
Chain of Custody on file: Y
Results
r
·---
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF DHS CERTIFIED ESTABLISHED 1906
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
) 3215 CHICAGO AVE.
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827-06
Marketplace SWATs
water sample MP-3
P.O. BOX 432
RIVERSIDE. CALIFORNIA 92502
10/20/89
Chain
Parameter Name Results Paralaeter Name
EPA Methcxi 9060
. Total Organic Carbon 95 mg/L
!')
Date analysis completed: 09/15/89
Notes: Practical Quantitation Limit = 1.0 mg/L
ND = None Detected at FQL
Lab No. 890908-486
Invoice No. 53527
Subnitted Sampled
DLG DLG/KBA
09/07/89 09/07/89
22:42
of Custody on file: Y
Results
cc: Edward s. Babcock A: Sons, Inc.
~frk&,/
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1906
PHONE (714) 684·1881
') LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
- . .L..
To: Intenvstic:nll Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sallple Marked:
Pj#240827-06 Marketplace
SWATs water sample MP-4
P.O. BOX 432
RIVERSIDE. CALIFORNIA 92502
10/12/89
Results
EPA Method 9060
_'fotal Organic Cartx>n 28 mg/L
\
)I
Date analysis completed: 09/15/89
Notes: Practical Quanti tat ion Limit = 1 . Omg/L
ND = None Detected at PQL
lab No. 890908-487
Invoice No. 53527
Subnitted Sampled
DLG
09/07/89
22:42
DLGIKBA
9/7/89
Chain of CUstody on file: Y
Results
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF DHS CERTIFIED ESTABLISHEO 1906
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
To: Internati<D.ll Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92114
Attn: David L. Guth
Sallple ftuoked:
Pj#240827-06 Marketplace
SWATs water sample MP-5
P 0. BOX 432
RIVERSIDE. CALIFORNIA 92502
10/12/89
Results
Lab No. 890908-488
Invoice No. 53527
Subai tted Sampled
DW
09/07/89
22:42
DLG!KBA
9/6/89
Chain of Custody oo file: Y
Results
EPA Method 9060
.. Total Organic Carbon 56 mg/L
)
Date analysis completed: 09/15/89
Notes: Practical Quanti tation Limit = 1 • Oma/L
ND = None Detected at PQL
cc: EciNard. s. Babcock 1: &ms, Inc.
~-: I!Jwir
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1906
PHONE i714) 684·1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
To: Internatiooal Tech. Corp.
17461 Derian AveBJe Suite 190
Irvine, CA 92714
Attn: De.vid L. Guth
Sallple Marked:
Pj#240827-06 Marketplace
SWATs water sample
MP-Blank
P 0. BOX 432
RIVERSIDE. CALIFORNIA 92502
10/12/89
Results
lBh No. 890908-489
Invoice No. 53527
Subnitted.
DLG
09/07/89
22:42
Sampled
DLG!KBA
9/7/89
Chain of Custody on file: Y
Results
EPA Method 9060
Total Organic Carbon ND mg/L
.I
Date analysis completed: 09/15/89
Notes: Practical Quanti tation Limit = 1. Omg/L
ND = None Detected at FQL
cc: F.dwa.rd s. Ba1xxJck & Sons, Inc.
~f!Yy-:
(
BACTERIOLOGY
WATER TESciNG
HAZARDOUS WASTE TESTING
CALIF. OHS CERTIFIED ESTABLISHED 1908
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
- L.
To: Inte:ma.tional Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827/8/9 Bixby SWAT
Travel Blank prepared by
ESB
P 0. BOX 432
RIVERSIDE. CALIFORNIA 92502
10/13/89
Lab No. 890909-666
Invoice No. 53580
Sutmitted
DLG
09/08/89
22:14
Sampled
ESB Inc
19/1/89
Chain of Custody on file: Y
Parameter Name Results Parameter Name Results
EPA Method 9060
Total Organic Carbon
Date analysis completed: 09/15/89
ND mg/L
Notes: Practical Quantitation Limit = 1.0 mgjL
ND = None Detected
cc: Edward s. Ba:t:xxx* 1:. SalS ' Inc.
C)flk;-~
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF DHS CERTIFIED ESTABLISHED 1906
PHONE (714) 684-1881
') LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
P 0. BOX 432 3215 CHICAGO AVE.
RIVERSIDE. CALIFORNIA 92502
To: Intematic.mal Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sallple Marked:
Pj#240827-06 Marketplace
SWATs water sample MP-1
Results
10/12/89
EPA Method 9020
Total Organic Halides 1.1 mg/L
)
Date analysis completed: 09/20/89
Notes: Practical Quantitation Limit = 0.5ma/L
ND = None Detected at IQL
r.b No.
Invoice No.
890908-490
53527
Sutmitted Sampled
DW
09/07/89
22:42
DW!KBA
9/6/89
Chain of Custody an file: Y
Results
cc: HdNard s. 8Aboock ~ Sam, Inc.
¢<4;..~
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF DHS CERTIFIED ESTABLISHED '906
PHONE (714) 684·1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
- .L..
To: International Tech. Corp.
17 461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sa.ple Marked:
Pj#240827-06 Marketplace
SWATs water sample MP-2
P 0. BOX 432
RIVERSIDE. CALIFORNIA 92502
10/12/89
Results
lab No. 890908-491
Invoice .No. 53527
Sutmitted
DW
09/07/89
22:42
Sampled
DLG/KBA
9/6/89
Chain of Custody on file: Y
Results
EPA Method 9020
Total Organic Halides ND mg/L
)
Date analysis completed: 09/20/89
Notes: Practical Quanti tation Limit = 2. 5mg/L
ND = None Detected at roL
cc: Bdle.rd 8. Babxx* &; &ms, Inc.
~~
)
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF DHS CERTIFIED ESTABLISHED 1906
PHONE (714) 684·1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
-.L....
To: IntematiCI1Bl Tech. Corp.
17 461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sallple Harked:
Pj.# 240827-06
Marketplace SWAT MP-3
Water sample
P 0. BOX 432
RIVERSIDE. CALIFORNIA 92502
10/12/89
Results
lab .No. 890908_492
InYoioe .No. 53527
Sut:mitted
DLG
09/07/89
22:42
Saqlled
DLG/KBA.
09/07/89
Chain of CUstody on file: Y
Results
EPA Method 9020
Total Organic Halides 1. 7 mg/L
)
Date analysis completed: 10/03/89
Notes: Practical Quanti tat ion Limit = 1 • 0 rog/L.
ND = None detected at PQL,
cc: Fdle.rd s. B!Uxxdr 1:. Sons' Inc.
~~
( )
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF DHS CERTIFIED ESTABLISHED 1906
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
To: Interna.tioneJ. Tech.. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: DBvid L. Out.h
Sallple ~ed.:
Pj#240827-06
Marketplace SWATs
W'B.ter sample MP-4
P 0. BOX 432
RIVERSIDE. CALIFORNIA 92502
10/12/89
Hesults
IBb No. 890908_493
Invoice No. 53527
Sutmitted
Dl.G
09/07/89
22:42
Sampled
Dl.D!KBA
09/07/89
Chain of Custody on file: Y
Results
EPA Method 9020
Total Organic Halides 0.5 rogjL
)
Date analysis completed: 09/20/89
Notes: Practical Quantitation Limit = 0.5 ma/L.
ND = None detected at PQL,
cc: EdiBrd s. Babcnr* & &ms, ~-
~ffUr:
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1908
PHONE (714) 684·1881
. ) LABORATORIES
3215 CHICAGO AVE.
EDWARD S. BABCOCK & SONS, INC .
- L._
To: International Tech. Corp.
17461 Derian Avera.ae Suite 190
Irvine, CA 92714
Attn: David L. Outh
Sallple MB.rtred:
Pj#240827-06 Marketplace
SWATs water sample MP-5
P 0. BOX 432
RIVERSIDE. CALIFORNIA 92502
10/12/89
Results
EPA Method 9020
Total Organic Halides 1.4 mg/L
)
Date analysis completed: 09/20/89
Notes: Practical Quanititation Limit =
ND=None Detected at FQL
cc:
0.26 mg/L
I..t> No. 890908-494
Invoice No. 53527
Sutmitted
DLG
09/07/89
22:42
Sampled
DLG/KBA
9/6/89
Chain of Custody on file: Y
Results
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 190e
PHONE (714) 684·1881
EDWARD S. BABCOCK & SONS, INC .
. ) LABORATORIES
3215 CHICAGO AVE.
To: Intematiooal Tech. Corp.
17 461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Outh
Sa.ple Marked:
Pjl240827-06 Marketplace
SWATs water sample
MP-Blank
PO. BOX 432
RIVERSIDE. CALIFORNIA 92502
10/12/89
Reaults
EPA Method 9020
Total Organic Halides ND mg/L
)
Date analysis completed: 09/20/89
Notes: Practical Quanititation Limit = 0.01 mg/L
) ND=None Detected at FQL
cc:
lab No. 890908-495
~ice No. 53527
Sut:mitted
DLG
09/07/89
22:42
Sampled
IX.GIKBA
9/7/89
Chain of Custody on file: Y
Results
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1908
PHONE (714) 684-1881 EDWARD S. BABCOCK & SONS, INC.
') LABORATORIES
3215 CHICAGO AVE.
- L..
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked:
Pj#240827/8/9 Bixby SWAT
Travel Blank prepared by
ESB
P.O. BOX 432
RIVERSIDE. CALIFORNIA 92502
10/13/89
Chain
Parameter Name Results Parameter Name
EPA Methcxi 9020
Total Organic Halides ND .mgjL
Date analysis completed: 10/03/89
Notes: Practical Quanti tation Limit = 0. 01 mg/L
ND = None Detected
Lab No. 890909-667
Invoice No. 53580
Sul:mitted Sampled
DLG ESB, Inc
09/08/89 9/1/89
22:14
of Custody on file: Y
Results
cc: Edward s. BabJock c\ Sons, Inc.
¢/h~ /DJ-r:
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
ESTABLISHED 1906
)
CALIF. DHS CERTIFIED
PHONE (714) 684-1881
LA BORA TORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE. CALIFORNIA 92502
- ..L 10/25/89
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Lab No. 890908-496
Invoice No. 53528
Customer No. in0292
Sul::mitted Sampled
Sample Marked: Pj#240827-06 Marketplace
SWATs water sample MP-1
By DLG
Date 09/07/89
Time 22:42
DLG/KBA
09/06/89
Chain of Custody on file: Y
Purgeable Halocarbons and Aromatics
EPA Method 624
Parameter Results( llg/L
Acrolein ND
Acrylonitrile ND
Benzene ND
Bromodichloromethane ND
Bromofonn. ND
Bromornethane ND
Carbon tetrachloride ND
Chlorobenzene ND
Chloroethane ND
2-Chloroethylvinyl ether ND
Chloroform ND
Chloromethane ND
Dibromochloromethane ND
1,2-Dichlorobenzene ND
1,3-Dichlorobenzene ND
1,4-Dichlorobenzene ND
1,1-Dichloroethane ND
1,2-Dichloroethane ND
ND=None detected, detection limit:
Date analysis completed: 09/14/89
··Notes:
cc:
Parameter Results( 1-lg/L
1,1-Dichloroethene ND
trans-1,2-Dichloroethene ND
1,2-Dichloropropane ND
cis-1,3-Dichloropropene ND
trans-1,3-Dichloropropene ND
Ethyl benzene ND
Methylene chloride ND
1,1,2,2-Tetrachloroethane ND
Tetrachloroethene ND
Toluene ND
1,1,1-Trichloroethane ND
1,1,2-Trichloroethane ND
Trichloroethene ND
Trichlorofluoromethane ND
Vinyl chloride ND
Methyl Ethyl Ketone ND
Acetone ND
0.5 ~/L NI=Not identifiable
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 11l0e
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
10/25/89
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Lab No. 890908-497
Invoice No. 53528
Customer No. in0292
Subnitted. Sampled
Sample Marked: Pj#240827-06 Marketplace
SWATs water sample MP-2
By DLG
Date 09/07/89
Time 22:42
DLG!KBA
09!06!89
Chain of Custody on file: Y
Purgeable Halocarbons and Aromatics
EPA Method 624
Parameter Results ( 1-lg/L
Acrolein ND
Acrylonitrile ND
Benzene ND
Bromodichloromethane ND
Bromoform ND
Bromomethane ND
carbon tetrachloride ND
Chlorobenzene ND
Chloroethane ND
2-Chloroethylvinyl ether ND
Chloroform ND
Chloromethane ND
Dibromochloromethane ND
1,2-Dichlorobenzene ND
1,3-Dichlorobenzene ND
1,4-Dichlorobenzene ND
1,1-Dichloroethane ND
1,2-Dichloroethane ND
ND=None detected, detection limit:
Date analysis completed: 09/14/89
Notes:
cc:
Parameter Results( 1-lg/L
1,1-Dichloroethene ND
trans-1,2-Dichloroethene ND
1,2-Dichloropropane ND
cis-1,3-Dichloropropene ND
trans-1,3-Dichloropropene ND
Ethyl benzene ND
Methylene chloride ND
1,1,2,2-Tetrachloroethane ND
Tetrachloroethene ND
Toluene ND
1,1,1-Trichloroethane ND
1,1,2-Trichloroethane ND
Trichloroethene ND
Trichlorofluoromethane ND
Vinyl chloride ND
Methyl Ethyl Ketone ND
Acetone ND
0.5 ~/L NI=Not identifiable
/ )
)
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 190e
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P.O. SOX 432
RIVERSIDE. CALIFORNIA 92502
10/25/89
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Lab No. 890908-498
Invoice No. 53528
Customer No. in0292
Sutmitted Sampled
Sample Marked: Pj#240827-06 Marketplace
SWATs water sample MP-3
By DLG
Date 09/07/89
Time 22:42
DLGIKBA
09/07/89
Chain of Custody on file: Y
Purgeable Halocarbons and Aromatics
EPA Method 624
Parameter Results( ~g/L
Acrolein ND
Acrylonitrile ND
Benzene 310
Bromodichloromethane ND
Bromoform ND
Brornomethane ND
Carbon tetrachloride ND
Chlorobenzene ND
Chloroethane ND
2-Chloroethylvinyl ether ND
Chloroform ND
Chloromethane ND
Dibromochloromethane ND
1,2-Dichlorobenzene ND
1,3-Dichlorobenzene ND
1,4-Dichlorobenzene ND
1,1-Dichloroethane ND
1,2-Dichloroethane ND
ND=None detected, detection limit:
Parameter Results ( ~g/L
1,1-Dichloroethene ND
trans-1,2-Dichloroethene 0.6
1,2-Dichloropropane ND
cis-1,3-Dichloropropene ND
trans-1,3-Dichloropropene ND
Ethyl benzene 18
Methylene chloride ND
1,1,2,2-Tetrachloroethane ND
Tetrachloroethene ND
Toluene ND
1,1,1-Trichloroethane ND
1,1,2-Trichloroethane ND
Trichloroethene ND
Trichlorofluoromethane ND
Vinyl chloride ND
Methyl Ethyl Ketone ND
Acetone ND
0.5 ~/L NI=Not identifiable
Date analysis completed: 09/14/89
)Notes:
cc:
Edward 8. J3ahxx* & Sons, Inc.
~ .ffk4r
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED
PHONE (714) 684-1881
ESTABLISHED 1908
) LABORATORIES
3215 CHICAGO AVE.
EDWARD S. BABCOCK & SONS, INC.
P.O. BOX 432
RIVERSIDE. CALIFORNIA 92502
)
-L....
10/25/89
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Lab No. 890908-499
Invoice No. 53528
Customer No. in0292
Sui::mitted Sampled
Sample Marked: Pj#240827-06 Marketplace
SWATs water sample MP-4
By DLG
Date 09/07/89
Time 22:42
DLG/KBA
09/07/89
Chain of Custody on file: Y
Purgeable Halocarbons and Aromatics
EPA Method 624
Parameter Results( IJg/L Parameter Results( !Jg/L
Acrolein ND 1,1-Dichloroethene ND
Acrylonitrile ND trans-1,2-Dichloroethene ND
Benzene ND 1,2-Dichloropropane ND
Bromodichloromethane ND cis-1,3-Dichloropropene ND
Bromoform ND trans-1,3-Dichloropropene ND
Bromomethane ND Ethyl benzene ND
Carbon tetrachloride ND Methylene chloride ND
Chlorobenzene ND 1,1,2,2-Tetrachloroethane ND
Chloroethane ND Tetrachloroethene ND
2-Chloroethylvinyl ether ND Toluene ND
Chloroform ND 1,1,1-Trichloroethane ND
Chloromethane ND 1,1,2-Trichloroethane ND
Dibromochloromethane ND Trichloroethene ND
1,2-Dichlorobenzene ND Trichlorofluoromethane ND
1,3-Dichlorobenzene ND Vinyl chloride ND
1,4-Dichlorobenzene ND Methy 1 Ethy 1 Ketone ND
1,1-Dichloroethane ND Acetone ND
1,2-Dichloroethane ND
ND=None detected, detection limit:
----~ Date analysis completed: 09/14/89
Notes:
0.5 !Jg/L NI=Not identifiable
cc:
Edward s. Ba.bcock & Sa1s, Inc.
~/f04?
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1906
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE. CALIFORNIA 92502
- L.. 10/25/89
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Lab No. 890908-500
Invoice No. 53528
Customer No. in0292
Subnitted Sampled
Sample Marked: P,j#240827-06 Marketplace
SWATs water sample MP-5
By DLG
Date 09/07/89
Time 22:42
DLGIKBA
09/06/89
Chain of CUstody on file: Y
Purgeable Halocarbons and Aromatics
EPA Method 624
Parameter Results( llg/L Parameter Results( llg/L
Acrolein ND 1,1-Dichloroethene ND
Acrylonitrile ND trans-1,2-Dichloroethene ND
Benzene ND 1,2-Dichloropropane ND
Bromodichloromethane ND cis-1,3-Dichloropropene ND
Bromofonn ND trans-1,3-Dichloropropene ND
Bromomethane ND Ethyl benzene ND
Carbon tetrachloride ND Methylene chloride ND
Chlorobenzene ND 1,1,2,2-Tetrachloroethane ND
Chloroethane ND Tetrachloroethene ND
2-Chloroethylvinyl ether ND Toluene ND
Chlorofonn ND 1,1,1-Trichloroethane ND
Chloromethane ND 1,1,2-Trichloroethane ND
Dibromochloromethane ND Trichloroethene ND
1,2-Dichlorobenzene ND Trichlorofluoromethane ND
1,3-Dichlorobenzene ND Vinyl chloride ND
1,4-Dichlorobenzene ND Methyl Ethyl Ketone ND
1,1-Dichloroethane ND Acetone ND
1,2-Dichloroethane ND
ND=None detected, detection limit: 0.5 ~/L NI=Not identifiable Date analysis completed: 09/14/89
Notes:
cc:
Edward s. BabJock a-. Sons' Inc.
~~
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED
PHONE (714) 684-1881
ESTABLISHED 190e
. /
) LABORATORIES
3215 CHICAGO AVE.
EDWARD S. BABCOCK & SONS, INC .
P.O. BOX 432
)
RIVERSIDE. CALIFORNIA 92502
10/25/89
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Lab No. 890908-501
Invoice No. 53528
Customer No. in0292
Sui::mitted Sampled
Sample Marked: Pj#240827-06 Marketplace
SWATs water sample
MP-Blank
By DLG
Date 09/07/89
Time 22:42
DLG(KBA
09/07/89
Chain of Custody on file: Y
Purgeable Halocarbons and Aromatics
EPA Method 624
Parameter Results ( 1-lg/L
Acrolein ND
Acrylonitrile ND
Benzene ND
Bromodichloromethane ND
Bromoform. ND
Bromornethane ND
Carbon tetrachloride ND
Chlorobenzene ND
Chloroethane ND
2-Chloroethylvinyl ether ND
Chloroform ND
Chloromethane ND
Dibromochloromethane ND
1,2-Dichlorobenzene ND
1,3-Dichlorobenzene ND
1,4-Dichlorobenzene ND
1,1-Dichloroethane ND
1,2-Dichloroethane ND
Parameter Results ( 1-lg/L
1,1-Dichloroethene ND
trans-1,2-Dichloroethene ND
1,2-Dichloropropane ND
cis-1,3-Dichloropropene ND
trans-1,3-Dichloropropene ND
Ethyl benzene ND
Methylene chloride ND
1,1,2,2-Tetrachloroethane ND
Tetrachloroethene ND
Toluene ND
1,1,1-Trichloroethane ND
1,1,2-Trichloroethane ND
Trichloroethene ND
Trichlorofluoromethane ND
Vinyl chloride ND
Methyl Ethyl Ketone ND
Acetone ND
ND=None detected, detection limit:
) Date analysis completed: 09/14/89
Notes:
0.5 J..lg/L NI=Not identifiable
cc:
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1 goe
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92502
-·-- -L. 10/25/89
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked: Pj#240827/8/9
Bixby SWAT
Lab No. 890909-668
Invoice No. 53581
Customer No. in0292
Subnitted. Sampled
By DLG
09/01/89
water sample Travel Blank
Date 09/08/89
Time 22:14
Chain of Custody on file: Y
Purgeable Haloca.rbons and Aromatics
EPA Method 624
Parameter
Acrolein
Acrylonitrile
Benzene
Bromodichloromethane
Bromofonn
Bromomethane
Carbon tetrachloride
Chlorobenzene
Results(
ND
ND
ND
ND
ND
ND
ND
ND
ND
ether ND
Chloroethane
2-Chloroethylvinyl
Chlorofonn
Chloromethane
Dibromochloromethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
ND
ND
ND
ND
ND
ND
ND
ND
1-lg/L
ND=None detected, detection limit:
Date analysis completed: 09/15/89
Notes:
cc:
Parameter Results(
1,1-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethyl benzene
Methylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Me thy 1 Ethy 1 Ketone
Acetone
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1-lg/L
0.5 1-1S:/L NI=Not identifiable
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
~-- ~--~~ --·-··----------~ ~
CALIF. DHS CERTIFIED
PHONE (714) 684-1881
LABORATORIES
ESTABLISHED 1906
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 92513ate of Report; 10125189
To: International Tech. Corp.
17461 Derian ~erfue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked: P,j#240867-06 Marketplace
SWATs water sample MP-1
Lab No. 890908-502
Invoice No. 53528
Customer No. in0292
Submitted Sampled
By DLG
Date 09/07/89
Time 22:42
DLG/KBA
09/06/89
Chain of Custody on file: Y
Base Neutral and Acid Extractable Compounds
EPA Method 625 )
Parueter Results( ~g/L l Parateter Results( ug/L i Paraaeter Results( ug/L Base{leatral l!rtractables .......................................•.....
Acenaph thene ND
Acenaphthylene ND
Anthracene liD
Aldrin ND
Benzo(a)anthfacene ND
Benzo(blfluoranthene ND
Benzo(klfluoranthene ND
Bmo! a)pyrene liD
Benzo!ghilperylene ND
Benzyl butyl phthalate ND
b-BHC ND
o-BHC ND
Bis!2-chloroethyllether ND
Bisl2-chloroethoxy)aethane ND
Bisl2-ethylhexyl)phthalate ND
Bisl2-chloroisopropyllether ND
4-Bro•ophenyl phenyl ether ND
Chlordane ND
2-Gbloronaphthalene ND
4-Cblorophenyl phenyl ether MD
Chrysene liD
4-Cbloro-3-•ethylphenol ND
2-Cblorophenol ND
2,4-Dichlorophenol ND
2,4-Ditethylphenol ND
Benzidine
a-BHC
y-BHC
ND
ND
liD
4,4'-DDD ND
4,4'-008 NO
4,4'-DDr ND
Dibenzo(a,h)anthracene ND
Di-n-butylphthalate ND
t ,3-Dichlorobenzene ND
1,2-Dichlorobenzene ND
1,4-Dichlorobenzene ND
3,3'-Dichlorobenzidine ND
Dieldrin ND
Diethyl phthalate ND
Di1ethyl phthalate ND
2,4-Dinitrotoluene ND
2,6-0initrotoluene ND
Di·n-octylphthalate ND
Endosulfan sulfate NI
Bndrin aldehyde ND
Fluoranthene ND
Fluorene ND
Heptachlor ND
Heptachlor epoxide MD
Acid lrtnctables
2,4-Dinitrophenol ND
2-Methyl-4,6-dinitrophenol ND
2-Nitrophenol ND
4-Nitrophenol ND
Add.i. tillllll lrtnctallle Panleters
Endosulfan I NI
Bndosulfan II MD
Bndrin ND
ND=None detected, detection limit:
Date analysis completed: 10/11/89
Notes: * See PQL list #1.
NI = Not Identifiable
cc:
Hexachlorobenzene MD
Hexachlorobutadiene ND
Hexachloroethane ND
[dena( 1, z, 3-cd )pyrene ND
rsophorone ND
Naphthalene ND
Nitrobenzene ND
N-Nitrosodi-n-propylaaine ND
PCB-1016 ND
PCB·1Z21 ND
PCB-1232 ND
PC8-1Z4Z ND
PCB-1248 ND
PCB·1Z54 MD
PCB-1260 ND
Phenanthrene ND
Pyrene ND
Toxaphene ND
1,2,4-Trichlorobenzene MD
llllllllllllllllltllltllllllllllltllllllllttll
Pentachlorophenol ND
Phenol ND
Z, 4, 6-Trichloropbenol liD
.......................................
Hexachlorocyclopentadiene ND
N-Nitrosodiaethylaaine ND
N-Nitrosodipkenylaaine ND
* ~/L NI=Not identifiable
/ ~.
i. )
)
----
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED
PHONE (714) 684-1881
LABORATORIES
ESTABLISHED 190e
EDWARD S. BABCOCK & SONS, INC.
P 0. BOX 432 3215 CHICAGO AVE. RIVERSIDE. CALIFORNIA 925~ f Re uate o port: 10/25/89 To: International Tech. Corp.
17461 Derian Averlbe Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked: Pj#240867-06 Market Place
SWATs water sample MP-2
Lab No. 890908-503
Invoice No. 53528
Customer No. in0292
Sutmi tted. Sampled
By DLG
Date 09/07/89
Time 22:42
DLG/KBA
09/06/89
Chain of Custody on file: Y
Base Neutral and Acid Extractable Compotmds
EPA Method 625 l
Paraaeter ~sults( ~g/L I Paraaeter ~sults( ~g/L ) Paraaeter Results( ~g/L 1 1 1 1 1 I 1 1 1 1 1 I t I f I I I I I I I f I I I I I I 0 f I I I Bl,se;/htrtl Xrtract,a,hles I I I I I I I I I I I I I I I I I I I I I I I I I t I I I I I I I I I I I I f I t I I I I Acenaphthene ND 4,4'-DDD liD Hexachlorobenzene ND
Acenaph thy lene liD 4,4'-DDE ND Hexachlorobutadiene ND Anthracene liD 4,4'-DDT liD Hexachloroethane liD
Aldrin I ND Dibenw( a, h) anthracene ND Ideno(1,2,3-cd)pyrene ND Benzo!alanthracene ND Di-n-butylphthalate liD Isopborone liD Benzol bl f luoranthene ND l, 3-Dicb lorobenrene liD Naphthalene ND Benzo( k I fluoranthene ND 1, 2-Dichlorobenrene liD Nitrobenzene ND Benzo(a)pyrene ND 1,4-Dichlorobenzene liD N-Nitrosodi-n-propylaaine ND Benzo(gbi)perylene liD 3,31-0ichloroben!lidine liD PCB-1016 ND Benzyl butyl phthalate ND Dieldrin ND PCB-1221 ND
b-BHC ND Diethyl phthalate liD PCB-1232 liD
S-BHC ND Di~ethyl phthalate liD PCB-1242 ND
Bis(2-chloroethyl)ether liD 2,4-Dinitrotoluene liD PCB-1248 ND BisiZ-chloroethoxy)aetbane liD 2,6-Dinitrotoluene liD PCB-1254 liD Bisl2-ethylhexyl)phtbalate liD Di-n-octylphthalate liD PCB-1260 liD Bis(Z-chloroisopropyl)ether liD Endosulfan sulfate III Phenanthrene ND 4-Broaophenyl phenyl et~r liD Endrin aldehyde liD Pyrene liD Chlordane liD Fluoranthene liD Toxaphene liD
2-Cb loronaphthalene liD Fluorene liD 1,2,4-Trichlorobenrene liD 4-Chlorophenyl phenyl ether liD Heptachlor 0.02
Chrysene liD Heptachlor epoxide liD
lllllfllllttlllllltllflllllfllllllllllllt Acid Krt.ractUlet fltltlllllllflllftllltllllltlllfllllllflllllll 4-Chloro-3-aethylphenol liD 2,4-Dinitrophenol liD Pentacklorophenol liD 2-Chloropbenol liD 2-Kethyl-4,6-dinitrophenol liD Phenol liD 2, 4-Dichlorophenol liD 2-lli trophenol liD 2,4,6-Trichlorophenol liD 2,4-Diaethy lphenol liD 4-Ni tropheno 1 liD
ltllllllllttllfllllllllllftllllt Addi tiOII&l lrtnctahle Parueters lllllllllflllflllllllttlflllltltfllllll Bmidine liD End.osulfan I NI Herachlorocyclopentadiene liD a-BHC liD Endosulfan II liD N-llitrosodiaethylaaine liD y-BHC liD Endrin liD N-Nitrosodiphenylaaine Nil
ND=None detected, detection limit: *
~/L NI=Not identifiable
Date analysis completed: 10/11/89
Notes: * See PQL list #1.
NI = Not Identifiable
cc: Fdlerd()
)
" \
/
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1908
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 9250_l
uate of Report: 10/25/89
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked: Pj#240867-06 Marketplace
SWATs w"B.ter sample MP-3
Lab No. 890908-504
Invoice No. 53528
Customer No. in0292
Sutmitted Sampled
By DLG
Date 09/07/89
Time 22:42
DLG/KBA
09/07/89
Chain of Custody on file: Y
Base Neutral and Acid Extractable Compmmds
( EPA Method 625
Paraaeter Results! ~g/L ) Paraaeter Results( ~g/L I Parueter Results( ~g/L ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, Base/Mettra.l lrtnctahles lllllltllltttltllltttltltllttlltltotltllllttt · Acenaphthene ND 4,4'-DDD ND Hexachlorobentene ND
Acenaphthy lene ND 4,4'-DDE ND Heracblorobutadiene ND
Anthracene ND 4,4'-DD'I' 0.07 Hexachloroethane ND
Aldrin ND Dibenzo(a,hlanthracene ND
Benzo( a) anthn.cene ND Di-n-butylphthalate ND
Benzo(blfluoranthene ND 1,3-Dichlorobenzene ND
Benzo!kifluoranthene ND 1,2-0ichlorobenzene ND
Benzo(a\pyrene ND 1,4-Dichlorobenzene ND
Ben zo i. gh i l pery 1 ene ND 3,3'-Dichlorobenzidine ND Benzyl butyl phthalate ND Dieldrin ND
b-BHC ND Diethyl phthalate ND
5-BHC ND Diaethyl phthalate ND
Bis( 2-chloroethyl)ether ND 2,4-Dinitrotoluene ND.
Bis ( 2-chloroethoxy) .ethane ND 2,6-Dinitrotoluene ND
Bis! 2-ethylhexyl i phthalate ND Di-n-octylphthalate ND Bis(2-chloroisopropyl)ether ND Endosulfan sulfate MI
4-Broaophenyl phenyl ether NO Endrin aldehyde ND
Chlordane ND Fluoranthene NO
2-Chloronaph thalene NO Fluorene ND
4-Chlorophenyl phenyl ether ND Heptachlor 10.0
Chrysene NO Heptachlor epoxide ND
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, Aci4 lrtnctables 4-Chloro-3-tethylphenol ND 2,4-0initrophenol liD
2-Chlorophenol ND 2-Methyl-4,6-dinitrophenol NO
Z,Hichloropbenol ND 2-Nitrophenol NO
Z,Hiaethylphenol ND 4-Nitrophenol NO
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, Additilal. lrtractahle Par.ten Benzidine ND Rndosulfan I
a-BHC ND Endosulf an II
y-BHC ND .Endrin
ND=None detected, detection limit:
Date analysis completed: 10/15/89
Notes: * See PQL List #2.
NI = Not Identifiable
cc:
NI
ND
ND
Ideno(1,2,3-cd)pyrene ND
Isopborone liD
Naphthalene liD
Nitrobenzene ND
N-Nitrosodi-n-propyla~ine ND
PCB-1016 ND
PCB-1221 ND
PCB-1232 ND
PCB-1242 ND
PCB-1248 ND
PCB-:1254 ND
PCB-1260 ND
Phenanthrene ND
Pyrene ND
Toxaphene ND
1,2,4-trichlorobenzene ND
llflllllllllllllflllltlllllltllfllltotlllllltl
Pentachlorophenol liD
Phenol liD
2,4,6-Tricbloropbenol ND
······································· Hexachlorocyclopentadiene ND N-Nitrosodimetbylaaine ND
N-Nitrosodipienylatine ND
* llg/L NI=Not identifiable
/
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1906
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P.O. SOX 432
RIVERSIDE. CALIFORNIA 92500a.te of Report: 10125189
To: International Tech. Corp.
17461 Derian ~~e Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked: Pj#240867-06 Marketplace
SWATs water sample MP-4
Lab No. 890908-505
Invoice No. 53528
Customer No. in0292
Sutmitted
By DLG
Date 09/07/89
Time 22:42
Sampled
DLG/KBA
09/07/89
Chain of Custody on file: Y
Base Neutral and Acid Extractable Compounds
( EPA Method 625
Para.Deter Results I ~g/ L I Paraaeter Results( ~g/L I Parateter Results( ug/L Base{leatral irtlactables ttolttlllttllltlftlt II Ill Ill II I ttlltlllllllll Acenaphthene NO
Acenaphthylene ND
Anthracene NO
Aldrin NO
Benroialanthracene NO
Bmo I b I fluoranthene NO
Ben~o(k)fluorantbene ND
Ben~ofalpyrene NO
Benrolghilperylene ND
Benzyl butyl phthalate ND
b-BHC ND
6-BHC ND
Bisl2-chloroethyllether ND
Bisl2-chloroethoxy)tethane ND
Bis(2-ethylhexyliphthalate ND
Bisl2-ch loroisopropy 11 ether ND
4-Brotophenyl phenyl ether HD
Chlordane ND
2-Ch loronaphthalene ND
4-Chlorophenyl phenyl ether ND
Chrysene HD
4-Chloro-3-tethylphenol ND
2-Chlorophenol ND
2,4-Dichlorophenol liD
2,4-Ditethylphenol liD
Ben~idine
a-BHC
y-BHC
HD
NO
liD
4,4'-DDD liD
4,4'-DDE liD
U' -DDT liD
Diben~o(a,hlanthracene ND
Di-n-butylphthalate ND
1, 3-Dichlorobeitrene ND
1,2-Dicblorobenrene NO
1, 4-Dichloroben~ene liD
3,3'-Dicbloroben~idine ND
Dieldrin liD
Diethyl phthalate ND
Diaetbyl phthalate liD
2,4-Dinitrotoluene liD
2,6-Dinitrotoluene liD
Di-n-octylphtbalate liD
Endosulfan sulfate HI
Endrin aldehyde NO
Fluoranthene liD
Fluorene liD
Heptachlor ND
Heptachlor epoxide ND
Acid htnctables
2,4-Dinitrophenol ND
2-Methyl-4,6-dinitropbenol liD
2-Nitrophenol ND
4-Nitrophenol liD
AdditiDII&l. lrtractahle Par.:ters
Endosulf an [ NI
Endosulfan II HD
Endrin MD
ND=None detected, detection limit:
Date analysis completed: 10/11/89
Notes: * See PQL List #1.
NI = Not Identifiable
cc:
Hexachlorobenzene ND
Hexachlorobutadiene ND
Hexachloroethane ND
[deno(1,2,3-cd)pyrene ND
Isopborone NO
Naphthalene ND
Nitrobenzene ND
N-Nitrosodi-n-propylaaine ND
PCB-1016 ND
PCB-1221 NO
PCB-1232 NO
PCB-1242 ND
PCB-1248 liD
PCB-1254 ND
PCB-1260 ND
Phenanthrene ND
Pyrene NO
Toxaphene ND
1,2,4-Tricblorobenrene ND
·············································· Pentachlorophenol ND Phenol ND
2,4,6-Tricblorophenol ND
llllfllllllllllltltlltltfllllltflllllll
Hexachlorocyclopentadiene ND
N-Nitrosodiaethylaaine MD
N-Nitrosodiphenylaline NO
* ~/L NI=Not identifiable
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED
PHONE (714) 684-1881
LABORATORIES
3215 CHICAGO AVE.
ESTABLISHED 190e
EDWARD S. BABCOCK & SONS, INC.
P.O. BOX 432
RIVERSIDE. CALIFORNIA 925~t f Re t
ua e o JX>r : 10/25/89
To: International Tech. Corp.
17461 Derian Averltle Suite 190
Irvine, CA 92714
Lab No. 890908-506
Invoice No. 53528
Customer No. in0292
Attn: David L. Guth
Sutmitted Sampled
Sample Marked: P,j#240867-06 Marketplace
SWATs water sample MP-5
By DLG
Date 09/07/89
Time 22:42
DLGIKBA
09/06/89
Chain of Custody on file: Y
Base Neutral and Acid Extractable Compotmds
Pa.raaeter
Acenaph thene
Acenaphthylene
Anthracene
Aldrin
Results! ug/L
ND
ND
ND
ND
Benzola)anthracene ND
Benzo(b)fluoranthene ND
Benzolklfluoranthene ND
Ben~o(alpyrene ND
Benzo(ghilperylene HD
Benzyl butyl phthalate HD
b-BHC HD
HHC HD
Bisl2-chloroethyl)ether ND
Bis(2-chloroethoxy)aethane ND
Bis(2-ethylhexyl)phthalate ND
Bisl2-chloroisopropyl)ether ND
4-BroJOphenyl phenyl ether ND
Chlordane HD
Z-Chloronaphthalene ND
4-Cblorophenyl phenyl ether ND
Chrysene ND
EPA Method 625 )
I Paraaeter Results( ~g/L l Paraaeter Results( ~g/L
lla.ae/leatnl !rtractables .............. , ... , ... , .. , ........ , . , ....... . 4, f -DDD ND Herachloroben~ene ND
4, 4' -ODE ND Hexacblorobutadiene liD
4, 4' -DDT ND Hexachloroethane ND
Dibenzo(a,b)antbracene ND [deno(l,2,3-cdlpyrene ND
Di-n-butylphthalate ND Isophorone ND
1, 3-Dichlorobenzene ND Naphthalene ND
1,2-Dichlorobenzene liD Nitrobenzene HD
1,4-Dichlorobenzene ND ~-Ni trosodi -n-propy laaine ND
3, 3'-Dichlorobenzidine ND PCB-1016 ND
Dieldrin ND PCB-1221 liD
Diethyl phthalate liD PCB-1232 ND
Ditethyl phthalate liD PCB-124Z ND
2,4-Dinitrotoluene ND PCB-1248 HD
2,6-Dinitrotoluene liD PCB-1254 ND
Di -n-octylphthalate liD PCB-1260 ND
BndosuHan sulfate NI Phenanthrene ND
Bndrin aldehyde ND Pyrene ND
Fluoranthene ND Toxaphene ND
Fluorene ND 1, 2, H'richlorobenzene ND
Heptachlor ND
Heptachlor eporide ND
,,,,,,,,,,,,,,,,,, ...................... . Acid Rrtnctables .............................................. 4-Chloro-3-tethylphenol ND
Z-Chlorophenol ND
2,4-Dichlorophenol ND
2, 4-Ditethylphenol Nil
Benzidine
a-BHC
y-BHC
liD
ND
liD
2,4-Dinitrophenol ND
2-Kethyl-4,6-dinitrophenol ND
2-Nitropienol ND
4-Nitrophenol ND
Addi.tiOII&l lrtnctaile Par.eten
Endosulfan I NI
Rndosulfan II liD
Rndrin liD
ND=None detected, detection limit:
Date analysis completed: 10/11/89
Notes: * See PQL List #1.
NI = Not Identifiable
cc:
Pentachlorophenol ND
Phenol ND
2, 4,6-Trichlorophenol ND
······································· Herachlorocyclopentadiene ND N-Nitrosoditethylaaine ND
N-Nitrosodipienyla~ine ND
* ~4/L NI=Not identifiable
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 190e
PHONE (714) 684-1881
) LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE. CALIFORNIA 9250f>ate Of Report: 10125189
To: International Tech. Corp.
17461 Derian Averfue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked: Pj#240867-06 Marketplace
SWATs water sample
MP-Blank
Lab No. 890908-507
Invoice No. 53528
Customer No. in0292
Submitted Sampled
By DLG
Date 09/07/89
Time 22:42
DLGIKBA
09/07/89
Chain of Custody on file: Y
Base Neutral and Acid Extractable Compounds
EPA Method 625 )
Paraaeter Results ( ~g/ L ) Paraaeter Results( ~g/L ) Parueter Results( ~g/L llase/leltral Krtractables ............. , ... , . , , ................ , ... , .. , Acenaphthene ND
Acenaphthylene MD
Anthracene ND
Aldrin ND
Ben~o(a)anthracene MD
Ben~(b)fluoranthene ND
Bengo(k)fluoranthene MD
Ben~(a)pyrene ND
Bengo(ghilperylene MD
Bengyl butyl phthalate MD
b-BHC liD
~-BRC ND
Bis ( 2-chloroethyll ether MD
Bisf2-chloroethoxy)~ethane ND
Bis ( 2-ethylheryll phthalate ND
Bis(2-chloroisopropyl)ether MD
4-Broaophenyl phenyl ether ND
Chlordane ND
2-Chloronaphthalene ND
4-Chloropbenyl phenyl ether MD
Chrysene ND
Hh loro-3-tethy lphenol ND
2-Ch lorophenol ND
2,4-Dichloropilenol MD
2,4-Diaethylphenol ND
Benr;idine
a-BHC
y-BIIt
ND
MD
ND
4,4' -ODD ND
4,4'-DDE KD
4,4'-DDT ND
Dibenzo(a,h)anthracene ND
Di-n-butylphthalate MD
1,3-Dichlorobenr;ene MD
1, 2-Dichlorobenr;ene MD
1, 4-Dichlorobenr;ene KD
3,3'-Dichlorobenr;idine ND
Dieldrin ND
Diethyl phthalate ND
Ditetbyl phthalate MD
2,4-Dinitrotoluene ND
2,6-Dinitrotoluene ND
Di -n-octylphthalate ND
&ndosulfan sulfate NI
Endrin aldehyde ND
Fluoranthene ND
Fluorene liD
Heptachlor ND
Heptachlor epoxide MD
Acid lltnctables
2,4-Dinitropbenol MD
Z-Methyl-4,6-dinitropilenol MD
2-Nitrophenol ND
4-Nitrophenol ND
Additioaallltnctable Pm.eten
Endosulfan·I NI
Endosulfan II HD
Endrin MD
ND=None detected, detection limit:
Date analysis completed: 10/11/89
Notes: * See PQL List #1.
NI = Not Identifiable
cc:
Heiachlorobenzene KD
Rexachlorobutadiene MD
Hexachloroethane liD
Ideno(l,2,3~cd)pyrene KD
Isophorone ND
Naphthalene ND
Nitrobenrene MD
N-Nitrosodi-n-propyla~ine ND
PCB-1016 KD
PCB-tm ND
PCB-1232 KD
PCB-1m KD
PCB-1248 ND
PCB-1254 MD
PCB-1260 MD
Phenanthrene KD
Pyrene MD
Toxaphene MD
1,2,4-Trichloroben~ene ND
flllltfflllltlltlltllllltllltltltllllttfllltlt
Pentachlorophenol ND
Phenol MD
2,4,6-Trichlorophenol ND
······································· Hexachlorocyclopentadiene ND N-Nitrosodiaethylaaine ND
N-Nitrosodiphenylaaine ND
* 1-1S/L NI=Not identifiable
)
)
\
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED
PHONE (714) 684-1881
LABORATORIES
ESTABLISHED l!lOe
EDWARDS. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE, CALIFORNIA 925'tate of Report: 10125189
To: International Tech. Corp.
17461 Derian Avenue Suite 190
Irvine, CA 92714
Attn: David L. Guth
Sample Marked: Pj#240827/8/9 Bixby SWATs
water sample Travel Blank
Lab No. 890909-669
Invoice No. 53581
Customer No. in0292
Submitted Sampled
By DLG
Date 09/08/89
Time 22:14
DLGIKBA
09/08/89
Chain of Custody on file: Y
Base Neutral and Acid Extractable Compotmd.s
EPA Method 625
Para~eter Results! ~g/L I Parameter Results\ ~g/L I Paraaeter Results( ~g/L .. , , , , , , . , , , , , , , . , , , , , , , , , , , , , , , , , Base/letltral Krt.raetables , , , , , , .. , .... , , , . , . , . , , , , , , . , , . , . , . , , , , , , ... , Acenaph thene tiD 4, 4' -ODD tiD Hexachlorobenzene tiD
Acenaphthylene tiD 4,4' -DOE tiD Hexachlorobutadiene tiD Anthracene tiD 4,4'-DDT tiD Hexachloroethane tiD
Aldrin tiD Dibenzo( a, h )anthracene tiD Ideno(1,2,3-cd)pyrene tiD Benzo(a)anthracene tiD Di-n-butylphthalate tiD Isophorone tiD Benzo(blfluoranthene iiD 1,3-Dichlorobenzene MD Naphthalene tiD Benzo(k)fluoranthene tiD 1,2-Dichlorobenzene MD Nitrobenzene MD Benzo(alpyrene ND 1,4-Dichlorobenzene tiD N-Nitrosodi-n-propylamine MD Benzo!ghi)perylene MD 3,3'-Dichlorobenzidine tiD PCB-1016 tiD Benzyl butyl phthalate tiD Dieldrin NO PCB-1221 tiD
b-BHC tiD Diethyl phthalate tiD PCB-1232 tiD
5-BHC tiD Diaethyl phthalate NO PCB-1Z4Z tiD
Bis(Z-chloroethyl)ether tiD 2,4-Dinitrotoluene tiD PCB-1248 MD Bis(2-chloroethoxyl•ethane tiD 2,6-Dinitrotoluene NO PCB-1254 MD Bis ( 2-etby lhexy l)ph thalate NI Di-n-octylphthalate ND PCB-1260 tiD Bis(2-chloroisopropyllether tiD Endosulfan sulfate NI Ph en an tb rene tiD Hro10phenyl phenyl ether tiD Endrin aldehyde tiD Pyrene tiD Chlordane tiD Fluoranthene MD Toraphene ND
2-Chloronaphthalene ND Fluorene tiD 1,2,4-Trichlorobenzene ND 4-Chlorophenyl phenyl ether ND Heptachlor ND
Chrysene ND Heptachlor eporide ND
,,,,,,,,,,,, ............................. Acid lrtractables ,,,,,,,,,,,, .................................. 4-Chloro-3-aethylphenol tiD 2, 4-Dini trophenol ND Pentachlorophenol MD 2-Chlorophenol ND 2-Methyl-4,6-dinitrophenol tiD Phenol liD 2,4-Dichlorophenol ND 2-Nitrophenol tiD 2,4,6-Trichlorophenol ND 2,4-Dilethylphenol MD 4-Nitrophenol ND
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, AdditiOII&l lrtnctaltle l'mlleten .......................................
Ben~idine ND Endosulf an I NI Herachlorocyclopentadiene MD a-BHC tiD Endosulfan II tiD N-Nitrosodiaethylaaine ND
y-BHC ND Endrin tiD N-Nitrosodiphenylaaine ND
ND=None detected, detection limit: *
~/L NI=Not identifiable
Date analysis completed: 10/15/89
Notes: * See PQL List #1.
NI = Not Identifiable
cc:
~~
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED
PHONE (714) 684-1881
\
) LABORATORIES
EDWARDS. BABCOCK & SONS, INC.
3215 CHICAGO AVE. P.O. BOX 432
RIVERSIDE. CALIFORNIA 92502
--...L..
EPA Method 625 and 608 Practical Quantitation Limit (1) Constituent
Acenaphthene
Acenaphthylene
Anthracene
Aldrin
Benzo(a)anthracene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl butyl phthalate
beta-BHC
delta-BHC
~- Bis(2-chloroethyl)ether
~Bis(2-chloroethoxy)metharie
1 8is(2-ethylhexyl)phthalate
Bis(2-chloroisopropyl)ether
4-Bromophenyl phenyl ether
Chlordane
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
4,4'-DDD
4,4'-DDE
4,4'-DDT
Dibenzo(a,h)anthracene
Di-n-butylphthalate
1,3-Dichlorobenzene
1,2-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichloroben~idine
Dieldrin
Diethyl phthalate
Dimethyl phthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octylphthalate
Endosulfan sulfate
Endrin aldehyde
· .. Fluoranthene
;Fluorene
Heptachlor
5.00 5.00
5.00 0.01
10.00 10.00
10.00 10.00
10.00 10.00
0.05 0.05
5.00 5.00
5.00 5.00
5.00 0.05
5.00 5.00
5.00 0.02
0.01 0.02
5.00 5.00
0.50 0.50
0.50 20.00
0.50 5.00
5.00 5.00
5.00 5.00
0.05 0.05
5.00 5.00
0.02 Constituent
Heptachlor epoxide
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Indeno(1,2,3-cd)pyrene
Isophorone
Naphthalene
Nitrobenzene
N-Nitrosodi-n-propylamine
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260
Phenanthrene
Pyrene
Toxaphene
1,2,4-Trichlorobenzene
4-Chloro-3-methylphenol
2-Chlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
2-Methyl-4,6-dinitrophenol
2-Nitrophenol
4-Nitrophenol
Pentachlorophenol
Phenol
2,4,6-Trichlorophenol
Benzidine
alpha-BHC
gamma-BHC
Endosulfan I
Endosulfan II
Endrin
Hexachlorocyclopentadiene
N-Nitrosodimethylamine
N-Nitrosodiphenylamine
PQL
(1-19/L)
0.10 5.00
5.00 5.00
10.00 10.00
5.00 5.00
5.00 0.02
0.02 0.02
0.02 0.20
0.20 0.20
5.00 5.00
0.05 5.00
5.00 5.00
5.00 5.00
5.00 5.00
5.00 5.00
0.50 5.00
5.00 5.00
0.01. 0.01
0.01 0.01
0.01 20. oo-
5.00 5.00
BACTERIOLOGY
WATER TESTING
HAZARDOUS WASTE TESTING
CALIF. DHS CERTIFIED ESTABLISHED 1908
PHONE (714) 684-1881
LABORATORIES
EDWARD S. BABCOCK & SONS, INC.
3215 CHICAGO AVE.
-- -L.
P.O. BOX 432
RIVERSIDE. CALIFORNIA 92502
EPA Method 625 and 608 Practical Quantitation Limit (2) Constituent
Acenaphthene
Acenaphthylene
Anthracene
Aldrin
Benzo(a)anthracene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl butyl phthalate
beta-BHC
delta-BHC
,Bis(2-chloroethyl)ether
)Bis(2-chloroethoxy)methane
'sis(2-ethylhexyl)phthalate
Bis(2-chloroisopropyl)ether
4-Bromophenyl phenyl ether
Chlordane
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
4,4'-DDD
4,4'-DDE
4,4'-DDT
Dibenzo(a,h)anthracene
Di-n-butylphthalate
1,3-Dichlorobenzene
1,2-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
Dieldrin
Diethyl phthalate
Dimethyl phthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octylphthalate
Endosulfan sulfate
Endrin aldehyde
r:-1uoranthene
)Fluorene
Heptachlor
PQL
(1-!9/L)
5.00 5.00
5.00 0.50
10.00 10.00
10.00 10.00
10.00 10.00
2.5 2.5
5.00 5.00
5.00 5.00
5.00 0.05
5.00 5.00
5.00 0.02
0.01 0.02
5.00 5.00
0.50 0.50
0.50 20.00
0.50 5.00
5.00 5.00
5.00 5.00
0.05 0.05.
5.00 s.oo
1.0 Constituent
Heptachlor epoxide
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Indeno(1,2,3-cd)pyrene
Isophorone
Naphthalene
Nitrobenzene
N-Nitrosodi-n-propylamine
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260
Phenanthrene
Pyrene
Toxaphene
1,2,4-Trichlorobenz~n~
4-Chloro-3-methylphenol
2-Chlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
2-Methyl-4,6~dinitrophenol
2-Nitrophenoi
4-Nitrophenoi
Pentachlorophenol
Phenol
2,4,6-TrichlOrophenol
Benzidine
alpha-BHC
gamma-BHC
Endosulfan I
Endosulfan II
Endrin
Hexachlorocyclopentadiehe
N-Nitrosodimethylamine
N-Nitrosodiphenylamine
PQL
(1-!9/L)
5.0 5.00
5;00
5.00 io.oo
10.00 5.00
5.00 5.00
0.02 .Q.02
0.02 d.o2
0.20 0.20
0.20 5.00
5.00 0.05
5.00 5.00
5.00 5.00
5.00 5.00
5.00 9.-oo
5.00 o~so
5.·00
5.00 5~oo
0.50 d.5o
0.-01
. 0.01
Cl. 01
zo.oo
5.00 5.00
.... _/
~/
Edward S. Babcock & Sons, Inc CHAIN OF CUSTODY RECORD I 3215 Chicago Avenue J7Jf(,1 P~trJ-.vAv~ #"-/~~'") Riverside, CA 92507
'ff' ~faR/}"ttoA/ :£-u,~~ cA- ~)..7/Y ;J.t.r,'TY/
(714) 684-1881
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Edward S. ~·-: acock & Sons, Inc
3215 Chicago Avenue
Riverside, CA 92507
(714) 684-1881
~---....---·-------- -----
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CHAIN OF CUSTODY RECORp
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INTERNATIONAL
TECHNOLOGY
CORPORATION
Mr. Robert P. Ghirelli, D. Env.
Executive Officer
June 10, 1994
California Regional Water Quality Control Board
Los Angeles Region
101 Centre Plaza Drive
Monterey Park, California 91754-2156
Attn: Ms. Blythe Ponek-Bacharowski
Submittal
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Semi-Annual Groundwater Monitoring Workplan
Bixby Ranch Company
Market Place Sanitary Landfill
Long Beach. California
Dear Mr. Ghirelli:
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Project No. 760211
On behalf of our client, Bixby Ranch Company, please find enclosed the workplan for semi annual groundwater monitoring at the Market Place Sanitary Landfill.
If you have any questions or require further information, please call Mr. Timothy J. King at (310) 493-1475.
Respectfully submitted,
IT CORPORATION
Kevin B. Aardahl
Project Manager
cc: Mr. Timothy J. King, Bixby Ranch Company
Regional Office
2355 Main Street Suite 100 • Irvine, California 92714-6222 • 714-261-6441 • FAX: 714-47 4-8309 IT Corporation is a wholly owned subsidiary of International Technology Corporation n
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WORK PLAN
FOR SEMI-ANNUAL
GROUNDWATER SAMPLING AND ANALYSIS
at
Market Place Sanitary Landfill
Long Beach, California
Project No. 760211
PREPARED FOR
Bixby Ranch Company
3010 Old Ranch Parkway, Suite 100
Seal Beach, California 90740-2750
PREPARED BY
IT Corporation
2355 Main Street, Suite 100
Irvine, California 92714
June 1994
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Table of Contents
List of Tables . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ii List of Figures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ii
1.0 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
2.0 Site Health and Safety Plan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
3. 0 Monitoring Locations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
4.0 Analytical Methods . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
5.0 Equipment Decontamination, Transportation, and Storage . . . . . . . . . . . . . . . . 3
5.1 Cleaning/Decontamination . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
5.2 Transportation and Storage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
6.0 Water and Well Depth Measurements . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
6.1 Water-Level Measurements. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
6.2 Well Depth Measurements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
7.0 Well Purging . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
8. 0 Sample Collection . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ·. . . . 6
8.1 Samples for Laboratory Analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
8.2 Samples for Field Measurements . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
9.0 Field Quality Assurance Samples . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
10.0 Sample Packaging and Shipment . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
11.0 Request-for-Analysis and Chain-of-Custody Procedures . . . . . . . . . . . . . . . . . . 9
12.0 Plan Revisions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
13.0 Reporting Requirements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
14.0 Preparation and Certification .................................. 10
15.0 References ............................................. 10 Tables
Figures
IR/6-94/KBN760211rl.toc 1
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Table Title
1 Analytical Methods and Detection Limits - Market Place Sanitary Landfill 2 Sampling and Preservation Techniques - Market Place Sanitary Landfill List of Figures ______________________________________ _ Figure Title
Topographic Map - Market Place Sanitary Landfill
2 Detailed Topographic Map - Market Place Sanitary Landfill IR/6-94/KBN7602llrl.toc 11
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1.0 /nuoducuon ____________________________________ ___ This document defines the procedures and techniques to be used for collecting, handling, and analyzing groundwater samples at the Market Place Sanitary Landfill in Long Beach, California. The site location is shown in Figure 1.
The following topics are addressed:
• Site health and safety
• Monitoring locations
• Analytical methods
• Equipment decontamination, transportation, and storage • Well and water depth measurements
• Well purging
• Sample collection
• Field Quality Assurrance samples
• Sample packaging and shipment
• Chain-of-custody control
• Plan revisions
• Reporting requirements
• Report preparation and certification.
This plan was developed in accordance with applicable laws and regulations set forth in Title 23, Division 3, Chapter 15, Article 5 and Title 22, Division 4, Chapter 15 of the California Code of Regulations (CCR).
Changes in the procedures outlined in this document may be required by circumstances arising during the program. All changes in procedures or deviations from the program will be described in written addenda to the plan. These addenda will be submitted to the Regional Water Quality Control Board (RWQCB) for approval. When field circumstances dictate deviations during the course of a given sampling event, these deviations will be evaluated as soon as possible after sampling to assess possible resampling requirements.
Deviations from the specified procedures will be clearly noted on the sampling logs used for recording data during each sampling event.
IR/6-94/KBN7602llrl 1
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2.0 Site Health and Safety Plan ___________ _
IT is committed to provide a safe and healthful work environment for all its employees and subcontractors. In accordance with Title 29, Code of Federal Regulations (CPR), Part 1910.120 and IT Procedure HS307, a site-specific Health and Safety Plan will be prepared for all proposed field activities. This plan will address known and potential site hazards, protective measures to minimize worker exposure, emergency routes to hospitals, and other considerations related to the safety of personnel on site. The Health and Safety Plan will be reviewed with all site personnel prior to the commencement of field activities, and an IT qualified site safety officer will provide for its enforcement.
3. 0 Monitoring Locations
Five groundwater monitoring wells were installed and sampled at the Market Place Sanitary Landfill as part of the SWAT investigation (IT, 1991). The location of these monitoring ;
wells is shown on Figure 2. The two proposed semi-annual sampling events will take place at the same locations.
4.0 Analytical Methods ______________ _
The RWQCB letter dated April 20, 1994, discussing the SWAT findings, emphasized that the SWAT monitoring network has not adequately demonstrated that the disposal site is not the source of lead, nickel, pesticides, and leachate indicators detected at the site. Therefore, it is proposed that each well be sampled and tested only for dissolved lead and nickel in accordance with EPA Method 6010, for pesticides in accordance with EPA Method 608 and for leachate indicators. These analyses will be conducted on samples collected semi-annually for the period of one year. Analytical methods and detection limits for chemical parameters are listed in Table 1, and sample preservation techniques are presented in Table 2.
Published method detection limits are routinely based on a single analysis of an analyte under optimum conditions and may not be achievable under typical analytical conditions. Detection IR/6-94/KBN7602llrl 2
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limits may vary for the following reasons:
• Method detection limits are highly matrix dependent. These limits should be considered as guidance and may not always be achievable. • The detectable quantity of a constituent may be affected by high levels of other constituents within the same sample. In this instance, dilution of the sample is the appropriate technique.
As technology improves, alternative approved methods and detection limits may be adopted.
5. 0 Equipment Decontamination, Transportation, and
Storage--------~----------------------------------
Monitoring wells will be purged and sampled using nondedicated purging/sampling equipment. The general inventory of equipment includes variable-flow electric submersible pumps, associated cables, replaceable polyethylene discharge hose, and support power equipment. The sampling equipment will be decontaminated prior to each use in accordance with the procedures outlined in Section 5 .1.
5. 1 Cleaning/Decontamination
All equipment will be handled in a manner intended to prevent cross-contamination of samples and to preclude the introduction of surface contamination into wells. The following decontamination procedures will be used for all purging and sampling equipment:
1. Pumps and cables will be cleaned as follows:
• The external surfaces of the pump and cable will be steam cleaned via direct spray from a steam generator.
• The pump will then be placed in a clean 5-gallon bucket containing a low alkaline, low-phosphate detergent solution. External surfaces will be scrubbed with a brush. Internal parts will be rinsed by flushing the solution through the pump.
• The external and internal components of the pump will be rinsed in a series of two buckets containing tap water. The rinse water will be flushed through the pump.
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INTERNATIONAL TECHNOLOGY CORPORATION
• The equipment will be final-rinsed with deionized water.
All equipment will be rinsed with deionized water immediately before being lowered into the well.
Prior to each sampling event, water-level measurement equipment, including lines/cables, will be rinsed with a low-alkaline, low-phosphate detergent solution; rinsed with tap water; and then triple-rinsed with deionized water.
A new length of polyethylene discharge hose will be used for purging and sample collection at each well. The hose will be rinsed with deionized water before being lowered into the well.
5. 2 Transportation and Storage
Immediately upon completion of decontamination, sampling equipment will be placed in new wrapping to assure that it remains clean during transport to the next sampling location.
Upon completion of all sampling, decontaminated equipment will be wrapped and stored.
6.0 Water and Well Depth Measurements _______ _
Depth to water and well depth measurements will be obtained for two monitoring objectives, as follows:
1. Hydrogeologic Survey- Water-level measurements will be obtained in all wells prior to purging and sampling so that water elevations can be calculated and potentiometric contour maps can be constructed. These measurements will also provide information to determine if the water surface is within the wells' screened interval. These measurements will be taken within the shortest time H possible to provide the most representative area-wide water-level data.
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2. Sampling and Purging - Prior to purging, well depth and water level measurements will be obtained so that the static water volume in each well can be calculated. The water volumes will be used to determine the amount of water to be purged (Section 7. 0).
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6.1 Water-Level Measurements
The water level in the wells will be measured with an electric water-level probe and recorded to the nearest 0. 01 foot. The probe will be lowered down the well, and the depth to water will be recorded in reference to a point permanently marked on the well casing (the reference point or top-of-casing point). This reference point itself is referenced to a specific datum point (i.e., mean sea level).
The probe-sensor and the part of the cable that comes into contact with the water will be decontaminated after each reading, as described in Section 5.1.
6. 2 Well Depth Measurements
Prior to purging, the depth of the well will be determined hy lowering the water-level probe to the bottom of the well as evidenced by slack in the cable. The depth of the well will be measured from the reference point and recorded to the nearest 0.01 foot using the same procedure described in Section 6.1.
The probe-sensor and the part of the cable that contacts water will be decontaminated prior to use in each well, as described in Section 5 .1.
All measurements pertaining to sampling, purging, standing water volumes, and well depth soundings will be recorded in the sampling log.
7.0 Well Purging _________________ _
The wells will be purged prior to sampling to ensure that the water entering the well is representative of formation water. The quantity, visual appearance, and color of water recovered during purging will be recorded in the sampling log. Any variation noted throughout the sampling event will also be noted in the log.
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The purge volume for each 'well will be calculated by using the following formula:
where:
Hwc
Dwell
Dwater
Vw
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0.163
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=
=
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Hwc = Dwell - Dwater
Vwc = Hwc X 0.163 X rZ
Height of water column in feet
Well depth in feet (from the reference point)
Depth to water in feet (from the reference point)
Volume of water column in gallons
Inside radius of well casing in inches
Constant that incorporates pi (3.14), conversions from
inches to feet and cubic feet to gallons.
Wells will be considered completely purged when three to five casing volumes have been removed by continuous pumping or until the groundwater temperature, pH, and specific conductivity have stabilized, whichever occurs first. Samples will be collected directly from the pump discharge hose when the water level in the well recovers to at least 80% of its pre purging level.
The purged well water will be placed in appropriately labeled DOT approved, 17H, steel, 55-gallon drums and stored at a central location on-site pending analytical results. IT will assist Bixby in the removal and disposal of the purge water, following applicable rules and regulations.
8.0 SampreCoUecuon ______________________________ _
This section describes procedures for collecting groundwater samples. Field data will be recorded in the sampling log. Wells will always be sampled starting with background locations/wells, followed by downgradient locations/wells. Wells known to be contaminated will be sampled last, in the order of increasing contamination.
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8. 1 Samples for Laboratory Analysis
After the well is purged, samples will be collected directly from the pump discharge hose.
Each sample collected will be split into the appropriate sample containers for the prescribed analysis. All sampling personnel will use disposable nitrile gloves during sampling.
Precleaned sample containers will be obtained from IT Analytical Services in Santa Ana, California. All sample containers will be filled completely to the brim. Containers will not be overfilled such that preservatives are diluted. Containers will be labeled in the field at the respective well locations. A sample label will be securely affixed to each sample bottle.
Sample labels will be completed with the following information using a permanent marker:
• Project name and number
• Sample number
• Collection date and time
• Collector's name
• Sample location
• Sample type and description
• Requested analytical tests
• Preservative added .
The information on the label will also be recorded on the request-for-analysis and chain-of custody documents (Section 11.0). Each sample will be given a unique identification number that indicates the sampling date and monitoring well number.
Sample containers and preservation techniques are listed in Table 2.
8. 2 Samples for Field Measurements
Specific conductivity, pH, and temperature will be measured and the turbidity will be estimated in the field during sample collection and will be recorded in the sampling log, along with color and any obvious odor noted. The method used for measurement will also be noted in the log.
Measurements will be taken before and during the sample collection sequence to ensure sample consistency.
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Instruments will be calibrated prior to sampling in accordance with the manufacturer's recommended procedures. Instrument types and serial numbers or other unique identifiers will be recorded with the calibration process and data in the sampling log.
9. 0 Field Quality Assurance Samples
A field quality assurance (QA) sampling scheme will be established to check sampling and analytical accuracy and precision. The field QA program will consist of collecting equipment rinsate samples.
After sampling equipment has been decontaminated and prior to its use for subsequent sampling, one field equipment rinsate sample will be collected for analysis during each sampling event as a check of field decontamination procedures. The rinsate sample will be collected by pumping deionized water through the decontaminated submersible pump with new discharge hose and into the appropriate sample bottles. Analysis of these samples helps determine the effectiveness of the decontamination procedures. Each sample will be analyzed for the same parameters specified for the well samples. Unique identification numbers will also be used for the equipment rinsate samples.
10.0 Sample Packaging and Shipment ________ _
Samples will be packaged and shipped in a manner to preserve the integrity of the samples.
Ice chests will be used as shipping containers. Custody sealed sample containers will be wrapped in bubble wrap and re-sealable plastic bags, placed in ice chests with double-bagged ice (or "blue ice," if necessary) and surrounded with packing material. Required documents will be hand-carried by the sampling personnel. The ice chest will be secured, and custody seals will be affixed to prevent tampering.
Authorized laboratory personnel will store and/or prepare the samples for analysis promptly upon receipt. If samples are not received in good condition, cannot be stored properly, or are not analyzed within the specified holding times, the laboratory will promptly notify the IR/6-94fKBA/7602llrl 8
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sampling team and the project manager. The need for resampling will be determined promptly upon such notification.
11.0 Request-for-Analysis and Chain-of-Custody
Procedures ______________________________________ _
Request-for-analysis and chain-of-custody documentation will be prepared for each sample container set.
The following sample information will be documented on the request-for-analysis/chain-of custody document(s): sample number, type, date of collection, time, container type, sample volume, and preservative. This information will be completed in waterproof ink at the sampling field location.
The documentation will specify the requested testing program, including analytical method number. When sample custody changes, signatures and affiliation of personnel relinquishing and accepting the samples will be recorded on the form, along with the date and time. A copy of the request-for-analysis/chain-of-custody form(s) will be retained by the shipper and will be placed in the project file. Signed and completed copies of the request-for:.. analysis/chain-of-custody document(s) will be returned with the laboratory report and placed in the project file.
12.0 Plan Revisions------------------
This plan will be revised as necessary to comply with evolving Federal or State regulations or to reflect changes in site conditions. Revisions to the plan will be submitted for regulatory approval as appropriate.
13.0 Reporting Requirements-------------
Following receipt of analytical data from each semi-annual sampling event, reports will be prepared. The first semi-annual report will include a discussion of the field activities, a summary of the analytical data in tabular format, a groundwater contour map, and copies of IR/6-94/KBN76021lrl 9
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the certificates-of-analysis and chain-of-custody documentation. The second semi-annual report will compare and summarize the analytical data for the year's monitoring and will include conclusions on the monitoring activities conducted at the landfill and recommendations based on the analytical results.
14.0 Preparation and Certification __________ _
The semi-annual sampling program at the Market Place Sanitary Landfill will be supervised by a geologist registered with the State Board of Registration for Geologists and Geophysicists. Each report will include a statement of certification signed and stamped by the supervising registered geologist.
15.0 References-------------------
California Regional Water Quality Control Board, Los Angeles Region, 1994, "SWAT Report Findings- Market Place Sanitary Landfill (City Dump Salvage No. 2), Long Beach," RWQCB (File No. 60-89), April.
IT Corporation, 1991, "Solid Waste Assessment Test (SWAT) Market Place Sanitary Landfill," Addendum Report, January.
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Table 1
Analytical Methods and Detection limits
Market Place Sanitary Landfill
Project No. 760211
(Sheet 1 of 2)
METHOD OF APPROXIMATE
ANALYSIS DETECTION
ANALYTE (EPA Method) LIMIT
LEACHATE INDICATORS: (MG/L)
pH (laboratory) 150.1 0.1 unit
SPECIFIC CONDUCTIVITY (laboratory) 120.1 1 umhos/cm
TOTAL DISSOLVED SOLIDS (TDS) 160.1 10.0
CHEMICAL OXYGEN DEMAND (COD) 410.4 3.0
BIOCHEMICAL OXYGEN DEMAND (BOD) 405.1 4.0
TOTAL ORGANIC CARBON (TOC) 415 1.0
TOTAL ORGANIC HALIDES (TOX) 9020 0.02
TOTAL ALKALINITY AS CaC03 310.1 1.0
METALS:
LEAD 6010 0.02
NICKEL 6010 0.04
PESTICIDES AND PCBs: (UG/Ll
ALDRIN 608 0.05
alpha-BHC 608 0.05
beta-BHC 608 0.05
delta- BHC 608 0.05
gamma - BHC (Lindane) 608 0.05
CHLORDANE (alpha) 608 0.05
4,4'- DDD 608 0.10
IR/6-941KBN760211rl.tl
MCL
(MG/L)
--
900 umhos/cm
1000
--
--
--
--
--
0.05 0.10
(UG/Ll
--
--
--
--
0.2 0.1
--
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Table 1
Analytical Methods and Detection limits
Market Place Sanitary Landfill
Project No. 760211
(Sheet 2 of 2)
METHOD OF APPROXIMATE
ANALYSIS DETECTION
ANALYTE (EPA Method) LIMIT
4,4'- DDE 608 0.10
4,4'- DDT 608 0.10
DIELDRIN 608 0.10
ENDOSULFAN I 608 0.05
ENDOSULFAN II 608 0.10
ENDRIN ALDEHYDE 608 0.10
EN DR IN 608 0.10
ENDOSULFAN SULFATE 608 0.05
HEPTACHLOR 608 0.01
HEPTACHLOR EPOXIDE 608 0.01
TOXAPHENE 608 1.0
PCB- 1016 608 0.5
PCB- 1221 608 0.5
PCB- 1232 608 0.5
PCB- 1242 608 0.5
PCB- 1248 608 0.5
PCB- 1254 608 1.0
PCB- 1260 608 0.10
1 Note: MCL - State of California Maximum contaminant level for drinking water. i
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MCL
--
--
--
--
--
--
0.2 --
0.01 0.01
5.0 --
--
--
--
--
--
--
Parameter
Inorganic Tests
Alkalinity
Biochemical oxygen demand
Total organic carbon
Total organic halides
Chemical oxygen demand
Hydrogen ion (pH)
Residue, filterable
Specific conductance
Metals (Dissolved)d
Organic Testse
Pesticides
PCBs
See footnotes at end of table.
IR/06-941WPC/f:projects:02llrl.t2
Table 2
Sampling and Preservation Requirements
Market Place Sanitary Landfill
Project No. 760211
(Sheet 1 of 2)
Volume
Required
Containers (ml) Preservationb
P,G 100 Cooi4°C
P,G 100 Cooi4°C
P,G 25 Cool 4°C, HCL/H 2 S04 to pH < 2
P,G 250 Cool 4°C, HCL/H 2 S04 to pH < 2
P,G 75 Cool 4°C, H2S0 4 to pH < 2
P,G 25 None required
P,G 100 Cooi4°C
P,G 100 Cooi4°C
p 500 Cool 4°C (filtered, HN0 3 to
ph< 2)d
p 1000 Cool 4°C, Na2S203 to pH 5-9
p 1000 Coo14°C
Maximum Holding
Tim esc
14 days
48 hours
28 days
7 days
28 days
Analyze immediately
48 hours
28 days
6 months
7 days until
extraction, 40 days
after extraction
7 days until
extraction, 40 days
after extraction
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Table 2
Sampling and Preservation Requirements
Market Place Sanitary landfill
Project No. 760211
(Sheet 2 of 2)
Reference: This table includes the requirements of the U.S. Environmental Protection Agency, as published in the Code of Federal Regulations, Vol. 49, No. 209, 40 CFR 136, October 26, 1984, pg. 43260. aPolyethylene (P) or glass (G)
bSample preservation should be performed immediately upon sample collection. For composite chemical samples, each aliquot should be preserved at the time of collection. When use of an automatic sampler makes it impossible to preserve each aliquot, then chemical samples may be preserved by maintaining at 4°C until compositing and sample splitting is completed. csamples should be analyzed as soon as possible after collection. The times listed are the maximum times that samples may be held before analysis and still be considered valid. Samples may be held for longer periods only if the permittee or monitoring laboratory has data on file to show that the specific types of samples under study are stable for the longer time. Some samples may not be stable for the maximum time period given in the table. A permittee or monitoring laboratory is obligated to hold the sample for a shorter period if knowledge exists to show this is necessary to maintain sample stability. dSamples for dissolved metals should be field filtered using 0.45 micron filter paper. The filtered sample should then be poured into a 500ml polyethylene bottle containing H2S04 preservatives and maintained at 4°C until analysis. "Guidance applies to samples to be analyzed by GC, LC, or GC/MS for specific compounds.
IR/06-94/WPC/f:projects:02llrl.t2
FIGURES
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\\ SCALE
SITE~ 0 2000 4000 FEET
REFERENCE:
USGS 7.5 MINUTE TOPOGRAPHIC MAP OF
LONG BEACH, LOS ALAMITOS AND SEAL BEACH,
CALIFORNIA QUADRANGLE; DATE: 1964,1964 AND
1965 RESPECTIVELY; PHOTOREVISED: 1981; SCALE 1:24000
FIGURE
TOPOGRAPHIC MAP
MARKET PLACE LANDFILL
PREPARE[) FOR
BIXBY RANCH COMPANY
SEAL BEACH, CALIFORNIA
N!
[i] ... Creating a Safer Tomorrow
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LEGEND
-5-- TOPOGRAPHIC CONTOUR
SWAT MONITORING WELL
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--,
600
REFERENCE=
1200 FEET
BASE MAP- CITY OF LONG BEACH, DEPARTMENT
OF ENGINEERING, 1978 THROUGH 1982.
FOR TOPOGRAPHIC REFERENCE, SEE FIGURE I.
··oa No! Scale Thts Orawtng·
FIGURE 2
DETAILED TOPOGRAPHIC MAP OF
MARKET PLACE LANDFILL
PREPARED FOR
BIXBY RANCH COMPANY
SEAL BEACH, CALIFORNIA
rn ... Creating a Safer Tomorrow
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INTERNATIONAL
TECHNOLOGY
CORPORATION
Mr. Robert P. Ghirelli, D. Env.
Executive Officer
October 17, 1994
California Regional Water Quality Control Board
Los Angeles Region
101 Centre Plaza Drive
Monterey Park, California 91754-2156
Attn: Ms. Blythe Ponek-Bacharowski
Project No. 760211
Addendum to Semi-Annual Groundwater Monitoring Worlg>lan Revised Groundwater Analytical Program
Bixby Ranch Company
Market Place Sanitary Landfill
Long Beach. California
Dear Mr. Ghirelli:
IT Corporation (IT) is submitting this addendum to the semi-annual groundwater monitoring work:plan for the Market Place Sanitary landfill in behalf of our client, Bixby Ranch Company. This addendum complies with the request for additional groundwater analyses stated in the September 19, 1994 letter issued by California Regional Water Quality Control Board (RWQCB). It is understood that the list of analyses may be reduced following receipt and review of the first semi-annual monitoring report. The enclosed tables summarize the analytical program for the first round of semi-annual sampling~ The original work:plan stated that one equipment rinsate sample would be collected per sampling event and that the sample would receive the same analyses as the samples collected from the wells. However, in an effort to reduce the cost for the additional analyses, rinsate samples will be tested for purgeable halocarbons (EPA Method 624) and pesticides and PCB' s (EPA Method 608) only.
Regional Office
2355 Main Street Suite 100 • Irvine, California 92714-6260 • 714-261-6441 • FAX: 714-474-8309 IT CoipOration is a wholly owned subsidiary of International Technology CoipOration ...
INTERNATIONAL TECHNOLOGY CORPORATION
Mr. Robert P. Ghirelli 2 October 17, 1994
. Following your review of this letter, please call me at (714) 660-5416 to confirm acceptance of this revised plan.
Respectfully submitted,
IT CORPORATION
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Kevin B. Aardahl
Project Manager
Enclosures
cc: Mr. Timothy J. King, Bixby Ranch Company
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Table 1
Proposed Groundwater Analytical Testing
General Chemistry
Bixby Ranch Company Landfills
ANALYSIS I UNITS I
pH pH units
Conductivity umhos/cm
Total Dissolved Solids mg/1
Total Alkalinity as CaCo3 mg/1
Chemical Oxygen Demand mg/1
Biochemical Oxygen Demand mg/1
Total Organic Carbon mg/1
Total Organic Halides mg/1
Hydroxide mg/1
Carbonate mg/1
Bicarbonate mg/1
Chloride mg/1
Fluoride mg/1
Nitrate mg/1
Phosphate as Total P mg/1
Sulfate mg/1
Bromide mg/1
Oil and grease mg/1
DETECTION
I LIMIT
0.1 0.1
5 2.5
5 2
1 0.01
1 1
3 1
0.1 1
0.03 1
1 1
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Table 2
Proposed Groundwater Analytical Testing
Metals EPA Method 6010/7000 (ICP/GFAA)
Bixby Ranch Company Landfills
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DETECTION
ANALYSIS UNITS LIMIT
Antimony mg/1 0.01
Arsenic mg/1 0.01
Barium mg/1 0.1
Beryllium mg/1 0.01
Cadmium mg/1 0.001
Calcium mg/1 1
Chromium (Total) mg/1 0.01
Cobalt mg/1 0.01
Copper mg/1 0.01
Iron mg/1 0.01
Lead mg/1 0.005
Magnesium mg/1 1
Manganese mg/1 0.01
Mercury mg/1 0.001
Molybdenum mg/1 0.1
Nickel mg/1 0.01
Potassium mg/1 1
Selenium mg/1 0.005
Sodium mg/1 1
Silver mg/1 0.01
Thallium mg/1 0.1
Vanadium mg/1 0.1
Zinc mg/1 0.01
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Proposed Groundwater Analytical Testing
Volatile Organic Compounds
EPA Method 624
Bixby Ranch Company Landfills
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DETECTION
ANALYSIS UNITS LIMIT
Acetone ug/1 0.5
Acrolein ug/1 0.5
Acrylonitrile ug/1 0.5
Benzene ug/1 0.5
Bromodichloromethane ug/1 0.5
Bromoform ug/1 0.5
Bromomethane ug/1 0.5
Carbon Tetrachloride ug/1 0.5
Chlorobenzene ug/1 0.5
Chloroethane ug/1 0.5
2-Chloroethylvinyl ether ug/1 0.5
Chloroform ug/1 0.5
Chloromethane ug/1 0.5
Dibromochloromethane ug/1 0.5
1 ,2-Dichlorobenzene ug/1 0.5
1 ,3-Dichlorobenzene ug/1 0.5
1 ,4-Dichlorobenzene ug/1 0.5
1 , 1-Dichloroethane ug/1 0.5
1 ,2 -Dichloroethane ug/1 0.5
1 , 1-Dichloroethene ug/1 0.5
trans-1 ,2-Dichloroethene ug/1 0.5
Ethyl benzene ug/1 0.5
Methylene chloride ug/1 0.5
Methyl Ethyl Ketone ug/1 0.5
Methyl Isobutyl Ketone ug/1 0.5
1 , 1 ,2,2-Tetrachloroethane ug/1 0.5
Tetrachloroethene ug/1 0.5
Toluene ug/1 0.5
1 , 1 , 1-Trichloroethane ug/1 0.5
1,1 ,2-Trichloroethane ug/1 0.5
Trichlorofluoromethane ug/1 0.5
Vinyl chloride ug/1 0.5
Xylene(s) ug/1 0.5
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Table 4
Proposed Groundwater Analytical Testing
Pesticides and PCB's
EPA Method 608
Bixby Ranch Company Landfills
DETECTION
ANALYSIS UNITS LIMIT
Aldrin ug/1 0.01
alpha-BHC ug/1 0.01
beta-BHC ug/1 0.05
delta-BHC ug/1 0.05
gamma-BHC ug/1 0.01
Chlordane ug/1 0.05
4,4'-DDD ug/1 0.02
4-4'-DDE ug/1 0.01
4,4'-DDT ug/1 0.02
Dieldren ug/1 0.5
Endrin ug/1 0.01
Endosulfan I ug/1 0.01
Endosulfan II ug/1 0.01
Endosulfan sulfate ug/1 0.05
Endrin aldehyde ug/1 0.05
PCB 1016 ug/1 0.02
PCB 1221 ug/1 0.02
PCB 1232 ug/1 0.02
PCB 1242 ug/1 0.02
PCB 1248 ug/1 0.02
PCB 1254 ug/1 0.02
PCB1260 ug/1 0.2
Toxaphene ug/1 0.05
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WORK PLAN
FOR SEMI-ANNUAL
GROUNDWATER SAMPLING AND ANALYSIS
at
Market Place Sanitary Landfill
Long Beach, California
Project No. 760211
PREPARED FOR
Bixby Ranch Company
3010 Old Ranch Parkway, Suite 100
Seal Beach, California 90 7 40-2 7 50
PREPARED BY
IT Corporation
2355 Main Street, Suite 100
Irvine, California 92714
June 1994
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Table of Contents
List of Tables . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ii List of Figures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . u
1.0 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
2.0 Site Health and Safety Plan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
3. 0 Monitoring Locations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
4.0 Analytical Methods . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
5.0 Equipment Decontamination, Transportation, and Storage . . . . . . . . . . . . . . . . 3
5.1 Cleaning/Decontamination . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
5.2 Transportation and Storage ......................... _. . . . . 4
6.0 Water and Well Depth Measurements . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
6.1 Water-Level Measurements. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
6.2 Well Depth Measurements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
7.0 Well Purging . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
8.0 Sample Collection ....................................... ~ 6
8.1 Samples for Laboratory Analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
8.2 Samples for Field Measurements . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
9. 0 Field Quality Assurance Samples . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
10.0 Sample Packaging and Shipment . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
11.0 Request-for-Analysis and Chain-of-Custody Procedures . . . . . . . . . . . . . . . . . . 9
12.0 Plan Revisions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
13.0 Reporting Requirements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
14.0 Preparation and Certification .................................. 10
15.0 References ............................................. 10 Tables
Figures
IR/6-941KBN760211 rl. toe 1
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Table Title
1 Analytical Methods and Detection Limits- Market Place Sanitary Landfill r 1
2 Sampling and Preservation Techniques - Market Place Sanitary Landfill I C -~
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Figure Title
1 Topographic Map - Market Place Sanitary Landfill
2 Detailed Topographic Map - Market Place Sanitary Landfill IR/6-94/KBA/760211 r1. toe 11
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1.0 lnuoducuon __________________________________ ~ __
This document defines the procedures and techniques to be used for collecting, handling, and analyzing groundwater samples at the Market Place Sanitary Landfill in Long Beach, California. The site location is shown in Figure 1.
The following topics are addressed:
• Site health and safety
• Monitoring locations
• Analytical methods
• Equipment decontamination, transportation, and storage • Well and water depth measurements
• Well purging
• Sample collection
• Field Quality Assurrance samples
• Sample packaging and shipment
• Chain-of-custody control
• Plan revisions
• Reporting requirements
• Report preparation and certification.
This plan was developed in accordance with applicable laws and regulations set forth in Title 23, Division 3, Chapter 15, Article 5 and Title 22, Division 4, Chapter 15 of the California Code of Regulations (CCR) .
Changes in the procedures outlined in this document may be required by circumstances arising during the program. All changes in procedures or deviations from the program will be described in written addenda to the plan. These addenda will be submitted to the Regional Water Quality Control Board (RWQCB) for approval. When field circumstances dictate deviations during the course of a given sampling event, these deviations will be evaluated as soon as possible after sampling to assess possible resampling requirements.
Deviations from the specified procedures will be clearly noted on the sampling logs used for recording data during each sampling event.
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2.0 Site Health and Safety Plan _______________ _
IT is committed to provide a safe and healthful work environment for all its employees and subcontractors. In accordance with Title 29, Code of Federal Regulations (CFR), Part 1910.120 and IT Procedure HS307, a site-specific Health and Safety Plan will be prepared for all proposed field activities. This plan will address known and potential site hazards, protective measures to minimize worker exposure, emergency routes to hospitals, and other considerations related to the safety of personnel on site. The Health and Safety Plan will be reviewed with all site personnel prior to the commencement of field activities, and an IT qualified site safety officer will provide for its enforcement.
3. 0 Monitoring Locations
Five groundwater monitoring wells were installed and sampled at the Market Place Sanitary Landfill as part of the SWAT investigation (IT, 1991). The location of these monitoring wells is shown on Figure 2. The two proposed semi-annual sampling events will take place at the same locations.
4.0 AnalyucaiMethods ____________________________ _
The RWQCB letter dated April 20, 1994, discussing the SWAT findings, emphasized that the SWAT monitoring network has not adequately demonstrated that the disposal site is not the source of lead, nickel, pesticides, and leachate indicators detected at the site. Therefore, it is proposed that each well be sampled and tested only for dissolved lead and nickel in accordance with EPA Method 6010, for pesticides in accordance with EPA Method 608 and for leachate indicators. These analyses will be conducted on samples collected semi-annually for the period of one year. Analytical methods and detection limits for chemical parameters are listed in Table 1, and sample preservation techniques are presented in Table 2.
Published method detection limits are routinely based on a single analysis of an analyte under optimum conditions and may not be achievable under typical analytical conditions. Detection IR/6-94/KBN760211rl 2
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limits may vary for the following reasons:
• Method detection limits are highly matrix dependent. These limits should be considered as guidance and may not always be achievable. • The detectable quantity of a constituent may be affected by high levels of other constituents within the same sample. In this instance, dilution of the sample is the appropriate technique.
As technology improves, alternative approved methods and detection limits may be adopted.
5. 0 Equipment Decontamination, Transportation, and
Storage------------------------~---------------
Monitoring wells will be purged and sampled using nondedicated purging/ sampling equipment. The general inventory of equipment includes variable-flow electric submersible pumps, associated cables, replaceable polyethylene discharge hose, and support power equipment. The sampling equipment will be decontaminated prior to each use in accordance with the procedures outlined in Section 5 .1.
5. 1 Cleaning/Decontamination
All equipment will be handled in a manner intended to prevent cross-contamination of samples and to preclude the introduction of surface contamination into wells. The following decontamination procedures will be used for all purging and sampling equipment:
1. Pumps and cables will be cleaned as follows:
IR/6-94/KBA/760211 r1
• The external surfaces of the pump and cable will be steam cleaned via direct spray from a steam generator.
• The pump will then be placed in a clean 5-gallon bucket containing a low alkaline, low-phosphate detergent solution. External surfaces will be scrubbed with a brush. Internal parts will be rinsed by flushing the solution through the pump.
• The external and internal components of the pump will be rinsed in a series of two buckets containing tap water. The rinse water will be flushed through the pump.
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• The equipment will be final-rinsed with deionized water.
2. All equipment will be rinsed with deionized water immediately before being lowered into the well.
3. Prior to each sampling event, water-level measurement equipment, including lines/cables, will be rinsed with a low-alkaline, low-phosphate detergent solution; rinsed with tap water; and then triple-rinsed with deionized water.
A new length of polyethylene discharge hose will be used for purging and sample collection at each well. The hose will be rinsed with deionized water before being lowered into the well.
5. 2 Transportation and Storage
Immediately upon completion of decontamination, sampling equipment will be placed in new wrapping to assure that it remains clean during transport to the next sampling location.
Upon completion of all sampling, decontaminated equipment will be wrapped and stored.
6.0 Water and Well Depth Measurements ________ _
Depth to water and well depth measurements will be obtained for two monitoring objectives, as follows:
1. Hydrogeologic Survey- Water-level measurements will be obtained in all wells prior to purging and sampling so that water elevations can be calculated and potentiometric contour maps can be constructed. These measurements will also provide information to determine if the water surface is within the wells' screened interval. These measurements will be taken within the shortest time possible to provide the most representative area-wide water-level data.
2. Sampling and Purging -Prior to purging, well depth and water level measurements will be obtained so that the static water volume in each well can be calculated. The water volumes will be used to determine the amount of water to be purged (Section 7. 0).
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6.1 Water-Level Measurements
The water level in the wells will be measured with an electric water-level probe and recorded to the nearest 0.01 foot. The probe will be lowered down the well, and the depth to water will be recorded in reference to a point permanently marked on the well casing (the reference point or top-of-casing point). This reference point itself is referenced to a specific datum point (i.e., mean sea level).
The probe-sensor and the part of the cable that comes into contact with the water will be decontaminated after each reading, as described in Section 5 .1.
6. 2 Well Depth Measurements
Prior to purging, the depth of the well will be determined by lowering the water-level probe to the bottom of the well as evidenced by slack in the cable. The depth of the well will be measured from the reference point and recorded to the n~est 0.01 foot using the same procedure described in Section 6.1.
The probe-sensor and the part of the cable that contacts water will be decontaminated prior to use in each well, as described in Section 5 .1.
All measurements pertaining to sampling, purging, standing water volumes, and well depth soundings will be recorded in the sampling log.
7.0 Well Purging _________________ _
The wells will be purged prior to sampling to ensure that the water entering the well is representative of formation water. The quantity, visual appearance, and color of water recovered during purging will be recorded in the sampling log. Any variation noted throughout the sampling event will also be noted in the log.
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The purge volume for each well will be calculated by using the following formula:
where:
Hwc
Dwell
Dwater
Vw
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0.163
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=
Hwc = Dwell - Dwater
v we = Hwc X 0.163 X r
Height of water column in feet
Well depth in feet (from the reference point)
Depth to water in feet (from the reference point)
Volume of water column in gallons
Inside radius of well casing in inches
Constant that incorporates pi (3 .14), conversions from inches to feet and cubic feet to gallons.
Wells will be considered completely purged when three to five casing volumes have been removed by continuous pumping or until the groundwater temperature, pH, and specific conductivity have stabilized, whichever occurs first. Samples will be collected directly from the pump discharge hose when the water level in the well recovers to at least 80% of its pre purging level.
The purged well water will be placed in appropriately labeled DOT approved, 17H, steel, 55-gallon drums and stored at a central location on-site pending analytical results. IT will assist Bixby in the removal and disposal of the purge water, following applicable rules and regulations.
8.0 Sample Collection _______________ _
This section describes procedures for collecting groundwater samples. Field data will be recorded in the sampling log. Wells will always be sampled starting with background locations/wells, followed by downgradient locations/wells. Wells known to be contaminated will be sampled last, in the order of increasing contamination.
IR/6-94/KBA/760211 rl 6
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8. 1 Samples for Laboratory Analysis
After the well is purged, samples will be collected directly from the pump discharge hose.
Each sample collected will be split into the appropriate sample containers for the prescribed analysis. All sampling personnel will use disposable nitrile gloves during sampling.
Precleaned sample containers will be obtained from IT Analytical Services in Santa Ana, California. All sample containers will be filled completely to the brim. Containers will not be overfilled such that preservatives are diluted. Containers will be labeled in the field at the respective well locations. A sample label will be securely affixed to each sample bottle.
Sample labels will be completed with the following information using a permanent marker:
• Project name and number
• Sample number
• Collection date and time
• Collector's name
• Sample location
• Sample type and description
• Requested analytical tests
• Preservative added .
The information on the label will also be recorded on the request-for-analysis and chain-of custody documents (Section 11.0). Each sample will be given a unique identification number that indicates the sampling date and monitoring well number.
Sample containers and preservation techniques are listed in Table 2.
8. 2 Samples for Field Measurements
Specific conductivity, pH, and temperature will be measured and the turbidity will be estimated in the field during sample collection and will be recorded in the sampling log, along with color and any obvious odor noted. The method used for measurement will also be noted in the log.
Measurements will be taken before and during the sample collection sequence to ensure sample consistency.
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Instruments will be calibrated prior to sampling in accordance with the manufacturer's recommended procedures. Instrument types and serial numbers or other unique identifiers will be recorded with the calibration process and data in the sampling log.
9. 0 Field Quality Assurance Samples
A field quality assurance (QA) sampling scheme will be established to check sampling and analytical accuracy and precision. The field QA program will consist of collecting equipment rinsate samples.
After sampling equipment has been decontaminated and prior to its use for subsequent sampling, one field equipment rinsate sample will be collected for analysis during each sampling event as a check of field decontamination procedures. The rinsate sample will be collected by pumping deionized water through the decontaminated submersible pump with new discharge hose and into the appropriate sample bottles. Analysis of these samples helps determine the effectiveness of the decontamination procedures. Each sample will be analyzed for the same parameters specified for the well samples. Unique identification numbers will also be used for the equipment rinsate samples.
10.0 Sample Packaging and Shipment ________ _
Samples will be packaged and shipped in a manner to preserve the integrity of the samples.
Ice chests will be used as shipping containers. Custody sealed sample containers will be wrapped in bubble wrap and re-sealable plastic bags, placed in ice chests with double-bagged ice (or "blue ice," if necessary) and surrounded with packing material. Required documents will be hand-carried by the sampling personnel. The ice chest will be secured, and custody seals will be affixed to prevent tampering.
Authorized laboratory personnel will store and/or prepare the samples for analysis promptly upon receipt. If samples are not received in good condition, cannot be stored properly, or are not analyzed within the specified holding times, the laboratory will promptly notify the IR/6-94/KBA/760211 r1 8
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sampling team and the project manager. The need for resampling will be determined promptly upon such notification.
11.0 Request-for-Analysis and Chain-of-Custody
Procedures ____________________________________ ___
r1 ! \ · Request-for-analysis and chain-of-custody documentation will be prepared for each sample L "
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The following sample information will be documented on the request-for-analysis/chain-of custody document(s): sample number, type, date of collection, time, container type, sample volume, and preservative. This information will be completed in waterproof ink at the sampling field location.
The documentation will specify the requested testing program, including analytical method number. When sample custody changes, signatures and affiliation of personnel relinquishing and accepting the samples will be recorded on the form, along with the date and time. A copy of the request-for-analysis/chain-of-custody form(s) will be retained by the shipper and will be placed in the project file. Signed and completed copies of the request-for analysis/chain-of-custody document(s) will be returned with the laboratory report and placed in the project file.
12.0 Plan Revisions _________________ _
This plan will be revised as necessary to comply with evolving Federal or State regulations or to reflect changes in site conditions. Revisions to the plan will be submitted for regulatory approval as appropriate.
13.0 Reporting Requirements--------------
Following receipt of analytical data from each semi-annual sampling event, reports will be prepared. The first semi-annual report will include a discussion of the field activities, a summary of the analytical data in tabular format, a groundwater contour map, and copies of IR/6-94/KBA/76021lrl 9
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the certificates-of-analysis and chain-of-custody documentation. The second semi-annual report will compare and summarize the analytical data for the year's monitoring and will include conclusions on the monitoring activities conducted at the landfill and recommendations based on the analytical results.
14.0 Preparation and Certification ___________ _
The semi-annual sampling program at the Market Place Sanitary Landfill will be supervised by a geologist registered with the State Board of Registration for Geologists and Geophysicists. Each report will include a statement of certification signed and stamped by the supervising registered geologist.
15.0 References-------------------
California Regional Water Quality Control Board, Los Angeles Region, 1994, "SWAT Report Findings - Market Place Sanitary Landfill (City Dump Salvage No. 2), Long Beach," RWQCB (File No. 60-89), April.
IT Corporation, 1991, "Solid Waste Assessment Test (SWAT) Market Place Sanitary Landfill," Addendum Report, January.
IR/6-94/KBA/760211rl 10
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TABLES
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Table 1
Analytical Methods and Detection Limits
Market Place Sanitary Landfill
Project No. 760211
(Sheet 1 of 2)
METHOD OF APPROXIMATE
ANALYSIS DETECTION
ANALYTE (EPA Method) LIMIT
LEACHATE INDICATORS: (MG/Ll
pH (laboratory) 150.1 0.1 unit
SPECIFIC CONDUCTIVITY (laboratory) 120.1 1 umhos/cm
TOTAL DISSOLVED SOLIDS (TDS) 160.1 10.0
CHEMICAL OXYGEN DEMAND (COD) 410.4 3.0
BIOCHEMICAL OXYGEN DEMAND (BOD) 405.1 4.0
TOTAL ORGANIC CARBON (TO C) 415 1.0
TOTAL ORGANIC HALIDES (TOX) 9020 0.02
TOTAL ALKALINITY AS CaC03 310.1 1.0
METALS:
LEAD 6010 0.02
NICKEL 6010 0.04
PESTICIDES AND PCBs: (UG/Ll
ALDRIN 608 0.05
alpha-BHC 608 0.05
beta-BHC 608 0.05
delta- BHC 608 0.05
gamma - BHC (Lindane) 608 0.05
CHLORDANE (alpha) 608 0.05
4,4'- DOD 608 0.10
IR/6-94/KBN760211rl.tl
MCL
(MG/Ll
--
900 umhos/cm
1000
--
--
--
--
--
0.05 0.10
(UG/L)
--
--
--
--
0.2 0.1
--
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Table 1
Analytical Methods and Detection Limits
Market Place Sanitary Landfill
Project No. 760211
(Sheet 2 of 2)
METHOD OF APPROXIMATE
ANALYSIS DETECTION
ANALYTE (EPA Method) LIMIT
4,4'- ODE 608 0.10
4,4'- DDT 608 0.10
DIELDRIN 608 0.10
ENDOSULFAN I 608 0.05
ENDOSULFAN II 608 0.10
ENDRIN ALDEHYDE 608 0.10
EN ORIN 608 0.10
ENDOSULFAN SULFATE 608 0.05
HEPTACHLOR 608 0.01
HEPTACHLOR EPOXIDE 608 0.01
TOXAPHENE 608 1.0
PCB- 1016 608 0.5
PCB- 1221 608 0.5
PCB- 1232 608 0.5
PCB- 1242 608 0.5
PCB- 1248 608 0.5
PCB- 1254 608 1.0
PCB- 1260 608 0.10
Note: MCL- State of California Maximum contaminant level for drinking water.
IR/6-94/KBN7602llrl.tl
MCL
--
--
--
--
--
--
0.2 --
0.01 0.01
5.0 --
--
--
--
--
--
--
Parameter
Inorganic Tests
Alkalinity
Biochemical oxygen demand
Total organic carbon
Total organic halides
Chemical oxygen demand
Hydrogen ion (pH)
Residue, filterable
Specific conductance
Metals (Dissolved)d
Organic Tests
8 Pesticides
PCBs
See footnotes at end of table.
IR/06-941WPC/f:projects:02llrl.t2
Table 2
Sampling and Preservation Requirements
Market Place Sanitary Landfill
Project No. 760211
(Sheet 1 of 2)
Volume
Required
Containera (ml) Preservationb
P,G 100 Cool 4°C
P,G 100 Cooi4°C
P,G 25 Cool 4°C, HCL/H 2 S04 to pH <2
P,G 250 Cool 4°C, HCL/H 2 S04 to pH < 2
P,G 75 Cool 4°C, H2S04 to pH < 2
P,G 25 None required
P,G 100- Cool 4°C
P,G 100 Cool 4°C
p 500 Cool 4°C (filtered, HN0 3 to
ph< 2)d
p 1000 Cool 4°C, Na2S203 to pH 5-9
p 1000 Cooi4°C
Maximum Holding
Tim esc
14 days
48 hours
28 days
7 days
28 days
Analyze immediately
48 hours
28 days
6 months
7 days until
extraction, 40 days
after extraction
7 days until
extraction, 40 days
after extraction
,-·- , r --
Table 2
Sampling and Preservation Requirements
Market Place Sanitary landfill
Project No. 760211
(Sheet 2 of 2)
Reference: This table includes the requirements of the U.S. Environmental Protection Agency, as published in the Code of Federal Regulations, Vol. 49, No. 209, 40 CFR 136, October 26, 1984, pg. 43260. "Polyethylene (P) or glass (G)
bSample preservation should be performed immediately upon sample collection. For composite chemical samples, each aliquot should be preserved at the time of collection. When use of an automatic sampler makes it impossible to preserve each aliquot, then chemical samples may be preserved by maintaining at 4°C until compositing and sample splitting is completed. csamples should be analyzed as soon as possible after collection. The times listed are the maximum times that samples may be held before analysis and still be considered valid. Samples may be held for longer periods only if the permittee or monitoring laboratory has data on file to show that the specific types of samples under study are stable for the longer time. Some samples may not be stable for the maximum time period given in the table. A permittee or monitoring laboratory is obligated to hold the sample for a shorter period if knowledge exists to show this is necessary to maintain sample stability. dSamples for dissolved metals should be field filtered using 0.45 micron filter paper. The filtered sample should then be poured into a 500ml polyethylene bottle containing H2S0 4 preservatives and maintained at 4°C until analysis. "Guidance applies to samples to be analyzed by GC, LC, or GC/MS for specific compounds.
IR/06-94/WPC/f:projects:02llrl.t2
FIGURES
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SITE~ 0 2000 4000 FEET
REFERENCE:
USGS 7.5 MINUTE TOPOGRAPHIC MAP OF
LONG BEACH, LOS ALAMITOS AND SEAL BEACH,
CALIFORNIA QUADRANGLE; DATE: 1964, 1964 AND
1965 RESPECTIVELY; PHOTOREVISED: 1981; SCALE 1:24000
FIGURE
TOPOGRAPHIC MAP
MARKET PLACE LANDFILL
PREPARED FOR
BIXBY RANCH COMPANY
SEAL BEACH, CALIFORNIA
m ... Creating a Safer Tomorrow
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LEGEND
-5-- TOPOGRAPHIC CONTOUR
SWAT MONITORING WELL
SCALE
__,
0 600 1200 FEET
REFERENCE:
BASE MAP-CITY OF LONG BEACH, DEPARTMENT
OF ENGINEERING, 1978 THROUGH 1982.
FOR TOPOGRAPHIC REFERENCE, SEE FIGURE I.
"Do Not Scale Th1s Draw1ng ..
;;·
FIGURE 2
DETAILED TOPOGRAPHIC MAP OF
MARKET PLACE LANDFILL
PREPARED FOR
BIXBY RANCH COMPANY
SEAL BEACH, CALIFORNIA
[]] ... Creating a Safer Tomorrow
/
• STATE OF CALIFORNIA-ENVIRONMENTAL PROTE( =I =AG=E=N=C'i===========l( ~~IV
PETE WILSON, Go.-ernor
•'
CALIFORNIA REGIONAL WATER QUALITY CONTROL BOARD
LOS ANGELES REGION
101 CENTRE PLAZA DRIVE
MONTEREY PARK, CA 9175.4-2156
(213) 266-7500
FAX: (213) 266-7600
September 19, 1994
Mr. Timothy King
Bixby Ranch Company
3010 Old Ranch Parkway, Suite 100
Seal Beach, CA 90740
ADDITIONAL SWAT MONITORING - MARKET PLACE SANITARY LANDFILL (CITY DUMP SALVAGE NO. 2), LONG BEACH (FILE NO. 60-89)
Thank you for the June 1994, "Work Plan for Semi-Annual Groundwater Sampling and Analysis" for the subject site, submitted in your behalf by International Technology Corporation. We apologize for the delay in commenting on the workplan, but did not receive your original June . 1994 submittal. A resubmittal was received on September 9, 1994.
The workplan generally meets the requirements of this Regional · Board. It is approved contingent upon receiving written confirmation that, in addition to pesticides and PCBs (EPA Method 608), dissolved lead and nickel, and leachate indicators, ground water samples will also be analyzed for volatile organic compounds (VOCs) (EPA Method 624), all heavy metals, and general minerals, as specified in our April 20, 1994, letter to the Bixby Ranch Company (copy attached) . After the first round of sampling results are received, Regional Board staff will review them for consistency with the original SWAT data and reduce the required analytes for . the second round of sampling, if appropriate.
Please also specify the method detection limits that the laboratory will be using for the VOC analyses.
Should you have any questions, please contact Blythe Ponek Bacharowski at (213) 266-7580.
RODNEY H. · NELSON
Senior Engineering Geologist
Landfills Unit
attachment
cc: Liz Haven, State Water Resources Control Board
Charlene Herbst, California Integrated Waste Management Board Bea Anderson, City of Long Beach, Department of Health
Kevin Aardahl, International Technology Corporation
/
(- - .·
STATE OF CALIFORNIA-ENVIRONMENTAL PROTECr.vN AGENCY
CALIFORNIA REGIONAL WATER QUALITY CONTROL BOARD
. LOS ANGELES REGION
101 CENTRE PLAZA DRIVE
MONTEREY PARK, CA 91754-2156
(213) 266-7500
FAX: (213) 266-7600
April 20, 1994
Mr. Ron Bradshaw
Bixby Ranch Company
3010 Old Ranch Parkway, Suite 100
Seal Beach, CA 90740
PETE WILSON, Governor
SWAT REPORT FINDINGS • MARKET PLACE SANITARY LANDFILL (CITY DUMP SALVAGE NO. 2) 1 LONG BEACH (FILE NO. G0-89)
We have· reviewed your ·June 1989 Preliminary SWAT Report, and January 1991 Addendum Report, submitted for the subject site on your behalf by International Technology Corporation. Based upon our review of these reports,·and the results of quarterly ground water monitoring performed between October 1988 and September 1989, we make the following findings:
1. This disposal. site is located in a flat, tidal marshland within the Alamitos Gap, in an area of seawater intrusion.
Ground water quality at this site is influenced by the
intermixing of ·freshwater from the adjacent San Gabriel River, and the seawater of the Long Beach Marina, located less than
2. 1/4 mile away. - --------------------------
Existing beneficial uses of the Long Beach Marina,
hydraulically connected to the ground water beneath this disposal site, include commercial and sport fishing,
preservation of rare endangered species, marine habitat, non contact water-recreationr-and.the .. potential use of shellfish harvesting. . -0---·-------=-=~')
3. Historical data indicate-that refuse may have been deposited into trenches excavated below the ground water table. The depth to ground water at this site averages approximately 10 ·feet below land surface,- and refuse, in some areas, may be inundated by ground water.
4. The following volatile organic compounds (VOCs) were detected (EPA Method 624) in ground water monit-oring wells at this site. . Only benzene · was detected in concentrations which exceed the California Department of Health Services' Maximum Contaminant Levels (MCLs): ·
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Mr. Bradshaw